CN1171935A - Gel cleanser composition - Google Patents
Gel cleanser composition Download PDFInfo
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- CN1171935A CN1171935A CN 97115358 CN97115358A CN1171935A CN 1171935 A CN1171935 A CN 1171935A CN 97115358 CN97115358 CN 97115358 CN 97115358 A CN97115358 A CN 97115358A CN 1171935 A CN1171935 A CN 1171935A
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- composition
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- cleanser composition
- gel
- gel cleanser
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Abstract
A gel cleanser composition which comprises the following components (A) and (B): (A) from 1 to 40% by weight of a nonionic surfactant; and (B) from 0.1 to 10% by weight of a water swelling clay mineral. The gel cleanser composition is excellent in detergency on makeup stains and sebum stains, less irritative to the skin and highly stable even at high temperatures and high humidity.
Description
The present invention relates to the water-soluable gel cleansing composition, it has very high detergency to cosmetics spot and sebum spot, and is little to skin irritation, shows good massage performance and easily flushing, and because the high stability of himself, even be adapted at using under high temperature and the high humility.
Use to comprise, can not be enough to make cosmetics (lipstick, vanishing cream, eye shadow oil, eyelashes wet goods) solubilising or the emulsifying of being rich in oiliness composition and hard fat with the conventional solid or the facial detergent of pasty state of soap as main component.Thereby, use this class detergent, almost can not remove the cosmetic spot.For except these cosmetic spots, use to comprise with the oiliness base as the gel cleanser of principal component, clean emulsion, clean wet goods always.
But using these to comprise the oiliness base can not be enough to remove the residual stain of sebum as the detergent of main constituent and comprise the solid spot of silting fine hair hole up.In addition, produce greasy feeling after described product uses.So, use this remover after, need to again wash one's face with the facial remover of pasty state.When using under high temperature and high humility, comprising with the oiliness base is the detergent of main constituent, owing to wherein contain moisture, the shortcoming of stability decreases is arranged.The problem that descends with detergency appears separating out in the result.In addition, another shortcoming of low viscosity detergent (for example wash oil) is from past dirty on the face, and in cleaning process, pollution clothes.
The cleansing composition that also requires to be used to remove oil-dirt (cosmetic spot, sebum spot etc.) is less to skin irritation.But it is generally bigger to skin irritatin as the product of base to comprise common fatty acids soap or anion surfactant.Although comprise with non-ionic surface active agent and have low irritant and high detergency as the product of base, but, when in order to improve shape retention and to eliminate toward dirty trend, and when making this product thickening, the detergency of this surfactant reduces greatly, and when cleaning, smooth is another shortcoming.
Therefore, the object of the invention provides has high detergency to cosmetic spot and sebum spot, to the little gel cleanser composition with having superior massage performance and cleaning easily of skin irritatin.
In this case, the present inventor has carried out extensive studies.Finally, they successfully find the water-soluable gel cleansing composition, it has high detergency to oil-dirt (cosmetic spot, sebum spot etc.), little to skin irritation, be easy to be coated in face or on hand, show good massage (promptly in massage, having very high ductility), be easy to wash, and because its high stability, even be adapted at using under high temperature and the high humility, can obtain said composition by mixing hereinafter with the composition (A) of detailed description with (B), thereby finish the present invention.
Therefore, the invention provides and comprise following ingredients (A) and gel cleanser composition (B).
(A) non-ionic surface active agent of 1-40% (weight); With
(B) water swelling clay mineral of 0.1-10% (weight).
The preferred embodiment that is used as the non-ionic surface active agent of composition of the present invention (A) comprises the epoxyethane derivative of higher fatty acids macrogol ester, polyoxyethylene sorbitan fatty acid ester, fatty glyceride, epoxyethane derivative, polyoxyethylene alkyl ether, polyoxypropylene alkyl ether, polyoxyethylene alkyl phenyl ether and the polyoxyethylene-hardened castor oil of fatty acid propylene glycol ester.In more detail; in above-mentioned non-ionic surface active agent; preferred higher fatty acids macrogol ester, the group that especially preferably has a 10-22 carbon atom is the higher fatty acids macrogol ester of caprylyl, lauroyl, myristoyl, palmityl and stearyl for example.Preferred polyoxyethylene group is counted average out to 10-30, because so can obtain the ability of enhanced dissolving cosmetic spot.
Composition (A) non-ionic surfactant concentration is 1-40% (weight) in the preferred gel cleanser composition of the present invention, more preferably 5-20% (weight).Especially preferred above-mentioned content is 8-15% (weight), and is because composition at this moment can reach sebum spot and the enough detergencies of cosmetic spot, simultaneously littler to skin irritatin.
In the present invention, can congruent (A) use anion or amphoteric surfactant for example soap and sodium lauryl sulphate together.
From shape retention and the stable angle of controlling described product, the content of mentioned component preferably is no more than 50% (weight).
The preferred montmorillonite that uses is as the water swelling clay mineral of composition among the present invention (B).Although any natural Montmorillonitum and synthetic Montmorillonitum are all suitable,, the preferred use comprises the Montmorillonitum that is no more than 5% glass (glass), Anhydrite, quartz, Muscovitum, calcium sulfate, calcium carbonate, manganese carbonate etc.The preferred embodiment of described Montmorillonitum comprises natural and synthetic colloidal silicate for example dioctahedron group silicate (for example, Montmorillonitum, visit stone, nontronite etc.) and trioctahedron group silicate (saponite, hectolite, rich magnesium Montmorillonitum etc.).Wherein, hectolite most preferably, the example of its commercially available prod comprises Laponite-Series (being produced by Laporte Absorbents), Kunipia (being produced by Kunimine Yakuhin) and Smectone (by Co-opChemical Co., Ltd. produces).
Preferably composition (B) content is 0.1-10% (weight) in gel cleanser composition of the present invention, more preferably 0.5-8% (weight) and 1-5% (weight) more preferably are because the compositions of this moment has highly-malleable and flatness in the middle of keeping suitable viscosity and massaging.
Preferred gel cleanser composition of the present invention can comprise monohydric alcohol or the polyalcohol as composition C in addition, because the cleansing composition adjusted rheological characteristic character that so obtains and improved moisture retention.Described monohydric alcohol or examples of polyhydric alcohols comprise ethanol, ethylene glycol, propylene glycol, Isopropanediol, two polypropylene glycols, 1,3 butylene glycol, two Polyethylene Glycol, polypropylene glycol, glycerol, tetramethylolmethane, sorbitol, mannitol and glycol ether.The example of described glycol ether comprises ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol one propyl ether, ethylene glycol monobutyl ether, two Polyethylene Glycol monomethyl ethers, dimerization ethylene glycol monoethyl ether, two Polyethylene Glycol, one propyl ether, two Polyethylene Glycol monobutyl ethers.Glycol Monomethyl ether, propylene glycol monoethyl ether and ethylene glycol one phenyl ether.In above-mentioned alcohol, the present invention preferably uses ethanol, propane diols, glycerine, sorbierite etc., because so can obtain having the remover of good detergency and suitable rheological property.
Composition (C) content is no more than 30% (weight) in the preferred gel cleanser composition of the present invention, 5-25% (weight) more preferably, the compositions of this moment most preferably is 5-20% (weight), because can keep its shape and miscible with various spots simultaneously in facial or expansion easily on hand.
In the present invention, lower alcohol for example ethanol can use with composition (C).The consumption of lower alcohol preferably is no more than 100% based on composition (C), so, can suitably select to obtain the viscoelasticity of compositions.
Gel cleanser composition of the present invention also comprises the inorganic powder as composition (D), so that flush away said composition easily.In addition, use this inorganic powder described composition can be processed into emulsus lotion, cream or paste.The example of described inorganic powder comprises Talcum, Muscovitum, titanium dioxide, Kaolin, serpentine, pyrophyllite, chlorite, Vermiculitum, meerschaum, palygorskite, allophane, imogolite, silica mineral, Anhydrite, carbonate mineral and sulfate mineral.In above-mentioned material, preferably use in the present invention talcum, mica or titanium dioxide.
Composition in the gel cleanser composition of the present invention (D) content preferably is no more than 30% (weight), 0.5-25% (weight) more preferably, compositions most preferably is 5-20% (weight), because can comprise the composition (D) of stable state and make skin produce refreshed sensation this moment in cleaning.
Gel cleanser composition of the present invention can also comprise the water-soluble polymer as composition (E), so that control massage performance and raising stability.As for water-soluble polymer, both can use natural polymer also can use synthetic polymer, as long as it is water-soluble.The example comprises pectin, carrageenin, locust bean gum, gelatin, synthesising biological polymeric gel, carboxy vinyl polymer, carboxymethyl hydroxyethyl cellulose, alginate, starch, polyvinyl alcohol, polyacrylate, polymethacrylates and Polyethylene Glycol.
Composition in the gel cleanser composition of the present invention (E) content preferably is no more than 5% (weight), more preferably 0.1-3% (weight), 0.1-2% (weight) most preferably, thus can keep the stability of described system and reduce clean in cohesive.
Except that mentioned component, gel cleanser composition of the present invention can comprise the various compositions that are commonly used in the cleansing composition for example except that the chemical compound of introducing as composition (C) emollient (as triglyceride, diglyceride, monoglyceride etc.), antibacterial, antiseptic, chelating agen, electrolyte, medicinal ingredient, dyestuff, spice, antioxidant and pH regulator agent, only otherwise damaging the invention process gets final product.
The present invention relates to gel cleanser composition, it comprises:
(A) non-ionic surface active agent of 1-40% (weight); (B) water swelling clay mineral of 0.1-10% (weight).This cleansing composition has cosmetic spot and the superior detergency of sebum spot, and good shape retention is as long as and be coated with on a small quantity on skin when massage.By the content of control, can adjust the static viscosity (viscosity coefficient) of described compositions as the water swelling clay mineral of composition (B) use.Can be as required, by will add as the polyalcohol of composition (C) composition (A) and (B) in, control arbitrarily the gelling performance of described composition.By suitably selecting type and the content of described polyalcohol (C), can adjust its viscoplasticity rate.Use suitable polyhydric alcohol (propylene glycol, 1,3 butylene glycol, sorbitol, glycerol, ethanol etc.) can produce the compositions of high ductibility, under little shearforce, can easily make its fracture, simultaneously, fully keep its shape retention.From the angle of described composition stable, preferred component (C) content is no more than 30% (weight).
When will as the inorganic powder of composition (D) be no more than 30% (weight) add mentioned component (A), (B) and (C) in the time, the described compositions of easier cleaning also can obtain refreshed sensation.By adding talcum, mica, titanium dioxide etc., can obtain being very easy to the butyrous composition of cleaning.By adding composition (E), also can adjust the viscoelasticity of described compositions to mentioned component (A), (B) with (D).At this moment, also can add simultaneously composition (C) and (E).Can adjust the viscosity of described compositions, so, add the stability that 0.1-3% (weight) hydroxyethyl-cellulose, carboxymethyl cellulose, carboxy vinyl polymer etc. can improve described system as composition (E).
Gel cleanser composition of the present invention is littler to skin irritatin, but cosmetic spot and skin spot are had the height detergency.And it can be easily by flush away.In addition, it has primely shape retention and can easily be coated in face or on hand.According to purposes and hobby, can be made into various forms example gel or ointment.In addition, even under high temperature and high humility, its performance does not reduce yet.
Embodiment
Introduce the present invention for further more detailed, rather than it is limited, provide the following example.
Embodiment 1
Use water-soluble cleansing composition that the conventional method preparation describes in detail in table 1 and table 2 and to its from outward appearance, detergency, massage performance, clean and estimated aspect easy degree, stability and the skin irritation.It the results are shown in table 1 and the table 2.
Evaluation methodology:
(1) detergency:
A certain amount of lipstick is coated onto experimenter's lower arms inboard.Then, use every kind of cleansing composition, press certain pressure, certain number of times is massaged the position of using lipstick, then flushing.Then, weigh this color distortion, thereby determine detergency (representing with percentage).According to its detergency of following standard evaluation.
◎: more than 80% or 80%.
Zero: 70% to being lower than 80%.
△: 50% to being lower than 70%.
*: be lower than 50%.
(2) massage performance (i.e. ductility in the massage):
Every kind of cleansing composition is coated onto technical specialist's face.After determining to massage certain number of times under the pressure, according to its fineness of following standard evaluation and quality.
Zero: highly-malleable.
△: moderate.
*: poor ductility.
(3) clean easy degree:
Every kind of cleansing composition is coated onto technical specialist's face.After massaging for 20 seconds, it is rinsed out with a certain amount of water.According to its residual fraction, clean easy degree by following standard evaluation.
Zero: wash off rapidly.
△: moderate.
*: almost do not wash off.
(4) stability
Every kind of cleansing composition is stored in the insulating box, and temperature wherein can be from 50--5 ℃ of circulation change.After 3 months, by following standard, estimate the situation of described composition.
◎: very good.
Zero: good.
△: muddiness, color and luster colorization and/or viscosity-modifying.
*: layering.
(5) zest:
By using the cultured cell from rabbit corneal, calculating described inhibitory rate of cell growth is 50% o'clock sample concentration (IC
50).According to following standard evaluation zest.
◎: low irritant: IC
50: 500ppm or more than the 500ppm
Zero: zest is moderate: IC
50: 200ppm～be lower than 500ppm
△: high zest: IC
50: be lower than 200ppm
Table 1
Product of the present invention
Composition (weight %)
12345678 9POE, (12) one laurates 10 10 10 10 10 10 10 10 10POE, (12) lauryl ether---1---lauryl sodium sulfate-----1--Lauric acid amide propylbetaine------1--ethanol-5 5555 5-5 propane diols-------5 5 synthetic hectolite*333333333 talcums--10 10 10 10 10 10 10 polyethylene glycol---0.1-----water, 87 82 72 71.9 71 71 71 72 67 appearance transparent gel ← simple ointments ← ← ← ← ← ← easy degree 000000000 stability of detergency 000000 ◎ 00 massage performances (ductility), 000000000 cleanings 000 ◎ 00000 skin irritations 000000000 *: Laponite XLG (being produced by Laporte Absorbents)
Table 2
Compare product component (weight %)
12345 6POE (12) one laurates 10 10 10--POE (12) lauryl ether-----lauryl sodium sulfate-----Lauric acid amide propylbetaine-----ethanol-5 5-5 5 propane diols------synthetic hectolite*---333 talcums--10--10 polyethylene glycol------water, 90 85 75 97 92 82 appearance transparent gel ← hierarchical-transparent gel ← simple ointment detergency 0 0-* * * massage performance (ductility) * *-zero 00 cleans stable zero △-0 00 of easy degree △ △-0 00 skin irritation 0 0-◎ ◎ ◎ *: Laponite XLG (being produced by Laporte Absorbents)
Embodiment 2
Be dissolved in 5g glycerol in the 77g water and add the 3g Montmorillonitum.After fully stirring, add 15g POE (12) one lauric acid esters again, obtain compositions.Resultant composition is the transparent also superior shape retention of tool.In addition, it have superior massage performance, to the superior detergency of cosmetic spot and sebum spot with clean easily.
Embodiment 3
The 5g polyethylene glycol is dissolved in the 62.5g water, and slowly adds the 2.5g montmorillonite.After fully stirring, add again 10gPOE (12) one laurates and 20g talcum, and fully stir the mixture that forms until evenly, thereby obtain composition.Resulting composition is butyraceous and has superior shape retention.In addition, it has superior massage performance, cosmetic spot and the superior detergency of sebum spot is also cleaned easily.
Claims (4)
1. comprise following ingredients (A) and gel cleanser composition (B):
(A) non-ionic surface active agent of 1-40% (weight); With
(B) water swelling clay mineral of 0.1-10% (weight).
2. according to the gel cleanser composition of claim 1, it also comprises monobasic or polyhydric alcohol (C).
3. according to the gel cleanser composition of claim 1 or 2, it also comprises inorganic powder (D).
4. according to each gel cleanser composition of claim 1-3, it also comprises water-soluble polymer (E).
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP200186/96 | 1996-07-30 | ||
| JP200186/1996 | 1996-07-30 | ||
| JP20018696A JP3629339B2 (en) | 1996-07-30 | 1996-07-30 | Cleaning composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1171935A true CN1171935A (en) | 1998-02-04 |
| CN1160054C CN1160054C (en) | 2004-08-04 |
Family
ID=16420233
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB971153582A Expired - Fee Related CN1160054C (en) | 1996-07-30 | 1997-07-30 | Gel cleanser composition |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP3629339B2 (en) |
| CN (1) | CN1160054C (en) |
| HK (1) | HK1007867A1 (en) |
| ID (1) | ID17588A (en) |
| TW (1) | TW420613B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6475496B1 (en) * | 2000-08-17 | 2002-11-05 | Revlon Consumer Products Corporation | Gelled cosmetic remover composition |
| DE10064489A1 (en) * | 2000-12-22 | 2002-07-11 | Henkel Kgaa | Peeling composition containing nanoparticles |
| ZA200606521B (en) | 2004-02-06 | 2008-02-27 | Unilever Plc | Improved detergent composition |
| JP2009275010A (en) * | 2008-05-16 | 2009-11-26 | Kao Corp | Skin cleanser composition |
| JP2011037733A (en) * | 2009-08-07 | 2011-02-24 | Moriroku Chemicals Co Ltd | Functional substance made of micronized allophane and composition thereof |
| JP5994095B2 (en) * | 2012-08-27 | 2016-09-21 | 株式会社バスクリン | Powder cosmetics for scrub massage |
| FR3117795B1 (en) * | 2020-12-22 | 2024-02-02 | Oreal | Cleaning compositions based on unmodified clay and polyglycerol surfactant |
-
1996
- 1996-07-30 JP JP20018696A patent/JP3629339B2/en not_active Expired - Fee Related
-
1997
- 1997-07-07 TW TW86109523A patent/TW420613B/en not_active IP Right Cessation
- 1997-07-28 ID IDP972609A patent/ID17588A/en unknown
- 1997-07-30 CN CNB971153582A patent/CN1160054C/en not_active Expired - Fee Related
-
1998
- 1998-07-09 HK HK98109042A patent/HK1007867A1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| TW420613B (en) | 2001-02-01 |
| JP3629339B2 (en) | 2005-03-16 |
| JPH1045565A (en) | 1998-02-17 |
| ID17588A (en) | 1998-01-15 |
| HK1007867A1 (en) | 1999-04-30 |
| CN1160054C (en) | 2004-08-04 |
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