CN1166382A - Ore-dressing trapping agent - Google Patents

Ore-dressing trapping agent Download PDF

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Publication number
CN1166382A
CN1166382A CN 96116124 CN96116124A CN1166382A CN 1166382 A CN1166382 A CN 1166382A CN 96116124 CN96116124 CN 96116124 CN 96116124 A CN96116124 A CN 96116124A CN 1166382 A CN1166382 A CN 1166382A
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CN
China
Prior art keywords
collecting agent
ore
alkyl
dressing
ether
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 96116124
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Chinese (zh)
Inventor
林乐成
张文学
张则俊
林均国
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MOUPING GOLD MINE YANTAI
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MOUPING GOLD MINE YANTAI
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by MOUPING GOLD MINE YANTAI filed Critical MOUPING GOLD MINE YANTAI
Priority to CN 96116124 priority Critical patent/CN1166382A/en
Publication of CN1166382A publication Critical patent/CN1166382A/en
Pending legal-status Critical Current

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Abstract

The present invention aims at solving the demerits of available composite collecting agent, which is used in case of runaway in floatation operation when the sulfur content is increased. The said trapping agent consists of hydroximic acid (C7-C9) 5-10%, thiamine ether ester or O-alkyl-N-alkyl thioncarbamate 20-30%, dihydroxyl dithiophosphate 40-50% and water 10-35%. It has high ore-dressing enrichment rate and yield and it may be widely used in the floatation of gold containing ore and copper and nickle containing ore.

Description

A kind of beneficiation collecting agent
The present invention relates to a kind of beneficiation collecting agent, particularly a kind of collecting agent that is applicable to the operation of high-sulfur flotation of pyrite.
In the background technology, the collecting agent that is applied to gold containing ore is single xanthate, black powder, in recent years, develop in succession, develop such as main component is the compound collecting agent such as 35# collecting agent, BK301 of hydroximic acid, fourth sodium, these compound collecting agents have certain excellent results in production practices, but are existing certain defective aspect the ore dressing of high-sulfur gold containing ore, that is: when sulfur content increases, flotation operation is " race " groove easily, causes recovery rate in ore-dressing, beneficiation enrichment than low.
The purpose of this invention is to provide a kind of compound flotation operation collecting agent, to improve beneficiation enrichment ratio, recovery rate in ore-dressing effectively.
The present invention implements by following technical solution: this collecting agent is made up of by carbamate, the dihydroxy dithiophosphates of 40-50% and the water of 10-35% the hydroximic acid (C7-C9) of 5-10%, thiamines ether-ether or the O-alkyl-N-alkyl sulfide of 20-30%, the dihydroxy dithiophosphates is selected isobutyl ammonium black powder for use, and O-alkyl-N-alkyl sulfide is selected (second) ethyl ammonia sulfate for use by carbamate.
The present invention has the following advantages and good effect:
1, owing to after hydroximic acid, dihydroxy dithiophosphates and thiamines ether-ether or O-alkyl-N-alkyl sulfide mixed by carbamate, produce ease of solubility preferably, makes valuable mineral produce hydrophobic performance, improved the effect of various compositions.
2, through experiment, use this collecting agent than 35# collecting agent beneficiation enrichment than high by 0.50, recovery rate in ore-dressing improves 1.19%, the low relatively 0.14g/t of tailings grade.
Below with embodiment the present invention is further elaborated.
Embodiment 1: get 5% hydroximic acid, 20% thiamines ether-ether, 40% dihydroxy dithiophosphates add 35% water after evenly mixing under normal temperature, the normal pressure, and stirring and dissolving promptly gets this collecting agent.In flotation operation, an amount of adding, can improve beneficiation enrichment ratio and recovery rate in ore-dressing effectively.
Embodiment 2: get 6% hydroximic acid, 25% thiamines ether-ether, 48% dihydroxy dithiophosphates after evenly mixing under normal temperature, the normal pressure, add 21% water, stirring and dissolving can make collecting agent equally, has same excellent results.

Claims (3)

1, a kind of beneficiation collecting agent is characterized in that this collecting agent is made up of by carbamate, the dihydroxy dithiophosphates of 40-50% and the water of 10-35% thiamines ether-ether or the O-alkyl-N-alkyl sulfide of the hydroximic acid (C7-C9) of 5-10%, 20-30%.
2, a kind of beneficiation collecting agent according to claim 1 is characterized in that described dihydroxy dithiophosphates selects isobutyl ammonium black powder for use.
3, a kind of beneficiation collecting agent according to claim 1 and 2 is characterized in that said O-alkyl-N-alkyl sulfide pursues carbamate and selects (second) ethyl ammonia sulfate for use.
CN 96116124 1996-12-12 1996-12-12 Ore-dressing trapping agent Pending CN1166382A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 96116124 CN1166382A (en) 1996-12-12 1996-12-12 Ore-dressing trapping agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 96116124 CN1166382A (en) 1996-12-12 1996-12-12 Ore-dressing trapping agent

Publications (1)

Publication Number Publication Date
CN1166382A true CN1166382A (en) 1997-12-03

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN 96116124 Pending CN1166382A (en) 1996-12-12 1996-12-12 Ore-dressing trapping agent

Country Status (1)

Country Link
CN (1) CN1166382A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101947497A (en) * 2010-08-10 2011-01-19 磐石市鑫达化工有限责任公司 Copper-nickel sulphide ore floatation collector
CN101698160B (en) * 2009-10-26 2012-07-11 中南大学 Sulfide flotation collector and preparation method
CN102773169A (en) * 2012-08-06 2012-11-14 辽宁科技大学 Collecting agent capable of achieving iron removal during reverse flotation and desiliconization of magnesite ore and preparation method thereof
CN103657872A (en) * 2013-12-03 2014-03-26 安徽朝山新材料股份有限公司 Gold ore collecting agent with high recovery rate and preparation method of gold ore collecting agent
CN103657871A (en) * 2013-12-03 2014-03-26 安徽朝山新材料股份有限公司 Collecting agent for separating gold from auriferous sphalerite and preparation method for collecting agent
CN103657869A (en) * 2013-12-03 2014-03-26 安徽朝山新材料股份有限公司 Collecting agent for copper and gold ores and method for manufacturing collecting agent
CN103657866A (en) * 2013-12-03 2014-03-26 安徽朝山新材料股份有限公司 Gold ore collecting agent and preparation method thereof
CN106513181A (en) * 2016-11-22 2017-03-22 广西大学 Flotation method of sulphide gold containing ores
CN110721816A (en) * 2019-11-12 2020-01-24 中南大学 Hydroximic acid-organic phosphoric acid multi-ligand metal complex collecting agent and preparation method and application thereof
CN116516460A (en) * 2022-01-24 2023-08-01 湖南天童环保有限公司 Process and device for electrocatalytic descaling agent for strip steel

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101698160B (en) * 2009-10-26 2012-07-11 中南大学 Sulfide flotation collector and preparation method
CN101947497A (en) * 2010-08-10 2011-01-19 磐石市鑫达化工有限责任公司 Copper-nickel sulphide ore floatation collector
CN102773169A (en) * 2012-08-06 2012-11-14 辽宁科技大学 Collecting agent capable of achieving iron removal during reverse flotation and desiliconization of magnesite ore and preparation method thereof
CN103657866A (en) * 2013-12-03 2014-03-26 安徽朝山新材料股份有限公司 Gold ore collecting agent and preparation method thereof
CN103657871A (en) * 2013-12-03 2014-03-26 安徽朝山新材料股份有限公司 Collecting agent for separating gold from auriferous sphalerite and preparation method for collecting agent
CN103657869A (en) * 2013-12-03 2014-03-26 安徽朝山新材料股份有限公司 Collecting agent for copper and gold ores and method for manufacturing collecting agent
CN103657872A (en) * 2013-12-03 2014-03-26 安徽朝山新材料股份有限公司 Gold ore collecting agent with high recovery rate and preparation method of gold ore collecting agent
CN103657871B (en) * 2013-12-03 2016-01-13 安徽朝山新材料股份有限公司 A kind of containing golden zincblende capture reagent for gold and preparation method thereof
CN103657866B (en) * 2013-12-03 2016-01-13 安徽朝山新材料股份有限公司 A kind of gold mine collecting agent and preparation method thereof
CN103657872B (en) * 2013-12-03 2016-01-13 安徽朝山新材料股份有限公司 A kind of high-recovery gold mine collecting agent and preparation method thereof
CN103657869B (en) * 2013-12-03 2016-02-17 安徽朝山新材料股份有限公司 A kind of cuproaurite collecting agent and preparation method thereof
CN106513181A (en) * 2016-11-22 2017-03-22 广西大学 Flotation method of sulphide gold containing ores
CN110721816A (en) * 2019-11-12 2020-01-24 中南大学 Hydroximic acid-organic phosphoric acid multi-ligand metal complex collecting agent and preparation method and application thereof
CN110721816B (en) * 2019-11-12 2021-07-27 中南大学 Hydroximic acid-organic phosphoric acid multi-ligand metal complex collecting agent and preparation method and application thereof
CN116516460A (en) * 2022-01-24 2023-08-01 湖南天童环保有限公司 Process and device for electrocatalytic descaling agent for strip steel

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