CN117085269A - Fire-retardant bag for electric power and preparation method and application thereof - Google Patents
Fire-retardant bag for electric power and preparation method and application thereof Download PDFInfo
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- CN117085269A CN117085269A CN202311026746.5A CN202311026746A CN117085269A CN 117085269 A CN117085269 A CN 117085269A CN 202311026746 A CN202311026746 A CN 202311026746A CN 117085269 A CN117085269 A CN 117085269A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 51
- 239000003063 flame retardant Substances 0.000 title claims abstract description 39
- 239000000945 filler Substances 0.000 claims abstract description 38
- 239000004744 fabric Substances 0.000 claims abstract description 37
- 239000000463 material Substances 0.000 claims abstract description 37
- 238000009413 insulation Methods 0.000 claims abstract description 20
- 239000000080 wetting agent Substances 0.000 claims abstract description 17
- 239000000835 fiber Substances 0.000 claims description 142
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 83
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 57
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical class [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims description 54
- 229910052863 mullite Inorganic materials 0.000 claims description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
- 238000002156 mixing Methods 0.000 claims description 30
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 22
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 20
- 239000004113 Sepiolite Substances 0.000 claims description 19
- 229920001721 polyimide Polymers 0.000 claims description 19
- 239000009719 polyimide resin Substances 0.000 claims description 19
- 235000019355 sepiolite Nutrition 0.000 claims description 19
- 229910052624 sepiolite Inorganic materials 0.000 claims description 19
- 239000005995 Aluminium silicate Substances 0.000 claims description 18
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 18
- 235000012211 aluminium silicate Nutrition 0.000 claims description 18
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 18
- 239000010451 perlite Substances 0.000 claims description 18
- 235000019362 perlite Nutrition 0.000 claims description 18
- 239000002694 phosphate binding agent Substances 0.000 claims description 18
- 239000002270 dispersing agent Substances 0.000 claims description 17
- 239000000843 powder Substances 0.000 claims description 17
- 239000010459 dolomite Substances 0.000 claims description 16
- 229910000514 dolomite Inorganic materials 0.000 claims description 16
- 238000010438 heat treatment Methods 0.000 claims description 16
- ZGUQGPFMMTZGBQ-UHFFFAOYSA-N [Al].[Al].[Zr] Chemical compound [Al].[Al].[Zr] ZGUQGPFMMTZGBQ-UHFFFAOYSA-N 0.000 claims description 13
- 239000007822 coupling agent Substances 0.000 claims description 13
- 229920003987 resole Polymers 0.000 claims description 12
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 12
- 238000005245 sintering Methods 0.000 claims description 12
- 239000005708 Sodium hypochlorite Substances 0.000 claims description 10
- 229920002472 Starch Polymers 0.000 claims description 10
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 10
- 229920006231 aramid fiber Polymers 0.000 claims description 10
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 10
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 10
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 10
- 239000008107 starch Substances 0.000 claims description 10
- 235000019698 starch Nutrition 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 238000009987 spinning Methods 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 230000009970 fire resistant effect Effects 0.000 claims description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- 239000004965 Silica aerogel Substances 0.000 claims description 3
- 229920002972 Acrylic fiber Polymers 0.000 claims description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 2
- INJRKJPEYSAMPD-UHFFFAOYSA-N aluminum;silicic acid;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O INJRKJPEYSAMPD-UHFFFAOYSA-N 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 claims description 2
- 229910052593 corundum Inorganic materials 0.000 claims description 2
- 239000010431 corundum Substances 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 239000010443 kyanite Substances 0.000 claims description 2
- 229910052850 kyanite Inorganic materials 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000011490 mineral wool Substances 0.000 claims description 2
- 239000005332 obsidian Substances 0.000 claims description 2
- 229940080313 sodium starch Drugs 0.000 claims description 2
- 239000001038 titanium pigment Substances 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 32
- 239000002002 slurry Substances 0.000 description 30
- 239000000203 mixture Substances 0.000 description 21
- 239000000725 suspension Substances 0.000 description 21
- 239000004964 aerogel Substances 0.000 description 17
- 238000001035 drying Methods 0.000 description 17
- 239000011268 mixed slurry Substances 0.000 description 17
- 239000005543 nano-size silicon particle Substances 0.000 description 17
- 235000012239 silicon dioxide Nutrition 0.000 description 17
- 239000004408 titanium dioxide Substances 0.000 description 16
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 14
- 239000002994 raw material Substances 0.000 description 14
- 238000002604 ultrasonography Methods 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 11
- 238000012360 testing method Methods 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 9
- 230000007935 neutral effect Effects 0.000 description 8
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 8
- 238000004806 packaging method and process Methods 0.000 description 8
- 238000007789 sealing Methods 0.000 description 8
- 238000009958 sewing Methods 0.000 description 8
- 229940032147 starch Drugs 0.000 description 8
- 238000005406 washing Methods 0.000 description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000012768 molten material Substances 0.000 description 7
- 238000000465 moulding Methods 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 238000000967 suction filtration Methods 0.000 description 7
- 238000005303 weighing Methods 0.000 description 7
- 230000008901 benefit Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000009286 beneficial effect Effects 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 238000003892 spreading Methods 0.000 description 3
- 230000007480 spreading Effects 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 238000002679 ablation Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C2/00—Fire prevention or containment
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C3/00—Fire prevention, containment or extinguishing specially adapted for particular objects or places
- A62C3/16—Fire prevention, containment or extinguishing specially adapted for particular objects or places in electrical installations, e.g. cableways
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/02—Inorganic materials
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
Abstract
The invention discloses a fire-retardant bag for electric power and a preparation method and application thereof. Relates to the technical field of fire-retarding bags. The fire-retardant bag comprises the following components in parts by weight: 45-75 parts of fireproof filler; 5-25 parts of heat insulation filler; 12-32 parts of an expansion material; 5-25 parts of fireproof cloth; 2-18 parts of wetting agent. The fire-retardant bag has high fire-retardant temperature, the outer layer fabric is not ablated at 700 ℃, and the inner filler is not easy to spill.
Description
Technical Field
The invention relates to the technical field of fire-retarding bags, in particular to a fire-retarding bag for electric power as well as a preparation method and application thereof.
Background
To reduce the economic loss caused by fire of wires and cables, fire-retardant packages have been developed. The fire-fighting device has the functions of blocking various cable, penetrating body or hollow and gap of the cable shaft, effectively preventing the diffusion and spreading of flame and smoke when fire occurs, controlling the fire in a certain range and reducing loss. Considering that fire-retarding bags are frequently replaced in use places, the drop resistance and fire resistance of the fire-retarding bags are required to be higher. The requirement on fire resistance is particularly characterized in that the fire-retarding bag needs to have high fire resistance (more than or equal to 3.00 h); the fire-retarding bag needs to have anti-falling performance, and is characterized in that the fire-retarding bag falls freely from a position with the height of 5 meters, and the bag body is not damaged.
In a fire disaster, the outer layer fabric of the traditional fire retardant bag is easy to ablate, and after the filler in the fire retardant bag overflows, the fire retardant layer is easy to collapse, so that a fire source and hot air cannot be completely blocked. According to analysis, the fire resistance temperature of the traditional fire-retardant bag fabric is about 600 ℃, and the temperature in a fire disaster reaches 700 ℃ and above, so that the phenomenon of collapse of the fire-retardant bag easily occurs during high-temperature combustion. In order to achieve better fireproof effect, the practical application will increase the plugging thickness of the fire-retardant bag, and the use cost will also increase.
Based on the above, there is a need to develop a new fire-retarding bag with low cost, ablation resistance, long fire-retarding time and other comprehensive properties.
Disclosure of Invention
The first technical problem to be solved by the invention is as follows:
a firestop bag is provided.
The second technical problem to be solved by the invention is as follows:
a method for preparing the fire-retardant bag is provided.
The third technical problem to be solved by the invention is:
the invention also provides a fire-retardant bag for electric power.
In order to solve the first technical problem, the invention adopts the following technical scheme:
the fire-retardant bag comprises the following components in parts by weight:
45-75 parts of fireproof filler;
5-25 parts of heat insulation filler;
12-32 parts of an expansion material;
5-25 parts of fireproof cloth;
2-18 parts of wetting agent.
According to the embodiments of the present invention, one of the technical solutions has at least one of the following advantages or beneficial effects:
the fire-retardant bag has high fire-retardant temperature, the outer layer fabric is not ablated at 700 ℃, and the inner filler is not easy to spill.
According to one embodiment of the invention, the insulating filler comprises at least one of modified porous mullite fibers and modified aluminum silicate fibers.
According to the embodiment of the invention, the fire-retarding bag added with the modified porous mullite fiber has at least one of the following advantages or beneficial effects:
the modified porous mullite fiber improves the high temperature resistance by adding a specific modifier. This means that it can better withstand the heat in high temperature environments, preventing the temperature inside the firestop bag from rising, thus protecting the equipment and structures. The modified porous mullite fiber is modified, so that the physical properties, such as mechanical strength, wear resistance and the like, of the modified porous mullite fiber are improved. This may make the firestop package more durable and better resistant to the effects of external forces. In addition, the modified porous mullite fiber has excellent fireproof performance, can resist the erosion of high temperature and flame, prevent the spread of fire and reduce the damage of the fire to equipment. It can form a barrier against flame intrusion, protecting the components and structures inside the device. Furthermore, the modified porous mullite fiber is internally provided with a non-closed air hole channel, so that the heat insulation property of the fire retardant package can be further improved, and the air hole channel can physically obstruct heat conduction to a certain extent, so that the heat needs to pass through a complex channel path, and the conduction speed is reduced.
According to the embodiment of the invention, the fire-retarding bag added with the modified aluminum silicate fiber has at least one of the following advantages or beneficial effects:
the modified aluminum silicate fiber has excellent heat insulation performance, and can effectively reduce heat conduction, so that the temperature rise speed in the case of fire is reduced, and the fire spreading is delayed. The modified aluminum silicate fiber is not easy to burn at high temperature, has good fire resistance, can reduce the risk of fire spread, and protects the power equipment from damage. The fiber can play a role in reinforcing the structure in the fire-retarding bag, so that the mechanical strength and stability of the material are improved, and the material is prevented from losing efficacy under the condition of fire. In addition, the modified aluminum silicate fiber also has a synergistic effect with the following components in the firestop bag: the modified aluminum silicate fiber, other fireproof fillers and heat insulation fillers form a multi-layer heat insulation barrier, so that the fire spreading speed is reduced together, and the fire resistance of the power equipment is improved; the modified aluminum silicate fiber interacts with the expansion material when a fire disaster occurs to assist the expansion material to release the expansion gas to form a heat insulation expansion layer, so that the fireproof effect of the fire retardant bag is enhanced; the interaction of the modified aluminum silicate fiber, the fireproof cloth and the wetting agent enhances the overall structural strength of the fire retardant package, and meanwhile, the synergistic effect among the components can be promoted through a certain wetting effect to form tighter combination.
According to one embodiment of the invention, the preparation method of the modified porous mullite fiber comprises the following steps: mixing mullite fiber, aluminum-zirconium coupling agent and resol, reacting, adding aramid fiber, calcined alumina, silica sol, sodium hypochlorite, starch and sodium carboxymethyl cellulose, and sintering to obtain the modified porous mullite fiber.
According to one embodiment of the invention, the aramid fiber and mullite fiber may form a mixed structure in the material, thereby improving the mechanical strength and stability of the modified porous mullite fiber. The two fibers may interweave with each other to form a network that helps to resist external forces and maintain the overall structure of the material. The resol resin and the mullite fiber surface undergo a grafting reaction, so that the combination of the fibers and the resin is realized. This helps to enhance the cohesiveness and overall strength of the material, improving the durability of the material. The calcined alumina and the silica sol act synergistically in the material to jointly improve the heat insulation performance and the high temperature resistance. Both alumina and silica sol have thermal insulation properties, and their combination can form a thermal insulation layer, reducing heat conduction. In addition, they interact with other components to promote the formation of pores. Sodium hypochlorite is decomposed during the high temperature sintering process, releasing gas, resulting in the formation of pores. It cooperates with alumina and silica sol to increase the porosity of the material and thus raise the heat insulating performance. Starch and sodium carboxymethyl cellulose are used to adjust the flowability and formability of the material. They may act as binders in the slurry, helping to mix the various ingredients evenly and maintain good formability. The aluminum-zirconium coupling agent chemically bonds with the mullite fiber at the interface, thereby enhancing the cohesiveness between the fiber and other components. This may help to improve the overall strength and structural stability of the material.
According to one embodiment of the invention, in the process of preparing the modified porous mullite fiber, the mass ratio of the mullite fiber to the aluminum-zirconium coupling agent is 100-150:10-15.
According to one embodiment of the invention, in the process of preparing the modified porous mullite fiber, the ratio of the total mass of the mullite fiber and the aluminum-zirconium coupling agent to the mass of the resol is 100-150:10-15.
According to one embodiment of the invention, the mullite fiber, the aluminum zirconium coupling agent and the resole resin are subjected to reaction and then further comprise the step of washing to be neutral and drying, wherein the pH is controlled to be about 7, the drying time is 2-4h, and the drying temperature is 60-80 ℃.
According to one embodiment of the invention, the sintering temperature is 500-1000 ℃ and the sintering time is 4-6 hours in the process of preparing the modified porous mullite fiber.
According to one embodiment of the present invention, the method for preparing the modified aluminum silicate fiber comprises the following steps: mixing kaolin powder, alumina, titanium pigment, aluminum phosphate binder, silane coupling agent, nano silica aerogel, polyimide resin and dispersing agent in an environment with pH of 4-6, heating and spinning to obtain the modified aluminum silicate fiber.
According to one embodiment of the present invention, a method for preparing a modified aluminum silicate fiber comprises the steps of: the following components were mixed: 110-120 parts of kaolin powder, 11-15 parts of aluminum oxide, 4-10 parts of titanium dioxide, 7-10 parts of dispersing agent, 28-30 parts of nano silicon dioxide aerogel, 9-10 parts of polyimide resin, 5-10 parts of silane coupling agent, 6-10 parts of aluminum phosphate binder and 240-300 parts of water.
According to one embodiment of the invention, the aluminum phosphate binder adsorbs and gels with the kaolin, alumina and titanium dioxide, causing them to form a uniform dispersion in water, facilitating uniform mixing of the subsequent ingredients. The nano silicon dioxide aerogel plays a plurality of roles in the mixed slurry, not only improves the fluidity and the formability of the slurry, but also improves the performance of the finished fiber through the effects of surface adsorption and the like. The polyimide resin plays a role in bonding in the mixed slurry, is favorable for firmly bonding various components together, can form a composite system with nano silica aerogel and the like, and enhances the structural strength of the modified aluminum silicate fiber. The silane coupling agent chemically reacts with other components in the mixed slurry, such as: the silane coupling agent can react with the nano silicon dioxide aerogel to form a silicon-oxygen bond, and the silane coupling agent can react with the functional groups in the polyimide resin to form a cross-linked structure in the material to form bonding or interaction, so that the adhesiveness and compatibility between components are improved, and the overall performance of the modified aluminum silicate fiber is enhanced.
According to one embodiment of the present invention, the fireproof filler includes at least one of pitchstone, obsidian, rock wool, dolomite, sepiolite, and corundum.
According to one embodiment of the invention, the expanded material comprises at least one of kyanite and expanded perlite.
According to one embodiment of the present invention, the fire cloth includes at least one of acrylic fiber fire cloth, zirconia ceramic fire cloth, and high silica cloth.
According to one embodiment of the invention, the wetting agent comprises at least one of sodium dodecyl sulfate, water, glycerin, and propylene glycol.
In order to solve the second technical problem, the invention adopts the following technical scheme:
a method of making the firestop package comprising the steps of:
mixing the fireproof filler, the heat-insulating filler, the expansion material, the fireproof cloth and the wetting agent, and mixing to obtain the fire-retarding bag.
According to one embodiment of the present invention, the kneading comprises the steps of charging a fire-proof filler, a heat-insulating filler, an expansion material, a fire-proof cloth and a wetting agent into a kneader at normal temperature, and kneading for 10 to 60 minutes.
In another aspect of the invention, a firestop bag for electric power is also provided. Including the firestop bag as described in the embodiment of aspect 1 above. The application adopts all the technical schemes of the fire-retarding bag, so that the fire-retarding bag has at least all the beneficial effects brought by the technical schemes of the embodiment.
Additional features and advantages of the invention will be set forth in the description which follows, and in part will be obvious from the description, or may be learned by practice of the invention.
Detailed Description
In the description of the present invention, the description of first, second, etc. is for the purpose of distinguishing between technical features only and should not be construed as indicating or implying a relative importance or implicitly indicating the number of technical features indicated or implicitly indicating the precedence of the technical features indicated.
In the description of the present invention, it should be understood that references to orientation descriptions, such as directions or positional relationships indicated above, below, etc., are based on the orientation or positional relationships shown in the embodiments, are merely for convenience of description of the present invention and to simplify the description, and do not indicate or imply that the apparatus or elements referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus should not be construed as limiting the present invention.
The words "preferably," "more preferably," and the like in the present invention refer to embodiments of the invention that may provide certain benefits in some instances. However, other embodiments may be preferred under the same or other circumstances. Furthermore, the recitation of one or more preferred embodiments does not imply that other embodiments are not useful, nor is it intended to exclude other embodiments from the scope of the invention.
When a range of values is disclosed herein, the range is considered to be continuous and includes both the minimum and maximum values for the range, as well as each value between such minimum and maximum values. Further, when a range refers to an integer, each integer between the minimum and maximum values of the range is included. Further, when multiple range description features or characteristics are provided, the ranges may be combined. In other words, unless otherwise indicated, all ranges disclosed herein are to be understood to include any and all subranges subsumed therein.
The technical solutions of the embodiments of the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention, and it is apparent that the described embodiments are only some embodiments of the present invention, not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to fall within the scope of the invention.
The reagents, methods and apparatus employed in the present invention, unless otherwise specified, are all conventional in the art.
Example 1
The fire-retardant bag comprises the following components in parts by weight:
fireproof filler: 67 parts of dolomite and sepiolite;
and (3) heat insulation filler: 12 parts of modified mullite fiber and modified aluminum silicate fiber;
expansion material: 16 parts of expanded perlite;
5-25 parts of fireproof cloth;
2-18 parts of wetting agent.
The preparation method of the fire-retardant bag comprises the following steps:
(1) 65 parts of dolomite, 16 parts of expanded perlite, 8 parts of modified mullite fiber, 4 parts of modified aluminum silicate fiber, 2 parts of sepiolite and 8 parts of water are put into a kneader at normal temperature and kneaded for 30 minutes.
(2) And (3) packaging: and taking out the mixed materials from the kneader into 11 parts of high silica cloth bags, sealing the bags by a sewing machine, and storing the bags for 24 hours for sample preparation and testing.
The preparation raw materials of the modified mullite fiber comprise:
85 parts of mullite fiber, 5 parts of aramid fiber, 0.1 part of calcined alumina micropowder, 0.5 part of silica sol, 0.2 part of sodium hypochlorite, 1.3 parts of starch and 1.5 parts of sodium carboxymethyl cellulose.
The preparation method of the modified mullite fiber comprises the following steps:
the mass fraction ratio of the unmodified mullite fiber to the aluminum-zirconium coupling agent is 100:10, mixing to obtain a mixture;
dispersing the mixture with ultrasound with an ultrasound power of 200KHZ for 30min;
the mass fraction ratio of the resol to the mixture is 10:100, carrying out grafting reaction;
washing with water to neutral, drying at 80deg.C for 2 hr at pH of about 7;
weighing the dried mullite fiber according to the proportion of the components, uniformly mixing, obtaining slurry through mixing, carrying out suction filtration molding, drying for 4 hours at 100+/-10 ℃, and then sending into 500-1000 ℃ for sintering for 4 hours to obtain the modified porous mullite fiber.
The preparation raw materials of the modified aluminum silicate fiber comprise:
110 parts of kaolin powder, 11 parts of aluminum oxide, 4 parts of titanium dioxide, 7 parts of dispersing agent, 28 parts of nano silicon dioxide aerogel, 9 parts of polyimide resin, 5 parts of silane coupling agent, 6 parts of aluminum phosphate binder and 240 parts of water.
The preparation method of the modified aluminum silicate fiber comprises the following steps:
firstly, adding kaolin powder, alumina, titanium dioxide and an aluminum phosphate binder into water to prepare suspension slurry;
adding phosphoric acid to adjust the pH value of the suspension slurry to 4-6, heating to 40 ℃ and keeping for 24 hours;
adding a silane coupling agent, nano silicon dioxide aerogel, polyimide resin and a dispersing agent into the suspension slurry, and uniformly stirring to obtain mixed slurry;
finally, heating the mixed slurry to 400 ℃ to obtain molten material liquid, and spinning to obtain the modified aluminum silicate fiber.
Example 2
The fire-retardant bag comprises the following components in parts by weight:
fireproof filler: 62 parts of dolomite and sepiolite;
and (3) heat insulation filler: 14 parts of modified mullite fiber and modified aluminum silicate fiber;
expansion material: 22 parts of expanded perlite;
5-25 parts of fireproof cloth;
2-18 parts of wetting agent.
The preparation method of the fire-retardant bag comprises the following steps:
(1) 61 parts of dolomite, 22 parts of expanded perlite, 9 parts of modified mullite fiber, 5 parts of modified aluminum silicate fiber, 1 part of sepiolite and 9 parts of water are put into a kneader at normal temperature and kneaded for 30 minutes.
(2) And (3) packaging: and taking out the mixed materials from the kneader into 12 parts of high silica cloth bag bags, sealing the bags by a sewing machine, and storing the bags for 24 hours for sample preparation and testing.
The preparation raw materials of the modified mullite fiber comprise:
85 parts of mullite fiber, 5 parts of aramid fiber, 0.1 part of calcined alumina micropowder, 0.5 part of silica sol, 0.2 part of sodium hypochlorite, 1.3 parts of starch and 1.5 parts of sodium carboxymethyl cellulose.
The preparation method of the modified mullite fiber comprises the following steps:
the mass fraction ratio of the unmodified mullite fiber to the aluminum-zirconium coupling agent is 100:10, mixing to obtain a mixture;
dispersing the mixture with ultrasound with an ultrasound power of 200KHZ for 30min;
the mass fraction ratio of the resol to the mixture is 10:100, carrying out grafting reaction;
washing with water to neutral, drying at 80deg.C for 2 hr at pH of about 7;
weighing the dried mullite fiber according to the proportion of the components, uniformly mixing, obtaining slurry through mixing, carrying out suction filtration molding, drying for 4 hours at 100+/-10 ℃, and then sending into 500-1000 ℃ for sintering for 4 hours to obtain the modified porous mullite fiber.
The preparation raw materials of the modified aluminum silicate fiber comprise:
110 parts of kaolin powder, 11 parts of aluminum oxide, 4 parts of titanium dioxide, 7 parts of dispersing agent, 28 parts of nano silicon dioxide aerogel, 9 parts of polyimide resin, 5 parts of silane coupling agent, 6 parts of aluminum phosphate binder and 240 parts of water.
The preparation method of the modified aluminum silicate fiber comprises the following steps:
firstly, adding kaolin powder, alumina, titanium dioxide and an aluminum phosphate binder into water to prepare suspension slurry;
adding phosphoric acid to adjust the pH value of the suspension slurry to 4-6, heating to 40 ℃ and keeping for 24 hours;
adding a silane coupling agent, nano silicon dioxide aerogel, polyimide resin and a dispersing agent into the suspension slurry, and uniformly stirring to obtain mixed slurry;
finally, heating the mixed slurry to 400 ℃ to obtain molten material liquid, and spinning to obtain the modified aluminum silicate fiber.
Example 3
The fire-retardant bag comprises the following components in parts by weight:
fireproof filler: 63 parts of dolomite and sepiolite;
and (3) heat insulation filler: 5-25 parts of modified mullite fiber and modified aluminum silicate fiber;
expansion material: 25 parts of expanded perlite;
5-25 parts of fireproof cloth;
2-18 parts of wetting agent.
The preparation method of the fire-retardant bag comprises the following steps:
(1) 58 parts of dolomite, 25 parts of expanded perlite, 9 parts of modified mullite fiber, 9 parts of modified aluminum silicate fiber, 5 parts of 1 part of sepiolite and 11 parts of water are put into a kneader at normal temperature and kneaded for 30 minutes.
(2) And (3) packaging: and taking out the mixed materials from the kneader into 13 parts of high silica cloth bags, sealing the bags by a sewing machine, and storing the bags for 24 hours for sample preparation and testing.
The preparation raw materials of the modified mullite fiber comprise:
85 parts of mullite fiber, 5 parts of aramid fiber, 0.1 part of calcined alumina micropowder, 0.5 part of silica sol, 0.2 part of sodium hypochlorite, 1.3 parts of starch and 1.5 parts of sodium carboxymethyl cellulose.
The preparation method of the modified mullite fiber comprises the following steps:
the mass fraction ratio of the unmodified mullite fiber to the aluminum-zirconium coupling agent is 100:10, mixing to obtain a mixture;
dispersing the mixture with ultrasound with an ultrasound power of 200KHZ for 30min;
the mass fraction ratio of the resol to the mixture is 10:100, carrying out grafting reaction;
washing with water to neutral, drying at 80deg.C for 2 hr at pH of about 7;
weighing the dried mullite fiber according to the proportion of the components, uniformly mixing, obtaining slurry through mixing, carrying out suction filtration molding, drying for 4 hours at 100+/-10 ℃, and then sending into 500-1000 ℃ for sintering for 4 hours to obtain the modified porous mullite fiber.
The preparation raw materials of the modified aluminum silicate fiber comprise:
110 parts of kaolin powder, 11 parts of aluminum oxide, 4 parts of titanium dioxide, 7 parts of dispersing agent, 28 parts of nano silicon dioxide aerogel, 9 parts of polyimide resin, 5 parts of silane coupling agent, 6 parts of aluminum phosphate binder and 240 parts of water.
The preparation method of the modified aluminum silicate fiber comprises the following steps:
firstly, adding kaolin powder, alumina, titanium dioxide and an aluminum phosphate binder into water to prepare suspension slurry;
adding phosphoric acid to adjust the pH value of the suspension slurry to 4-6, heating to 40 ℃ and keeping for 24 hours;
adding a silane coupling agent, nano silicon dioxide aerogel, polyimide resin and a dispersing agent into the suspension slurry, and uniformly stirring to obtain mixed slurry;
finally, heating the mixed slurry to 400 ℃ to obtain molten material liquid, and spinning to obtain the modified aluminum silicate fiber.
Example 4
The fire-retardant bag comprises the following components in parts by weight:
fireproof filler: 74 parts of dolomite and sepiolite;
and (3) heat insulation filler: 16 parts of modified mullite fiber and modified aluminum silicate fiber;
expansion material: 19 parts of expanded perlite;
5-25 parts of fireproof cloth;
2-18 parts of wetting agent.
The preparation method of the fire-retardant bag comprises the following steps:
(1) 72 parts of dolomite, 19 parts of expanded perlite, 10 parts of modified mullite fiber, 6 parts of modified aluminum silicate fiber, 2 parts of sepiolite and 12 parts of water are put into a kneader at normal temperature and kneaded for 30 minutes.
(2) And (3) packaging: and taking out the mixed materials from the kneader into 13 parts of high silica cloth bags, sealing the bags by a sewing machine, and storing the bags for 24 hours for sample preparation and testing.
The preparation raw materials of the modified mullite fiber comprise:
85 parts of mullite fiber, 5 parts of aramid fiber, 0.1 part of calcined alumina micropowder, 0.5 part of silica sol, 0.2 part of sodium hypochlorite, 1.3 parts of starch and 1.5 parts of sodium carboxymethyl cellulose.
The preparation method of the modified mullite fiber comprises the following steps:
the mass fraction ratio of the unmodified mullite fiber to the aluminum-zirconium coupling agent is 100:10, mixing to obtain a mixture;
dispersing the mixture with ultrasound with an ultrasound power of 200KHZ for 30min;
the mass fraction ratio of the resol to the mixture is 10:100, carrying out grafting reaction;
washing with water to neutral, drying at 80deg.C for 2 hr at pH of about 7;
weighing the dried mullite fiber according to the proportion of the components, uniformly mixing, obtaining slurry through mixing, carrying out suction filtration molding, drying for 4 hours at 100+/-10 ℃, and then sending into 500-1000 ℃ for sintering for 4 hours to obtain the modified porous mullite fiber.
The preparation raw materials of the modified aluminum silicate fiber comprise:
110 parts of kaolin powder, 11 parts of aluminum oxide, 4 parts of titanium dioxide, 7 parts of dispersing agent, 28 parts of nano silicon dioxide aerogel, 9 parts of polyimide resin, 5 parts of silane coupling agent, 6 parts of aluminum phosphate binder and 240 parts of water.
The preparation method of the modified aluminum silicate fiber comprises the following steps:
firstly, adding kaolin powder, alumina, titanium dioxide and an aluminum phosphate binder into water to prepare suspension slurry;
adding phosphoric acid to adjust the pH value of the suspension slurry to 4-6, heating to 40 ℃ and keeping for 24 hours;
adding a silane coupling agent, nano silicon dioxide aerogel, polyimide resin and a dispersing agent into the suspension slurry, and uniformly stirring to obtain mixed slurry;
finally, heating the mixed slurry to 400 ℃ to obtain molten material liquid, and spinning to obtain the modified aluminum silicate fiber.
Example 5
Example 5 differs from example 1 in that: and (3) replacing the high silica cloth bag in the step (2) with a low-melting-point glass fiber bag.
The fire-retardant bag comprises the following components in parts by weight:
fireproof filler: 67 parts of dolomite and sepiolite;
and (3) heat insulation filler: 12 parts of modified mullite fiber and modified aluminum silicate fiber;
expansion material: 16 parts of expanded perlite;
5-25 parts of fireproof cloth;
2-18 parts of wetting agent.
The preparation method of the fire-retardant bag comprises the following steps:
(1) 65 parts of dolomite, 16 parts of expanded perlite, 8 parts of modified mullite fiber, 4 parts of modified aluminum silicate fiber, 2 parts of sepiolite and 8 parts of water are put into a kneader at normal temperature and kneaded for 30 minutes.
(2) And (3) packaging: and taking out the mixed materials from the kneader into 11 parts of low-melting-point glass fiber bags, sealing the bags by a sewing machine, and storing the bags for 24 hours for sample preparation and testing.
The preparation raw materials of the modified mullite fiber comprise:
85 parts of mullite fiber, 5 parts of aramid fiber, 0.1 part of calcined alumina micropowder, 0.5 part of silica sol, 0.2 part of sodium hypochlorite, 1.3 parts of starch and 1.5 parts of sodium carboxymethyl cellulose.
The preparation method of the modified mullite fiber comprises the following steps:
the mass fraction ratio of the unmodified mullite fiber to the aluminum-zirconium coupling agent is 100:10, mixing to obtain a mixture;
dispersing the mixture with ultrasound with an ultrasound power of 200KHZ for 30min;
the mass fraction ratio of the resol to the mixture is 10:100, carrying out grafting reaction;
washing with water to neutral, drying at 80deg.C for 2 hr at pH of about 7;
weighing the dried mullite fiber according to the proportion of the components, uniformly mixing, obtaining slurry through mixing, carrying out suction filtration molding, drying for 4 hours at 100+/-10 ℃, and then sending into 500-1000 ℃ for sintering for 4 hours to obtain the modified porous mullite fiber.
The preparation raw materials of the modified aluminum silicate fiber comprise:
110 parts of kaolin powder, 11 parts of aluminum oxide, 4 parts of titanium dioxide, 7 parts of dispersing agent, 28 parts of nano silicon dioxide aerogel, 9 parts of polyimide resin, 5 parts of silane coupling agent, 6 parts of aluminum phosphate binder and 240 parts of water.
The preparation method of the modified aluminum silicate fiber comprises the following steps:
firstly, adding kaolin powder, alumina, titanium dioxide and an aluminum phosphate binder into water to prepare suspension slurry;
adding phosphoric acid to adjust the pH value of the suspension slurry to 4-6, heating to 40 ℃ and keeping for 24 hours;
adding a silane coupling agent, nano silicon dioxide aerogel, polyimide resin and a dispersing agent into the suspension slurry, and uniformly stirring to obtain mixed slurry;
finally, heating the mixed slurry to 400 ℃ to obtain molten material liquid, and spinning to obtain the modified aluminum silicate fiber.
Comparative example 1
Comparative example 1 differs from example 2 in that: the fire-resistant filler of comparative example 1 is boric acid and sepiolite.
The fire-retardant bag comprises the following components in parts by weight:
fireproof filler: 62 parts of boric acid and sepiolite;
and (3) heat insulation filler: 14 parts of modified mullite fiber and modified aluminum silicate fiber;
expansion material: 22 parts of expanded perlite;
5-25 parts of fireproof cloth;
2-18 parts of wetting agent.
The preparation method of the fire-retardant bag comprises the following steps:
(1) 61 parts of boric acid, 22 parts of expanded perlite, 9 parts of modified mullite fiber, 5 parts of modified aluminum silicate fiber, 1 part of sepiolite and 9 parts of water are put into a kneader at normal temperature and kneaded for 30 minutes.
(2) And (3) packaging: and taking out the mixed materials from the kneader into 12 parts of high silica cloth bag bags, sealing the bags by a sewing machine, and storing the bags for 24 hours for sample preparation and testing.
The preparation raw materials of the modified mullite fiber comprise:
85 parts of mullite fiber, 5 parts of aramid fiber, 0.1 part of calcined alumina micropowder, 0.5 part of silica sol, 0.2 part of sodium hypochlorite, 1.3 parts of starch and 1.5 parts of sodium carboxymethyl cellulose.
The preparation method of the modified mullite fiber comprises the following steps:
the mass fraction ratio of the unmodified mullite fiber to the aluminum-zirconium coupling agent is 100:10, mixing to obtain a mixture;
dispersing the mixture with ultrasound with an ultrasound power of 200KHZ for 30min;
the mass fraction ratio of the resol to the mixture is 10:100, carrying out grafting reaction;
washing with water to neutral, drying at 80deg.C for 2 hr at pH of about 7;
weighing the dried mullite fiber according to the proportion of the components, uniformly mixing, obtaining slurry through mixing, carrying out suction filtration molding, drying for 4 hours at 100+/-10 ℃, and then sending into 500-1000 ℃ for sintering for 4 hours to obtain the modified porous mullite fiber.
The preparation raw materials of the modified aluminum silicate fiber comprise:
110 parts of kaolin powder, 11 parts of aluminum oxide, 4 parts of titanium dioxide, 7 parts of dispersing agent, 28 parts of nano silicon dioxide aerogel, 9 parts of polyimide resin, 5 parts of silane coupling agent, 6 parts of aluminum phosphate binder and 240 parts of water.
The preparation method of the modified aluminum silicate fiber comprises the following steps:
firstly, adding kaolin powder, alumina, titanium dioxide and an aluminum phosphate binder into water to prepare suspension slurry;
adding phosphoric acid to adjust the pH value of the suspension slurry to 4-6, heating to 40 ℃ and keeping for 24 hours;
adding a silane coupling agent, nano silicon dioxide aerogel, polyimide resin and a dispersing agent into the suspension slurry, and uniformly stirring to obtain mixed slurry;
finally, heating the mixed slurry to 400 ℃ to obtain molten material liquid, and spinning to obtain the modified aluminum silicate fiber.
Comparative example 2
Comparative example 2 differs from example 1 in that: comparative example 2 employed unmodified mullite fiber.
The fire-retardant bag comprises the following components in parts by weight:
fireproof filler: 67 parts of dolomite and sepiolite;
and (3) heat insulation filler: 12 parts of unmodified mullite fiber and modified aluminum silicate fiber;
expansion material: 16 parts of expanded perlite;
5-25 parts of fireproof cloth;
2-18 parts of wetting agent.
The preparation method of the fire-retardant bag comprises the following steps:
(1) 65 parts of dolomite, 16 parts of expanded perlite, 8 parts of unmodified mullite fiber, 4 parts of modified aluminum silicate fiber, 2 parts of sepiolite and 8 parts of water are put into a kneader at normal temperature and kneaded for 30 minutes.
(2) And (3) packaging: and taking out the mixed materials from the kneader into 11 parts of high silica cloth bags, sealing the bags by a sewing machine, and storing the bags for 24 hours for sample preparation and testing.
The preparation raw materials of the modified aluminum silicate fiber comprise:
110 parts of kaolin powder, 11 parts of aluminum oxide, 4 parts of titanium dioxide, 7 parts of dispersing agent, 28 parts of nano silicon dioxide aerogel, 9 parts of polyimide resin, 5 parts of silane coupling agent, 6 parts of aluminum phosphate binder and 240 parts of water.
The preparation method of the modified aluminum silicate fiber comprises the following steps:
firstly, adding kaolin powder, alumina, titanium dioxide and an aluminum phosphate binder into water to prepare suspension slurry;
adding phosphoric acid to adjust the pH value of the suspension slurry to 4-6, heating to 40 ℃ and keeping for 24 hours;
adding a silane coupling agent, nano silicon dioxide aerogel, polyimide resin and a dispersing agent into the suspension slurry, and uniformly stirring to obtain mixed slurry;
finally, heating the mixed slurry to 400 ℃ to obtain molten material liquid, and spinning to obtain the modified aluminum silicate fiber.
Comparative example 3
Comparative example 3 differs from example 1 in that: comparative example 3 uses unmodified aluminum silicate fibers.
The fire-retardant bag comprises the following components in parts by weight:
fireproof filler: 67 parts of dolomite and sepiolite;
and (3) heat insulation filler: 12 parts of modified mullite fiber and unmodified aluminum silicate fiber;
expansion material: 16 parts of expanded perlite;
5-25 parts of fireproof cloth;
2-18 parts of wetting agent.
The preparation method of the fire-retardant bag comprises the following steps:
(1) 65 parts of dolomite, 16 parts of expanded perlite, 8 parts of modified mullite fiber, 4 parts of unmodified aluminum silicate fiber, 2 parts of sepiolite and 8 parts of water are put into a kneader at normal temperature and kneaded for 30 minutes.
(2) And (3) packaging: and taking out the mixed materials from the kneader into 11 parts of high silica cloth bags, sealing the bags by a sewing machine, and storing the bags for 24 hours for sample preparation and testing.
The preparation raw materials of the modified mullite fiber comprise:
85 parts of mullite fiber, 5 parts of aramid fiber, 0.1 part of calcined alumina micropowder, 0.5 part of silica sol, 0.2 part of sodium hypochlorite, 1.3 parts of starch and 1.5 parts of sodium carboxymethyl cellulose.
The preparation method of the modified mullite fiber comprises the following steps:
the mass fraction ratio of the unmodified mullite fiber to the aluminum-zirconium coupling agent is 100:10, mixing to obtain a mixture;
dispersing the mixture with ultrasound with an ultrasound power of 200KHZ for 30min;
the mass fraction ratio of the resol to the mixture is 10:100, carrying out grafting reaction;
washing with water to neutral, drying at 80deg.C for 2 hr at pH of about 7;
weighing the dried mullite fiber according to the proportion of the components, uniformly mixing, obtaining slurry through mixing, carrying out suction filtration molding, drying for 4 hours at 100+/-10 ℃, and then sending into 500-1000 ℃ for sintering for 4 hours to obtain the modified porous mullite fiber.
Performance test:
the firestop packages of examples 1-5 and comparative example 1 were tested, with reference to GB23864-2009, and the test results are shown in table 1.
TABLE 1
The firestop packages of example 1 and comparative examples 2-3 were tested, the test methods were referred to GB23864-2009, and the test results are shown in Table 2.
TABLE 2
The foregoing is merely exemplary embodiments of the present invention and are not intended to limit the scope of the present invention, and all equivalent modifications made by the present invention or direct or indirect application in the relevant art are intended to be included in the scope of the present invention.
Claims (10)
1. A fire-retardant package, characterized in that: comprises the following components in parts by weight:
45-75 parts of fireproof filler;
5-25 parts of heat insulation filler;
12-32 parts of an expansion material;
5-25 parts of fireproof cloth;
2-18 parts of wetting agent.
2. A firestop bag according to claim 1, wherein: the thermal insulation filler comprises at least one of modified porous mullite fibers and modified aluminum silicate fibers.
3. A firestop bag according to claim 2, wherein: the preparation method of the modified porous mullite fiber comprises the following steps: mixing mullite fiber, aluminum-zirconium coupling agent and resol, reacting, adding aramid fiber, calcined alumina, silica sol, sodium hypochlorite, starch and sodium carboxymethyl cellulose, and sintering to obtain the modified porous mullite fiber.
4. A firestop bag according to claim 2, wherein: the preparation method of the modified aluminum silicate fiber comprises the following steps: mixing kaolin powder, alumina, titanium pigment, aluminum phosphate binder, silane coupling agent, nano silica aerogel, polyimide resin and dispersing agent in an environment with pH of 4-6, heating and spinning to obtain the modified aluminum silicate fiber.
5. A firestop bag according to claim 1, wherein: the fireproof filler comprises at least one of pitchstone, obsidian, rock wool, dolomite, sepiolite and corundum.
6. A firestop bag according to claim 1, wherein: the expanded material includes at least one of kyanite and expanded perlite.
7. A firestop bag according to claim 1, wherein: the fireproof cloth comprises at least one of acrylic fiber fireproof cloth, zirconia ceramic fireproof cloth and high silica cloth.
8. A firestop bag according to claim 1, wherein: the wetting agent comprises at least one of sodium dodecyl sulfate, water, glycerin and propylene glycol.
9. A method of making a firestop bag as defined in any one of claims 1 to 8, wherein: the method comprises the following steps:
mixing the fireproof filler, the heat-insulating filler, the expansion material, the fireproof cloth and the wetting agent, and mixing to obtain the fire-retarding bag.
10. The utility model provides a fire-retardant package for electric power which characterized in that: a fire-resistant bag comprising a fire-resistant cloth bag and the fire-resistant bag of any one of claims 1 to 8 enclosed in the fire-resistant cloth bag.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202311026746.5A CN117085269A (en) | 2023-08-15 | 2023-08-15 | Fire-retardant bag for electric power and preparation method and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202311026746.5A CN117085269A (en) | 2023-08-15 | 2023-08-15 | Fire-retardant bag for electric power and preparation method and application thereof |
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| CN202311026746.5A Pending CN117085269A (en) | 2023-08-15 | 2023-08-15 | Fire-retardant bag for electric power and preparation method and application thereof |
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| CN (1) | CN117085269A (en) |
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