CN117160231B - Marine exhaust gas desulfurization equipment and method - Google Patents

Marine exhaust gas desulfurization equipment and method Download PDF

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Publication number
CN117160231B
CN117160231B CN202311426421.6A CN202311426421A CN117160231B CN 117160231 B CN117160231 B CN 117160231B CN 202311426421 A CN202311426421 A CN 202311426421A CN 117160231 B CN117160231 B CN 117160231B
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pipe
waste gas
desulfurizing tower
gas
rotating shaft
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CN117160231A (en
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赵明珠
陈志远
吴茂琛
陈文婷
白居申
魏迪
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Contiocean Environment Tech Co ltd
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Contiocean Environment Tech Co ltd
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Abstract

The invention belongs to the technical field of marine exhaust gas desulfurization equipment, in particular to marine exhaust gas desulfurization equipment and a marine exhaust gas desulfurization method, aiming at the problems that the prior art cannot timely carry out desulfurization treatment on a large amount of inflow exhaust gas, the tail gas is easy to gather to influence the later desulfurization operation, seawater is easy to gather at the bottom of a desulfurization tower and cannot be discharged quickly, and seawater is easy to enter a flue in the spraying process.

Description

Marine exhaust gas desulfurization equipment and method
Technical Field
The invention relates to the technical field of marine exhaust gas desulfurization equipment, in particular to marine exhaust gas desulfurization equipment and a marine exhaust gas desulfurization method.
Background
IMO will prohibit the use of fuels with sulfur content exceeding 0.5% by day 1 of 2020, whereas the current standard is 3.5%. The ship can continue burning high-sulfur fuel oil, but the sulfur content must be reduced to below 0.5% by using washing equipment, and the most commonly used marine desulfurization washing equipment at present is an open desulfurization tower, wherein the open desulfurization tower takes seawater as a washing medium, and the purpose of desulfurizing tail gas of the ship is achieved through the reaction of the seawater and flue gas.
However, the prior marine desulfurizing tower still has some defects when in use:
in the use process of the existing desulfurizing tower, as the tail gas discharged by the ship is more, the flow velocity of the tail gas flowing into the desulfurizing tower is larger, so that the desulfurizing tower cannot timely desulfurize the flowing tail gas;
In the process of the tail gas of the ship rushing into the desulfurizing tower, the tail gas generally moves upwards along the position of the air inlet pipe, so that the tail gas is relatively concentrated in the desulfurizing tower, and a spraying system in the desulfurizing tower cannot effectively desulfurize the gathered tail gas;
The desulfurization of the ship is generally carried out by spraying seawater, when the spraying flow rate of the seawater in the desulfurization tower is large, the seawater cannot be discharged in time, so that the seawater is gathered at the bottom of the desulfurization tower and is easy to corrode the inner wall of the desulfurization tower;
the general spraying is from top to bottom, so that seawater easily flows into the main machine through the inlet flue in the spraying process, the main machine flue is corroded due to contact with washing water if the seawater is light, and flameout accidents occur due to infiltration of the washing water if the seawater is heavy.
In order to solve the problems, the invention provides marine exhaust gas desulfurization equipment and a marine exhaust gas desulfurization method.
Disclosure of Invention
The invention aims to solve the defects that in the prior art, a large amount of inflow tail gas cannot be desulfurized in time, the tail gas is easy to gather to affect the later desulfurization operation, seawater is easy to gather at the bottom of a desulfurizing tower and cannot be discharged quickly, and seawater is easy to enter a flue in a spraying process.
In order to achieve the above purpose, the present invention adopts the following technical scheme:
the marine waste gas desulfurization equipment comprises a desulfurization tower, wherein an installation seat is welded on the outer wall of the desulfurization tower, a circular ring smoke exhaust pipe is fixed in the desulfurization tower through bolts, a rotating shaft is longitudinally connected in a rotating manner in the desulfurization tower, a cylinder is fixed on the top of the desulfurization tower through bolts, and the bottom of the installation seat is fixedly connected with the bottom of a ship cabin through a plurality of bolts;
The water retaining structure is arranged in the desulfurizing tower and is used for preventing seawater from penetrating into the circular smoke exhaust pipe in the spraying process;
The spraying structures are arranged in the desulfurizing tower and are used for spraying the waste gas;
the drainage structure is arranged at the bottom of the desulfurizing tower and is used for enabling the seawater at the bottom of the desulfurizing tower to be rapidly discharged into the ocean.
In one possible design, the water retaining structure comprises a first water retaining ring welded on the inner wall of the desulfurizing tower, the circular ring smoke exhaust pipe is positioned below the first water retaining ring, the outer wall of the bottom of the first water retaining ring is welded with a second water retaining ring, the outer wall of the second water retaining ring is welded with the side wall of the circular ring smoke exhaust pipe, one side of the circular ring smoke exhaust pipe is fixedly penetrated with a smoke inlet channel, one end of the smoke inlet channel extends to the outer side of the desulfurizing tower and is communicated with the smoke channel of the ship host, and the bottom of the circular ring smoke exhaust pipe is provided with a plurality of smoke exhaust holes; the tail gas of boats and ships gets into in the ring exhaust pipe through advancing the flue, can play the effect that shelters from the sea water to the ring exhaust pipe through the cooperation of first water retaining ring and second water retaining ring, avoids the sea water to get into in the ring exhaust pipe along the outer wall and the exhaust port of ring exhaust pipe.
In one possible design, the spraying structure comprises a grid plate fixedly connected in the desulfurizing tower through bolts, a spraying pipe group is fixedly connected in the desulfurizing tower through a connecting block and is positioned above the grid plate, a liquid injection pipe for providing seawater is fixedly penetrated in the spraying pipe group, a plurality of lower spraying heads and upper spraying heads are respectively arranged at the bottom and the top of the spraying pipe group, and the bottom end of the rotating shaft penetrates through the grid plate and the spraying pipe group; the tail gas passes the below of grid board upward movement to lower shower head in the in-process of floating, can evenly scatter tail gas in the desulfurizing tower through the grid board, avoid tail gas to appear gathering the phenomenon, lower shower head sprays downwards, preliminary sprays the tail gas of dispersion, and the desulfurization, when the tail gas after spraying moves upward to the top of upper shower head, the sea water that upper shower head upwards sprayed can spray waste gas from down upwards again, through the positive reverse spraying of lower shower head and upper shower head, effectually carries out the desulfurization to waste gas.
In one possible design, the spray pipe group is composed of a plurality of annular pipes with different inner diameters, the inner diameters of the annular pipes are sequentially reduced from outside to inside, two adjacent annular pipes are fixedly connected through a plurality of connecting rods, a plurality of lower spray heads and upper spray heads are respectively arranged at the bottom and the top of the corresponding annular pipes, the liquid injection pipe is composed of two hollow pipes and an annular communicating pipe, the two hollow pipes are respectively welded at two sides of the annular communicating pipe, the bottom end of the rotating shaft penetrates through the annular communicating pipe, one ends of the two hollow pipes are fixedly penetrated through the annular pipes, a plurality of through holes are formed in the outer wall of each hollow pipe, and the through holes correspond to the annular pipes; through the cooperation of a plurality of ring pipes and hollow tube, can provide the sea water for a plurality of lower shower heads and last shower heads simultaneously, be convenient for later stage lower shower head and last shower head have sufficient sea water to waste gas desulfurization.
In one possible design, the drainage structure comprises a liquid outlet pipe fixedly penetrating through the bottom of the desulfurizing tower, a rack is fixed on the inner wall of the bottom of the desulfurizing tower through bolts, the bottom end of the rotating shaft is rotationally connected with the top of the rack, a gearbox is arranged in the rack, an output shaft of the gearbox is fixedly connected with the bottom end of the rotating shaft through a coupler, a rotating rod is fixed on the output shaft of the gearbox through the coupler, the bottom end of the rotating rod extends into the liquid outlet pipe, a plurality of stirring rods are welded on the outer wall of the rotating rod, and the stirring rods are positioned in the liquid outlet pipe; the bottom inner wall of desulfurizing tower holds a large amount of sea water under long-time spraying, and the drain pipe can't in time repel the sea water, and the axis of rotation passes through gearbox drive pivot and puddler fast turn, can be with the sea water stirring that desulfurizing tower bottom held through the puddler, makes the sea water form the swirl, and then can be quick make the sea water discharge to the ocean from the drain pipe in.
In one possible design, a motor is fixed at the top of the cylinder through a bolt, an output shaft of the motor extends into the cylinder and is fixedly provided with a rotating shaft, a connecting frame is fixed in the cylinder through the bolt, the top end of the rotating shaft is rotationally connected with the bottom of the connecting frame, the bottom end of the rotating shaft rotationally penetrates through the connecting frame and is rotationally connected with the top end of the rotating shaft, a flue gas analyzer is arranged on the inner wall of one side of the cylinder, a first backflow pipe fixedly penetrates through one side of the cylinder, the bottom end of the first backflow pipe fixedly extends into the desulfurizing tower and is fixedly provided with an air injection ring, the air injection ring is rotationally sleeved on the outer wall of the rotating shaft, a cavity is arranged in the rotating shaft, the air injection ring is communicated with the cavity through a plurality of air inlet holes, the outer wall of the rotating shaft is provided with a plurality of inclined holes below the air injection ring, the inclined holes are communicated with the cavity, and an exhaust pipe communicated with the top of the first backflow pipe is arranged; waste gas passes through in the first back flow gets into the blast pipe to through blast pipe and external chimney intercommunication, and then discharge waste gas to the outside, when flue gas analyzer detects waste gas and does not reach standard, close the solenoid valve on the blast pipe, open the solenoid valve on the first back flow, waste gas passes through in the first back flow gets into the gas injection ring, then waste gas passes through in the inlet flue gets into the cavity, along with the rotation of axis of rotation, waste gas in the cavity passes through inclined hole oblique downward spray to the desulfurizing tower in, waste gas uses the axis of rotation as the centre of a circle circulation spray to the desulfurizing tower in, can evenly spread waste gas in the desulfurizing tower in the later stage of being convenient for spray.
In one possible design, a sea water transfer box is welded on one side of the desulfurizing tower, a liquid inlet pipe is fixedly penetrated on one side of the sea water transfer box, the liquid inlet pipe is communicated with an external water pump, and one ends of a plurality of liquid injection pipes extend into the sea water transfer box; the seawater is pumped into the seawater transfer box through the water pump and the liquid inlet pipe, and then the sufficient slave seawater can be provided for the lower spray header and the upper spray header through the matching of the seawater transfer box and the liquid injection pipe.
In one possible design, the opening at the outer side of the inclined hole is inclined downwards, a plurality of groups of scattering structures are fixedly sleeved on the outer wall of the rotating shaft and positioned below the grid plate, the scattering structures are formed by a plurality of arc-shaped scattering plates, and electromagnetic valves are sleeved on the outer walls of the liquid inlet pipe, the flue inlet pipe, the exhaust pipe and the first return pipe; can avoid sea water to get into in the cavity through the inclined hole in spraying the in-process, when the axis of rotation drives the arc and breaks up the board and rotate, when waste gas is surging on passing through the grid board, the arc is broken up the board and can be broken up waste gas one step, makes waste gas even pass the grid board, is convenient for spray in later stage.
In one possible design, a gas storage tank is fixed on one side, far away from the seawater transfer tank, of the desulfurizing tower through a bolt, a sieve plate is fixed in the gas storage tank through a bolt, an active carbon layer is paved above the sieve plate, the bottom end of the first return pipe extends into the gas storage tank and penetrates through the sieve plate, an air pump is fixed on one side, far away from the desulfurizing tower, of the gas storage tank through a bolt, an air inlet of the air pump extends into the gas storage tank through a pipeline, the pipeline is positioned above the active carbon layer, a second return pipe is arranged at an air outlet of the air pump, and one end of the second return pipe extends into the desulfurizing tower and is communicated with an air injection ring; the air pump is through in first back flow inhales the gas receiver with waste gas, the gas receiver can carry out preliminary storage with the waste gas that does not reach standard, and can adsorb waste gas through the active carbon layer when waste gas moves up, filter, the gas pump will adsorb, in the gas injection ring is gone into to the waste gas after the filtration, waste gas gets into the cavity through the inlet, along with the rotation of axis of rotation, waste gas in the cavity is through the inclined hole oblique downward spray to the desulfurizing tower in, waste gas uses the axis of rotation to circulate as the centre of a circle in the desulfurizing tower, can evenly spread waste gas in the desulfurizing tower be convenient for later stage spray, the desulfurization.
The application discloses a using method of marine exhaust gas desulfurization equipment, which comprises the following steps:
S1, pumping seawater into a seawater transfer box through a water pump and a liquid inlet pipe, respectively injecting seawater into corresponding annular pipes through a plurality of through holes in the liquid inlet pipe, enabling tail gas of a ship to enter the annular smoke exhaust pipe through a smoke inlet pipe, enabling the tail gas to float upwards through smoke exhaust holes, enabling the tail gas to pass through a grid plate to move upwards below a lower spray header in the floating process, enabling the tail gas to be uniformly dispersed in a desulfurization tower through the grid plate and the plurality of smoke exhaust holes, avoiding aggregation of the tail gas, enabling the annular smoke exhaust pipe to have the effect of shielding seawater through the cooperation of a first water blocking ring and a second water blocking ring, and avoiding the seawater from entering the annular smoke exhaust pipe along the outer wall of the annular smoke exhaust pipe and the smoke exhaust holes;
S2, starting a lower spray header and an upper spray header, spraying downwards by the lower spray header, primarily spraying and desulfurizing dispersed tail gas, when the sprayed tail gas moves upwards to the upper part of the upper spray header, spraying the waste gas again by the upward seawater sprayed by the upper spray header from the lower part, effectively desulfurizing the waste gas by the forward and reverse spraying of the lower spray header and the upper spray header, continuously moving upwards by the waste gas, and entering a subsequent spraying structure, wherein the waste gas can be sprayed and desulfurized for a plurality of times by the subsequent spraying structure;
S3, additionally starting a motor to drive the rotating shaft and the arc scattering plate to rotate, when the waste gas passes through the grid plate to rush up, the arc scattering plate can scatter the waste gas in one step, so that the waste gas uniformly passes through the grid plate, later spraying is convenient, when the waste gas enters the cylinder after spraying, the waste gas is communicated with an external chimney through an exhaust pipe, and the waste gas is further discharged to the outside;
S4, when the flue gas analyzer detects that the waste gas does not reach the standard, the electromagnetic valve on the exhaust pipe is closed, the electromagnetic valve on the first return pipe is opened, the air pump is started, the air pump sucks the waste gas into the air storage tank through the first return pipe, the air storage tank can primarily store the waste gas which does not reach the standard, the waste gas can be adsorbed and filtered through the activated carbon layer when the waste gas moves upwards, the air pump discharges the adsorbed and filtered waste gas into the gas injection ring, then the waste gas enters the cavity through the flue inlet, and along with the rotation of the rotating shaft, the waste gas in the cavity is obliquely sprayed into the desulfurizing tower downwards through the inclined hole, the waste gas is circularly sprayed into the desulfurizing tower around the rotating shaft as the center of a circle, and the waste gas can be uniformly scattered in the desulfurizing tower so as to be convenient for later spraying and desulfurizing, in addition, as the opening at the outer side of the inclined hole is inclined downwards, seawater is prevented from entering the cavity through the inclined hole in the spraying process;
S5, a large amount of seawater is contained in the inner wall of the bottom of the desulfurizing tower under long-time spraying, the liquid outlet pipe cannot repel the seawater in time, the rotating shaft drives the rotating shaft and the stirring rod to rotate rapidly through the gearbox, the seawater contained in the bottom of the desulfurizing tower can be stirred through the stirring rod, the seawater forms a vortex, and then the seawater can be rapidly discharged from the liquid outlet pipe to the ocean.
In the invention, the spray structure comprises a grid plate fixed in a desulfurizing tower, a spray pipe group is fixed in the desulfurizing tower and positioned above the grid plate, and a plurality of lower spray heads and upper spray heads are respectively arranged at the bottom and the top of the spray pipe group; the tail gas passes through the grid plate to move upwards to the lower part of the lower spray header in the process of floating upwards, the tail gas can be uniformly dispersed in the desulfurization tower through the grid plate, the aggregation phenomenon of the tail gas is avoided, the lower spray header sprays downwards, the dispersed tail gas is primarily sprayed, when the tail gas moves upwards to the upper part of the upper spray header, the seawater sprayed upwards by the upper spray header can spray the waste gas again from the lower part to the upper part, and the waste gas is effectively desulfurized through the forward and reverse spraying of the lower spray header and the upper spray header;
In the invention, a first water blocking ring is welded on the inner wall of the desulfurizing tower, the circular ring smoke exhaust pipe is positioned below the first water blocking ring, a second water blocking ring is welded on the outer wall of the bottom of the first water blocking ring, and the outer wall of the second water blocking ring is welded with the side wall of the circular ring smoke exhaust pipe; the tail gas of the ship enters the circular ring smoke exhaust pipe through the smoke inlet channel, and the circular ring smoke exhaust pipe can be shielded by the cooperation of the first water blocking ring and the second water blocking ring, so that the seawater is prevented from entering the circular ring smoke exhaust pipe along the outer wall of the circular ring smoke exhaust pipe and the smoke exhaust hole;
In the invention, a gearbox is arranged in the frame, an output shaft of the gearbox is fixedly connected with the bottom end of a rotating shaft, a rotating rod is fixed on the output shaft of the gearbox, and a plurality of stirring rods are welded on the outer wall of the rotating rod; the rotating shaft drives the rotating shaft and the stirring rod to rotate rapidly through the gearbox, and the seawater held at the bottom of the desulfurizing tower can be stirred through the stirring rod, so that the seawater at the bottom of the desulfurizing tower forms a vortex, and further the seawater can be rapidly discharged from the liquid outlet pipe to the ocean;
In the invention, the bottom end of the first return pipe fixedly extends into the desulfurizing tower and is fixedly provided with an air injection ring, the air injection ring is rotationally sleeved on the outer wall of the rotating shaft, the air injection ring is communicated with the cavity through a plurality of smoke inlets, and the outer wall of the rotating shaft is provided with a plurality of inclined holes; waste gas enters the gas injection ring through the first return pipe, then the waste gas enters the cavity through the smoke inlet, and along with the rotation of the rotating shaft, the waste gas in the cavity is sprayed into the desulfurizing tower obliquely downwards through the inclined hole, and the waste gas is circularly sprayed into the desulfurizing tower by taking the rotating shaft as the center of a circle, so that the waste gas can be uniformly dispersed in the desulfurizing tower to be convenient for later spraying and desulfurizing.
According to the invention, when the waste gas is sprayed, seawater can be prevented from penetrating into the circular ring smoke exhaust pipe through the smoke exhaust holes by matching the first water blocking ring and the second water blocking ring, the waste gas can be scattered by matching the grid plate and the arc scattering plate when the waste gas rises, the influence of waste gas aggregation on later spraying is avoided, in addition, the waste gas can be sprayed in multiple directions by matching the lower spray header and the upper spray header, the waste gas spraying efficiency is improved, in addition, when the rotating shaft rotates, the waste gas can be scattered by the arc scattering plate, the seawater at the bottom of the desulfurizing tower can form vortex, and the discharge of the seawater is facilitated.
Drawings
FIG. 1 is a schematic three-dimensional structure of a marine exhaust gas desulfurization apparatus according to embodiment 1 of the present invention;
FIG. 2 is a schematic view showing a three-dimensional cross-sectional structure of a marine exhaust gas desulfurization apparatus according to embodiment 1 of the present invention;
FIG. 3 is a schematic view of a three-dimensional explosion structure of a circular smoke exhaust pipe, a first water blocking ring and a second water blocking ring of a marine exhaust gas desulfurization apparatus according to embodiment 1 of the present invention;
fig. 4 is a schematic three-dimensional sectional structure diagram of a circular ring smoke exhaust pipe, a first water blocking ring and a second water blocking ring of the marine exhaust gas desulfurization apparatus according to embodiment 1 of the present invention;
FIG. 5 is a schematic view of a three-dimensional explosion structure of a grid plate, an arc-shaped scattering plate and an annular pipe of a marine exhaust gas desulfurization apparatus according to embodiment 1 of the present invention;
FIG. 6 is a schematic view of a three-dimensional explosion structure of a ring pipe, an upper shower head and a lower shower head of a marine exhaust gas desulfurization apparatus according to embodiment 1 of the present invention;
FIG. 7 is a schematic view of a three-dimensional explosion structure of a liquid injection pipe and an annular pipe of a marine exhaust gas desulfurization apparatus according to embodiment 1 of the present invention;
FIG. 8 is a schematic view showing a partially three-dimensional cross-sectional structure of a rotary shaft of a marine exhaust gas desulfurization apparatus according to embodiment 1 of the present invention;
FIG. 9 is an enlarged view of FIG. 2 at A;
FIG. 10 is an enlarged view of FIG. 8 at B;
FIG. 11 is an enlarged view of FIG. 8 at C;
Fig. 12 is a schematic diagram showing a schematic cross-sectional front view of a marine exhaust gas desulfurization apparatus according to embodiment 2 of the present invention.
In the figure: 1. a desulfurizing tower; 2. a mounting base; 3. a circular ring smoke exhaust pipe; 4. a first water blocking ring; 5. a second water blocking ring; 6. a flue is entered; 7. a grid plate; 8. an annular tube; 9. a connecting rod; 10. a lower spray header; 11. a liquid injection pipe; 12. a through hole; 13. an annular communicating pipe; 14. a top shower head; 15. a seawater transfer box; 16. a liquid inlet pipe; 17. a cylinder; 18. a connecting frame; 19. a rotating shaft; 20. a motor; 21. a rotating shaft; 22. a flue gas analyzer; 23. a first return pipe; 24. an arc-shaped scattering plate; 25. an air injection ring; 26. a cavity; 27. a smoke inlet; 28. inclined holes; 29. a frame; 30. a gearbox; 31. a rotating lever; 32. a stirring rod; 33. a liquid outlet pipe; 34. an exhaust pipe; 35. a smoke vent; 36. a bolt; 37. an electromagnetic valve; 38. a gas storage tank; 39. a sieve plate; 40. an activated carbon layer; 41. an air pump; 42. and a second return pipe.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely with reference to the accompanying drawings, in which it is apparent that the embodiments described are only some embodiments of the present invention, but not all embodiments.
Example 1
Referring to fig. 1-11, an exhaust gas desulfurization device is applied to the field of marine exhaust gas desulfurization devices, and comprises a desulfurization tower 1, wherein an installation seat 2 is welded on the outer wall of the desulfurization tower 1, a circular ring smoke exhaust pipe 3 is fixed in the desulfurization tower 1 through bolts, a rotating shaft 19 is longitudinally and rotatably connected in the desulfurization tower 1, a cylinder 17 is fixed at the top of the desulfurization tower 1 through bolts, and the bottom of the installation seat 2 is fixedly connected with the bottom of a ship cabin through a plurality of bolts 36.
Referring to fig. 2, 3, 4 and 9, the apparatus further comprises a water blocking structure provided in the desulfurizing tower 1 for preventing seawater from penetrating into the annular smoke exhaust pipe 3 during spraying; the water retaining structure comprises a first water retaining ring 4 welded on the inner wall of the desulfurizing tower 1, a circular ring smoke exhaust pipe 3 is positioned below the first water retaining ring 4, a second water retaining ring 5 is welded on the outer wall of the bottom of the first water retaining ring 4, the outer wall of the second water retaining ring 5 is welded with the side wall of the circular ring smoke exhaust pipe 3, one side of the circular ring smoke exhaust pipe 3 is fixedly penetrated with a smoke inlet channel 6, one end of the smoke inlet channel 6 extends to the outer side of the desulfurizing tower 1 and is communicated with a smoke channel of a ship host, and a plurality of smoke exhaust holes 35 are formed in the bottom of the circular ring smoke exhaust pipe 3; the tail gas of boats and ships gets into in the ring exhaust pipe 3 through advance flue 6, can play the effect of sheltering from the sea water to ring exhaust pipe 3 through the cooperation of first water retaining ring 4 and second water retaining ring 5, avoids the sea water to get into in the ring exhaust pipe 3 along the outer wall and the exhaust port 35 of ring exhaust pipe 3.
Referring to fig. 2, 5, 6 and 9, the apparatus further includes a plurality of sets of spray structures provided in the desulfurizing tower 1 for spraying the exhaust gas; the spray structure comprises a grid plate 7 fixedly connected in the desulfurizing tower 1 through bolts, a spray pipe group is fixedly connected in the desulfurizing tower 1 through a connecting block, the spray pipe group is positioned above the grid plate 7, a liquid injection pipe 11 for providing seawater is fixedly penetrated in the spray pipe group, a plurality of lower spray heads 10 and upper spray heads 14 are respectively arranged at the bottom and the top of the spray pipe group, and the bottom end of a rotating shaft 19 penetrates through the grid plate 7 and the spray pipe group; the tail gas passes through the grid plate 7 and moves up to the below of the lower spray header 10 in the process of floating, the tail gas can be uniformly dispersed in the desulfurizing tower 1 through the grid plate 7, the aggregation phenomenon of the tail gas is avoided, the lower spray header 10 sprays downwards, the dispersed tail gas is sprayed and desulfurized preliminarily, when the sprayed tail gas moves up to the upper part of the upper spray header 14, the seawater sprayed upwards by the upper spray header 14 can spray the waste gas again from the lower part upwards, and the waste gas is desulfurized effectively by the forward and reverse spraying of the lower spray header 10 and the upper spray header 14.
Referring to fig. 2, 5, 6, 7 and 9, the spray pipe group is composed of a plurality of annular pipes 8 with different inner diameters, the inner diameters of the annular pipes 8 are sequentially reduced from outside to inside, two adjacent annular pipes 8 are fixedly connected through a plurality of connecting rods 9, a plurality of lower spray heads 10 and upper spray heads 14 are respectively arranged at the bottom and the top of the corresponding annular pipes 8, the liquid injection pipe 11 is composed of two hollow pipes and an annular communicating pipe 13, the two hollow pipes are respectively welded at two sides of the annular communicating pipe 13, the bottom end of a rotating shaft 19 penetrates through the annular communicating pipe 13, one ends of the two hollow pipes are fixedly penetrated through the annular pipes 8, a plurality of through holes 12 are formed in the outer wall of each hollow pipe, and the through holes 12 correspond to the annular pipes 8; through the cooperation of a plurality of ring pipes 8 and hollow tube, can provide the sea water for a plurality of lower shower heads 10 and last shower heads 14 simultaneously, be convenient for later stage lower shower head 10 and last shower head 14 have sufficient sea water to the waste gas desulfurization.
Referring to fig. 2, 5 and 9, a sea water transfer tank 15 is welded on one side of the desulfurizing tower 1, a liquid inlet pipe 16 is fixedly penetrated on one side of the sea water transfer tank 15, the liquid inlet pipe 16 is communicated with an external water pump, and one ends of a plurality of liquid injection pipes 11 extend into the sea water transfer tank 15; seawater is pumped into the seawater transfer box 15 through the water pump and the liquid inlet pipe 16, and sufficient slave seawater can be provided for the lower spray header 10 and the upper spray header 14 through the matching of the seawater transfer box 15 and the liquid injection pipe 11.
Referring to fig. 2, 8, 9, 10 and 11, the apparatus further includes a drain structure provided at the bottom of the desulfurizing tower 1 for rapidly discharging seawater at the bottom of the desulfurizing tower 1 into the ocean; the drainage structure comprises a liquid outlet pipe 33 fixedly penetrating through the bottom of the desulfurizing tower 1, a rack 29 is fixed on the inner wall of the bottom of the desulfurizing tower 1 through bolts, the bottom end of a rotating shaft 19 is rotationally connected with the top of the rack 29, a gearbox 30 is arranged in the rack 29, an output shaft of the gearbox 30 is fixedly connected with the bottom end of the rotating shaft 19 through a coupling, a rotating rod 31 is fixed on the output shaft of the gearbox 30 through the coupling, the bottom end of the rotating rod 31 extends into the liquid outlet pipe 33, a plurality of stirring rods 32 are welded on the outer wall of the rotating rod 31, and the stirring rods 32 are positioned in the liquid outlet pipe 33; the bottom inner wall of desulfurizing tower 1 holds a large amount of sea water under long-time spraying, drain pipe 33 can't in time repel the sea water, and axis of rotation 19 passes through gearbox 30 and drives pivot 21 and puddler 32 fast rotation, can stir the sea water that desulfurizing tower 1 bottom held through puddler 32, makes the sea water form the swirl, and then can be quick make the sea water discharge to the ocean from drain pipe 33.
Referring to fig. 2, 8, 9, 10 and 11, a motor 20 is fixed at the top of a cylinder 17 through bolts, an output shaft of the motor 20 extends into the cylinder 17 and is fixed with a rotating shaft 21, a connecting frame 18 is fixed in the cylinder 17 through bolts, the top end of the rotating shaft 19 is rotationally connected with the bottom of the connecting frame 18, the bottom end of the rotating shaft 21 rotationally penetrates through the connecting frame 18 and is rotationally connected with the top end of the rotating shaft 19, a flue gas analyzer 22 is arranged on the inner wall of one side of the cylinder 17, a first return pipe 23 fixedly penetrates through one side of the cylinder 17, the bottom end of the first return pipe 23 fixedly extends into the desulfurizing tower 1 and is fixedly provided with an air injection ring 25, the air injection ring 25 is rotationally sleeved on the outer wall of the rotating shaft 19, a cavity 26 is arranged in the rotating shaft 19, a plurality of inclined holes 28 positioned below the air injection ring 25 are arranged between the air injection ring 25 and the cavity 26 through a plurality of air inlet 27, and the inclined holes 28 are communicated with the cavity 26, and an exhaust pipe 34 is arranged at the top of the first return pipe 23 and is communicated with the cavity 26; exhaust gas enters the exhaust pipe 34 through the first return pipe 23, is communicated with an external chimney through the exhaust pipe 34, and is discharged to the outside, when the flue gas analyzer 22 detects that the exhaust gas does not reach the standard, the electromagnetic valve 37 on the exhaust pipe 34 is closed, the electromagnetic valve 37 on the first return pipe 23 is opened, the exhaust gas enters the gas injection ring 25 through the first return pipe 23, then the exhaust gas enters the cavity 26 through the smoke inlet 27, and along with the rotation of the rotating shaft 19, the exhaust gas in the cavity 26 is sprayed into the desulfurizing tower 1 obliquely downwards through the inclined hole 28, and the exhaust gas is circularly sprayed into the desulfurizing tower 1 by taking the rotating shaft 19 as a circle center, so that the exhaust gas can be uniformly dispersed in the desulfurizing tower 1 to facilitate later spraying and desulfurizing.
Referring to fig. 2, 5, 8, 9, 10 and 11, the opening at the outer side of the inclined hole 28 is inclined downwards, a plurality of groups of scattering structures are fixedly sleeved on the outer wall of the rotating shaft 19, the scattering structures are positioned below the grid plate 7 and consist of a plurality of arc-shaped scattering plates 24, and electromagnetic valves 37 are sleeved on the outer walls of the liquid inlet pipe 16, the flue 6, the exhaust pipe 34 and the first return pipe 23; seawater can be prevented from entering the cavity 26 through the inclined holes 28 in the spraying process, when the rotating shaft 19 drives the arc-shaped scattering plate 24 to rotate, the arc-shaped scattering plate 24 can scatter waste gas in one step when the waste gas passes through the grid plate 7 to be gushed, so that the waste gas uniformly passes through the grid plate 7, and later spraying is facilitated.
Example 2
Referring to fig. 12, the improvement is based on example 1: the side of the desulfurizing tower 1 far away from the seawater transfer box 15 is fixedly provided with a gas storage box 38 through bolts, a sieve plate 39 is fixedly arranged in the gas storage box 38 through bolts, an activated carbon layer 40 is paved above the sieve plate 39, the bottom end of the first return pipe 23 extends into the gas storage box 38 and penetrates through the sieve plate 39, the side of the gas storage box 38 far away from the desulfurizing tower 1 is fixedly provided with an air pump 41 through bolts, an air inlet of the air pump 41 extends into the gas storage box 38 through a pipeline, the pipeline is positioned above the activated carbon layer 40, an air outlet of the air pump 41 is provided with a second return pipe 42, and one end of the second return pipe 42 extends into the desulfurizing tower 1 and is communicated with the gas injection ring 25; the air pump 41 is through in first back flow 23 inhales the gas receiver 38 with waste gas, and the gas receiver 38 can carry out preliminary storage with the waste gas that does not reach standard, and can adsorb waste gas through activated carbon layer 40 when waste gas moves up, filter, in the gas pump 41 will adsorb, the waste gas after the filtration is discharged into gas injection ring 25, then waste gas gets into cavity 26 through inlet 27, along with rotation of axis of rotation 19, waste gas in the cavity 26 is through inclined hole 28 oblique downward spraying to desulfurizing tower 1 in, waste gas uses axis of rotation 19 to circulate and spouts to desulfurizing tower 1 in the centre of a circle, can evenly spread waste gas in desulfurizing tower 1 the later stage of being convenient for spray, the desulfurization.
The application method of the marine exhaust gas desulfurization equipment comprises the following steps:
S1, pumping seawater into a seawater transfer box 15 through a water pump and a liquid inlet pipe 16, respectively injecting seawater into corresponding annular pipes 8 through a plurality of through holes 12 in a liquid injection pipe 11, enabling tail gas of a ship to enter the annular smoke exhaust pipe 3 through a smoke inlet pipe 6, enabling the tail gas to float upwards through smoke exhaust holes 35, enabling the tail gas to pass through a grid plate 7 in the floating process and move upwards below a lower spray header 10, enabling the tail gas to be uniformly dispersed in a desulfurizing tower 1 through the grid plate 7 and the plurality of smoke exhaust holes 35, avoiding aggregation of the tail gas, enabling the annular smoke exhaust pipe 3 to be shielded by the cooperation of a first water blocking ring 4 and a second water blocking ring 5, and avoiding the seawater from entering the annular smoke exhaust pipe 3 along the outer wall of the annular smoke exhaust pipe 3 and the smoke exhaust holes 35;
S2, starting the lower spray header 10 and the upper spray header 14, spraying the lower spray header 10 downwards, primarily spraying and desulfurizing the dispersed tail gas, when the sprayed tail gas moves upwards above the upper spray header 14, spraying the waste gas again from the lower part to the upper part by the seawater sprayed upwards by the upper spray header 14, effectively desulfurizing the waste gas by forward and reverse spraying of the lower spray header 10 and the upper spray header 14, continuously moving the waste gas upwards, and spraying and desulfurizing the waste gas for a plurality of times by a subsequent spray structure;
S3, additionally, the motor 20 is started to drive the rotating shaft 19 and the arc-shaped scattering plate 24 to rotate, when the waste gas passes through the grid plate 7 to rush up, the arc-shaped scattering plate 24 can scatter the waste gas in one step, so that the waste gas uniformly passes through the grid plate 7, later spraying is convenient, when the waste gas enters the cylinder 17 after being sprayed, the waste gas is communicated with an external chimney through the exhaust pipe 34, and then the waste gas is discharged to the outside;
s4, when the flue gas analyzer 22 detects that the waste gas does not reach the standard, the electromagnetic valve 37 on the exhaust pipe 34 is closed, the electromagnetic valve 37 on the first return pipe 23 is opened, the air pump 41 is started, the air pump 41 sucks the waste gas into the air storage box 38 through the first return pipe 23, the air storage box 38 can primarily store the waste gas which does not reach the standard, and the waste gas can be adsorbed and filtered through the activated carbon layer 40 when moving upwards, the air pump 41 discharges the adsorbed and filtered waste gas into the gas injection ring 25, then the waste gas enters the cavity 26 through the flue inlet 27, and the waste gas in the cavity 26 is obliquely sprayed downwards into the desulfurizing tower 1 through the inclined hole 28 along with the rotation of the rotating shaft 19, and the waste gas is circularly sprayed into the desulfurizing tower 1 by taking the rotating shaft 19 as a circle center, so that the waste gas can be uniformly scattered in the desulfurizing tower 1, and is convenient for later spraying and desulfurizing, in addition, the opening outside the inclined hole 28 is inclined downwards, so that seawater is prevented from entering the cavity 26 through the inclined hole 28 in the spraying process;
S5, a large amount of seawater is contained in the inner wall of the bottom of the desulfurizing tower 1 under long-time spraying, the liquid outlet pipe 33 cannot repel the seawater in time, the rotating shaft 19 drives the rotating shaft 21 and the stirring rod 32 to rotate rapidly through the gearbox 30, the seawater contained in the bottom of the desulfurizing tower 1 can be stirred through the stirring rod 32, the seawater forms a vortex, and then the seawater can be rapidly discharged from the liquid outlet pipe 33 to the ocean.
However, as well known to those skilled in the art, the working principles and wiring methods of the motor 20, the smoke analyzer 22, the electromagnetic valve 37 and the air pump 41 are common, which are all conventional means or common general knowledge, and are not described herein in detail, and any choice can be made by those skilled in the art according to their needs or convenience.
The foregoing is only a preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art, who is within the scope of the present invention, should make equivalent substitutions or modifications according to the technical scheme of the present invention and the inventive concept thereof, and should be covered by the scope of the present invention.

Claims (3)

1. The marine waste gas desulfurization equipment comprises a desulfurization tower (1), and is characterized in that an installation seat (2) is welded on the outer wall of the desulfurization tower (1), a circular ring smoke exhaust pipe (3) is fixed in the desulfurization tower (1) through bolts, a rotating shaft (19) is longitudinally connected in the desulfurization tower (1) in a rotating mode, a cylinder (17) is fixed at the top of the desulfurization tower (1) through bolts, and the bottom of the installation seat (2) is fixedly connected with the bottom of a ship cabin through a plurality of bolts (36);
The water retaining structure is arranged in the desulfurizing tower (1) and is used for preventing seawater from penetrating into the circular smoke exhaust pipe (3) in the spraying process; the water retaining structure comprises a first water retaining ring (4) welded on the inner wall of the desulfurizing tower (1), the circular ring smoke exhaust pipe (3) is positioned below the first water retaining ring (4), a second water retaining ring (5) is welded on the outer wall of the bottom of the first water retaining ring (4), the outer wall of the second water retaining ring (5) is welded with the side wall of the circular ring smoke exhaust pipe (3), one side of the circular ring smoke exhaust pipe (3) is fixedly penetrated with a smoke inlet channel (6), one end of the smoke inlet channel (6) extends to the outer side of the desulfurizing tower (1) and is communicated with a flue of a ship host, and a plurality of smoke exhaust holes (35) are formed in the bottom of the circular ring smoke exhaust pipe (3);
the spraying structures are arranged in the desulfurizing tower (1) and are used for spraying the waste gas; the spray structure comprises a grid plate (7) fixedly connected in the desulfurizing tower (1) through bolts, a spray pipe group is fixedly connected in the desulfurizing tower (1) through a connecting block, the spray pipe group is positioned above the grid plate (7), a liquid injection pipe (11) for providing seawater is fixedly penetrated in the spray pipe group, a plurality of lower spray heads (10) and upper spray heads (14) are respectively arranged at the bottom and the top of the spray pipe group, and the bottom end of the rotating shaft (19) penetrates through the grid plate (7) and the spray pipe group;
the drainage structure is arranged at the bottom of the desulfurizing tower (1) and is used for quickly draining the seawater at the bottom of the desulfurizing tower (1) into the ocean;
The drainage structure comprises a liquid outlet pipe (33) fixedly penetrating through the bottom of the desulfurizing tower (1), a rack (29) is fixedly arranged on the inner wall of the bottom of the desulfurizing tower (1) through bolts, the bottom end of the rotating shaft (19) is rotationally connected with the top of the rack (29), a gearbox (30) is arranged in the rack (29), an output shaft of the gearbox (30) is fixedly connected with the bottom end of the rotating shaft (19) through a coupling, a rotating rod (31) is fixedly arranged on the output shaft of the gearbox (30) through the coupling, the bottom end of the rotating rod (31) extends into the liquid outlet pipe (33), a plurality of stirring rods (32) are welded on the outer wall of the rotating rod (31), and the stirring rods (32) are positioned in the liquid outlet pipe (33);
the top of the cylinder (17) is fixedly provided with a motor (20) through a bolt, an output shaft of the motor (20) extends into the cylinder (17) and is fixedly provided with a rotating shaft (21), a connecting frame (18) is fixedly arranged in the cylinder (17) through the bolt, the top end of the rotating shaft (19) is rotationally connected with the bottom of the connecting frame (18), the bottom end of the rotating shaft (21) rotates to penetrate through the connecting frame (18) and is rotationally connected with the top end of the rotating shaft (19), one side inner wall of the cylinder (17) is provided with a flue gas analyzer (22), one side of the cylinder (17) is fixedly penetrated with a first backflow pipe (23), the bottom end of the first backflow pipe (23) is fixedly extended into the desulfurizing tower (1) and is fixedly provided with an air injection ring (25), the air injection ring (25) is rotationally sleeved on the outer wall of the rotating shaft (19), a cavity (26) is arranged in the rotating shaft (19), a plurality of air inlet ports (27) are formed between the air injection ring (25) and the cavity (26), the outer wall of the rotating shaft (19) is provided with a plurality of inclined holes (28) positioned below the air injection ring (25), and the top of the air exhaust pipe (28) is communicated with the first backflow pipe (28);
One side of the desulfurizing tower (1) is welded with a seawater transfer box (15), one side of the seawater transfer box (15) is fixedly penetrated with a liquid inlet pipe (16), the liquid inlet pipe (16) is communicated with an external water pump, and one ends of a plurality of liquid injection pipes (11) extend into the seawater transfer box (15);
The opening at the outer side of the inclined hole (28) is inclined downwards, a plurality of groups of scattering structures are fixedly sleeved on the outer wall of the rotating shaft (19), the scattering structures are positioned below the grid plate (7), the scattering structures are composed of a plurality of arc-shaped scattering plates (24), and electromagnetic valves (37) are sleeved on the outer walls of the liquid inlet pipe (16), the flue inlet pipe (6), the exhaust pipe (34) and the first return pipe (23);
The utility model provides a desulfurization tower (1) is kept away from one side of sea water transfer case (15) and is had gas receiver (38) through the bolt fastening, be equipped with sieve (39) through the bolt fastening in gas receiver (38), active carbon layer (40) have been laid to the top of sieve (39), the bottom of first back flow (23) extends to in gas receiver (38) and runs through sieve (39), one side that desulfurizing tower (1) was kept away from to gas receiver (38) is equipped with air pump (41) through the bolt fastening, the air inlet of air pump (41) extends to in gas receiver (38) through the pipeline, and the pipeline is located the top of active carbon layer (40), the gas outlet of air pump (41) is equipped with second back flow (42), and the one end of second back flow (42) extends to in desulfurizing tower (1) and is linked together with gas filling ring (25).
2. The marine exhaust gas desulfurization apparatus according to claim 1, wherein the spray pipe group is composed of a plurality of annular pipes (8) having different inner diameters, the inner diameters of the annular pipes (8) are sequentially reduced from outside to inside, two adjacent annular pipes (8) are fixedly connected through a plurality of connecting rods (9), a plurality of lower spray heads (10) and upper spray heads (14) are respectively arranged at the bottom and the top of the corresponding annular pipes (8), the liquid injection pipe (11) is composed of two hollow pipes and an annular communicating pipe (13), the two hollow pipes are respectively welded at two sides of the annular communicating pipe (13), the bottom ends of the rotating shafts (19) penetrate through the annular communicating pipe (13), one ends of the two hollow pipes are fixedly penetrated through the annular pipes (8), a plurality of through holes (12) are formed in the outer wall of each hollow pipe, and the through holes (12) correspond to the annular pipes (8).
3. The method of using a marine exhaust gas desulfurization apparatus according to claim 2, comprising the steps of:
S1, pumping sea water into a sea water transfer box (15) through a water pump and a liquid inlet pipe (16), respectively injecting sea water into corresponding annular pipes (8) through a plurality of through holes (12) in a liquid injection pipe (11), enabling tail gas of a ship to enter the annular smoke exhaust pipe (3) through a smoke inlet pipe (6), enabling the tail gas to float upwards through smoke exhaust holes (35), enabling the tail gas to pass through a grid plate (7) to move upwards to the position below a lower spray header (10) in the floating process, enabling the tail gas to be uniformly dispersed in a desulfurizing tower (1) through the grid plate (7) and the plurality of smoke exhaust holes (35), avoiding aggregation of the tail gas, and enabling the annular smoke exhaust pipe (3) to be shielded by matching of a first water blocking ring (4) and a second water blocking ring (5) so as to avoid the sea water from entering the annular smoke exhaust pipe (3) along the outer wall of the annular smoke exhaust pipe (3) and the smoke exhaust holes (35);
S2, starting a lower spray header (10) and an upper spray header (14), spraying downwards by the lower spray header (10), primarily spraying and desulfurizing dispersed tail gas, when the sprayed tail gas moves upwards to the upper part of the upper spray header (14), spraying the waste gas again by the upward seawater sprayed upwards by the upper spray header (14), effectively desulfurizing the waste gas by forward and reverse spraying by the lower spray header (10) and the upper spray header (14), continuously moving upwards by the waste gas, entering a subsequent spray structure, and spraying and desulfurizing the waste gas for multiple times by the subsequent spray structure;
S3, additionally, a motor (20) is started to drive a rotating shaft (19) and an arc-shaped scattering plate (24) to rotate, when waste gas flows up through a grid plate (7), the arc-shaped scattering plate (24) can scatter the waste gas in one step, so that the waste gas uniformly passes through the grid plate (7) to facilitate later spraying, and when the waste gas enters a cylinder (17) after being sprayed, the waste gas is communicated with an external chimney through an exhaust pipe (34) to further exhaust the waste gas to the outside;
S4, when the flue gas analyzer (22) detects that the waste gas does not reach the standard, an electromagnetic valve (37) on an exhaust pipe (34) is closed, an electromagnetic valve (37) on a first return pipe (23) is opened, an air pump (41) is started, the air pump (41) sucks the waste gas into an air storage tank (38) through the first return pipe (23), the air storage tank (38) can primarily store the waste gas which does not reach the standard, and the waste gas can be adsorbed and filtered through an active carbon layer (40) when the waste gas moves upwards, the air pump (41) discharges the adsorbed and filtered waste gas into an air injection ring (25), then the waste gas enters a cavity (26) through a smoke inlet (27), and along with the rotation of a rotating shaft (19), the waste gas in the cavity (26) is sprayed downwards into a desulfurizing tower (1) obliquely through an inclined hole (28), and the waste gas is circularly sprayed into the desulfurizing tower (1) by taking the rotating shaft (19) as a circle center, so that the waste gas can be uniformly scattered in the desulfurizing tower (1) to be convenient for later stage, and in addition, the waste gas is prevented from entering the cavity (26) through the inclined hole (28) in the inclined hole (28);
S5, a large amount of seawater is contained in the inner wall of the bottom of the desulfurizing tower (1) under long-time spraying, the liquid outlet pipe (33) cannot repel the seawater in time, the rotating shaft (19) drives the rotating rod (31) and the stirring rod (32) to rotate rapidly through the gearbox (30), the seawater contained in the bottom of the desulfurizing tower (1) can be stirred through the stirring rod (32), the seawater forms a vortex, and then the seawater can be rapidly discharged from the liquid outlet pipe (33) to the ocean.
CN202311426421.6A 2023-10-31 2023-10-31 Marine exhaust gas desulfurization equipment and method Active CN117160231B (en)

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CN111036064A (en) * 2019-12-30 2020-04-21 江苏大洋海洋装备有限公司 Desulfurizing tower and desulfurization system for ship tail gas treatment
CN217725083U (en) * 2022-05-20 2022-11-04 四川省中思源科技有限公司 High-efficiency waste gas spray tower
CN217855420U (en) * 2022-08-31 2022-11-22 山东助友润滑科技有限公司 Tail gas absorption treatment device
CN116440660A (en) * 2023-06-02 2023-07-18 重庆丰化科技有限公司 Waste gas treatment spray tower for pesticide production

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CN111036064A (en) * 2019-12-30 2020-04-21 江苏大洋海洋装备有限公司 Desulfurizing tower and desulfurization system for ship tail gas treatment
CN217725083U (en) * 2022-05-20 2022-11-04 四川省中思源科技有限公司 High-efficiency waste gas spray tower
CN217855420U (en) * 2022-08-31 2022-11-22 山东助友润滑科技有限公司 Tail gas absorption treatment device
CN116440660A (en) * 2023-06-02 2023-07-18 重庆丰化科技有限公司 Waste gas treatment spray tower for pesticide production

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