CN116463174A - 一种羽绒服专用干洗剂及其制备方法 - Google Patents
一种羽绒服专用干洗剂及其制备方法 Download PDFInfo
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Abstract
本发明涉及衣物洗涤技术领域，尤其涉及IPC C11D3领域，更具体的，涉及一种羽绒服专用干洗剂及其制备方法。按重量百分比计，组分包括：表面活性剂4‑7％，溶剂3‑7％，渗透剂4‑9％，抑菌剂0.1‑0.2％，酶制剂0.1‑0.2％，水补足余量。所述溶剂、渗透剂和酶制剂重量比为(5‑7)：(5‑8)：(0.1‑0.15)时，可提高干洗剂的去污和渗透效果；所述酶制剂包括蛋白酶、纤维素酶，所述蛋白酶、纤维素酶重量比为1：(0.5‑1)时，可进一步提高干洗剂对聚酯纤维面料的清洁能力。
Description
技术领域
本发明涉及衣物洗涤技术领域，尤其涉及IPC C11D3领域，更具体的，涉及一种羽绒服专用干洗剂及其制备方法。
背景技术
目前的羽绒服干洗剂通常以渗透性强的表面活性剂作为主要成分，清洁力不够高，留有残留，不能从根本上去除污渍，有的则以油性溶剂发挥相似相溶的作用，去除羽绒服上的污渍，由于羽绒服装的填充料是禽类羽绒，在干洗过程中，羽绒完全浸泡在干洗剂中，药水渗人到了纤维内部，再加上羽绒服装选用的布料一般都是高密度织物或涂层织物，所以虽经过高速甩干和烘干回收，但渗入服装和纤维内部的干洗液难以完全排出，以致长期残留在羽绒服装之内，经过干洗的羽绒服装往往在很长一段时间内都会散发出异味，存在一定的毒性，这种残留的干洗剂可能对人体健康造成危害。
CN 111334377B公开了一种相变羽绒服干洗剂及其制备方法，包括如下重量份数的原料，二甲基硅油1.5～3.5份、硅胶4～8.5份、生物质表面活性剂2.5～5份、第一溶剂57～80份、第二溶剂16.5～27份，其中第一溶剂为有机溶剂，过多的有机溶剂残留一定程度对健康造成危害。
发明内容
为克服背景技术中的不足，本发明提供了一种羽绒服专用干洗剂及其制备方法，通过调整组分间的配比，降低了有机溶剂的添加量，同时仍能保持优异的稳定性、去污能力以及渗透效果。
为达到本发明的目的，本发明第一方面提供了一种羽绒服专用干洗剂，按重量百分比计，组分包括：表面活性剂4-7％，溶剂3-7％，渗透剂4-9％，抑菌剂0.1-0.2％，酶制剂0.1-0.2％，水补足余量。
所述表面活性剂包括表面活性剂A，表面活性剂B，表面活性剂C，所述表面活性剂A，表面活性剂B，表面活性剂C重量比为1：(0.2-0.5)：(2-4)。
优选的，所述表面活性剂A，表面活性剂B，表面活性剂C重量比为1：0.3：2。
所述表面活性剂A包括烷基糖苷，烷基醇醚，所述烷基糖苷，烷基醇醚重量比为1：(0.8-1.5)。
优选的，所述表面活性剂A包括烷基糖苷，烷基醇醚，所述烷基糖苷，烷基醇醚重量比为1：1.5。
所述烷基醇醚包括十二烷基醇醚硫酸铵、十八烷基胺聚氧乙烯醚、烷基聚乙二醇醚中的一种。
优选的，所述烷基醇醚包括十二烷基醇醚硫酸铵，品牌：巴斯夫，型号：ASESA。
优选的，烷基糖苷包括C8-C14的烷基糖苷。
优选的，所述烷基糖苷包括C12-C14的烷基糖苷，购自山东金裕世嘉化工有限公司。
所述表面活性剂B包括磺化琥珀酸二辛酯钠盐，牛脂胺聚氧乙烯醚，失水山梨醇脂肪酸酯，山梨醇聚氧乙烯醚油酸酯中的一种。
优选的，所述表面活性剂B包括磺化琥珀酸二辛酯钠盐，购自江苏省海安石油化工厂。
所述表面活性剂C包括C12-C15异构醇乙氧基化物。
优选的，所述表面活性剂C包括C13异构醇乙氧基化物，型号：沙索13/90，品牌：湖北鑫宇宏。
所述溶剂包括乙二醇、丙二醇、丙三醇、丙二醇甲醚、丙二醇乙醚、丙二醇丙醚、丙二醇丁醚、二丙二醇甲醚、二丙二醇乙醚、二丙二醇丙醚、二丙二醇丁醚中至少一种。
优选的，所述溶剂包括丙二醇甲醚。
所述渗透剂包括二甲基亚砜，硫酸化蓖麻油、烷基磺酸钠、烷基苯磺酸钠、中的一种或者多种。
优选的，所述渗透剂包括二甲基亚砜。
所述抑菌剂包括柠檬烯、肉桂醛、丹皮酚、壳聚糖、变性乙醇和柠檬酸钠中至少一种。
优选的，所述抑菌剂包括柠檬烯。
所述酶制剂包括蛋白酶、纤维素酶，所述蛋白酶、纤维素酶重量比为1：(0.5-1)。
优选的，所述酶制剂包括蛋白酶、纤维素酶，所述蛋白酶、纤维素酶重量比为1：0.6。
优选的，所述蛋白酶包括酸性蛋白酶、中性蛋白酶、碱性蛋白酶、木瓜蛋白酶中一种。
进一步优选的，所述蛋白酶包括碱性蛋白酶，购自河南辉腾化工产品销售有限公司。
优选的，所述纤维素酶包括中性纤维素酶，购自夏盛生物科技开发有限公司。
所述表面活性剂和渗透剂的重量比为1：(0.8-1.3)。
优选的，所述表面活性剂和渗透剂的重量比为1：1。
本申请人研究发现，所述溶剂、渗透剂和酶制剂重量比为(5-7)：(5-8)：(0.1-0.15)时，可提高干洗剂的去污和渗透效果，干洗剂接触污渍后，溶剂接触到污渍，溶解污渍表层的同时充分包覆污渍，酶制剂可进一步对污渍进行溶解，为了进一步提高酶制剂的溶解效率，特定比例的渗透剂可加快污渍的分解，同时降低溶剂的添加量，提高干洗剂的安全性，进一步研究发现，溶剂为丙二醇甲醚，渗透剂为二甲基亚砜，可增加干洗剂对油污的清洁能力，尽管溶剂与渗透剂具有较强的油溶性，使得亲水性较差，但在多种表面活性剂的作用下，溶剂和渗透剂的润湿性得到有效提升。
所述溶剂、渗透剂和酶制剂重量比为(5-7)：(5-8)：(0.1-0.15)。
优选的，所述溶剂、渗透剂和酶制剂重量比为7：5：0.1。
本发明第二方面提供了一种羽绒服专用干洗剂及其制备方法，包括以下步骤：
S1，将表面活性剂，溶剂，渗透剂加入到水中，混合均匀，得到混合液1；
S2，将抑菌剂与酶制剂加入到混合液1中，混合均匀，即得。
有益效果：
1.所述溶剂、渗透剂和酶制剂重量比为(5-7)：(5-8)：(0.1-0.15)时，可提高干洗剂的去污和渗透效果。
2.所述酶制剂包括蛋白酶、纤维素酶，所述蛋白酶、纤维素酶重量比为1：(0.5-1)
时，可进一步提高干洗剂对聚酯纤维面料的清洁能力。
3.所述表面活性剂包括表面活性剂A，表面活性剂B，表面活性剂C，所述表面活性剂A，表面活性剂B，表面活性剂C重量比为1：(0.2-0.5)：(2-4)时，可提高干洗剂的稳定性。
4.所述表面活性剂和渗透剂的重量比为1：(0.8-1.3)时，可提高干洗剂的渗透能力，同时降低溶剂的使用量。
具体实施方式
实施例1
一种羽绒服专用干洗剂，按重量百分比计，组分为：表面活性剂5％，溶剂7％，渗透剂5％，抑菌剂0.15％，酶制剂0.1％，水补足余量。
所述表面活性剂包括表面活性剂A，表面活性剂B，表面活性剂C，所述表面活性剂A，表面活性剂B，表面活性剂C重量比为1：0.3：2。
所述表面活性剂A为烷基糖苷，烷基醇醚，所述烷基糖苷，烷基醇醚重量比为1：1.5。
所述烷基醇醚为十二烷基醇醚硫酸铵，品牌：巴斯夫，型号：ASESA。
所述烷基糖苷为C12-C14的烷基糖苷，购自山东金裕世嘉化工有限公司。
所述表面活性剂B为磺化琥珀酸二辛酯钠盐，购自江苏省海安石油化工厂。
所述表面活性剂C为C13异构醇乙氧基化物，型号：沙索13/90，品牌：湖北鑫宇宏。
所述溶剂为丙二醇甲醚(CAS登录号107-98-2)。
所述渗透剂为二甲基亚砜(CAS登录号67-68-5)。
所述抑菌剂为柠檬烯(CAS登录号138-86-3)。
所述酶制剂为蛋白酶、纤维素酶，所述蛋白酶、纤维素酶重量比为1：0.6。
所述蛋白酶为碱性蛋白酶，购自河南辉腾化工产品销售有限公司。
所述纤维素酶为中性纤维素酶，购自夏盛生物科技开发有限公司。
本发明第二方面提供了一种羽绒服专用干洗剂及其制备方法，为以下步骤：
S1，将表面活性剂，溶剂，渗透剂加入到水中，混合均匀，得到混合液1；
S2，将抑菌剂与酶制剂加入到混合液1中，混合均匀，即得。
实施例2
具体实施方式同实施例1；不同的是，实施例2中所述组分为：表面活性剂6％，溶剂6％，渗透剂5％，抑菌剂0.15％，酶制剂0.1％，水补足余量。
实施例3
具体实施方式同实施例1；不同的是，实施例3中所述表面活性剂A，表面活性剂B，表面活性剂C重量比为1：0.2：2.5。
对比例1
具体实施方式同实施例1；不同的是，对比例1中所述表面活性剂A，表面活性剂B，表面活性剂C重量比为1：1：1。
对比例2
具体实施方式同实施例1；不同的是，对比例2中所述组分为：表面活性剂5％，溶剂8％，渗透剂4％，抑菌剂0.15％，酶制剂0.1％，水补足余量。
对比例3
具体实施方式同实施例1；不同的是，对比例3中所述组分为：表面活性剂5％，溶剂9％，渗透剂3％，抑菌剂0.15％，酶制剂0.1％，水补足余量。
性能测试方法
将实施例1-3和对比例1-3中所得干洗剂进行性能测试，测试数据列于表1中。
1)稳定性：高温稳定性-在40℃保持24h，恢复至室温后，观察与实验前是否有明显变化(分层、絮状杂质)；低温稳定性-在-5℃保持24h，恢复至室温后，观察与实验前是否有明显变化(分层、絮状杂质)。
2)去污力：对白色羽绒服上的酒渍、果汁、血渍、油渍喷洒上干洗剂，30s后，进行相同力度的擦拭，直到无残留，记录擦拭次数。
3)渗透力：对白色羽绒服上的油渍喷洒上羽绒服干洗剂，10s后，喷洒擦拭8次，对比残留，分为A\B\C\D四个等级，使用白度测试仪测试(纺织面料白度仪WSB-3)，初始白度为S0，测试白度为S，净率定义为M＝
(S0-S)/S*100％，定义等级A的M为95-100％,等级B的M为85-95％,等级C的M为65-85％,等级D的M为低于65％。
性能测试数据
表1
Claims (10)
1.一种羽绒服专用干洗剂，其特征在于，按重量百分比计，组分包括：表面活性剂4-7％，溶剂3-7％，渗透剂4-9％，抑菌剂0.1-0.2％，酶制剂0.1-0.2％，水补足余量。
2.根据权利要求1所述的一种羽绒服专用干洗剂，其特征在于，所述表面活性剂包括表面活性剂A，表面活性剂B，表面活性剂C，所述表面活性剂A，表面活性剂B，表面活性剂C重量比为1：(0.2-0.5)：(2-4)。
3.根据权利要求2所述的一种羽绒服专用干洗剂，其特征在于，所述表面活性剂A包括烷基糖苷，烷基醇醚，所述烷基糖苷，烷基醇醚重量比为1：(0.8-1.5)。
4.根据权利要求3所述的一种羽绒服专用干洗剂，其特征在于，所述表面活性剂C包括C12-C15异构醇乙氧基化物。
5.根据权利要求4所述的一种羽绒服专用干洗剂，其特征在于，所述酶制剂包括蛋白酶、纤维素酶，所述蛋白酶、纤维素酶重量比为1：(0.5-1)。
6.根据权利要求1或4所述的一种羽绒服专用干洗剂，其特征在于，所述渗透剂包括二甲基亚砜、硫酸化蓖麻油、烷基磺酸钠、烷基苯磺酸钠、中的一种或者多种。
7.根据权利要求6所述的一种羽绒服专用干洗剂，其特征在于，所述抑菌剂包括柠檬烯、肉桂醛、丹皮酚、壳聚糖、变性乙醇和柠檬酸钠中至少一种。
8.根据权利要求1所述的一种羽绒服专用干洗剂，其特征在于，所述表面活性剂和渗透剂的重量比为1：(0.8-1.3)。
9.根据权利要求1所述的一种羽绒服专用干洗剂，其特征在于，所述溶剂、渗透剂和酶制剂重量比为(5-7)：(5-8)：(0.1-0.15)。
10.一种根据权利要求1所述羽绒服专用干洗剂的制备方法，其特征在于，包括以下步骤：
S1，将表面活性剂，溶剂，渗透剂加入到水中，混合均匀，得到混合液1；
S2，将抑菌剂与酶制剂加入到混合液1中，混合均匀，即得。
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