CN1172868C - Environment protecting cement-base composite material - Google Patents

Environment protecting cement-base composite material Download PDF

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Publication number
CN1172868C
CN1172868C CNB011271833A CN01127183A CN1172868C CN 1172868 C CN1172868 C CN 1172868C CN B011271833 A CNB011271833 A CN B011271833A CN 01127183 A CN01127183 A CN 01127183A CN 1172868 C CN1172868 C CN 1172868C
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CN
China
Prior art keywords
cement
composite material
flyash
base composite
environment protecting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB011271833A
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Chinese (zh)
Other versions
CN1403402A (en
Inventor
伟 孙
孙伟
张亚梅
刘斯凤
秦鸿根
李刚
赖建中
林玮
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Southeast University
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Southeast University
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Filing date
Publication date
Application filed by Southeast University filed Critical Southeast University
Priority to CNB011271833A priority Critical patent/CN1172868C/en
Publication of CN1403402A publication Critical patent/CN1403402A/en
Application granted granted Critical
Publication of CN1172868C publication Critical patent/CN1172868C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The present invention discloses a cement-based composite material with environmental protection, which comprise active components, fine aggregating materials, water and a superplasticizer, wherein the active components comprise 1 portion of cement and 0.2 to 1.5 portions of pulverized coal ash according to proportion by weight. The active components can comprise1 portion of cement, 0.2 to 1.3 portions of pulverized coal ash and 0.05 to 0.2 portion of silica ash according to proportion by weight, and can also comprise 1 portion of cement, 0.2 to 0.8 portion of mineral powder and 0.2 to 0.8 portion of pulverized coal ash according to proportion by weight. Because the mineral powder and the pulverized coal ash which are industrial waste residues are used as raw materials, the cement-based composite material has the advantages of environmental protection, cost reduction and high compressive resistance.

Description

Environment protecting cement-base composite material
(1) technical field: the present invention relates to a kind of material of construction, especially a kind of environment protecting cement-base composite material.
(2) technical background: the super high strength concrete that reaches 150-200MPa for ultimate compression strength, be starting material with cement, silicon ash, sand, ultrafine quartz powder, superplasticizer, water, fine steel fiber in the world, by hot water maintenance or high-temperature pressurizing maintenance, prepare ultimate compression strength and reached 170-230MPa, bending strength reaches the very-high performance RPC of 30-60MPa, but this material exists the manufacturing cost height, is not suitable for the defective that China produces.The reason that this defective produces is: 1. used raw material silicon ash volume height (more than 25%) in the prior art, and the silicon of China ash output is very low, price height (being higher than 2500 yuan/ton) is difficult to realize that the large-scale popularization of RPC uses.In addition, the silicon ash is light especially because of it, transportation inconvenience.2. the levigate silica powder consumption of used starting material big (more than 30%) in the prior art, energy consumption is big, price is high.
(3) summary of the invention:
Technical problem the present invention is directed to the high defective of material cost in the prior art, proposes the environment protecting cement-base composite material that a kind of cost is low and performance is fair.
A kind of environment protecting cement-base composite material of technical scheme comprises: active constituent, fine aggregate, water and superplasticizer, active constituent comprises: cement and flyash, its proportioning (weight ratio) is: cement: flyash=1: (0.2-0.5).
Beneficial effect is 1. because the present invention has utilized flyash, breeze as its raw material, consumed the existing industrial residue that is unfavorable for environmental protection, both reduced cost, help environmental protection again, in addition, the present invention has the high advantage of ultimate compression strength, its ultimate compression strength is higher than 100 MPas, even be higher than 120 MPas, so the present invention is the environment protecting cement-base composite material that a kind of performance is fair and cost is low.2. the adding of silicon ash has further improved ultimate compression strength, make its ultimate compression strength be not less than 150 MPas, though the adding of silicon ash has slightly improved cost, but because the add-on of silicon ash is lower than the add-on of prior art, so, the technical measures that add the silicon ash had both improved ultimate compression strength, had kept the cheap relatively advantage of cost again.3. fortifying fibre can improve more than the ultimate compression strength 10%-30%, and bending strength improves more than 2-4 times, and energy-to-break improves more than 50 times.4. comprise the technical scheme of components such as breeze, cement, flyash, silicon ash, fortifying fibre, can make ultimate compression strength of the present invention reach 160-250MPa, bending strength reaches 30-60MPa.5. fine aggregate adopts natural fine sand to help further reducing cost, and not only can make the present invention with low cost by the fine aggregate that natural fine sand and levigate silica powder are formed, and can improve ultimate compression strength of the present invention.
(4) embodiment: the present invention is a kind of environment protecting cement-base composite material, comprise: active constituent, fine aggregate, water and superplasticizer, active constituent comprises: cement and flyash, its proportioning (weight ratio) is: cement: flyash=1: (0.2-1.5), can select for use 1: 0.2, also can select for use 1: 1.5, can also select 1: 0.5 or 1: 1.1 etc. for use, active constituent of the present invention also comprises the silicon ash, cement, the proportioning of flyash and silicon ash (weight ratio) is: cement: flyash: silicon ash=1: (0.2-1.3): (0.05-0.2), can select for use 1: 0.2: 0.05, also can select for use 1: 1.3: 0.2, can also select for use 1: 1: 0.06,1: 0.4: 0.17 or 1: 0.7: 0.12, active constituent of the present invention also comprises breeze, cement, the proportioning of breeze and flyash (weight ratio) is: cement: breeze: flyash=1: (0.2-0.8): (0.2-0.8), for example: its proportioning (weight ratio) can be selected for use 1: 0.2: 0.2, also can select for use 1: 0.8: 0.8, can also select for use 1: 0.3: 0.7,1: 0.7: 0.4 or 1: 0.4: 0.4, in the present embodiment, the present invention includes fortifying fibre, the fortifying fibre volume that is added is the 1%-3% of the mixed back of all the other components cumulative volume, above-mentioned fine aggregate is that natural fine sand or above-mentioned fine aggregate are made up of natural fine sand and levigate silica powder, and levigate silica powder normally particle diameter is not more than 0.1 millimeter silica powder.The proportioning of active constituent and fine aggregate, water, superplasticizer (weight ratio) is 1: (1-1.4): (0.14-0.25): (0.01-0.02).Manufacturing process of the present invention is as follows: (1) active constituent is stirred (if superplasticizer adopts pulvis, then stirring simultaneously with active constituent); (2) fine aggregate is added in the active constituent stir; (3) fortifying fibre is scattered in the above-mentioned mixed material, makes fiber dispersion even; (4) water (if superplasticizer adopts aqua, then adding simultaneously with water) is added in the mixed material of front, stir; (5) with above-mentioned mixed material dress mould, vibratory compaction, curing in the mold demoulding after 24 hours; (6) test specimen after the demoulding was carried out 60-90 ℃ of hot water maintenance 1-3 days or through the hot water maintenance after 1-3 days again through 160-300 ℃ of high temperature steam press maintenance 6-12 hour, or some days of maintenance in the environment of preserving moisture naturally.

Claims (5)

1. environment protecting cement-base composite material, it is characterized in that forming by active constituent, fine aggregate, water, fortifying fibre and superplasticizer, the weight ratio of active constituent and fine aggregate, water, superplasticizer is 1: (1-1.4): (0.14-0.25): (0.01-0.02), the fortifying fibre volume that is added is the 1%-3% of the mixed back of whole components cumulative volume, active constituent comprises: cement and flyash, its weight ratio is: cement: flyash=1: (0.2-1.5).
2. environment protecting cement-base composite material according to claim 1, it is characterized in that active constituent is made up of cement, flyash and silicon ash, the weight ratio of cement, flyash and silicon ash is: cement: flyash: silicon ash=1: (0.2-1.3): (0.05-0.2).
3. environment protecting cement-base composite material according to claim 1, it is characterized in that active constituent is made up of cement, breeze and flyash, the weight ratio of cement, breeze and flyash is: cement: breeze: flyash=1: (0.2-0.8): (0.2-0.8).
4. environment protecting cement-base composite material according to claim 1 and 2 is characterized in that fine aggregate is natural fine sand.
5. environment protecting cement-base composite material according to claim 1 and 2 is characterized in that fine aggregate is made up of natural fine sand and levigate silica powder.
CNB011271833A 2001-09-07 2001-09-07 Environment protecting cement-base composite material Expired - Fee Related CN1172868C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB011271833A CN1172868C (en) 2001-09-07 2001-09-07 Environment protecting cement-base composite material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB011271833A CN1172868C (en) 2001-09-07 2001-09-07 Environment protecting cement-base composite material

Publications (2)

Publication Number Publication Date
CN1403402A CN1403402A (en) 2003-03-19
CN1172868C true CN1172868C (en) 2004-10-27

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101143775B (en) * 2007-08-29 2011-02-02 北京振利高新技术有限公司 Large adulteration quantity fly ash gel material for building mortar and preparation method thereof

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US7714897B2 (en) * 2005-09-15 2010-05-11 Nokia Corporation Trigger tone of a camera
CN100393661C (en) * 2006-03-22 2008-06-11 西安建筑科技大学 Concrete used for shaped-steel and concrete joint construction
CN101713236B (en) * 2009-11-30 2011-03-02 陈兆平 Light and high-strength wallboard made from fiber reinforced concrete and preparation method thereof
CN101805158B (en) * 2010-04-14 2012-07-04 东南大学 High-strength panel with favorable fireproof performance
CN101823860B (en) * 2010-05-25 2012-04-25 陈耀强 High-strength active powder fiber concrete slab and manufacturing method thereof
CN102092996A (en) * 2010-11-30 2011-06-15 南京理工大学 Cement-based composite material with high-temperature resistance and superhigh performance and preparation method thereof
CN102079647A (en) * 2010-11-30 2011-06-01 南京理工大学 Basalt fiber reinforced cement matrix composite and preparation method thereof
DE102011107285A1 (en) * 2011-07-06 2013-01-10 Thomas Teichmann Ultra-high-strength concrete
CN102503292B (en) * 2011-10-21 2013-07-31 黄贺明 Concrete and preparation method thereof
CN102976682A (en) * 2012-11-27 2013-03-20 常州大学 Environment friendly cement-based composite material
CN104386966B (en) * 2014-11-04 2016-09-21 潍坊德霖建材科技有限公司 A kind of high performance corrosion-proof is dry mixed waterproof mortar
CN110204268A (en) * 2019-04-10 2019-09-06 浙江大学 A kind of superelevation is centrifuged by force electric pole fiber concrete and preparation method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101143775B (en) * 2007-08-29 2011-02-02 北京振利高新技术有限公司 Large adulteration quantity fly ash gel material for building mortar and preparation method thereof

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Granted publication date: 20041027

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