CN1174008C - 聚合烯烃的方法、聚烯烃以及由其制备的薄膜和制品 - Google Patents

聚合烯烃的方法、聚烯烃以及由其制备的薄膜和制品 Download PDF

Info

Publication number
CN1174008C
CN1174008C CNB99817100XA CN99817100A CN1174008C CN 1174008 C CN1174008 C CN 1174008C CN B99817100X A CNB99817100X A CN B99817100XA CN 99817100 A CN99817100 A CN 99817100A CN 1174008 C CN1174008 C CN 1174008C
Authority
CN
China
Prior art keywords
hydrogen atoms
contain
group
hydrogen
halogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CNB99817100XA
Other languages
English (en)
Chinese (zh)
Other versions
CN1406250A (zh
Inventor
R��R������
R·R·福特
小R·K·斯图尔特
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Westlake Longview Corp
Original Assignee
Eastman Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chemical Co filed Critical Eastman Chemical Co
Publication of CN1406250A publication Critical patent/CN1406250A/zh
Application granted granted Critical
Publication of CN1174008C publication Critical patent/CN1174008C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
CNB99817100XA 1999-06-25 1999-10-14 聚合烯烃的方法、聚烯烃以及由其制备的薄膜和制品 Expired - Lifetime CN1174008C (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US14114199P 1999-06-25 1999-06-25
US60/141,141 1999-06-25
US38654699A 1999-08-31 1999-08-31
US09/386,546 1999-08-31

Publications (2)

Publication Number Publication Date
CN1406250A CN1406250A (zh) 2003-03-26
CN1174008C true CN1174008C (zh) 2004-11-03

Family

ID=26838826

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB99817100XA Expired - Lifetime CN1174008C (zh) 1999-06-25 1999-10-14 聚合烯烃的方法、聚烯烃以及由其制备的薄膜和制品

Country Status (8)

Country Link
US (1) US20020004566A1 (enExample)
EP (1) EP1194459B1 (enExample)
JP (1) JP2003503561A (enExample)
CN (1) CN1174008C (enExample)
BR (1) BR9917391B1 (enExample)
CA (1) CA2377259A1 (enExample)
DE (1) DE69928969T2 (enExample)
WO (1) WO2001000691A1 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
WO2004046214A2 (en) 2002-10-15 2004-06-03 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7053158B2 (en) * 2003-09-22 2006-05-30 Agency For Science, Technology And Research Carborane trianion based catalyst
US7238756B2 (en) 2003-10-15 2007-07-03 Univation Technologies, Llc Polymerization process and control of polymer composition properties
US6828395B1 (en) 2003-10-15 2004-12-07 Univation Technologies, Llc Polymerization process and control of polymer composition properties
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
JP5325023B2 (ja) * 2009-05-28 2013-10-23 三菱重工業株式会社 含水固体燃料の乾燥装置及び乾燥方法
US9034685B2 (en) * 2011-02-11 2015-05-19 Dow Global Technologies Llc Methodology for forming pnictide compositions suitable for use in microelectronic devices
EP3102661B1 (en) 2014-02-07 2020-08-05 GOJO Industries, Inc. Compositions and methods with efficacy against spores and other organisms

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4659685A (en) * 1986-03-17 1987-04-21 The Dow Chemical Company Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
FR2656315B1 (fr) * 1989-12-22 1992-04-17 Bp Chemicals Snc Procede de preparation d'un catalyseur a base de zirconium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
US5258475A (en) * 1991-07-12 1993-11-02 Mobil Oil Corporation Catalyst systems for polymerization and copolymerization of olefins
US5608019A (en) * 1992-12-28 1997-03-04 Mobil Oil Corporation Temperature control of MW in olefin polymerization using supported metallocene catalyst
AU6596694A (en) * 1993-06-28 1995-01-05 Union Carbide Chemicals & Plastics Technology Corporation Use of lewis bases for activity reduction in metallocene catalyzed olefin polymerization process
EP0728151B1 (en) * 1993-11-08 2001-03-21 Mobil Oil Corporation Process for the polymerization or copolymerization of ethylene
US6417299B1 (en) * 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers
US6417298B1 (en) * 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers

Also Published As

Publication number Publication date
CN1406250A (zh) 2003-03-26
BR9917391B1 (pt) 2009-05-05
EP1194459B1 (en) 2005-12-14
BR9917391A (pt) 2002-03-12
WO2001000691A1 (en) 2001-01-04
US20020004566A1 (en) 2002-01-10
EP1194459A1 (en) 2002-04-10
CA2377259A1 (en) 2001-01-04
DE69928969T2 (de) 2006-06-14
JP2003503561A (ja) 2003-01-28
DE69928969D1 (de) 2006-01-19

Similar Documents

Publication Publication Date Title
JP5685233B2 (ja) エチレンとオレフィンとのコポリマー並びにそれから製造されるフィルム及び物品
CN1138792C (zh) 双反应器乙烯聚合方法
CN1188431C (zh) 有机金属化合物催化剂
RU2233292C2 (ru) Способ введения в растворе нескольких катализаторов
US9062134B2 (en) Half-metallocene compounds and catalyst compositions
CN1174008C (zh) 聚合烯烃的方法、聚烯烃以及由其制备的薄膜和制品
CN1165151A (zh) 长链支化聚烯烃的生产方法
CN1177869C (zh) 生产聚烯烃的工艺
JP5662083B2 (ja) ポリオレフィンの重合媒体の静電荷を減少させる方法
CN1174009C (zh) 聚烯烃生产方法
CZ20002404A3 (cs) Způsob polymerace olefinů, nové polyethyleny a film a výrobky z nich vyrobené
MXPA00006282A (en) Process for the polymerization of olefins;polyethylenes, and films and articles produced therefrom
HK1015791A1 (en) Metallocenes, their preparation and use in the polymerization of alphaolefins
HK1015791B (en) Metallocenes, their preparation and use in the polymerization of alphaolefins

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
ASS Succession or assignment of patent right

Owner name: WESTLAKE LONGVIEW CORPORATION

Free format text: FORMER OWNER: YISIMAN CHEMICAL COMPANY

Effective date: 20070518

C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20070518

Address after: American Texas

Patentee after: Westlake Longview Corp.

Address before: Tennessee

Patentee before: Eastman Chem Co.

CX01 Expiry of patent term
CX01 Expiry of patent term

Granted publication date: 20041103