CN117105434A - Carbon source medicament for sewage treatment and preparation method and application thereof - Google Patents

Carbon source medicament for sewage treatment and preparation method and application thereof Download PDF

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Publication number
CN117105434A
CN117105434A CN202311392107.0A CN202311392107A CN117105434A CN 117105434 A CN117105434 A CN 117105434A CN 202311392107 A CN202311392107 A CN 202311392107A CN 117105434 A CN117105434 A CN 117105434A
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carbon source
parts
sewage treatment
sewage
composite
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Inventor
杨东
陈健
唐翀鹏
周海龙
邢巍
陈宏秋
潘建通
陈凯华
迟金宝
汪翠萍
黄文涛
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Beijing Bohuite Environmental Technology Co ltd
Camce Environmental Technology Co ltd
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Beijing Bohuite Environmental Technology Co ltd
Camce Environmental Technology Co ltd
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Priority to CN202311392107.0A priority Critical patent/CN117105434A/en
Publication of CN117105434A publication Critical patent/CN117105434A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • C02F3/343Biological treatment of water, waste water, or sewage characterised by the microorganisms used for digestion of grease, fat, oil
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
    • C02F5/12Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/06Nutrients for stimulating the growth of microorganisms

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biological Treatment Of Waste Water (AREA)
  • Treatment Of Biological Wastes In General (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

The application relates to a carbon source medicament for sewage treatment, a preparation method and application thereof, which are suitable for treating oily sewage rich in 10-25% of grease. The microbial agent can utilize grease decomposing bacteria to decompose grease so as to supplement glycerol carbon source, improve the life cycle of microorganisms in the carbon source agent for sewage treatment, improve the lasting efficacy of the carbon source agent for sewage treatment, and prolong the purifying capacity of the carbon source agent for sewage treatment on sewage. The volcanic powder is utilized to improve the removal rate of COD and BOD. Other medicament components are concentrated together by utilizing the carbon-based culture medium, so that the medicament components are not easy to be washed away by sewage, a growth temperature bed and a required direct life carbon source are provided for bacteria, microorganism propagation is facilitated, and the sewage treatment life cycle of microorganisms is prolonged. The method can effectively treat the oil sewage in various ranges and types in cities, and improves the applicability and application range of the carbon source medicament for sewage treatment in sewage treatment.

Description

Carbon source medicament for sewage treatment and preparation method and application thereof
Technical Field
The application relates to the technical field of sewage treatment, in particular to a carbon source medicament for sewage treatment, a preparation method and application thereof.
Background
Sewage treatment is generally classified into production sewage treatment and domestic sewage treatment according to sewage sources. The water pollution is classified into two categories according to the nature of the water pollution: one type is natural pollution; the other is artificial contamination.
Sewage treatment, such as carbon source, requires sewage treatment agents with different application functions. Along with the extension of sewage treatment technology, the carbon source can provide organic substances, and is degraded and utilized by microorganisms in the bioreactor, so that on one hand, the growth and the propagation of microorganisms can be promoted, and on the other hand, denitrification bacteria are provided with denitrification and denitrification carbon elements, and the rapid removal of pollutants by the microorganisms is promoted.
However, when a carbon source chemical is used, the following problems have been found:
the carbon source agent has single use, has single performance on sewage treatment, mainly plays roles in microbial growth and denitrification, and has no removal effect on minerals such as dirt in sewage;
secondly, the existing carbon source medicaments for sewage treatment are liquid or soluble solids, and besides being utilized by microorganisms, the medicaments can flow and run away along with sewage to achieve the denitrification effect, and the medicaments are required to be continuously put in;
and thirdly, the carbon source medicament with composite components is simply mixed with carbon sources with various components, so that the carbon source medicament has the same function as a single-component carbon source, only plays roles in microbial biochemistry and denitrification, and has no adsorption and purification capability on impurity particles in sewage.
Disclosure of Invention
In order to solve the problems, the application provides a carbon source medicament for sewage treatment, and a preparation method and application thereof.
On the one hand, the application provides a carbon source medicament for sewage treatment, which is suitable for treating oily sewage rich in 10-25% of grease, and comprises the following components in parts by weight:
12-15 parts of a composite flocculant, 4-10 parts of a composite microbial agent, 10-25 parts of volcanic powder, 3-5 parts of a coagulant aid, 10-25 parts of a carbon-based culture medium, 8-15 parts of a corrosion inhibitor, 3-5 parts of a chelate, 3-10 parts of a water softener and 20-35 parts of composite carbon;
wherein:
the composite carbon source comprises the following components in parts by weight: 15-25 parts of polyalcohol and 5-10 parts of monosaccharide;
the compound microbial agent at least comprises: 1.2-2.4 parts of grease decomposing bacteria, wherein grease decomposing bacteria are utilized to decompose grease in grease-rich oily water, so that the grease is decomposed into glycerin, and the glycerin is used as a 'supplementary carbon source' of the carbon source medicament for sewage treatment;
the carbon-based culture medium is in a paste state, other medicament components are concentrated together, the medicament components are not easy to be washed away by sewage, a growth hotbed and a required direct life carbon source are provided for bacteria, the microorganism propagation is facilitated, and the sewage treatment life cycle of the microorganism is prolonged.
As an alternative embodiment of the present application, optionally, the composite flocculant is composed of the following components in parts by weight:
6-7 parts of modified multi-cation inorganic flocculant, 4-5 parts of cation organic polymer flocculant and 2-3 parts of microbial flocculant.
As an alternative embodiment of the present application, optionally, the modified polycationic inorganic flocculant comprises at least one of the following polycationic inorganic flocculants:
polyaluminum ferric sulfate chloride, aluminum iron copolymerization composite flocculant, polyaluminum sulfate, polysilicic acid flocculant, polysilicic acid ferric sulfate or polyaluminum ferric chloride.
As an optional embodiment of the present application, the cationic organic polymeric flocculant may comprise at least one of the following organic polymeric flocculants:
polyacrylamide, sodium polyacrylate or polyethyleneimine.
As an optional embodiment of the application, optionally, the composite microbial agent further comprises the following components in parts by weight:
1.0 to 3.5 parts of nitrifying bacteria, 0.5 to 3.0 parts of denitrifying bacteria, 0.2 to 0.8 part of hydrolytic zymocyte, 0.5 to 1.0 part of glycerol septic tank bacteria and 0.6 to 1.3 parts of oleaginous bacteria.
As an alternative embodiment of the present application, the coagulant aid is optionally one of the following components:
polyacrylamide, active silicic acid or bone cement;
the corrosion inhibitor is one of the following components: nitrite or chromate.
As an alternative embodiment of the present application, optionally, the chelate is one of the following components:
polyphosphates, aminocarboxylic acids, 1, 3-diketones or hydroxycarboxylic acids.
In another aspect of the present application, a method for preparing the carbon source agent for sewage treatment is provided, comprising the steps of:
step 1: sequentially adding polyalcohol and monosaccharide into distilled water at 55-70 ℃, fully stirring until no particles exist, and taking the mixture as a composite carbon source for standby after cooling to room temperature;
step 2: weighing a composite microbial agent, adding the composite microbial agent into the solution prepared in the step 1, uniformly stirring, and standing for 3-5 minutes;
step 3: weighing a composite flocculant, a coagulant aid, a carbon-based culture medium, a corrosion inhibitor and a chelate, fully mixing, and then adding mixed powder into the solution prepared in the step 2; after the adding, stirring at a high speed for 1-3 minutes to fully melt the mixed powder into the solution;
step 4: weighing a liquid water softener, adding the water softener into the solution prepared in the step 3, fully stirring, and standing;
step 5: weighing volcanic powder, mixing the volcanic powder with the melt in the step 4, stirring to obtain a viscous mixture, pouring the viscous mixture into a preset mold, and air-drying to obtain a sewage treatment carbon source component; when the sewage treatment carbon source assembly is used, the sewage treatment carbon source assembly is placed in a sewage pipeline, sewage flows through the sewage treatment carbon source assembly, and dynamic purification of the sewage is realized through flowing instead of standing;
step 6: and after the monitoring recovery of the sewage treatment carbon source component reaches the effective time of the corresponding component, recovering the sewage treatment carbon source component, and carbonizing at high temperature to form the activated carbon.
The application has the technical effects that:
the application adopts a compound sewage treatment agent, is suitable for treating oily sewage rich in 10-25% of grease, and comprises the following steps: 12-15 parts of a composite flocculant, 4-10 parts of a composite microbial agent, 3-5 parts of a coagulant aid, 10-25 parts of a carbon-based culture medium, 8-15 parts of a corrosion inhibitor, 3-5 parts of a chelate, 3-10 parts of a water softener and 20-35 parts of a composite carbon source. The composite carbon source is used for providing carbon elements required by microorganisms to promote the growth and reproduction of the microorganisms, and the composite microbial agent is further adopted to be matched with the carbon elements required by the microorganisms provided by the composite carbon source for growth and reproduction, and the composite carbon source and bacteria are matched with each other to participate in sewage purification.
Furthermore, the application also adopts other components which are conducive to sewage purification, can combine with a composite carbon source, a composite microbial agent and the like to effectively treat various urban sewage quality in various ranges and types, and improves the applicability and application range of the carbon source agent for sewage treatment in sewage treatment. The microbial agent can utilize grease decomposing bacteria to decompose grease so as to supplement glycerol carbon source, improve the life cycle of microorganisms in the carbon source agent for sewage treatment, improve the lasting efficacy of the carbon source agent for sewage treatment, and prolong the purifying capacity of the carbon source agent for sewage treatment on sewage.
The volcanic powder is utilized to improve the removal rate of COD and BOD, and the generation cost of the carbon source medicament is reduced. The residual substances are intensively cultured and collected by utilizing a carbon-based culture medium, and the waste is recycled. The carbon-based culture medium is in a paste state, other medicament components are concentrated together, the medicament components are not easy to be washed away by sewage, a growth hotbed and a required direct life carbon source are provided for bacteria, the microorganism propagation is facilitated, and the sewage treatment life cycle of the microorganism is prolonged.
Detailed Description
The carbon source medicament for sewage treatment is suitable for treating oily sewage rich in 10-25% of grease, and comprises the following components in parts by weight:
12-15 parts of a composite flocculant, 4-10 parts of a composite microbial agent, 10-25 parts of volcanic powder, 3-5 parts of a coagulant aid, 10-25 parts of a carbon-based culture medium, 8-15 parts of a corrosion inhibitor, 3-5 parts of a chelate, 3-10 parts of a water softener and 20-35 parts of composite carbon;
wherein:
the composite carbon source comprises the following components in parts by weight: 15-25 parts of polyalcohol and 5-10 parts of monosaccharide;
the compound microbial agent at least comprises: 1.2-2.4 parts of grease decomposing bacteria;
the carbon-based culture medium is in a paste state.
The product is suitable for oily sewage and is grease-rich sewage, and is mainly applied to sewage treatment of sewer such as restaurants, hotels and the like, because grease in the places is concentrated, the grease accounts for 10-20 percent;
the carbon-based culture medium is in a paste state, other medicament components are concentrated together, the medicament components are not easy to be washed away by sewage, a growth hotbed and a required direct life carbon source are provided for bacteria, the microorganism propagation is facilitated, and the sewage treatment life cycle of the microorganism is prolonged.
The composite carbon source consists of polyalcohol and monosaccharide, the polyalcohol can be propanol or butanol, and the monosaccharide can be glucose, sucrose, fructose, etc. The composite carbon source can provide carbon elements required by microorganisms, promote the growth and propagation of the microorganisms, and the microorganisms absorb and grow by utilizing organic substances, so that harmful substances are degraded.
The composite microbial agent contains a plurality of bacteria, but must have an appropriate amount of grease-decomposing bacteria, and the grease-decomposing bacteria can be used to decompose grease in grease-rich oily wastewater, thereby decomposing fat into fatty acid and glycerin. And glycerol can be used as a carbon source, can provide carbon elements for microorganisms and promote the growth and propagation of the microorganisms.
Therefore, the carbon source of glycerol can be generated by utilizing the action of the grease decomposing bacteria of the compound microorganism bacteria in the carbon source medicament for sewage treatment, and the carbon source except the compound carbon source can be supplemented, so that the carbon source can be continuously supplemented for the carbon source medicament for sewage treatment, the life cycle of microorganisms in the carbon source medicament for sewage treatment can be improved, the lasting efficacy of the carbon source medicament for sewage treatment can be improved, and the purifying capability of the carbon source medicament for sewage treatment for sewage can be prolonged.
If the original product is free of grease decomposing bacteria, the carbon source provided for microorganisms in the product can be in the range of 5-12 months.
If the grease decomposing bacteria are provided, the grease can be continuously decomposed to obtain glycerin, the carbon source can be continuously supplemented for the microorganism, and the life cycle of the microorganism can be prolonged.
Volcanic powder is crushed to 100-500 meshes in advance by a crusher, and is blended with liquid to form thick slurry. The volcanic rock powder has developed pores, has the functions of reinforcing water supply and accelerating water seepage, can effectively remove organic matters in sewage, and improves the removal rate of COD and BOD.
A carbon-based medium, such as beef extract, suitable for growth of carbon-based microorganisms may be used. Microorganisms can be cultured on carbon-based media to provide a direct source of carbon for growth. Meanwhile, the carbon-based culture medium can provide a growing attachment point for various bacteria, so that the various bacteria are concentrated on the culture medium, and the various bacteria are conveniently concentrated.
The carbon-based culture medium is in a paste state, is not easy to be washed away by sewage, can concentrate the medicament components of the scheme together, simultaneously provides a growth temperature bed and a required direct life carbon source for bacteria, is convenient for microorganism propagation, and greatly prolongs the sewage treatment life cycle of microorganisms.
The composite flocculant mainly comprises a modified multi-cation inorganic flocculant, a cationic organic polymer flocculant and a microbial flocculant, so that the flocculant is not only one type and attribute flocculant, but also a mixed flocculant of organic, inorganic and microorganisms. The multi-cation inorganic flocculant can strongly adsorb colloid particles, and promotes colloid coagulation through the actions of adhesion, bridging and crosslinking, and has high specific gravity and high flocculation speed. The cationic organic polymeric flocculant has the advantages of more active groups, high molecular weight, less consumption, strong flocculation capacity, easy separation of flocs and good oil and suspended matter removal effects. The microbial flocculant can overcome the inherent defects of inorganic polymer and synthetic organic polymer flocculant, and finally realize pollution-free emission.
The composite microbial agent can be obtained by utilizing a plurality of microbial colonies and fermenting, extracting and refining microorganisms such as bacteria, fungi and the like, and is a high-efficiency, nontoxic and secondary pollution-free water treatment agent with biodegradability and safety. The microbial flocculant can overcome the inherent defects of inorganic polymer and synthetic organic polymer flocculant, and finally realize pollution-free emission.
As an alternative embodiment of the present application, optionally, the modified polycationic inorganic flocculant comprises at least one of the following polycationic inorganic flocculants:
polyaluminum ferric sulfate chloride, aluminum iron copolymerization composite flocculant, polyaluminum sulfate, polysilicic acid flocculant, polysilicic acid ferric sulfate or polyaluminum ferric chloride.
As an optional embodiment of the present application, the cationic organic polymeric flocculant may comprise at least one of the following organic polymeric flocculants:
polyacrylamide, sodium polyacrylate or polyethyleneimine.
The component types of the specific inorganic flocculant and the organic polymeric flocculant can be selected specifically by a tester according to the proportion of the application.
The compound microbial agent adopts the following strains:
as an optional embodiment of the application, optionally, the composite microbial agent further comprises the following components in parts by weight:
1.0 to 3.5 parts of nitrifying bacteria, 0.5 to 3.0 parts of denitrifying bacteria, 0.2 to 0.8 part of hydrolytic zymocyte, 0.5 to 1.0 part of glycerol septic tank bacteria and 0.6 to 1.3 parts of oleaginous bacteria.
Nitrifying bacteria are aerobic bacteria and contain nitrite bacteria and nitrate bacteria. Plays an important role in the process of purifying the water quality of nitrogen circulation, rapidly oxidizes ammonia into nitrite, further oxidizes nitrite into nitrate through nitrifying bacteria, rapidly eliminates the harm of nitrite in water, and has quick and simple use.
Denitrifying bacteria are bacteria which can cause denitrification, and are subjected to long-time targeted screening, domestication technology, rejuvenation culture and fine fermentation to culture denitrifying bacteria flora which can adapt to different polluted environments, and the denitrification of returned nitrate nitrogen into nitrogen is realized under an anoxic environment so as to realize quick denitrification effect. The method is mainly applied to sewage treatment such as landscape water treatment, urban river treatment, aquaculture and the like.
The grease decomposing bacteria can secrete lipase capable of decomposing grease, and decompose the grease formed by combining glycerol with 3 fatty acids into substances which can be absorbed by microorganisms, and the substances are absorbed by the microorganisms and are metabolized in the body, so that degradation is finally obtained.
The hydrolytic zymophyte has the characteristics of strong adaptability, various types and the like. They are capable of cellulose decomposition in the anaerobic digestion system, decomposing cellulose into simple sugars; performing lipolysis to decompose the lipid into fatty acid; protein decomposition is performed to form amino acids and the like. The strains play an important role in sewage treatment, and can effectively remove impurities and peculiar smell in water, so that the sewage treatment is more efficient and environment-friendly.
The sweet septic tank bacteria can eliminate bad smell of the septic tank and solve the environmental pollution problem of organic pollutant and human excrement. Introducing microbial flora into a biological septic tank to form a microbial flora biomembrane, and absorbing, digesting and decomposing organic pollutants in sewage by using the metabolism of microbial fermentation to convert the organic pollutants into stable harmless substances so as to achieve the functions of purifying water quality and deodorizing.
The oleaginous bacteria can quickly remove floating greasy dirt on the surface of the water body, block the breeding of harmful pathogenic bacteria, prevent and control the generation of peculiar smell, promote the growth of beneficial algae and optimize the water body environment.
The different strains can be added in batches by a tester according to life characteristics of the tester.
As an alternative embodiment of the present application, the coagulant aid is optionally one of the following components:
polyacrylamide, active silicic acid or bone cement;
the corrosion inhibitor is one of the following components: nitrite or chromate.
As an alternative embodiment of the present application, optionally, the chelate is one of the following components:
polyphosphates, aminocarboxylic acids, 1, 3-diketones or hydroxycarboxylic acids.
The coagulant aid and the corrosion inhibitor are specifically selected by testers. Specific functions are not described in detail.
The water softener is used for reducing the chelating ability of heavy metal ions in sewage, sealing the heavy metal ions, avoiding the chelating of the heavy metal ions in the sewage and softening the water.
The chelate can effectively prevent metal ions such as calcium and the like from forming precipitates in sewage, thereby preventing pipeline scaling and gradually removing original scaling.
The chelate can be natural polymer chelating agent such as cellulose and alginic acid.
When the scheme is implemented in practice, the viscous mixture of the components can be poured into a preset mould, and the sewage treatment carbon source component is obtained after air drying; when the sewage treatment carbon source assembly is used, the sewage treatment carbon source assembly is placed in a sewage pipeline, sewage flows through the sewage treatment carbon source assembly, and dynamic purification of the sewage is realized through flowing instead of standing; and after the monitoring recovery of the sewage treatment carbon source component reaches the effective time of the corresponding component, recovering the sewage treatment carbon source component, and carbonizing at high temperature to form the activated carbon.
The mold may house one or more components depending on the cross-sectional flow shape of the treated wastewater.
Example 1
Weighing: 12 parts of a composite flocculant (3 parts of a multi-cation inorganic flocculant, 5 parts of a cationic organic polymeric flocculant and 4 parts of a microbial flocculant), 4 parts of a composite microbial agent (1.2 parts of grease decomposing bacteria, 1.0 part of nitrifying bacteria, 0.5 part of denitrifying bacteria, 0.2 part of hydrolytic zymocyte, 0.5 part of glycerol septic tank bacteria and 0.6 part of oleaginous bacteria), 10 parts of volcanic powder, 3 parts of a coagulant aid (bone glue), 10 parts of a carbon-based culture medium, 8 parts of a corrosion inhibitor (nitrite), 3 parts of a chelate (alginic acid), 3 parts of a water softener (aqueous polyurethane resin) and 20 parts of a composite carbon source, wherein the composite carbon source comprises the following components in parts by weight: 15 parts of polyalcohol and 5 parts of monosaccharide.
The preparation method of the carbon source medicament for sewage treatment comprises the following steps:
step 1: sequentially adding polyalcohol and monosaccharide into distilled water at 55 ℃, fully stirring until no particles exist, and taking the mixture as a composite carbon source for standby after cooling to room temperature;
step 2: weighing a composite microbial agent, adding the composite microbial agent into the solution prepared in the step 1, uniformly stirring, and standing for 3 minutes;
step 3: weighing a composite flocculant, a coagulant aid, a carbon-based culture medium, a corrosion inhibitor and a chelate, fully mixing, and then adding mixed powder into the solution prepared in the step 2; after the adding, stirring at high speed for 1 minute to fully melt the mixed powder into the solution;
step 4: weighing a liquid water softener, adding the water softener into the solution prepared in the step 3, fully stirring, and standing;
step 5: weighing volcanic powder, mixing the volcanic powder with the melt in the step 4, stirring to obtain a viscous mixture, pouring the viscous mixture into a preset mold, and air-drying to obtain a sewage treatment carbon source component; when the sewage treatment carbon source assembly is used, the sewage treatment carbon source assembly is placed in a sewage pipeline, sewage flows through the sewage treatment carbon source assembly, and dynamic purification of the sewage is realized through flowing instead of standing;
step 6: and after the monitoring recovery of the sewage treatment carbon source component reaches the effective time of the corresponding component, recovering the sewage treatment carbon source component, and carbonizing at high temperature to form the activated carbon.
Test:
filtering urban sewer sewage, removing particle impurities, placing the sewage in a beaker, and detecting COD, BOD and SS;
adding the prepared carbon source medicament for sewage treatment into a beaker, and uniformly stirring;
standing for 5 minutes after stirring, taking supernatant after standing, detecting COD, BOD and SS in the purified sewage, and supervising the effective time of the sewage treatment carbon source component in the sewage:
the comparative example was treated with a conventional single carbon source agent, as follows. After 18 months of putting the components into use, the components are recovered, carbonized and reused.
Example 2
Weighing: 13 parts of composite flocculant (4 parts of multi-cation inorganic flocculant, 5 parts of cation organic polymer flocculant and 4 parts of microbial flocculant), 6 parts of composite microbial inoculant (2.2 parts of grease decomposing bacteria, 1.5 parts of nitrifying bacteria, 0.5 part of denitrifying bacteria, 0.7 part of hydrolytic zymocyte, 0.5 part of glycerol septic tank bacteria and 0.6 part of oleaginous bacteria), 15 parts of volcanic powder, 4 parts of coagulant aid (bone glue), 15 parts of carbon-based culture medium, 10 parts of corrosion inhibitor (nitrite), 4 parts of chelate (alginic acid), 5 parts of water softener (aqueous polyurethane resin) and 25 parts of composite carbon source, wherein: the composite carbon source comprises the following components in parts by weight: 20 parts of polyalcohol and 5 parts of monosaccharide.
Step 1: sequentially adding polyalcohol and monosaccharide into 65 ℃ distilled water, fully stirring until no particles exist, and taking the mixture as a composite carbon source for standby after cooling to room temperature;
step 2: weighing a composite microbial agent, adding the composite microbial agent into the solution prepared in the step 1, uniformly stirring, and standing for 5 minutes;
step 3: weighing a composite flocculant, a coagulant aid, a carbon-based culture medium, a corrosion inhibitor and a chelate, fully mixing, and then adding mixed powder into the solution prepared in the step 2; after the adding, stirring at high speed for 3 minutes to fully melt the mixed powder into the solution;
step 4: weighing a liquid water softener, adding the water softener into the solution prepared in the step 3, fully stirring, and standing;
step 5: weighing volcanic powder, mixing the volcanic powder with the melt in the step 4, stirring to obtain a viscous mixture, pouring the viscous mixture into a preset mold, and air-drying to obtain a sewage treatment carbon source component; when the sewage treatment carbon source assembly is used, the sewage treatment carbon source assembly is placed in a sewage pipeline, sewage flows through the sewage treatment carbon source assembly, and dynamic purification of the sewage is realized through flowing instead of standing;
step 6: and after the monitoring recovery of the sewage treatment carbon source component reaches the effective time of the corresponding component, recovering the sewage treatment carbon source component, and carbonizing at high temperature to form the activated carbon.
Test:
filtering urban sewer sewage, removing particle impurities, placing the sewage in a beaker, and detecting COD, BOD and SS;
adding the prepared carbon source medicament for sewage treatment into a beaker, and uniformly stirring;
standing for 5 minutes after stirring, taking supernatant after standing, detecting COD, BOD and SS in the purified sewage, and supervising the effective time of the sewage treatment carbon source component in the sewage:
example 3
Weighing: 15 parts of a composite flocculant, 8 parts of a composite microbial agent, 25 parts of volcanic powder, 5 parts of a coagulant aid, 25 parts of a carbon-based culture medium, 13 parts of a corrosion inhibitor, 5 parts of a chelate, 7 parts of a water softener, 35 parts of a composite carbon source, 15 parts of a composite flocculant (4 parts of a multi-cation inorganic flocculant, 6 parts of a cationic organic polymeric flocculant and 5 parts of a microbial flocculant), 8 parts of a composite microbial agent (2.2 parts of grease decomposing bacteria, 1.5 parts of nitrifying bacteria, 1.5 parts of denitrifying bacteria, 0.7 part of hydrolytic fermentation bacteria, 0.8 part of glycerol septic tank bacteria and 1.3 parts of oleaginous bacteria), 25 parts of volcanic powder, 5 parts of a coagulant aid (bone glue), 25 parts of a carbon-based culture medium, 13 parts of a corrosion inhibitor (nitrite), 5 parts of a chelate (alginic acid), 7 parts of a water softener (aqueous polyurethane resin) and 35 parts of a composite carbon source, wherein: the composite carbon source comprises the following components in parts by weight: 25 parts of polyalcohol and 10 parts of monosaccharide.
Step 1: sequentially adding polyalcohol and monosaccharide into distilled water at 70 ℃, fully stirring until no particles exist, and taking the mixture as a composite carbon source for standby after cooling to room temperature;
step 2: weighing a composite microbial agent, adding the composite microbial agent into the solution prepared in the step 1, uniformly stirring, and standing for 5 minutes;
step 3: weighing a composite flocculant, a coagulant aid, a carbon-based culture medium, a corrosion inhibitor and a chelate, fully mixing, and then adding mixed powder into the solution prepared in the step 2; after the adding, stirring at high speed for 3 minutes to fully melt the mixed powder into the solution;
step 4: weighing a liquid water softener, adding the water softener into the solution prepared in the step 3, fully stirring, and standing;
step 5: weighing volcanic powder, mixing the volcanic powder with the melt in the step 4, stirring to obtain a viscous mixture, pouring the viscous mixture into a preset mold, and air-drying to obtain a sewage treatment carbon source component; when the sewage treatment carbon source assembly is used, the sewage treatment carbon source assembly is placed in a sewage pipeline, sewage flows through the sewage treatment carbon source assembly, and dynamic purification of the sewage is realized through flowing instead of standing;
step 6: and after the monitoring recovery of the sewage treatment carbon source component reaches the effective time of the corresponding component, recovering the sewage treatment carbon source component, and carbonizing at high temperature to form the activated carbon.
Test:
filtering urban sewer sewage, removing particle impurities, placing the sewage in a beaker, and detecting COD, BOD and SS;
adding the prepared carbon source medicament for sewage treatment into a beaker, and uniformly stirring;
standing for 5 minutes after stirring, taking supernatant after standing, detecting COD, BOD and SS in the purified sewage, and supervising the effective time of the sewage treatment carbon source component in the sewage:
according to the data of the above examples 1-3, as the amount of the composite carbon source increases, the corresponding composite microbial agent increases, and the increased composite carbon source can provide the required carbon element for the increased microbial flora, so that the two materials cooperate to perform sewage treatment together. Microorganisms absorb and grow by using organic substances, thereby degrading harmful substances.
The carbon-based culture medium is added to provide a growth environment for microorganisms, provide a carbon source directly needed by the life of the microorganisms, provide a propagation foundation for the microorganisms, and provide a propagation hotbed to increase the life cycle of the microorganisms, so that the carbon-based medicament can grow in sewage for a long time and effectively purify the sewage for a long time.
According to the scheme, the carbon-based culture medium can concentrate various components, is convenient to recycle subsequently, can obtain active carbon through carbonization of a recycle, can be used for re-adsorption of sewage and the like, and achieves the effect of environmental protection.
Therefore, the application not only utilizes the composite carbon source to provide carbon elements required by microorganisms to promote the growth and the reproduction of the microorganisms, but also further adopts the composite microorganism microbial inoculum to match the carbon elements required by the microorganisms provided by the composite carbon source to grow and reproduce, and the composite carbon source and bacteria are mutually matched to jointly participate in sewage purification. Other components which are conducive to sewage purification are adopted, and the composite carbon source, the composite microbial agent and the like can be combined to effectively treat various urban sewage quality in various ranges and types, so that the applicability and the application range of the carbon source agent for sewage treatment in sewage treatment are improved.
Example 4
In another aspect, the application also provides an application method of the carbon source medicament for sewage treatment, wherein the carbon source medicament for sewage treatment is applied to oil sewage treatment.
When the scheme is used for treating oily water, the carbon source agent for treating the oily water can be configured according to the amount of the oily water, and the embodiment is not limited.
If the amount of the composite carbon source is increased, the amount of the composite microbial agent can be correspondingly increased, and the composite carbon source and the composite microbial agent are mutually configured.
The foregoing description of embodiments of the application has been presented for purposes of illustration and description, and is not intended to be exhaustive or limited to the embodiments disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the various embodiments described. The terminology used herein was chosen in order to best explain the principles of the embodiments, the practical application, or the technical improvements in the marketplace, or to enable others of ordinary skill in the art to understand the embodiments disclosed herein.

Claims (9)

1. The carbon source medicament for sewage treatment is characterized by being suitable for treating oily sewage rich in 10-25% of grease, and comprises the following components in parts by weight:
12-15 parts of a composite flocculant, 4-10 parts of a composite microbial agent, 10-25 parts of volcanic powder, 3-5 parts of a coagulant aid, 10-25 parts of a carbon-based culture medium, 8-15 parts of a corrosion inhibitor, 3-5 parts of a chelate, 3-10 parts of a water softener and 20-35 parts of composite carbon;
wherein:
the composite carbon source comprises the following components in parts by weight: 15-25 parts of polyalcohol and 5-10 parts of monosaccharide;
the compound microbial agent at least comprises: 1.2-2.4 parts of grease decomposing bacteria.
2. The carbon source medicament for sewage treatment according to claim 1, wherein the composite flocculant comprises the following components in parts by weight:
6-7 parts of modified multi-cation inorganic flocculant, 4-5 parts of cation organic polymer flocculant and 2-3 parts of microbial flocculant.
3. The carbon source chemical for sewage treatment according to claim 2, wherein the modified polycationic inorganic flocculant comprises at least one of the following polycationic inorganic flocculants: polyaluminum ferric sulfate chloride, aluminum iron copolymerization composite flocculant, polyaluminum sulfate, polysilicic acid flocculant, polysilicic acid ferric sulfate or polyaluminum ferric chloride.
4. The carbon source chemical for sewage treatment according to claim 2, wherein the cationic organic polymeric flocculant comprises at least one of the following organic polymeric flocculants: polyacrylamide, sodium polyacrylate or polyethyleneimine.
5. The carbon source medicament for sewage treatment according to claim 1, wherein the composite microbial agent further comprises the following components in parts by weight: 1.0 to 3.5 parts of nitrifying bacteria, 0.5 to 3.0 parts of denitrifying bacteria, 0.2 to 0.8 part of hydrolytic zymocyte, 0.5 to 1.0 part of glycerol septic tank bacteria and 0.6 to 1.3 parts of oleaginous bacteria.
6. The carbon source chemical for sewage treatment according to claim 1, wherein the coagulant aid is one of the following components: polyacrylamide, active silicic acid or bone cement; the corrosion inhibitor is one of the following components: nitrite or chromate.
7. The carbon source chemical for sewage treatment according to claim 1, wherein the chelate compound is one of the following components: polyphosphates, aminocarboxylic acids, 1, 3-diketones or hydroxycarboxylic acids.
8. The method for producing a carbon source chemical for sewage treatment according to any one of claims 1 to 7, comprising the steps of: step 1: sequentially adding polyalcohol and monosaccharide into distilled water at 55-70 ℃, fully stirring until no particles exist, and taking the mixture as a composite carbon source for standby after cooling to room temperature; step 2: weighing a composite microbial agent, adding the composite microbial agent into the solution prepared in the step 1, uniformly stirring, and standing for 3-5 minutes; step 3: weighing a composite flocculant, a coagulant aid, a carbon-based culture medium, a corrosion inhibitor and a chelate, fully mixing, and then adding mixed powder into the solution prepared in the step 2; after the adding, stirring at a high speed for 1-3 minutes to fully melt the mixed powder into the solution; step 4: weighing a liquid water softener, adding the water softener into the solution prepared in the step 3, fully stirring, and standing; step 5: weighing volcanic powder, mixing the volcanic powder with the melt in the step 4, stirring to obtain a viscous mixture, pouring the viscous mixture into a preset mold, and air-drying to obtain a sewage treatment carbon source component; when the sewage treatment carbon source assembly is used, the sewage treatment carbon source assembly is placed in a sewage pipeline, sewage flows through the sewage treatment carbon source assembly, and dynamic purification of the sewage is realized through flowing instead of standing; step 6: and after the monitoring recovery of the sewage treatment carbon source component reaches the effective time of the corresponding component, recovering the sewage treatment carbon source component, and carbonizing at high temperature to form the activated carbon.
9. The use of a carbon source chemical for sewage treatment according to any one of claims 1 to 7, wherein the carbon source chemical for sewage treatment is applied to oil sewage treatment.
CN202311392107.0A 2023-10-25 2023-10-25 Carbon source medicament for sewage treatment and preparation method and application thereof Pending CN117105434A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004022494A1 (en) * 2002-09-06 2004-03-18 Franz Josef Astleithner Method for eliminating oil and fat or pollutants containing oil and fat
CN104211149A (en) * 2014-08-25 2014-12-17 刘娟娟 Composite flocculant used in spinning sewage treatment process
US20150239763A1 (en) * 2014-02-27 2015-08-27 Hong Kong Baptist University Biogenic Flocculant Composition To Enhance Flocculation And Dewaterability Of Chemically Enhanced Primary Treatment Sludge
CN105399219A (en) * 2015-12-23 2016-03-16 太仓东浔生物科技有限公司 Water quality regulation and control compound microbial preparation and production method thereof
CN110818079A (en) * 2019-11-20 2020-02-21 德蓝水技术股份有限公司 Bioactive carbon source for sewage treatment and preparation method thereof
CN116218718A (en) * 2023-01-04 2023-06-06 上海乾界生物科技有限公司 Microbial agent for decomposing grease

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004022494A1 (en) * 2002-09-06 2004-03-18 Franz Josef Astleithner Method for eliminating oil and fat or pollutants containing oil and fat
US20150239763A1 (en) * 2014-02-27 2015-08-27 Hong Kong Baptist University Biogenic Flocculant Composition To Enhance Flocculation And Dewaterability Of Chemically Enhanced Primary Treatment Sludge
CN104211149A (en) * 2014-08-25 2014-12-17 刘娟娟 Composite flocculant used in spinning sewage treatment process
CN105399219A (en) * 2015-12-23 2016-03-16 太仓东浔生物科技有限公司 Water quality regulation and control compound microbial preparation and production method thereof
CN110818079A (en) * 2019-11-20 2020-02-21 德蓝水技术股份有限公司 Bioactive carbon source for sewage treatment and preparation method thereof
CN116218718A (en) * 2023-01-04 2023-06-06 上海乾界生物科技有限公司 Microbial agent for decomposing grease

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