CN117223716A - Spinosad insecticidal aerosol and application thereof - Google Patents
Spinosad insecticidal aerosol and application thereof Download PDFInfo
- Publication number
- CN117223716A CN117223716A CN202310973106.9A CN202310973106A CN117223716A CN 117223716 A CN117223716 A CN 117223716A CN 202310973106 A CN202310973106 A CN 202310973106A CN 117223716 A CN117223716 A CN 117223716A
- Authority
- CN
- China
- Prior art keywords
- spinosad
- insecticidal aerosol
- solvent oil
- insecticidal
- propathrin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000443 aerosol Substances 0.000 title claims abstract description 40
- JFLRKDZMHNBDQS-UCQUSYKYSA-N CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C Chemical compound CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C JFLRKDZMHNBDQS-UCQUSYKYSA-N 0.000 title claims abstract description 38
- 239000005930 Spinosad Substances 0.000 title claims abstract description 38
- 229940014213 spinosad Drugs 0.000 title claims abstract description 38
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 34
- 239000002904 solvent Substances 0.000 claims abstract description 26
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 230000002195 synergetic effect Effects 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 239000003380 propellant Substances 0.000 claims abstract description 8
- 239000003381 stabilizer Substances 0.000 claims abstract description 8
- WXBHKHTWAPLUSQ-UHFFFAOYSA-N (2-methyl-5-prop-2-ynylfuran-3-yl)methyl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCC1=C(C)OC(CC#C)=C1 WXBHKHTWAPLUSQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229960005235 piperonyl butoxide Drugs 0.000 claims abstract description 4
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 claims abstract description 3
- CXBMCYHAMVGWJQ-CABCVRRESA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-CABCVRRESA-N 0.000 claims abstract description 3
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 claims abstract description 3
- 229940024113 allethrin Drugs 0.000 claims abstract description 3
- 229960005199 tetramethrin Drugs 0.000 claims abstract description 3
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 claims abstract 2
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 claims abstract 2
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 claims abstract 2
- 239000003921 oil Substances 0.000 claims description 17
- 241000255925 Diptera Species 0.000 claims description 14
- 235000005979 Citrus limon Nutrition 0.000 claims description 10
- 239000000341 volatile oil Substances 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 241001674044 Blattodea Species 0.000 claims description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 4
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 4
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000004821 distillation Methods 0.000 claims description 4
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 4
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 claims description 4
- 239000001294 propane Substances 0.000 claims description 3
- GXDHCNNESPLIKD-UHFFFAOYSA-N 2-methylhexane Natural products CCCCC(C)C GXDHCNNESPLIKD-UHFFFAOYSA-N 0.000 claims description 2
- AEXMKKGTQYQZCS-UHFFFAOYSA-N 3,3-dimethylpentane Chemical compound CCC(C)(C)CC AEXMKKGTQYQZCS-UHFFFAOYSA-N 0.000 claims description 2
- 244000248349 Citrus limon Species 0.000 claims 2
- 239000007921 spray Substances 0.000 description 15
- 238000012360 testing method Methods 0.000 description 14
- 239000000575 pesticide Substances 0.000 description 9
- 244000131522 Citrus pyriformis Species 0.000 description 8
- 241000238631 Hexapoda Species 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 239000003814 drug Substances 0.000 description 6
- 238000005507 spraying Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 230000005540 biological transmission Effects 0.000 description 5
- 238000003825 pressing Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 238000005303 weighing Methods 0.000 description 5
- 239000005946 Cypermethrin Substances 0.000 description 4
- 239000005892 Deltamethrin Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229960005424 cypermethrin Drugs 0.000 description 4
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 4
- 229960002483 decamethrin Drugs 0.000 description 4
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 2
- 241000271566 Aves Species 0.000 description 2
- 241000238657 Blattella germanica Species 0.000 description 2
- 241000256054 Culex <genus> Species 0.000 description 2
- 241000124008 Mammalia Species 0.000 description 2
- 241000257226 Muscidae Species 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 244000191502 Chenopodium murale Species 0.000 description 1
- 240000001624 Espostoa lanata Species 0.000 description 1
- 235000009161 Espostoa lanata Nutrition 0.000 description 1
- MKXZASYAUGDDCJ-SZMVWBNQSA-N LSM-2525 Chemical compound C1CCC[C@H]2[C@@]3([H])N(C)CC[C@]21C1=CC(OC)=CC=C1C3 MKXZASYAUGDDCJ-SZMVWBNQSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000222640 Polyporus Species 0.000 description 1
- 241000868102 Saccharopolyspora spinosa Species 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229960001985 dextromethorphan Drugs 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 230000032669 eclosion Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000003120 macrolide antibiotic agent Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- -1 tetrafluoroethrin Chemical compound 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a spinosad insecticidal aerosol and application thereof, comprising the following raw materials in percentage: spinosad 0.21.0%; knockdown agent 0.010.1%; 0.65.0% of synergistic ether; a solvent 1030%; a stabilizer 0.10.4%; the balance of propellant. The knockdown agent comprises one or more of propathrin, dextro-propathrin, biological propathrin, tetrafluoro-ether pyrethrin, allethrin or tetramethrin; the synergistic ether comprises piperonyl butoxide. The invention is green, environment-friendly, degradable and good in insecticidal effect.
Description
Technical Field
The invention relates to the technical field of biological pesticides, in particular to a spinosad insecticidal aerosol and application thereof.
Background
At present, the mosquito and fly killing pesticide mainly comprises three varieties of organic phosphorus, pyrethroid and carbamate, and with the improvement of the awareness of the international society on food safety and environmental protection, the varieties of high-toxicity and high-residue pesticides are limited, and the high-efficiency and low-toxicity biological source pesticide is environment-friendly, is not easy to generate resistance, and is favored by countries around the world.
The spinosad, which is a macrolide nuisance-free high-efficiency biological pesticide extracted from the fermentation liquor of spinosad sugarcane and polyporus (Saccharopolyspora spinosa), is always applied to farmland disinsection, but has quick-acting property of chemical pesticides and safety of biological pesticides, has been obtained from the general U.S. green chemical challenge, has high activity on mosquitoes and flies, has short degradation half-life in low-dose spraying environment, and is safe to mammals, birds and fish; therefore, it is important to develop a spinosad insecticidal aerosol and a preparation method thereof, and apply the spinosad insecticidal aerosol to mosquitoes and flies.
Disclosure of Invention
The invention aims to overcome the defects of the prior art, and provides a spinosad insecticidal aerosol and application thereof, which are green, environment-friendly, degradable and good in insecticidal effect.
In order to achieve the above purpose, the technical scheme adopted by the invention is as follows:
the spinosad insecticidal aerosol comprises the following raw materials in percentage:
further, the knockdown agent comprises one or more of propathrin, dextromethorphan, biological propathrin, tetrafluoroethrin, allethrin or tetramethrin;
the synergistic ether comprises piperonyl butoxide.
Further, the solvent comprises sec-butanol, tert-butanol, ethanol, dimethylpentane, nonane, dodecane, solvent oil, isoparaffin solvent oil.
Further, the solvent oil adopts one or two of D60 solvent oil and D80 solvent oil;
the isoparaffin solvent oil adopts isoparaffin solvent oil with the distillation range of 249-267 ℃ or isoparaffin solvent oil with the distillation range of 186-20 ℃.
Further, the stabilizer comprises one or more of BHT or BHA.
Further, the propellant comprises propane, compressed air or dimethyl ether.
Further, the lemon essential oil comprises 0.01-0.05% of lemon essential oil.
Further, the mass ratio of the spinosad to the lemon essential oil is 20-30:1.
The spinosad insecticidal aerosol is applied to killing mosquitoes, flies and cockroaches.
Compared with the prior art, the invention has the following beneficial effects:
the spinosad is taken as an effective medicinal component, has the quick action of chemical pesticides and the safety of biological pesticides, has high activity on mosquitoes and flies, has short degradation half-life in a low-dose spraying environment, is safe to mammals, birds and fishes, is an insecticidal aerosol product with higher safety, and in addition, the spinosad and the lemon essential oil are compounded, and the insecticidal activity of the spinosad is greatly improved by utilizing the synergistic effect of the spinosad and the lemon essential oil.
Detailed Description
The present invention will be described in further detail with reference to examples.
In the present invention,
spinosad (99.1% content): shaanxi Rui Minde Biotechnology Co., ltd;
lemon essential oil: purchased from Jiangxi Tai Chengcheng natural perfume Co., ltd;
the tebufenprox original drug (content 92%): purchased from Jiangsu Jie Biotech Co., ltd;
piperonyl butoxide: wenzhou Cheng chemical technology Co., ltd;
d60 solvent oil: exxon Mobil chemical;
d80 solvent naphtha, exxonmobil chemical;
BHT (2, 6-di-t-butyl-p-cresol), shandong euosol chemical engineering limited;
propane, south Beijing Zhongzhi energy Co., ltd;
cypermethrin technical (97.8% content), basf, germany;
deltamethrin technical (content 98.5%), guangxi nan Ning Lv Feng chemical Co., ltd;
example 1
The spinosad insecticidal aerosol comprises the following raw materials in percentage by weight:
a preparation method of spinosad insecticidal aerosol comprises the following steps:
weighing the raw materials according to a proportion, adding spinosad, lemon essential oil, knockdown agent, stabilizer, synergistic ether and solvent into a spray can, installing an aerosol valve, pressing a propellant into the spray can, shaking to dissolve solids, and installing a transmission device on the spray can.
Example 2
The spinosad insecticidal aerosol comprises the following raw materials in percentage by weight:
a preparation method of spinosad insecticidal aerosol comprises the following steps: as in example 1.
Example 3
The spinosad insecticidal aerosol comprises the following raw materials in percentage by weight:
a preparation method of spinosad insecticidal aerosol comprises the following steps: as in example 1.
Example 4
The spinosad insecticidal aerosol comprises the following raw materials in percentage by weight:
a preparation method of spinosad insecticidal aerosol comprises the following steps:
weighing the raw materials according to a proportion, adding spinosad, knockdown agent, stabilizer, synergistic ether and solvent into a spray can, installing an aerosol valve, pressing a propellant into the spray can, shaking to dissolve solids, and installing a transmission device on the spray can.
Comparative example 1
An aerosol comprises the following raw materials in percentage by weight:
a method of preparing an aerosol comprising the steps of:
after weighing the raw materials according to the proportion, adding lemon essential oil, knockdown agent, stabilizer, synergistic ether and solvent into a spray can, installing an aerosol valve, then pressing propellant into the spray can, shaking to dissolve solids, and then installing a transmission device on the spray can.
Comparative example 2
The cypermethrin insecticidal aerosol comprises the following raw materials in percentage by weight:
the preparation method of the cypermethrin insecticidal aerosol comprises the following steps:
after weighing the raw materials according to the proportion, adding cypermethrin, knockdown agent, stabilizer, synergistic ether and solvent into a spray can, installing an aerosol valve, then pressing propellant into the spray can, shaking to dissolve solid, and then installing a transmission device on the spray can.
Comparative example 3
The deltamethrin insecticidal aerosol comprises the following raw materials in percentage by weight:
the preparation method of the deltamethrin insecticidal aerosol comprises the following steps:
the preparation method comprises the steps of weighing the raw materials according to a proportion, adding deltamethrin, knockdown agent, stabilizer, synergistic ether and solvent into a spray can, installing an aerosol valve, pressing a propellant into the spray can, shaking to dissolve solids, and installing a transmission device on the spray can.
Effect example 1:
the aerosols of example 1 and each comparative example were subjected to mosquito, fly and cockroach killing tests according to GB/T13917.2-2009, and the results are shown in tables 1-3;
mosquito killing test: adopting culex light color, and taking female mosquito which does not suck blood on the 3 rd to 5 th days after eclosion as a test insect;
fly killing test: adopting houseflies, and male and female half-adults on days 3-4 after emergence as test insects;
cockroach killing test: adopting German cockroach, adults with ages of 10 days to 15 days, and male and female parts of the adults as test insects;
the test method comprises the following steps: sucking 30 test insects, placing into a sealed cylinder device for testing, recovering the test insects to normal activity, horizontally arranging an aerosol cylinder, arranging a nozzle downwards and vertically, spraying medicine to a medicine spraying hole on the cylinder, spraying 1.0g of medicine, immediately plugging the medicine spraying hole by a rubber plug, pumping out a pull plate after 1 minute, recording the number of knocked-down test insects at regular intervals for 20 minutes, transferring the knocked-down test insects into a clean raising cage, recovering standard raising, and feeding with 5% sugar cotton balls. Each test was repeated three more times and the KT50 value was calculated for half knockdown of the test insects.
Table 1 comparison of drug efficacy against culex light color
Table 2 comparison of drug effects against houseflies
Table 3 comparison of the efficacy of German cockroaches
The above described embodiments are only preferred examples of the invention and are not exhaustive of the possible implementations of the invention. Any obvious modifications thereof, which would be apparent to those skilled in the art without departing from the principles and spirit of the present invention, should be considered to be included within the scope of the appended claims.
Claims (9)
1. The spinosad insecticidal aerosol is characterized by comprising the following raw materials in percentage by weight:
2. a spinosad insecticidal aerosol according to claim 1, wherein,
the knockdown agent comprises one or more of propathrin, dextro-propathrin, biological propathrin, tetrafluoro-ether pyrethrin, allethrin or tetramethrin;
the synergistic ether comprises piperonyl butoxide.
3. A spinosad insecticidal aerosol according to claim 1, wherein,
the solvent comprises sec-butanol, tert-butanol, ethanol, dimethylpentane, nonane, dodecane, solvent oil, isoparaffin solvent oil.
4. A spinosad insecticidal aerosol according to claim 3, characterized in that,
the solvent oil adopts one or two of D60 solvent oil and D80 solvent oil;
the isoparaffin solvent oil adopts isoparaffin solvent oil with the distillation range of 249-267 ℃ or isoparaffin solvent oil with the distillation range of 186-20 ℃.
5. A spinosad insecticidal aerosol according to claim 1, wherein,
the stabilizer comprises one or more of BHT or BHA.
6. A spinosad insecticidal aerosol according to claim 1, wherein,
the propellant comprises propane, compressed air or dimethyl ether.
7. A spinosad insecticidal aerosol according to claim 1, wherein,
and 0.01-0.05% lemon essential oil.
8. The spinosad insecticidal aerosol of claim 1, wherein the mass ratio of spinosad to said lemon essential oil is 20-30:1.
9. Use of the spinosad insecticidal aerosol of claims 1-8 for killing mosquitoes, flies and cockroaches.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310973106.9A CN117223716A (en) | 2023-08-03 | 2023-08-03 | Spinosad insecticidal aerosol and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310973106.9A CN117223716A (en) | 2023-08-03 | 2023-08-03 | Spinosad insecticidal aerosol and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN117223716A true CN117223716A (en) | 2023-12-15 |
Family
ID=89088713
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202310973106.9A Pending CN117223716A (en) | 2023-08-03 | 2023-08-03 | Spinosad insecticidal aerosol and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN117223716A (en) |
-
2023
- 2023-08-03 CN CN202310973106.9A patent/CN117223716A/en active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103141526B (en) | Botanical insecticide aerosol containing natural pyrethrin and plant essential oil and method | |
| CN103081912B (en) | Celastrus angulatus and cnidium lactone compounded pesticide and preparation method thereof | |
| EP2894973B1 (en) | Device for attracting insects and use thereof | |
| CN103141488B (en) | Pesticide compounded by azadirachtin and cnidium lactone and preparation method thereof | |
| CN101627757A (en) | Dark melolonthidae sex pheromone and sex attractant | |
| CN101845282A (en) | Components of armyworm adhesive and method for preparing same | |
| CN104273138A (en) | Fruit fly trapping and killing agent and preparation method thereof | |
| CN101874486A (en) | Insecticide composition containing spinosad and etofenprox | |
| CN103749555B (en) | A kind of toxic bait pesticide | |
| CN101953368A (en) | Composition containing chlorine fluorine ethofenprox and beta-cypermethrin and application thereof | |
| CN117223716A (en) | Spinosad insecticidal aerosol and application thereof | |
| CN101961028A (en) | Insecticide aerosol | |
| CN105052924A (en) | Apocheima cinerarius erschoff sex attractant | |
| CN105580835A (en) | Multifunctional insecticide | |
| CN107232227A (en) | A kind of AVM hereinafter triazophos compound pesticide and preparation method thereof | |
| CN115005204B (en) | Food attractant for preventing and treating spodoptera frugiperda and application of food attractant | |
| CN101953365A (en) | Composition containing etrafluorine ethofenprox and high-efficiency cypermethrin and application thereof | |
| CN101953367B (en) | Composition containing tetraflumethrin and cypermethrin and application thereof | |
| CN101961026B (en) | Composition containing tetrafluoride etofenprox and bifenthrin as well as application thereof | |
| CN111436433B (en) | Gypsy moth adult attractant and preparation method and application thereof | |
| KR102178885B1 (en) | Stable insect pest control product comprising caprylic acid and a method of preparation thereof | |
| CN1593126A (en) | Selaginella moellendorfii essential oil alcohol-based aerosol and preparation method thereof | |
| CN106106436B (en) | A kind of pesticidal preparations and the preparation method and application thereof for preventing and treating vegetable-crop pest-insect beet armyworm | |
| CN101953369A (en) | Composition containing chlorine fluorine ethofenprox and deltamethrin and application thereof | |
| CN101953370A (en) | Composite containing chlorine fluorine ethofenprox and cypermethrin and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |