CN116575174A - Anti-ultraviolet knitted fabric and weaving method thereof - Google Patents
Anti-ultraviolet knitted fabric and weaving method thereof Download PDFInfo
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- CN116575174A CN116575174A CN202310849565.6A CN202310849565A CN116575174A CN 116575174 A CN116575174 A CN 116575174A CN 202310849565 A CN202310849565 A CN 202310849565A CN 116575174 A CN116575174 A CN 116575174A
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- ultraviolet
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- rare earth
- resistant
- knitted fabric
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- 239000004744 fabric Substances 0.000 title claims abstract description 55
- 238000009941 weaving Methods 0.000 title claims abstract description 18
- 238000000034 method Methods 0.000 title abstract description 18
- 239000004677 Nylon Substances 0.000 claims abstract description 38
- 229920001778 nylon Polymers 0.000 claims abstract description 38
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 34
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 34
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 17
- 229920002334 Spandex Polymers 0.000 claims abstract description 16
- 239000004759 spandex Substances 0.000 claims abstract description 16
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000009940 knitting Methods 0.000 claims abstract description 11
- 229910001954 samarium oxide Inorganic materials 0.000 claims abstract description 6
- 229940075630 samarium oxide Drugs 0.000 claims abstract description 6
- FKTOIHSPIPYAPE-UHFFFAOYSA-N samarium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Sm+3].[Sm+3] FKTOIHSPIPYAPE-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000005516 engineering process Methods 0.000 claims description 5
- 230000006750 UV protection Effects 0.000 abstract description 15
- 230000035699 permeability Effects 0.000 abstract description 13
- 238000004383 yellowing Methods 0.000 abstract description 11
- 238000005406 washing Methods 0.000 abstract description 10
- 230000037303 wrinkles Effects 0.000 abstract description 4
- 230000003115 biocidal effect Effects 0.000 abstract 1
- 230000000638 stimulation Effects 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 description 12
- 238000001514 detection method Methods 0.000 description 12
- 239000004753 textile Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- 230000006870 function Effects 0.000 description 8
- -1 lanthanide metals Chemical class 0.000 description 7
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 6
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 229920002994 synthetic fiber Polymers 0.000 description 4
- 239000012209 synthetic fiber Substances 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 230000001153 anti-wrinkle effect Effects 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 230000008676 import Effects 0.000 description 3
- 230000007794 irritation Effects 0.000 description 3
- 238000002074 melt spinning Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- 229910000420 cerium oxide Inorganic materials 0.000 description 2
- 230000035597 cooling sensation Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 229910001940 europium oxide Inorganic materials 0.000 description 2
- AEBZCFFCDTZXHP-UHFFFAOYSA-N europium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Eu+3].[Eu+3] AEBZCFFCDTZXHP-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229910001938 gadolinium oxide Inorganic materials 0.000 description 2
- 229940075613 gadolinium oxide Drugs 0.000 description 2
- CMIHHWBVHJVIGI-UHFFFAOYSA-N gadolinium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Gd+3].[Gd+3] CMIHHWBVHJVIGI-UHFFFAOYSA-N 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000004224 protection Effects 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 210000004243 sweat Anatomy 0.000 description 2
- PFHLGILELJGQSJ-UHFFFAOYSA-N 4-(2h-benzotriazol-4-ylmethyl)-2h-benzotriazole;2-butyl-3,4,5,6-tetramethylphenol Chemical compound CCCCC1=C(C)C(C)=C(C)C(C)=C1O.C=1C=CC=2NN=NC=2C=1CC1=CC=CC2=C1N=NN2 PFHLGILELJGQSJ-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 208000002177 Cataract Diseases 0.000 description 1
- 241001391944 Commicarpus scandens Species 0.000 description 1
- 229920004934 Dacron® Polymers 0.000 description 1
- 239000005892 Deltamethrin Substances 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 208000000453 Skin Neoplasms Diseases 0.000 description 1
- 206010070835 Skin sensitisation Diseases 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 229920002978 Vinylon Polymers 0.000 description 1
- 241000212749 Zesius chrysomallus Species 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- RWZYAGGXGHYGMB-UHFFFAOYSA-N anthranilic acid Chemical compound NC1=CC=CC=C1C(O)=O RWZYAGGXGHYGMB-UHFFFAOYSA-N 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000009194 climbing Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010227 cup method (microbiological evaluation) Methods 0.000 description 1
- 229960002483 decamethrin Drugs 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- QILSFLSDHQAZET-UHFFFAOYSA-N diphenylmethanol Chemical compound C=1C=CC=CC=1C(O)C1=CC=CC=C1 QILSFLSDHQAZET-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 208000026278 immune system disease Diseases 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000011858 nanopowder Substances 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 230000019612 pigmentation Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 231100000370 skin sensitisation Toxicity 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/16—Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/106—Radiation shielding agents, e.g. absorbing, reflecting agents
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
- D10B2321/022—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polypropylene
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/04—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of halogenated hydrocarbons
- D10B2321/041—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of halogenated hydrocarbons polyvinyl chloride or polyvinylidene chloride
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/06—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated alcohols, e.g. polyvinyl alcohol, or of their acetals or ketals
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/10—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/22—Physical properties protective against sunlight or UV radiation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
- Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Knitting Of Fabric (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses an anti-ultraviolet knitted fabric which is characterized in that, by weight, 6 parts of lanthanum oxide, 5 parts of samarium oxide and 86 parts of nylon carrier are firstly mixed to prepare rare earth anti-ultraviolet master batch, and then 7 parts of master batch and 93 parts of nylon chips are melt-spun to prepare rare earth anti-ultraviolet yarn; and knitting and weaving the rare earth ultraviolet resistant yarn and spandex. The knitted fabric prepared by the method has the excellent performances of ultraviolet resistance, cool feel, moisture permeability, antibiosis, washing resistance, wrinkle resistance, yellowing resistance, mild skin, no stimulation and the like.
Description
Technical Field
The invention relates to the technical field of textile industry, in particular to an ultraviolet-resistant knitted fabric and a weaving method thereof.
Background
Altitude of the plateau area is relatively high, and attenuation effect of the atmosphere on ultraviolet rays is relatively less than that of the plateau area with low altitude; the human smoke is rare, the industrial pollution is avoided, the air is cleaner, and the ultraviolet rays in sunlight are less absorbed; the snow on the plateau has long period and high reflectivity on the snow surface; all three factors enhance the radiation intensity of ultraviolet rays to human bodies. The ultraviolet reflectance at sea is high, sand and sand at sea mutually reflect, the reflection of ultraviolet rays can reach 15-20%, the reflection of seawater is as high as 100% like a mirror, the ultraviolet reflectance of grasslands is less than 5%, grasslands and trees can absorb sunlight for photosynthesis, and asphalt is higher than that of grasslands but not more than 10% in terms of ultraviolet reflectance; the air at sea and the sea is good, and the ultraviolet ray is high in direct incidence; the skin content water rises, so that ultraviolet rays are easier to absorb; these three aspects result in the human body being exposed to very intense ultraviolet radiation at sea and at sea. Ozone absorbs ultraviolet light, so that the ozone layer cavity can cause the increase of ultraviolet radiation; in the ozone layer cavity area, high intensity ultraviolet radiation can pose a great threat to human health.
In recent years, outdoor exercises are popular worldwide, and have become a mainstream exercise form. When people are engaged in mountain climbing, outdoor activities in high altitude areas, maritime play, maritime sports amusement projects and extreme exercises in special areas, the human body is beneficial to health due to the fact that the human body is properly irradiated by ultraviolet rays, and when the human body is subjected to excessive ultraviolet rays in UVB sections, red spots, blisters and burns, even skin cancers, cataracts, immune system disorders and the like are generated; uv light in the UVA range activates melanin in the skin, causing pigmentation, thereby forming black spots. The protection of ultraviolet rays is becoming more and more important for people in outdoor exercises in special areas such as high altitude areas, seasides, ozone layer cavities and the like. With the rapid development of these outdoor exercises and the increasing tendency of outdoor exercise garments, there is a need for ultra-high ultraviolet resistant outdoor exercise garments having ultra-high UPF values and full-band ultraviolet absorption.
Knitted fabrics are classified into warp knitted fabrics and weft knitted fabrics. Weft knitting fabrics generally have good elasticity and extensibility, soft, firm and crease-resistant fabrics, and are easy to wash and dry, but the fabrics are poor in hygroscopicity, stiff and smooth, and easy to break loose, curled, fuzzed, pilled and hooked. Warp knitted fabrics have good air permeability, smoothness, flatness, easy care, ironing, stable structure and difficult detachment, so the warp knitted fabrics are commonly used for manufacturing sportswear, such as swimwear, track and field wear, gymnastics wear, basketball wear and the like, are convenient to stretch in the process of sports and have excellent comfortableness.
With outdoor exercises and the improvement of comfort and functionality, consumers pay more attention to the functionality of the fabric, such as the continuous improvement of performance requirements on ultraviolet resistance, moisture absorption, quick drying, cool feeling, antibacterial and deodorizing of the fabric in the exercise process. For the clothing fabric for outdoor exercises, the ultraviolet-proof and cool feeling functions are particularly emphasized.
Patent document CN103290613a discloses a soft warp knitted fabric, which is woven by warp knitting, and achieves comfort and aesthetic feeling of the knitted fabric, but does not have ultraviolet resistance or sun-screening function.
Patent document CN107868987B discloses a preparation method of an anti-ultraviolet anti-aging insect-resistant fiber, wherein the functional components are complexes formed by lanthanide metals and monobasic organic compounds or complexes formed by polybasic organic compounds, permethrin and deltamethrin. The ultraviolet protection coefficients of the fibers prepared in examples 1-3 were all 50, which still had some room for improvement.
Patent document CN112899801a discloses an anti-ultraviolet aging-resistant synthetic fiber added with rare earth, and a preparation method and application thereof, which not only can keep anti-ultraviolet efficacy for a long time, but also can prevent aging, but also has more complex functional components, namely, a mixture of rare earth oxides such as cerium oxide, yttrium oxide, samarium oxide, gadolinium oxide and the like, inorganic oxides such as silicon dioxide, ferric oxide and the like, benzophenone, salicylic acid, anthranilone, benzhydrol polymerization hindered amine, methylenebis-benzotriazole tetramethylbutylphenol and the like; and the ultraviolet protection coefficient of the fiber prepared in examples 1-3 is 100, which can not well meet the requirements of outdoor sportswear in special areas such as high altitude areas, offshore seasides, ozone layer cavities and the like, and further needs to improve the UPF value and realize full-band ultraviolet absorption.
In the prior art, a method for preparing the textile fabric by adding the ultraviolet resistant auxiliary agent into the master batch is also available. The common anti-ultraviolet auxiliary agent of the master batch comprises organic anti-ultraviolet agents such as benzophenone, salicylate, anthranilate and the like, strongly absorbs ultraviolet light, is well fused with a polymer and has small influence on the mechanical properties of fibers, but has the defects of poor fastness, toxicity of substances generated by molecular chain breakage after absorbing ultraviolet light, and serious influence on human health. The anti-ultraviolet auxiliary agent added in the master batch also comprises inorganic anti-ultraviolet auxiliary agents such as nano titanium dioxide, zinc oxide and the like, can resist high temperature, has good stability, has no irritation to human bodies, basically has no problems of decomposition and the like, but has common absorption and anti-ultraviolet performance in partial wave bands, and can destroy the lasting performance of the anti-ultraviolet after long shielding time.
Disclosure of Invention
In order to solve the problem that outdoor sportswear in special areas such as high altitude areas, seaside, ozone layer holes and the like has requirements for ultra-high UPF values and full-band ultraviolet-absorbing knitted fabrics, and in view of the defects in the prior art: the ultraviolet-resistant knitted fabric disclosed by the invention can effectively solve the technical problems, and the ultraviolet-resistant knitted fabric cannot achieve ultraviolet resistance, cooling sensation, moisture permeability, antibacterial property, washing resistance, yellowing resistance and crease resistance at the same time and still has a large improvement space for the performances.
The invention also discloses a weaving method of the ultraviolet-resistant knitted fabric, which improves the performances of ultraviolet resistance, cool feel, moisture permeability, antibacterial property, washing resistance, yellowing resistance, wrinkle resistance and the like of the fabric.
The specific technical scheme of the invention is as follows:
firstly, 10-20 parts by weight of rare earth oxide and 75.5-88 parts of synthetic fiber carrier are blended to prepare rare earth anti-ultraviolet master batch, and then 4-9 parts of master batch and 91-96 parts of synthetic fiber slices are melt spun to prepare rare earth anti-ultraviolet yarn; and knitting and weaving the rare earth ultraviolet resistant yarn and the textile fiber material.
In some embodiments, 45-75 parts of the rare earth ultraviolet resistant yarn is knitted with 25-55 parts of textile fiber material.
In some embodiments, the rare earth oxide is selected from one or more of cerium oxide, gadolinium oxide, lanthanum oxide, europium oxide, neodymium oxide, samarium oxide.
In some embodiments, the rare earth oxide is nanoscale, nanopowder D 100 Less than 200nm. The nano rare earth oxide can make the knitted fabric have more excellent performance.
In some embodiments, the synthetic fiber carrier is selected from one or more of dacron, nylon, spandex, vinylon, polypropylene, and polyvinyl chloride. Preferably one or more carriers selected from terylene, nylon and spandex.
In some embodiments, the yarn has a thickness of 20d to 40d. The coarser yarn can affect the cloth cover effect of the knitted fabric, so that the finished product effect cannot reach the optimal appearance.
In some embodiments, the textile fiber material is selected from one or more of polyester, nylon, spandex, velcro, polypropylene, and chloraman yarns.
In some embodiments, the knitted fabric is weft knitting using a high gauge high density weaving process.
In some embodiments, the knitted fabric is warp knitted using a high gauge high density weaving process.
The beneficial effects of the invention are as follows:
according to the invention, by designing the master batch formula and only adding rare earth oxide as an ultraviolet absorbent, the rare earth ultraviolet-resistant polyester yarn, rare earth ultraviolet-resistant nylon yarn, rare earth ultraviolet-resistant spandex yarn and other differentiated yarns are prepared, ultraviolet is absorbed in a full wave band and light conversion is continued, and the master batch is light-resistant, acid-resistant, alkali-resistant and high-temperature-resistant, not easy to decompose and long-term effective, so that extremely excellent ultraviolet-resistant effects are achieved; meanwhile, the product has good antibacterial effect and does not irritate the skin. The rare earth material has strong capability of capturing hydroxyl, and enhances the moisture absorption and sweat release functions of the cloth and the cool feeling brought by the moisture absorption and sweat release functions. In addition, the spinning performance is good, and the production cost is reduced.
Meanwhile, the function of the ultra-high ultraviolet resistant knitted fabric has great relation with the weaving mode. The invention is directly knitted by adopting the yarn with the ultraviolet-resistant function instead of the common coating or finishing mode, which ensures the air permeability and moisture permeability of the fabric and realizes the purpose of lasting and effective ultraviolet-resistant function. The warp knitted fabric adopts high-needle-number high-density weaving equipment and technology, is fine and compact, has soft skin, and improves the ultraviolet resistance of the knitted fabric.
Detailed Description
The invention is further described below in order to make the technical means, the inventive features, the achievement of the purpose and the effect of the implementation of the invention easy to understand. The present invention is not limited to the following examples.
It should be understood that the disclosure of the present invention is not limited to the specific conditions for implementing the present invention, and any structural modifications, proportional changes or size adjustments may be made without affecting the efficacy and achievement of the present invention, and still fall within the scope of the disclosure.
One or more yarns of the polyester, nylon, spandex, velcro, polypropylene, and polyvinyl chloride disclosed in the present invention may be produced by a person skilled in the art by a conventional method.
Example 1
The ultra-high anti-ultraviolet knitted fabric is knitted by rare earth anti-ultraviolet nylon yarns and spandex yarns; the rare earth anti-ultraviolet nylon yarn is prepared by firstly blending 18 parts of lanthanum oxide, 2 parts of europium oxide and 76 parts of nylon carrier to prepare rare earth anti-ultraviolet master batch, and then melt spinning 6 parts of master batch and 94 parts of nylon chips. The rare earth anti-ultraviolet nylon yarn is 20D.
The weaving method of the rare earth ultraviolet-resistant knitted fabric comprises the following steps: the German import KARL MAYER machine equipment is adopted, high-needle-number high-density equipment and technology are adopted, rare earth ultraviolet-resistant antibacterial nylon yarns 20D FDY 74%, spandex yarns 24% and nylon yarns 2% in the rest are adopted, and the warp knitting is performed for 44 needles.
Example 2
The ultra-high anti-ultraviolet knitted fabric is knitted by rare earth anti-ultraviolet nylon yarns and spandex yarns; the rare earth anti-ultraviolet nylon yarn is prepared by blending 6 parts of lanthanum oxide, 5 parts of samarium oxide and 86 parts of nylon carrier to prepare rare earth anti-ultraviolet master batch, and then melt spinning 7 parts of master batch and 93 parts of nylon chips. The rare earth anti-ultraviolet nylon yarn is 40D.
The weaving method of the rare earth ultraviolet-resistant knitted fabric comprises the following steps: the German import KARL MAYER machine equipment is adopted, high-needle-number high-density equipment and technology are adopted, rare earth ultraviolet-resistant antibacterial nylon yarn 40D DTY 74%, spandex yarn 24% and nylon yarn 2% in the rest are adopted, and warp knitting is carried out on 44 needles.
Comparative example 1
The common knitted fabric is knitted by common nylon yarns and spandex yarns; the common nylon yarn is 20D.
The weaving method of the common knitted fabric comprises the following steps: using german inlet KARL MAYER machine equipment, using high gauge high density equipment and process, using common nylon yarn 20d FDY 74%, spandex yarn 24%, the remaining 2% being nylon yarn, warp knitting 44 needles.
Comparative example 2
The ultraviolet-resistant knitted fabric is knitted by rare earth ultraviolet-resistant nylon yarns and spandex yarns; the rare earth anti-ultraviolet nylon yarn is prepared by blending 6 parts of lanthanum oxide, 5 parts of samarium oxide and 86 parts of nylon carrier to prepare rare earth anti-ultraviolet master batch, and then melt spinning 7 parts of master batch and 93 parts of nylon chips. The rare earth anti-ultraviolet nylon yarn is 40D.
The weaving method of the rare earth ultraviolet-resistant knitted fabric comprises the following steps: the German import KARL MAYER machine equipment is adopted, high-needle-number high-density equipment and technology are adopted, rare earth ultraviolet-resistant antibacterial nylon yarn 40D DTY 74%, spandex yarn 24% and nylon yarn 2% in the rest are adopted, and 36 needles are warp-knitted.
The knitted fabrics prepared in the examples and the comparative examples are subjected to washing 50 times without water and are subjected to washing according to GB/T24218.1-2009, part 1 of a test method for textile non-woven fabrics: the measurement of unit area quality is used for gram weight detection, ultraviolet resistance detection is carried out according to GB/T18830-2009 'evaluation of ultraviolet resistance of textiles', yellowing resistance detection is carried out according to GB/T30689-2014 'light yellowing resistance fastness of textile color fastness test', contact instant cool feeling detection is carried out according to GB/T35263-2017 'detection and evaluation of textile contact instant cool feeling performance', moisture permeability detection is carried out according to GB/T12704-1991 'moisture permeability cup method of fabric moisture permeability measurement method', antibacterial detection is carried out according to ASTM E2149-2013 a 'antibacterial behavior of steady-state antibacterial agent measured under dynamic contact condition', anti-wrinkle detection is carried out according to GB/T3819-1997 'determination return angle method of crease recovery of textile fabric', and the performance detection results are shown in tables 1 and 2 respectively.
TABLE 1 detection results of anti-UV, anti-yellowing, cool feel, moisture permeability, antibacterial, anti-wrinkle Properties (no washing)
TABLE 2 detection results of anti-UV, anti-yellowing, cool feeling, moisture permeability, antibacterial, anti-wrinkle Properties (after 50 times of washing)
The knitted fabrics prepared in all examples were evaluated according to ISO 10993-10:2010 medical device biology evaluation-part 10: stimulus and skin sensitization test skin irritation tests were performed and the test results are shown in table 3.
TABLE 3 skin irritation test results
As can be seen from the test results shown in Table 1 and Table 2, the knitted fabric obtained in examples 1 to 2 has excellent properties of ultraviolet resistance, yellowing resistance, cooling sensation, moisture permeability, antibacterial property and wrinkle resistance, and UPF in example 2 AV The value is up to 1000+, and after 50 times of washing, each performance of the knitted fabric is basically unchanged, which shows that the durability is superior.
The knitted fabric produced in comparative example 1 did not have the anti-uv function and yellowing resistance even without water washing. The knitted fabric prepared in the comparative example 2 has the effects of ultraviolet resistance and yellowing resistance, and the ultraviolet resistance of the fabric is greatly reduced by adopting a 36-needle weaving method compared with that of a 44-needle high-density weaving method. As can be seen from the detection results in Table 3, the knitted fabric prepared in examples 1-2 is mild, has no irritation to skin, and is safe and reliable.
The advantages of the knitted fabric of the invention are summarized as follows:
(1) Has excellent anti-ultraviolet capability and UPF AV Values up to 1000+;
(2) The ultraviolet resistance has durability, and the excellent ultraviolet resistance can be still maintained after washing for 50 times;
(3) The product has multiple effects of resisting ultraviolet and yellowing, cooling sense, moisture permeability, bacteria resistance, wrinkle resistance and the like;
(4) Has no toxicity or irritation, mild skin and good safety.
The foregoing describes in detail preferred embodiments of the present invention. It should be understood that numerous modifications and variations can be made in accordance with the concepts of the invention without requiring creative effort by one of ordinary skill in the art. Therefore, all technical solutions which can be obtained by logic analysis, reasoning or limited experiments based on the prior art by the person skilled in the art according to the inventive concept shall be within the scope of protection defined by the claims.
Claims (1)
1. The ultraviolet-resistant knitted fabric is characterized in that, by weight, 6 parts of lanthanum oxide, 5 parts of samarium oxide and 86 parts of nylon carrier are firstly blended to prepare rare earth ultraviolet-resistant master batch, and then 7 parts of master batch and 93 parts of nylon chips are melt-spun to prepare rare earth ultraviolet-resistant nylon yarn 40D DTY; knitting and weaving the rare earth ultraviolet resistant nylon yarn 40D DTY and spandex yarn, wherein the knitting and weaving are warp knitting 44 needles;
the ultraviolet-resistant knitted fabric adopts high-needle-number high-density equipment and technology, uses 40D DTY 74% of rare earth ultraviolet-resistant nylon yarns, 24% of spandex yarns and the balance of 2% of nylon yarns.
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