CN116516087A - Method for increasing temperature of top gas of hydrogen-rich carbon circulating oxygen blast furnace - Google Patents

Method for increasing temperature of top gas of hydrogen-rich carbon circulating oxygen blast furnace Download PDF

Info

Publication number
CN116516087A
CN116516087A CN202310529988.XA CN202310529988A CN116516087A CN 116516087 A CN116516087 A CN 116516087A CN 202310529988 A CN202310529988 A CN 202310529988A CN 116516087 A CN116516087 A CN 116516087A
Authority
CN
China
Prior art keywords
gas
compressed air
heat storage
cylinder
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202310529988.XA
Other languages
Chinese (zh)
Inventor
季书民
袁万能
贾志国
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xinjiang Bayi Iron and Steel Co Ltd
Original Assignee
Xinjiang Bayi Iron and Steel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xinjiang Bayi Iron and Steel Co Ltd filed Critical Xinjiang Bayi Iron and Steel Co Ltd
Priority to CN202310529988.XA priority Critical patent/CN116516087A/en
Publication of CN116516087A publication Critical patent/CN116516087A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B5/00Making pig-iron in the blast furnace
    • C21B5/06Making pig-iron in the blast furnace using top gas in the blast furnace process
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B7/00Blast furnaces
    • C21B7/002Evacuating and treating of exhaust gases
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B7/00Blast furnaces
    • C21B7/24Test rods or other checking devices

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)

Abstract

The invention discloses a method for improving the temperature of top gas of a hydrogen-rich carbon circulating oxygen blast furnace, which is characterized in that a combustion heat storage device for burning decarburization gas is arranged at a furnace throat steel brick of the throat of the hydrogen-rich carbon circulating oxygen blast furnace, a combustion cylinder of the combustion heat storage device adopts a high-speed airflow jet heating technology, decarburization gas and compressed air are mixed in the combustion cylinder according to a certain proportion, and the decarburization gas and the compressed air are ignited by an electronic spark device on the inner cylinder wall to be burnt to form a stable heat source. The mixed gas burns 85-94% in the cylinder and the rest burns completely in the heat accumulating cylinder. The hot gas of a large amount of surplus gas and flue gas is sprayed out at a high speed of 110-250 m/s, so that strong convection heat transfer is generated in the hydrogen-rich carbon circulating oxygen blast furnace, and the blending temperature of the low-temperature gas at the top 1 of the hydrogen-rich carbon circulating oxygen blast furnace is uniform due to strong stirring of a large amount of gas.

Description

Method for increasing temperature of top gas of hydrogen-rich carbon circulating oxygen blast furnace
Technical Field
The invention relates to a method for improving the temperature of top gas of a hydrogen-rich carbon circulating oxygen blast furnace.
Background
The hydrogen-rich carbon circulating oxygen blast furnace replaces the traditional preheated air blast with oxygen blast, and removes CO from the top gas 2 And then the recycled hydrogen-rich carbon circulating oxygen blast furnace ironmaking process is returned to be utilized. The cyclic utilization of the top gas improves the partial pressure of CO, enhances the reduction potential of the gas, strengthens the reduction of the iron-containing furnace burden and directly returnsThe original degree is reduced, the iron-making production efficiency is improved, the fuel consumption is reduced, and the carbon emission is reduced. The process reduces direct reduction and removes CO due to development of indirect reduction 2 The top gas after that has a high concentration of reducing components (CO and H 2 ) The method has the advantages that the reduction potential in the furnace is improved, indirect reduction is developed, the fuel ratio is reduced, but due to the adoption of pure oxygen blasting, the gas quantity in the furnace is reduced, and due to the fact that the heat utilization efficiency of the whole furnace body needs to be optimized in a flow field and a temperature field in the furnace under the condition of circulating gas injection, the top temperature of a hydrogen-rich carbon circulating oxygen blast furnace is often lower through production practice parameters and is lower than 70 ℃ for a long time, the too low top temperature can lead a gas rising pipe and a falling pipe to condense and adhere dust, the accident of blocking a gas pipeline is caused, in addition, water vapor of water-containing gas is solidified, dust in the gas is settled in a gravity dust collector, a dust discharging channel at the lower part of the gravity dust collector is blocked, so that gas dust is hardened at a cone section at the lower part of the gravity dust collector, and the normal production of the hydrogen-rich carbon circulating oxygen blast furnace is seriously influenced.
Disclosure of Invention
The invention aims to provide a method for improving the temperature of the top gas of a hydrogen-rich carbon circulating oxygen blast furnace, which can improve the temperature of the top gas of the hydrogen-rich carbon circulating oxygen blast furnace and ensure normal production.
The technical scheme adopted by the invention is as follows: a method for raising the temp of top gas of hydrogen-enriched carbon-circulated oxygen blast furnace features that a combustion and heat accumulating unit for burning decarbonized gas is installed to the steel brick at throat of hydrogen-enriched carbon-circulated oxygen blast furnace, and said combustion and heat accumulating unit is divided into combustion cylinder and heat accumulating cylinder, where mixed gas is burnt by 85-94% and the rest is completely burnt. Spraying a large amount of surplus gas and flue gas hot gas into a hydrogen-rich carbon circulating oxygen blast furnace at a high speed of 110-250 m/s;
the end face of the combustion cylinder device is provided with a decarburization gas burner, the top face of the combustion cylinder device is provided with a compressed air burner and an electronic spark device, the decarburization gas burner is connected with a decarburization gas pipeline of 0.5MPa and a control system, the decarburization gas control system consists of a gas quick-cutting valve, a regulating valve, a gate valve and a pressure gauge, the decarburization gas control system is matched with a nitrogen security purging system, the compressed air burner is connected with a compressed air pipeline of 0.6MPa and the control system, the compressed air pipeline and the control system consist of a compressed air quick-cutting valve, a regulating valve, a gate valve and a pressure gauge, and the compressed air pipeline and the control system are matched with a nitrogen security purging system; the control of the above systems is connected with the digital control system through cables;
the heat storage cylinder is cylindrical, the front end surface of the heat storage cylinder is provided with a combustion cylinder, the upper cylinder side is provided with a gas oxygen content detection device and an excess gas smoke temperature detection device, a circular ring refractory brick wall is built inside the heat storage cylinder, a honeycomb refractory heat storage masonry which is less short than the axial dimension of the brick wall is arranged inside the brick wall, and the excess gas smoke heats the brick wall and an internal empty heat storage masonry which penetrates through the honeycomb refractory;
the decarbonization gas contains more than 65% of CO, the decarbonization gas burner and the compressed air burner are mixed and combusted in a combustion cylinder at high speed to generate 1200 ℃ excess gas smoke, the flow of decarbonization gas and the control of compressed air are established by a digital computer by 1.15 times of excess gas coefficient, and the opening of a compressed air pipeline and a regulating valve on a decarbonization gas control system are automatically regulated to finish the process; the decarburization gas is used in an amount ranging from 900 to 1100Nm 3 The pressure is controlled at 0.5Mpa, and the usage amount of compressed air is 1400-1600Nm 3 Pressure is controlled at 0.6Mpa, and flow rate of top gas of hydrogen-rich carbon circulating oxygen blast furnace is 80000Nm 3 And/h, maintaining the pressure at 0.16-0.18 Mpa; the gas oxygen content detection device is arranged on the upper cylinder side of the heat storage cylinder to detect the oxygen content of the excessive gas smoke in real time, the oxygen content is controlled below 0.8%, the excessive gas smoke temperature detection device is arranged on the upper cylinder side of the heat storage cylinder, and the temperature of the excessive gas smoke is controlled at 1200 ℃.
According to the heat storage barrel, the brick wall and the honeycomb refractory heat storage masonry, the heat of the excessive gas smoke is utilized, wherein brick holes in the honeycomb refractory heat storage masonry can pass through the high-temperature smoke and store a certain amount of heat. The invention mainly provides high-temperature flue gas or excessive high-temperature flue gas by adopting a furnace top combustion part to decarbonize gas, and a method for heating the furnace top gas is adopted, so that the furnace top gas can rise from 70 ℃ to 90-95 ℃ to ensure that water in the gas is not separated out, and the gas is in a gaseous state, and enters a double-text scrubber along with the gas through a gas rising pipe, a falling pipe and a gravity dust remover, and crystal water is not formed before the double-text scrubber.
The key core technology of the invention is that a combustion heat storage device for burning decarburized gas is arranged at the furnace throat steel brick of the throat of the hydrogen-rich carbon circulating oxygen blast furnace, the combustion heat storage device is utilized to generate high-temperature surplus gas smoke, the temperature is controlled to be about 1200 ℃, the high-temperature surplus gas smoke is mixed with 70 ℃ low-temperature gas at the furnace top, and the low-temperature gas at the furnace top is heated to be more than 90 ℃. The combustion heat storage device is divided into a combustion cylinder and a heat storage cylinder. The combustion cylinder of the combustion heat storage device adopts a high-speed airflow jet heating technology, a high-speed burner is arranged, decarburized coal gas and compressed air are mixed in the combustion cylinder in a certain proportion, and the decarburized coal gas and the compressed air are ignited by an electronic spark device on the inner cylinder wall to be combusted, so that a stable heat source is formed. The mixed gas burns 85-94% in the cylinder and the rest burns completely in the heat accumulating cylinder. The hot gas of a large amount of surplus gas and flue gas is sprayed out at a high speed of 110-250 m/s, so that strong convection heat transfer is generated in the hydrogen-rich carbon circulating oxygen blast furnace, and the blending temperature of the low-temperature gas at the top of the hydrogen-rich carbon circulating oxygen blast furnace is uniform due to strong stirring of a large amount of gas.
Compared with the prior art, the technical scheme provided by the invention has the beneficial effects that: the top gas of the hydrogen-rich carbon circulating oxygen blast furnace can be raised to 90-95 ℃ from 70 ℃ so that water in the gas is not separated out and is in a gaseous state, and the gas passes through a gas ascending pipe, a descending pipe and a gravity dust remover to enter a double-text scrubber along with the gas, so that crystal water is not formed before the double-text scrubber. The gas oxygen content detection device is arranged on the upper cylinder side of the cylinder device to detect the oxygen content of the excessive gas smoke in real time, and the decarbonized gas is controlled below 0.8%, so that the gas safety is ensured. The decarburization gas control system and the compressed air control system are matched with the nitrogen security purging system and the quick-cut valve, so that the connection between the system and the hydrogen-rich carbon circulating oxygen blast furnace can be quickly cut off when the machine is jumped and the wind is restored in an emergency, and the safety production is ensured. The brick wall of the heat storage barrel device and the honeycomb refractory heat storage masonry store a certain amount of ground heat, and can be used as a safe ignition source for re-ignition after fire extinguishment of the burner. In order to safely control the oxygen content, the flue gas is in a reducing atmosphere by adopting excessive gas combustion, so that the safety requirement that the oxygen content in the gas is less than 0.8% is met.
Drawings
FIG. 1 is a schematic diagram of the connection structure of the present invention;
fig. 2 is a side cross-sectional view of the interior void thermal storage masonry of fig. 1.
Description of the embodiments
As shown in figures 1 and 2, a combustion heat storage device for burning decarburization gas is arranged at a furnace throat steel brick of a furnace throat of the hydrogen-rich carbon circulating oxygen blast furnace, the combustion heat storage device is divided into a combustion cylinder 2 and a heat storage cylinder 3, the combustion cylinder 2 of the combustion heat storage device adopts a high-speed air flow jet heating technology and is provided with a high-speed burner, decarburization gas and compressed air flow and are mixed in the combustion cylinder 2 according to a certain proportion, and the decarburization gas and the compressed air are ignited by an electronic spark device 6 on the inner cylinder wall to burn to form a stable heat source. The mixed gas burns 85-94% in the cylinder, and the rest burns completely in the heat accumulating cylinder 3. The hot gas of a large amount of surplus gas and flue gas is sprayed out at a high speed of 110-250 m/s, so that strong convection heat transfer is generated in the hydrogen-rich carbon circulating oxygen blast furnace, and the mixing temperature of the low-temperature gas at the top 1 of the hydrogen-rich carbon circulating oxygen blast furnace is uniform due to strong stirring of a large amount of gas;
the end face of the combustion cylinder device 2 is provided with a decarburization gas burner 4, the top face of the combustion cylinder device is provided with a compressed air burner 5 and an electronic spark device 6, the decarburization gas burner 4 is connected with a decarburization gas pipeline of 0.5MPa and a control system 7, the decarburization gas control system 7 is formed by connecting and installing a gas quick-cutting valve, a regulating valve, a gate valve and a pressure gauge, the decarburization gas control system 7 is matched with a nitrogen security purging system 10 at the same time, the compressed air burner 5 is connected and installed with a compressed air pipeline of 0.6MPa and a control system 8, the compressed air pipeline and the control system 8 is formed by connecting and installing a compressed air quick-cutting valve, a regulating valve, a gate valve and a pressure gauge, and the compressed air pipeline and the control system 8 are matched with a nitrogen security purging system 11 at the same time; the control of the above systems is connected with a digital control system 9 through cables;
the heat storage cylinder 3 is cylindrical, the front end face of the heat storage cylinder is provided with a combustion cylinder 2, the upper cylinder side is provided with a gas oxygen content detection device 12 and an excess gas smoke temperature detection device 13, a circular ring refractory brick wall 14 is built inside the heat storage cylinder, a honeycomb refractory heat storage masonry 15 which is less short than the axial dimension of the brick wall 14 is arranged inside the brick wall 14, and the excess gas smoke heats the brick wall 14 and an internal empty heat storage masonry 15 which penetrates through the honeycomb refractory;
the decarbonization gas contains more than 65% of CO, the decarbonization gas burner 4 and the compressed air burner 5 are mixed and combusted in a combustion cylinder 2 at high speed to generate 1200 ℃ excess gas smoke, the flow of the decarbonization gas and the control of the compressed air are established by a digital computer by 1.15 times of excess gas coefficient, and the opening of a compressed air pipeline and a regulating valve on a decarbonization gas control system are automatically regulated to finish the process; the decarburization gas is used in an amount ranging from 900 to 1100Nm 3 The pressure is controlled at 0.5Mpa, and the usage amount of compressed air is 1400-1600Nm 3 The pressure is controlled at 0.6Mpa, and the flow rate of the top 1 gas of the hydrogen-rich carbon circulating oxygen blast furnace is 80000Nm 3 And/h, maintaining the pressure at 0.16-0.18 Mpa; the gas oxygen content detection device 12 is arranged on the upper cylinder side of the heat storage cylinder 3 to detect the oxygen content of the excessive gas smoke in real time, the oxygen content is controlled below 0.8%, the excessive gas smoke temperature detection device 13 is arranged on the upper cylinder side of the heat storage cylinder 3, and the temperature of the excessive gas smoke is controlled at 1200 ℃.
The hot gas of a large amount of surplus gas and flue gas is sprayed out at a high speed of 110-250 m/s, so that strong convection heat transfer is generated in the top space of the hydrogen-rich carbon circulating oxygen blast furnace, and the mixing temperature of the low-temperature gas at the top 1 of the hydrogen-rich carbon circulating oxygen blast furnace is uniform due to strong stirring of a large amount of gas, and the top temperature of 70 ℃ is increased to 90-95 ℃.
Examples
And (3) re-wind production of the hydrogen-rich carbon circulating oxygen blast furnace: before closing the furnace top ignition manhole, opening a regulating valve of the compressed air burner 5 and starting an electronic spark device 6 for ignition, then opening a regulating valve of the decarburization gas burner 4, and performing stable combustion by small fire, wherein the compressed air flow is controlled to be 50 Nm 3 And/h, controlling the flow of decarbonized gas at40 Nm 3 And/h, preparing to open the air to close an ignition manhole at the top of the furnace, and after the air is opened, recovering the production stage of the hydrogen-rich carbon circulating oxygen blast furnace, wherein the low-load (a large amount of fuel coke) damping down material input by the hydrogen-rich carbon circulating oxygen blast furnace reacts, the gas quantity at the top of the furnace is sufficient, the temperature at the top of the furnace exceeds 90 ℃, the gas utilization efficiency is improved along with the adjustment of the furnace condition after the furnace is opened, the temperature at the top of the furnace has a descending trend, and the flow of decarburized gas needs to be adjusted by entering the compressed air flowmeter in the embodiment 2.
Examples
Normal production of hydrogen-rich carbon circulating oxygen blast furnace: the flow rate of the top gas of the hydrogen-rich carbon circulating oxygen blast furnace is 80000m3/h, the temperature of the top is lower than 70 ℃, the control of the decarburization gas flow rate and the compressed air establishes an excess gas coefficient which is 1.15 times through a digital computer, meanwhile, an excess gas flue gas temperature detection device 13 is set, the excess gas flue gas temperature detection device is controlled at 1200 ℃, the integrated control of the flow rate and the temperature of the top gas of the hydrogen-rich carbon circulating oxygen blast furnace is combined, at the moment, the opening of a compressed air pipeline and the opening of a regulating valve on a decarburization gas control system are automatically regulated through a computer, and the using amount range of the decarburization gas is regulated to 900-1100Nm 3 And/h, the use amount of the compressed air is adjusted to 1400-1600Nm 3 In the range of the ratio/h, the top gas of the hydrogen-rich carbon circulating oxygen blast furnace is heated to 90 ℃. When the oxygen content of the gas fume exceeds 0.8%, the oxygen content of the gas fume can be properly increased by 10-30 Nm 3 And/h decarburization gas quantity.
Examples
Stopping production by damping down the hydrogen-rich carbon circulating oxygen blast furnace: before stopping production, the quick-cut valve of the compressed air burner 5 and the quick-cut valve of the decarburization gas burner 4 are closed, and simultaneously, the decarburization gas control system and the compressed air control system are opened to be simultaneously matched with the nitrogen security purging systems 10 and 11 to purge for 2 minutes, and then the purging valves are closed.

Claims (1)

1. A method for increasing the temperature of the top gas of a hydrogen-rich carbon circulating oxygen blast furnace is characterized in that a combustion heat storage device for burning decarburized gas is arranged at the position of a furnace throat steel brick of the throat of the hydrogen-rich carbon circulating oxygen blast furnace, the combustion heat storage device is divided into a combustion cylinder and a heat storage cylinder, the mixed gas is burnt in 85-94% in the combustion cylinder, and the rest is completely burnt in the heat storage cylinder. Spraying a large amount of surplus gas and flue gas hot gas into a hydrogen-rich carbon circulating oxygen blast furnace at a high speed of 110-250 m/s;
the end face of the combustion cylinder device is provided with a decarburization gas burner, the top face of the combustion cylinder device is provided with a compressed air burner and an electronic spark device, the decarburization gas burner is connected with a decarburization gas pipeline of 0.5MPa and a control system, the decarburization gas control system consists of a gas quick-cutting valve, a regulating valve, a gate valve and a pressure gauge, the decarburization gas control system is matched with a nitrogen security purging system, the compressed air burner is connected with a compressed air pipeline of 0.6MPa and the control system, the compressed air pipeline and the control system consist of a compressed air quick-cutting valve, a regulating valve, a gate valve and a pressure gauge, and the compressed air pipeline and the control system are matched with a nitrogen security purging system; the control of the above systems is connected with the digital control system through cables;
the heat storage cylinder is cylindrical, the front end surface of the heat storage cylinder is provided with a combustion cylinder, the upper cylinder side is provided with a gas oxygen content detection device and an excess gas smoke temperature detection device, a circular ring refractory brick wall is built inside the heat storage cylinder, a honeycomb refractory heat storage masonry which is less short than the axial dimension of the brick wall is arranged inside the brick wall, and the excess gas smoke heats the brick wall and an internal empty heat storage masonry which penetrates through the honeycomb refractory;
the decarbonization gas contains more than 65% of CO, the decarbonization gas burner and the compressed air burner are mixed and combusted in a combustion cylinder at high speed to generate 1200 ℃ excess gas smoke, the flow of decarbonization gas and the control of compressed air are established by a digital computer by 1.15 times of excess gas coefficient, and the opening of a compressed air pipeline and a regulating valve on a decarbonization gas control system are automatically regulated to finish the process; the decarburization gas is used in an amount ranging from 900 to 1100Nm 3 The pressure is controlled at 0.5Mpa, and the usage amount of compressed air is 1400-1600Nm 3 Pressure is controlled at 0.6Mpa, and flow rate of top gas of hydrogen-rich carbon circulating oxygen blast furnace is 80000Nm 3 And/h, maintaining the pressure at 0.16-0.18 Mpa; a gas oxygen content detection device is arranged on the upper cylinder side of the heat storage cylinder to detect the oxygen content of the excessive gas smoke in real time, and the oxygen content is controlled below 0.8 percent, and the gas is storedThe upper cylinder side of the hot cylinder is provided with an excess gas flue gas temperature detection device, and the excess gas flue gas temperature is detected in real time and controlled at 1200 ℃.
CN202310529988.XA 2023-05-11 2023-05-11 Method for increasing temperature of top gas of hydrogen-rich carbon circulating oxygen blast furnace Pending CN116516087A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310529988.XA CN116516087A (en) 2023-05-11 2023-05-11 Method for increasing temperature of top gas of hydrogen-rich carbon circulating oxygen blast furnace

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202310529988.XA CN116516087A (en) 2023-05-11 2023-05-11 Method for increasing temperature of top gas of hydrogen-rich carbon circulating oxygen blast furnace

Publications (1)

Publication Number Publication Date
CN116516087A true CN116516087A (en) 2023-08-01

Family

ID=87404492

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202310529988.XA Pending CN116516087A (en) 2023-05-11 2023-05-11 Method for increasing temperature of top gas of hydrogen-rich carbon circulating oxygen blast furnace

Country Status (1)

Country Link
CN (1) CN116516087A (en)

Similar Documents

Publication Publication Date Title
CN114317853B (en) Based on 2500m 3 Heating method for high-temperature gas by carbon-carbon circulation blowing of blast furnace gas
KR20170048370A (en) Improved burn profiles for coke operation
JP6256710B2 (en) Oxygen blast furnace operation method
JP5522325B1 (en) Blast furnace operation method
JP7297091B2 (en) Blast furnace operation method
EP0793071A2 (en) Furnace waste gas combustion control
JPH05179323A (en) Operating method for blast furnace
CN116516087A (en) Method for increasing temperature of top gas of hydrogen-rich carbon circulating oxygen blast furnace
CN101871026A (en) Method for injecting carbon dioxide into blast furnace
CN215103367U (en) Gas CO of smelting reduction furnace2Carbon neutralization device
CN113088608A (en) Gas CO of smelting reduction furnace2Method and apparatus for carbon neutralization
CN101693936A (en) Explosion suppression device of combustible gas for flues
CN201512551U (en) Combustible gas explosion-suppressing device for flue
US9004910B2 (en) Method for combustion of a low-grade fuel
CN116536473B (en) Explosion-proof efficiency improving method and explosion-proof efficiency improving system for converter flue
CN219772158U (en) Hot air furnace system using pure blast furnace gas
CN103740873A (en) Blast furnace ironmaking system
CN116855669A (en) Steelmaking method and system for improving flue safety and gas calorific value
CN217031214U (en) Tail gas treatment and incineration device for silver-process formaldehyde
LU102438B1 (en) Method for operating a blast furnace plant
KR102161597B1 (en) Method and apparatus for manufacturing molten iron
KR100431864B1 (en) Method For Manufacturing Molten Iron By COREX Process
CN115111599A (en) Control method for ultralow NOx emission in ignition and blowing-in process of circulating fluidized bed boiler
CN117327848A (en) Method for treating suspended materials in hydrogen-rich carbon circulating oxygen blast furnace
JPH04354810A (en) Method for blowing fine coal into blast furnace and device therefor

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination