CN116396814A - Functional washing gel and preparation method thereof - Google Patents
Functional washing gel and preparation method thereof Download PDFInfo
- Publication number
- CN116396814A CN116396814A CN202111611615.4A CN202111611615A CN116396814A CN 116396814 A CN116396814 A CN 116396814A CN 202111611615 A CN202111611615 A CN 202111611615A CN 116396814 A CN116396814 A CN 116396814A
- Authority
- CN
- China
- Prior art keywords
- parts
- ether
- essence
- fatty alcohol
- modified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005406 washing Methods 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title abstract description 15
- 238000001879 gelation Methods 0.000 title description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 96
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 46
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 33
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 31
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 31
- 239000002775 capsule Substances 0.000 claims abstract description 30
- 239000002245 particle Substances 0.000 claims abstract description 26
- -1 alkyl glycoside Chemical class 0.000 claims abstract description 23
- 239000007788 liquid Substances 0.000 claims abstract description 20
- 229930182470 glycoside Natural products 0.000 claims abstract description 19
- 108091005804 Peptidases Proteins 0.000 claims abstract description 17
- 239000004365 Protease Substances 0.000 claims abstract description 17
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims abstract description 17
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 17
- 239000011734 sodium Substances 0.000 claims abstract description 17
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 16
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims abstract description 16
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 15
- 150000001412 amines Chemical class 0.000 claims abstract description 15
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 15
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004711 α-olefin Substances 0.000 claims abstract description 15
- 239000002738 chelating agent Substances 0.000 claims abstract description 14
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 14
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 claims abstract description 11
- 239000003755 preservative agent Substances 0.000 claims abstract description 11
- 230000002335 preservative effect Effects 0.000 claims abstract description 11
- 229940079781 sodium cocoyl glutamate Drugs 0.000 claims abstract description 11
- 239000004519 grease Substances 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000003112 inhibitor Substances 0.000 claims abstract description 6
- 239000008187 granular material Substances 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 28
- 238000006243 chemical reaction Methods 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 10
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 claims description 9
- 235000013923 monosodium glutamate Nutrition 0.000 claims description 9
- 229940073490 sodium glutamate Drugs 0.000 claims description 9
- 235000019482 Palm oil Nutrition 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 239000002540 palm oil Substances 0.000 claims description 8
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 6
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 6
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 claims description 6
- 239000003346 palm kernel oil Substances 0.000 claims description 6
- 235000019865 palm kernel oil Nutrition 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 5
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims description 5
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical group [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 5
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 5
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical group C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 claims description 5
- 239000002285 corn oil Substances 0.000 claims description 5
- 235000005687 corn oil Nutrition 0.000 claims description 5
- 229920001519 homopolymer Polymers 0.000 claims description 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 5
- 239000011976 maleic acid Substances 0.000 claims description 5
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 5
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical group O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims description 5
- 229940061605 tetrasodium glutamate diacetate Drugs 0.000 claims description 5
- UZVUJVFQFNHRSY-OUTKXMMCSA-J tetrasodium;(2s)-2-[bis(carboxylatomethyl)amino]pentanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC[C@@H](C([O-])=O)N(CC([O-])=O)CC([O-])=O UZVUJVFQFNHRSY-OUTKXMMCSA-J 0.000 claims description 5
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 239000000796 flavoring agent Substances 0.000 claims description 4
- 235000019634 flavors Nutrition 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 239000005711 Benzoic acid Substances 0.000 claims description 3
- 235000010233 benzoic acid Nutrition 0.000 claims description 3
- 235000012343 cottonseed oil Nutrition 0.000 claims description 3
- 239000002385 cottonseed oil Substances 0.000 claims description 3
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 claims description 3
- 235000010199 sorbic acid Nutrition 0.000 claims description 3
- 239000004334 sorbic acid Substances 0.000 claims description 3
- 229940075582 sorbic acid Drugs 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 2
- 235000019198 oils Nutrition 0.000 claims description 2
- GIYMJJRYEFFRKQ-UHFFFAOYSA-K [Na+].[Na+].[Na+].CNCC(=O)[O-].CNCC(=O)[O-].CNCC(=O)[O-] Chemical compound [Na+].[Na+].[Na+].CNCC(=O)[O-].CNCC(=O)[O-].CNCC(=O)[O-] GIYMJJRYEFFRKQ-UHFFFAOYSA-K 0.000 claims 1
- 239000003599 detergent Substances 0.000 abstract description 17
- 239000003094 microcapsule Substances 0.000 abstract description 8
- 239000002280 amphoteric surfactant Substances 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 239000003205 fragrance Substances 0.000 abstract description 4
- 239000004094 surface-active agent Substances 0.000 abstract description 4
- 239000006260 foam Substances 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000000007 visual effect Effects 0.000 abstract description 3
- 230000036571 hydration Effects 0.000 abstract description 2
- 238000006703 hydration reaction Methods 0.000 abstract description 2
- 239000000686 essence Substances 0.000 abstract 4
- 239000000047 product Substances 0.000 description 11
- 230000006872 improvement Effects 0.000 description 8
- 239000003945 anionic surfactant Substances 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000008280 blood Substances 0.000 description 3
- 210000004369 blood Anatomy 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 235000013336 milk Nutrition 0.000 description 3
- 239000008267 milk Substances 0.000 description 3
- 210000004080 milk Anatomy 0.000 description 3
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 2
- MLDWGLQSBBCMMO-UHFFFAOYSA-N [Na].[Na].[Na].CNCC(=O)O Chemical compound [Na].[Na].[Na].CNCC(=O)O MLDWGLQSBBCMMO-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- 239000012263 liquid product Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 238000012356 Product development Methods 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
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- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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Abstract
The invention relates to the field of laundry detergent, in particular to functional laundry gel and a preparation method thereof, wherein the functional laundry gel comprises the following raw materials: fatty alcohol polyoxyethylene ether sodium sulfate, alpha-olefin sodium sulfonate, branched fatty alcohol polyoxyethylene ether, fatty alcohol polyoxyethylene polyoxypropylene ether, isomeric alcohol ether, end-capped alcohol ether, modified grease, alkyl glycoside, sodium cocoyl glutamate, amine oxide, cross-color inhibitor, liquid protease, chelating agent, granule capsule essence, preservative and water. The functional washing gel and the preparation method thereof reduce foam and have good rinsing property; the addition of the amphoteric surfactant improves the viscosity of the system by utilizing the hydration of the amphoteric surfactant and hydrophilic groups of various surfactants, and has good dispersibility; the visual large-particle essence and small-particle micro-capsule essence reduce the loss of essence volatilization in the production of the laundry detergent product and have better fragrance retaining effect.
Description
Technical Field
The invention relates to the field of laundry detergent, in particular to functional laundry gel and a preparation method thereof.
Background
The detergent is a mixed system compounded by a plurality of surfactants and assistants, the washing powder is composed of linear sodium alkylbenzenesulfonate and assistants, the detergent has strong detergency when in use, but the washed clothes are easy to harden, the irritation to skin is high when the detergent is used, and the soap takes sodium stearate as a main component, so that the detergent is suitable for hand washing, is unsuitable for machine washing and is easy to generate soap scum; the liquid laundry detergent consists of anionic surfactant, nonionic surfactant, auxiliary agent and the like, is convenient to use, mild in performance and good in biodegradability, and is more and more favored by consumers.
The concentration, greenization and individuation of the laundry detergent products are sustainable development directions of the country and industry. In order to meet the personalized and customized market demands, the demands of consumers on the washing functions are further subdivided, and the functions of decontamination or cleaning power, bacteriostasis, sterilization, mite removal and the like are considered as basic functions of the liquid laundry detergent, so that the fashion and artistry of the product are more concerned. Products meeting consumer demand are therefore the subject of laundry detergent product development.
Chinese patent CN105861176 a provides a laundry gel capable of improving cleaning ability and reducing foaming and a preparation method thereof. The washing gel comprises the following components in percentage by mass: 14-20 parts of fatty alcohol polyoxyethylene ether sodium sulfate, 10-15 parts of fatty alcohol polyoxyethylene ether, 4-6 parts of coconut diethanolamide, 2.5-5 parts of sodium citrate, 0.5-1.8 parts of acrylic acid/maleic anhydride copolymer, 0.1-0.15 part of methyl chloroisothiazolinone and 50-70 parts of auxiliary materials. However, the invention only improves the cleaning ability and reduces the foaming of the laundry gel, and does not mention that the product has other functions.
The traditional laundry detergent system is an anionic surfactant-nonionic surfactant compound system, has low viscosity and can not reach a gel state; in addition, if a high molecular polymer thickener, polyacrylic acid, natural organic high molecular and polyurethane are added, the viscosity of the system can be improved, but the dispersibility of the system is poor.
The multifunctional washing gel product has the appearance of gel, high viscosity and good dispersibility, can prevent clothes from color cross, remove protein stains such as blood stains and milk stains, and simultaneously has better fragrance retention effect due to the addition of the visual large-particle essence and the small-particle micro-capsule essence, so that the loss of the volatile essence in the production of the washing liquid product is reduced.
Disclosure of Invention
The invention aims to provide functional laundry gel with strong detergency, low foam, good solubility and dispersibility, cross color prevention, blood stain removal, milk stain removal and other characteristic stains, and long-time fragrance retention effects and a preparation method thereof.
The invention is realized by the following technical scheme: a functional laundry gel comprises the following raw materials in parts by weight:
10-20 parts of fatty alcohol polyoxyethylene ether sodium sulfate, 5-10 parts of alpha-olefin sodium sulfonate, 0.5-5 parts of branched fatty alcohol polyoxyethylene ether, 0.5-5 parts of fatty alcohol polyoxyethylene polyoxypropylene ether, 0.5-5 parts of isomeric alcohol ether, 0.5-5 parts of end-capped alcohol ether, 1-5 parts of modified grease, 1-5 parts of alkyl glycoside, 1-5 parts of cocoyl sodium glutamate, 5-10 parts of amine oxide, 1-5 parts of cross-color inhibitor, 0.1-1 part of liquid protease, 0.1-1 part of chelating agent, 0.1-1 part of granule capsule essence, 0.01-0.1 part of preservative and 40-75 parts of water.
As a further improvement of the technical scheme of the functional washing gel, the modified grease is modified palm oil, modified palm kernel oil, modified rapeseed oil, modified cotton seed oil, modified corn oil, a mixture of the modified palm oil and the palm kernel oil or modified stearic acid.
As a further improvement of the technical scheme of the functional washing gel, the color-cross prevention agent is pyrrolidone, maleic acid/acrylic acid copolymer or acrylic acid homopolymer.
As a further improvement of the technical scheme of the functional washing gel, the chelating agent is disodium ethylenediamine tetraacetate, tetrasodium ethylenediamine tetraacetate, trisodium nitrilotriacetate, tetrasodium glutamate diacetate or trisodium methylglycine diacetate.
As a further improvement of the technical scheme of the functional washing gel, the preservative is benzisothiazolinone, a mixture of methyl chloroisothiazolinone and methyl isothiazolinone, nipagin ester, sorbic acid and salts thereof or benzoic acid and salts thereof.
As a further improvement of the technical scheme of the functional washing gel, the granular capsule essence comprises at least one size granular capsule essence.
As a further improvement of the technical scheme of the functional washing gel, the granular capsule essence comprises granular capsule essence with two sizes, wherein 0.05-0.5 part of small-grain microcapsule essence and 0.05-0.5 part of large-grain capsule essence.
The invention further provides a preparation method of the functional washing gel, which comprises the following steps:
(1) Adding water into a reaction container, sequentially adding branched chain fatty alcohol polyoxyethylene ether, fatty alcohol polyoxyethylene polyoxypropylene ether, isomeric alcohol ether, end-capped alcohol ether and modified grease, stirring fatty alcohol polyoxyethylene ether sodium sulfate and alpha-olefin sodium sulfonate, and dissolving and uniformly mixing the materials;
(2) Adding alkyl glycoside, stirring, adding sodium cocoyl glutamate and color-mixing preventing agent, and stirring;
(3) Adding liquid protease and chelating agent under stirring;
(4) And finally adding amine oxide, large-particle capsule essence, small-particle capsule essence and preservative, and uniformly stirring to obtain the functional washing gel.
As a further improvement of the technical scheme of the preparation method, in the step (2), after the alkyl glycoside is added, the sodium cocoyl glutamate and the color-mixing preventing agent are added after stirring for 5-10 minutes.
As a further improvement of the technical scheme of the preparation method, in the step (3), the temperature in the reaction vessel is ensured to be lower than 40 ℃, and then the liquid protease and the chelating agent are added.
According to the functional washing gel and the preparation method thereof, the anionic surfactant sodium alcohol polyoxyethylene ether sulfate (AES), alpha-olefin sodium sulfonate (AOS), branched chain and end-capped nonionic surfactants (fatty alcohol polyoxyethylene polyoxypropylene ether, isomeric alcohol ether and end-capped alcohol ether) and alkyl glycoside (APG) are adopted, and the amphoteric surfactant (cocoyl sodium glutamate and amine oxide) is not added into a multi-component compound system, so that the viscosity of the product reaches about 3000 centipoise, and in the using process, the product has good detergency due to the addition of the anionic surfactant, the fatty alcohol polyoxyethylene polyoxypropylene ether, isomeric alcohol ether and end-capped alcohol ether are added, so that the product has excellent penetrability and emulsifying power, and the addition of the alkyl glycoside and cocoyl sodium glutamate greatly reduces the irritation of the anionic surfactant and the nonionic surfactant, and simultaneously reduces the foam, so that the product has good rinsing property; the addition of the amphoteric surfactant improves the viscosity of the system by utilizing the hydration of the amphoteric surfactant and hydrophilic groups of various surfactants, and has good dispersibility; the visual large-particle essence and small-particle micro-capsule essence reduce the loss of essence volatilization in the production of the laundry detergent product and have better fragrance retaining effect.
Detailed Description
The following description of the present invention will be made clearly and fully, and it is apparent that the embodiments described are some, but not all, of the embodiments of the present invention. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
The invention provides a specific embodiment of functional washing gel, which comprises the following raw materials in parts by weight: 10-20 parts of fatty alcohol polyoxyethylene ether sodium sulfate, 5-10 parts of alpha-olefin sodium sulfonate, 0.5-5 parts of branched fatty alcohol polyoxyethylene ether, 0.5-5 parts of fatty alcohol polyoxyethylene polyoxypropylene ether, 0.5-5 parts of isomeric alcohol ether, 0.5-5 parts of end-capped alcohol ether, 1-5 parts of modified grease, 1-5 parts of alkyl glycoside, 1-5 parts of cocoyl sodium glutamate, 5-10 parts of amine oxide, 1-5 parts of cross-color inhibitor, 0.1-1 part of liquid protease, 0.1-1 part of chelating agent, 0.1-1 part of granule capsule essence, 0.01-0.1 part of preservative and 40-75 parts of water.
Further, the specific embodiment of the functional washing gel is prepared from the following raw materials in parts by weight: 10-20 parts of fatty alcohol polyoxyethylene ether sodium sulfate, 5-10 parts of alpha-olefin sodium sulfonate, 0.5-5 parts of branched fatty alcohol polyoxyethylene ether, 0.5-5 parts of fatty alcohol polyoxyethylene polyoxypropylene ether, 0.5-5 parts of isomeric alcohol ether, 0.5-5 parts of end-capped alcohol ether, 1-5 parts of modified grease, 1-5 parts of alkyl glycoside, 1-5 parts of cocoyl sodium glutamate, 5-10 parts of amine oxide, 1-5 parts of cross-color inhibitor, 0.1-1 part of liquid protease, 0.1-1 part of chelating agent, 0.1-1 part of granule capsule essence, 0.01-0.1 part of preservative and 40-75 parts of water.
In one embodiment provided by the invention, the modified oil is modified palm oil, modified palm kernel oil, modified rapeseed oil, modified cottonseed oil, modified corn oil, a mixture of modified palm oil and palm kernel oil, or modified stearic acid. The color-cross-linking agent is pyrrolidone, maleic acid/acrylic acid copolymer or acrylic acid homopolymer. The chelating agent is disodium edetate, tetrasodium edetate, trisodium nitrilotriacetate, tetrasodium glutamate diacetate or trisodium methylglycine diacetate. The preservative is benzisothiazolinone, a mixture of methyl chloroisothiazolinone and methyl isothiazolinone, nipagin ester, sorbic acid and salts thereof or benzoic acid and salts thereof. . The particulate capsule flavor includes at least one size particulate capsule flavor.
Specifically, the granular capsule essence comprises granular capsule essence with two sizes, wherein 0.05-0.5 part of small-particle microcapsule essence and 0.05-0.5 part of large-particle capsule essence.
The invention also provides a preparation method of the functional washing gel, which comprises the following steps:
(1) Adding water into a reaction container, sequentially adding branched chain fatty alcohol polyoxyethylene ether, fatty alcohol polyoxyethylene polyoxypropylene ether, isomeric alcohol ether, end-capped alcohol ether and modified grease, stirring fatty alcohol polyoxyethylene ether sodium sulfate and alpha-olefin sodium sulfonate, and dissolving and uniformly mixing the materials;
(2) Adding alkyl glycoside, stirring, adding sodium cocoyl glutamate and color-mixing preventing agent, and stirring;
(3) Adding liquid protease and chelating agent under stirring;
(4) And finally adding amine oxide, large-particle capsule essence, small-particle capsule essence and preservative, and uniformly stirring to obtain the functional washing gel.
The reaction vessel in the steps (1), (2) and (3) may be a reaction kettle or a homogenizer. However, the reaction vessel used in the step (4) may not use a homogenizer.
In the specific implementation, in the step (2), after adding alkyl glycoside, stirring for 5-10 minutes, and then adding sodium cocoyl glutamate and the color-mixing inhibitor. Naturally, after adding the sodium cocoyl glutamate and the color-mixing preventing agent, stirring for 5-10 minutes, and uniformly stirring.
Specifically, in the step (3), the temperature in the reaction vessel is ensured to be lower than 40 ℃, then the liquid protease and the chelating agent are added, and the mixture is stirred for 5 to 10 minutes, so that the mixture can be uniformly stirred.
In order to more clearly describe the technical scheme of the present invention, the following detailed description is made by specific examples.
Example 1
A preparation method of functional laundry gel comprises the following raw materials in percentage by weight:
10 parts of fatty alcohol polyoxyethylene ether sodium sulfate, 10 parts of alpha-olefin sodium sulfonate, 5 parts of branched fatty alcohol polyoxyethylene ether, 2 parts of fatty alcohol polyoxyethylene polyoxypropylene ether, 2 parts of isomeric alcohol ether, 5 parts of capped alcohol ether, 2 parts of modified palm oil and fat, 2 parts of alkyl glycoside (APG), 2 parts of cocoyl sodium glutamate, 8 parts of amine oxide, 2 parts of maleic acid/acrylic acid copolymer, 0.3 part of liquid protease, 0.2 part of tetra sodium ethylenediamine tetraacetate, 0.1 part of large-particle capsule essence, 0.15 part of small-particle microcapsule essence, 0.04 part of benzisothiazolinone and 56.7 parts of water.
The components are prepared according to the following processes:
(1) 56.7 parts of water is added into a reaction kettle, and 5 parts of branched chain fatty alcohol polyoxyethylene ether, 2 parts of fatty alcohol polyoxyethylene polyoxypropylene ether, 2 parts of isomeric alcohol ether, 5 parts of end capping alcohol ether, 2 parts of modified palm oil, 10 parts of fatty alcohol polyoxyethylene ether sodium sulfate and 10 parts of alpha-olefin sodium sulfonate are sequentially added, and the temperature is heated to 50+/-5 ℃ and stirred until the components are completely dissolved.
(2) 2 parts of alkyl glycoside (APG)) were added to the reaction vessel and stirred for 5 minutes, and 2 parts of sodium cocoyl glutamate and 2 parts of maleic acid/acrylic acid copolymer were added and stirred for another 5 minutes.
(3) And (3) after the temperature in the reaction kettle is reduced to below 40 ℃, 0.3 part of liquid protease and 0.2 part of tetrasodium ethylenediamine tetraacetate are added in sequence under the stirring condition, and the stirring is carried out for 5 minutes.
(4) 8 parts of amine oxide, 0.1 part of large-particle capsule essence, 0.15 part of small-particle microcapsule essence and 0.04 part of benzisothiazolinone are added into a reaction kettle, and the mixture is slowly stirred in the reaction kettle until the mixture is uniformly mixed. The pH of the functional laundry gel is 7.8.
Example 2
A preparation method of functional laundry gel comprises the following raw materials in percentage by weight:
20 parts of fatty alcohol polyoxyethylene ether sodium sulfate, 8 parts of alpha-olefin sodium sulfonate, 3 parts of branched fatty alcohol polyoxyethylene ether, 5 parts of fatty alcohol polyoxyethylene polyoxypropylene ether, 0.5 part of isomeric alcohol ether, 2 parts of end capping alcohol ether, 5 parts of modified rapeseed oil, 1 part of alkyl glycoside (APG), 5 parts of cocoyl sodium glutamate, 5 parts of amine oxide, 5 parts of polyacrylamide homopolymer, 0.1 part of liquid protease, 0.1 part of disodium edetate, 0.5 part of large-particle capsule essence, 0.05 part of small-particle capsule essence, 0.01 part of a mixture of methyl chloroisothiazolinone and methyl isothiazolinone (the mass ratio is 1:2) and 75 parts of water.
The components are prepared according to the following processes:
(1) 75 parts of water is added into a reaction kettle, and 3 parts of branched chain fatty alcohol polyoxyethylene ether, 5 parts of fatty alcohol polyoxyethylene polyoxypropylene ether, 0.5 part of isomeric alcohol ether, 2 parts of end capping alcohol ether, 5 parts of modified rapeseed oil, 20 parts of fatty alcohol polyoxyethylene ether sodium sulfate and 8 parts of alpha-olefin sodium sulfonate are sequentially added, and are mixed at high speed for 10 minutes by a homogenizer until the components are completely dissolved.
(2) 1 part of alkyl glycoside (APG) was added to the reaction vessel and stirred for 10 minutes, followed by addition of 5 parts of sodium cocoyl glutamate and 5 parts of polyacrylamide homopolymer and further stirring for 10 minutes.
(3) While stirring, 0.1 part of liquid protease and 0.1 part of disodium ethylenediamine tetraacetate were added in this order, and stirred for 10 minutes.
(4) 5 parts of amine oxide, 0.5 part of large-particle capsule essence, 0.05 part of small-particle capsule essence and 0.01 part of a mixture of methyl chloroisothiazolinone and methyl isothiazolinone are added into a reaction kettle, and the mixture is slowly stirred in the reaction kettle until the mixture is uniformly mixed, so that the operation of the step of high-speed homogenization is not required. The pH of the functional laundry gel is 8.0.
Example 3
A preparation method of functional laundry gel comprises the following raw materials in percentage by weight:
15 parts of fatty alcohol polyoxyethylene ether sodium sulfate, 5 parts of alpha-olefin sodium sulfonate, 0.5 part of branched fatty alcohol polyoxyethylene ether, 0.5 part of fatty alcohol polyoxyethylene polyoxypropylene ether, 5 parts of isomeric alcohol ether, 0.5 part of capped alcohol ether, 1 part of modified corn oil, 5 parts of alkyl glycoside (APG), 1 part of cocoyl sodium glutamate, 10 parts of amine oxide, 1 part of pyrrolidone, 1 part of liquid protease, 1 part of tetrasodium glutamate diacetate, 0.05 part of large-particle capsule essence, 0.5 part of small-particle microcapsule essence, 0.1 part of sodium benzoate and 40 parts of water.
The components are prepared according to the following processes:
(1) Adding 40 parts of water into a reaction kettle, sequentially adding 0.5 part of branched chain fatty alcohol polyoxyethylene ether, 0.5 part of fatty alcohol polyoxyethylene polyoxypropylene ether, 5 parts of isomeric alcohol ether, 0.5 part of end capping alcohol ether, 1 part of modified corn oil, 15 parts of fatty alcohol polyoxyethylene ether sodium sulfate and 5 parts of alpha-olefin sodium sulfonate, and mixing at a high speed by a homogenizer until the components are completely dissolved.
(2) Adding 5 parts of alkyl glycoside (APG) into a reaction kettle, stirring for 8 minutes, adding 1 part of sodium cocoyl glutamate and 1 part of pyrrolidone, and stirring for 8 minutes;
(3) 1 part of liquid protease and 1 part of tetrasodium glutamate diacetate are sequentially added under stirring, and stirring is carried out for 8 minutes.
(4) 10 parts of amine oxide, 0.05 part of large-particle capsule essence, 0.5 part of small-particle capsule essence and 0.1 part of sodium benzoate are added into a reaction kettle, and the mixture is slowly stirred in the reaction kettle until the mixture is uniformly mixed, so that the step of high-speed homogenization is not needed. The pH of the functional laundry gel is 7.9.
After the components are compounded, the product formed by the invention has the advantages of concentrated laundry detergent and fragrance-retaining beads, is quick to dissolve and convenient to use, has the functions of preventing color cross of clothes and removing protein stains such as blood stains and milk stains, is mild and non-irritating, does not contain phosphate, fluorescent whitening agent and alkylphenol polyoxyethylene, has no pollution to the environment, and accords with the development direction of environmental protection, energy saving and water saving to low carbon economy in the national detergent field.
The performance test results of the samples prepared in the above examples are shown in the following table:
the performance test results are all carried out according to the QB/T1224 clothing liquid detergent standard. The concentration of the sample is 1 per mill when the detergency is tested; viscosity testing was performed according to the GB/T15357 method for testing the viscosity of liquid products using a surfactant and detergent rotational viscometer. From the experimental results in the table, each performance of the samples prepared in the above examples is beyond the QB/T1224 standard.
Finally, it should be noted that: the above embodiments are only for illustrating the technical solution of the present invention, and not for limiting the same; although the invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical scheme described in the foregoing embodiments can be modified or some or all of the technical features thereof can be replaced by equivalents; such modifications and substitutions do not depart from the spirit of the invention.
Claims (10)
1. The functional laundry gel is characterized by comprising the following raw materials in parts by weight:
10-20 parts of fatty alcohol polyoxyethylene ether sodium sulfate, 5-10 parts of alpha-olefin sodium sulfonate, 0.5-5 parts of branched fatty alcohol polyoxyethylene ether, 0.5-5 parts of fatty alcohol polyoxyethylene polyoxypropylene ether, 0.5-5 parts of isomeric alcohol ether, 0.5-5 parts of end-capped alcohol ether, 1-5 parts of modified grease, 1-5 parts of alkyl glycoside, 1-5 parts of cocoyl sodium glutamate, 5-10 parts of amine oxide, 1-5 parts of cross-color inhibitor, 0.1-1 part of liquid protease, 0.1-1 part of chelating agent, 0.1-1 part of granule capsule essence, 0.01-0.1 part of preservative and 40-75 parts of water.
2. The functional laundry gel of claim 1, wherein the modified oil is modified palm oil, modified palm kernel oil, modified rapeseed oil, modified cottonseed oil, modified corn oil, a mixture of modified palm oil and palm kernel oil, or modified stearic acid.
3. A functional laundry gel according to claim 1, wherein the anti-cross-color agent is a pyrrolidone, a maleic acid/acrylic acid copolymer or an acrylic acid homopolymer.
4. The functional laundry gel of claim 1, wherein the chelating agent is disodium edetate, tetrasodium edetate, trisodium nitrilotriacetate, tetrasodium glutamate diacetate, or trisodium methylglycinate.
5. The functional laundry gel of claim 1, wherein the preservative is benzisothiazolinone, a mixture of methyl chloroisothiazolinone and methyl isothiazolinone, nipagin ester, sorbic acid and salts thereof, or benzoic acid and salts thereof.
6. A functional laundry gel according to claim 1, wherein the particulate encapsulated flavour comprises at least one size of particulate encapsulated flavour.
7. The functional laundry gel of claim 6, wherein the particulate encapsulated essence comprises two sizes of particulate encapsulated essence, wherein the small particulate encapsulated essence is 0.05-0.5 parts and the large particulate encapsulated essence is 0.05-0.5 parts.
8. A method of preparing a functional laundry gel according to any one of claims 1 to 7, comprising the steps of:
(1) Adding water into a reaction container, sequentially adding branched chain fatty alcohol polyoxyethylene ether, fatty alcohol polyoxyethylene polyoxypropylene ether, isomeric alcohol ether, end-capped alcohol ether and modified grease, stirring fatty alcohol polyoxyethylene ether sodium sulfate and alpha-olefin sodium sulfonate, and dissolving and uniformly mixing the materials;
(2) Adding alkyl glycoside, stirring, adding sodium cocoyl glutamate and color-mixing preventing agent, and stirring;
(3) Adding liquid protease and chelating agent under stirring;
(4) And finally adding amine oxide, large-particle capsule essence, small-particle capsule essence and preservative, and uniformly stirring to obtain the functional washing gel.
9. The method for preparing functional laundry gel according to claim 8, wherein in the step (2), after adding alkyl glycoside, stirring for 5-10 minutes, and then adding sodium cocoyl glutamate and anti-cross color agent.
10. The method of preparing a functional laundry gel according to claim 8, wherein in step (3), the liquid protease and the chelating agent are added while ensuring the temperature in the reaction vessel is lower than 40 ℃.
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