CN103694564A - PP/PMMA (polypropylene/polymethyl methacrylate) alloy material and preparation method thereof - Google Patents

PP/PMMA (polypropylene/polymethyl methacrylate) alloy material and preparation method thereof Download PDF

Info

Publication number
CN103694564A
CN103694564A CN201310743694.3A CN201310743694A CN103694564A CN 103694564 A CN103694564 A CN 103694564A CN 201310743694 A CN201310743694 A CN 201310743694A CN 103694564 A CN103694564 A CN 103694564A
Authority
CN
China
Prior art keywords
pmma
alloy
polypropylene
mixture
pmma alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201310743694.3A
Other languages
Chinese (zh)
Other versions
CN103694564B (en
Inventor
徐东
张乐福
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Polymer Science Anhui New Material Co Ltd
Original Assignee
Polymer Science Anhui New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polymer Science Anhui New Material Co Ltd filed Critical Polymer Science Anhui New Material Co Ltd
Priority to CN201310743694.3A priority Critical patent/CN103694564B/en
Publication of CN103694564A publication Critical patent/CN103694564A/en
Application granted granted Critical
Publication of CN103694564B publication Critical patent/CN103694564B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/04—Particle-shaped
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/02—Making granules by dividing preformed material
    • B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92514—Pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/9258—Velocity
    • B29C2948/9259—Angular velocity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92819—Location or phase of control
    • B29C2948/92857—Extrusion unit
    • B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92885—Screw or gear
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92819—Location or phase of control
    • B29C2948/92857—Extrusion unit
    • B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92895—Barrel or housing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers

Abstract

The invention discloses a PP/PMMA (polypropylene/polymethyl methacrylate) alloy material and a preparation method thereof. The PP/PMMA alloy material comprises the following components in percentage by weight: 70%-90% of PP, 2%-15% of PMMA, 2%-15% of a compatilizer, 0.1%-0.3% of an antioxidant and 0.1%-5% of a lubricant. According to the preparation method, the PP is taken as a basic body and added with the PMMA, so that the alloy material is cooperatively improved in hardness, scratch resistance and normal-temperature impact resistance and is good in glossiness. Meanwhile, the compatilizer and the antioxidant are added in the PP/PMMA alloy material, so that the PMMA is prevented from being degraded at high temperature, two incompatible polymers of crystalline PP and non-crystalline PMMA are compatible with each other, and a stable structure is formed.

Description

A kind of PP/PMMA alloy material and preparation method thereof
Technical field
The present invention relates to technical field of polymer materials, relate in particular to a kind of PP/PMMA alloy material and preparation method thereof.
Background technology
Polypropylene (PP) is translucent Crystalline plastics, have plasticity-, and odorless is nontoxic.The highly crystalline due to PP compound with regular structure, therefore fusing point can have good normal temperature shock resistance up to 167 ℃, and heat-resisting, corrosion-resistant, density is little, is the lightest current general-purpose plastics.Yet, because the molecular structure of PP is regular, make PP toughness poor, and PP surface hardness is not high, easily snag.In addition, current pure PP material is in use subject to the effect of light, heat and oxygen and is aging, and the bad demand that can not meet market of tint permanence.
Polymethyl methacrylate (PMMA) is a kind of transparent material of excellent combination property, and its relative molecular mass is about 2,000,000, and the molecular chain forming is very soft, and therefore, PMMA physical strength is higher, and hardness is better.And PMMA has fabulous light transmission, have certain thermotolerance, winter resistance, weathering resistance and erosion resistance, and insulating property are good, but its thermal stability is poor, normal temperature shock resistance is not good, easily aging so limited his application in a lot of fields.
Summary of the invention
The object of the invention is to overcome the above-mentioned deficiency of prior art, provide a kind of and there is excellent glossiness, hardness and normal temperature shock resistance, and the good PP/PMMA alloy material of consistency.
Another object of the present invention is to provide the preparation method of this PP/PMMA alloy material.
In order to realize foregoing invention object, technical scheme of the present invention is as follows:
A PP/PMMA alloy material, comprises following component by weight percentage:
And a kind of preparation method of PP/PMMA alloy material, comprises the following steps:
Formula according to above-mentioned PP/PMMA alloy material takes each component;
Above-mentioned PP, PMMA, compatilizer, oxidation inhibitor and lubricant are carried out to mixing treatment, obtain mixture;
By said mixture material melt extrude, granulation, dry, obtain PP/PMMA alloy material.
Above-mentioned PP/PMMA alloy material be take PP as matrix, by doping component PMMA in PP, not only improve the surface hardness of PP, scrape resistant, and the normal temperature resistance to impact shock of reinforced PMMA, collaborative hardness, scratch resistance performance and the normal temperature shock resistance that strengthens PP/PMMA alloy material, and make material there is good gloss.Meanwhile, also, by add compatilizer and oxidation inhibitor in PP/PMMA alloy material, not only effectively prevent that PMMA from degrading under hot conditions, and it is compatible that crystal type PP and two kinds of incompatible polymers of non-crystalline type PMMA are realized, thereby form rock steady structure.
The preparation method of above-mentioned PP/PMMA alloy material is easy and simple to handle, with low cost, is suitable for the suitability for industrialized production of PP/PMMA alloy material.
Accompanying drawing explanation
Fig. 1 is embodiment of the present invention PP/PMMA alloy material preparation method's process flow diagram.
Embodiment
In order to make the technical problem to be solved in the present invention, technical scheme and beneficial effect clearer, below in conjunction with embodiment and accompanying drawing, the present invention is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
The embodiment of the present invention provides a kind of and has excellent glossiness, hardness and normal temperature shock resistance, and the good PP/PMMA alloy material of consistency, comprises by weight percentage following component:
Particularly, the above-mentioned PP/PMMA alloy material component PMMA that physical strength is higher and light transmission is fabulous by adulterating in PP matrix component strengthens surface hardness, glossiness and the mechanical property of PP, and because PP molecular structure is regular, highly crystalline, effectively the normal temperature shock resistance of strongthener.Therefore, PP, PMMA have following preferred embodiment:
As preferred embodiment, any in the mixture that above-mentioned matrix component PP is homo-polypropylene, Co-polypropylene, homo-polypropylene and Co-polypropylene, its melting index is 20～50g/10min(230 ℃/2.16Kg), notched Izod impact strength is 50～150J/M.Because homo-polypropylene only be take propylene as monomer, its symmetry is good, is conducive to improve the normal temperature shock resistance of material, and thus, further preferably, this matrix component PP is homo-polypropylene.
As another preferred embodiment, the melting index of above-mentioned PMMA is preferably 10～20g/10min(200 ℃/5Kg), the good fluidity in the course of processing of the PMMA in this numerical range, is conducive to the machine-shaping of material.
Because PP is Crystalline plastics, PMMA is non-crystalline type polymkeric substance, and PMMA and PP present different two-phases, so PP is incompatible with PMMA.For realizing PMMA and PP is compatible, improve the stability of material, the present embodiment preferably polyethylene grafted maleic anhydride is compatilizer, its percentage of grafting is 0.3-1%.Wherein, further preferably, the preparation method of this Research of Grafting Malaic Anhydride Onto Polyethylene comprises the following steps:
(1) take by weight percentage polyethylene 94.2～97.3%, vinylbenzene 1～2%, maleic anhydride 1.5～3%, crosslinking agent B IBP0.2～0.8%;
(2) crosslinking agent B IBP is dissolved in vinylbenzene, mixes with PP afterwards, obtain mixture;
(3) maleic anhydride is added in mixture and melt extruded, obtain Research of Grafting Malaic Anhydride Onto Polyethylene.
Above-mentioned preparation method be take vinylbenzene as compatilizer, under the initiation of crosslinking agent B IBP, make the side group anhydride bond of polyethylene (PE) grafted maleic anhydride (MAH), afterwards with the ester group of PMMA further combined with, and PE and PP are completely compatible, like this, the interfacial free energy of PP, PMMA blend and the free entropy of PE-MAH are reduced, finally reduce the free energy of blend, thereby reach the complete compatible object of PP, PMMA, PE-MAH.
In specific embodiment, in above-mentioned steps (1), take Research of Grafting Malaic Anhydride Onto Polyethylene weight percent as 100% calculating, this polyethylene is 96%, vinylbenzene is 1.6%, maleic anhydride is 2%, linking agent is BIBP0.4%; The step that melt extrudes of step (3) is: at extrusion temperature, be 170-190 ℃, screw speed is under the condition of 300-400r/min, by screw rod shearing, mixing, the molten materials of screw extrusion press, after extrude successively, granulation, drying treatment, obtain Research of Grafting Malaic Anhydride Onto Polyethylene.
Because PP, PMMA component are in use subject to the effect of light, heat and oxygen and aging, and these two kinds of superpolymer of PP and PMMA are easily degraded under hot conditions, causes the mechanical property of material and transparency obviously to decline, color and luster variation, therefore, in above-mentioned PP/PMMA alloy material, add oxidation inhibitor.
As preferred embodiment, above-mentioned oxidation inhibitor is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, β-(3,5-di-tert-butyl-hydroxy phenyl) any one or the two or more mixtures of the positive octadecanol ester of propionic acid, three [2.4-di-tert-butyl-phenyl] phosphorous acid ester, select this kind antioxidant to be conducive to each component compatibility of itself and alloy material, thereby can improve the stability of PP/PMMA alloy material performance.Further preferably, this oxidation inhibitor is that above three kinds of oxidation inhibitor carry out composite acquisition according to mass ratio 1:1:1-2.
For improving mobility and the release property of material in processing, prevent material and adhere to and the defects such as generation flake in machine or in mould, and for improving above-mentioned each component in preparation process as melt extruding the dispersing uniformity in process, in above-described embodiment, add lubricant.Preferably, this lubricant is any one or two or more mixture of Zinic stearas, calcium stearate, ethylene bis stearamide.Further preferably, this lubricant is that above three kinds of lubricants carry out composite acquisition according to mass ratio 1:1:1.5-3.
Above-mentioned PP/PMMA alloy material be take PP as matrix, by doping component PMMA in PP, not only improve the surface hardness of PP, scrape resistant, and the normal temperature resistance to impact shock of reinforced PMMA, collaborative hardness, scratch resistance performance and the normal temperature shock resistance that strengthens PP/PMMA alloy material, and make material there is good gloss.Simultaneously, also by add oxidation inhibitor, compatilizer and lubricant in PP/PMMA alloy material, effectively prevent that PP and PMMA from degrading under hot conditions, improve crystal type PP performance incompatible with non-crystalline type PMMA, and promote the dispersed and mobility of each component in the course of processing, thereby form stable PP/PMMA alloy material.
Correspondingly, the embodiment of the present invention also provides the preparation method of above-mentioned PP/PMMA alloy material, and its technical process as shown in Figure 1.The method comprises the following steps:
S01. take each component of PP/PMMA alloy material: by the formula of above-mentioned PP/PMMA alloy material, take each component;
S02. each component is carried out to mixing treatment: each component taking in step S01 is carried out to mixing treatment, obtain mixture;
S03. mixture is melt extruded to processing: by mixture melt extrude, granulation, dry, obtain PP/PMMA alloy material.
In above-mentioned steps S03, the optimal process parameter melt extruding is: district's temperature is 100-120 ℃, and two district's temperature are 200-220 ℃, and three district's temperature are 200-220 ℃, and four district's temperature are 200-220 ℃, and die temperature is 100-120 ℃.Wherein, as long as can realize the above-mentioned process that melt extrudes, total the class of concrete forcing machine is not limited at this.
Preparation method by above-mentioned PP/PMMA alloy material can obtain that glossiness is high, hardness large, normal temperature excellent shock resistance, and the good PP/PMMA alloy material of consistency, improves its good article rate.In addition, this preparation method is easy and simple to handle, with low cost, is suitable for the suitability for industrialized production of PP/PMMA alloy material.
Formula and the preparation method of PP/PMMA alloy material of now take is example, and the present invention is further elaborated.
In following all embodiment, PP is homo-polypropylene PPH, is selected from Sinopec V30G; PMMA is selected from the strange beautiful CM205 in Zhenjiang, Taiwan; Compatilizer is Research of Grafting Malaic Anhydride Onto Polyethylene, and its preparation method as mentioned above, does not repeat them here; Oxidation inhibitor is by four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, β-positive octadecanol ester of (3,5-di-tert-butyl-hydroxy phenyl) propionic acid and three kinds of oxidation inhibitor of three (2.4-di-tert-butyl-phenyl) phosphorous acid ester are that 1:1:2 carries out composite acquisition according to mass ratio; Lubricant profit is carried out composite acquisition by Zinic stearas, calcium stearate, three kinds of lubricants of ethylene bis stearamide according to mass ratio 1:1:1.5.
Embodiment 1～5
In embodiment 1～5, each PP/PMMA alloy material concrete component by weight percentage sees the following form 1.
In above-described embodiment 1～5, the preparation method of each PP/PMMA alloy material is identical, includes following steps:
S1. whole components of each PP/PMMA alloy material in above-described embodiment 1～5 are taken to each component in the concrete ratio in table 1 respectively;
S2. above-mentioned each component is carried out to mixing treatment in mixing tank, obtain mixture;
S3. mixture is placed in to screw extrusion press melt extrudes, granulation, dry and cooling, obtain PP/PMMA alloy material.Wherein, each zone temperatures of forcing machine is: 120 ℃, a district, two 200 ℃, districts, three 210 ℃, districts, four 220 ℃, districts; Melt pressure is 20MPa, and die temperature is 100 ℃, screw speed 130-150 rev/min, side feeding rotating speed 50-80 rev/min.
Comparative example 1～2
Comparative example 1～2 interalloy material concrete component by weight percentage sees the following form 1.
In comparative example 1～2, the preparation method of each alloy material is identical with the preparation method of each PP/PMMA alloy material in above-described embodiment 1～5.
Performance test:
The PP/PMMA alloy material that above-described embodiment 1～5 and comparative example 1～2 are prepared is dry 4-6 hour in the convection oven of 70-90 ℃, again dry material is prepared to test bars according to same injecting condition on 80T injection moulding machine, concrete injecting condition is, injection temperature: 220-250 ℃, injection pressure: 70-120Mpa, die temperature: 40-70 ℃.Concrete physicals test item is as follows:
Tensile strength is tested according to ASTM D638 standard;
Cantilever beam impact strength is tested according to ASTM D256 standard;
Flexural strength and modulus in flexure are tested by ASTM D790 standard;
Resistance to pencil scraping grade is measured according to ISO15194 standard.
The performance test results of the PP/PMMA alloy material that above-described embodiment 1～5 and comparative example 1～2 prepare sees the following form 1.
Table 1
From upper table 1, in the PP/PMMA alloy material of embodiment 1～5 preparation, PP adds, and is conducive to the raising of the normal temperature shock resistance of above-mentioned alloy material, but its lower hardness; The increase of PMMA and compatibilizer content, the scraping and wiping resistance performance of alloy material and hardness strengthen, but therefore its normal temperature shock resistance reduction need to adjust the compound proportion between PP, PMMA and compatilizer, could work in coordination with the mechanical property that improves above-mentioned alloy material; And when existing without PMMA and compatilizer (comparative example 1), flexural strength and the modulus in flexure of alloy material are poor, and the unusual scrape resistant not of material; When existing without PP and compatilizer (comparative example 2), the normal temperature shock resistance of alloy material is poor, has also limited the application of this alloy material.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any modifications of doing within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all should being included in protection scope of the present invention.

Claims (9)

1. a PP/PMMA alloy material, comprises following component by weight percentage:
2. PP/PMMA alloy material as claimed in claim 1, it is characterized in that, described PP is any in the mixture of homo-polypropylene, Co-polypropylene, homo-polypropylene and Co-polypropylene, its melting index is 20～50g/10min(230 ℃/2.16Kg), notched Izod impact strength is 50～150J/M.
3. PP/PMMA alloy material according to claim 1, is characterized in that, the melting index of described PMMA is 10～20g/10min(230 ℃/5Kg).
4. PP/PMMA alloy material according to claim 1, is characterized in that, described compatilizer is Research of Grafting Malaic Anhydride Onto Polyethylene, and its percentage of grafting is 0.3～1%.
5. PP/PMMA alloy material according to claim 4, is characterized in that, described Research of Grafting Malaic Anhydride Onto Polyethylene is got by following steps preparation:
Take described Research of Grafting Malaic Anhydride Onto Polyethylene weight percent as 100% calculating, take polyethylene 94.2～97.3%, vinylbenzene 1～2%, maleic anhydride 1.5～3%, crosslinking agent B IBP0.2～0.8%;
Described crosslinking agent B IBP is dissolved in described vinylbenzene, mixes with described PP afterwards, obtain mixture;
Described maleic anhydride is added in described mixture to melting and extrudes, obtain described Research of Grafting Malaic Anhydride Onto Polyethylene.
6. the polypropylene composite material as described in as arbitrary in claim 1～5, it is characterized in that, described oxidation inhibitor is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] any one or the two or more mixtures of pentaerythritol ester, the positive octadecanol ester of β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid, three (2.4-di-tert-butyl-phenyl) phosphorous acid ester.
7. the polypropylene composite material as described in as arbitrary in claim 1～5, is characterized in that, described lubricant is any one or two or more mixture of Zinic stearas, calcium stearate, ethylene bis stearamide.
8. a preparation method for PP/PMMA alloy material, comprises the following steps:
Formula according to the arbitrary described PP/PMMA alloy material of claim 1～7 takes each component;
Described PP, PMMA, compatilizer, oxidation inhibitor and lubricant are carried out to mixing treatment, obtain mixture;
By described mixture melt extrude, granulation, dry, obtain described PP/PMMA alloy material.
9. the preparation method of PC material according to claim 9, is characterized in that, described in the processing parameter that melt extrudes be: district's temperature is 100-120 ℃, two district's temperature are 200-220 ℃, three district's temperature are 200-220 ℃, and four district's temperature are 200-220 ℃, and die temperature is 100-120 ℃.
CN201310743694.3A 2013-12-27 2013-12-27 A kind of PP/PMMA alloy material and preparation method thereof Expired - Fee Related CN103694564B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310743694.3A CN103694564B (en) 2013-12-27 2013-12-27 A kind of PP/PMMA alloy material and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310743694.3A CN103694564B (en) 2013-12-27 2013-12-27 A kind of PP/PMMA alloy material and preparation method thereof

Publications (2)

Publication Number Publication Date
CN103694564A true CN103694564A (en) 2014-04-02
CN103694564B CN103694564B (en) 2017-01-04

Family

ID=50356240

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310743694.3A Expired - Fee Related CN103694564B (en) 2013-12-27 2013-12-27 A kind of PP/PMMA alloy material and preparation method thereof

Country Status (1)

Country Link
CN (1) CN103694564B (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104311998A (en) * 2014-10-31 2015-01-28 苏州润佳工程塑料股份有限公司 High-fluidity glass fiber reinforced polypropylene composite material and preparation method thereof
CN105713331A (en) * 2016-04-28 2016-06-29 苏州新区华士达工程塑胶有限公司 High-temperature corrosion-resistant plastic
CN105949564A (en) * 2016-05-09 2016-09-21 安徽江淮汽车股份有限公司 Anti-mould PE (polyethylene) alloy with high hardness and friction resistance and preparation method of anti-mould PE alloy
CN106519452A (en) * 2016-11-24 2017-03-22 杭州富阳新远新能源有限公司 High brightness PP and preparation method thereof
CN108250586A (en) * 2017-12-29 2018-07-06 青岛海尔新材料研发有限公司 A kind of PP/PMMA alloy materials and its preparation method and application
CN108948712A (en) * 2018-07-31 2018-12-07 惠州莹光塑胶颜料有限公司 A kind of frosted material and preparation method thereof
CN111057304A (en) * 2018-10-16 2020-04-24 中国石油化工股份有限公司 High-gloss and high-rigidity polypropylene composite material and preparation method thereof
CN112724578A (en) * 2020-12-29 2021-04-30 金发科技股份有限公司 Polypropylene compound and application and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101787158A (en) * 2009-10-10 2010-07-28 深圳市科聚新材料有限公司 Directly sprayed polypropylene material and preparation method thereof
CN102532771A (en) * 2010-12-23 2012-07-04 上海日之升新技术发展有限公司 Environment-friendly polyethylene compatilizer and preparation method thereof
CN102757613A (en) * 2012-06-27 2012-10-31 深圳市科聚新材料有限公司 Faint-odor polypropylene stem grafting maleic anhydride extruded by double screws and preparation method thereof
CN103059412A (en) * 2013-01-16 2013-04-24 合肥杰事杰新材料股份有限公司 Polypropylene composite material with low after-shrinkage and high gloss and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101787158A (en) * 2009-10-10 2010-07-28 深圳市科聚新材料有限公司 Directly sprayed polypropylene material and preparation method thereof
CN102532771A (en) * 2010-12-23 2012-07-04 上海日之升新技术发展有限公司 Environment-friendly polyethylene compatilizer and preparation method thereof
CN102757613A (en) * 2012-06-27 2012-10-31 深圳市科聚新材料有限公司 Faint-odor polypropylene stem grafting maleic anhydride extruded by double screws and preparation method thereof
CN103059412A (en) * 2013-01-16 2013-04-24 合肥杰事杰新材料股份有限公司 Polypropylene composite material with low after-shrinkage and high gloss and preparation method thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104311998A (en) * 2014-10-31 2015-01-28 苏州润佳工程塑料股份有限公司 High-fluidity glass fiber reinforced polypropylene composite material and preparation method thereof
CN104311998B (en) * 2014-10-31 2016-07-06 苏州润佳工程塑料股份有限公司 A kind of high fluidity glass fiber reinforced polypropylene composite material and preparation method thereof
CN105713331A (en) * 2016-04-28 2016-06-29 苏州新区华士达工程塑胶有限公司 High-temperature corrosion-resistant plastic
CN105949564A (en) * 2016-05-09 2016-09-21 安徽江淮汽车股份有限公司 Anti-mould PE (polyethylene) alloy with high hardness and friction resistance and preparation method of anti-mould PE alloy
CN106519452A (en) * 2016-11-24 2017-03-22 杭州富阳新远新能源有限公司 High brightness PP and preparation method thereof
CN108250586A (en) * 2017-12-29 2018-07-06 青岛海尔新材料研发有限公司 A kind of PP/PMMA alloy materials and its preparation method and application
CN108948712A (en) * 2018-07-31 2018-12-07 惠州莹光塑胶颜料有限公司 A kind of frosted material and preparation method thereof
CN111057304A (en) * 2018-10-16 2020-04-24 中国石油化工股份有限公司 High-gloss and high-rigidity polypropylene composite material and preparation method thereof
CN112724578A (en) * 2020-12-29 2021-04-30 金发科技股份有限公司 Polypropylene compound and application and preparation method thereof

Also Published As

Publication number Publication date
CN103694564B (en) 2017-01-04

Similar Documents

Publication Publication Date Title
CN103694564A (en) PP/PMMA (polypropylene/polymethyl methacrylate) alloy material and preparation method thereof
CN102816384B (en) Glass fiber-reinforced polypropylene material with shallow shrinkage mark and low warpage as well as preparation method and application thereof
CN102391432B (en) High-fluidity ethylene-alpha-octene graft copolymer and preparation method thereof
CN101580632B (en) High-gloss high-performance fiber glass reinforced PBT material and preparation method thereof
CN104004253A (en) High-molecular-weight polymer nucleating agent-modified ultrahigh-molecular-weight polyethylene blend material
CN102408704A (en) Polyamide composite material and its preparation method and application
CN101955664A (en) Reinforced wear-resistance nylon 66 composite for textile apparatuses and preparation method thereof
CN103571039A (en) High-melt index polypropylene composition and preparation method thereof
CN105542310A (en) PP (Propene Polymer) resin composition, glass fiber reinforcement PP resin and preparation method of glass fiber reinforcement PP resin
CN102391575B (en) Polypropylene (PP) alloy material with low molding shrinkage and preparation method thereof
CN102532682B (en) Low-warpage high-glaze filling reinforcing polypropylene material and preparation method thereof
CN103087412B (en) A kind of high workability glass fiber reinforced polypropylene composite material and preparation method thereof
CN102643480B (en) Anti-static alloy composite material and preparation method thereof
CN102241860A (en) Reinforced polypropylene material and preparation method thereof
CN102276972A (en) Polychloroprene/acrylonitrile butadiene styrene (PC/ABS) defective material recovery composition and preparation method thereof
CN102030946A (en) Modified material based on polypropylene
CN102993709B (en) PA6 polyblend, its preparation method and application
CN103709674A (en) PET/PP alloy material and preparation method thereof
CN103937231A (en) Glass fiber reinforced nylon compound used for extrusion molding, and preparation method and application thereof
CN109957239A (en) A kind of thermoplasticity enhancing biology base PA56/PA66 alloy and preparation method thereof
CN101875768A (en) Antiaging glass fiber-reinforced polycarbonate composition and preparation method thereof
CN103289346B (en) A kind of low-expansion coefficient high-ductility height heat conduction functional composite material and preparation method thereof
CN102942736B (en) High-glass fiber content reinforced polypropylene material and preparation method thereof
CN105462064A (en) Polypropylene/polyethylene/wood fiber composite and preparation method thereof
CN106566158A (en) Reinforced ASA composition and application thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20170104

Termination date: 20181227