CN116497292A - Composite material for reducing internal air pressure of thermal battery and preparation method and application thereof - Google Patents
Composite material for reducing internal air pressure of thermal battery and preparation method and application thereof Download PDFInfo
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- CN116497292A CN116497292A CN202310634153.0A CN202310634153A CN116497292A CN 116497292 A CN116497292 A CN 116497292A CN 202310634153 A CN202310634153 A CN 202310634153A CN 116497292 A CN116497292 A CN 116497292A
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- composite material
- thermal battery
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- air pressure
- reducing
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- 239000002131 composite material Substances 0.000 title claims abstract description 33
- 230000001603 reducing effect Effects 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 229910052751 metal Inorganic materials 0.000 claims abstract description 49
- 239000002184 metal Substances 0.000 claims abstract description 49
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 30
- 239000011575 calcium Substances 0.000 claims abstract description 30
- 238000010438 heat treatment Methods 0.000 claims abstract description 7
- 238000001816 cooling Methods 0.000 claims abstract description 5
- 239000012298 atmosphere Substances 0.000 claims abstract description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 239000006260 foam Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 239000012466 permeate Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 239000011888 foil Substances 0.000 claims description 2
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 10
- 239000007789 gas Substances 0.000 abstract description 9
- 239000002905 metal composite material Substances 0.000 abstract description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 4
- 238000007599 discharging Methods 0.000 abstract description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 2
- 239000001257 hydrogen Substances 0.000 abstract description 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 2
- 238000002844 melting Methods 0.000 abstract description 2
- 230000008018 melting Effects 0.000 abstract description 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 2
- 239000001301 oxygen Substances 0.000 abstract description 2
- 229910052760 oxygen Inorganic materials 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 230000000149 penetrating effect Effects 0.000 abstract 1
- 230000009286 beneficial effect Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000012300 argon atmosphere Substances 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 229910000521 B alloy Inorganic materials 0.000 description 1
- 229910000882 Ca alloy Inorganic materials 0.000 description 1
- 229910013618 LiCl—KCl Inorganic materials 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- PPTSBERGOGHCHC-UHFFFAOYSA-N boron lithium Chemical compound [Li].[B] PPTSBERGOGHCHC-UHFFFAOYSA-N 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000004137 mechanical activation Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 239000012782 phase change material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/30—Deferred-action cells
- H01M6/36—Deferred-action cells containing electrolyte and made operational by physical means, e.g. thermal cells
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/81—Solid phase processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C47/00—Making alloys containing metallic or non-metallic fibres or filaments
- C22C47/02—Pretreatment of the fibres or filaments
- C22C47/06—Pretreatment of the fibres or filaments by forming the fibres or filaments into a preformed structure, e.g. using a temporary binder to form a mat-like element
- C22C47/062—Pretreatment of the fibres or filaments by forming the fibres or filaments into a preformed structure, e.g. using a temporary binder to form a mat-like element from wires or filaments only
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C47/00—Making alloys containing metallic or non-metallic fibres or filaments
- C22C47/08—Making alloys containing metallic or non-metallic fibres or filaments by contacting the fibres or filaments with molten metal, e.g. by infiltrating the fibres or filaments placed in a mould
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C49/00—Alloys containing metallic or non-metallic fibres or filaments
- C22C49/02—Alloys containing metallic or non-metallic fibres or filaments characterised by the matrix material
- C22C49/04—Light metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C49/00—Alloys containing metallic or non-metallic fibres or filaments
- C22C49/14—Alloys containing metallic or non-metallic fibres or filaments characterised by the fibres or filaments
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/50—Methods or arrangements for servicing or maintenance, e.g. for maintaining operating temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/102—Nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/104—Oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/108—Hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- Hybrid Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
The invention belongs to the technical field of chemical power supply thermal batteries, and particularly relates to a composite material for reducing the internal air pressure of a thermal battery, a preparation method and application thereof, wherein the composite material is prepared from metal calcium and a metal carrier according to a mass ratio of 85:15-99:1, and the composite material is prepared by placing the metal calcium on the metal carrier, carrying out high-temperature heat treatment in an inert atmosphere environment, and penetrating molten calcium metal into the metal carrier; naturally cooling to obtain a calcium metal composite material; the composite material was then cut into a sheet shape and placed at both ends of the battery stack. The composite material can react with oxygen, nitrogen, sulfur vapor, hydrogen and other gases generated in the discharging process of the thermal battery and has the characteristics of high melting point, so that the air pressure in the high-temperature environment inside the cylinder in the working process of the thermal battery is effectively reduced, and the safety and reliability of the working of the thermal battery are obviously improved.
Description
Technical Field
The invention belongs to the technical field of chemical power supply thermal batteries, and particularly relates to a composite material for reducing internal air pressure of a thermal battery, and a preparation method and application thereof.
Background
The thermal battery is a thermal-activated battery which can be discharged in extreme environments and has high specific energy, and is widely applied to the fields of military, space exploration, underground mining industry and the like. The pyrotechnic system inside the thermal battery is ignited by means of electric activation or mechanical activation, and then the igniting strip ignites the heating material to release heat. In seconds or even tens of milliseconds, the internal temperature of the battery rises rapidly, the molten salt electrolyte in the solid state melts rapidly, and the battery begins to discharge. The effective working temperature range of the thermal battery is 450-550 ℃.
Typically, the heating material in the thermal battery, once ignited, can release a large amount of heat in a few seconds, the temperature inside the thermal battery rapidly rises, and a large amount of gas is generated. The gas is accumulated in a large quantity, so that the internal gas pressure of the battery is gradually increased, and when the internal gas pressure of the battery exceeds the critical gas pressure value borne by the cylinder, the cylinder is fused and exploded, and serious potential safety hazards exist.
The patent with publication number CN216085007U can regularly remove the atmosphere inside the thermal battery shell through the air suction valve on the thermal battery, improves the storage life of the thermal battery, reduces the internal air pressure of the thermal battery shell, but the scheme has a complex structure.
The patent with publication number CN109135684A comprises the following components in percentage by weight: 30-90% of phase-change molten salt, 0.1-20% of carbon material and 5-70% of carrier with porosity reaching 30-99%. The composite phase change material in the scheme can actively adjust the temperature inside the thermal battery, but the material composition of the scheme is complex.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides a composite material for reducing the internal air pressure of a thermal battery, and a preparation method and application thereof.
The method is realized by the following technical scheme:
a composite material for reducing the internal air pressure of a thermal battery is prepared from metal calcium and a metal carrier according to a mass ratio of 85:15-99:1.
The metal calcium material is at least one of high-purity metal calcium particles, metal calcium blocks and calcium foil.
The metal carrier is any one of foam nickel, foam copper and foam iron nickel with a net structure.
The porosity of the metal carrier is more than or equal to 96%, and the thickness is 0.2mm-2mm.
The invention controls the porosity of the metal carrier, is beneficial to reducing the quality of the composite material, increases the contact area of the composite material, and simultaneously ensures good electron conduction effect; the invention controls the thickness of the metal carrier, is beneficial to ensuring the air pressure reducing effect and ensuring the full contact between the metal calcium and the gas, if the thickness is too thin, the gas adsorption is incomplete, and if the thickness is too thick, the mass is increased, so that the manufacturing cost is higher and the raw materials are wasted.
The preparation process of composite material for reducing the internal air pressure of thermal battery includes the first setting calcium metal onto metal carrier, the subsequent high temperature heat treatment at 850-1000 deg.c in inert atmosphere for 0.1-1 hr to make molten calcium metal permeate into the metal carrier, and final natural cooling to form composite calcium metal material.
The application of a composite material for reducing the internal air pressure of a thermal battery in assembling the thermal battery.
The application method is that the composite material for reducing the internal air pressure of the thermal battery is cut into a sheet shape and then is placed at the end position of the battery stack.
The beneficial effects are that:
the preparation method and the application method are simple and feasible, are suitable for large-scale production, do not influence the battery structure and occupy small battery space, and effectively improve the safety and reliability of the thermal battery in the discharging process.
The composite material for reducing the internal air pressure of the thermal battery has higher melting point, and can ensure that the original shape can be maintained within the working temperature range of the thermal battery.
The composite material of the invention takes a metal carrier with a network structure as a support, and plays roles of support and electron conduction.
The calcium alloy layer is formed on the surface of the composite material and can react with gases (such as oxygen, nitrogen, sulfur vapor, hydrogen and the like) generated in the discharging process of the thermal battery to generate a solid product, so that the internal air pressure of the thermal battery is reduced when the thermal battery works at high temperature, the internal air pressure of the battery is ensured to be lower than the critical air pressure value borne by the cylinder body, and the safety and the reliability of the thermal battery in the discharging process are improved.
Detailed Description
The following detailed description of the invention is provided in further detail, but the invention is not limited to these embodiments, any modifications or substitutions in the basic spirit of the present examples, which still fall within the scope of the invention as claimed.
The thermal battery in the following examples 1, 2 and 1 was positiveExtremely select CoS 2 The negative electrode material adopts lithium boron alloy, and the electrolyte adopts LiCl-KCl system.
Example 1: the preparation method of the composite material for reducing the internal air pressure of the thermal battery comprises the following steps:
step one: weighing metal calcium and a metal carrier according to the weight ratio of 96:4, wherein the metal carrier is a copper metal mesh-shaped carrier with the porosity of 98% and the thickness of 0.3 mm;
step two: placing the metal calcium weighed in the first step on a metal carrier, then carrying out heat treatment for 0.5h at 900 ℃ in argon atmosphere to enable molten calcium metal to permeate into the metal carrier, and then naturally cooling to form a calcium metal composite material;
step three: and (3) placing the calcium metal composite material sheet with the diameter of 60mm in the second step of 4 sheets at the end part of the thermal battery pile with the height of 300 mm.
At 2A/cm 2 And under the current density, constant-current discharge test is carried out, and the thermal battery cylinder body does not bulge, melt and pass through and the like in the whole process.
Example 2: the preparation method of the composite material for reducing the internal air pressure of the thermal battery comprises the following steps:
step one: weighing metal calcium and a metal carrier according to the weight ratio of 93:7, wherein the metal carrier is a nickel metal reticular structure carrier with the porosity of 98% and the thickness of 0.3 mm;
step two: placing the metal calcium weighed in the first step on a metal carrier, then carrying out high-temperature heat treatment for 0.5h at 900 ℃ under argon atmosphere to enable molten calcium metal to permeate into the metal carrier, and then naturally cooling to form a calcium metal composite material;
step three: and (3) placing the calcium metal composite material sheet with the diameter of 60mm in the second step of 4 sheets at the end part of the thermal battery pile with the height of 300 mm.
At 2A/cm 2 And under the current density, constant-current discharge test is carried out, and the thermal battery cylinder body does not bulge, melt and pass through and the like in the whole process.
Comparative example 1
The powder was heated according to examples 1 and 2 aboveWeight, heat design was performed, and the same-sized thermal batteries were assembled, but the end of the cell stack of comparative example 1 was not provided with a composite material. The cell of comparative example 1 was at 2A/cm 2 Under the current density, discharge test is carried out, the voltage is fluctuated severely at 10s, and then the cylinder body is melted through.
Claims (7)
1. The composite material for reducing the internal air pressure of the thermal battery is characterized by being prepared from metal calcium and a metal carrier according to the mass ratio of 85:15-99:1.
2. The composite material for reducing the internal air pressure of the thermal battery according to claim 1, wherein the metal calcium material is at least one of high-purity metal calcium particles, metal calcium blocks and calcium foil.
3. The composite material for reducing the internal air pressure of the thermal battery according to claim 1, wherein the metal carrier is any one of foam nickel, foam copper and foam iron nickel with a net structure.
4. A composite material for reducing the internal air pressure of a thermal battery according to claim 1 or 3, wherein the porosity of the metal carrier is more than or equal to 96% and the thickness is 0.2mm-2mm.
5. The composite material for reducing the internal air pressure of the thermal battery according to claim 1, wherein the preparation method of the composite material for reducing the internal air pressure of the thermal battery is characterized in that metal calcium is firstly placed on a metal carrier, then the metal carrier is subjected to high-temperature heat treatment under the inert atmosphere and the temperature of 850-1000 ℃ to enable molten calcium metal to permeate into the metal carrier, and finally the composite material for reducing the internal air pressure of the thermal battery is formed by natural cooling.
6. Use of a composite material according to any one of claims 1-5 for reducing the internal gas pressure of a thermal battery in assembling a thermal battery.
7. Use of a composite material for reducing internal gas pressure of a thermal battery according to claim 6 for assembling a thermal battery, wherein the use is to cut the composite material for reducing internal gas pressure of a thermal battery into a sheet shape and then to place it at the end position of a cell stack.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310634153.0A CN116497292A (en) | 2023-05-31 | 2023-05-31 | Composite material for reducing internal air pressure of thermal battery and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310634153.0A CN116497292A (en) | 2023-05-31 | 2023-05-31 | Composite material for reducing internal air pressure of thermal battery and preparation method and application thereof |
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| CN116497292A true CN116497292A (en) | 2023-07-28 |
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| CN202310634153.0A Pending CN116497292A (en) | 2023-05-31 | 2023-05-31 | Composite material for reducing internal air pressure of thermal battery and preparation method and application thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009013629A2 (en) * | 2007-07-24 | 2009-01-29 | Toyota Jidosha Kabushiki Kaisha | Air battery system and methods for using and controlling air |
| CN102709535A (en) * | 2012-06-21 | 2012-10-03 | 广西大学 | Fe-based hydrogen storage alloy electrode material and preparation method thereof |
| CN109346738A (en) * | 2018-09-25 | 2019-02-15 | 贵州梅岭电源有限公司 | A kind of thermal cell with gas absorber |
| CN110137411A (en) * | 2019-04-04 | 2019-08-16 | 河南鑫泉能源科技有限公司 | Explosion rupture disk and its preparation method and application for lithium battery cap |
| CN112467270A (en) * | 2020-11-03 | 2021-03-09 | 浙江锋锂新能源科技有限公司 | Composite air suction element, preparation method thereof and flatulence-preventing self-repairing soft-package lithium battery |
-
2023
- 2023-05-31 CN CN202310634153.0A patent/CN116497292A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009013629A2 (en) * | 2007-07-24 | 2009-01-29 | Toyota Jidosha Kabushiki Kaisha | Air battery system and methods for using and controlling air |
| CN102709535A (en) * | 2012-06-21 | 2012-10-03 | 广西大学 | Fe-based hydrogen storage alloy electrode material and preparation method thereof |
| CN109346738A (en) * | 2018-09-25 | 2019-02-15 | 贵州梅岭电源有限公司 | A kind of thermal cell with gas absorber |
| CN110137411A (en) * | 2019-04-04 | 2019-08-16 | 河南鑫泉能源科技有限公司 | Explosion rupture disk and its preparation method and application for lithium battery cap |
| CN112467270A (en) * | 2020-11-03 | 2021-03-09 | 浙江锋锂新能源科技有限公司 | Composite air suction element, preparation method thereof and flatulence-preventing self-repairing soft-package lithium battery |
Non-Patent Citations (1)
| Title |
|---|
| 萨维茨基，Е.М.: "温度对金属及合金机械性能的影响", 30 April 1965, 北京：中国工业出版社, pages: 84 * |
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