CN1080557C

CN1080557C - Cleansing compositions

Info

Publication number: CN1080557C
Application number: CN95197516A
Authority: CN
Inventors: 拉塞尔·P·埃利奥特; 马修·T·格林; 克里斯托弗·D·莱希; 埃利尼·佩普迪米特里奥
Original assignee: Proctor And Gambar
Current assignee: Proctor And Gambar; Procter and Gamble Co
Priority date: 1994-12-03
Filing date: 1995-12-01
Publication date: 2002-03-13
Anticipated expiration: 2015-12-01
Also published as: MX9704085A; WO1996017916A1; BR9509947A; JPH10509991A; EG20929A; CN1174565A; EP0794997A1; GB9424476D0; EP0794997A4

Abstract

A liquid personal cleansing composition comprising: a) from about 5% to about 60% by weight of water-soluble surfactant selected from anionic, nonionic and amphoteric surfactants and mixtures thereof; b) from about 0.01% to about 10% by weight of a hydrophobically modified nonionic cellulose ether selected from C10-C24 alkyl and alkenyl modified methyl, hydroxyethyl and hydroxypropyl cellulose ethers having a degree of nonionic substitution in the range of from about 1.8 to about 4 and a degree of hydrophobic substitution in the range of from about 0.1% to about 1% by weight; c) from about 0% to about 10% by weight of a water-soluble polyol; d) from about 0.01% to about 5% by weight of cationic polymeric skin conditioning agent; and e) water, and wherein the composition displays a shear stress of about 150 Pa at a shear rate in the range from about 100 s-1 to about 600 s-1 at 25 DEG C. The products demonstrate excellent in-use efficacy benefits including mildness, a moisturised skin feel, desirable rheology and application characteristics, good rinsibility and good product stability.

Description

Cleasing compositions

The present invention relates to Cleasing compositions.Be particularly related to the personal cleaning compositions of gentleness with good skin sense, rheological behavior and foam characteristic, it is suitable for cleaning simultaneously and conditioning skin and/or hair, can adopt various ways to use, for example, foam bath in a tub preparation, shower articles for use, skin abluent, hands, face and body abluent, shampoo or the like.

Gentle make-up composition need satisfy many standards, comprises cleaning force, foaming characteristic and skin, hair and eye mucus are had gentleness/low irritant/feel good.Skin is by which floor cellularity, and it coats and shielding angle albumen and collagen fiber albumen, and they have constituted the skeleton of skin texture.Be known as cuticular this which floor most external, known is to be made of 250 dust protein bundles that surrounded by the thick layer of 80 dusts.Hair has the outermost protection covering of similarly sealing hair fiber, and this covering is called epidermis.Anion surfactant can see through cutin tunic and epidermis, and destroys the integrity of film by defat.This effect to skin and hair protecting film can cause the pachylosis sense and to the stimulation of eye, and surfactant and keratin and hair protein are interacted, and causes the afunction of stimulations, barrier loss and reservation moisture content.

Ideal cosmetic abluent should leniently clean skin or hair, and often use can defat and/or made hair and xerosis cutis, also can exciting eye mucus or make skin tight.Many foaming fancy soaps, shower and bath in a tub product, shampoo and soap bar are unsatisfactory in this respect.

Known some synthetic surfactant is gentle.But, to compare with the highest shampoo and the standard of soap bar, a major defect of the gentleest synthetic surfactant is, when being used to prepare shampoo or individual and cleaning product, their character that spumes is relatively poor.Therefore those to belong to the gentleest surfactant all be not good enough aspect foaming.On the other hand, use known high foaming anion surfactant and foaming promoter,, sacrificed the flexibility of skin though can obtain acceptable foam quality and volume.These two kinds of factors make the selection of surfactant, the compound method that helps foaming characteristic and mildness become a delicate balance.

Except consumer required cleaning and frothing capacity, valuable especially is that personal cleansing product further provides the rheological equationm of state in some use.Particularly a kind of shower gels product enjoys consumer's favorable comment, and it can show shear thinning performance (shear thinning behavior) on imposing on skin the time.The known water-soluble polymer that uses is providing product thickening character, and further, hydrophobic modified water-soluble polymer can show the product thickening characteristic of improvement and produce the shear thinning feature.But also known, total this product thickening/shear-thinning effect is influenced by the surface-active contents in the system, in fact, even very the water soluble surfactant active of low content existence also can obviously reduce thickening/refinement effect.Contain hydrophobic modified water-soluble polymer (HMWSP _S) system in, second effect of high surfactant and electrolyte concentration be exactly, along with surface-active contents increases, HMWSP can become and be insoluble to more in the product substrate.

Therefore need a kind of personal cleansing product that transmits the skin sense feature in the acceptable use and can not make the skin dehydration or cause skin elasticity to be lost, it will provide a kind of skin condition performance in cleaning and rinse products, this performance could obtain after having only the back of cleaning to use the cosmetic humidizer in addition in the past, and this product can produce stable and high-quality foam, but it has rheological behavior and rinsing feature in the good use, be effective hair and skin cleaner, it has stable product and viscosity characteristics simultaneously, and keeps complete stability under long-term and harsh storage temperature.

Non-ionic water-soluble cellulose ether can have many application, comprises Haircare composition.Widely used commercial available nonionic cellulose ether comprises methylcellulose, hydroxypropyl emthylcellulose, hydroxyethyl-cellulose, hydroxypropyl cellulose and ethylhydroxyethylcellulose.

The cellulose ether of some modification is disclosed in US-A-4, and 288,277, Landoll, on October 14th, 1980 is open; Their molecular weight is lower, but can produce highly viscous aqueous solution under application concentration.These materials are nonionic cellulose ethers, they have the enough nonionic substitution values that are selected from methyl, ethoxy and hydroxypropyl, this causes them soluble in water, and it is further replaced by alkyl, this alkyl has 10～24 carbon atoms, and its amount is that 0.2 (wt) % and making is lower than between the water-soluble amount of the described cellulose ether of 1% (wt).The cellulose ether for the treatment of modification is preferably and is low to moderate intermediate molecular weight, promptly is lower than 800,000 and preferred 20,000 and 700,000 (75～2500 averages degree of polymerization (D.P.)).

Modified cellulose ethers discloses and can use in multiple types of compositions.Landoll (US4,228,277) points out to use some material to be used for the shampoo prescription.The Hercules trade literature points out that modified cellulose ethers is used for shampoo, liquid soap and skin care liquid.US-A-4,683,004 disclose modified cellulose ethers is used for the hair mouse compositions.US-A-4,485,089 disclose a kind of dentifrice composition of cellulose ether.

Have now found that, with some modified cellulose ethers, cationic polymer and surfactant be in conjunction with can providing personal cleaning compositions, thus it in use or the skin sense and the humidification character that have improvement after using ideal thickening/refinement (rheological characteristic) product stability that benefit is become reconciled is provided.Find that also the modified cellulose ethers with certain specific substitution value and chain length is providing special benefit aspect stability and the application characteristic in personal cleaning compositions.

Theme of the present invention is shear thinning gentleness, that foam that is suitable for personal cleanliness's hair and skin, stable cleaning product, and it can be used as foam bath in a tub and shower product, skin detergents and shampoo etc.According to an aspect of the present invention, provide a kind of liquid personal cleansing composition, it contains:

(a) about water soluble surfactant active of 5%～about 60% (wt), it is selected from anion, nonionic, amphion and amphoteric surfactant and composition thereof;

(b) the hydrophobic modified nonionic cellulose ether of about 0.01%～about 10% (wt), it is selected from C ₁₀-C ₂₄The methyl of alkyl and alkenyl modification, ethoxy and hydroxypropylcelluloether ether, it has the nonionic substitution value of about 1.8～about 4 scopes and the hydrophobic substitution value of about 0.1%～about 1% (wt) scope;

(c) about water-soluble polyol of 0%～about 10% (wt);

(d) the cationic polymerization skin conditioning agent of about 0.01%～about 5% (wt); With

(e) water.

This compositions is about 100S 25 ℃ of down cut speed ^-1～about 600S ^-1, preferably about 400S ^-1～about 600S ^-1In the time of in the scope, the preferred shear stress that shows is about 150Pa.

According to a further aspect in the invention, provide a kind of personal cleaning compositions, it contains:

(a) about water soluble surfactant active of 5%～about 60% (wt), it is selected from anion, nonionic and amphoteric surfactant and composition thereof;

(b) the hydrophobic modified nonionic cellulose ether of about 0.01%～about 10% (wt), it is selected from C ₁₄-C ₁₈The hydroxyethyl ether cellulose of alkyl and alkenyl modification, it has the nonionic substitution value of about 2.2～about 2.8 scopes and the hydrophobic substitution value of about 0.4%～about 6% (wt) scope; With

(c) water;

Said composition is about 400S 25 ℃ of down cut speed ^-1～about 600S ^-1The time, the preferred shear stress that shows is about 150Pa.

In highly preferred embodiment, the present invention adopts the form that produces foamy liquid cleansing composition, it has good skin sense and rinsing characteristic, excellent rheological properties, perceptible dry sensation and the fractionated dry sensation of expert that improves and skin hydration is measured and exocuticle moisture loss (TEWL), and have good foam, invariant feature, cleaning force and conditioning performance simultaneously.

Unless specialize, all concentration and ratio are all in Cleasing compositions weight.Unless specialize, the surfactant chain length also is based on the weight average chain length.

Liquid cleansing composition is based on the combination of gentle surfactant and some hydrophobicity modified cellulose ethers and polymerization skin conditioning agent herein.Also contain spice or oil for cosmetic purpose in the preferred embodiment.

As base stock, the present composition contains hydrophobic modified cellulose ether as rheology control agent.

Before hydrophobic modified, the nonionic substitution value that cellulose ether has be about 1.8～about 4.0, preferred about 2～about 3, and especially preferred about 2.2～about 2.8.Then, cellulose ether is further had 10～24, and the alkyl of preferred 14～18 carbon atoms or alkenyl replace, its amount for about 0.1～about 1, preferred about 0.3～about 0.8, and preferred especially about 0.4～about 0.6 (wt%).The cellulose ether for the treatment of modification is preferably and is low to moderate intermediate molecular weight, promptly is lower than 800,000 and preferred 20,000 and 700,000 (75～2500 degree of polymerization (D.P.)).

Preferred cellulose ether substrate is a molecular weight 50,000～70,000 hydroxyethyl-cellulose (HEC).The HEC of this molecular weight is the most hydrophilic in the material.Therefore, use this substrate, the control of the control of modifying process and modified product performance can be more accurate.The hydrophilic of the most frequently used nonionic cellulose ether changes according to following general sequence:

Ethoxy＞hydroxypropyl＞hydroxypropyl methyl＞methyl

By ether, ester or urethane bond, long chain alkyl modifier can be connected in cellulose ether substrate.Preferably pass through ehter bond.Though modified cellulose ethers is called " alkyl-modified " (alkyl generally also comprises alkenyl) herein, it should be understood that modifier is not a simple chain alkyl except the situation with the alkyl halide modification.In fact, this group is the Alpha-hydroxy alkyl when epoxide, is urethane groups when isocyanates, or is acyl group when acid chloride.The conventional method of preparation modified cellulose ethers is seen Landoll (' 277), and second blocks 36～65 row.

In personal cleaning compositions of the present invention, having the modified cellulose ethers that limits substitution value and hydrophobic chain length is very ideal as rheology modifier.These materials can stable dispersion phase float, and when being used for the present composition with other component, they can generate the condensed product of rheological characteristic, and this product shows ideal shear thinning behavior in using.In addition, when being used for skin or hair, take into consideration, find that it also is very helpful that hydrophobic modified cellulose ether combines with the cationic polymerization skin conditioning agent from viscosity improvement and shear thinning behavior.

Rheology modifier used herein is selected from hydrophobic modified water-soluble polymer, is selected from hydrophobic modified hydroxy ethyl cellulose polymer especially.1% aqueous viscosities that suitable hydrophobic modified hydroxy ethyl cellulose (HMHEC) polymer has is about 8,000 to about 13,000mPas (Brookfield LVT viscometer, axle No.4, speed 4).

A kind of commercial materials that is fit to herein use is NATROSOL PLUS Grade 330CS (RTM), and it is a kind of hydrophobic modified hydroxy ethyl cellulose, available from Aqualon company, Wilmington, Delaware.This material has the C of 0.4～0.8% (wt) ₁₆The alkyl substitution value.The hydroxyethyl molar substitution of this material is 3.0～3.7.The mean molecule quantity of the water-soluble cellulose before the modification is about 300,000.

The another kind of material of this class material is the material of selling with trade name NATROSOL PLUS CS Grade D-67 (RTM), available from Aqualon company, Wilmington, Delaware.This material has the C of 0.50～0.95% (wt) ₁₆The alkyl substitution value.The hydroxyethyl molar substitution of this material is 2.3～3.7.The mean molecule quantity about 700,000 of the water-soluble cellulose before the modification.

That preferably uses is C herein ₁₄-C ₁₈The hydroxy ethyl cellulose polymer of alkyl and alkenyl modification, the ethoxyquin degree that it has be about 1.8～about 3.2, preferred about 2.0～about 3.0, more preferably from about 2.2～2.8, and alkyl and alkenyl substitution value are about 0.3～about 0.8, preferred about 0.4～about 0.6.Very preferably be cetyl modified hydroxyl ECN7NF, available from Aqualon Co. trade name Polysurf67 (RTM).

Hydrophobic modified cellulose ether preferred content (wt) is about 0.02%～5%, more preferably from about 0.05%～about 1%, and especially preferred about 0.1%～about 0.5%.

This modified cellulose ethers is useful especially, can provide good invariant feature at normal temperature, and provide the shear thinning characteristic in high surfactant substrate, and combine with selected cationic polymerization skin conditioning agent, and the rheological behavior of improvement is provided.

The present composition is a shear thinning, and is about 100S in shear rate in the time of 25 ℃ preferably ^-1～about 600S ^-1The shearing stress that shows is about 150Pa down.Compositions very preferably is about 400S in shear rate in the time of 25 ℃ ^-1～about 600S ^-1The shearing stress that shows is about 150Pa (use Carri-Med CSL100 flow graph to measure, the axis of cone is that 4cm and 2 degree block for 49 microns) down.

The nertralizer that the neutralization of Shi Yonging herein contains the rheology modifier of acidic-group comprises NaOH, potassium hydroxide, ammonia, monoethanolamine, diethanolamine and triethanolamine and composition thereof.

The present composition also preferably contains the skin condition cationic polymer.Cationic polymer is useful in the present composition, good skin sense feature can be provided and the rheology and the application characteristic of improvement are provided in the presence of partly at hydrophobic modified cellulose ether.The polymerization skin conditioning agent is with about 0.01%～about 5% (wt%), preferred about 0.05%～about 3% and preferred about especially content of 0.1%～about 2% exist.

Suitable polymers is high molecular weight material (weight average molecular weight by for example light scattering method measure), and general about 2,000 to about 5,000,000, preferred about 5,000 to about 3,000,000, more preferably 100,000 to 1,000,000.

The representative category of polymer comprises cationic polysaccharide; The cationic homopolymer of derived from propylene acid and/or methacrylic acid and copolymer; The cationic cellulose resin; Dimethyl diallyl ammonium chloride and acrylamide and/or acrylic acid cation copolymer; The cationic homopolymer of dimethyl diallyl ammonium chloride; Cation polyolefin and ethyoxyl polyalkylene imine; Quaternised siloxanes and their mixture.

By way of example, the cationic polymer that is suitable for herein using comprises cationic guar gum, Hydroxyproyl Trimethyl ammonium guar gum (substitution value (d.s) is 0.11 to 0.22) for example, with trade name Jaguar C-14-S (RTM), Jaguar C-17 (RTM) and Jaguar C-16 (RTM) in market sale, it is except that containing above-mentioned cation group, also contain hydroxypropyl substituent group (substitution value d.s0.8～1.1), and with trade name Ucare Polymer JR-30M, JR-400, the quaternised cellulose ether that Catanal (RTM) and Celquat sell.Other cationic polymer that is suitable for is to be the homopolymer of the dimethyl diallyl ammonium chloride sold with trade name Merquat100, the copolymer of dimethyl amino ethyl methacrylate and acrylamide, with trade name Merquat550 and the dimethyl diallyl ammonium chloride of Merquat S sale and the copolymer of acrylamide, acrylic acid/dimethyl diallyl ammonium chloride/acrylamide copolymer with trade name Merquat sale, the acrylate of the quaternised vinyl pyrrolidone of the amino alcohol of selling with trade name Gafquat or the copolymer such as the polyquaternium 11 of methacrylate, 23 and 28 (quaternised copolymer-Gafquat755N of vinyl pyrrolidone and dimethyl amino ethyl methacrylate and HS-100), the copolymer of vinyl pyrrolidone/vinyl imidazole methochloride of selling with trade name Luviquat HM552, polyquaternium 2, and the polyalkylene imine polymine of polymine and ethoxylation for example.

This compositions also can contain a kind of nonionic or anionic polymerisation thickening component, particularly water-soluble, polymeric material, and its molecular weight is greater than about 20,000." water-soluble polymer " refers under 25 ℃ 1% the concentration, and this material can form the viscosity that basic clear solutions and this material will increase water in water.The example that can be used as the water-soluble polymer of additional thickening composition in the present composition ideally is a hydroxyethyl-cellulose, hydroxypropyl cellulose, hydroxypropyl emthylcellulose, Polyethylene Glycol, polyacrylamide, polyacrylic acid, polyvinyl alcohol, polyvinylpyrrolidone K-120, dextrose, the thick Grade2P of Dextrun purification for example is available from D﹠amp; O chemicals, carboxymethyl cellulose, plant exudate be arabic gum for example, and ghatti gum and tragacanthin (tragacanth), seaweed extract be sodium alginate, propylene glycol alginate and angle dish acid sodium (sodiumcarrageenan) for example.The preferred additional thickener of the present invention is the natural polysaccharide material.Its example is guar gum, locust bean gum and xanthan gum.Also the preferred substance of Shi Heing is for having the hydroxyethyl-cellulose of about 700,000 molecular weight.

Other polymeric viscosifier is the copolymer and the carboxy vinyl polymer of acrylic acid/ethyl acrylate, and it is sold with Carbopol resin trade name by B.F.Goodrich company.This resin is with 0.75%-2.00% cross-linking agent such as polyene propyl group sucrose or the crosslinked acrylic acid colloidal state water-soluble poly alkenyl polyether cross linked polymer of polyene propyl group tetramethylolmethane basically.Example comprises Carbopol 934, Carbopol 940, Carbopol 950, Carbopol 980, Carbopol 951 and Carbopol 981.Carbopol 934 is with on average the have an appointment polymer of the crosslinked water-soluble acrylic of 5.8 allylic sucrose polyallyl ethers of each sucrose molecule of about 1%.Being suitable for of the present invention in addition is to have amphipathic hydrophobic modified crosslinked acrylate copolymer, and commercially available commodity are Carbopol 1382, Carbopol 1342 and Pemulen TR-1 (CTFA title; Acrylate/10-30 alkyl acrylate crosspolymer).The crosslinked acrylate copolymer of polyalkenyl polyethers combines with the crosslinked acrylic acid polymer of hydrophobic modification and also is suitable for the present invention.

If exist in the present composition, the content of polymeric viscosifier is about 0.3%～5.0% (wt), preferred 0.4%～3.0%.

Further suitable thickening comprises fatty acid ethylene glycol or macrogol ester, it has about 16～about 22 carbon atoms and seven ethylene oxy unit at the most, be preferably glycol stearate (single or two stearates), but distearate comprises and is less than about 7% monostearate; Fatty acid alkanol amides, it has about 16～22 carbon atoms, preferred about 16～18 carbon atoms, stearic acid monoethanolamide for example, Stearic acid diethanolamine salt, stearic acid list isopropanol amide and stearic acid monoethanolamide; Alkyl (C ₁₆-C ₂₂) the dimethyl amine oxide, for example, stearyl dimethyl amine oxide and electrolyte, for example magnesium sulfate and sodium chloride salt.

A solubilizer that preferred feature is hydrophobic modified cellulose ether of the present composition.This solubilizer helps condensing by the restriction cellulose ether of the interaction around the hydrophobicity side chain on the polymeric part.The solubilizer preferred content is about 0.1%～about 10% (wt), and more preferably from about 0.5% to about 5%, especially preferred about 1% to about 4%.The ratio of hydrophobic modified cellulose ether and solubilizer is about 0.1: 10 to about 0.2: 5, preferred about 0.3: 5 to about 0.4: 1.

Suitable solubilizer comprises water-soluble polyol.Preferred water-soluble polyol has about 40 to about 2000, and more preferably from about 50 to about 500 and especially preferred about 58 to about 200 molecular weight and polyhydroxy group.The polyhydroxy group refers to about 2 herein to about 6 hydroxyls.Be suitable for water-soluble polyol as solubilizer herein and be selected from the ethylene glycol of the ethylene glycol of glycerol, propylene glycol, hexanediol, mannitol, Polyethylene Glycol, sorbitol, methyl glucoside and propylene glycol (for example ethyl glucam E-20 and propyl group glucam P-10), lanolin alcohol and propylene glycol (for example Solulan～75) and composition thereof.Solubilizer very preferably is glycerol and propylene glycol.

The gentle surfactant that is suitable for adding the present composition is selected from anion, nonionic, both sexes and zwitterionic surfactant and composition thereof.The surfactant total content is preferably (wt) about 5% to about 60%, and more preferably from about 6% to about 40% and especially preferred about 8% to mixture about 35%, that compositions preferably contains anion and amphion and/or amphoteric surfactant.Independent anion, amphion and amphoteric surfactant component content, if exist, be about 1% to about 15%, particularly about 2% to about 13%, and the content of non-ionic surface active agent if exist, is about 0.1% to about 20%, preferred 0.5% to about 16%, and more preferably from about 1% to about 12% (wt).Anion surfactant: amphion and/or amphoteric surfactant proportion are about 1: 2 to about 6: 1.Other suitable compositions in the scope of the invention comprises the mixture of anion, amphion and/or amphoteric surfactant and one or more non-ionic surface active agents.Preferred uses be solubility or dispersible non-ionic surface active agent, it is selected from animal and plant oil ﹠ fat of ethoxylation and composition thereof, also is referred to as " oily deutero-" non-ionic surface active agent sometimes.

The anion surfactant that is suitable for adding the present composition is generally gentle synthesis of detergent surfactant; the alkyl sulfate that comprises ethoxylation; alkyl glycerol ether sulfonate; methyl-acyl taurine salt; fat acidyl glycine salt; the N-acyl glutamate; acyl isethinate; salts of alkyl sulfosuccinates salt; α-sulfonated fatty acid, their salt and/or ester, alkyl ethoxy carboxylate, alkyl phosphate; the alkyl phosphate of ethoxylation, acyl sarcosinates and fatty acid/protein condensation substance and their mixture.The alkyl of these surfactants and/or acyl group chain length are C ₈-C ₂₂, be preferably C ₁₀-C ₁₈, C more preferably ₁₂-C ₁₄

From the mildness and the bubbling character viewpoint of the best, preferably being suitable for of the present invention is 1 mole high fatty alcohol and about 1 salt to the sulfuric ester of the product of about 12 moles oxirane, and its counter ion is preferably sodium and magnesium.Particularly preferably be and contain about 2 to 6, the alkyl sulfate of preferred 2 to 4 moles oxirane, for example dodecyl polyoxyethylene ether 2 (laureth-2) sodium sulfate, dodecyl polyoxyethylene ether 3 (laureth-3) sodium sulfate and dodecyl polyoxyethylene ether 3.6 (laureth-3.6) magnesium sulfate sodium.In preferred embodiments, anion surfactant contains at least 50%, especially at least about the alkyl sulfate of the ethoxylation of 75% (weight).

Compositions of the present invention also is fit to comprise a kind of amphoteric surfactant.The amphoteric surfactant that is applicable to compositions of the present invention comprises:

(a) imidazoline surfactant of formula (I):

R wherein ₁Be C ₇-C ₂₂Alkyl or alkenyl, R ₂Be hydrogen or CH ₂Z, each Z is respectively CO ₂M or CH ₂CO ₂M, and M is H, alkali metal, alkaline-earth metal, ammonium or alkanol ammonium; And/or the derivant of the ammonium of formula (II):

R wherein ₁, R ₂Define as above with Z.

(b) the amino-alkane hydrochlorate of formula (III):

R ₁NH(CH ₂) _nCO ₂M

The iminodiacetic alkanoate of formula (IV):

R ₁N[(CH ₂) _mCO ₂M] ₂

Imino group multichain alkyl salt with formula V:

Wherein n, m, p and q are 1 to 4 number, and R ₁With M is independently to be selected from above-mentioned definition group; With

(c) their mixture.

(a) the suitable amphoteric surfactant of type is sold with trade name Miranol and Empigen, and thinks that they have comprised the complex mixture of each material.Think that traditionally Miranol has the structure of formula I, though the 3rd edition of CTFA cosmetic ingredient dictionary shows that it is the structure of non-annularity formula II, and the 4th edition isomer (wherein, R that is indicated as another kind of structure ₂Be to link to each other with O but not N links to each other).In fact, may for the purpose of complete, provide two definition for the complex mixture of ring-type and non-annularity material.Even so, being preferred for of the present invention is acyclic material.

(a) example of the suitable amphoteric surfactant of type comprises the chemical compound of formula I and/or formula II, R wherein ₁Be C ₈H ₁₇(particularly iso-octyl), C ₉H ₁₉And C ₁₁H ₂₃Alkyl.Particularly preferably be wherein R ₁Be C ₉H ₁₉, Z is CO ₂M and R ₂Chemical compound for H; R wherein ₁Be C ₁₁H ₂₃, Z is CO ₂M and R ₂Be CH ₂CO ₂The chemical compound of M; And R wherein ₁Be C ₁₁H ₂₃, Z is CO ₂M and R ₂Chemical compound for H.

In CTFA name, the material that is used for the present invention comprises Cortex cocois radicis both sexes carboxyl propionic ester, Cortex cocois radicis both sexes carboxyl propanoic acid, and particularly Cortex cocois radicis both sexes acetas and Cortex cocois radicis both sexes diacetate esters (can be described as Cortex cocois radicis both sexes carboxyl glycinate in addition).Concrete commercially available prod comprises with following trade name product sold: Ampholak 7TX (many propyl group of carboxyl methyl Adeps Bovis seu Bubali amine sodium), Empigen CDL60 and CDR60 (Albright; Wilson), Miranol H2M Conc.Miranol C2M Conc.N.P., MiranolC2M Conc.O.P., Miranol C2M SF, Miranol CM Special (Rhone-Poulenc); Alkateric 2CIB (Alkaril Chemicals); Amphoterge W-2 (Lonza, Inc.); MonatericCDX-38, Monateric CSH-32 (Mona Industries); Rewoteric AM-2C (RewoChemical Group); With Schercotic MS-2 (Scher Chemicals).

Be to be understood that, the obtainable amphoteric surfactant in more such markets is with the form produce and market of electric neutrality complex, they have for example hydroxyl counter ion or anion sulfate acid ester (salt) or sulphonic acid ester (salt) surfactant, particularly those Sulfated C ₈-C ₁₈Alcohol, C ₈-C ₁₈The alcohol of ethoxylation or C ₈-C ₁₈The acyl glyceride type.But from the viewpoint of mildness and product stability, preferred compositions is substantially free of (non-ethoxylatedization) Sulfated pure surfactant.It should be noted the concentration and the surfactants based non-complexed forms formula of weight ratio of amphoteric surfactant simultaneously, the counter ion of any anion surfactant is all regarded the part of total anion surfactant component content as.

(b) example of the amphoteric surfactant that is fit to of type comprises that N-alkyl polytrimethylene gathers the carboxyl methyl amine, and such material is sold by Berol Nobel with trade name Ampholak X07 and Ampholak 7CX; Also comprise salt, particularly tri ethanol ammonium salt and N-lauryl-Beta-alanine salt and N-lauryl-imino group-dipropionate.Such material is sold by Henkel with trade name Deriphat and is sold by Rhone Poulenc with trade name Mirataine.

The present composition also can contain a kind of zwitterionic surfactant, and its content is about 0.1% to 20%, and is preferred about 0.1% to 10%, and especially preferred about 1% to 8%.

The beet alkali surface activator that is suitable for adding the present composition comprises formula R ₅R ₆R ₇N ⁺(CH ₂) _nCO ₂The amido betaines of the alkyl betaine of M (VI) and formula (VII):

R ₆

R ₅CON(CH ₂) _mN(CH ₂) _nCO ₂M

R ₇

Wherein, R ₅Be C ₁₂-C ₂₂Alkyl or alkenyl, R ₆And R ₇Be C independently ₁-C ₃Alkyl, M are H, alkali metal, alkaline-earth metal, ammonium or alkanol ammonium, and n, and m is arbitrary number of 1 to 4.Preferred betanin comprises Cortex cocois radicis acylamino-propyl-dimethyl carboxymethyl betaine, lauryl acylamino-propyl-dimethyl carboxymethyl betaine and Tego betanin (fatty acid acyl aminoalkyl betanin).

Compositions of the present invention also can contain oily deutero-non-ionic surface active agent or its mixture, and its weight content is about 0.1% to 20%, and is preferred about 1% to 15%, and more preferably from about 2% to 10%.The deutero-non-ionic surface active agent of oil can provide the skin sense advantage after the use neutralization of compositions of the present invention is used.Suitable oily deutero-ionic surfactant pack is drawn together the emollient that comes from water-soluble plant and animal, for example is embedded with the triglyceride of polyglycol chain; Adeps Bovis seu Bubali derivant of the mono and di-glycerides of ethoxylation, the lanoline of many ethoxylations and ethoxylation and composition thereof.The preferred oily deutero-non-ionic surface active agent of one class has following general formula (VIII): Wherein n is about 5 to about 200, and preferred about 20 to about 100, and more preferably from about 30 to about 85, and wherein R comprises an aliphatic group, and this aliphatic group has average about 5 to about 20 carbon atoms, and preferred about 7 to about 18 carbon atoms.

The oil ﹠ fat of this suitable class ethoxylation comprises the polyethyleneglycol derivative of following material: glycerol Cortex cocois radicis ester, caproin, glycerol caprylate, glycerol Adeps Bovis seu Bubali ester, palmitin, glyceryl stearate, glycerol monolaurate, glyceryl oleate, glycerol ricinoleate ester and the fatty acid glyceride that is derived from triglyceride, for example Petiolus Trachycarpi oil, almond oil and Semen Maydis oil, preferably glycerol Adeps Bovis seu Bubali ester and glycerol Cortex cocois radicis ester.

The suitable deutero-non-ionic surface active agent of this class oil can be by Croda Inc. (New York, USA) obtain with its Crovol series material, for example, Crovol EP40 (PEG20 Flos Caryophylli Radix Oenotherae erythrosepalae glyceride), Crovol EP70 (PEG60 Flos Caryophylli Radix Oenotherae erythrosepalae glyceride), Crovol A-40 (PEG20 almond oil glyceride), Crovol A-70 (PEG60 Semen Armeniacae Amarum glyceride), Crovol M-40 (PEG20 corn glyceride), Crovol M-70 (PEG60 corn glyceride), Crovol PK-40 (PEG12 Petiolus Trachycarpi nuclear glyceride), and Crovol PK-70 (PEG45 Petiolus Trachycarpi nuclear glyceride), also have Solan series material, for example Solan E, the wool grease of many ethoxylations of E50 and X and the Aqualose L-20 (PEG 24 lanolin alcohols) and the Aqualose W15 (PEG 15 lanolin alcohols) that can obtain from Westbrook Lanotin.The suitable surfactant of other this class can (Dublin, ohio USA), obtain with the form of Varonic LI series of surfactants by Sherex Chemical Co..These comprise, for example, and VaronicLI 48 (Polyethylene Glycol (n=80) glycerol Adeps Bovis seu Bubali ester is also referred to as PEG80 glycerol Adeps Bovis seu Bubali ester in addition), Varonic LI 2 (PEG28 glycerol Adeps Bovis seu Bubali ester); Varonic LI 420 (PEG200 glycerol Adeps Bovis seu Bubali ester) and Varonic LI 63 and 67 (PEG30 and PEG80 glycerol Cortex cocois radicis ester).Other oily deutero-emollient that is suitable for be Semen Maydis oil, American Avocado Tree oil and babassu oil polyethyleneglycol derivative, and Softigen767 (PEG (6) suffering/caprin).

The non-ionic surface active agent of suitable use herein is derived from the material of composite plant fat or derivatives thereof in addition, extracts in the fruit of this composite plant fat by Butyrospermum (Butyrospermum Karkii Kotschy).This plant fat that is referred to as Adeps Bovis seu Bubali resin in non-area widely use, soap system and make cold cream for example, it is sold by Sederma (78610 Le Perray En Yvelines, France).Particularly suitable is the derivant of the ethoxylation of Adeps Bovis seu Bubali resin, by Karlshamn Chemical Co. (Columbos, Ohio, the U.S.) with the sale of Lipex series chemicals, for example Lipex 102 E-75 and Lipex 102 E-3 (list of the ethoxylation of Adeps Bovis seu Bubali resin or double glyceride).Similarly, the derivant of the ethoxylation of Fructus Mangifera Indicae oil, cupu oil and Illipe fat also can be used in the compositions of the present invention.Though the non-ionic surface active agent that these classify as ethoxylation should be appreciated that to still have certain proportion still to be the vegetable oil of non-ethoxylatedization or fat.

Other suitable ionic surfactant pack derived from oil is drawn together the derivant of the ethoxylation of following oil: almond oil, Oleum Arachidis hypogaeae semen, Testa oryzae oil, wheat germ oil, Semen Lini oil, jojoba oil, almond oil, walnut oil, the Petiolus Trachycarpi fruit oil, pistachio nut oil, sesame seed oil, Oleum Brassicae campestris, Du's Oleum pini koraiensis, Semen Maydis oil, Semen Persicae oil, seed of Papaver somniferum L. powder, Oleum pini koraiensis, Oleum Ricini, Oleum Glycines, American Avocado Tree oil, safflower oil, Oleum Cocois, hazelnut oil, olive oil, Oleum Vitis viniferae and Oleum helianthi.

From the mildness of the best and the viewpoint of skin sense feature, oily deutero-non-ionic surface active agent very preferably used herein is Lipex 102-3 (RTM) (derivant of the ethoxylation of PEG 3 Adeps Bovis seu Bubali resin) and Softigen767 (PEG (6) suffering/caprin).

Except that the deutero-non-ionic surface active agent of above-mentioned oil, the present composition also contains auxiliary non-ionic surface active agent, and its content is about 0.1% to about 20% (wt), and more preferably from about 0.1% to about 10%, and especially preferred about 1% to about 8%.This class surfactant comprises C ₁₂-C ₁₄Fatty acid list and di-methylcarbinol amide, the polyhydroxy fatty acid amide surfactant of Olestra surfactant and general formula (IX):

Preferred N-alkyl, N-alkoxyl or the N-aryloxy group of general formula I X, polyhydroxy fatty acid amide surfactant are those wherein R ₈Be C ₅-C ₃₁, preferred C ₉-C ₁₇Alkyl, comprise alkyl and alkenyl or its mixture of straight or branched; And R ₉Be typically C ₁-C ₈Alkyl or hydroxy alkyl, preferable methyl or formula-R ¹-O-R ²Group, R wherein ¹Be C ₂-C ₈Comprise straight chain, side chain or cyclic (comprising aryl) alkyl, preferred C ₂-C ₄Alkylidene, R ²Be C ₁-C ₈Comprise straight chain, side chain or cyclic alkyl (comprising aryl and oxygen base alkyl), and preferred C ₁-C ₄Alkyl, particularly methyl or phenyl.Z ₂It is polyhydroxy alkyl, it has linear alkyl chain, wherein have two hydroxyls (when being glyceraldehyde) at least or have at least three hydroxyls (when being other reducing sugar) to be directly connected on this hydrocarbon chain, or the derivant of its alkoxylate (preferred ethoxylation or propoxylation).Z ₂Be preferably in reduction amination and derive, Z from reducing sugar ₂Glycosyl (glycityl) more preferably.Suitable reducing sugar comprises glucose, fructose, maltose, lactose, galactose, mannose and xylose and glyceraldehyde.As raw material, the various sugar that can utilize high dextrorotation corn syrup, high-fructose corn syrup and high malt sugar corn syrup and list above.These corn syrup can produce as Z ₂The mixed sugar composition.Should be appreciated that and do not get rid of other proper raw material.Z ₂Be preferably and be selected from-CH ₂(CHOH) _n-CH ₂OH ,-CH (CH ₂OH)-(CHOH) _N-1-CH ₂OH ,-CH ₂-(CHOH) ₂(CHOR ') (CHOH)-CH ₂OH, wherein n is 1-5 integer (containing), and R ' is hydrogen or cyclic monosaccharide or polysaccharide and its alkoxy derivative.Most preferred for n wherein is 4 glycosyl, particularly-CH ₂(CHOH) ₄-CH ₂OH.

Most preferably polyhydroxy fatty acid amide has formula R ₈(CO) N (CH ₃) CH ₂(CHOH) ₄CH ₂The structure of OH, wherein R ₈Be C ₇-C ₁₇Straight chained alkyl or alkenyl.

In the chemical compound of following formula, R ₈-CO-N＜can be for example cocoamide, stearmide, oleamide, lauramide, myristamide, decyl amide, palmitamide, Adeps Bovis seu Bubali amide or the like.

The preferred method for preparing following formula (IX) chemical compound comprises the polyhydroxy amine reaction of a kind of fatty acid triglycercide and N-replacement, is reflected at essentially no rudimentary (C ₁-C ₄) alcoholic solvent exists down and carry out, and still preferably has oxyalkylated alcohol or alkoxylated alkyl group phenol, for example NEODOL; And using alkoxide catalysis is 50～140 degrees centigrade of required products that obtain high yield (90～98%) down in temperature.

The present composition contains insoluble spice or oil for cosmetic purpose or wax or its mixture in addition, and its content at the most 10% by weight, and is preferably about at the most 3%, and its medium oil or wax are insoluble to be meant insoluble in product substrate under 25 degrees centigrade.Adding these oil or wax can make personal cleaning compositions of the present invention have the feature of emollient, mildness and rinsability.But a feature of the present invention is, emollient that this oil-based composition is good and mildness and ideal physical property, oil-containing not substantially simultaneously, that is, add oil phase weigh less than 1%, preferably be lower than 0.5%.Such compositions preferably is the form or the microemulsion form of optical transparency solution on physical property.In the compositions of the spice that contains adding or oil for cosmetic purpose or wax, oily deutero-non-ionic surface active agent and the weight ratio of being refueled are preferably at least about 1: 2, preferably at least about 3: 1.

The insoluble oil for cosmetic purpose and the wax that are suitable for the present invention's application can be selected from the water-insoluble siloxanes, comprise non-volatile poly-alkyl and poly-aryl siloxanes natural gum and liquid, volatile cyclic and linear poly-alkylsiloxane, the siloxanes of poly-alkoxylation, the siloxanes of amino and quaternary ammonium modification, rigidity crosslinked with siloxanes that strengthen and composition thereof, C ₈-C ₃₀The C of fatty acid ₁-C ₂₄Ester such as isopropyl myristate, nutmeg acid nutmeg ester and hexadecane ricinoleate, benzoic C ₈-C ₃₀Ester, Cera Flava, saturated and unsaturated fatty alcohol such as docosanol, hydro carbons such as mineral oil, vaseline squalane and Squalene, polybutene, the fat Isosorbide Dinitrate is (referring to US-A-3988255, Seiden, on October 26th, 1976 issued), lanoline and class oil lanolin derivative, the animal and plant triglyceride is almond oil for example, Oleum Arachidis hypogaeae semen, wheat germ oil, Testa oryzae oil, Semen Lini oil, jojoba oil, almond oil, walnut oil, palm kernel oil, pistachio nut oil, sesame seed oil, Oleum Brassicae campestris, Du's Oleum pini koraiensis, Semen Maydis oil, Semen Persicae oil, seed of Papaver somniferum L. powder, Oleum pini koraiensis, Oleum Ricini, Oleum Glycines, American Avocado Tree oil, safflower oil, Oleum Cocois, hazelnut oil, olive oil, the C of Oleum Vitis viniferae and Oleum helianthi and dimerization and trimer acid ₁-C ₂₄Ester, for example dimeric dibasic acid diisopropyl ester, malic acid two iso stearyl esters, two iso stearyls, two polyester and three iso stearyls, three polyester.

The viscosity of final composition (Brookfield RVTDCP, 1rpm, awl CP41 or CP52,25 ℃, pure substance) is preferably at least about 500 centipoises, more preferably from about 1,000 to about 50,000 centipoises, and preferred especially about 4,000 to about 30,000 centipoise, more preferred about 4,000 to about 15,000 centipoises.

Cleasing compositions of the present invention also can contain other skin that is dissolved in this Cleasing compositions matrix or hair humidizer, and its content is preferably about 0.5% to about 20%.In preferred embodiments, humidizer is selected from the naturally occurring essential amino acid found and the non-occlusions of water miscible non-polyhydric alcohol and composition thereof in keratodermatitis.

Preferred non-some examples that contain humidizer (moisturizer) are: polybutene, squalane, pyrrolidone sodium carboxylate, lactic acid, the L-proline, guanidine, ketopyrrolidine, aminosal and the deutero-protein of other collagen, Aloe gel and acetic acid single ethanol amide (acetamide MEA) and LMEA and composition thereof.

Compositions of the present invention also comprises opacifier or pearling agent.The content of these materials can for (wt) about 0.01% to about 5%, preferred about 0.2% to about 1.3%.The opacifier that the present invention is fit to is a polystyrene dispersions, and it is produced by Morton international corporation, and commodity are called Lytron 621﹠amp; 631 (RTM).

The other operable opacifier/pearling agent of compositions of the present invention comprises: titanium dioxide TiO ₂EUERLAN 810 (RTM); TEGO-PEARL (RTM); Long-chain C ₁₆-C ₂₂Acyl derivative for example has about 16～22 carbon atoms and 7 unitary fatty acid glycol of ethylene oxy or macrogol ester at the most; Have about 16～22, the alkanolamide of the fatty acid of preferred 16-18 carbon atom, for example stearic acid monoethanolamide, Stearic acid diethanolamine salt, stearic acid list isopropanol amide and stearic acid monoethanolamide; And alkyl (C ₁₆-C ₂₂) dimethyl amine oxide, for example stearyl dimethyl amine oxide.

In preferred compositions, opacifier/pearling agent exists with crystalline form.In compositions very preferably, opacifier/pearling agent is the polystyrene dispersions of granulation, and its particle diameter is the 0.05-0.45 micron, preferred 0.17-0.3 micron.From being provided, the best rheological characteristic and the aspect of shear thinning feature consider that this dispersion is preferred.It is most preferred that styrene PVP copolymer and Lyton631 (RTM).

Some other optional materials can add in this Cleasing compositions, and each substance weight content is about 0.1% to about 2%.These materials comprise protein and polypeptide and derivant thereof; But the antiseptic such as the DMDM Hydantoin of water solublity and solubilization, Germall 115, first, the second of hydroxy benzoic acid, third and butyl ester, EDTA, Euxyl (RTM) K400, natural antiseptic agent such as benzyl alcohol, potassium sorbate and bisabolol; Sodium benzoate and 2-phenyl phenol; Other humidizer such as hyaluronic acid, chitin and starch-grafted sodium polyacrylate such as Sanwet (RTM) IM-1000, IM-1500 and IM-2500 are (by Celanese Superabsorbent Materials, Portsmith, VA, the U.S. sells, and be disclosed in US-A-4, in 076,663); Solvent; Antibacterial such as Oxeco (phenoxy group isopropyl alcohol); Low temperature adjust mutually agent for example ammonium ion source (as NH ₄Cl); Viscosity-control additive such as magnesium sulfate and other electrolyte; Coloring agent; TiO ₂And TiO ₂The Muscovitum of coating; Spice and spice cosolvent; With zeolite such as Valfour BV400 and derivant thereof, Ca ²⁺/ Mg ²⁺Chelating agen such as multi-carboxylate, aminopolycanboxylic acid's salt, polyphosphonic acid salt, aminopolyphosphonic acid salt etc.Simultaneously water also with present composition weight about 15% to about 94.98%, preferred about 40% to about 90%, more preferably exist at least about 65% content.

The pH value of this compositions preferably about 4 is to about 10, and more preferably from about 6 to about 9, and especially preferred about 5 to about 6.

The present invention is by following non-limiting example explanation.

In an embodiment, all concentration are all in 100% activity, and abbreviation has as giving a definition:

Both sexes cocoa both sexes diacetate esters

Anion 1 dodecyl polyoxyethylene ether-3-sodium sulfate

Anion 2 sodium N-lauroyl sarcosinates

Nonionic PEG-3 Adeps Bovis seu Bubali ester

Crovol Crovol EP 70 (PEG 60 Flos Caryophylli Radix Oenotherae erythrosepalae triglyceride)

The polyhydroxy fatty acid amide of GA formula IX, wherein R ₈Be C ₁₁-C ₁₇Alkane

Base, R ₉Be methyl, and Z ₂Be CH ₂(CHOH) ₄CH ₂OH

The hydroxy ethyl cellulose of HMHEC cetyl modification, its non-ionic substitution value is for about

0.4 to 0.6 and ethoxylation degree be about 2.2 to 2.8-Polysurf67

(RTM)

Polymer 1 polymer JR-30 (RTM)-hydroxy ethyl cellulose and chloropropylene oxide reaction

And it is quaternized with trimethylamine.A heavy molecular weight, m.wt.4 * 10 ⁶

Polymer 2 Gafquat 755N

Antiseptic phenoxyethanol/sodium benzoate/EDTA (4: 2: 1)

Pearling agent diglycol stearate/emulsifier mixture

Opacifier Lytron 631 (RTM)

Oil Oleum Glycines

Softigen767 PEG (6) capric acid/caprylin

Embodiment 1 to 6

Below be the personal cleaning compositions of shower gels or bath in a tub froth pulp form, they are representatives of the present invention:

I II III IV V VI both sexes 3.0 3.0-5.0-4.0 anion 1 6.0 6.0 13.0 10.0 6.0 4.0 anion 2 1.0 2.0 2.0 2.0 1.0-GA 3.0--3.0 3.0-oil-4.0-6.0 4.0-Softigen767-1.0-2.0 2.0-nonionic------0.8--1.0 water------is to 100---for 3.0 1.0 1.0 opacifiers, 0.2 0.3 0.4---anticorrisive agents, 0.5 0.5 0.5 1.0 1.0 1.0 spices, 1.0 1.0 1.0 1.0 1.0 1.0 zinc stearates for 0.4-1.0-0.3 Crovol--1.0--3.0 HMHEC 0.3 0.4 0.5 0.1 0.3 0.35 polymer 1 0.8 1.0-0.2 0.8-polymer 2--0.5--0.2 glycerine 1.0 3.0 1.0 2.0 1.5 5.0 pearling agents

Under 25 degrees centigrade, at first water solublity or colloid water-soluble polymeric rheology control agent are dispersed in the water, or before with sodium hydroxide or neutralization of other mixture alkali and hydration, lasting stirring prepares composition I-VI with Triblender.At embodiment 2,4, in 6, mixture can be heated to 50 degrees centigrade and improve dispersion efficiency.Then add solubilizing agent, continue simultaneously to stir.Add surfactant and other skin protectant with water miscible, the oily insoluble composition of residue.In the compositions that contains the insoluble composition of water, formed oil phase B by the molten composition of these oil, then at ambient temperature, with the A premix.This polymeric dispersion adds in the mixture of ambient temperature then, adds remaining water, antiseptic, opacifier and spice at last.

This product provide in the good use and effective benefit, comprise mildness, skin condition, skin moisturizing, stability, rheological characteristic, operating characteristic, cleaning force, foaming characteristic and rinsing.

Claims

1. liquid personal cleansing composition comprises:

A) water soluble surfactant active of 5% to 60% weight is selected from anion surfactant, non-ionic surface active agent, zwitterionic surfactant and amphoteric surfactant and their mixture;

B) the hydrophobic modified nonionic cellulose ether of 0.01% to 10% weight is selected from C ₁₀-C ₂₄The methyl of alkyl and alkenyl modification, ethoxy and hydroxypropylcelluloether ether, their nonionic substitution value is 1.8 to 4, the hydrophobic substitution value is 0.1 to 1% weight;

C) the water miscible polyhydric alcohol of 0 to 10% weight; And

D) cationic polymeric skin conditioning agent of 0.01% to 5% weight is selected from copolymer, acrylic acid/dimethyl diallyl ammonium chloride/acrylamide ter-polymers, quaternized vinyl pyrrolidone acrylate or methacrylate ester copolymer, vinyl pyrrolidone/vinyl imidazole methochloride copolymer, polyalkyleneimine and their mixture of amino alcohol of copolymer, dimethyl diallyl ammonium chloride and acrylamide of homopolymer, amino-ethyl methacrylate dimethyl ester and the acrylamide of cationic guar gum, dimethyl diallyl ammonium chloride.

E) water,

Wherein said composition was at 25 ℃, 100 seconds ^-1To 600 seconds ^-1Shear rate the time, the shear stress of demonstration is 150 handkerchiefs.

2. according to the compositions of claim 1, wherein hydrophobic modified cellulose ether is selected from the hydroxyethyl-cellulose derivant, and its nonionic substitution value is 2.0 to 3.0, the hydrophobic substitution value is 0.3% to 0.8% weight.

3. according to the compositions of claim 2, wherein hydrophobic modified cellulose ether is selected from C ₁₄-C ₁₈The hydroxyethyl-cellulose of alkyl and alkenyl modification, its nonionic substitution value are 2.2 to 2.8, the hydrophobic substitution value is 0.4% to 0.6% weight.

4. according to the compositions of claim 1, wherein the molecular weight of water-soluble polyol is 40 to 200 and has 2 to 6 hydroxyls.

5. according to the compositions of claim 4, wherein water-soluble polyol is selected from glycerol, propylene glycol, Polyethylene Glycol, polypropylene glycol, sorbitol and their mixture.

6. according to the compositions of claim 1, wherein the viscosity of compositions is 1,000 to 50,000 centipoise.

7. according to the compositions of claim 1, wherein the weight average molecular weight of polymeric skin conditioning agent is 2,000 to 5,000,000.

8. according to the compositions of claim 1, the mixture that wherein comprises anion surfactant and zwitterionic surfactant and/or amphoteric surfactant, and wherein anion surfactant, zwitterionic surfactant and amphoteric surfactant content separately is 1% to 15% weight.

9. compositions according to Claim 8 wherein comprises the non-ionic surface active agent of 0.1% to 20% weight, is selected from the oil ﹠ fat of the ethoxylation with following general formula (VIII):

Wherein n is 5 to 200, and wherein R comprises the aliphatic group that on average has 5 to 20 carbon atoms and their mixture.

10. compositions according to Claim 8, wherein anion surfactant is selected from the alkyl sulfate, alkyl glycerol ether sulfonate, methyl-acyl taurine salt, fatty acyl group Glycinates, alkyl ethoxy carboxylate, N-acyl glutamate, acyl isethinate, alkyl sulfo succinate, α-sulfonated fatty acid, their salt and/or their ester, alkyl phosphate, alkyl phosphate, acyl sarcosinates and the fatty acid/protein concentrates of ethoxylation and their mixture of ethoxylation.

11. according to the compositions of claim 10, wherein anion surfactant comprises the C of ethoxylation ₈-C ₂₂Alkyl sulfate.

12. compositions according to Claim 8, wherein amphoteric surfactant is selected from:

(a) imidazolidine derivatives of formula (I):

R wherein ₁Be C ₇-C ₂₂Alkyl or alkenyl, R ₂Be hydrogen or CH ₂Z, each Z are CO independently ₂M or CH ₂CO ₂M, and M is H, alkali metal, alkaline-earth metal, ammonium or alkanol ammonium; And/or Formula Il) ammonium derivative:

R wherein ₁, R ₂With the definition of Z such as above-mentioned;

(b) the amino-alkane hydrochlorate of formula (III):

R ₁NH(CH ₂) _nCO ₂M

The imino group alkanoate of formula (IV):

R ₁N[(CH ₂) _mCO ₂M] ₂

Imino group multichain alkyl salt with formula V:

Wherein, n, m, p and q are the number of 1-4, R ₁Be independently selected from the group of above-mentioned definition with M; With

(c) their mixture.

13. according to the compositions of claim 12, wherein amphoteric surfactant is selected from imidazoline surfactant and/or the ammonium derivative of formula (II) and their mixture of formula (I).

14. according to the compositions of claim 12, wherein anion surfactant: the weight ratio of zwitterionic surfactant and/or amphoteric surfactant is 1: 2 to 6: 1.

15. according to the compositions of claim 10, it also comprises the auxiliary non-ionic surface active agent of 0.1% to 20% weight, this surfactant is selected from C ₁₂-C ₁₄The fatty acid list-and diglycollic amide and polyhydroxy fatty acid amide surfactant.

16. according to the compositions of claim 9, it also comprises the auxiliary non-ionic surface active agent of 0.1% to 20% weight, this surfactant is selected from C ₁₂-C ₁₄The fatty acid list-and diglycollic amide and polyhydroxy fatty acid amide surfactant.

17. according to the compositions of claim 1, it also comprises humidizer, is selected from pyrrolidone sodium carboxylate, L-proline and their mixture.