CN103657871B - A kind of containing golden zincblende capture reagent for gold and preparation method thereof - Google Patents
A kind of containing golden zincblende capture reagent for gold and preparation method thereof Download PDFInfo
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- CN103657871B CN103657871B CN201310635796.3A CN201310635796A CN103657871B CN 103657871 B CN103657871 B CN 103657871B CN 201310635796 A CN201310635796 A CN 201310635796A CN 103657871 B CN103657871 B CN 103657871B
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Abstract
A kind of containing golden zincblende capture reagent for gold, be made up of the raw material of following weight portion: nonyl sodium xanthogenate 18-20, diethyldithiocarbamate 4-7, aluminum sulfate 3-4, ferrous sulfate 3-5, dialkyl succinylsuccinate ester sodium sulfonate 12-15, n-octyl alcohol 12-14, carboxymethyl cellulose 1-2, phenethyl cumenyl phenol polyethenoxy ether 2-3, parabenzoquinone dioxime 12-14, oxine 3-5, activator 10-12; Collecting agent of the present invention has the double action of collecting and foaming, and strong to golden collecting ability, make the gold mine rate of recovery high, to Zn, Fe not collecting, selective good, gold ore grade is high; The activator of the application of the invention, changes gold mine surface hydrophobic, and activation internal structure, improves the collecting performance of collecting agent to gold; Be applicable to choosing gold in zincblende or marmatite.
Description
Technical field
The present invention relates to mineral floating technical field, particularly a kind of containing golden zincblende capture reagent for gold and preparation method thereof.
Background technology
The enrichment method of gold mine is except leaching, and majority selects factory or selective flotation method gold recovering mineral.The collecting agent of better collecting effect is had to have puratized agricultural spray black powder, butyl ammonium aerofloat, catch the floating agents such as Jin Ling, Y-89, M16, QF to gold mineral at present, the collecting ability of conventional flotation medicament to gold mine is stronger, but it is selective poor, the problem that to also exist that gold recovery is low, index fluctuates large, flotation effect is undesirable, the problem that resource utilization is low.
In recent years, the research application that is novel, efficient combination floating agent carried out around improving golden mineral processing index achieves greater advance.Especially the most outstanding to change surname medicament in the investigation and application of new and effective medicament.Medicament modification comprises: introduce in existing medicament and can improve and strengthen the force of reagents and mineral surfaces other active group interactional; Develop individual water-soluble chelating or complexation agent; Select to have different activities and function two kinds and various medicaments combination and mixed reagent.Although the research of gold ore flotation medicament achieves significant progress, but still understand because partially carbonized thing adsorpting formulation in floatation process, or other reason, cause the loss to a certain degree of gold, gold mine samples the problem differed, and causes damage to enterprise and society.
Summary of the invention
The object of this invention is to provide a kind of containing golden zincblende capture reagent for gold and preparation method thereof, this collecting agent has selective good, the advantage that collecting ability is strong.
Technical scheme of the present invention is as follows:
A kind of containing golden zincblende capture reagent for gold, it is characterized in that being made up of the raw material of following weight portion: nonyl sodium xanthogenate 18-20, diethyldithiocarbamate 4-7, aluminum sulfate 3-4, ferrous sulfate 3-5, dialkyl succinylsuccinate ester sodium sulfonate 12-15, n-octyl alcohol 12-14, carboxymethyl cellulose 1-2, phenethyl cumenyl phenol polyethenoxy ether 2-3, parabenzoquinone dioxime 12-14, oxine 3-5, activator 10-12;
Described activator is made up of the raw material of following weight portion: sodium lignin sulfonate 2-3, silane resin acceptor kh-550 1-2, neopelex 2-3, sodium phosphate trimer 1-2, dimethicone 4-5, polyacrylic acid 2-3, HPMA 3-4, water 40-50; Its preparation method is mixed by each raw material, is heated to 60-65 DEG C, stirs 45-60 minute, to obtain final product.
The described preparation method containing golden zincblende capture reagent for gold, it is characterized in that: by other composition mixing except activating agent, at 45-50 DEG C, under 8000-9000 rev/min, stir 10-15 minute, add activator again, stir under 5000-7000 rev/min 20-30 minute and get final product.
Beneficial effect of the present invention
Collecting agent of the present invention has the double action of collecting and foaming, and strong to golden collecting ability, make the gold mine rate of recovery high, to Zn, Fe not collecting, selective good, gold ore grade is high; The activator of the application of the invention, changes gold mine surface hydrophobic, and activation internal structure, improves the collecting performance of collecting agent to gold; Be applicable to choosing gold in zincblende or marmatite.
Detailed description of the invention
A kind of containing golden zincblende capture reagent for gold, be made up of the raw material of following weight portion (kilogram): nonyl sodium xanthogenate 19, diethyldithiocarbamate 6, aluminum sulfate 3.5, ferrous sulfate 4, dialkyl succinylsuccinate ester sodium sulfonate 14, n-octyl alcohol 13, carboxymethyl cellulose 1.5, phenethyl cumenyl phenol polyethenoxy ether 2.5, parabenzoquinone dioxime 13, oxine 4, activator 11;
Described activator is made up of the raw material of following weight portion (kilogram): sodium lignin sulfonate 2.5, silane resin acceptor kh-550 1.5, neopelex 2.5, sodium phosphate trimer 1.5, dimethicone 4.5, polyacrylic acid 2.5, HPMA 3.5, water 45; Its preparation method is mixed by each raw material, is heated to 63 DEG C, stirs 50 minutes, to obtain final product.
The described preparation method containing golden zincblende capture reagent for gold is: by other composition mixing except activating agent, at 47 DEG C, stir 13 minutes, then add activator under 8500 revs/min, stir 25 minutes and get final product under 6000 revs/min.
Experimental data
To head grade 4.80g/t carry out flotation containing golden zincblende stone time, when using this collecting agent, Au thick gold mine productive rate is 19.02%, thick gold ore grade 20.70g/t, Au rate of recovery 82.02% of Au.
Comparative example
To grade identical in specific embodiment carry out flotation containing golden zincblende stone time, use butyl xanthate and QF combination, Au thick gold mine productive rate is 18.97%, thick gold ore grade 20.57g/t, Au rate of recovery 77.30% of Au.
Find out that the collecting agent collecting ability of the embodiment of the present invention is strong, selective good from above data.
Claims (2)
1., containing a golden zincblende capture reagent for gold, it is characterized in that being made up of the raw material of following weight portion: nonyl sodium xanthogenate 18-20, diethyldithiocarbamate 4-7, aluminum sulfate 3-4, ferrous sulfate 3-5, dialkyl succinylsuccinate ester sodium sulfonate 12-15, n-octyl alcohol 12-14, carboxymethyl cellulose 1-2, phenethyl cumenyl phenol polyethenoxy ether 2-3, parabenzoquinone dioxime 12-14, oxine 3-5, activator 10-12;
Described activator is made up of the raw material of following weight portion: sodium lignin sulfonate 2-3, silane resin acceptor kh-550 1-2, neopelex 2-3, sodium phosphate trimer 1-2, dimethicone 4-5, polyacrylic acid 2-3, HPMA 3-4, water 40-50; Each raw material mixes by the preparation method of described activator, is heated to 60-65 DEG C, stirs 45-60 minute, to obtain final product.
2. the preparation method containing golden zincblende capture reagent for gold according to claim 1, it is characterized in that: by other composition mixing except activating agent, at 45-50 DEG C, 10-15 minute is stirred under 8000-9000 rev/min, add activator again, stir under 5000-7000 rev/min 20-30 minute and get final product.
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CN103657871A CN103657871A (en) | 2014-03-26 |
CN103657871B true CN103657871B (en) | 2016-01-13 |
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CN110605184B (en) * | 2019-05-30 | 2021-11-30 | 核工业北京化工冶金研究院 | Flotation collector for uranium asphalt ore and application thereof |
CN115634777B (en) * | 2022-10-31 | 2023-06-20 | 江西省宜丰万国矿业有限公司 | Flotation method for improving recovery rate of associated gold and silver in lead zinc sulfide ore |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1166382A (en) * | 1996-12-12 | 1997-12-03 | 烟台市牟平金矿 | Ore-dressing trapping agent |
RU2185249C1 (en) * | 2000-11-21 | 2002-07-20 | Красноярская государственная академия цветных металлов и золота | Process of flotation of sulfide gold-containing ores |
RU2280509C1 (en) * | 2005-02-21 | 2006-07-27 | Открытое акционерное общество "Ново-Широкинский рудник" | Method of flotation of the polymetallic gold-carrying ores |
CN102806149A (en) * | 2012-08-03 | 2012-12-05 | 西北矿冶研究院 | Collecting agent for low-grade refractory gold ores |
CN103350036A (en) * | 2013-06-29 | 2013-10-16 | 西北矿冶研究院 | Collecting agent for refractory gold ores |
-
2013
- 2013-12-03 CN CN201310635796.3A patent/CN103657871B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1166382A (en) * | 1996-12-12 | 1997-12-03 | 烟台市牟平金矿 | Ore-dressing trapping agent |
RU2185249C1 (en) * | 2000-11-21 | 2002-07-20 | Красноярская государственная академия цветных металлов и золота | Process of flotation of sulfide gold-containing ores |
RU2280509C1 (en) * | 2005-02-21 | 2006-07-27 | Открытое акционерное общество "Ново-Широкинский рудник" | Method of flotation of the polymetallic gold-carrying ores |
CN102806149A (en) * | 2012-08-03 | 2012-12-05 | 西北矿冶研究院 | Collecting agent for low-grade refractory gold ores |
CN103350036A (en) * | 2013-06-29 | 2013-10-16 | 西北矿冶研究院 | Collecting agent for refractory gold ores |
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