CN1166855A - Detergent composition comprising clay and polysaccharide gum stabilizing agents - Google Patents

Detergent composition comprising clay and polysaccharide gum stabilizing agents Download PDF

Info

Publication number
CN1166855A
CN1166855A CN 95196471 CN95196471A CN1166855A CN 1166855 A CN1166855 A CN 1166855A CN 95196471 CN95196471 CN 95196471 CN 95196471 A CN95196471 A CN 95196471A CN 1166855 A CN1166855 A CN 1166855A
Authority
CN
China
Prior art keywords
composition
oil
alkyl
weight
nonionogenic tenside
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 95196471
Other languages
Chinese (zh)
Inventor
温迪·V·J·理查森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of CN1166855A publication Critical patent/CN1166855A/en
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/90—Block copolymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/18—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Dermatology (AREA)
  • Inorganic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

A personal cleansing comprising: (a) from about 1.5 % to about 10 % by weight of an oil dispersing nonionic surfactant; (b) from about 0.1 % to about 10 % by weight of auxiliary surfactant selected from other nonionic, anionic, zwitterionic and/or amphoteric surfactants and mixtures thereof; (c) from about 3 % to about 30 % by weight of a perfume or cosmetic oil; (d) from about 0.01 % to about 15 % by weight of a stabilising system comprising a clay primary stabilising agent and a hetero polysaccharide gum secondary stabilising agent; and (e) water, and wherein the ratio of primary to secondary stabilising agent is in the range of from about 32:1 to about 1:1. The cleansing products demonstrate excellent in-use efficacy benefits including excellent lather volume, stability and appearance characteristics, good skin feel during and after use, skin conditioning, mildness, stability, cleansing, good water feel and appearance and rinsibility.

Description

The detergent composition that contains clay and polysaccharide gum stabilizing agents
The present invention relates to detergent composition.Particularly, the present invention relates to gentle personal cleaning compositions, it has skin sense feature and the foam characteristics that is suitable for cleaning simultaneously with conditioning skin and/or hair, it can use in a variety of forms, for example, foam bathing preparation, shower articles for use, skin cleaner, hand, face and body sanitising agent, shampoo or the like.
Gentle cosmetic composition need satisfy many standards, comprises cleaning power, whipability and skin, hair and eye mucus are had gentleness/low irritant/feel good.Skin is by which floor cellularity, and it coats and shielding angle albumen and collegen filament albumen, and these albumen have constituted the skeleton of skin texture.Be known as cuticular this which floor most external, known is to be made of 250 dust protein bundles that surrounded by the thick layer of 80 dusts.Hair has the outermost protection covering of similarly sealing hair fiber, and this covering is called epidermis.Anion surfactant can see through cutin tunic and epidermis, and destroys the integrity of film by degreasing.This effect to skin and hair protective membrane can cause the pachylosis sense and to the stimulation of eye, and tensio-active agent and Keratin sulfate and hair protein are interacted, and causes the afunction of stimulations, barrier loss and reservation moisture content.
Ideal cosmetic sanitising agent is cleaning skin or hair leniently, and often use can degreasing and/or made hair and xerosis cutis, also can exciting eye mucus or make skin tight.Many foaming soap, shower and the product of having a bath, shampoo and soap bar are unsatisfactory in this respect.
Known some synthetic surfactant is gentle.But, to compare with the highest shampoo and the standard of soap bar, a major defect of the gentleest most synthetic surfactants is that when being used to prepare shampoo or personal cleanliness's product, their character that spumes is relatively poor.Therefore those belong to the gentleest tensio-active agent, and for example lauryl glyceryl ether sulfonic acid sodium, alkyl glycerol ether sulfonate (AGS) all are not good enough aspect foaming.On the other hand, use known high foaming anion surfactant and foaming promotor,, sacrificed the flexibility of skin though can obtain acceptable froth quality and volume.These two kinds of factors make the selection of tensio-active agent, the compound method that helps whipability and mildness become a delicate balance.
Although cosmetic industry has been carried out years of researches perhaps to personal cleanliness's product, consumers in general are the mildness of dissatisfied current cleaning compositions still, they find, for example after using shower or body washing agent, for keeping the fat abstraction of skin elasticity and moisture content, counteracting sanitising agent, need re-use other skin lotion or soothing cream.
The oil that adds in bath composition known in this field can the good skin sense in useful back.But, add oil with the concentration that is enough to provide the benefit that the human consumer can notice and be still a challenge, particularly in the presence of oil, have simultaneously emulsion form, avoid undesirable " satiny " talent for swimming or oily outward appearance when stablizing good bubbling character and providing ideal with soft skin sense afterwards.With a large amount of oil is combined another relevant difficult point with conventional cleaning system is the formation of stable system, and oil can be released and enter in the water between the usage period in this system.Have now found that, but adopt certain content and the nonionogenic tenside of ratio and the mixed stability system of cosurfactant and dispersed oil, can form skin sense feature after the use neutralization that improves is used and good whipability and stable personal cleaning compositions.
Therefore need a kind of personal cleaning compositions, it can not make the skin dehydration or cause the skin elasticity loss, it will possess skin condition performance to a certain degree, this performance could obtain after having only the cleaning back to use the cosmetic wetting agent in addition in the past, and this composition can produce lather volume and appearance stablity and high-quality foam, it is effective hair and skin cleaner, but it has aesthetic feeling and rinsing feature in the good use, it has stable product and viscosity characteristics simultaneously, and keeps complete stability under long-term and strict storage temperature.
Theme of the present invention is a kind of gentleness, produces the foamy cleaning product that it is suitable for the cleaning of individual's skin or hair and can be used as foam having a bath and shower product, skin cleaner and shampoo etc.An aspect of of the present present invention provides a kind of washing composition, personal cleanliness or cosmetic composition, and it comprises:
(a) about 1.5% the diffusing nonionogenic tenside of oil content to about 10% weight;
(b) about 0.1% cosurfactant to about 5% weight, it is selected from other nonionic, negatively charged ion, zwitter-ion and/or amphoterics and composition thereof;
(c) about 3% spices or oil for cosmetic purpose to about 30% weight;
(d) about 0.01% stable system to about 15% weight, this system comprise main clay stabilizer and auxiliary other polysaccharide gum stabilizing agents; With
(e) water,
Wherein, the ratio of main stablizer and auxiliary stabilizer be about 32: 1 to about 2: 1 scope.
In highly preferred embodiment, the present invention adopts the form that produces the foamy cleaning compositions, it has good foam and invariant feature, superior skin sense feature, perceptible dry sensation and the tight sense of estimating and the high-grade drying property of improvement, and good cleaning power and hair conditioning performance are arranged simultaneously.
Unless specialize, all concentration of this paper and ratio are all in the weight of cleaning compositions.Unless specialize, the tensio-active agent chain length also is based on the mean chain length of weight.
The cleaning compositions of this paper is based on the loose combination of mixed stable system of nonionogenic tenside, spices or oil for cosmetic purpose and gentle cosurfactant of specific oil content, and gentle cosurfactant wherein generally can be selected from other nonionic, negatively charged ion, both sexes and zwitterionics and composition thereof.The total amount of tensio-active agent comprises that negatively charged ion, nonionic, zwitter-ion, both sexes and other tensio-active agent composition are preferably about 1.6% to about 15%, more preferably from about 2% to 12%, and preferred about 5% to about 10% (weight) especially.This composition preferably includes a mixture, and this mixture is by oily dispersive nonionic and anion surfactant is optional and auxiliary nonionic, zwitter-ion and/or amphoterics are formed.The total amount of cosurfactant is about 0.1% to about 10%, preferred especially about 0.5% to about 5%, more preferably from about 1% to about 3.5%, most preferably from about 2% to about 3% (with composition weight meter), and oil content looses the content preferably about 2% of nonionogenic tenside to about 9%, and more preferably from about 4.5% to about 7% (weight).The weight ratio of anion surfactant and auxiliary nonionic, zwitter-ion and/or amphoterics is about 8: 1 to about 1: 2.Cosurfactant and oil content loose the ratio of nonionogenic tenside preferably at 1: 100 to about 1: 10, more preferably from about 1: 8 to about 1: 2.Preferred composition comprises nonionogenic tenside, dispersible spices or oil for cosmetic purpose and auxiliary negatively charged ion, zwitter-ion and/or amphoterics in the scope of the invention, the content of wherein dispersible spices or oil for cosmetic purpose is about 6% to about 25%, preferred about 10% to about 20%, more preferably from about 15% to about 20% (with composition weight meter), and, the diffusing nonionogenic tenside of oil content is about 1: 20 to about 3: 2 with disperseing the weight ratio of spices or oil for cosmetic purpose, preferred about 1: 6 to about 1: 2, more preferably from about 1: 4 to about 1: 3.
The stable system that is suitable for adding composition of the present invention comprises main and auxiliary stabilizer, and wherein main stablizer is the clay or the argillaceous material of any modification, and auxiliary stabilizer is a mixed polysaccharide glue.Use the blended stabiliser system to help providing foam, can improve the skin sense simultaneously with good volume, stability and external appearance characteristic.The applicant finds, of the present invention have blended composition main and auxiliary stabilizer and compare with the composition that contains main or auxiliary stabilizer separately, has the foam characteristics of improvement when oil for cosmetic purpose concentration is higher.
Existing total content main and auxiliary stabilizer is about 0.01% to about 15% by weight, be preferably about 0.05% to about 12%, more preferably about 0.1% to about 10%, most preferably be about 0.5% to about 5%, the ratio of wherein main stablizer and auxiliary stabilizer is about 32: 1 to about 1: 1, be preferably about 16: 1 to about 1: 1, more preferably about 4: 1 to about 2: 1.
In preferred compositions of the present invention, main stablizer is the clay-based material of modification.
Be suitable for main suspension agent of the present invention and comprise magnesium aluminum silicate (Al 2Mg 8Si 2), wilkinite, hectorite and their derivative.Natural terre verte material for example colemanite, talcum powder and the sapphire of being conigenous of magnesium aluminum silicate.The refining magnesium aluminum silicate of Shi Heing can be bought from R.T.Vanderbilt company herein, and trade mark is that Veegum (RTM) buys from ECC America, and trade mark is Gelwhite MAS-H (RTM).The magnesium aluminum silicate material of modification for example magnesium aluminum silicate CMC can be bought from R.T.Vanderbilt company, and trade mark is Veegum Plus (RTM).The magnesium aluminum silicate material of this modification contains the smectic clays with carboxymethyl cellulose and titanium dioxide.Wilkinite is the aluminum silicate clay of the colloidal of natural hydration, and it can buy the ECC in the U.S., and trade mark is called Bentonite H (RTM), also can buy in Whittaker Clark﹠amp; Daniels, trade mark is called Mineral Colloid BP 2430 (RTM).Hectorite is a kind of montmorillonite mineral, and it is the main component of POLARGEL NF.Hectorite can be bought the company in Rheox, trade mark Bentone EW (RTM) by name and Macaloid (RTM).
Preferred main stablizer is magnesium aluminum silicate CMC, and it can be bought from RT.Vanderbilt company, and trade mark is Veegum Plus (RTM).
The preferred auxiliary stabilizer of the present composition is xanthan gum (xanthan/corn carbohydrate gum), and it is the molecular weight that formed by carbohydrate and Xanthomonas campestris pure culture fermentation greater than about 1,000,000 mixed polysaccharide glue.It is considered to contain molar ratio is 2.8: 2.0: 2.0 D-glucose, D-seminose and D-Glucoronate.Polysaccharide carries out partial acetylation with 4.7% ethanoyl.This biosynthetic sizing material can be bought from Calgon company, and trade mark is Kelgum CG (RTM), from Kelko (Merck﹠amp; Co. the branch of company), Meer and R.T.Vanderbilt company buy, and trade mark is respectively Keltrol (RTM), and Merezan 8 (RTM) and Rhodigel (RTM) also can be from other source acquisitions.Xanthan gum mixtures can be bought in Calgon, Alban Muller or the like, and also be fit to add in the composition of the present invention.Further information about xanthan gum can be referring to industrial glue-polysaccharide and the derivative thereof of Whistler.Roy L (editor), New York, the academic press, 1973 (Industrial Gums-P0lysaccharides and Their Derivatives., New York:Academic Press, 1993).
The diffusing nonionogenic tenside of oil content that is fit to add in the composition of the present invention has the diffusing characteristic of good oil content, and this can be confirmed by microscopic examination and dip test.
In order to confirm that nonionogenic tenside is suitable for adding in the composition of the present invention, prepared to comprise the test parent of nonionogenic tenside to be measured and other composition composition.Use the part of the microscopic examination prototype of the little viewer Videomicrowatcher of Nikon Optipot-2 type image.Be suitable for adding the common evenly product matrix of (opaque) that generates of tensio-active agent of composition of the present invention, wherein the mean diameter of oil droplet is about 5 microns to about 30 microns, and preferably about l0 micron is to about 20 microns.
The feature during use of assessment prototype parent in dip test.In fact, 6 milliliters prototype parent is scattered in 40 ℃ 20 premium on currency.Estimate the physical appearance of gained solution then.As long as desired skin sense can be provided, the composition of the solution of the muddiness of the oil droplet that wherein is invisible to the naked eye (cloud) is called as and shows perfect performance.
Although the reason of the skin sense beneficial effect relevant with the present composition fails to be expressly understood, but believe that the specific nonionogenic tenside that this paper stipulates can be scattered in a large amount of oil in the composition parent basically, this causes having a bath or during shower, may be owing to oilyly be released to the advantage that skin surface has good skin sense.
The oil content that is suitable for adding the present composition nonionogenic tenside that looses is selected from C 12-C 18Polyhydroxy fatty amido tensio-active agent, preferred C 12-C 16Polyhydroxy fatty amido tensio-active agent, more preferably C 12-C 14Polyhydroxy fatty amido tensio-active agent, it has following general formula (I):
Figure A9519647100091
Preferred N-alkyl, N-alkoxyl group or N-aryloxy, polyhydroxy fatty amido tensio-active agent are those wherein R 8Be C 5-C 31Alkyl, C preferably 9-C 17Alkyl comprises alkyl and alkenyl or its mixture of straight or branched.And R 9C normally 1-C 8Alkyl or hydroxyalkyl, preferable methyl or formula-R 1-O-R 2Group, R wherein 1Be C 2-C 8Comprise straight chain, side chain or the ring-type alkyl of (comprising phenyl), R 2Be C 1-C 8Straight chain, side chain or cyclic alkyl, comprise aryl and oxygen base alkyl, and preferred C 1-C 4Alkyl, particularly methyl or phenyl.Z 2Be polyhydroxy alkyl, it has linear alkyl chain, and wherein have two (when being Glycerose) at least or have at least three (when being other reducing sugar) hydroxyls to be directly connected on this hydrocarbon chain, or the derivative of its alkoxylate (preferred ethoxylation or propoxylation).Z 2The reducing sugar that is preferably in the reduction amination is derived, Z 2Most preferably be glycosyl (glycityl).Suitable reducing sugar comprises glucose, fructose, maltose, lactose, semi-lactosi, seminose and wood sugar and Glycerose.As starting material, the various one sugar that can utilize high glucose maize treacle, high-fructose corn syrup and high malt sugar maize treacle and list above.These maize treacle can produce a kind of sugared mixture of ingredients as Z 2Should be appreciated that and do not get rid of other proper raw material.Z 2Be preferably and be selected from-CH 2(CHOH) n-CH 2OH ,-CH (CH 2OH)-(CHOH) N-1-CH 2OH ,-CH 2-(CHOH) 2(CHOR) (CHOH)-CH 2OH, wherein n is 1-5 (containing 1 and 5), and R is monose or polysaccharide and its oxyalkylated derivative of hydrogen or cyclic.Most preferred for n wherein is 4 glycosyl, particularly-CH 2(CHOH) 4-CH 2OH.
In the compound of following formula, R 8-CO-N can be for example cocoa amido, stearyl amino, oleoyl amino, lauroyl amino, mnyristoyl amino, certain herbaceous plants with big flowers amido, palmityl amino, butter amido or the like.
The preferred method for preparing following formula (I) compound comprises the polyhydroxy amine reaction of a kind of fatty acid triglycercide and N-replacement, reacts essentially no rudimentary (C 1-C 4) the alcoholic solvent existence, but preferably have oxyalkylated alcohol or alkoxylated alkyl group phenol, for example NEODOL, and use alcoxylates catalyzer, temperature is 50～140 degrees centigrade, obtains the required product of high yield (90～98%) with this.
The structural formula of most preferred polyhydroxy fatty amido is R 8(CO) N (CH 3) CH 2(CHOH) 4CH 2OH, wherein R 8Be C 11-C 17Straight chained alkyl or alkenyl.
The present composition contains dispersible spices or oil for cosmetic purpose or its mixture in addition, and content about 3% is to about 30% by weight, and preferred about 6% to about 25%, and more preferably from about 12% to about 18%.Adding these oil or wax can make personal cleaning compositions of the present invention have the feature of moistness, mildness and rinsability.But a feature of the present invention is, this oil-based composition is owing to be released into oil ingredient in the cleaning water, thereby has the skin sense after outstanding use neutralization is used, good moistness and mildness and ideal physical properties.Such preferred compositions is the form of opaque solution on physical properties, this opaque solution forms turbid liquid when disperseing in water.In the present composition that contains spices and oil for cosmetic purpose, the weight ratio of nonionogenic tenside and oil preferably about 1: 20 to about 3: 2, more preferably from about 1: 6 to about 1: 2, and preferred about 1: 4 to about 1: 3 especially.
Be suitable for the oil for cosmetic purpose that the present invention uses and can be selected from the water-insoluble siloxanes, comprise siloxanes, the rigidity of siloxanes, amino and quaternary ammonium modification of non-volatile poly-alkyl and poly-aryl siloxanes natural gum and fluid, volatile cyclic and linear poly-alkylsiloxane, poly-alkoxylation crosslinked with siloxanes reinforcement and composition thereof, C 8-C 30The C of lipid acid 1-C 24Ester such as Isopropyl myristate and hexadecanol ricinoleate, beeswax, saturated and unsaturated fatty alcohol such as behenyl alcohol, hydro carbons such as mineral oil, paraffin oil and squalene, the fat Isosorbide Dinitrate is (referring to US-A-3988255, Seiden, on October 26th, 1976 issued), lanolin and oily lanolin derivative, the animal and plant triglyceride level is Prunus amygdalus oil for example, peanut oil, wheat germ oil, Toenol 1140, simmondsia oil, apricot line oil, walnut oil, palm-nut oil, pistachio oil, sesame seed oil, rapeseed oil, Du's pine nut oil, Semen Maydis oil, peach oil, poppyseed oil, pine nut oil, Viscotrol C, soya-bean oil, Lipoval A, Thistle oil, Oleum Cocois, hazelnut oil, sweet oil, the C of raisin seed oil and sunflower oil and dimerization and trimer acid 1-C 24Ester, for example dimeracid diisopropyl ester, oxysuccinic acid two iso stearyl esters, dimeracid two iso stearyl esters and trimer acid three iso stearyl esters and composition thereof.
Most preferred spices or oil for cosmetic purpose are mineral oil.
The anion surfactant that is suitable for adding the present composition is generally gentle synthesis of detergent tensio-active agent, comprises the alkylsulfonate, alkyl glycerol ether sulfonate, formyl radical taurate, fatty acyl glycinate, N-acyl glutamate, acyl isethinate, salts of alkyl sulfosuccinates salt, α-sulfonated lipid acid of ethoxylation, their salt and/or alkyl phosphate, acyl sarcosinate and the lipid acid/protein condenses and their mixture of ester, alkyl ethoxy carboxylate, alkyl phosphate, ethoxylation.The alkyl of these tensio-active agents and/or acyl group chain length are C 8-C 22, be preferably C 10-C 18
From the mildness and the bubbling character viewpoint of the best, being suitable for of the present invention is 1 mole high fatty alcohol and about 1 salt to the sulfuric ester of the reaction product of about 12 moles oxyethane, and its counter ion is preferably sodium and magnesium.Particularly preferably be and contain about 2 to 6, the alkyl-sulphate of preferred 2 to 4 moles oxyethane, for example lauryl polyoxyethylene (2) ether (laureth-2) sodium sulfate, lauryl polyoxyethylene (3) ether (laureth-3) sodium sulfate and lauryl polyoxyethylene (3.6) ether (laureth-3.6) sal epsom sodium.In preferred embodiments, anion surfactant contains at least about 50%, especially at least about the alkyl-sulphate of the ethoxylation of 75% (weight).
Composition of the present invention is suitable for also comprising a kind of amphoterics.The amphoterics that is applicable to composition of the present invention comprises: (a) the imidazole salts tensio-active agent of formula (II):
Figure A9519647100111
R wherein 1Be C 7-C 22Alkyl or alkenyl, R 2Be hydrogen or CH 2Z, each Z is respectively CO 2M or CH 2CO 2M, and M is H, basic metal, alkaline-earth metal, ammonium or alkanol ammonium; And/or the derivative of the ammonium of formula (III): R wherein 1, R 2Define as above with Z.(b) the amino-alkane hydrochlorate of formula (IV):
R 1NH (CH 2) nCO 2The iminodiacetic alkanoate of M and formula V:
R 1N[(CH 2) mCO 2M] 2
Wherein n and m are 1 to 4 numeral, and R 1With M for independently to be selected from the group of above-mentioned definition; With
(c) their mixture.
(a) the suitable amphoterics of type is sold with trade(brand)name Miranol and Empigen, and thinks that they have comprised the complex mixture of each material.Think that traditionally Miranol has the structure of formula II, though the 4th edition of CTFA cosmetic ingredient dictionary shows that it is the structure of non-annularity formula III.In fact, may for the purpose of complete, provide two definition for the complex mixture of ring-type and non-annularity material.Even so, being preferred for of the present invention is acyclic material.
The example of the suitable amphoterics of formula (a) comprises the compound of those formulas II and/or formula III, R wherein 1Be C 8H 17(particularly iso-octyl), C 9H 19And C 11H 23Alkyl.Particularly preferably be wherein R 1Be C 9H 19, Z is CO 2M and R 2Compound for H; R wherein 1Be C 11H 23, Z is CO 2M and R 2Be CH 2CO 2The compound of M; And R wherein 1Be C 11H 23, Z is CO 2M and R 2Compound for H.
In CTFA name, the material that is preferred among the present invention comprises coconut both sexes carboxyl propionic ester, coconut both sexes carboxyl propionic acid, and particularly coconut both sexes acetic ester and coconut both sexes diacetate esters (can be described as coconut both sexes carboxyl glycinate in addition).Concrete commercially available prod comprises with following trade(brand)name product sold: Empigen CDL60 and CDR60 (Albright﹠amp; Wilson), Miranol H2MConc.Miranol C2M Conc.N.P, Miranol C2M Cone.O.P, Miranol C2M SF, Miranol CM Special (Rhone-Poulenc); Alkateric 2CIB (Alkaril Chemicals); Amphoterge W-2 (Lonza, Inc.); Monateric CDX-38, Monateric CSH-32 (MonaIndustries); Rewoteric AM-2C (Rewo Chemical Group); With Schercotic MS-2 (Scher Chemicals).
Be to be understood that, the obtainable amphoterics in more such markets is with the form produce and market of electric neutrality mixture, they combine with for example hydroxide radical counter ion or anion sulfate acid ester salt or sulphonate salt surfactant, particularly those Sulfated C 8-C 18Alcohol, C 8-C 18The alcohol of ethoxylation or C 8-C 18The acyl glyceride type.But from the viewpoint of mildness and product stability, preferred compositions is substantially free of (non-ethoxylatedization) Sulfated pure tensio-active agent.It should be noted the concentration and the surfactants based non-mixed form of weight ratio of amphoterics simultaneously, the counter ion of any anion surfactant is all regarded the part of total anion surfactant component content as.
(b) example of the amphoterics that is fit to of type comprises salt, particularly tri ethanol ammonium salt and N-lauryl-β-An Jibingsuan salt and N-lauryl-imino--dipropionate.Such material is sold by Henkel with the Deriphat trade(brand)name and is sold by Rhone Poulenc with the Mirataine trade(brand)name.But the amphoterics that preferably uses is the material of formula (II) and/or formula (III) herein.
Composition of the present invention also can contain auxiliary nonionogenic tenside.Be applicable to that auxiliary nonionogenic tenside herein can be selected from C 12-C 14Lipid acid list and di-methylcarbinol amido and sucrose polyester tensio-active agent, come from the softener (oily deutero-) of water-soluble plant and animal, for example embed the triglyceride level of polyglycol chain; The mono and di-glycerides of ethoxylation, the lanolin of many ethoxylations and shea butter derivative and composition thereof.The auxiliary nonionogenic tenside of the preferred oily deutero-of one class has following general formula (VI):
RCOOCH 2CH (OH) CH 2(OCH 2CH 2) nOH wherein n is about 5 to about 200, and preferred about 20 to about 100, and more preferably from about 30 to about 85, and wherein R comprises an aliphatic group, and it has average about 5 to about 20 carbon atoms, and preferred about 9 to about 18 carbon atoms.
The oil ﹠ fat of this suitable class ethoxylation comprises the polyethyleneglycol derivative of following material: glycerine coconut ester, caproin, glycerol caprylate, glycerine butter ester, palmitic acid glyceride, Vinlub, glycerol laurate, oleic acid glyceride, glycerine ricinoleate ester and the glycerol fatty acid ester that is derived from triglyceride level, for example plam oil, Prunus amygdalus oil and Semen Maydis oil, preferably glycerine butter ester and glycerine coconut ester.
The suitable auxiliary nonionogenic tenside of this class oil deutero-can be by Croda Inc. (NeWYork, USA) obtain with its Crovol series material, for example, Crovol EP40 (PEG20 primrose in night glyceryl ester), Crovol EP70 (PEG60 primrose in night glyceryl ester), Crovol A-40 (PEG20 almond glyceryl ester), Crovol A-70 (PEG60 almond glyceryl ester), Crovol M-40 (PEG20 corn glyceryl ester), Crovol M-70 (PEG60 corn glyceryl ester), Crovol PK-40 (PEG12 palm nuclear glyceryl ester), and Crovol PK-70 (PEG45 palm nuclear glyceryl ester), also have Solan series material, for example Solan E, the ethylating wool grease of the polyoxy of E50 and X.The suitable tensio-active agent of other this class can (Dublin, ohio USA) obtain, and sell with the form of Varonic LI series of surfactants by Sherex Chemical Co..These comprise, for example, and Varonic LI 48 (polyoxyethylene glycol (n=80) glycerine butter ester is also referred to as PEG80 glycerine butter ester in addition), Varonic LI 2 (PEG28 glycerine butter ester); Varonic LI 420 (PEG200 glycerine butter ester) and Varonic LI 63 and 67 (PEG30 and PEG80 glycerine coconut ester).The water-soluble plant deutero-softener that other is suitable for using be Semen Maydis oil, Lipoval A and babassu oil polyethyleneglycol derivative.
The auxiliary nonionogenic tenside that is suitable for herein is derived from composite plant fat or derivatives thereof, refines in the fruit of this composite plant fat by Butyrospermum Parkii (Butyrospermum Karkii Kotschy).This vegetation fat that is referred to as shea butter in non-area widely use, soap system and make cold cream for example, it is sold by Sedema (78610 Le Perray En Yvelines, France).The also derivative of the ethoxylation of shea butter alternatively, by Karlshamn Chemical Co. (Columbos, Ohio, the U.S.) sell, be Lipex series chemical, Lipex 102 E-75 (list of the ethoxylation of shea butter or double glyceride) and sell with its Crovol series material from Croda company (New York) for example are as Crovol SB70 (RTM) (shea butter of ethoxylation).Similarly, the derivative of the ethoxylation of mango oil, theobroma oil and Illipe fat also can be used in the composition of the present invention.Though the nonionogenic tenside that these classify as ethoxylation should be appreciated that the vegetables oil or the fat that still have certain proportion to be left non-ethoxylatedization.
Other suitable ionic surfactant pack derived from oil is drawn together the derivative of the ethoxyquin of following oil: Prunus amygdalus oil, peanut oil, wheat germ oil, Toenol 1140, simmondsia oil, apricot line oil, walnut oil, palm fruit oil, pistachio oil, sesame seed oil, rapeseed oil, Du's pine nut oil, Semen Maydis oil, peach oil, poppyseed oil, pine nut oil, Viscotrol C, soya-bean oil, Lipoval A, Thistle oil, Oleum Cocois, hazelnut oil, sweet oil, raisin seed oil and sunflower oil.
From the mildness of the best and the viewpoint of skin sense feature, the auxiliary nonionogenic tenside of oily deutero-very preferably used herein is PEG60 primrose in a night triglyceride level; The derivative of the derivative of PEG55 lanolin polyethoxylated and the ethoxylation of shea butter.
Composition of the present invention preferably also contains zwitterionics.
The beet alkali surface activator that is suitable for adding the present composition comprises formula R 5R 6R 7N +(CH 2) nThe amido betaines of the alkyl betaine of M (VII) and formula (VIII):
Figure A9519647100141
Wherein, R 5Be C 12-C 22Alkyl or alkenyl, R 6And R 7Be C independently 1-C 3Alkyl, M are H, basic metal, alkaline-earth metal, ammonium or alkanol ammonium, and n, and m is arbitrary numeral of 1 to 4.Preferred trimethyl-glycine comprises coconut amido propyl-dimethyl carboxymethyl betaine, lauryl amido propyl-dimethyl carboxymethyl betaine and Tego trimethyl-glycine.
But composition of the present invention is cation or non-ionic polymeric skin or hair conditioner also, and content is about 0.01% to about 5%, and preferred about 0.04% to about 2%, especially preferred about 0.05% to about 1%.Find these polymkeric substance to improve slip and froth quality and hair is provided and skin conditioning extremely valuable.
Suitable polymers is that the high-molecular weight material (measure, light scattering method for example, generally from about 2000 to about 3,000,000, preferred about 5,000 to about 1,000,000 by weight-average molecular weight.)
Useful polymkeric substance is those positively charged ions that are applied to cosmetic field, nonionic, both sexes and anionic polymkeric substance.Positively charged ion and the non-ionic polymers used of cosmetic field preferably as hair or skin conditioning agent.
The representative classification of polymkeric substance comprises positively charged ion and nonionic polysaccharide; The positively charged ion of derived from propylene acid and/or methacrylic acid and nonionic homopolymer and multipolymer; Positively charged ion and non-ionic cellulose resin; Dimethyl diallyl ammonium chloride and acrylic acid cationic copolymer; The cationic homopolymer of dimethyl diallyl ammonium chloride; Positively charged ion polyolefine and oxyethyl group polyalkylene imine; Quaternised siloxanes and their mixture.
By way of example, the cationic polymers that is suitable for herein using comprises cationic guar gum, Hydroxyproyl Trimethyl ammonium guar gum (substitution value (d.s) is 0.11 to 0.22) for example, with trade(brand)name Jaguar C-14-S (RTM), Jaguar C-17 (RTM) and Jaguar C-16 (RTM) in market sale, it is except that containing above-mentioned cation group, also contain hydroxypropyl substituting group (d.s.0.8～1.1), and the quaternised ether of cellulose of selling with trade(brand)name Ucare Polymer JR and Celquat.Other cationic polymers that is suitable for is that trade(brand)name is the multipolymer of multipolymer, dimethyl amino ethyl methacrylate and the acrylamido of the dimethyl diallyl ammonium chloride sold with Merquat100, the acrylate of the quaternised vinyl pyrrolidone of the multipolymer of the dimethyl diallyl ammonium chloride sold with trade(brand)name Merquat550 and Merquat S and acrylamido, the amino alcohol sold with trade(brand)name Gafquat or the multipolymer of methacrylic ester, and the polyalkylene imine polymine of polymine and ethoxylation for example.
The non-ionic polymers that is applicable to the present composition comprises any conventional non-ionic polymers that uses, and preferably those Pluronic that can buy by BASF and Synperonic bunch polyoxyethylene polyoxypropylene block copolymer, for example Pluronic L-121 and from ICI bought as Synperonic PE-F127.
The anionic polymer of Shi Yonging comprises the cross-linked polymer with amphipathic acrylic acid hydrophobically modified herein, and it is sold by BF Goodrich with trade(brand)name Pemulen TRI and Pemulen TR2; And the carboxy vinyl polymer of selling by BF Goodrich with trade mark Carbopol, it contains by vinylformic acid and polyene propyl group sugar or the crosslinked polymkeric substance of polyene propyl group tetramethylolmethane, and for example, Carbopol 934,940 and 950.
The viscosity of final composition (Brookfield RVT, Spindle4,20rpm, 25 ℃, pure substance) is preferably at least about 500 centipoises, and more preferably from about 1,000 to about 10,000 centipoises, and preferred about 2,000 to about 6,000 centipoises especially.
This cleaning compositions can be chosen wantonly and contain hair or the skin moisturizing agent that is dissolved in the cleaning compositions parent.Moisturizing agent content preferably about 0.5% is to about 20% (weight).In preferred embodiments, moisturizing agent is selected from:
1, liquid water-soluble polyalcohols;
2, the indispensable amino acid compound of in keratoderma, finding that exists naturally; With
3, non-occlusions of water-soluble non-polyvalent alcohol and composition thereof.
Preferred non-some examples that contain moisturizing agent are: the protein and the protein derived protein of other collegen filament of the polyoxyethylene glycol of the polyoxyethylene glycol of glycerine, polyoxyethylene glycol, propylene glycol, sorbyl alcohol, methyl glucoside (as methyl glucam-20) and the ether of propylene glycol, Wool wax alcohol (as Solulan-75) and the ether of propylene glycol, pyrrolidone sodium carboxylate, lactic acid, urea, L-proline(Pro), citrulline, pyrrolidone, hydrolysis, Aloe gel and acetate monoethanolamine amido (acetamide MEA) and composition thereof.In above-mentioned each material, glycerine is extremely preferred.
Some other optional materials can add in this cleaning compositions.These materials comprise protein and polypeptide with and derivative; First, the second of water dissolvable sanitas such as DMDM Hydantoin, Germall 115, hydroxy-benzoic acid, third and butyl ester, EDTA, Euxyl (RTM) K400, Bronopol (2-bromo-2-nitro the third-1,3-glycol), Sodium Benzoate, potassium sorbate and 2-phenoxyethyl alcohol; Other moisturizing agent such as hyaluronic acid, chitin, starch-grafted sodium polyacrylate such as Sanwet (RTM) IM-1000, IM-1500 and IM-2500 are by Celanese Superabsorbent Materials, Portsmith, VA, US-A-4 is sold and be disclosed in the U.S., in 076,663; Solvent such as hexylene glycol and propylene glycol; Antiseptic-germicide such as Oxeco (phenoxy group Virahol); Low temperature adjust mutually agent for example ammonium ion source (as NH 4Cl); Viscosity control agent such as sal epsom, Citrate trianion and other ionogen; Tinting material; Perlite and opalizer such as vinylbenzene polyvinylpyrrolidone (PVP) are as Lytron 631 (RTM), TiO 2And TiO 2The mica of coating; Spices and spices solubility promoter; With zeolite such as Valfour BV400 and derivative thereof, Ca 2+/ Mg 2+Sequestrant such as multi-carboxylate, aminopolycanboxylic acid's salt, polyphosphate, polyphosphonic acid salt, aminopolyphosphonic acid salt and gluconate etc. and pH regulator agent such as citric acid and salt thereof.Contain water simultaneously, its content counts about 35% to about 95.4%, preferably at least about 50% with present composition weight.
The pH value of this composition preferred about 4 to about 8.
The present invention is by following non-limiting example explanation.
In an embodiment, all concentration are all in 100% activity, and abbreviation has following appointment implication:
The polyhydroxy fatty amido of GA formula I, wherein R 8Be C 11-C 17Alkyl, R 9Be methyl, and Z 2Be CH 2(CHOH) 4CH 2OH
Anionic lauryl polyoxyethylene (2) ether (laureth-2) sodium sulfate
Amphoteric Empigen CDL60, it is by 23.5% coconut both sexes acetate (R wherein 1Be coconut alkyl, R 2Be H, and Z is CO 2Na) and 1.35% coconut both sexes diacetin (R wherein 1Be coconut alkyl, R 2Be CH 2CO 2Na and Z are CO 2Na) aqueous mixture of Zu Chenging.
Betaine coconut amido propyl-dimethyl carboxymethyl betaine
Oil mineral oil
Solan Solan (RTM) E (PEG55 lanolin)
The water-soluble shea butter of Shea (PEG75)
Sanitas DMDM Hydantoin (DMDM hydantoin)
Stablizer 1 magnesium aluminum silicate CMC (Veegum Plus (RTM))
Stablizer 2 xanthan gum example I are to VII
Below be the personal cleaning compositions of the shower glue or the froth product form of having a bath, they are representatives of the present invention:
I II III IV V VI VII
GA 2.0 5.0 6.0 4.0 9.0 6.0 5.0
Anionic 4.0 2.0 1.0 2.5 0.5 0.5 1.5
Amphoteric - 2.0 - - - - 0.5
Betaine 0.5 0.5 1.0 - - 0.5 0.5
Oil 10.0 15.0 18.0 16.0 30.0 12.0 12.0
Solan 0.5 0.5 - - - - -
Shea - - - 0.5 - - -
Stablizer 1 0.8 1.6 4.0 0.3 1.6 2.0 0.2
Stablizer 2 0.025 0.1 0.5 0.075 0.05 1.0 0.01
Spices 1.5 1.5 1.5 1.5 1.5 1.5 1.5
Sanitas 0.15 0.15 0.15 0.15 0.15 0.2 0.2
---------------Jia entry is to 100---------------------for water
At ambient temperature, earlier main stablizer and water are stirred hydration, add auxiliary stabilizer then, continue stirring and hydration and add mineral oil to prepare composition I-VII.Separately anion surfactant is mixed with water and is heated to 20～50 degrees centigrade and come hydration.Then add oily dispersive nonionogenic tenside, continue to stir, mixture is cooled to 20～40 degrees centigrade, adds in the mixture of the stablizer that stirs then.The mixture that merges adds all the other water, sanitas, spices and other material after stirring and being cooled to room temperature.
At last, the range of viscosities of composition (Brookfeld RVT, Spindle4,20rpm, 25 ℃, pure substance) is 1,000 to 10,000 centipoise.
This product provides the good use effective benefit that neutralizes, and comprising: good foam volume and stable Skinfeel, skin condition, mildness, stability, cleaning after feature, good use neutralization are used Power, good talent for swimming and outward appearance and rinsing.

Claims (24)

1, a kind of personal cleaning compositions comprises:
(a) about 1.5% the diffusing nonionogenic tenside of oil content to about 10% weight;
(b) about 0.1% cosurfactant to about 10% weight, it is selected from other nonionic, negatively charged ion, zwitter-ion and/or amphoterics and composition thereof;
(c) about 3% spices or oil for cosmetic purpose to about 30% weight;
(d) about 0.01% stable system to about 15% weight comprises main clay stabilizer and auxiliary other polysaccharide gum stabilizing agents; With
(e) water,
Wherein, the ratio of main stablizer and auxiliary stabilizer be about 32: 1 to about 1: 1 scope.
2, the composition of claim 1, wherein the viscosity of composition is 1,000 to 10,000 centipoise (Brookfield RVT, Spindle4,20rpm, 25 ℃, pure substance).
3, claim 1 or 2 composition, wherein the oil content nonionogenic tenside that looses is selected from the C with following general formula (I) 12-C 18The polyhydroxy fatty amido:
R wherein 9Be C 1-C 4Alkyl, and R 8Be C 7-C 19Alkyl and alkenyl, or its mixture; Z 2Be polyhydroxy alkyl, it has linear alkyl chain, wherein has at least three hydroxyls to be directly connected on this hydrocarbon chain, or its oxyalkylated derivative.
4, each composition in the claim 1 to 3, wherein oily dispersive nonionogenic tenside is for having formula R 8(CO) N (CH 3) CH 2(CHOH) 4CH 2The polyhydroxy fatty amido of OH, wherein R 8Be C 11-C 17Straight chained alkyl or alkenyl.
5, each composition in the claim 1 to 4, wherein oily dispersive nonionogenic tenside is C 12-C 14The polyhydroxy fatty amido.
6, each composition in the claim 1 to 5 contains 2% to about 9%, the preferred about 4.5% diffusing nonionogenic tenside of oil content to about 7% (weight) of having an appointment.
7, each composition in the claim 1 to 6 contains and has an appointment 6% to about 25%, 10% spices or oil for cosmetic purpose more preferably from about to about 20% (weight), and wherein spices or oil for cosmetic purpose can be dispersed in oil content and loose in the nonionogenic tenside.
8, each composition in the claim 1 to 7, wherein oil for cosmetic purpose is selected from the crosslinked and siloxanes strengthened of siloxanes, the rigidity of siloxanes, amino and quaternary ammonium modification of water-insoluble siloxanes and modification and their mixture, C 8-C 30The C of lipid acid 1-C 24The C of ester, saturated and unsaturated fatty alcohol, hydro carbons, fatty Isosorbide Dinitrate, lanolin and class oil lanolin derivative, animal and plant triglyceride level and dimerization and trimer acid 1-C 24Ester and composition thereof.
9, each composition in the claim 1 to 8, wherein oil for cosmetic purpose is a mineral oil.
10, each composition in the claim 1 to 9, wherein the ratio of the diffusing nonionogenic tenside of oil content and spices or oil for cosmetic purpose is about 1: 20 to about 3: 2, preferred about 1: 6 to about 1: 2, more preferably from about 1: 4 to about 1: 3.
11, each composition in the claim 1 to 10, the ratio of wherein main stablizer and auxiliary stabilizer is about 16: 1 to about 1: 1, is preferably about 4: 1 to about 2: 1 scope.
12, each composition in the claim 1 to 11, wherein the stablizer total content is about 0.05% to about 12% by weight, is preferably about 0.1% to about 10%, more preferably about 0.5% to about 5%.
13, each composition in the claim 1 to 12, wherein main stablizer is the clay material of magnesium aluminum silicate base.
14, each composition in the claim 1 to 13, wherein auxiliary stabilizer is an xanthan gum.
15, each composition in the claim 1 to 14 contains the mixture of oily dispersive nonionic, negatively charged ion and optional other nonionic, zwitter-ion and/or amphoterics and mineral oil.
16, each composition in the claim 1 to 15 contains cosurfactant, and its total content is about 0.5% to about 4% by weight, is more preferably 1% to about 3.5%, is most preferably 2% to about 3%.
17, each composition in the claim 1 to 16, wherein the ratio of cosurfactant and oily dispersive nonionogenic tenside is 1: 100 to about 1: 1, preferred about 1: 8 to about 1: 2.
18, each composition in the claim 1 to 17; anion surfactant wherein is selected from the alkyl-sulphate, alkyl glyceryl ether sulfonate, formyl radical taurate, fat acidyl glycine salt, alkyl ethoxy carboxylate, N-acyl glutamate, acyl isethinate, salts of alkyl sulfosuccinates salt, α-sulfonated lipid acid of ethoxylation, their salt and/or alkyl phosphate, acyl sarcosinate and the lipid acid/protein condenses of ester, alkyl phosphate, ethoxylation, and their mixture.
19, each composition in the claim 1 to 18, wherein anion surfactant contains the C of an ethoxylation 8-C 22Alkyl-sulphate.
20, each composition in the claim 1 to 19, wherein amphoterics is selected from: (a) the imidazole salts derivative of formula (II): R wherein 1Be C 7-C 22Alkyl or alkenyl, R 2Be hydrogen or CH 2Z, each Z are CO independently 2M or CH 2CO 2M, and M is H, basic metal, alkaline-earth metal, ammonium or alkanol ammonium; And/or the ammonium derivative of formula (III): R wherein 1, R 2Define as above with Z.
(b) the amino-alkane hydrochlorate of formula (IV):
R 1NH(CH 2) nCO 2M
Iminodiacetic alkanoate with formula V:
R 1N[(CH 2) mCO 2M] 2Wherein n and m are 1 to 4 numeral, and R1 and M are independently selected from (a) group of above-mentioned definition; With
(c) their mixture.
21, the composition of claim 20, wherein amphoterics is selected from the imidazole salts derivative of formula (II) and/or the ammonium derivative of formula (III).
22, each composition in the claim 1 to 21, wherein the weight ratio of anion surfactant and other nonionic, zwitter-ion and/or amphoterics is about 1: 2 to about 6: 1.
23, each composition in the claim 1 to 22, also contain positively charged ion or non-ionic polymeric skin or hair conditioner, its content is about 0.01% to about 5%, preferred about 0.04% to about 2%, more preferably from about 0.05% to about 1%, and they are selected from positively charged ion and nonionic polysaccharide; Be derived from positively charged ion and the nonionic homopolymer and the multipolymer of vinylformic acid and/or methacrylic acid; Positively charged ion and non-ionic cellulose resin; Dimethyl diallyl ammonium chloride and acrylic acid cationic copolymer; The cationic homopolymer of dimethyl diallyl ammonium chloride; Positively charged ion polyolefine and oxyethyl group polyalkylene imine; Quaternised siloxanes and their mixture.
24, each composition in the claim 1 to 23, also contain moisturizing agent, be selected from ether, pyrrolidone sodium carboxylate, lactic acid, L-proline(Pro) of the polyoxyethylene glycol of glycerine, polyoxyethylene glycol, propylene glycol, sorbyl alcohol, methyl glucoside and polypropylene glycol and composition thereof.
CN 95196471 1994-11-29 1995-10-30 Detergent composition comprising clay and polysaccharide gum stabilizing agents Pending CN1166855A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9424008A GB9424008D0 (en) 1994-11-29 1994-11-29 Cleansing compositions
GB9424008.2 1994-11-29

Publications (1)

Publication Number Publication Date
CN1166855A true CN1166855A (en) 1997-12-03

Family

ID=10765100

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 95196471 Pending CN1166855A (en) 1994-11-29 1995-10-30 Detergent composition comprising clay and polysaccharide gum stabilizing agents

Country Status (4)

Country Link
EP (1) EP0795003A4 (en)
CN (1) CN1166855A (en)
GB (1) GB9424008D0 (en)
WO (1) WO1996017050A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1315453C (en) * 2001-12-04 2007-05-16 荷兰联合利华有限公司 Hair treatment composition comprising composite particles of clay and charged organic molecule
CN104245910B (en) * 2012-04-23 2017-02-15 荷兰联合利华有限公司 Externally structured aqueous isotropic liquid detergent compositions

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9524575D0 (en) * 1995-12-01 1996-01-31 Unilever Plc Thickener for cosmetic composition
US5916575A (en) * 1997-01-27 1999-06-29 The Procter & Gamble Company Cleaning products
US6407197B1 (en) 1998-03-04 2002-06-18 Dsm N.V. Aqueous dispersion of a polymer
GB0200151D0 (en) 2002-01-04 2002-02-20 Unilever Plc Fabric conditioning compositions

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8606368D0 (en) * 1986-03-14 1986-04-23 Unilever Plc Skin treatment composition
DE3711776A1 (en) * 1987-04-08 1988-10-27 Huels Chemische Werke Ag USE OF N-POLYHYDROXYALKYL Fatty Acid Amides As Thickeners For Liquid Aqueous Surfactant Systems
US5340492A (en) * 1990-11-26 1994-08-23 The Procter & Gamble Company Shaped solid made with a rigid, interlocking mesh of neutralized carboxylic acid
AU649294B2 (en) * 1990-12-17 1994-05-19 Unilever Plc Phosphate esters and compositions containing them
US5264145A (en) * 1991-06-18 1993-11-23 The Procter & Gamble Company Personal cleansing freezer bar with selected fatty acid soaps and synthetic surfactant for reduced bathtub ring, improved mildness, and good lather
US5262079A (en) * 1992-03-20 1993-11-16 The Procter & Gamble Company Framed neutral pH cleansing bar

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1315453C (en) * 2001-12-04 2007-05-16 荷兰联合利华有限公司 Hair treatment composition comprising composite particles of clay and charged organic molecule
CN104245910B (en) * 2012-04-23 2017-02-15 荷兰联合利华有限公司 Externally structured aqueous isotropic liquid detergent compositions

Also Published As

Publication number Publication date
GB9424008D0 (en) 1995-01-18
WO1996017050A1 (en) 1996-06-06
MX9703909A (en) 1998-05-31
EP0795003A4 (en) 1998-03-25
EP0795003A1 (en) 1997-09-17

Similar Documents

Publication Publication Date Title
CN1080558C (en) Cleansing compositions
CN1080557C (en) Cleansing compositions
CN1057327C (en) Cleansing compositions
CN1092041C (en) Cleansing compositions
CN1047620C (en) Cleansing compositions
CN1103809C (en) Aqueous personal cleansing compositions comprising specific nonocclusive liquid polyol fatty acid polyester
KR101045901B1 (en) Thickening composition
CN1190986A (en) Liquid personal cleansing composition containing cationic polymeric skin conditioning agent
CN1076049C (en) Cleansing composition containing polyhydroxy fatty acid amide surfactants
CN1116858A (en) Cleansing compossitions
US6191083B1 (en) Cleansing compositions
CN1092043C (en) Cleansing compositions
CN1341012A (en) Cleaning compositions
CN1174567A (en) Cleansing compositions
CN1113645C (en) Cleansing compositions
CN1227597A (en) Cleaning compositions
CN1174501A (en) Cleaning composition
CN1100862C (en) Aqueous personal cleansing composition with dispersed oil phase comprising two specifically defined oil component
CN1092042C (en) Cleansing compositions
JP2010235833A (en) Cleaning composition
JPH10512254A (en) Cleansing composition
CN1166855A (en) Detergent composition comprising clay and polysaccharide gum stabilizing agents
CN1227592A (en) Cleaning compositions
CN1227596A (en) Cleaning compositions
CN1177372A (en) Cleasing compositions

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication