CN116731577A - High polymer cement waterproof paint - Google Patents
High polymer cement waterproof paint Download PDFInfo
- Publication number
- CN116731577A CN116731577A CN202310925243.5A CN202310925243A CN116731577A CN 116731577 A CN116731577 A CN 116731577A CN 202310925243 A CN202310925243 A CN 202310925243A CN 116731577 A CN116731577 A CN 116731577A
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- CN
- China
- Prior art keywords
- modified zeolite
- parts
- zeolite
- high polymer
- polymer cement
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000011414 polymer cement Substances 0.000 title claims abstract description 25
- 239000003973 paint Substances 0.000 title claims description 21
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 63
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 22
- 239000010457 zeolite Substances 0.000 claims abstract description 22
- 238000002156 mixing Methods 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000006004 Quartz sand Substances 0.000 claims abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- 239000000243 solution Substances 0.000 claims description 28
- 238000001035 drying Methods 0.000 claims description 16
- 239000003513 alkali Substances 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 10
- 239000003431 cross linking reagent Substances 0.000 claims description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 239000011259 mixed solution Substances 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 5
- 238000010992 reflux Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000009210 therapy by ultrasound Methods 0.000 claims description 5
- 238000001291 vacuum drying Methods 0.000 claims description 5
- 238000000576 coating method Methods 0.000 abstract description 31
- 239000011248 coating agent Substances 0.000 abstract description 30
- 238000010276 construction Methods 0.000 abstract description 12
- 239000004568 cement Substances 0.000 abstract description 10
- 238000005336 cracking Methods 0.000 abstract description 6
- 239000000839 emulsion Substances 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 239000011148 porous material Substances 0.000 abstract description 4
- 239000011398 Portland cement Substances 0.000 abstract description 3
- 230000036571 hydration Effects 0.000 abstract description 3
- 238000006703 hydration reaction Methods 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 239000003899 bactericide agent Substances 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 239000013530 defoamer Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention belongs to the technical field of waterproof coating, and discloses a high polymer cement waterproof coating, which is prepared by mixing the following raw materials, by mass, 25-35 parts of acrylic emulsion, 1-10 parts of water, 0.1-1 part of defoamer, 0.1-1 part of bactericide, 28-38 parts of Portland cement, 28-38 parts of quartz sand, 0.1-1 part of water reducer and 5-10 parts of modified zeolite. The beneficial effects of the invention are as follows: the modified zeolite can play a role in moisture release, moisture is provided for cement hydration, meanwhile, due to the hard structural characteristic of the zeolite, after the moisture in zeolite pores reacts with cement, the volume of the zeolite is unchanged, the coating can be supported, and the volume shrinkage of the coating is avoided, so that the phenomenon of cracking of a film layer of the high polymer cement waterproof coating can be avoided when the coating thickness is large, the construction steps are simplified, and the construction efficiency is improved.
Description
Technical Field
The invention belongs to the technical field of waterproof coatings, and particularly relates to a high polymer cement waterproof coating.
Background
The waterproof material is a main material for solving the waterproof problem of the building engineering, is a key carrier for improving the waterproof performance of the building engineering, and has very important promotion effect on improving the quality of the building waterproof engineering. The polymer cement waterproof paint is JS waterproof paint for short, J refers to polymer, S refers to cement, so JS is polymer cement waterproof paint. The polymer cement waterproof paint is an organic liquid material composed of polymer emulsion such as polyacrylate emulsion, ethylene-vinyl acetate copolymer emulsion and various additives.
The quality of the polymer cement paint is greatly influenced by construction environment, air temperature and humidity after the coating, the surface of the coating is quickly formed into a film, the film forming thickness is thinner, the surface strength of the coating is lower, the bottom of the coating is slow in drying and curing speed, and the cement can generate hydration in the drying and curing process to generate the phenomenon of volume shrinkage, so that when the coating thickness is larger, the surface of the coating is cracked in the process of drying to form a coating film. The constructor often needs to coat a thinner layer each time, and after the thin coating dries out, the constructor covers a layer again and repeats three to four times, and the construction process is tedious and the construction time is long. In the air-dried area, the water in the coating gradually evaporates, so that the volume of the coating is reduced, and the drying crack occurs, so that the service life of the coating is short.
Disclosure of Invention
The invention aims to provide a high polymer cement waterproof coating which has the effects of convenient construction and difficult cracking.
The technical aim of the invention is realized by the following technical scheme: the high polymer cement waterproof paint is prepared by mixing the following raw materials in parts by mass:
the invention is further provided with: also comprises 5-10 parts of modified zeolite.
The invention is further provided with: the modified zeolite is prepared by the following steps:
s1, selecting zeolite with 100-200 meshes, adopting sodium hydroxide alkali to mix and soak for 1-2 hours, and drying to obtain alkali modified zeolite;
s2, refluxing the alkali modified zeolite in the step S1 in an absolute ethanol solution of hexadecyl trimethyl ammonium bromide at 70 ℃ to obtain an organized modified zeolite;
s3, dropwise adding sodium hydroxide with the mass fraction of 20% into acrylic acid, adding the organic modified zeolite into the part solution, adding potassium persulfate, stirring and mixing a cross-linking agent N-N' -methylene bisacrylamide, and performing ultrasonic treatment for 30min to obtain an emulsified solution;
s4, removing oxygen in the cyclohexane and the mixed solution by using nitrogen, dissolving at 40 ℃, pouring the emulsified solution into the cyclohexane solution, reacting for 4 hours at 79 ℃, and carrying out vacuum drying and grinding on the obtained sample to obtain the modified zeolite.
The invention is further provided with: the step S3 comprises 10-20 parts by mass of organic modified zeolite, 100 parts by mass of solution and 0.3-1 part by mass of cross-linking agent N-N' -methylene bisacrylamide.
The invention is further provided with: the mesh number of the quartz sand is 70-140 meshes.
The beneficial effects of the invention are as follows:
1. the modified zeolite has good moisture absorption rate and moisture release rate, the modified zeolite is added into the high polymer cement, after the high polymer cement is coated, the surface of the coating is quickly formed into a film, the bottom of the coating is dried in the early stage, the modified zeolite can play a role in moisture release to provide moisture for cement hydration, meanwhile, the volume of the zeolite is unchanged after the moisture in the zeolite pores reacts with the cement due to the relatively hard structural characteristic of the zeolite, the function of supporting the coating can be realized, the volume shrinkage of the coating is avoided, and therefore, when the coating thickness of the high polymer cement waterproof coating is relatively large, the phenomenon of cracking of a film layer can not occur, the construction steps are simplified, and the construction efficiency is improved.
2. In the later drying and solidifying process of the coating, the modified zeolite can play a role in retaining water, can continuously provide water for cement in a drying environment, and avoids shrinkage and drying crack of the cement stone due to water loss in the drying environment.
The zeolite with the mesh of 3.100-200 is filled in the pores of the Portland cement, thereby increasing the structural density of the inside of the concrete and improving the mechanical property of the cement.
4. The sodium polyacrylate in the zeolite can be associated with acrylic acid ester in the acrylic emulsion, so that the tensile strength of the acrylic emulsion after film formation is enhanced, and the cracking of a coating is avoided.
Detailed Description
The technical solutions in the embodiments will be clearly and completely described below. It will be apparent that the described embodiments are only some, but not all, embodiments of the invention. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to fall within the scope of the invention.
Example 1
The high polymer cement waterproof paint is characterized by being prepared by mixing the following raw materials in parts by mass:
the modified zeolite is prepared by the following steps:
s1, selecting 100-mesh zeolite, mixing and soaking the zeolite with sodium hydroxide alkali for 2 hours, and drying the zeolite to obtain alkali modified zeolite;
s2, refluxing the alkali modified zeolite in the step S1 in an absolute ethanol solution of hexadecyl trimethyl ammonium bromide at 70 ℃ to obtain an organized modified zeolite;
s3, dropwise adding 20% sodium hydroxide into acrylic acid, adding 10 parts of organic modified zeolite into 100 parts of solution, adding 3 parts of potassium persulfate, 0.3 part of cross-linking agent N-N' -methylene bisacrylamide, stirring and mixing, and performing ultrasonic treatment for 30min to obtain an emulsified solution;
s4, removing oxygen in the cyclohexane and the mixed solution by using nitrogen, dissolving at 40 ℃, pouring the emulsified solution into the cyclohexane solution, reacting for 4 hours at 79 ℃, and carrying out vacuum drying and grinding on the obtained sample to obtain the modified zeolite.
Example 2
The high polymer cement waterproof paint is characterized by being prepared by mixing the following raw materials in parts by mass:
the modified zeolite is prepared by the following steps:
s1, selecting zeolite with 200 meshes, mixing and soaking the zeolite with sodium hydroxide alkali for 1h, and drying the zeolite to obtain alkali modified zeolite;
s2, refluxing the alkali modified zeolite in the step S1 in an absolute ethanol solution of hexadecyl trimethyl ammonium bromide at 70 ℃ to obtain an organized modified zeolite;
s3, dropwise adding 20% sodium hydroxide into acrylic acid, adding 20 parts of organic modified zeolite into 100 parts of solution, adding 2 parts of potassium persulfate, 1 part of cross-linking agent N-N' -methylene bisacrylamide, stirring and mixing, and carrying out ultrasonic treatment for 30min to obtain an emulsified solution;
s4, removing oxygen in the cyclohexane and the mixed solution by using nitrogen, dissolving at 40 ℃, pouring the emulsified solution into the cyclohexane solution, reacting for 4 hours at 79 ℃, and carrying out vacuum drying and grinding on the obtained sample to obtain the modified zeolite.
Example 3
The high polymer cement waterproof paint is characterized by being prepared by mixing the following raw materials in parts by mass:
example 4
The high polymer cement waterproof paint is characterized by being prepared by mixing the following raw materials in parts by mass:
the modified zeolite is prepared by the following steps:
s1, selecting 100-mesh zeolite, mixing and soaking the zeolite with sodium hydroxide alkali for 2 hours, and drying the zeolite to obtain alkali modified zeolite;
s2, refluxing the alkali modified zeolite in the step S1 in an absolute ethanol solution of hexadecyl trimethyl ammonium bromide at 70 ℃ to obtain an organized modified zeolite;
s3, dropwise adding 20% sodium hydroxide into acrylic acid, adding 10 parts of organic modified zeolite into 100 parts of solution, adding 3 parts of potassium persulfate, 0.3 part of cross-linking agent N-N' -methylene bisacrylamide, stirring and mixing, and performing ultrasonic treatment for 30min to obtain an emulsified solution;
s4, removing oxygen in the cyclohexane and the mixed solution by using nitrogen, dissolving at 40 ℃, pouring the emulsified solution into the cyclohexane solution, reacting for 4 hours at 79 ℃, and carrying out vacuum drying and grinding on the obtained sample to obtain the modified zeolite.
Test data
According to the raw materials in examples 1-4, the raw materials were stirred and mixed to prepare a high polymer waterproof paint, and the drying time, tensile strength and elongation at break of the paint were tested with reference to GB T23445-2009 polymer cement waterproof paint, and the test results are shown in Table 1 below.
TABLE 1
The waterproof coating is constructed on the ground, the vertical face and the internal corner, the construction thickness is 2mm, the construction is performed once, the cracking state of the coating is observed, and the test results are shown in the following table 2.
TABLE 2
As can be seen from the combination of table 1 and table 2, the drying times of example 1 and example 2 are longer, but the strength after drying is higher, and cracking is not easy; the zeolite is adopted in the embodiment 3, the zeolite is not added in the embodiment 4, and the strength and the crack resistance in the embodiments 3 and 4 are not ideal, so that the modified zeolite can ensure that the high polymer cement waterproof paint can not crack when the coating thickness is larger, the construction step is simplified, the construction efficiency is improved, the zeolite with 100-200 meshes is filled in the pores of the Portland cement, the structural density in the concrete is increased, and the mechanical property of the cement can be improved.
Claims (5)
1. The high polymer cement waterproof paint is characterized by being prepared by mixing the following raw materials in parts by mass:
2. the high polymer cement waterproof paint as claimed in claim 1, wherein: also comprises 5-10 parts of modified zeolite.
3. A high polymer cement waterproof paint according to claim 2, characterized in that: the modified zeolite is prepared by the following steps:
s1, selecting zeolite with 100-200 meshes, adopting sodium hydroxide alkali to mix and soak for 1-2 hours, and drying to obtain alkali modified zeolite;
s2, refluxing the alkali modified zeolite in the step S1 in an absolute ethanol solution of hexadecyl trimethyl ammonium bromide at 70 ℃ to obtain an organized modified zeolite;
s3, dropwise adding sodium hydroxide with the mass fraction of 20% into acrylic acid, then adding the organic modified zeolite into the solution, adding potassium persulfate, stirring and mixing a cross-linking agent N-N' -methylene bisacrylamide, and carrying out ultrasonic treatment for 30min to obtain an emulsified solution;
s4, removing oxygen in the cyclohexane and the mixed solution by using nitrogen, dissolving at 40 ℃, pouring the emulsified solution into the cyclohexane solution, reacting for 4 hours at 79 ℃, and carrying out vacuum drying and grinding on the obtained sample to obtain the modified zeolite.
4. A high polymer cement waterproof paint according to claim 3, characterized in that: the step S3 comprises 10-20 parts by mass of organic modified zeolite, 100 parts by mass of solution and 0.3-1 part by mass of cross-linking agent N-N' -methylene bisacrylamide.
5. The high polymer cement waterproof paint as claimed in claim 1, wherein: the mesh number of the quartz sand is 70-140 meshes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310925243.5A CN116731577A (en) | 2023-07-26 | 2023-07-26 | High polymer cement waterproof paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310925243.5A CN116731577A (en) | 2023-07-26 | 2023-07-26 | High polymer cement waterproof paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN116731577A true CN116731577A (en) | 2023-09-12 |
Family
ID=87915259
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202310925243.5A Pending CN116731577A (en) | 2023-07-26 | 2023-07-26 | High polymer cement waterproof paint |
Country Status (1)
| Country | Link |
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| CN (1) | CN116731577A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009073925A (en) * | 2007-09-20 | 2009-04-09 | Aisin Chem Co Ltd | Aqueous coating type damping material |
| US20100210745A1 (en) * | 2002-09-09 | 2010-08-19 | Reactive Surfaces, Ltd. | Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes |
| CN102504466A (en) * | 2011-10-17 | 2012-06-20 | 常熟市星源金属涂层厂 | Method for preparing modified zeolite-sodium acrylate moisture-absorbing composite material |
| CN104140728A (en) * | 2014-08-08 | 2014-11-12 | 鳄鱼制漆(上海)有限公司 | JS elastic waterproof coating |
| CN106316293A (en) * | 2016-08-24 | 2017-01-11 | 河南省德嘉丽科技开发有限公司 | Water-proof coating of cement-based polymer |
| CN107629499A (en) * | 2017-09-29 | 2018-01-26 | 佛山市涂无忧建材有限公司 | A kind of elastic polymer waterproof paint and preparation method thereof |
| CN108147726A (en) * | 2017-12-29 | 2018-06-12 | 中山市诚美涂料有限公司 | A kind of water-repellent paint and preparation method thereof |
-
2023
- 2023-07-26 CN CN202310925243.5A patent/CN116731577A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100210745A1 (en) * | 2002-09-09 | 2010-08-19 | Reactive Surfaces, Ltd. | Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes |
| JP2009073925A (en) * | 2007-09-20 | 2009-04-09 | Aisin Chem Co Ltd | Aqueous coating type damping material |
| CN102504466A (en) * | 2011-10-17 | 2012-06-20 | 常熟市星源金属涂层厂 | Method for preparing modified zeolite-sodium acrylate moisture-absorbing composite material |
| CN104140728A (en) * | 2014-08-08 | 2014-11-12 | 鳄鱼制漆(上海)有限公司 | JS elastic waterproof coating |
| CN106316293A (en) * | 2016-08-24 | 2017-01-11 | 河南省德嘉丽科技开发有限公司 | Water-proof coating of cement-based polymer |
| CN107629499A (en) * | 2017-09-29 | 2018-01-26 | 佛山市涂无忧建材有限公司 | A kind of elastic polymer waterproof paint and preparation method thereof |
| CN108147726A (en) * | 2017-12-29 | 2018-06-12 | 中山市诚美涂料有限公司 | A kind of water-repellent paint and preparation method thereof |
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