CN116575106A - Electrochemical treatment auxiliary equipment and method for hollow metal interventional instrument - Google Patents

Electrochemical treatment auxiliary equipment and method for hollow metal interventional instrument Download PDF

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Publication number
CN116575106A
CN116575106A CN202310582765.XA CN202310582765A CN116575106A CN 116575106 A CN116575106 A CN 116575106A CN 202310582765 A CN202310582765 A CN 202310582765A CN 116575106 A CN116575106 A CN 116575106A
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China
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hollow metal
electrolyte
flow
electrochemical treatment
guide plates
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CN202310582765.XA
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Chinese (zh)
Inventor
喻凌峰
王晓辉
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Guichuang Tongqiao Medical Technology Co ltd
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Guichuang Tongqiao Medical Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25FPROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
    • C25F7/00Constructional parts, or assemblies thereof, of cells for electrolytic removal of material from objects; Servicing or operating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)

Abstract

The invention discloses electrochemical treatment auxiliary equipment and a method for hollow metal interventional instruments, which relate to the technical field of biomedical materials and comprise a servo control system, a cooling system, an electrolyte circulation flow system, a cantilever mechanism and an electrolytic tank, wherein the servo control system is used for adjusting the vertical displacement of the cantilever mechanism and electrolytic polishing parameters, the cooling system is used for controlling the temperature of electrolyte, the electrolyte circulation flow system is used for stirring and controlling the flow direction of the electrolyte to form a circulation flow, a clamping tool used for horizontally supporting hollow metal is arranged on the cantilever mechanism, an anode wire used for penetrating through an inner cavity of the hollow metal is arranged on the clamping tool, the electrolyte circulation flow system comprises a stirrer and a flow guiding member used as a cathode, the stirrer is used for driving the electrolyte to flow, and the flow guiding member is arranged in the electrolytic tank and is used for guiding the electrolyte and forming an electrolyte flow stream parallel to the axis of the hollow metal. The hollow metal inner and outer surfaces of the invention have even polishing and good polishing quality.

Description

Electrochemical treatment auxiliary equipment and method for hollow metal interventional instrument
Technical Field
The invention relates to the technical field of biomedical materials, in particular to electrochemical treatment auxiliary equipment and method for a hollow metal interventional instrument.
Background
Interventional therapy is a main minimally invasive method for treating vascular obstruction diseases, and interventional instruments such as stents, catheters, guide wires, embolism and the like are gradually becoming the focus of research as key components of interventional therapy.
The interventional device formed by the laser engraving process occupies a large specific gravity, and after the interventional device is subjected to laser cutting or heat treatment shaping, the surface of the interventional device has defects such as pits, scratches, burrs, oxide layers and the like, if the interventional device is directly implanted into a human body without treatment, blood platelets in blood vessels can be adhered, thrombus and intimal hyperplasia are easy to form, or blood vessels are easy to scratch when the thrombus is removed mechanically through an intracranial thrombus removal bracket. In particular, cardiac stents have a higher requirement for surface roughness, and thus, the cut or heat treated stents also require polishing processes.
Research shows that during electrolytic polishing, the stirring of the electrolyte can often improve the polishing quality, because the electrolyte can update the polishing liquid near the surface of the anode, the temperature of the polishing liquid is more uniform, the local overheating of the metal surface is prevented, and the dissolution speed of a mucous membrane is accelerated, so that the polishing speed is improved; meanwhile, bubbles remained on the surface of the metal can be removed by stirring, so that pits or stripes can be eliminated.
In the prior art, for example, patent application publication No. WO2010081723A1, the inventor is WulfElena, and the electrolyte stirring method disclosed in the patent application is to vertically submerge a support in the center of a polishing container filled with polishing liquid, wherein the support is used as an anode, and a spiral cathode is close to the wall of the polishing container; the bottom of the polishing container is provided with a magnetic stirrer, and the polishing electrolyte is driven to rotate by a rotor, so that an electrolyte circulation flow flowing along the radial direction of the wall of the polishing container is generated. However, by means of the magnetic stirring mode, the flowing of electrolyte on the inner surface of the support is relatively slow, and the interaction of ions on the outer surface of the support is caused, so that the polishing removal amount of the inner surface of the support is insufficient, and the polishing quality of the inner surface is poor. The polishing tank disclosed by the inventor is provided with a stirring mechanism, wherein the stirring mechanism comprises a base arranged at the bottom of the polishing tank, a motor, a rotating rod and stirring impeller blades arranged on the rotating rod, the rotating rod penetrates through the bottom of the polishing tank, the stirring impeller blades are positioned in polishing electrolyte, and a polished support is vertically immersed in the polishing electrolyte; in the patent application, the stirring mechanism is arranged, so that the flowing speed of the polishing electrolyte is enhanced, and an axially flowing electrolyte circulating flow is generated, so that the polishing electrolyte is uniformly distributed, and the polishing efficiency is accelerated; however, the electrolyte circulation flow formed by the stirring mechanism and the polishing support form an included angle, so that the inner surface of the support cannot be well and uniformly flushed, the polishing removal amount of part of the surface in the support is insufficient, and the inner surface of the support is finally uneven in polishing and poor in polishing quality.
Disclosure of Invention
The invention aims to provide electrochemical treatment auxiliary equipment and method for a hollow metal interventional instrument, which are used for solving the problems in the prior art, and the inner and outer surfaces of the hollow metal are polished uniformly and have good polishing quality.
In order to achieve the above object, the present invention provides the following solutions:
the invention provides electrochemical treatment auxiliary equipment for a hollow metal interventional instrument, which comprises a servo control system, a cooling system, an electrolyte circulation flow system, a cantilever mechanism and an electrolytic tank, wherein the servo control system is used for adjusting the vertical displacement of the cantilever mechanism and electrolytic polishing parameters, the cooling system is used for controlling the temperature of electrolyte in the electrolytic tank, the electrolyte circulation flow system is used for stirring and controlling the flow direction of the electrolyte in the electrolytic tank to form a circulation flow, a clamping tool used for horizontally supporting the hollow metal is arranged on the cantilever mechanism, an anode wire used for penetrating through a cavity of the hollow metal is arranged on the clamping tool, the hollow metal can be immersed into the electrolyte through the cantilever mechanism, the electrolyte circulation flow system comprises a stirrer and a flow guiding component used as a cathode, and the stirrer is used for driving the electrolyte to flow and is arranged in the electrolytic tank and used for guiding the electrolyte and forming an electrolyte flow beam parallel to the axis of the hollow metal.
Preferably, the agitator comprises an impeller and an agitator motor for driving the impeller in rotation.
Preferably, the guide member comprises two first guide plates parallel to each other, the same ends of the two first guide plates are connected through an arc guide plate and a second guide plate, the first guide plates and the second guide plates are of flat plate structures, the first guide plates, the second guide plates and the arc guide plates are perpendicular to the bottom surface of the electrolytic tank, the second guide plates are tangential to the arc guide plates, the two arc guide plates are diagonally arranged and are oppositely arranged in the opening direction, and each arc guide plate is internally provided with an impeller.
Preferably, the cooling system comprises a cooling tank, a compressor and a circulating pump, wherein the electrolytic tank is arranged in a water bath environment of the cooling tank, a heat exchange tube is arranged in the cooling tank, a heat exchange medium is arranged in the heat exchange tube, and two ends of the heat exchange tube are connected with the circulating pump through the compressor to form a circulating loop.
Preferably, the cantilever mechanism is provided with two clamping tools for horizontally supporting two hollow metals respectively.
Preferably, a cover plate is arranged at the top end of the electrolytic tank, two through holes corresponding to the two clamping tools are arranged on the cover plate respectively, the clamping tools submerge hollow metal into electrolyte through the through holes, and the stirring motor is connected to the cover plate.
Preferably, the number of the stirrers is more than 2; at this time, the stirrers are arranged in one of S-shaped array, symmetrical arrangement and common tangent arrangement. It will be appreciated that arranging a number of said agitators in said arrangement is beneficial in driving a horizontally uniform circulating flow of electrolyte.
Preferably, when the number of agitators is 2 or more, the rotational speeds of the agitators are set to form a rotational speed difference, that is, there is a first rotational speed of the agitators having the same rotational direction that is greater than a second rotational speed of the agitators. It will be appreciated that the presence of a rotational speed differential is beneficial to the remixing of the electrolyte.
Preferably, the flow guiding member is made of stainless steel.
The invention also provides an electrochemical treatment method for the hollow metal interventional instrument, which adopts the electrochemical treatment auxiliary equipment for the hollow metal interventional instrument and comprises the following steps of:
s1: the hollow metal is horizontally supported through the clamping tool, the anode wire penetrates through the hollow metal cavity, the height of the cantilever mechanism is adjusted through the servo control system, and the hollow metal is immersed into electrolyte in the electrolytic tank;
s2, adjusting electrolytic polishing parameters, enabling electrolyte to flow in an axial direction inside and outside the hollow cavity of the hollow metal, and uniformly flushing the inner surface and the outer surface of the hollow metal, and uniformly electropolishing the inner surface and the outer surface of the hollow metal.
Compared with the prior art, the invention has the following technical effects:
the invention provides electrochemical treatment auxiliary equipment and method for a hollow metal interventional instrument, wherein an electrolyte flow beam parallel to the axis of the hollow metal is formed through a stirrer and a flow guide member, so that the inner and outer surfaces of the hollow metal are uniformly flushed, the inner and outer surfaces of the hollow metal are uniformly polished, and the polishing quality is improved.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings that are needed in the embodiments will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and other drawings may be obtained according to these drawings without inventive effort for a person skilled in the art.
FIG. 1 is a schematic view of an electrochemical treatment assistance device for a hollow metal interventional instrument according to the present invention;
FIG. 2 is a schematic view of the structural positions of a flow guiding member, an impeller and an electrolytic tank in the invention;
FIG. 3 is a top view of FIG. 2;
in the figure: the device comprises a 1-cantilever mechanism, a 2-electrolytic tank, a 3-clamping tool, 4-hollow metal, 5-anode wires, a 6-stirrer, 7-flow guiding components, 8-impellers, 9-stirring motors, 10-first flow guiding plates, 11-arc-shaped flow guiding plates, 12-second flow guiding plates, 13-cooling tanks, 14-cover plates and 15-through holes.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely with reference to the accompanying drawings, in which it is apparent that the embodiments described are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
The invention aims to provide electrochemical treatment auxiliary equipment and method for a hollow metal interventional instrument, which are used for solving the problems in the prior art, and the inner and outer surfaces of the hollow metal are polished uniformly and have good polishing quality.
In order that the above-recited objects, features and advantages of the present invention will become more readily apparent, a more particular description of the invention will be rendered by reference to the appended drawings and appended detailed description.
As shown in fig. 1-3, the present embodiment provides an electrochemical treatment auxiliary device for a hollow metal interventional instrument, which comprises a servo control system, a cooling system, an electrolyte circulation system, a cantilever mechanism 1 and an electrolytic tank 2, wherein the servo control system is used for adjusting the vertical displacement of the cantilever mechanism 1 and the electrolytic polishing parameters, the cooling system is used for controlling the temperature of electrolyte in the electrolytic tank 2, the electrolyte circulation system is used for stirring and controlling the flow direction of the electrolyte in the electrolytic tank 2 to form a circulation flow, a clamping tool 3 for horizontally supporting the hollow metal 4 is arranged on the cantilever mechanism 1, an anode wire 5 for penetrating through the inner cavity of the hollow metal 4 is arranged on the clamping tool 3, the hollow metal 4 can be immersed into the electrolyte through the cantilever mechanism 1, the electrolyte circulation system comprises a stirrer 6 and a guide member 7 serving as a cathode, the stirrer 6 is used for driving the electrolyte to flow, and the guide member 7 is arranged in the electrolytic tank 2 and is used for guiding the electrolyte and forming an electrolyte flow stream parallel to the axis of the hollow metal 4.
When the polishing device is used, the hollow metal 4 (such as a vascular stent) is horizontally supported through the clamping tool 3, the anode wire 5 penetrates through the inner cavity of the hollow metal 4, then the cantilever mechanism 1 is controlled to descend, the hollow metal 4 is immersed into electrolyte in the electrolytic tank 2, the electrolyte is driven to flow through the stirrer 6, the electrolyte is guided through the guide member 7 to form an electrolyte flow beam parallel to the axis of the hollow metal 4, electrolytic polishing parameters are adjusted, and uniform flushing of the inner surface and the outer surface of the hollow metal is realized through the electrolyte (polishing liquid), so that the inner surface and the outer surface of the hollow metal are uniformly polished, and the polishing quality is improved.
In the present embodiment, the agitator 6 includes an impeller 8 and an agitator motor 9 for driving the impeller 8 to rotate, and the impeller 8 is driven to rotate by the agitator motor 9, thereby achieving the purpose of driving the electrolyte to flow in the electrolytic bath 2.
In this embodiment, the flow guiding member 7 includes two first flow guiding plates 10 parallel to each other, the same ends of the two first flow guiding plates 10 are connected by an arc-shaped flow guiding plate 11 and a second flow guiding plate 12, the first flow guiding plate 10 and the second flow guiding plate 12 are all in a flat plate structure, the first flow guiding plate 10, the second flow guiding plate 12 and the arc-shaped flow guiding plate 11 are all perpendicular to the bottom surface of the electrolytic tank 2, the second flow guiding plate 12 is tangential to the arc-shaped flow guiding plate 11, the two arc-shaped flow guiding plates 11 are diagonally arranged and are oppositely arranged in the opening direction, and an impeller 8 is arranged on the inner side of each arc-shaped flow guiding plate 11. Through the arrangement of the first guide plate 10, the second guide plate 12 and the arc guide plate 11, under the rotating action of the impeller 8, the outer side of the first guide plate 10 can form electrolyte flow beams parallel to the axis of the hollow metal 4 and circulate in the electrolytic tank 2, so that the aim of evenly flushing the inner surface and the outer surface of the hollow metal 4 for electrolytic polishing is fulfilled.
In this embodiment, the cooling system includes a cooling tank 13, a compressor and a circulating pump, the electrolytic tank 2 is disposed in a water bath environment of the cooling tank 13, a heat exchange tube is disposed in the cooling tank 13, a heat exchange medium is disposed in the heat exchange tube, and two ends of the heat exchange tube are connected to form a circulating loop through the compressor and the circulating pump. The heat exchange medium can select alcohol, after the compressor compresses the alcohol, the alcohol is conveyed into the heat exchange tube in the cooling tank 13 through the circulating pump, heat exchange is carried out between the alcohol and water in the cooling tank 13, the water is cooled, and then the cooling of the electrolytic tank 2 is realized through the water bath environment of the cooling tank 13, and the temperature of electrolyte in the electrolytic tank 2 is regulated.
In this embodiment, two clamping tools 3 are disposed on the cantilever mechanism 1 and are respectively used for horizontally supporting two hollow metals 4, so that the purpose of simultaneously electropolishing the two hollow metals 4 can be achieved.
In this embodiment, a cover plate 14 is disposed at the top end of the electrolytic tank 2, two through holes 15 corresponding to the two clamping tools 3 are disposed on the cover plate 14, the clamping tools 3 submerge the hollow metal 4 into the electrolyte through the through holes 15, and the stirring motor 9 is connected to the cover plate 14.
In this embodiment, the flow guiding member 7 is made of stainless steel.
An electrochemical treatment method for a hollow metal interventional instrument, employing the electrochemical treatment assistance device for a hollow metal interventional instrument described above, comprising the steps of:
s1: the hollow metal 4 is horizontally supported through the clamping tool 3, the anode wire 5 penetrates through the inner cavity of the hollow metal 4, the height of the cantilever mechanism 1 is adjusted through the servo control system, and the hollow metal 4 is immersed into electrolyte in the electrolytic tank 2;
s2, adjusting electrolytic polishing parameters, wherein electrolyte flows in an axial direction inside and outside the cavity of the hollow metal 4, uniformly washes the inner surface and the outer surface of the hollow metal 4, and uniformly electropolishes the inner surface and the outer surface of the hollow metal 4.
Wherein, the electropolishing parameters comprise the temperature of the polishing solution, the voltage and current of electropolishing and the flow rate and direction of the polishing solution. By adjusting the rotation directions of the stirrers 6, the rotation directions of the two stirrers 6 arranged in a tangential line arrangement in the electrolyte circulation system are simultaneously anticlockwise rotation or clockwise rotation, and the electrolyte is driven to horizontally and uniformly pass through the circulation flow from the inner surface and the outer surface of the hollow metal 4.
In some embodiments, to uniformly mix electrolyte solutions in the electrolyte circulation system, the maldistribution of electrolyte components after depletion is suppressed, and the rotational speeds of the agitators are set to form a rotational speed difference, i.e., there is a first agitator rotational speed with the same rotational direction that is greater than a second agitator rotational speed.
The principles and embodiments of the present invention have been described in detail with reference to specific examples, which are provided to facilitate understanding of the method and core ideas of the present invention; also, it is within the scope of the present invention to be modified by those of ordinary skill in the art in light of the present teachings. In view of the foregoing, this description should not be construed as limiting the invention.

Claims (8)

1. An electrochemical treatment assistance device for a hollow metal interventional instrument, characterized in that: the electrolytic solution polishing device comprises a servo control system, a cooling system, an electrolyte circulation flow system, a cantilever mechanism and an electrolytic tank, wherein the servo control system is used for adjusting vertical displacement of the cantilever mechanism and electrolytic polishing parameters, the cooling system is used for controlling the temperature of electrolyte in the electrolytic tank, the electrolyte circulation flow system is used for stirring and controlling the flow direction of the electrolyte in the electrolytic tank to form a circulation flow, a clamping tool used for horizontally supporting hollow metal is arranged on the cantilever mechanism, an anode wire used for penetrating through an inner cavity of the hollow metal is arranged on the clamping tool, the hollow metal can be immersed into the electrolyte through the cantilever mechanism, the electrolyte circulation flow system comprises a stirrer and a flow guide member used as a cathode, the stirrer is used for driving the electrolyte to flow, and the flow guide member is arranged in the electrolytic tank and used for guiding the electrolyte and forming an electrolyte flow stream parallel to the axis of the hollow metal.
2. Electrochemical treatment assistance device for a hollow metal interventional instrument according to claim 1, characterized in that: the stirrer comprises an impeller and a stirring motor for driving the impeller to rotate.
3. Electrochemical treatment assistance device for a hollow metal interventional instrument according to claim 2, characterized in that: the guide member comprises two first guide plates which are parallel to each other, the same ends of the two first guide plates are connected through an arc guide plate and a second guide plate, the first guide plates and the second guide plates are of flat plate structures, the first guide plates, the second guide plates and the arc guide plates are perpendicular to the bottom surface of the electrolytic tank, the second guide plates are tangential to the arc guide plates, the two arc guide plates are arranged diagonally and are opposite to each other in opening direction, and the inner sides of the arc guide plates are provided with impellers.
4. Electrochemical treatment assistance device for a hollow metal interventional instrument according to claim 1, characterized in that: the cooling system comprises a cooling tank, a compressor and a circulating pump, wherein the electrolytic tank is arranged in the water bath environment of the cooling tank, a heat exchange tube is arranged in the cooling tank, a heat exchange medium is arranged in the heat exchange tube, and two ends of the heat exchange tube are connected with the circulating pump through the compressor to form a circulating loop.
5. Electrochemical treatment assistance device for a hollow metal interventional instrument according to claim 2, characterized in that: the cantilever mechanism is provided with two clamping tools which are respectively used for horizontally supporting two hollow metals.
6. The electrochemical treatment assistance device for a hollow metal interventional instrument of claim 5, wherein: the top end of the electrolytic tank is provided with a cover plate, two through holes corresponding to the two clamping tools are formed in the cover plate respectively, the clamping tools submerge hollow metal into electrolyte through the through holes, and the stirring motor is connected to the cover plate.
7. Electrochemical treatment assistance device for a hollow metal interventional instrument according to claim 1, characterized in that: the flow guiding component is made of stainless steel.
8. Electrochemical treatment method for hollow metal interventional instruments, characterized in that it uses an electrochemical treatment auxiliary device for hollow metal interventional instruments according to any one of claims 1-7, comprising the steps of:
s1: the hollow metal is horizontally supported through the clamping tool, the anode wire penetrates through the hollow metal cavity, the height of the cantilever mechanism is adjusted through the servo control system, and the hollow metal is immersed into electrolyte in the electrolytic tank;
s2, adjusting electrolytic polishing parameters, enabling electrolyte to flow in an axial direction inside and outside the hollow cavity of the hollow metal, and uniformly flushing the inner surface and the outer surface of the hollow metal, and uniformly electropolishing the inner surface and the outer surface of the hollow metal.
CN202310582765.XA 2023-05-19 2023-05-19 Electrochemical treatment auxiliary equipment and method for hollow metal interventional instrument Pending CN116575106A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310582765.XA CN116575106A (en) 2023-05-19 2023-05-19 Electrochemical treatment auxiliary equipment and method for hollow metal interventional instrument

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202310582765.XA CN116575106A (en) 2023-05-19 2023-05-19 Electrochemical treatment auxiliary equipment and method for hollow metal interventional instrument

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117568907A (en) * 2023-11-10 2024-02-20 天水华洋电子科技股份有限公司 Novel electroplating process of nickel-palladium-gold lead frame

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117568907A (en) * 2023-11-10 2024-02-20 天水华洋电子科技股份有限公司 Novel electroplating process of nickel-palladium-gold lead frame
CN117568907B (en) * 2023-11-10 2024-05-17 天水华洋电子科技股份有限公司 Electroplating process of nickel-palladium-gold lead frame

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