CN116376284B - Polymer friction plate and application thereof in wind power sliding bearing - Google Patents

Polymer friction plate and application thereof in wind power sliding bearing Download PDF

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Publication number
CN116376284B
CN116376284B CN202310659988.1A CN202310659988A CN116376284B CN 116376284 B CN116376284 B CN 116376284B CN 202310659988 A CN202310659988 A CN 202310659988A CN 116376284 B CN116376284 B CN 116376284B
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parts
friction plate
fiber
injection molding
epoxypropyl
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CN116376284A (en
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王建
穆崇
翟政
牟瑞晨
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Hengshui Zhongcheng Friction Material Co ltd
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Hengshui Zhongcheng Friction Material Co ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/02Polythioethers; Polythioether-ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/08Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/70Wind energy
    • Y02E10/72Wind turbines with rotation axis in wind direction

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Wind Motors (AREA)

Abstract

The invention relates to the technical field of polymer composite materials, and provides a polymer friction plate and application thereof in a wind power sliding bearing. The high polymer friction plate comprises the following components in parts by mass: 20-40 parts of PA66, 60-80 parts of PPS, 5-10 parts of fiber, 10-30 parts of filler and 2-5 parts of compatilizer; the compatibilizing agent comprises 1, 2-epoxyeicosane and/or bis (2, 3-epoxypropyl) isophthalate. Through the technical scheme, the problems of low tensile strength, low impact strength and low friction coefficient of the PPS and PA66 composite material in the related technology are solved.

Description

Polymer friction plate and application thereof in wind power sliding bearing
Technical Field
The invention relates to the technical field of polymer composite materials, in particular to a polymer friction plate and application thereof in a wind power sliding bearing.
Background
The wind power yaw brake has the following functions in the wind turbine generator system: when the wind direction changes, the yaw brake pressure is released, and a certain damping force is kept by using lower working pressure, so that the fan is ensured to run stably, and the damage of a fan gear and a connecting structural member is avoided. When the direction of the fan is adjusted in place, the yaw brake is pressurized to use larger working pressure, so that the fan is always aligned to the wind direction, and the wind direction deviation is avoided, and the wind power efficiency is reduced.
Early wind-powered electricity generation yaw brake mainly takes initiative formula as the main part, and the fan adopts ball bearing mode to bear fan cabin, generator, upper portion fan weight such as blade, and wherein yaw friction disc mainly plays friction damping effect. Along with the reform of fan design theory, transition is towards slide bearing mode now, and the weight of fan upper portion cabin, generator and blade is born by the friction disc promptly, has reduced the input of driftage bearing, but has put forward higher requirement to the friction disc.
At present, more than 90% of fan main machine manufacturers adopt a sliding bearing mode, so that the market demand of friction plates is greatly increased, but the existing resin-based friction plates have the problems of low mechanical strength and easy fragmentation, so that the friction plates with high mechanical strength and good impact toughness are necessary to be provided, and meanwhile, a large amount of heat is generated due to friction, so that higher requirements are also provided for the heat resistance of the friction plates.
Along with the continuous development of materials, researchers find that polyphenylene sulfide (PPS) has good heat resistance, chemical resistance and flame resistance, but has the defect of poor impact toughness, while PA66 has good wear resistance and impact toughness, so that a composite material obtained by blending PPS and PA66 has good characteristics of both, not only has good heat resistance, chemical resistance and flame resistance, but also has good wear resistance and impact toughness, and is more suitable for being used as a base material of a friction plate. However, the greatest problem is that the PPS and the PA66 are easy to generate serious phase separation phenomenon in the temperature reduction process after the processing of the composite material, so that the bonding force of the two-phase interface is weaker, and the tensile strength, the impact strength and the friction coefficient of the composite material are not ideal.
Disclosure of Invention
The invention provides a high molecular friction plate and application thereof in a wind power sliding bearing, and solves the problems of low tensile strength, low impact strength and low friction coefficient of a PPS and PA66 composite material in the related technology.
The technical scheme of the invention is as follows:
the high polymer friction plate comprises the following components in parts by mass: 20-40 parts of PA66, 60-80 parts of PPS, 5-10 parts of fiber, 10-30 parts of filler and 2-5 parts of compatilizer;
the compatibilizing agent comprises 1, 2-epoxyeicosane and/or bis (2, 3-epoxypropyl) isophthalate.
As a further embodiment, the compatibilizing agent comprises 1, 2-epoxyeicosane and bis (2, 3-epoxypropyl) isophthalate.
As a further technical scheme, the mass ratio of the 1, 2-epoxyeicosane to the di (2, 3-epoxypropyl) isophthalate is 1-3:3-1.
As a further technical scheme, the mass ratio of the 1, 2-epoxyeicosane to the di (2, 3-epoxypropyl) isophthalate is 1:1.
As a further technical scheme, the fiber comprises one or more of aramid fiber, acrylic fiber, carbon fiber and glass fiber.
As a further technical scheme, the filler comprises one or more of antimony trisulfide, graphite, barium sulfate, silicate, zirconium dioxide and silicon dioxide.
The invention also provides a preparation method of the high polymer friction plate, which comprises the following steps: and mixing the components in parts by mass, and performing injection molding to obtain the high-molecular friction plate.
As a further technical scheme, the method further comprises extrusion granulation and drying after mixing and before injection molding.
As a further technical scheme, during injection molding, the injection molding temperature is 260-300 ℃ and the injection molding time is 5-7 s;
and (3) maintaining the pressure for 4-6 s at 50-70 bar after injection molding is completed.
The invention also provides an application of the high polymer friction plate or the high polymer friction plate obtained by the preparation method in a wind power sliding bearing.
The working principle and the beneficial effects of the invention are as follows:
1. according to the invention, 1, 2-epoxyeicosane and/or di (2, 3-epoxypropyl) isophthalate is used as a compatilizer between PPS and PA66, so that the tensile strength, impact strength and friction coefficient of a high-molecular friction plate prepared by taking PPS and PA66 as matrix materials are improved, the problems that in the prior art, serious phase separation phenomenon is easy to occur between PPS and PA66 in the cooling process after the PPS and PA66 composite materials are processed, the bonding force of two-phase interfaces is weaker, and the tensile strength, impact strength and friction coefficient of the composite materials are reduced are solved, and the effect of improving the tensile strength, impact strength and friction coefficient of the high-molecular friction plate is achieved.
2. According to the invention, the compatilizer is limited to 1, 2-epoxyeicosane and di (2, 3-epoxypropyl) isophthalate with the mass ratio of 1-3:3-1, so that the tensile strength, impact strength and friction coefficient of the high molecular friction plate are further improved.
Detailed Description
The technical solutions of the embodiments of the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention, and it is apparent that the described embodiments are only some embodiments of the present invention, not all embodiments. All other embodiments, which can be made by one of ordinary skill in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Example 1
30 parts of PA66, 70 parts of PPS, 2 parts of carbon fiber, 2 parts of aramid fiber, 3 parts of acrylic fiber, 1 part of glass fiber, 3 parts of antimony trisulfide, 2 parts of graphite, 3 parts of barium sulfate, 3 parts of calcium silicate, 1 part of zirconium silicate, 2 parts of zirconium dioxide, 6 parts of silicon dioxide and 2 parts of 1, 2-eicosane oxide are premixed in a stirrer, melted, blended, extruded and granulated by a double screw extruder at 280 ℃ and 300r/min, dried for 5h at 90 ℃, added into an injection molding machine at 300-280-270-260 ℃ respectively for 6s, and subjected to pressure maintaining for 5s at 60bar, and cooled to obtain the high polymer friction plate.
Example 2
30 parts of PA66, 70 parts of PPS, 2 parts of carbon fiber, 2 parts of aramid fiber, 3 parts of acrylic fiber, 1 part of glass fiber, 3 parts of antimony trisulfide, 2 parts of graphite, 3 parts of barium sulfate, 3 parts of calcium silicate, 1 part of zirconium silicate, 2 parts of zirconium dioxide, 6 parts of silicon dioxide and 2 parts of bis (2, 3-epoxypropyl) isophthalate are premixed in a stirrer, melted, blended, extruded and granulated by a double screw extruder at 280 ℃ and 300r/min, dried for 5 hours at 90 ℃, added into an injection molding machine with four areas of 300-280-270-260 ℃ respectively for 6 seconds, and kept at 60bar pressure for 5 seconds after cooling, thus obtaining the high molecular friction plate.
Example 3
30 parts of PA66, 70 parts of PPS, 2 parts of carbon fiber, 2 parts of aramid fiber, 3 parts of acrylic fiber, 1 part of glass fiber, 3 parts of antimony trisulfide, 2 parts of graphite, 3 parts of barium sulfate, 3 parts of calcium silicate, 1 part of zirconium silicate, 2 parts of zirconium dioxide, 6 parts of silicon dioxide, 1 part of 1, 2-eicosane oxide and 3 parts of bis (2, 3-epoxypropyl) isophthalate are premixed in a stirrer, melted, blended, extruded and granulated by a double-screw extruder at 280 ℃ and 300r/min, dried at 90 ℃ for 5 hours, then added into an injection molding machine with four areas of 300-280-270-260 ℃ respectively for 6 seconds of injection molding, kept at 60bar pressure for 5 seconds, and cooled to obtain the high-molecular friction plate.
Example 4
30 parts of PA66, 70 parts of PPS, 2 parts of carbon fiber, 2 parts of aramid fiber, 3 parts of acrylic fiber, 1 part of glass fiber, 3 parts of antimony trisulfide, 2 parts of graphite, 3 parts of barium sulfate, 3 parts of calcium silicate, 1 part of zirconium silicate, 2 parts of zirconium dioxide, 6 parts of silicon dioxide, 2 parts of 1, 2-eicosane oxide and 2 parts of bis (2, 3-epoxypropyl) isophthalate are premixed in a stirrer, melted, blended, extruded and granulated by a double-screw extruder at 280 ℃ and 300r/min, dried at 90 ℃ for 5 hours, then added into an injection molding machine with four areas of 300-280-270-260 ℃ respectively for 6 seconds of injection molding, kept at 60bar pressure for 5 seconds, and cooled to obtain the high-molecular friction plate.
Example 5
30 parts of PA66, 70 parts of PPS, 2 parts of carbon fiber, 2 parts of aramid fiber, 3 parts of acrylic fiber, 1 part of glass fiber, 3 parts of antimony trisulfide, 2 parts of graphite, 3 parts of barium sulfate, 3 parts of calcium silicate, 1 part of zirconium silicate, 2 parts of zirconium dioxide, 6 parts of silicon dioxide, 3 parts of 1, 2-eicosane oxide and 1 part of bis (2, 3-epoxypropyl) isophthalate are premixed in a stirrer, melted, blended, extruded and granulated by a double-screw extruder at 280 ℃ and 300r/min, dried at 90 ℃ for 5 hours, then added into an injection molding machine with four areas of 300-280-270-260 ℃ respectively for 6 seconds of injection molding, kept at 60bar pressure for 5 seconds, and cooled to obtain the high-molecular friction plate.
Example 6
20 parts of PA66, 80 parts of PPS, 2 parts of carbon fiber, 2 parts of aramid fiber, 1 part of glass fiber, 2 parts of antimony trisulfide, 3 parts of graphite, 4 parts of zirconium silicate, 1 part of silicon dioxide, 1 part of 1, 2-epoxyeicosane and 1 part of bis (2, 3-epoxypropyl) isophthalate are premixed in a stirrer, melted, blended, extruded and granulated by a double screw extruder at 280 ℃ and 300r/min, dried at 90 ℃ for 5 hours, added into an injection molding machine with four areas of 300-280-270-260 ℃ respectively for 5 seconds of injection molding, and subjected to pressure maintaining for 6 seconds under 50bar pressure, and cooled to obtain the high polymer friction plate.
Example 7
Premixing 40 parts of PA66, 60 parts of PPS, 5 parts of carbon fiber, 5 parts of glass fiber, 10 parts of zirconium silicate, 20 parts of silicon dioxide, 2.5 parts of 1, 2-epoxyeicosane and 2.5 parts of di (2, 3-epoxypropyl) isophthalate in a stirrer, carrying out melt blending extrusion granulation by a double-screw extruder at 280 ℃ and 300r/min, drying at 90 ℃ for 5h, adding into an injection molding machine with four areas of 300-280-270-260 ℃ respectively for 7s of injection molding, maintaining the pressure for 4s under 70bar pressure, and cooling to obtain the high molecular friction plate.
Comparative example 1
The only difference from example 1 is that no 1, 2-epoxyeicosane was added.
Performance test:
(1) Reference is made to GB/T1040.2-2022 determination of tensile Properties of plastics part 2: test conditions for molded and extruded plastics the tensile strength was tested in the method of;
(2) The notch impact strength is tested by referring to the method of GB/T1843-2008 "determination of Plastic cantilever impact Strength";
(3) The materials obtained in examples 1 to 7 and comparative example 1 were respectively prepared into test bars of 30mm×7mm×6mm, 3 were prepared in parallel, and the average friction coefficient was tested on a frictional wear test instrument under a test load of 200N at a rotation speed of 200r/min for a test time of 3600s.
The test results are recorded in table 1.
TABLE 1 tensile Strength, notched impact Strength and average Friction coefficient of Polymer Friction plates
As can be seen from Table 1, the tensile strength of the high molecular friction plate provided by the invention is more than 72.1MPa, and the notch impact strength is 63 kJ/m 2 The average friction coefficient is above 0.427, and the friction material has good mechanical property and friction property.
Example 1 in comparison with comparative example 1, 2-epoxyeicosane was added in example 1, and 1, 2-epoxyeicosane was not added in comparative example 1, and the tensile strength, notched impact strength and average friction coefficient of the polymer friction plate obtained in example 1 were higher than those of comparative example 1. The compatibility between PA66 and PPS can be improved by adding 1, 2-epoxy eicosane, and the mechanical property and the friction property of the high polymer friction plate are improved.
Examples 1 to 2 were compared with examples 3 to 5, 1, 2-epoxyeicosane was used in example 1, bis (2, 3-epoxypropyl) isophthalate was used in example 2, 1, 2-epoxyeicosane and bis (2, 3-epoxypropyl) isophthalate were used in examples 3 to 5, and the tensile strength, notched impact strength and average friction coefficient of the polymer friction plate obtained in examples 1 to 2 were inferior to those of examples 3 to 5. The compatibility between PA66 and PPS is improved better by using 1, 2-epoxyeicosane and di (2, 3-epoxypropyl) isophthalate together than by using single 1, 2-epoxyeicosane or di (2, 3-epoxypropyl) isophthalate, and the mechanical property and the friction property of the high polymer friction plate can be greatly improved by using 1, 2-epoxyeicosane and di (2, 3-epoxypropyl) isophthalate.
The foregoing description of the preferred embodiments of the invention is not intended to be limiting, but rather is intended to cover all modifications, equivalents, alternatives, and improvements that fall within the spirit and scope of the invention.

Claims (6)

1. The high polymer friction plate is characterized by comprising the following components in parts by mass: 20-40 parts of PA66, 60-80 parts of PPS, 5-10 parts of fiber, 10-30 parts of filler and 2-5 parts of compatilizer;
the compatilizer comprises 1, 2-epoxyeicosane and di (2, 3-epoxypropyl) isophthalate;
the mass ratio of the 1, 2-epoxyeicosane to the di (2, 3-epoxypropyl) isophthalate is 1-3:3-1;
the fiber comprises one or more of aramid fiber, acrylic fiber, carbon fiber and glass fiber;
the filler comprises one or more of antimony trisulfide, graphite, barium sulfate, silicate, zirconium dioxide and silicon dioxide.
2. The polymeric friction plate of claim 1, wherein the mass ratio of 1, 2-epoxyeicosane to di (2, 3-epoxypropyl) isophthalate is 1:1.
3. The method for preparing the polymer friction plate according to any one of claims 1-2, which is characterized by comprising the following steps: and mixing the components in parts by mass, and performing injection molding to obtain the high-molecular friction plate.
4. The method for producing a polymer friction plate according to claim 3, further comprising extrusion granulation and drying after mixing and before injection molding.
5. The method for preparing the polymer friction plate according to claim 3, wherein the injection molding is carried out at a temperature of 260-300 ℃, a pressure of 30-100 bar and a time of 5-7 s;
and (3) maintaining the pressure for 4-6 s at 50-70 bar after injection molding is completed.
6. The use of a polymer friction plate according to any one of claims 1-2 or a polymer friction plate obtained by the preparation method according to any one of claims 3-5 in a wind-powered sliding bearing.
CN202310659988.1A 2023-06-06 2023-06-06 Polymer friction plate and application thereof in wind power sliding bearing Active CN116376284B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005264349A (en) * 2004-03-16 2005-09-29 Toray Ind Inc Polyphenylene sulfide fiber and industrial textile
CN102705410A (en) * 2012-06-15 2012-10-03 株洲时代新材料科技股份有限公司 Composite friction plate and preparation method thereof
CN102775788A (en) * 2012-07-16 2012-11-14 大连工业大学 Preparation method of wear-resisting composite material
CN104804419A (en) * 2015-04-22 2015-07-29 合肥康龄养生科技有限公司 Nylon composite with lower friction coefficient and excellent lubricity and preparation method thereof
EP3635036A1 (en) * 2017-06-07 2020-04-15 Solvay Specialty Polymers USA, LLC Process for preparing particles of polyphenylene sulfide polymer

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005264349A (en) * 2004-03-16 2005-09-29 Toray Ind Inc Polyphenylene sulfide fiber and industrial textile
CN102705410A (en) * 2012-06-15 2012-10-03 株洲时代新材料科技股份有限公司 Composite friction plate and preparation method thereof
CN102775788A (en) * 2012-07-16 2012-11-14 大连工业大学 Preparation method of wear-resisting composite material
CN104804419A (en) * 2015-04-22 2015-07-29 合肥康龄养生科技有限公司 Nylon composite with lower friction coefficient and excellent lubricity and preparation method thereof
EP3635036A1 (en) * 2017-06-07 2020-04-15 Solvay Specialty Polymers USA, LLC Process for preparing particles of polyphenylene sulfide polymer

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