CN116744792A - 液体农用化学组合物 - Google Patents
液体农用化学组合物 Download PDFInfo
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- CN116744792A CN116744792A CN202180074530.9A CN202180074530A CN116744792A CN 116744792 A CN116744792 A CN 116744792A CN 202180074530 A CN202180074530 A CN 202180074530A CN 116744792 A CN116744792 A CN 116744792A
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Classifications
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
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- A—HUMAN NECESSITIES
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- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
- A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P13/00—Herbicides; Algicides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P3/00—Fungicides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
一种液体农用化学组合物包含:农用化学品,其包括杀真菌剂和/或选自麦草畏、2,4‑滴、草铵膦及其组合的除草剂,并且基于组合物的总重量,其量为约0.05至约60重量%;和表面活性剂,基于组合物的总重量,其以约0.05至约50重量%的量存在,并且由以下组成:(i)至少一种烷氧基化甘油单酯,其以约30至约45重量%的量存在,(ii)至少一种烷氧基化甘油二酯,其以约40至约50重量%的量存在,(iii)至少一种烷氧基化甘油三酯,其以约8至约10重量%的量存在,并且(iv)至少一种烷氧基化甘油,其以约6至约8重量%的量存在,各自基于所述表面活性剂的总重量。
Description
技术领域
总体而言,本公开涉及液体农用化学组合物,并且更具体而言,涉及包含表面活性剂的液体农用化学组合物,所述表面活性剂包括特定量的烷氧基化甘油单酯、烷氧基化甘油二酯、烷氧基化甘油三酯和烷氧基化甘油。
背景技术
众所周知,许多除草剂和杀真菌剂受益于表面活性剂的存在来增强生物功效并提高整体性能。表面活性剂可以作为浓缩杀虫制剂的一部分包含在内,或者可以由最终使用者添加到稀释的喷雾溶液中。
表面活性剂的选择很重要,因为表面活性剂在增强杀虫功效的能力存在很大差异。除草剂或杀真菌剂溶液的功效在很大程度上取决于两个因素:选择合适的表面活性剂和在制剂中提供有效量的该表面活性剂。虽然目前使用的一些现有表面活性剂表现出优异的生物功效增强能力,但它们也可能对眼睛有很大刺激性。具有较低眼睛刺激性能且对水生生物具有较低毒性的替代品将是有利的。
本领域技术人员已知,找到具有良好功效增强性能的合适的表面活性剂可能是困难的。然而,找到在具有良好的功效增强性能之外还具有低眼睛刺激性和水生生物毒性的合适的表面活性剂更加困难。目前使用的已知表面活性剂很少具有良好的眼睛刺激性和水生生物毒性,而且大多数在不同的除草剂和杀真菌剂中都不是特别有效。使用基于天然和可再生材料的表面活性剂将是合乎期望的特征。因此,仍有改进的机会。
发明内容
本公开提供了一种液体农用化学组合物,其包含:
农用化学品,其包括杀真菌剂和/或选自麦草畏、2,4-滴、草铵膦及其组合的除草剂,并且基于组合物的总重量,其以约0.05至约60重量%的量存在;和
表面活性剂,基于组合物的总重量,其以约0.05至约50重量%的量存在,并且由以下组成:
(i)至少一种烷氧基化甘油单酯,基于表面活性剂的总重量,其以约30至约45重量%的量存在,
(ii)至少一种烷氧基化甘油二酯,基于表面活性剂的总重量,其以约40至约50重量%的量存在,
(iii)至少一种烷氧基化甘油三酯,基于表面活性剂的总重量,其以约8至约10重量%的量存在,并且
(iv)至少一种烷氧基化甘油,基于表面活性剂的总重量,其以约6至约8重量%的量存在。
本公开还提供了一种液体农用化学组合物,其主要由以下组成:
农用化学品,其包括杀真菌剂和/或选自麦草畏、2,4-滴、草铵膦及其组合的除草剂,并且基于组合物的总重量,其以约0.05至约60重量%的量存在;和
表面活性剂,基于组合物的总重量,其以约0.05至约50重量%的量存在,并且由以下组成:
(i)至少一种烷氧基化甘油单酯,其以表面活性剂的约30至约45重量%的摩尔量存在,并且具有以下结构
(ii)至少一种烷氧基化甘油二酯,基于表面活性剂中(i)-(iv)的总摩尔数,其以约40至约50重量%的摩尔量存在,并且具有以下结构
(iii)至少一种烷氧基化甘油三酯,基于表面活性剂中(i)-(iv)的总摩尔数,其以约8至约10重量%的摩尔量存在,并且具有以下结构
和
(iv)至少一种烷氧基化甘油,基于表面活性剂中(i)-(iv)的总摩尔数,其以约6至约8重量%的摩尔量存在,并且具有以下结构
其中每个R独立地为C7-C23饱和或不饱和基团;
其中每个R1独立地为H、CH3或CH2CH3;和
其中(x+y+z)的总和为约2至约40。
具体实施方式
下面的详细描述本质上仅是示例性的并不旨在限制本公开的液体农用化学组合物。此外,无意受限于在前述背景技术或以下详细描述中提出的任何理论。
本公开的实施方案总体上涉及液体农用化学组合物及其形成方法。为了简洁起见,可能未在本文中详细描述与形成液体农用化学组合物有关的常规技术。此外,这里描述的各种任务和方法步骤可以结合到具有在此没有详细描述的附加步骤或功能的更全面的过程或方法中。特别地,液体农用化学组合物的制造中的各种步骤是众所周知的,因此,为了简洁起见,许多常规步骤将在本文中仅简要地提及或完全将其省略而不提供众所周知的工艺细节。
本公开提供了一种液体农用化学组合物。术语“液体”描述了在大约25℃的温度下该组合物被本领域技术人员视为液体(而不是固体)。在各种实施方案中,使用任何合适的仪器诸如Brookfield粘度计在25℃下测得组合物的粘度为约1至约70,000cps,其中当使用该方法测定时水的粘度大约是1cps。在各种实施方案中,使用任何合适的仪器诸如Brookfield粘度计在25℃下测得组合物的粘度为约1至约50,000、约1至约25,000、约1至约10,000、约1至约5,000、约1至约1,000、约1至约100、约100至约10,000、约100至约5,000、约100至约2,500、约100至约1,000、约100至约500、约1,000至约25,000、约1,000至约15,000、约1,000至约10,000、约1,000至约5,000、约5,000至约70,000、约5,000至约50,000、约5,000至25,000、约5,000至约10,000、约10,000至约70,000、约10,000至约50,000、约25,000至约70,000、约25,000至约50,000或约50,000至约70,000cps,其中当使用该方法测定时水的粘度大约是1cps。在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
在各种实施方案中,所述组合物包含:
农用化学品,其包括杀真菌剂和/或选自麦草畏、2,4-滴、草铵膦及其组合的除草剂,并且基于组合物的总重量,其以约0.05至约60重量%的量存在;和
表面活性剂,基于组合物的总重量,其以约0.05至约50重量%的量存在,并且由以下组成:
(i)至少一种烷氧基化甘油单酯,基于表面活性剂的总重量,其以约30至约45重量%的量存在,
(ii)至少一种烷氧基化甘油二酯,基于表面活性剂的总重量,其以约40至约50重量%的量存在,
(iii)至少一种烷氧基化甘油三酯,基于表面活性剂的总重量,其以约8至约10重量%的量存在,并且
(iv)至少一种烷氧基化甘油,基于表面活性剂的总重量,其以约6至约8重量%的量存在。
在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
本公开还提供了一种液体农用化学组合物,其主要由以下组成:
农用化学品,其包括杀真菌剂和/或选自麦草畏、2,4-滴、草铵膦及其组合的除草剂,并且基于组合物的总重量,其以约0.05至约60重量%的量存在;和
表面活性剂,基于组合物的总重量,其以约0.05至约50重量%的量存在,并且由以下组成:
(i)至少一种烷氧基化甘油单酯,其以表面活性剂的约30至约45重量%的摩尔量存在,并且具有以下结构
(ii)至少一种烷氧基化甘油二酯,基于表面活性剂中(i)-(iv)的总摩尔数,其以约40至约50重量%的摩尔量存在,并且具有以下结构
(iii)至少一种烷氧基化甘油三酯,基于表面活性剂中(i)-(iv)的总摩尔数,其以约8至约10重量%的摩尔量存在,并且具有以下结构
和
(iv)至少一种烷氧基化甘油,基于表面活性剂中(i)-(iv)的总摩尔数,其以约6至约8重量%的摩尔量存在,并且具有以下结构
其中每个R独立地为C7-C23饱和或不饱和基团;
其中每个R1独立地为H、CH3或CH2CH3;和
其中(x+y+z)的总和为约2至约40。
在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
农用化学品可以是杀真菌剂和/或除草剂、包括杀真菌剂和/或除草剂、主要由杀真菌剂和/或除草剂组成或由杀真菌剂和/或除草剂组成,所述除草剂例如选自麦草畏、2,4-滴、草铵膦及其组合。然而,预期可使用任何除草剂。除上述物质之外,农用化学品还可包含额外的除草剂诸如共除草剂,或者可以不含任何额外的除草剂诸如共除草剂。此外,可以使用共杀真菌剂。在一个实施方案中,一种或多种杀真菌剂和/或共杀真菌剂可以与一种或多种除草剂和/或共除草剂组合。
术语“主要由……组成”描述了不含(或包含少于5、4、3、2、1、0.5或0.1重量%)本文未描述的其他农用化学品的实施方案。这些其他农用化学品可包括但不限于除害剂、上文未描述的除草剂、杀昆虫剂、灭鼠剂等。在一个实施方案中,农用化学品可以是杀真菌剂、包括杀真菌剂、主要由杀真菌剂组成或由杀真菌剂组成。在另一个实施方案中,农用化学品可以是麦草畏、包括麦草畏、主要由麦草畏组成或由麦草畏组成。在另一个实施方案中,农用化学品可以是2,4-滴、包括2,4-滴、主要由2,4-滴组成或由2,4-滴组成。在另一个实施方案中,农用化学品可以是草铵膦、包括草铵膦、主要由草铵膦组成或由草铵膦组成。在另一个实施方案中,农用化学品可以是麦草畏、2,4-滴和草铵膦的组合、包括麦草畏、2,4-滴和草铵膦的组合、主要由麦草畏、2,4-滴和草铵膦的组合组成或由麦草畏、2,4-滴和草铵膦的组合组成(其中所述组合可以包括或可以不包括杀真菌剂)。在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
杀真菌剂没有特别限制并且可以是本领域已知的任何杀真菌剂。在各种实施方案中,所述杀真菌剂选自啶虫脒(acetamiprid)、噻虫胺(clothianidin)、呋虫胺(dinotefuran)、吡虫啉(imidacloprid)、噻虫嗪(thiamethoxam)、烯啶虫胺(nitenpyram)、唑类诸如灭菌唑(triticonazole)、氟喹唑(fluquinconazole)、丙硫菌唑(prothioconazole)、苯醚甲环唑(difenoconazole)、种菌唑(ipconazole)、粉唑醇(flutriafol)和戊唑醇(tebuconazole)、甲基硫菌灵(thiophanate-甲基)、咪鲜胺(prochloraz)、唑菌胺酯(pyraclostrobin)、嘧菌酯(azoxystrobin)、肟菌酯(trifloxystrobin)、肟醚菌胺(orysastrobin)、甲霜灵(metalaxyl)、烯酰吗啉(dimethomorph)、N-(3',4',5'-三氟联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺)、(N-[2-(4'-三氟甲基硫代)-联苯]-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺)、(N-(3',4'-二氯-5-氟联苯-2-基)-3-二氟甲基-1-甲基吡唑-4-甲酰胺(俗名联苯吡菌胺(bixafen))、(N-[2-(1,3-二甲基丁基)-苯基]-1,3-二甲基-5-氟-1H-吡唑-4-甲酰胺)、(N-(2-二环丙基-2-基-苯基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺(俗名:氟唑环菌胺(sedaxane))、(N-[1,2,3,4-四氢-9-(1-甲基乙基)-1,4-甲桥萘-5-基]-3-(二氟甲基)-1-甲基-1H-吡唑-4-甲酰胺(俗名:吡唑萘菌胺(isopyrazam))和N-[2-(1,3-二甲基丁基)-3-噻吩基]-1-甲基-3-(三氟甲基)-1H-吡唑-4-甲酰胺(俗名:吡噻菌胺(penthiopyrad);及其组合。在其他实施方案中,杀真菌剂可以选自三唑类、Strobilurins类、酰基氨基酸类、嘧啶类、吡啶类、芳基苯基酮类、酰胺类、苯甲酰苯胺类、咪唑类、二硝基酚类、吗啉类、苯基磺酰胺类和有机磷杀真菌剂。实例包括苯霜灵(benalaxyl)、精苯霜灵(benlaxyl-M)、糠菌唑(bromuconazole)、布瑞莫(bupirimate)、环氟菌胺(cyflufenamid)、苯醚甲环唑(difenoconazole)、Dinobuton、吗菌灵(dodemorph)、乙酸吗菌灵(dodemorph acetate)、氰菌胺(fenoxanil)、氟硅唑(flusilazole)、氟担菌宁(flutolanil)、抑霉唑(imazalil)、亚胺唑(imibenconazole)、种菌唑(ipconazole)、稻瘟灵(isoprothiolane)、醚菌酯(kresoxim-methyl)、双炔酰菌胺(mandipropamid)、灭锈胺(mepronil)、氰霜唑(metconazole)、苯菌酮(metrafenone)、戊菌唑(penconazole)、啶氧菌酯(picoxystrobin)、咪鲜胺(prochloraz)、唑菌胺酯(pyraclostrobin)、吡菌磷(pyrazophos)、硅噻菌胺(silthiofam)、戊唑醇(tebuconazole)、甲基立枯磷(tolclofos-methyl)、对甲抑菌灵(tolylfluanid)、三唑酮(triadimefon)和肟菌酯(trifloxystrobin)。适合的水溶性杀真菌剂包括苯霜灵(benalaxyl)、精苯霜灵(benlaxyl-M)、乙酸吗菌灵(dodemorph acetate)、氟担菌宁(flutolanil)、种菌唑(ipconazole)、醚菌酯(kresoxim-methyl)、氰霜唑(metconazole)、啶氧菌酯(picoxystrobin)、唑菌胺酯(pyraclostrobin)和戊唑醇(tebuconazole)及其组合。
除上述除草剂外,所述组合物还可包含或不含一种或多种共除草剂,包括但不限于芳氧基苯氧基丙酸酯类(例如炔草酯(clodinafop-propargyl)、禾草灵(diclofop-methyl)、噁唑禾草灵(fenoxaprop-ethyl)、吡氟禾草灵(fluazifop-butyl)、氟吡甲禾灵(haloxyfop-methyl)、喔草酯(propaquizafop)、喹禾灵(quizalofop-ethyl)、环己烷二酮类(例如丁氧环酮(butroxydim)、烯草酮(clethodim)、噻草酮(cycloxydim)、烯禾啶(sethoxydim)、肟草酮(tralkoxydim))、磺酰基脲类(例如酰嘧磺隆(amidosulfuron)、四唑嘧磺隆(azimsulfuron)、苄嘧磺隆(bensulfuron-methyl)、氯嘧磺隆(chlorimuron-ethyl)、氯磺隆(chlorsulfuron)、醚磺隆(cinosulfuron)、环丙磺隆(cyclosulfamuron)、胺苯磺隆(ethametsulfuron-methyl)、乙氧嘧磺隆(ethoxysulfuron)、啶嘧磺隆(flazasulfuron)、氯吡嘧磺隆(halosulfuron)、咪唑磺隆(imazosulfuron)、甲磺隆(metsulfuron)、环氧嘧磺隆(oxasulfuron)、氟嘧磺隆(primisulfuron)、氟磺隆(prosulfuron)、吡嘧磺隆(pyrazosulfuron-ethyl)、砜嘧磺隆(rimsulfuron)、磺酰磺隆(sulfosulfuron)、噻吩磺隆(thifensulfuron)、醚苯磺隆(triasulfuron)、苯磺隆(tribenuron)、氟胺磺隆(triflusulfuron))、咪唑啉类(Imadazolilines)(例如甲氧咪草烟(imazamox))、三唑并嘧啶类(例如唑嘧磺草胺(flumetsulam)和磺草唑胺(metosulam))、三嗪类(例如莠灭净(ametryn)、莠去津(atrazine)、氰草津(cyanazine)、敌草净(desmetryn)、异戊乙净(dimethametryn)、扑灭通(prometon)、扑草净(prometryn)、扑灭津(propazine)、西玛津(simazine)、西草净(simetryne)、特丁通(terbumeton)、特丁津(terbuthylazine)、特丁净(terbutryn)、草达津(trietazine))、三嗪酮类(例如环嗪酮(hexazinone)、苯嗪草酮(metamitron)和赛克津(metribuzin))、尿嘧啶类(例如环草定(lenacil)和特草定(terbacil))、哒嗪酮类(例如氯草敏(chloridazon))、苯基氨基甲酸酯类(例如甜菜胺(desmedipham)和甜菜宁(phenmedipham))、脲类(例如绿麦隆(chlorotoluron)、噁唑隆(dimefuron)、敌草隆(diuron)、非草隆(fenuron)、氟草隆(fluometuron)、异丙隆(isoproturon)、异噁隆(isouron)、利谷隆(linuron)、甲基苯噻隆(methabenzthiazuron)、溴谷隆(metobromuron)、甲氧隆(metoxuron)、绿谷隆(monolinuron)、草不隆(neburon)、环草隆(siduron)和丁噻隆(tebuthiuron))、酰胺类(例如敌稗(propanil)和蔬草灭(pentanochlor))、腈类(例如溴酚肟(bromofenoxim))、联吡啶鎓类(例如敌草快(diquat)和百草枯(paraquat))、二苯基醚类(例如甲羧除草醚(bifenox)、甲氧除草醚(chlomethoxyfen)、乙羧氟草醚乙酯(fluoroglycofen-ethyl)、氟磺胺草醚(fomesafen)、克阔乐(lactofen)和乙氧氟草醚(oxyfluorfen))、(苯基吡唑类(例如吡草醚(pyraflufen-ethyl))、N-苯基邻苯二甲酰胺类(例如氟烯草酸戊酯(flumiclorac-pentyl))、噁二唑类(例如噁草酮(oxadiazon))、三唑啉酮类(例如唑啶草酮(azafenidin)、三唑酮草酯(carfentrazone-ethyl)和甲磺草胺(sulfentrazone))、噁唑啉二酮类(例如环戊噁草酮(pentoxazone))、哒嗪酮类(例如达草灭(norflurazon))、吡啶甲酰胺类(例如氟吡草胺(diflufenican))、三酮类(例如硝磺草酮(mesotrione)和磺草酮(sulcotrione))、异噁唑类(例如异噁唑草酮(isoxaflutole))、吡唑类(例如吡草酮(benzofenap)、吡唑特(pyrazolynate)和苄草唑(pyrazoxyfen))、二硝基苯胺类(例如地乐胺(butralin)、敌乐胺(dinitramine)、丁氟消草(ethalfluralin)和二甲戊灵(pendimethalin))、吡啶类(例如氟硫草定(dithiopyr))、苯甲酸类(例如敌草索(chlorthal-dimethyl))、氨基甲酸酯类(例如氯苯胺灵(chlorpropham)、苯胺灵(propham)和长杀草(carbetamide))、氯代乙酰胺类(例如乙草胺(acetochlor)、甲草胺(alachlor)、丁草胺(butachlor)和二甲草胺(dimethachlor))、腈类(例如敌草腈(dichlobenil)和氯硫酰草胺(chlorthiamid))、苯甲酰胺类(例如异噁酰草胺(isoxaben))、三唑并甲酰胺类(例如氟胺草唑(flupoxam))、喹啉羧酸类(例如快杀稗(quinclorac))、二硝基酚类(例如特乐酚(dinoterb))、硫代氨基甲酸酯(例如苏达灭(butylate)、草灭特(cycloate)、哌草丹(dimepiperate)、EPTC、戊草丹(esprocarb)、禾草特(molinate)、坪草丹(orbencarb)、克草猛(pebulate)、苄草丹(prosulfocarb)、禾草丹(thiobencarb)、仲草丹(tiocarbazil)、野麦畏(triallate)和灭草猛(vernolate))、二硫代磷酸酯类(例如地散磷(bensulide))、苯并呋喃类(例如呋草黄(benfuresate)和乙氧呋草黄(ethofumesate))、氯代碳酸类(例如(TCA))、苯氧基羧酸类(例如稗草胺(clomeprop)、2,4-滴B和(MCPA))、苯甲酸类、喹啉羧酸类(例如二氯喹啉酸(quinclorac))、邻氨基甲酰基苯甲酸半卡巴腙类(phthalamatesemicarbazones)(例如萘草胺(naptalam))和芳基氨基丙酸类(例如麦草伏-甲酯(flamprop-methyl))、三氟羧草醚(acifluorfen)、丙烯醛(acrolein)、杀草强(amitrole)、磺草灵(asulam)、阔草克(benazolin)、苯达松(bentazon)、双丙氨磷(bialaphos)、除草定(bromacil)、溴苯腈(bromoxynil)、草灭平(chloramben)、氯乙酸、毕克草(clopyralid)、(4-(2,4-二氯苯氧基)丁酸(2,4-滴B))、茅草枯(dalapon)、2,4-滴丙酸(dichlorprop)、野燕枯(difenzoquat)、敌草快(diquat)、草藻灭(endothall)、伐草克(fenac)、精噁唑禾草灵(fenoxaprop)、麦草伏(flamprop)、氟烯草酸(flumiclorac)、乙羧氟草醚(fluoroglycofen)、四氟丙酸(flupropanate)、氟磺胺草醚(fomesafen)、杀木膦(fosamine)、甲基咪草烟(imazameth)、咪草酸(imazamethabenz)、甲氧咪草烟(Imazamox)、甲咪唑烟酸(imazapic)、咪唑烟酸(imazapyr)、咪唑喹啉酸(imazaquin)、咪草烟(Imazethapyr)、碘苯腈(ioxynil)、(4-氯-2-甲基苯氧基乙酸(MCPA))、(4-(4-氯-2-甲基苯氧基)丁酸(MCPB))、甲氯丙酸(mecoprop)、甲基胂酸、萘草胺(naptalam)、壬酸、百草枯(paraquat)、毒莠定(picloram)、二氯喹啉酸(quinclorac)、氨基磺酸、(2,3,6-三氯苯甲酸(2,3,6-TBA))、三氯乙酸酯(TCA))、定草酯(triclopyr)及其水溶性盐)、乙草胺(acetochlor)、苯草醚(aclonifen)、甲草胺(alachlor)、莠灭净(ametryn)、酰嘧磺隆(amidosulfuron)、莎稗磷(anilofos)、莠去津(atrazine)、唑啶草酮(azafenidin)、四唑嘧磺隆(azimsulfuron)、乙丁氟灵(benfluralin)、呋草磺(benfuresate)、苄嘧磺隆(bensulfuron-methyl)、地散磷(bensulide)、吡草酮(benzofenap)、甲羧除草醚(bifenox)、溴丁酰草胺(bromobutide)、溴酚肟(bromofenoxim)、丁草胺(butachlor)、抑草磷(butamifos)、地乐胺(butralin)、丁氧环酮(butroxydim)、苏达灭(butylate)、苯酮唑(cafenstrole)、长杀草(carbetamide)、三唑酮草酯(carfentrazone-ethyl)、甲氧除草醚(chlomethoxyfen)、氯溴隆(chlorbromuron)、氯草敏(chloridazon)、氯嘧磺隆(chlorimuron-ethyl)、草枯醚(chlornitrofen)、绿麦隆(chlorotoluron)、氯苯胺灵(chlorpropham)、氯磺隆(chlorsulfuron)、敌草索(chlorthal-dimethyl)、氯硫酰草胺(chlorthiamid)、环庚草醚(cinmethylin)、(cinosulfuron)、醚磺隆(cinosulfuron)、烯草酮(clethodim)、炔草酯(clodinafop-propargyl)、异噁草酮(clomazone)、稗草胺(clomeprop)、氯酯磺草胺(cloransulam-methyl)、氰草津(cyanazine)、草灭特(cycloate)、环丙磺隆(cyclosulfamuron)、噻草酮(cycloxydim)、氰氟草酯(cyhalofop-butyl)、杀草隆(daimuron)、甜菜胺(desmedipham)、敌草净(desmetryn)、敌草腈(dichlobenil)、禾草灵(diclofop-methyl)、氟吡草胺(diflufenican)、噁唑隆(dimefuron)、哌草丹(dimepiperate)、二甲草胺(dimethachlor)、异戊乙净(dimethametryn)、二甲噻草胺(dimethenamid)、敌乐胺(dinitramine)、特乐酚(dinoterb)、草乃敌(diphenamid)、氟硫草定(dithiopyr)、敌草隆(diuron)、N,N-二丙基硫代氨基甲酸乙酯(EPTC)、戊草丹(esprocarb)、丁氟消草(ethalfluralin)、胺苯磺隆(ethametsulfuron-methyl)、乙氧呋草黄(ethofumesate)、乙氧嘧磺隆(ethoxysulfuron)、乙氧苯草胺(etobenzanid)、噁唑禾草灵(fenoxaprop-ethyl)、非草隆(fenuron)、麦草伏-甲酯(flamprop-methyl)、啶嘧磺隆(flazasulfuron)、吡氟禾草灵(fluazifop-butyl)、氟消草(fluchloralin)、唑嘧磺草胺(flumetsulam)、氟烯草酸戊酯(flumiclorac-pentyl)、丙炔氟草胺(flumioxazin)、氟草隆(fluometuron)、氟咯草酮(fluorochloridone)、乙羧氟草醚乙酯(fluoroglycofen-ethyl)、氟胺草唑(flupoxam)、抑草丁(flurenol)、氟啶酮(fluridone)、氟草烟-1-甲庚酯(fluoroxypyr-1-methylheptyl)、呋草酮(flurtamone)、嗪草酸甲酯(fluthiacet-methyl)、氟磺胺草醚(fomesafen)、氯吡嘧磺隆(halosulfuron)、氟吡甲禾灵(haloxyfop-methyl)、环嗪酮(hexazinone)、甲氧咪草烟(imazamox)、咪唑磺隆(imazosulfuron)、茚草酮(indanofan)、异丙隆(isoproturon)、异噁隆(isouron)、异噁酰草胺(isoxaben)、异噁唑草酮(isoxaflutole)、异噁草醚(isoxapyrifop)、克阔乐(lactofen)、环草定(lenacil)、利谷隆(linuron)、苯噻草胺(mefenacet)、硝磺草酮(mesotrione)、苯嗪草酮(metamitron)、吡唑草胺(metazachlor)、甲基苯噻隆(methabenzthiazuron)、甲基杀草隆(methyldymron)、吡喃隆(metobenzuron)、溴谷隆(metobromuron)、异丙甲草胺(metolachlor)、磺草唑胺(metosulam)、甲氧隆(metoxuron)、赛克津(metribuzin)、甲磺隆(metsulfuron)、禾草特(molinate)、绿谷隆(monolinuron)、萘丙胺(naproanilide)、敌草胺(napropamide)、萘草胺(naptalam)、草不隆(neburon)、烟嘧磺隆(nicosulfuron)、达草灭(norflurazon)、坪草丹(orbencarb)、氨磺乐灵(oryzalin)、丙炔噁草酮(oxadiargyl)、噁草酮(oxadiazon)、环氧嘧磺隆(oxasulfuron)、乙氧氟草醚(oxyfluorfen)、克草猛(pebulate)、二甲戊灵(pendimethalin)、蔬草灭(pentanochlor)、环戊噁草酮(pentoxazone)、甜菜宁(phenmedipham)、哌草磷(piperophos)、丙草胺(pretilachlor)、氟嘧磺隆(primisulfuron)、氨氟乐灵(prodiamine)、扑灭通(prometon)、扑草净(prometryn)、毒草安(propachlor)、敌稗(propanil)、喔草酯(propaquizafop)、扑灭津(propazine)、苯胺灵(propham)、毒草胺(propisochlor)、戊炔草胺(propyzamide)、苄草丹(prosulfocarb)、氟磺隆(prosulfuron)、吡草醚(pyraflufen-ethyl)、吡唑特(pyrazolynate)、吡嘧磺隆(pyrazosulfuron-ethyl)、苄草唑(pyrazoxyfen)、稗草畏(pyributicarb)、哒草特(pyridate)、嘧草醚(pyriminobac-methyl)、快杀稗(quinclorac)、氯甲喹啉酸(quinmerac)、喹禾灵(quizalofop-ethyl)、砜嘧磺隆(rimsulfuron)、烯禾啶(sethoxydim)、环草隆(siduron)、西玛津(simazine)、西草净(simetryn)、磺草酮(sulcotrione)、甲磺草胺(sulfentrazone)、嘧黄隆(sulfometuron)、磺酰磺隆(sulfosulfuron)、牧草胺(tebutam)、丁噻隆(tebuthiuron)、特草定(terbacil)、特丁通(terbumeton)、特丁津(terbuthylazine)、特丁净(terbutryn)、噻吩草胺(thenylchlor)、噻草定(thiazopyr)、噻吩磺隆(thifensulfuron)、禾草丹(thiobencarb)、仲草丹(tiocarbazil)、肟草酮(tralkoxydim)、野麦畏(triallate)、醚苯磺隆(triasulfuron)、苯磺隆(tribenuron)、草达津(trietazine)、氟乐灵(trifluralin)、氟胺磺隆(triflusulfuron)和灭草猛(vernolate)、其盐及其组合。
在其他实施方案中,共除草剂可以包括或可以是三氟羧草醚(acifluorfen)、丙烯醛(acrolein)、杀草强(amitrole)、磺草灵(asulam)、阔草克(benazolin)、苯达松(bentazon)、双丙氨磷(bialaphos)、除草定(bromacil)、溴苯腈(bromoxynil)、草灭平(chloramben)、溴苯腈(bromoxynil)、草灭平(chloramben)、氯乙酸、毕克草(clopyralid)、4-(2,4-二氯苯氧基)丙酸(2,4-滴B)、茅草枯(dalapon)、2,4-滴丙酸(dichlorprop)、野燕枯(difenzoquat)、敌草快(diquat)、草藻灭(endothall)、伐草克(fenac)、精噁唑禾草灵(fenoxaprop)、麦草伏(flamprop)、氟烯草酸(flumiclorac)、乙羧氟草醚(fluoroglycofen)、四氟丙酸(flupropanate)、氟磺胺草醚(fomesafen)、杀木膦(fosamine)、甲基咪草烟(imazameth)、咪草酸(imazamethabenz)、甲氧咪草烟(imazamox)、甲咪唑烟酸(imazapic)、咪唑烟酸(imazapyr)、咪唑喹啉酸(imazaquin)、咪草烟(imazethapyr)、碘苯腈(ioxynil)、4-氯-2-甲基苯氧基乙酸(MCPA)、4-(4-氯-2-甲基苯氧基)丁酸(MCPB)、甲氯丙酸(mecoprop)、甲基砷酸、萘草胺(naptalam)、壬酸、百草枯(paraquat)、毒莠定(picloram)、快杀稗(quinclorac)、氨基磺酸、2,3,6-三氯苯甲酸(2,3,6-TBA)、三氯乙酸酯(TCA)、定草酯(triclopyr)、乙草胺(acetochlor)、苯草醚(aclonifen)、甲草胺(alachlor)、莠灭净(ametryn)、莎稗磷(anilofos)、莠去津(atrazine)、唑啶草酮(azafenidin)、乙丁氟灵(benfluralin)、呋草黄(benfuresate)、地散磷(bensulide)、吡草酮(benzofenap)、甲羧除草醚(bifenox)、溴丁酰草胺(bromobutide)、溴酚肟(bromofenoxim)、丁草胺(butachlor)、抑草磷(butamifos)、地乐胺(butralin)、丁氧环酮(butroxydim)、苏达灭(butylate)、苯酮唑(cafenstrole)、长杀草(carbetamide)、三唑酮草酯(carfentrazone-ethyl)、甲氧除草醚(chlomethoxyfen)、氯溴隆(chlorbromuron)、氯草敏(chloridazon)、草枯醚(chlornitrofen)、绿麦隆(chlorotoluron)、氯苯胺灵(chlorpropham)、敌草索(chlorthal-dimethyl)、氯硫酰草胺(chlorthiamid)、环庚草醚(cinmethylin)、烯草酮(clethodim)、烯草酮(clethodim)、炔草酯(clodinafop-propargyl)、异噁草酮(clomazone)、稗草胺(clomeprop)、氯酯磺草胺(cloransulam-methyl)、氰草津(cyanazine)、草灭特(cycloate)、噻草酮(cycloxydim)、氰氟草酯(cyhalofop-butyl)、杀草隆(daimuron)、甜菜胺(desmedipham)、敌草净(desmetryn)、敌草腈(dichlobenil)、禾草灵(diclofop-methyl)、氟吡草胺(diflufenican)、噁唑隆(dimefuron)、哌草丹(dimepiperate)、二甲草胺(dimethachlor)、异戊乙净(dimethametryn)、二甲噻草胺(dimethenamid)、敌乐胺(dinitramine)、特乐酚(dinoterb)、草乃敌(diphenamid)、氟硫草定(dithiopyr)、敌草隆(diuron)、N,N-二丙基硫代氨基甲酸乙酯(EPTC)、戊草丹(esprocarb)、丁氟消草(ethalfluralin)、乙氧呋草黄(ethofumesate)、乙氧苯草胺(etobenzanid)、噁唑禾草灵(fenoxaprop-ethyl)、非草隆(fenuron)、麦草伏-甲酯(flamprop-methyl)、吡氟禾草灵(fluazifop-butyl)、氟消草(fluchloralin)、唑嘧磺草胺(flumetsulam)、氟消草(fluchloralin)、唑嘧磺草胺(flumetsulam)、氟烯草酸戊酯(flumiclorac-pentyl)、丙炔氟草胺(flumioxazin)、氟草隆(fluometuron)、氟咯草酮(fluorochloridone)、乙羧氟草醚乙酯(fluoroglycofen-ethyl)、氟胺草唑(flupoxam)、抑草丁(flurenol)、氟啶酮(fluridone)、氟草烟-1-甲庚酯(fluoroxypyr-1-methylheptyl)、呋草酮(flurtamone)、嗪草酸甲酯(fluthiacet-methyl)、氟磺胺草醚(fomesafen)、氟吡甲禾灵(haloxyfop-methyl)、环嗪酮(hexazinone)、甲氧咪草烟(imazamox)、茚草酮(indanofan)、异丙隆(isoproturon)、异噁隆(isouron)、异噁酰草胺(isoxaben)、异噁唑草酮(isoxaflutole)、异噁草醚(isoxapyrifop)、克阔乐(lactofen)、环草定(lenacil)、利谷隆(linuron)、苯噻草胺(mefenacet)、硝磺草酮(mesotrione)、苯嗪草酮(metamitron)、吡唑草胺(metazachlor)、甲基苯噻隆(methabenzthiazuron)、甲基杀草隆(methyldymron)、吡喃隆(metobenzuron)、溴谷隆(metobromuron)、异丙甲草胺(metolachlor)、磺草唑胺(metosulam)、甲氧隆(metoxuron)、赛克津(metribuzin)、禾草特(molinate)、绿谷隆(monolinuron)、萘丙胺(naproanilide)、敌草胺(napropamide)、萘草胺(naptalam)、草不隆(neburon)、达草灭(norflurazon)、坪草丹(orbencarb)、氨磺乐灵(oryzalin)、丙炔噁草酮(oxadiargyl)、噁草酮(oxadiazon)、乙氧氟草醚(oxyfluorfen)、克草猛(pebulate)、二甲戊灵(pendimethalin)、蔬草灭(pentanochlor)、环戊噁草酮(pentoxazone)、甜菜宁(phenmedipham)、哌草磷(piperophos)、丙草胺(pretilachlor)、氨氟乐灵(prodiamine)、扑灭通(prometon)、扑草净(prometryn)、毒草安(propachlor)、敌稗(propanil)、喔草酯(propaquizafop)、扑灭津(propazine)、苯胺灵(propham)、毒草胺(propisochlor)、戊炔草胺(propyzamide)、苄草丹(prosulfocarb)、吡草醚(pyraflufen-ethyl)、吡唑特(pyrazolynate)、苄草唑(pyrazoxyfen)、稗草畏(pyributicarb)、哒草特(pyridate)、嘧草醚(pyriminobac-methyl)、快杀稗(quinclorac)、氯甲喹啉酸(quinmerac)、喹禾灵(quizalofop-ethyl)、烯禾啶(sethoxydim)、环草隆(siduron)、西玛津(simazine)、西草净(simetryn)、磺草酮(sulcotrione)、甲磺草胺(sulfentrazone)、牧草胺(tebutam)、丁噻隆(tebuthiuron)、特草定(terbacil)、特丁通(terbumeton)、特丁津(terbuthylazine)、特丁净(terbutryn)、噻吩草胺(thenylchlor)、噻草定(thiazopyr)、禾草丹(thiobencarb)、仲草丹(tiocarbazil)、肟草酮(tralkoxydim)、野麦畏(triallate)、草达津(trietazine)、氟乐灵(trifluralin)、氟胺磺隆(triflusulfuron)、灭草猛(vernolate)、其盐及其组合。
在其他实施方案中,共除草剂可以是或包括4-氯苯氧基乙酸(4-CPA)或其盐、3,4-二氯苯氧基乙酸(3,4-DA)或其盐、4-氯-2-甲基苯氧基乙酸(MCPA)或其盐、2,4,5-三氯苯氧基乙酸(2,4,5-T)或其盐、2-(3-氯苯氧基)丙酸(调果酸(cloprop))或其盐、2-(4-氯苯氧基)丙酸(4-CPP)或其盐、2-(2,4-二氯苯氧基)丙酸(2,4-滴丙酸(dichlorprop))或其盐、2-(3,4-二氯苯氧基)丙酸(3,4-DP)或其盐、2-(2,4,5-三氯苯氧基)丙酸(2,4,5-涕丙酸(fenoprop))或其盐、2-(4-氯-2-甲基苯氧基)丙酸(甲氯丙酸(mecoprop))或其盐、4-(4-氯苯氧基)丁酸(4-CPB)或其盐、4-(2,4-二氯苯氧基)丁酸(2,4-滴B)或其盐、4-(3,4-二氯苯氧基)丁酸(3,4-DB)或其盐、4-(4-氯-2-甲基苯氧基)丁酸(MCPB)或其盐、4-(2,4,5-三氯苯氧基)丁酸(2,4,5-TB)或其盐、3-氨基-2,5-二氯苯甲酸(草灭平(chloramben))或其盐、2,3,6-三氯苯甲酸(2,3,6-TBA)或其盐、2,3,5-三氯-6-甲氧基苯甲酸(tricamba)或其盐、4-氨基-3,6-二氯-2-吡啶羧酸(氯氨吡啶酸(aminopyralid))或其盐、3,6-二氯-2-吡啶甲酸(毕克草(clopyralid))或其盐、4-氨基-3,5,6-三氯-2-吡啶甲酸(毒莠定(picloram))或其盐、3,5,6-三氯-2-吡啶基-氧乙酸(定草酯(triclopyr))或其盐及其组合。
基于组合物的总重量,农用化学品以约0.05至约60重量%的量存在。在各种实施方案中,基于组合物的总重量,农用化学品以约0.05至约1、约0.1至约0.95、约0.15至约0.9、约0.2至约0.85、约0.25至约0.8、约0.3至约0.75、约0.35至约0.7、约0.4至约0.65、约0.45至约0.6或约0.5至约0.55重量%的量存在。在其他实施方案中,基于组合物的总重量,农用化学品以约1至约60、约5至约55、约10至约50、约15至约45、约20至约40、约25至约35或约30至约35重量%的量存在。在进一步的实施方案中,组合物可以是罐装组合物,使得基于组合物的总重量,农用化学品以约15至约60、约20至约55、约25至约50、约30至约50、约35至约45、约40至约45、约30至约60、约35至约55、约40至约50或约40至约55重量%的量存在。在其他实施方案中,组合物可以是喷雾组合物,并且基于组合物的总重量,农用化学品可以约0.05至约5、约0.1至约4.9、约0.2至约4.8、约0.3至约4.7、约0.4至约4.6、约0.5至约4.5、约0.6至约4.4、约0.7至约4.3、约0.8至约4.2、约0.9至约4.1、约1至约4、约1.1至约3.9、约1.2至约3.8,约1.3至约3.7、约1.4至约3.6、约1.5至约3.5、约1.6至约3.4、约1.7至约3.3、约1.8至约3.2、约1.9至约3.1、约2至约3、约2.1至约2.9、约2.2至约2.8、约2.3至约2.7、约2.4至约2.6、或约2.5重量%的量存在。在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
现在来看表面活性剂,基于组合物的总重量,所述表面活性剂以约0.05至约50重量%的量存在。在各种实施方案中,基于组合物的总重量,所述表面活性剂以约0.05至约1、约0.1至约0.95、约0.15至约0.9、约0.2至约0.85、约0.25至约0.8、约0.3至约0.75、约0.35至约0.7、约0.4至约0.65、约0.45至约0.6或约0.5至约0.55重量%的量存在。在其他实施方案中,基于组合物的总重量,所述表面活性剂以约1至约50、约5至约45、约10至约40、约15至约35、约20至约30或约25至约30重量%的量存在。在进一步的实施方案中,组合物可以是罐装组合物,使得基于组合物的总重量,所述表面活性剂以约5至约50、约10至约45、约15至约40、约20至约35或约25至约30重量%的量存在。在其他实施方案中,组合物可以是喷雾组合物并且基于组合物的总重量,表面活性剂可以约0.05至约0.5、约0.1至约0.45、约0.15至约0.4、约0.2至约0.35、约0.25至约0.3或约0.3至约0.35重量%的量存在。在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
表面活性剂可以是以下、包括以下、主要由以下组成或由以下组成:
(i)至少一种烷氧基化甘油单酯,基于表面活性剂的总重量,其以约30至约45重量%的量存在,
(ii)至少一种烷氧基化甘油二酯,基于表面活性剂的总重量,其以约40至约50重量%的量存在,
(iii)至少一种烷氧基化甘油三酯,基于表面活性剂的总重量,其以约8至约10重量%的量存在,并且
(iv)至少一种烷氧基化甘油,基于表面活性剂的总重量,其以约6至约8重量%的量存在。
替代地,表面活性剂可以是以下、包括以下、主要由以下组成或由以下组成:
(i)所述至少一种烷氧基化甘油单酯,基于表面活性剂的总重量,其以约35至约37重量%的量存在,
(ii)所述至少一种烷氧基化甘油二酯,基于表面活性剂的总重量,其以约47至约49重量%的量存在,
(iii)所述至少一种烷氧基化甘油三酯,基于表面活性剂的总重量,其以约8.25至约8.75重量%的量存在,并且
(iv)所述至少一种烷氧基化甘油,基于表面活性剂的总重量,其以约7.25至约7.75重量%的量存在。
措词“主要由……组成”可描述不含其他表面活性剂或包含其量小于约5、4、3、2、1、0.5或0.1重量%的其他表面活性剂的实施方案,基于表面活性剂的总重量。这些其他表面活性剂可以是任何类型,例如非离子、阳离子、阴离子和/或两性/两性离子表面活性剂,它们中的每一种都可以是本领域已知的任何类型。这些表面活性剂包括Cutcheon'sEmulsifier and Detergents,北美版,2006中公开的那些。阳离子表面活性剂的非限制性实例是烷氧基化烷基胺及其季型衍生物、烷氧基化醚胺及其季型衍生物、烷氧基化烷基氧化胺、烷氧基化烷基醚氧化胺、烷基酰氨基丙基氧化胺、烷基三甲基氯化铵和烷基(优选C6至C10)二甲基酰氨基丙基胺。阴离子表面活性剂的非限制性实例是烷基硫酸盐、烷基醚硫酸盐、烷基磺酸盐、烷基磺基琥珀酸盐、烷氧基化磷酸酯、烷基α-烯烃磺酸盐、烷基N-甲基牛磺酸盐、脂肪酸羟乙基磺酸盐和烷基醚羧酸盐。非离子表面活性剂的非限制性实例是脱水山梨糖醇酯及其烷氧基化衍生物、山梨糖醇酯及其烷氧基化衍生物、脂肪酸酯、蓖麻油烷氧基化物、醇烷氧基化物、链烷醇酰胺、链烷醇酰胺烷氧基化物和烷基多糖苷。两性表面活性剂的非限制性实例是烷基甜菜碱、烷基酰氨基丙基甜菜碱、烷基两性乙酸盐、烷基两性二乙酸盐、烷基两性羧酸盐、烷基两性丙酸盐、烷基两性二丙酸盐、烷基酰氨基胺羧酸盐、烷基两性羟丙基磺酸盐、烷基磺基甜菜碱、烷基酰氨基丙基羟基磺基甜菜碱、烷基二羟乙基甘氨酸盐和烷基氨基丙酸盐。在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
在各种实施方案中,共表面活性剂可与上述表面活性剂一起使用。例如,共表面活性剂可以是本领域已知的任何表面活性剂,例如非离子、阳离子、阴离子和/或两性/两性离子表面活性剂,或任何上述表面活性剂。共表面活性剂可以任何量使用,至多与例如如上所述表面活性剂本身使用的量大约相同。例如,共表面活性剂可以与表面活性剂的重量比至多为约1:1的量使用。
现在来看所述至少一种烷氧基化甘油单酯,基于表面活性剂的总重量,其以约30至约45重量%的量存在。在各种实施方案中,基于表面活性剂的总重量,所述至少一种烷氧基化甘油单酯以约30.5至约44.5、约31至约44、约31.5至约43.5、约32至约42、约32.5至约41.5、约33至约41、约33.5至约40.5、约34至约40、约34.5至约39.5、约35至约39、约35.5至约38.5、约36至约38、约36.5至约37.5或约37至约37.5重量%的量存在。在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
在各种实施方案中,所述至少一种烷氧基化甘油单酯具有以下结构:
在该结构中,每个R独立地为C7-C23饱和或不饱和基团,每个R1独立地为H、CH3或CH2CH3,并且(x+y+z)的总和为约2至约40。
现在来看所述至少一种烷氧基化甘油二酯,基于表面活性剂的总重量,其以约40至约50重量%的量存在。在各种实施方案中,基于表面活性剂的总重量,所述至少一种烷氧基化甘油二酯以约40.5至约49.5、约41至约49、约41.5至约48.5、约42至约48、约42.5至约47.5、约43至约47、约43.5至约46.5、约44至约46、约44.5至约45.5或约45至约45.5重量%的量存在。在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
在各种实施方案中,所述至少一种烷氧基化甘油二酯具有以下结构:
在该结构中,每个R独立地为C7-C23饱和或不饱和基团,每个R1独立地为H、CH3或CH2CH3,并且(x+y+z)的总和为约2至约40。
现在来看所述至少一种烷氧基化甘油三酯,基于表面活性剂的总重量,其以约8至约10重量%的量存在。在各种实施方案中,基于表面活性剂的总重量,所述至少一种烷氧基化甘油三酯以约8.5至约9.5、约8.5至约9或约9至约9.5重量%的量存在。在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
在各种实施方案中,所述至少一种烷氧基化甘油三酯具有以下结构:
在该结构中,每个R独立地为C7-C23饱和或不饱和基团,每个R1独立地为H、CH3或CH2CH3,并且(x+y+z)的总和为约2至约40。
现在来看所述至少一种烷氧基化甘油,基于表面活性剂的总重量,其以约6至约8重量%的量存在。在各种实施方案中,基于表面活性剂的总重量,所述至少一种烷氧基化甘油以约6.5至约7.5、约6.5至约7、或约7至约7.5重量%的量存在。在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
在各种实施方案中,所述至少一种烷氧基化甘油具有以下结构:
在该结构中,每个R独立地为C7-C23饱和或不饱和基团,每个R1独立地为H、CH3或CH2CH3,并且(x+y+z)的总和为约2至约40。
在上述各结构中,结构内和结构间的任何一个或多个R可以独立地为C7-C23饱和或不饱和基团,即包括7、8、9、10、11、12、13、14、15、16、17、18、19、20、21、22或23个碳原子的基团。在各种实施方案中,所述C7-C23饱和或不饱和基团可具有7至23、8至22、9至21、10至20、11至19、12至18、13至17、14至16、8至18、8至16、8至14、8至12、8至10、10至18、10至16、10至14、10至12、12至18、12至16、12至14、14至18、14至16或16至18个碳原子。此外,饱和基团可以是本领域已知的任何具有上述碳原子数的基团,包括所有可能的异构体。类似地,不饱和基团可以是本领域已知的任何具有上述碳原子数的基团,包括所有可能的异构体。例如,一个或多个R基团可以在相同结构内不同和/或可以在结构之间不同。在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
此外,在结构内和结构间的任何一个或多个R1可以独立地为H、CH3或CH2CH3。例如,一个或多个R1可以在相同结构内不同和/或可以在结构之间不同。
此外,每个结构中(x+y+z)的总和独立地为约2至约40。在各种实施方案中,该总和为约3至约39、约4至约38、约5至约37、约6至约36、约7至约35、约8至约34、约9至约33、约10至约32、约11至约31、约12至约30、约13至约29、约14至约28、约15至约27、约16至约26、约17至约25、约18至约24、约19至约23、约20至约22、约21至约22,或约2、3、4、5、6、7、8、9、10、11、12、13、14、15、16、17、18、19、20、21、22、23、24、25、26、27、28、29、30、31、32、33、34、35、36、37、38、39或40。例如,该总和在结构之间可以相同或不同。在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
农用化学组合物可包含或不含一种或多种以下物质:杀螨剂、杀菌剂、除昆虫剂、除草安全剂、昆虫引诱剂、驱虫剂、植物活化剂、植物生长调节剂、增效剂、染料、稳定剂、香料、降粘添加剂、相容剂、凝固点抑制剂或其组合。
例如,组合物可以包含或不含杀昆虫剂,诸如由有机磷类定义的那些、昆虫生长调节剂(诸如几丁质合成抑制剂、保幼激素模拟物和蜕皮激素、抑制剂和模拟物)、拟除虫菊酯类、邻苯二甲酰亚胺类、吡唑类、有机氯类、氨基甲酸酯类和烟碱类、乙基谷硫磷(azinphos-ethyl)、β-氯氰菊酯、香豆磷(coumaphos)、苯氧威(fenoxycarb)、哒嗪硫磷(pyridaphenthion)、嘧啶(嘧螨醚)和胺菊酯(tetramethrin)及其组合。
一种或多种添加剂:
组合物可以包含或不含一种或多种添加剂。例如,添加剂可以是硫酸铵、硫酸钾、氯化钾、硫酸钠、尿素、甘油、二醇、聚乙二醇或其混合物。在其他实施方案中,添加剂可被描述为共佐剂、速燃添加剂、湿润剂、共除草剂、其他除害剂、杀真菌剂、除昆虫剂、植物健康剂、其他胺化合物(例如二甲胺、异丙胺、三乙胺、二乙醇胺)、染料、颜料、腐蚀抑制剂、增稠剂、分散剂、钙螯合剂、泡沫调节剂或消泡剂、防冻剂、增溶组分、倾点抑制剂、抗胶凝剂、pH调节剂、防腐剂、水溶助长剂、溶剂、加工助剂或其混合物。在进一步的实施方案中,添加剂可以是消泡剂诸如基于有机硅的组合物。用于该组合物的泡沫调节剂的实例是可从GESilicones Corporation(Wilton,CT)获得的SAG-10。
在进一步的实施方案中,添加剂可以是一种或多种防腐剂诸如杀生物剂,如防霉剂和抑菌剂、对羟基苯甲酸甲酯、对羟基苯甲酸乙酯和对羟基苯甲酸丙酯;短链有机酸(例如乙酸、乳酸和/或乙醇酸);双胍化合物(例如Dantagard和/或Glydant);短链醇(例如乙醇和/或IPA);5-氯-2-甲基-4-异噻唑啉-3-酮(KATHON GC)、2-甲基-4-异噻唑啉-3-酮(KATHON ICP)、5-氯-2-甲基-4-异噻唑啉-3-酮(KATHON 886),都可从Rohm and HaasCompany获得;2-溴-2-硝基丙-1,3-二醇(BRONOPOL),来自Boots Company Ltd.;对羟基苯甲酸丙酯(PROXEL CRL),来自ICI PLC;1,2-苯并异噻唑-3(2H)-酮杀生物剂(PROXEL GXL),来自Zeneca Specialties Co.;邻苯基苯酚Na+盐(NIPASOL M),来自Nipa LaboratoriesLtd.;1,2-苯并异噻唑啉酮-3-酮(DOWICIDE A)和1-(3-氯烯丙基)-3,5,7-三氮杂-1-氮鎓金刚烷氯化物(DOWICIL 75),以及来自Dow Chemical Co.的含有顺式-1-(3-氯烯丙基)-3,5,7-三氮杂-1-氮鎓金刚烷氯化物的DOWICIL 150(CAS号051229-78-8);来自Akzo Nobel的在2-丙醇中的季型烷基氯化铵(ARQUAD 2.8-50);来自Ciba-Geigy A.G的2,4,4'-三氯-2-羟基二苯醚(IRGASAN DP 200);得自Clariant Corporation(Greensboro,N.C.)等等含有苯并异噻唑啉酮的NIPACIDE BIT20DPG、得自Rohm and HaasCo.的LEGEND MK抗微生物杀生物剂(Philadelphia,Pa.)、山梨酸及其混合物等。
在额外的实施方案中,添加剂可以是合适的防冻剂诸如乙二醇和丙二醇。防冻剂有助于降低水溶液的凝固点并保持组合物组分的溶解度,使得组分在冷冻和解冻循环期间不会结晶或沉淀。
添加剂也可以是增溶剂(通常也称为浊点增强剂或稳定剂),可以显著改善制剂的性能。增溶剂包括乙二醇和丙二醇的聚合物衍生物(例如,平均分子量为200-1200)、甘油、糖、其混合物等。在其他实施方案中,添加剂可以是合适的染料诸如食品级染料、颜料染料和焦糖色。
农用化学组合物的制备方法
农用化学组合物可以通过本领域已知的任何方法形成,包括以任何顺序和以间歇或连续工艺将各组分混合在一起。例如,所述方法可包括提供农用化学品、提供表面活性剂和提供任何任选的成分并将这些组分混合在一起的步骤。
可以使用本领域已知的任何方法或添加顺序来形成所述组合物。在各种实施方案中,可以使用机械搅拌器、球磨机或任何其他合适的产生必要量的搅拌或循环以彻底混合各成分的容器或装置来组合各组分。可以通过稀释或混合来制备即用型的本公开的组合物(即,RTU组合物)。
制备表面活性剂的方法:
表面活性剂可以通过本领域已知的任何方法制备。例如,在各种实施方案中,表面活性剂可通过各种甘油解(glycerolysis)法制备,例如如综述文章(Norman Sonntag,JAOCS,第59卷,第10期,1982年10月,795A-802A页)中所述。在其他实施方案中,表面活性剂通过酯交换法获得,该方法使甘油与甘油三酯或脂肪酸反应,接着进行烷氧基化。表面活性剂也可以通过首先将甘油烷氧基化然后接着用脂肪酸或脂肪酸酯酯化来获得。
Sonntag描述了多种甘油解工艺,包括间歇型工艺。这些方法被描述为通常包括(a)使用加热和搅拌使甘油在脂肪相中的溶解度最大化,(b)使用与2摩尔的理论需要量相比过量的甘油,并在甘油解结束时去除过量甘油,(c)使用催化剂/乳化剂系统,和(d)在反应完成后且去除过量甘油并冷却前中和催化剂。
描述为影响甘油解的实际成功的一个考虑因素是建立足够程度的均匀性(即甘油在初始的甘油三酯脂肪或在随后的脂肪样相中的溶解度)。在室温下甘油在普通脂肪中不能溶解到允许摩尔过量的甘油完全反应的程度。因此,升高的温度(例如,超过约200℃、超过约220℃或约240℃的温度)通常用于增加甘油的溶解度并驱动反应完成。温度上限可能取决于多种因素。例如,在超过255℃或超过260℃的温度下可能会形成不期望的副产物(例如,丙烯醛)。也可利用搅拌来提高甘油的溶解度。搅拌的方式和程度都没有严格的限制,并且可以由本领域技术人员考虑特定的反应条件来选择。
甘油解反应通常是被催化的,通常使用碱性催化剂(例如,NaOH、KOH、Ca(OH)2、CaO、SrO)、低级脂肪醇(例如,甲醇和乙醇)的钠盐以及酸。各种金属诸如Na、K或Sn也可用作催化剂。通常,优选碱性催化剂。更具体地,由于它们的有效性和低成本,NaOH和KOH通常优选作为工业甘油解的催化剂。因为催化剂提高了反应速率,所以催化剂的存在可以增加所需的单酸甘油酯逆转回反应物形式。这种逆转可以通过催化剂的相对快速中和、反应混合物的冷却和/或在所需反应期结束时除去甘油来最小化。
Sonntag还描述和/或列出了本领域已知的多种间歇和连续甘油解法,包括例如美国专利第4,025,540、4,950,441和6,723,863号;在各种非限制性实施方案中出于所有相关目的,其全部内容通过引用并入本文。间歇型甘油解方法包括在美国专利第1,505,560、2,197,339、2,197,340、2,206,167、2,206,168、2,748,354、2,496,328、2,909,540和3,083,216号中描述的那些,在各种非限制性实施方案中出于所有相关目的,其全部内容通过引用并入本文。连续型甘油解方法包括在美国专利第2,383,581、2,474,740、2,634,278、2,634,279、2,875,221、3,102,129、3,095,431、3,079,412、3,313,834和4,950,441号中描述的那些,在各种非限制性实施方案中出于所有相关目的,其全部内容通过具体引用并入本文。
可选择甘油和脂肪酸的相对比例以提供甘油酯的混合物。不管烷氧基化和酯化的顺序如何,制备本公开化合物的烷氧基化通常可以根据本领域已知的常规方法进行。烷氧基化通常包括在催化剂存在下环氧烷与含有至少一个活性氢的有机化合物(即甘油或其酯)的缩合反应。众所周知,各种催化剂用于烷氧基化工艺,例如包括各种酸性和碱性催化剂(例如氢氧化钾)。各种烷氧基化方法是本领域熟知的,例如包括在美国专利第4,754,075、5,114,900和5,120,697号中描述的那些。合适的烷氧基化方法的条件是本领域众所周知的。例如,反应温度通常足以提供合适的反应速率,但并没有反应物或反应产物的不期望的降解。通常,烷氧基化温度可以在约50℃至约270℃,或约100℃至约200℃的范围内。烷氧基化反应的压力不是严格关键的。通常,搅拌烷氧基化介质以促进反应物和催化剂彻底分散。在各种非限制性实施方案中,所有上述参考文献均通过具体引用并入本文。在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
本公开还提供了一种通过喷雾或以其他方式将有效量的所述组合物施用于待处理的目标来杀死或防治杂草或其他不需要的植物或真菌的方法。可以通过本领域技术人员熟知的任何合适的方法将组合物施用于待处理植物的叶子。在一些实施方案中,将RTU组合物包装在便携式容器中,所述容器适合由使用者手提并且配备有用于将组合物以喷雾的形式从容器手动释放到待处理植物的叶子上的装置。
本公开的组合物可用于杀死或防治多种植物、真菌等的生长。在各种实施方案中,植物包括苘麻(Abutilon theophrasti)、苋属(Amaranthus spp.)、丰花草属(Borreriaspp.)、欧洲油菜、加拿大油菜、印度芥菜等(芸苔属(Brassica spp.))、鸭跖草属(Commelina spp.)、牻牛儿苗属(Erodium spp.)、向日葵属(Helianthus spp.)、牵牛花属(Ipomoea spp.)、地肤(Kochia scoparia)、锦葵属(Malva spp.)、野荞麦、蓼属(Polygonumspp.)、马齿苋(马齿苋属(Portulaca spp.)、猪毛菜属(Salsola spp.)、水飞蓟属(Sidaspp.)、野芥(Sinapis arvensis)和苍耳属(Xanthium spp.)。在其他实施方案中,植物包括野燕麦(Avena fatua)、地毯草(地毯草属(Axonopus spp.))、旱雀麦(Bromus tectorum)、马唐属(Digitaria spp.)、稗草(Echinochloa crus-galli)、牛筋草(Eleusine indica)、多花黑麦草(Lolium multiflorum)、水稻(Oryza sativa)、露籽草(Ottochloa nodosa)、百喜草(Paspalum notatum)、虉草属(Phalaris spp.)、狗尾草属(Setaria spp.)、小麦(Triticum aestivum)和玉米(Zea mays)。在其他实施方案中,植物包括蒿属(Artemisiaspp.)、马利筋属(Asclepias spp.)、加拿大蓟(Cirsium arvense)、田旋花(Convolvulusarvensis)和葛藤属(Pueraria spp.)。在进一步的实施方案中,植物包括臂形草属(Brachiaria spp.)、狗牙根草(Cynodon dactylon)、偃麦草(Elymus repens)、白茅(Imperata cylindrica)、多年生黑麦草(Lolium perenne)、大黍(Panicum maximum)、毛花雀稗(Paspalum dilatatum)、芦苇属(Phragmites spp.)、石茅(Sorghum halepense)和蒲菜属(Typha spp.)。在进一步的实施方案中,植物包括木贼属(Equisetum spp.)、蕨(Pteridium aquilinum)、黑莓属(Rubus spp.)和荆豆(Ulex europaeus)。
可以采用各种施用方法,包括用本公开的稀释组合物喷撒、定向喷射或擦拭叶子。取决于所需的防治程度、植物的年龄和种类、天气条件和其他因素,典型的有效施用量为约0.1至约10kg a.e./ha、优选约0.25至约2.5kg a.e./ha,尽管可以施用更多或更少的量。在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
其他实施方案:
在一个实施方案中,所述组合物为一种罐装组合物,其中
所述农用化学品为除草剂;
基于组合物的总重量,所述除草剂以约15至约60重量%的量存在;和
基于组合物的总重量,所述表面活性剂以约5至约50重量%的量存在。
在另一个实施方案中,所述组合物为喷雾组合物,其中
所述农用化学品为除草剂;
基于组合物的总重量,所述除草剂以约0.05至约5重量%的量存在;和
基于组合物的总重量,所述表面活性剂以约0.05至约0.5重量%的量存在。
在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
在另一个实施方案中,所述组合物为罐装组合物,其中
所述农用化学品为杀真菌剂;
基于组合物的总重量,所述除草剂以约15至约60重量%的量存在;和
基于组合物的总重量,所述表面活性剂以约5至约50重量%的量存在。
在另一个实施方案中,所述组合物为喷雾组合物,其中
所述农用化学品为杀真菌剂;
基于组合物的总重量,所述除草剂以约0.05至约5重量%的量存在;和
基于组合物的总重量,所述表面活性剂以约0.05至约0.5重量%的量存在。
在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
在另一个实施方案中,每个R1是H或CH3。
在另一个实施方案中:
(i)基于表面活性剂的总重量,所述至少一种烷氧基化甘油单酯以约35至约43重量%的量存在,
(ii)基于表面活性剂的总重量,所述至少一种烷氧基化甘油二酯以约41至约48重量%的量存在,
(iii)基于表面活性剂的总重量,所述至少一种烷氧基化甘油三酯以约8.5至约9重量%的量存在,并且
(iv)基于表面活性剂的总重量,所述至少一种烷氧基化甘油以约7至约7.5重量%的量存在。
在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
在另一个实施方案中,甘油单酯与甘油二酯的摩尔比为约1.2:1至约1.8:1。在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
在另一个实施方案中,甘油单酯与甘油二酯的重量比为约0.74至约1.04。在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
在另一个实施方案中,所述组合物为喷雾组合物,其中
所述农用化学品为草铵膦,基于组合物的总重量,其以约0.05至约5重量%的量存在;
基于组合物的总重量,所述表面活性剂以约0.05至约0.5重量%的量存在,其中每个R1是H或CH3,并且
(i)基于表面活性剂的总重量,所述至少一种烷氧基化甘油单酯以约35至约43重量%的量存在,
(ii)基于表面活性剂的总重量,所述至少一种烷氧基化甘油二酯以约41至约48重量%的量存在,
(iii)基于表面活性剂的总重量,所述至少一种烷氧基化甘油三酯以约8.5至约9重量%的量存在,并且
(iv)基于表面活性剂的总重量,所述至少一种烷氧基化甘油以约7至约7.5重量%的量存在。
在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
在另一个实施方案中,所述组合物为罐装组合物,其中
所述农用化学品为草铵膦,基于组合物的总重量,其以约15至约60重量%的量存在;
基于组合物的总重量,所述表面活性剂以约5至约50重量%的量存在,其中每个R1是H或CH3,并且
(i)基于表面活性剂的总重量,所述至少一种烷氧基化甘油单酯以约35至约43重量%的量存在,
(ii)基于表面活性剂的总重量,所述至少一种烷氧基化甘油二酯以约41至约48重量%的量存在,
(iii)基于表面活性剂的总重量,所述至少一种烷氧基化甘油三酯以约8.5至约9重量%的量存在,并且
(iv)基于表面活性剂的总重量,所述至少一种烷氧基化甘油以约7至约7.5重量%的量存在。
在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
在另一个实施方案中,所述组合物为喷雾组合物,其中
所述农用化学品为麦草畏,基于组合物的总重量,其以约0.05至约5重量%的量存在;
基于组合物的总重量,所述表面活性剂以约0.05至约0.5重量%的量存在,其中每个R1是H或CH3,并且
(i)基于表面活性剂的总重量,所述至少一种烷氧基化甘油单酯以约35至约43重量%的量存在,
(ii)基于表面活性剂的总重量,所述至少一种烷氧基化甘油二酯以约41至约48重量%的量存在,
(iii)基于表面活性剂的总重量,所述至少一种烷氧基化甘油三酯以约8.5至约9重量%的量存在,并且
(iv)基于表面活性剂的总重量,所述至少一种烷氧基化甘油以约7至约7.5重量%的量存在。
在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
在另一个实施方案中,所述组合物为罐装组合物,其中
所述农用化学品为麦草畏,基于组合物的总重量,其以约15至约60重量%的量存在;
基于组合物的总重量,所述表面活性剂以约5至约50重量%的量存在,其中每个R1是H或CH3,并且
(i)基于表面活性剂的总重量,所述至少一种烷氧基化甘油单酯以约35至约43重量%的量存在,
(ii)基于表面活性剂的总重量,所述至少一种烷氧基化甘油二酯以约41至约48重量%的量存在,
(iii)基于表面活性剂的总重量,所述至少一种烷氧基化甘油三酯以约8.5至约9重量%的量存在,并且
(iv)基于表面活性剂的总重量,所述至少一种烷氧基化甘油以约7至约7.5重量%的量存在。
在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
在另一个实施方案中,所述组合物为喷雾组合物,其中
所述农用化学品为2,4-滴,基于组合物的总重量,其以约0.05至约5重量%的量存在;
基于组合物的总重量,所述表面活性剂以约0.05至约0.5重量%的量存在,其中每个R1是H或CH3,并且
(i)基于表面活性剂的总重量,所述至少一种烷氧基化甘油单酯以约35至约43重量%的量存在,
(ii)基于表面活性剂的总重量,所述至少一种烷氧基化甘油二酯以约41至约48重量%的量存在,
(iii)基于表面活性剂的总重量,所述至少一种烷氧基化甘油三酯以约8.5至约9重量%的量存在,并且
(iv)基于表面活性剂的总重量,所述至少一种烷氧基化甘油以约7至约7.5重量%的量存在。
在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
在另一个实施方案中,所述组合物为罐装组合物,其中
所述农用化学品为2,4-滴,基于组合物的总重量,其以约15至约60重量%的量存在;
基于组合物的总重量,所述表面活性剂以约5至约50重量%的量存在,其中每个R1是H或CH3,并且
(i)基于表面活性剂的总重量,所述至少一种烷氧基化甘油单酯以约35至约43重量%的量存在,
(ii)基于表面活性剂的总重量,所述至少一种烷氧基化甘油二酯以约41至约48重量%的量存在,
(iii)基于表面活性剂的总重量,所述至少一种烷氧基化甘油三酯以约8.5至约9重量%的量存在,并且
(iv)基于表面活性剂的总重量,所述至少一种烷氧基化甘油以约7至约7.5重量%的量存在。
在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
在其他实施方案中,(i)所述至少一种烷氧基化甘油单酯、(ii)所述至少一种烷氧基化甘油二酯、(iii)所述至少一种烷氧基化甘油三酯和(iv)所述至少一种烷氧基化甘油的重量和摩尔百分比如下所述:
*可以为两种异构体的总和
在各种非限制性实施方案中,所有数值(包括整数和小数)和数值范围,包括上述数值和介于上述数值之间的数值,均在此明确考虑使用。
实施例
大豆脂肪酸甘油酯的制备
使用标准方法如Sonntag先前概述的程序进行大豆脂肪酸与甘油的酯化。酯混合物SMG的分析通过NMR完成并示于在下表中。
大豆甘油单酯(SMG)的NMR分析
摩尔% | 重量% | |
零酯(甘油) | ||
(0,0,0) | 24.4 | 7.5 |
单酯 | ||
(1,0,0) | 33.6 | 30.8 |
(0,1,0) | 5.3 | 4.9 |
二酯(甘油二酯) | ||
(1,1,0) | 11.2 | 17.0 |
(1,0,1) | 20.6 | 31.3 |
三酯(甘油三酯) | ||
(1,1,1) | 5.0 | 8.5 |
游离酸 | n.d. | n.d. |
大豆甘油酯的典型乙氧基化:
向2升高压釜中添加300.6g SMG和6g KOH(45%)。在400cc/min的氮气吹扫下将系统加热到110℃。干燥2小时后,KF的水分为0.04重量%。来自反应器的总样品总计11.5g,剩下289.1克即0.75摩尔的大豆-MG。然后将反应器加热至135℃并在3小时内添加EO(660g,15.5mol),接着消化1小时。然后将反应冷却至80℃并用氮气吹扫,排气管线通向洗涤器以除去任何未反应的EO。分配了664.8克SMG+20EO,达到了99.4%的质量平衡。
按照相同的基本程序,由5-50mol的EO实现了其他乙氧基化度。
其他实施例:
温室测试1:
在第一系列实施例中,使用以下化合物来评估各种除草剂与各种表面活性剂的组合对两种类型杂草的功效:
除草剂:2,4-滴酯;麦草畏;和草铵膦
表面活性剂:
单大豆甘油酯+10EO;
单大豆甘油酯+15EO;
单大豆甘油酯+20EO;
单大豆甘油酯+30EO;
单大豆甘油酯+50EO;
大豆油+20EO;
参考物1-聚氧乙烯(20)失水山梨糖醇单月桂酸酯
参考物2-十二烷基醚硫酸钠
使用以下测试方案:
2x 2测试网格(test grid)(采用2个活性物等级和2个表面活性剂等级=对每个活性物/表面活性剂组合进行4次测试)
活性物等级:如下表所示
表面活性剂等级:
2,4-滴酯:0.1%和0.25%
麦草畏:0.1%和0.25%
草铵膦:0.25%和0.5%
处理总数#:96(8种表面活性剂x每个进行4次测试,每个处理重复4次)
杂草:
苜蓿:用于2,4-滴和麦草畏
牵牛花:用于草铵膦
在每周结束时收集数据,持续4周。结果以杂草防治百分比来表示,其中标准偏差基于4次重复数据点。杂草防治百分比基于对植物破坏(生长缓慢、生长较少等)的视觉评估。经处理的杂草植物在施用除草剂+表面活性剂后不会死亡。它们只是被破坏了。它们仍然可以随时间而生长。这就是为什么在一些数据集中,随着植物重新生长,杂草防治百分比会随时间而降低。
结果列于下表1A-1D、2A-2D和3A-3D中。
表1A-1D包括与2,4-滴相关的数据。
表2A-2D包括与麦草畏相关的数据。
表3A-3D包括与草铵膦相关的数据。
与2,4-滴相关的数据和表1A-1D:
相对于2,4-滴,单大豆甘油酯20EO和30EO等同于或优于参考物。
表1A
表1B
表1C
表1D
与麦草畏相关的数据和表2A-2D:
相对于麦草畏,单大豆甘油酯15、20、30和50EO表现出与月桂基醚硫酸钠相似的性能,并且在低活化物等级下表现出比聚氧乙烯(20)失水山梨糖醇单月桂酸酯更好的性能。在高活化物等级下,所有表面活性剂都表现出相似的性能。
表2A
表2B
表2C
表2D
与草铵膦相关的数据和表3A-3D:
相对于草铵膦,在低活性物等级下,GMS 15和20EO表现出比醚硫酸盐更好的性能。在高活性物等级下,GMS 15、20EO和30EO表现出与十二烷基醚硫酸钠相似的性能。
表3A
表3B
表3C
表3D
温室试验2:
在第二系列实施例中,使用以下化合物来评估各种杀真菌剂与各种表面活性剂的组合抗真菌的功效:
杀真菌剂:
己唑醇5% EC;烯酰吗啉50WP;甲基硫菌灵(Thiophenate methyl)70%WP;嘧菌酯23SC
表面活性剂:
磺基琥珀酸二辛酯
具有20EO的烷氧基化甘油酯;
具有50EO的烷氧基化甘油酯;
硅氧烷聚氧化烯共聚物
真菌:
白粉病(Erysiphenecator);
霜霉病(Plasmoparaviticola);
炭疽病(Colletotrichumgloeosporioides);和
早疫病(Alternariasolani)。
使用以下测试方案:
针对4种不同的有害物(真菌)对4种不同的杀真菌剂制剂进行了测试。对于每个试验,都有未处理的对照物(#1)以及只有杀真菌剂而没有表面活性剂的制剂(#2)。使用与上述相同的通用方案。
结果如下所示并且表明在所有情况下磺基琥珀酸二辛酯都表现出总体上良好的防治。仅在表C中,与具有20EO的烷氧基化甘油酯相比,表现出功效缺乏。
烷氧基化甘油酯#1是具有20EO的产品。
烷氧基化甘油酯#2是具有50EO的产品。
表A.不同表面活性剂与标准杀真菌剂己唑醇5% EC对葡萄叶上的白粉病的生物功效
*PDI:疾病百分比指数
表B.不同表面活性剂与标准杀真菌剂烯酰吗啉50WP对葡萄叶霜霉病的生物功效
*PDI:疾病百分比指数
表C.不同表面活性剂与标准杀真菌剂甲基硫菌灵70%WP对葡萄叶炭疽病的生物功效
*PDI:疾病百分比指数
表D.不同表面活性剂与标准杀真菌剂嘧菌酯23SC对番茄上早疫病防治的生物功效
*PDI:疾病百分比指数
白粉病、霜霉病、炭疽病和早疫病的疾病百分比指数(PDI)通过下式计算:
在葡萄的情况下,记录在随机选择的茎上对最少十片叶子和一个分支的评级。每株植物观察十根这样的茎。记录了分布在四次重复实验中的8株植物的观察结果。因此,PDI所呈现的数据是随机选择的80根茎的平均值。
在西红柿的情况下,在每次喷洒开始时和第二次喷洒后15天,从每次重复实验中取非边缘行的10株植物并进行评分。
这里给出的与杀真菌剂和烷氧基化甘油酯#1和#2一起使用的数据表现出出人意料地优于对照物和硅氧烷聚氧化烯共聚物的优异结果。
表明烷氧基化甘油酯#1在4种杀真菌剂制剂的1种中是最好的化合物,在其他3种中次于最好,因此在所有情况下都优于硅氧烷聚氧化烯共聚物。在所有情况下,烷氧基化甘油酯#2的性能也优于硅氧烷聚氧化烯共聚物。
虽然在前面的详细描述中已经给出了至少一个示例性实施方案,但是应当理解存在大量的变型。还应当理解,所述至少一个示例性实施方案或多个示例性实施方案仅是实例,并不旨在以任何方式限制范围、适用性或配置。相反,前述详细描述将为本领域技术人员提供用于实施示例性实施方案的方便路线图。应当理解,在不脱离所附权利要求所规定的范围的情况下,可以对示例性实施方案中描述的要素的功能和布置进行各种改变。
Claims (20)
1.一种液体农用化学组合物,其包含:
农用化学品,其包括杀真菌剂和/或选自麦草畏、2,4-滴、草铵膦及其组合的除草剂,并且基于所述组合物的总重量,其以约0.05至约60重量%的量存在;和
表面活性剂,基于所述组合物的总重量,其以约0.05至约50重量%的量存在,并且由以下组成:
(i)至少一种烷氧基化甘油单酯,基于所述表面活性剂的总重量,其以约30至约45重量%的量存在,
(ii)至少一种烷氧基化甘油二酯,基于所述表面活性剂的总重量,其以约40至约50重量%的量存在,
(iii)至少一种烷氧基化甘油三酯,基于所述表面活性剂的总重量,其以约8至约10重量%的量存在,并且
(iv)至少一种烷氧基化甘油,基于所述表面活性剂的总重量,其以约6至约8重量%的量存在。
2.根据权利要求1所述的组合物,其中:
(i)所述至少一种烷氧基化甘油单酯具有以下结构:
(ii)所述至少一种烷氧基化甘油二酯具有以下结构:
(iii)所述至少一种烷氧基化甘油三酯具有以下结构:
和
(iv)所述至少一种烷氧基化甘油具有以下结构:
其中每个R独立地为C7-C23饱和或不饱和基团;
其中每个R1独立地为H、CH3或CH2CH3;
其中(x+y+z)的总和为约2至约40。
3.根据权利要求1或2所述的组合物,其为罐装组合物,其中
所述农用化学品为除草剂;
基于所述组合物的总重量,所述除草剂以约15至约60重量%的量存在;和
基于所述组合物的总重量,所述表面活性剂以约5至约50重量%的量存在。
4.根据权利要求1或2所述的组合物,其为喷雾组合物,其中
所述农用化学品为除草剂;
基于所述组合物的总重量,所述除草剂以约0.05至约5重量%的量存在;和
基于所述组合物的总重量,所述表面活性剂以约0.05至约0.5重量%的量存在。
5.根据权利要求1或2所述的组合物,其为罐装组合物,其中
所述农用化学品为杀真菌剂;
基于所述组合物的总重量,所述除草剂以约15至约60重量%的量存在;和
基于所述组合物的总重量,所述表面活性剂以约5至约50重量%的量存在。
6.根据权利要求1或2所述的组合物,其为喷雾组合物,其中
所述农用化学品为杀真菌剂;
基于所述组合物的总重量,所述除草剂以约0.05至约5重量%的量存在;和
基于所述组合物的总重量,所述表面活性剂以约0.05至约0.5重量%的量存在。
7.根据前述权利要求中任一项所述的组合物,其中每个R1是H或CH3。
8.根据前述权利要求中任一项所述的组合物,其中:
(i)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油单酯以约35至约37重量%的量存在,
(ii)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油二酯以约47至约49重量%的量存在,
(iii)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油三酯以约8.25至约8.75重量%的量存在,并且
(iv)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油以约7.25至约7.75重量%的量存在。
9.根据前述权利要求中任一项所述的组合物,其中甘油单酯与甘油二酯的摩尔比为约1.2:1至约1.8:1。
10.根据前述权利要求中任一项所述的组合物,其中甘油单酯与甘油二酯的重量比为约0.74至约1.04。
11.根据权利要求1所述的组合物,其为喷雾组合物,其中
所述农用化学品为草铵膦,基于所述组合物的总重量,其以约0.05至约5重量%的量存在;
基于所述组合物的总重量,所述表面活性剂以约0.05至约0.5重量%的量存在,其中每个R1是H或CH3,并且
(i)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油单酯以约35至约37重量%的量存在,
(ii)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油二酯以约47至约49重量%的量存在,
(iii)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油三酯以约8.25至约8.75重量%的量存在,并且
(iv)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油以约7.25至约7.75重量%的量存在。
12.根据权利要求1所述的组合物,其为罐装组合物,其中
所述农用化学品为草铵膦,基于所述组合物的总重量,其以约15至约60重量%的量存在;
基于所述组合物的总重量,所述表面活性剂以约5至约50重量%的量存在,其中每个R1是H或CH3,并且
(i)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油单酯以约35至约37重量%的量存在,
(ii)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油二酯以约47至约49重量%的量存在,
(iii)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油三酯以约8.25至约8.75重量%的量存在,并且
(iv)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油以约7.25至约7.75重量%的量存在。
13.根据权利要求1所述的组合物,其为喷雾组合物,其中
所述农用化学品为麦草畏,基于所述组合物的总重量,其以约0.05至约5重量%的量存在;
基于所述组合物的总重量,所述表面活性剂以约0.05至约0.5重量%的量存在,其中每个R1是H或CH3,并且
(i)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油单酯以约35至约37重量%的量存在,
(ii)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油二酯以约47至约49重量%的量存在,
(iii)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油三酯以约8.25至约8.75重量%的量存在,并且
(iv)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油以约7.25至约7.75重量%的量存在。
14.根据权利要求1所述的组合物,其为罐装组合物,其中
所述农用化学品为麦草畏,基于所述组合物的总重量,其以约15至约60重量%的量存在;
基于所述组合物的总重量,所述表面活性剂以约5至约50重量%的量存在,其中每个R1是H或CH3,并且
(i)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油单酯以约35至约37重量%的量存在,
(ii)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油二酯以约47至约49重量%的量存在,
(iii)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油三酯以约8.25至约8.75重量%的量存在,并且
(iv)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油以约7.25至约7.75重量%的量存在。
15.根据权利要求1所述的组合物,其为喷雾组合物,其中
所述农用化学品为2,4-滴,基于所述组合物的总重量,其以约0.05至约5重量%的量存在;
基于所述组合物的总重量,所述表面活性剂以约0.05至约0.5重量%的量存在,其中每个R1是H或CH3,并且
(i)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油单酯以约35至约37重量%的量存在,
(ii)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油二酯以约47至约49重量%的量存在,
(iii)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油三酯以约8.25至约8.75重量%的量存在,并且
(iv)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油以约7.25至约7.75重量%的量存在。
16.根据权利要求1所述的组合物,其为罐装组合物,其中
所述农用化学品为2,4-滴,基于所述组合物的总重量,其以约15至约60重量%的量存在;
基于所述组合物的总重量,所述表面活性剂以约5至约50重量%的量存在,其中每个R1是H或CH3,并且
(i)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油单酯以约35至约37重量%的量存在,
(ii)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油二酯以约47至约49重量%的量存在,
(iii)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油三酯以约8.25至约8.75重量%的量存在,并且
(iv)基于所述表面活性剂的总重量,所述至少一种烷氧基化甘油以约7.25至约7.75重量%的量存在。
17.一种液体农用化学组合物,其主要由以下组成:
农用化学品,其包括杀真菌剂和/或选自麦草畏、2,4-滴、草铵膦及其组合的除草剂,并且基于组合物的总重量,其以约0.05至约60重量%的量存在;和
表面活性剂,基于组合物的总重量,其以约0.05至约50重量%的量存在,并且由以下组成:
(i)至少一种烷氧基化甘油单酯,其以所述表面活性剂的约30至约45重量%的摩尔量存在,并且具有以下结构
(ii)至少一种烷氧基化甘油二酯,基于表面活性剂中(i)-(iv)的总摩尔数,其以约40至约50重量%的摩尔量存在,并且具有以下结构
(iii)至少一种烷氧基化甘油三酯,基于表面活性剂中(i)-(iv)的总摩尔数,其以约8至约10重量%的摩尔量存在,并且具有以下结构
和
(iv)至少一种烷氧基化甘油,基于表面活性剂中(i)-(iv)的总摩尔数,其以约6至约8重量%的摩尔量存在,并且具有以下结构
其中每个R独立地为C7-C23饱和或不饱和基团;
其中每个R1独立地为H、CH3或CH2CH3;和
其中(x+y+z)的总和为约2至约40。
18.根据权利要求17所述的组合物,其中所述农用化学品为杀真菌剂。
19.根据权利要求17所述的组合物,其中所述农用化学品为2,4-滴。
20.根据权利要求17所述的组合物,其中所述农用化学品为草铵膦。
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CN100581363C (zh) * | 2003-07-25 | 2010-01-20 | 石原产业株式会社 | 具有增强的除草效果的除草组合物以及增强除草效果的方法 |
RU2543281C2 (ru) * | 2009-03-11 | 2015-02-27 | Акцо Нобель Н.В. | Состав гербицида, содержащий глифосат и алкоксилированные глицериды (варианты) и способ борьбы с нежелательной растительностью |
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2021
- 2021-11-23 CN CN202180074530.9A patent/CN116744792A/zh active Pending
- 2021-11-23 US US18/254,444 patent/US20240215573A1/en active Pending
- 2021-11-23 AU AU2021386290A patent/AU2021386290B2/en active Active
- 2021-11-23 EP EP21819426.4A patent/EP4250925A1/en active Pending
- 2021-11-23 WO PCT/EP2021/082721 patent/WO2022112269A1/en active Application Filing
- 2021-11-23 CA CA3201292A patent/CA3201292A1/en active Pending
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CA3201292A1 (en) | 2022-06-02 |
AU2021386290B2 (en) | 2024-05-02 |
AU2021386290A1 (en) | 2023-05-25 |
EP4250925A1 (en) | 2023-10-04 |
US20240215573A1 (en) | 2024-07-04 |
AU2021386290A9 (en) | 2024-09-26 |
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