CN100393661C - Concrete used for shaped-steel and concrete joint construction - Google Patents
Concrete used for shaped-steel and concrete joint construction Download PDFInfo
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- CN100393661C CN100393661C CNB2006100419595A CN200610041959A CN100393661C CN 100393661 C CN100393661 C CN 100393661C CN B2006100419595 A CNB2006100419595 A CN B2006100419595A CN 200610041959 A CN200610041959 A CN 200610041959A CN 100393661 C CN100393661 C CN 100393661C
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract
The present invention discloses concrete for steel reinforced concrete composite structure. Cement, coarse aggregate, fine aggregate, water, a high efficiency water reducing agent, silica fume and dust coal can be made into concrete with different strength grades according to different proportion. The concrete has the advantages of good mechanical performance(comprising strength, plasticity and adhesive performance with profile steel), excellent working performance, good durability and relatively low cost, and is suitable for the steel reinforced concrete composite structure. The concrete can reduce construction working procedure, save steels and enhance the efficiency of construction, so the present invention has remarkable economic benefits.
Description
Technical field
The present invention relates to a kind of concrete, particularly a kind of concrete that is used for reinforced concrete composite structure.
Background technology
Shaped steel high-strength high-performance concrete unitized construction is the application of novel High Technique Concrete in steel reinforced concrete (SRC) unitized construction.Wherein, reinforced concrete composite structure (being called for short the SRC structure) is a kind of principal mode of steel-concrete combined structure, because its supporting capacity height, rigidity reach advantages such as anti-seismic performance is good greatly, be applied to more and more to stride greatly, the high level and the high-rise building of heavy type structure and seismic region.SRC texture ratio steel construction can be saved great deal of steel, and increasing section rigidity has overcome shortcomings such as steel construction resistivity against fire and poor durability and easy flexing unstability, and the ability of steel is fully played, and general comparable pure steel structure is saved steel about 50%.Compare with ordinary reinforced concrete (RC) structure, the ratio of reinforcement of joining in the comparable skeleton construction of steel rate in the steel reinforced concrete structure is a lot of greatly, therefore can in limited section area, dispose more steel, so the supporting capacity of steel reinforced concrete member is higher than the supporting capacity of reinforced concrete member of same profile more than one times, thereby can reduce the sectional dimension of member effectively, avoid the normal fat beams and columns phenomenon that occurs in the skeleton construction, increase the usable floor area and the headroom of building structure and reduce the cost of building, obtain remarkable economic efficiency.In construction, the Steel Skeleton of steel reinforced concrete structure can be used as and bears whole construction loads supporting system of (comprise and hang mould and institute's pouring concrete), has simplified the formwork engineering greatly.Because it is strong that the SRC structure has globality, advantages such as good working ductility, can improve the fragility character of Steel Concrete sheared destruction greatly, structural seismic performance is significantly improved, intensity and ductility all are greatly improved than reinforced concrete structure, therefore even in high-rise steel structure, the bottom several layers also often is the SRC structural shape, as the Kowloon mansion in emperor's mansion in Shanghai Jin Mao Tower, Shenzhen, Hong Kong and international public finance center etc.Show in the 95 building numbers of plies of investigation are 7～17 layers SRC building, only have 13% (Building 12) that the main body slight damage takes place towards the statistics of earthquake according to Japan city wall county in 1978.Therefore in developed countries such as Japan and America and Europes, SRC structure and steel construction, timber structure, skeleton construction also are called four macrostructures.Japan's earthquake resistant code regulation: the buildings that highly surpasses 45 meters must not use skeleton construction, and steel reinforced concrete structure is then not limited.China also is earthquake country more than, and most areas be the seismic region, and some areas are positioned at the highly seismic region, so in China, and is particularly underdeveloped and be subjected to the bigger west area popularization SRC structure of earthquake effect just to have very important realistic meaning.Up to the present, the floor area of building of China employing SRC structure is about the thousandth of gross floors area, and Japan adopts the buildings of SRC structure to account for 62.8% of gross building area in the buildings more than six layers.Therefore, the SRC structure has boundless application prospect in China, especially along with the successful development of the continuous enhancing of China's economic strength and high-strength steel and high-strength high-performance concrete (they be putative 21 century material) with use, will promote applying of this structural system.
Good cohesive action is the basis that guarantees shaped steel and concrete co-ordination in the steel reinforced concrete member between shaped steel and the concrete, shaped steel, reinforcing bar and three kinds of material elements collaborative works of concrete, to resist various external action effects, can give full play to the advantage of reinforced concrete composite structure.But the remarkable difference of steel reinforced concrete structure and skeleton construction is the cohesive force between shaped steel and the concrete and is far smaller than the cohesive force between reinforcing bar and the concrete that the cohesive force of shaped steel and normal concrete approximately only is equivalent to 45% of plain bar cohesive force.Domestic and international many experimental study results show, exist the bonding sliding phenomenon between shaped steel and the concrete, and the stress performance of SRC member is had remarkably influenced.Therefore, how to guarantee shaped steel and concrete effectively collaborative work become one of emphasis of reinforced concrete composite structure research.Treatment process to bonding slippage problem between shaped steel and the concrete in the engineering design at present generally has two kinds: the first adds shearing connecting piece in component surface, certainly will cause the inconvenience in the construction like this and improve cost; It two is the supporting capacitys that reduce member, to consider the bonding sliding influence, certainly exists uneconomic factor like this.On the other hand, ubiquity is focused on intensity and the phenomenon of light weather resistance in the engineering structure design, has occurred the security in use of many concrete structures and the problem of weather resistance aspect both at home and abroad.Half is promptly because alkali-aggregate reaction, chlorion erosion etc. are former thereby completely lose functions of use and even supporting capacity using not enough design period for some concrete structures, indivedual engineerings even partial collapse occurs or integral body is collapsed cause casualties or Architectural Equipment is destroyed.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, a kind of concrete that is used for reinforced concrete composite structure is provided.This concrete can improve the adhesive property between shaped steel and the concrete, and can improve durability of structures, and has good working performance, high volume stability and economy.
For solving the problems of the technologies described above, the present invention is achieved in that
Strength grade of concrete is C60, and this mix proportion is:
Cement: coarse aggregate: fine aggregate: water: high efficiency water reducing agent: flyash is: (unit: Kg/m
3):
350∶700∶1150∶150∶8∶150。
Described high efficiency water reducing agent is selected polycarboxylic acid series high efficiency water reducing agent, and water-reducing rate is greater than 25%.
The invention has the beneficial effects as follows:
1. the concrete of the present invention's production is a kind of high-strength high-performance concrete that is applicable to reinforced concrete composite structure.It can guarantee its mechanics (being intensity and the plasticity) performance that should possess and having on the basis of high-durability, high workability, high volume stability and economy, improved the adhesive property between concrete and the shaped steel significantly, make in steel reinforced concrete structure design and need not (or only needing a little ground) and add shearing connecting piece in component surface, can guarantee shaped steel and concrete effective collaborative work, thereby reduced working procedure, steel have been saved, improve operating efficiency, had remarkable economic efficiency.
2. the high efficiency water reducing agent that uses among the present invention is compared the water reducer of other type, does not wherein contain Na
2SO
4, can further improve concrete weather resistance.
3. the high-strength high-performance concrete produced of the present invention is realized under the normal concrete manufacturing condition, and raw materials for production are that the locality can get, and are convenient to large-scale promotion application, have the good social benefit.
4. containing a large amount of industrial wastes in the high-strength high-performance concrete raw material that the present invention produces, meet the requirement of Sustainable development, is a kind of green concrete.
5. the present invention is the high-strength high-performance concrete of producing under the condition that does not change conventional production process that is used for reinforced concrete composite structure.
Embodiment:
The present invention is improving the adhesive property between shaped steel and the concrete, and to improve durability of structures be aim, studies the technology of preparing of the high-strength high-performance concrete that is used for reinforced concrete composite structure.Owing to make the used cement type quality height of high-strength high-performance concrete, and to the processing request height of active mineral admixture, the research of basic raw material such as high efficiency water reducing agent, superplasticizer has all obtained bigger progress both at home and abroad at present with using in addition, thereby has identified the basis for the realization of above-mentioned research aim.Simultaneously, the cement consumption that high-strength high-performance concrete requires is less, means a large amount of dischargings of carbonic acid gas and produce cement, thereby has alleviated the Greenhouse effect that the earth is caused to a certain extent; Its requires to have the adulterants such as flyash, slag of sufficient amount, means the reasonable disposal utilization of industrial waste, will help forming good production cycle and environment protection, and that these conditions are improved the concrete material self performance just is needed.Use high-strength high-performance concrete and can save material, prolong engineering working life, and finally preserve the ecological environment and natural resources.In sum, the research and development that are used for the high-strength high-performance concrete of reinforced concrete composite structure will have been walked out the road of a Sustainable development for using concrete better.
The high-strength high-performance concrete of the present invention's development has also added its indispensable component: high efficiency water reducing agent and mineral admixture except adopting materials similar-cement, sand, stone, the water with normal concrete.High-strength high-performance concrete is different with normal concrete, and its intensity and performance all are greatly improved than normal concrete.The water cement ratio of high-strength high-performance concrete is generally all less than 0.38, and the water cement ratio of normal concrete is generally more than 0.45, and the maximum aggregate size of high-strength high-performance concrete is also less than normal concrete.Above-mentioned every difference has caused high-strength high-performance concrete and normal concrete that very big difference is arranged on performance, by adding mineral superfine powder, the interface structure in the high-strength high-performance concrete between aggregate and the cement stone and the pore structure of cement stone all are improved, typical dense structure can expand to aggregate surface, thereby make concrete closely knit more hard, mechanical properties of concrete (comprise and shaped steel between adhesive property) and endurance quality all improve a lot.
Similar with concrete bonding to plain bar, shaped steel and concrete cohesive force mainly are made up of chemical bond power, friction resistance and mechanical snap power three parts.Each component part of cohesive force is all closely related with concrete performance.
Chemical bond power is chemical clinging power or the adsorptive power that the cement gel body in the concrete produces on the shaped steel surface, and its (shearing resistance) ultimate value depends on the character of cement and the degree of roughness of rebar surface.During casting concrete, cement slurry produces surface tension on the surface of steel, and under capillary effect, the cement slurry on the steel surface will form self-equilibrating; Deposit concrete generally will vibrate, and the infiltration of cement slurry to the steel surface zone of oxidation can be strengthened and accelerate to the power of vibrating (disturbance); Cement slurry crystallization in maintenance processes, and then crystal forms chemical bond power.Chemical bond power only exists under the original formation state of member, in case the bonding slippage on the joint face takes place, the cement crystal is just cut off and attrition crushing, and chemical bond power is then lost.The main factor that influences chemical bond power has concrete strength, shaped steel surface appearance, test specimen to build mode and the maintenance and the concrete contraction situation in vibrate degree and later stage.
After the chemical bond power forfeiture,, make that the concrete crystal grain is interlocked on itself and the contact surface, so just formed mechanical snap power owing to the coarse injustice and the caused steel surface changed condition of other reason (uneven) of steel surface.For the rolling joist steel of handling plant produced and postmenstruation, in case bonding slippage development strengthens the crushed integration of concrete crystal on steel and the concrete surface, at this moment also substantial loss of mechanical snap power.The principal element that influences mechanical snap power is the degree of roughness of steel surface and the force way of surface appearance, concrete grating, concrete strength and test specimen.
The shaped steel surrounding concrete also is to form in concrete clinging power forfeiture back to the friction resistance of shaped steel, and mainly is just to play a role after mechanical snap power is lost substantially.When chemical glue is puted forth effort; especially after the forfeiture of mechanical snap power; owing to cut off crushing and expansion with the concrete crystal on the shaped steel contact surface; lateral confinement such as protective layer and stirrup in addition; to on shaped steel and concrete joint face, produce positive pressure; add that frictional coefficient is bigger on the joint face, thereby formed friction resistance.Friction resistance all exists after the forfeiture of chemical bond power always, is the major portion of later stage cohesive force between shaped steel and the concrete.The factor (protective layer thickness, stirrup ratio, concrete shrinkage) that the factor that influences friction resistance has the surface characteristic of shaped steel, force way, concrete grating and influences lateral confinement.
Key technical problem to be solved by this invention is, guarantee high-strength high-performance concrete mechanics (being intensity and the plasticity) performance that should possess and having on the basis of high-durability, high workability, high volume stability and economy, improve the adhesive property between concrete and the shaped steel significantly, make in steel reinforced concrete structure design to need not (or only needing a little ground) and add shearing connecting piece, can guarantee shaped steel and concrete effective collaborative work in component surface.
The present invention is on principle and principle of design, break the restriction of " full sieve rice " formula, by contrast experiment's method, consider the consistency of high efficiency water reducing agent and cement simultaneously, aggregate size is to the performance factors such as pozzolanic activity of the strength of materials and Effect on Performance and mineral additive, select the high-quality coarse-fine aggregate for use and control particle diameter and grating, in material, mix a certain amount of high efficiency water reducing agent and composite minerals ultrafine powder, reduce water cement ratio, be based on existing local material, do not change conventional production process, make full use of the filling effect and the fluidisation effect of mineral admixture, the super synergistic effect of high efficiency water reducing agent and composite blend, make mechanical property (comprise and shaped steel between adhesive property) good, the serviceability excellence, excellent in durability, cost is relatively low is applicable to the high-strength high-performance concrete of widely applying in steel reinforced concrete structure.
The mineral admixture grain diameter is more tiny than cement granules particle diameter, can the filling concrete gap between particles.The concrete aggressiveness of outside deterioration factor pair depends on the pore fluid of concrete structure to a great extent, and this causes the major cause of concrete durability problem just.When low, will helping the improvement of concrete every performance greater than the macropore content of 0.1 μ m in the cement stone, otherwise, all unfavorable to concrete intensity, anti-permeability performance and endurance quality.The silicate cement particle diameter is 10.4 μ m, and the particle diameter of silicon ash is less than 1 μ m, and median size is 0.1 μ m, and the particle diameter of first level flour coal ash is less than 1 μ m.When cement and flyash and silicon ash compound tense by a certain percentage, the porosity of gelling material has very big decline, and the pore structure of cement stone is improved, and correspondingly the degree of compactness of concrete material improves.
Behind mineral admixture replacement part cement, mineral admixture that the portion of water in the cement granules space is filled in it is extruded, and the degree of mobilization of cement paste increases thereupon.But also not all mineral admixture all has this fluidisation effect, mainly be because the specific surface area of the mineral admixture that has is too big or itself have vesicular structure, though can discharge the part moisture in the cement paste behind its replacement cement, but since itself the suction or wetted surface need more free water, cause the flowability of cement paste not increase.Develop concrete high workload performance in order to guarantee, the present invention adopts high efficiency water reducing agent and the two methods of mixing of mineral admixture, after having mixed high efficiency water reducing agent, the mineral admixture particle has adsorbed the high efficiency water reducing agent molecule, the electrostatic repulsion that the electrostatic double layer current potential that its surface forms is produced impels powder granule to disperse greater than the universal gravitation between the powder particle, and further aggravates the cement particulate and disperse, the flowability of cement paste is increased, thereby improved the flowability of cement slurry preferably.
For normal concrete, usually contain a large amount of alkali in the grout body opening liquid, its pH value can reach 13, and aggregate also has basic active, therefore in the time of in being in wet environment, hydroxide ion in its hole liquid will with the silicon generation alkali-aggregate reaction of certain kind in the aggregate, thereby cause the expansion and the cracking of concrete structure.In addition, villaumite is the most deleterious a kind of aggressiveness compound, when chlorion corrodes in the concrete microstructure, will be to the hydrated cementitious phase shift of separating out, and finally cause concrete to be etched damage.Therefore, improving concrete pore structure and anti-permeability performance is to improve it to resist the effective way of chlorion erosional competency.The present invention adopts low alkali cement, aggregate that activated silica content is little, and mixes that measure such as mineral admixture suppresses alkali-aggregate reaction and chlorion corrodes.Test-results shows, behind a part of cement of silicon ash replacement that mixes, can alleviate even eliminate fully the expansion that alkali-aggregate reaction causes effectively.Its mechanism of action is: before the concrete strength development, the silicon ash can consume potash and the soda in the liquid of hole rapidly, so that hydroxide ion concentration reaches lower level; The silicon ash also can consume the calcium hydroxide that is discharged by hydrated cementitious.After adding mineral superfine powder in the concrete of the present invention, concrete electric conduction quantity obviously descends, and chloride permeability is controlled at very low level, thereby has realized good weather resistance.
The aggregate that is used for concrete material should have higher inherent strength, toughness and stability, can resisting various static state and dynamic stress, impact and abrasive action, and can not cause the decline of concrete performance.Because the condition of surface difference of different aggregates causes the cohesive strength between cement slurry and the aggregate also inequality, generally rubble has higher bonding strength than cobble; On the other hand, the cohesive strength that contains in the cement slurry with not siliceous when ash differs also very big, and when mixing the silicon ash, the cohesive strength between cement slurry and the aggregate is much higher when not mixing.Normal concrete is when destroying, the crack is to occur along the interface of cement slurry and aggregate, aggregate generally can not destroy, and cause and the destruction of high-strength high-performance concrete is destruction owing to aggregate mostly, so the performance of aggregate has bigger influence to the performance of high-strength high-performance concrete.The coarse aggregate of selecting for use in this research is a surface irregularity, the rubble that grating is good.Fine aggregate adopts that particle slyness, quality are hard, collection is joined good, thick river sand during silt content is little.
In the adhesive property test of shaped steel and high-strength high-performance concrete, after shaped steel and concrete generation slippage, chemical glue between shaped steel surface and the concrete is puted forth effort forfeiture, when slippage is big, mechanical snap power between shaped steel and the concrete also disappears substantially, thereafter load is mainly born by the friction resistance between shaped steel and the concrete, promptly relies on the concrete crystalline shearing resistance on concrete and the shaped steel contact surface to resist load.In the high-strength high-performance concrete of the present invention's development, along with the raising of aggregate intensity, concrete strength has also obtained than leap ahead, the also corresponding reinforcement of ability of its opposing shearing action.So, adopt fine quality rubble, can improve the friction resistance part in shaped steel and the concrete binding power.
Embodiment:
(1) starting material:
1. cement
Select the stable P.O 52.5R cement of capability and performance, need to carry out fluidity test before using, thereby select and the good cement type of high efficiency water reducing agent consistency with high efficiency water reducing agent.Selected cement performance index (comprises fineness, SO
3Content, MgO content, presetting period, final setting time, 3 days intensity, 28 days intensity) must reach the requirement of relevant national standard.
2. aggregate
Fine aggregate adopts that particle slyness, quality are hard, collection join good in thick river sand, the quality of sand should reach the high-quality sand standard of stipulating in the GB/T14684-93 building sand standard.Its fineness modulus is (concrete grade of preparation is high more, and the fineness modulus of sand should be taked the upper limit as far as possible) between 2.5～3.4, and silt content is controlled at below 1.0%.
Rubbles such as coarse aggregate adopts that the quality densification is hard, intensity is high, surface irregularity, faller gill shape content is little, grating is good limestone, grouan, diabase.The cubic compressive strength of aggregate parent rock should be higher more than 20% than the concrete strength of being prepared.Maximum particle diameter should be controlled between 10～20mm, and silt content is controlled at below 0.5%, and a faller gill shape sticking content should not be greater than 5%, and must not sneak into the weathering particle.
3. flyash
Adopt the I level flyash of power plant's production of coal-fired technology advanced person.Its loss on ignition should not be greater than 5%, SO
3Content is not more than 3%, and water demand ratio should be not more than 105%, and specific surface area should be greater than 600m
2/ Kg.
4. silicon ash
Dioxide-containing silica in the silicon ash should be less than 85%, and median size 0.1～0.2 μ m, water ratio are less than 3%, and loss on ignition is less than 6%, and the pozzolanic activity index is greater than 90%, and specific surface area is not less than 15000m
2/ kg.
5. high efficiency water reducing agent
High efficiency water reducing agent is selected polycarboxylic acid series high efficiency water reducing agent, and water-reducing rate should be greater than 25%.The volume of high efficiency water reducing agent is 2% of whole binder total amounts, adopts the method for mixing together, and must carry out fluidity test with selected cement type before using.
6. mixing water
Selecting tap water for use is mixing water.Its quality should meet the regulation of concrete mixing water supply standard JGJ63-89.
(2) proportioning:
The present invention is as shown in table 1 for the proportioning that the high-strength high-performance concrete of C60～C100 provides for the strength grade that will widely apply in steel reinforced concrete structure.
Table 1 is used for the high-strength high-performance concrete proportioning (unit: Kg) of reinforced concrete composite structure
| Strength grade of concrete | Cement type | Cement | Sand | Stone | Water | Water reducer | The silicon ash | Flyash |
| C60 | P.O 52.5R | 350 | 700 | 1150 | 150 | 8 | 0 | 150 |
| C70 | P.O 52.5R | 400 | 576 | 1224 | 148 | 8 | 30 | 120 |
| C80 | P.O 52.5R | 450 | 544 | 1156 | 156 | 12 | 30 | 120 |
| C90 | P.O 52.5R | 450 | 493 | 1207 | 150 | 12 | 60 | 90 |
| C100 | P.O 52.5R | 450 | 510 | 1190 | 144 | 12 | 60 | 90 |
(3) comparative test result:
The high-strength high-performance concrete of preparing according to above-mentioned proportioning that is applicable to reinforced concrete composite structure and result's (C30, C40, C50 grade are normal concrete in the table) as shown in table 2 of normal concrete simultaneous test:
Table 2 concrete comparative test result
| Strength grade of concrete | The slump/mm | Cubic compressive strength/MPa | Split tensile strength/MPa | With shaped steel bonding strength/MPa | Concrete permeability grade (NEL method) |
| C30 | 100 | 34.37 | 2.75 | 1.09 | III |
| C40 | 120 | 39.73 | 3.03 | 1.52 | III |
| C50 | 80 | 48.54 | 3.46 | 1.89 | III |
| C60 | 120 | 70.9 | 5.9 | 3.51 | IV |
| C70 | 140 | 88.3 | 6.8 | 3.74 | IV |
| C80 | 130 | 93.0 | 6.5 | 3.45 | IV |
| C90 | 120 | 103.4 | 7.0 | 3.67 | IV |
| C100 | 120 | 115.3 | 7.2 | 3.82 | V |
Above-mentioned test-results shows, high-strength high-performance concrete by this technology preparation, can guarantee its mechanics (being intensity and the plasticity) performance that should possess and having on the basis of high-durability, high workability, high volume stability and economy, improved the adhesive property between concrete and the shaped steel significantly, make in steel reinforced concrete structure design to need not (or only needing a little ground) and add shearing connecting piece, can guarantee shaped steel and concrete effective collaborative work in component surface.
Claims (2)
1. concrete that is used for reinforced concrete composite structure, it is characterized in that: this mix proportion is a cement: coarse aggregate: fine aggregate: water: high efficiency water reducing agent: flyash is: 350: 700: 1150: 150: 8: 150, component unit: Kg/m
3
2. the concrete that is used for reinforced concrete composite structure according to claim 1 is characterized in that: described high efficiency water reducing agent is selected polycarboxylic acid series high efficiency water reducing agent, and water-reducing rate is greater than 25%.
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| Application Number | Priority Date | Filing Date | Title |
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| CNB2006100419595A CN100393661C (en) | 2006-03-22 | 2006-03-22 | Concrete used for shaped-steel and concrete joint construction |
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|---|---|---|---|
| CNB2006100419595A CN100393661C (en) | 2006-03-22 | 2006-03-22 | Concrete used for shaped-steel and concrete joint construction |
Related Child Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007101991162A Division CN101195530B (en) | 2006-03-22 | 2006-03-22 | Concrete with strength grade of C70 for section steel concrete composite structure |
| CN200710199123A Division CN100577598C (en) | 2006-03-22 | 2006-03-22 | Concrete with strength grade of C90 for section steel concrete composite structure |
| CN2007101991247A Division CN101195532B (en) | 2006-03-22 | 2006-03-22 | Concrete with strength grade of C80 for section steel concrete composite structure |
| CN2007101991196A Division CN101250040B (en) | 2006-03-22 | 2006-03-22 | Concrete with strength grade of C100 used for steel reinforced concrete combined structure |
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|---|---|
| CN1830880A CN1830880A (en) | 2006-09-13 |
| CN100393661C true CN100393661C (en) | 2008-06-11 |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1403402A (en) * | 2001-09-07 | 2003-03-19 | 东南大学 | Environment protecting cement-base composite material |
| CN1451626A (en) * | 2002-04-17 | 2003-10-29 | 杨果林 | High strength steel fibre concrete and making method thereof |
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- 2006-03-22 CN CNB2006100419595A patent/CN100393661C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1403402A (en) * | 2001-09-07 | 2003-03-19 | 东南大学 | Environment protecting cement-base composite material |
| CN1451626A (en) * | 2002-04-17 | 2003-10-29 | 杨果林 | High strength steel fibre concrete and making method thereof |
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