CN1163237A - Super high strength quick hardening sulfaluminous cement - Google Patents

Super high strength quick hardening sulfaluminous cement Download PDF

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Publication number
CN1163237A
CN1163237A CN97101307A CN97101307A CN1163237A CN 1163237 A CN1163237 A CN 1163237A CN 97101307 A CN97101307 A CN 97101307A CN 97101307 A CN97101307 A CN 97101307A CN 1163237 A CN1163237 A CN 1163237A
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China
Prior art keywords
cement
gypsum
grog
quick hardening
wingdale
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CN97101307A
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Chinese (zh)
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CN1061951C (en
Inventor
邓君安
石履钰
杨仲森
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Yangquan Joint Special Cement Mill Cement Inst China Architecture Material Sc
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Yangquan Joint Special Cement Mill Cement Inst China Architecture Material Sc
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Priority to CN97101307A priority Critical patent/CN1061951C/en
Publication of CN1163237A publication Critical patent/CN1163237A/en
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Publication of CN1061951C publication Critical patent/CN1061951C/en
Anticipated expiration legal-status Critical
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06—Aluminous cements
    • C04B28/065—Calcium aluminosulfate cements, e.g. cements hydrating into ettringite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/29—Frost-thaw resistance
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention belongs to the field of building material. The sulfaaluminous cement is produced with clinker in 45-60%, gypsum in 3-10% and duff (gangue and limestone) in 31-45% and through mixing, crushing, calcination, cooling, assimilation and other processes. It has the merits of high early strength, good imperviousness, high freezing resistance and quick hardening.

Description

Super high strength quick hardening sulfaluminous cement
The present invention relates to a kind of superelevation quick hardening sulphoaluminate cement that is fired into by bauxitic clay grog, gypsum, Wingdale, flyash, belong to building material field.
CN1096504 discloses the patent application technology that name is called " ultralight, high temperature resistant, high-strength cement mortar ", it utilizes low calcium-aluminate refractory cements to be gelling material, float pearl and the microballon that add the flyash extract stir and form, have advantages such as high temperature resistant, light capacity, high strength, but in the cement early strength performance, still be weak.
The purpose of this invention is to provide a kind of characteristics such as early strong, high-strength, impervious and resisting erosion of sulfate that have, be applicable to the super high strength quick hardening sulfaluminous cement of subzero temperature construct, slurry anchor, bolting and shotcreting, assembly unit node, geology well cementation, repairing leak stopping.
The present invention has taked following technical scheme:
With anhydrous sulplo-aluminate is the modified sulphur hydrochlorate grog of major ingredient, is equipped with proper amount of gypsum, Wingdale and the flyash low hydraulic cementing materials of the levigate basicity that forms of admixture such as (coal gangues).Its component and content (in 100% weight ratio) are respectively modified sulphur hydrochlorate grog 45～60%, gypsum 3～10%, flyash (coal gangue, Wingdale) 31～45%.Modified sulphur hydrochlorate grog is formed through the broken calcining of proportion design by bauxitic clay, Wingdale, three kinds of raw material of gypsum.Wherein bauxitic clay should be suitable for Al 2O 3Content is at the mineral reserve than higher-grade more than 70%, Wingdale CaO 〉=52%, SlO≤1%, gypsum SO 3＞38%.
The proportion design of raw material:
The charge calculation formula of raw material comes out according to following release: suppose in the clinker burning process Al in the alumina 2O 3All form C 4A 3S, SlO 2All form β-C 2S, TlO 2Form CT, and Fe 2O 3Form C 2F, establish alumina 100 (butt) then this moment:
Figure A9710130700032
In the formula: Al 2O 3, SlO 2, Fe 2O 3, TlO 2Be percentage composition in the alumina.
CaO is a percentage composition in the Wingdale.
SO 2Be percentage composition in the gypsum.
Above-mentioned three data are converted into percentage ratio promptly get raw-meal ingredient.Calculate Chemical Composition and mineral composition living, grog according to raw-meal ingredient again, be calculated as follows:
C 4A sS＝1.99Al 2O 3 C 2F＝1.70Fe 2O 3
C 2S＝2.87SlO 2 CT＝1.70TiO 2
In the formula: SlO 2, AlO 3, Fe 2O 3, TiO 2Be percentage composition in the grog, can get the each component amount ranges of the invention described above thus.
Production process is for to measure three kinds of raw material respectively, mix and be crushed to less than 20cm, be milled to 0.08mm screening surplus less than 12% by ball mill, even by homogenizing storehouse homogenizing again, send into raw material silo, finish fs work, qualified raw material and kiln tail sedimentation compartment kiln ash are promoted to kiln tail storehouse behind the mixing in proportion and, unload to kiln, through the rotary kiln tilting rotary table by the spiral metering, slowly flow forward, after bituminous coal was dried by preheating in rotary kiln, grinding was blown into the rotary kiln burning to qualified through gas blower, like this, raw material drying, preheating, decompose, burn till, processes such as cooling form with C 4A 3S is the modified sulphur hydrochlorate grog of essential mineral, by fragmentation, finishes subordinate phase work.The modified sulphur hydrochlorate grog that the digestion cooling is good is carried into standby storehouse, with the gypsum that is crushed to certain particle size, Wingdale utilize microcomputer automatic gauge proportioning machine by modified sulphur hydrochlorate grog be 45～60%, after gypsum 3～10%, flyash (coal gangue, Wingdale) 31～45% weight percents carry out accurate proportioning, the input ball mill carry out grinding to specific surface greater than 3800cm 2/ g, the defeated appointment warehouse compartment of choosing, the manufacture of cement whole process is finished in the packing pack.
Advantage of the present invention is:
Early strength performance is higher, frost resistance, impervious good, has fast hard characteristics, is suitable for the building operation under the special environment condition and the needs of extraordinary construction work.
Embodiment:
Above-mentioned three kinds of compositions in weight percentage are respectively:
Modified sulphur hydrochlorate grog 50%, gypsum 7%, flyash (coal gangue, Wingdale) 43% adopt above-mentioned production process to produce can obtain super high strength quick hardening sulfaluminous cement.

Claims (2)

1, a kind of super high strength quick hardening sulfaluminous cement of making by the hydraulic cementing materials that with the anhydrous sulfate is modified sulphur hydrochlorate grog, gypsum, Wingdale and the levigate low basicity that forms of (flyash, coal gangue) admixture of major ingredient, it is characterized in that each component content (in 100% weight ratio) is respectively modified sulphur hydrochlorate grog 45～60%, gypsum 3～10%, flyash (coal gangue, Wingdale) 31～45%.
2, superstrength quick hardening sulphoaluminate cement according to claim 1 is characterized in that each component optimized percentage weight proportion is, modified sulphur hydrochlorate grog 50%, and gypsum 7%, flyash (coal gangue, Wingdale) is 43%.
CN97101307A 1997-01-08 1997-01-08 Super high strength quick hardening sulfaluminous cement Expired - Fee Related CN1061951C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN97101307A CN1061951C (en) 1997-01-08 1997-01-08 Super high strength quick hardening sulfaluminous cement

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN97101307A CN1061951C (en) 1997-01-08 1997-01-08 Super high strength quick hardening sulfaluminous cement

Publications (2)

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CN1163237A true CN1163237A (en) 1997-10-29
CN1061951C CN1061951C (en) 2001-02-14

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1098225C (en) * 1998-12-21 2003-01-08 蒋元海 Manufacture method for tubular pile cement
CN100351197C (en) * 2002-09-25 2007-11-28 陈智丰 Process for making quick hardening aluminosulfate cement
CN100360451C (en) * 2006-04-20 2008-01-09 中国地质大学（北京） Method for preparing sulphate aluminium cement by red mud
CN100396635C (en) * 2006-09-11 2008-06-25 山东大学 Technology of sintering sulfur aluminate cement using desulfur ash
CN101596040B (en) * 2009-06-23 2011-02-09 岳大德 Indeformable stone imitation table-board of furniture
CN101318783B (en) * 2008-07-22 2011-02-16 浙江大学宁波理工学院 Activation method for coal gangue burned ash
CN101671133B (en) * 2009-09-30 2012-03-21 永州市中大特种水泥有限责任公司 Modified low-alkalinity sulphoaluminate cement
CN102424535A (en) * 2011-09-14 2012-04-25 南昌大学 Method for preparing low-alkality sulphate aluminium cement by using lepidolite sulfuric acid method
CN102807333A (en) * 2012-08-23 2012-12-05 黄靖宇 Method for preparing sulphoaluminate cement by using fluorine-containing sludge
CN103601381A (en) * 2013-11-07 2014-02-26 广西云燕特种水泥建材有限公司 Environment-friendly high-performance cement and production method thereof
CN105331341A (en) * 2015-10-13 2016-02-17 嘉华特种水泥股份有限公司 High-temperature oil gas well cementing material
CN106634902A (en) * 2016-12-19 2017-05-10 西南石油大学 High-temperature-resistant acid-soluble hydraulic cementing material and oil well cement slurry system
CN108383403A (en) * 2018-04-12 2018-08-10 济南大学 A kind of calcined clay type sulphate aluminium cement gel rubber material
CN108395127A (en) * 2018-04-12 2018-08-14 济南大学 A kind of burnedc lay type phosphor aluminate cement cementitious material
WO2019232687A1 (en) * 2018-06-05 2019-12-12 华智节能(香港)有限公司 Ultra-rapid-hardening special inorganic cement material and preparation method therefor
CN113800794A (en) * 2021-09-26 2021-12-17 乐山嘉豫环境科技有限公司 Preparation method of curing agent for waste drilling mud in oil field

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100334027C (en) * 2006-01-18 2007-08-29 内蒙古西水创业股份有限公司 Freeze-thaw resisting cement and its production process

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1096504A (en) * 1993-06-18 1994-12-21 郭成正 Ultralight, high temperature resistant, high-strength cement mortar
CN1039582C (en) * 1994-11-30 1998-08-26 桦甸市松源水泥有限公司 Process for producing, early strength expansive cement

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1098225C (en) * 1998-12-21 2003-01-08 蒋元海 Manufacture method for tubular pile cement
CN100351197C (en) * 2002-09-25 2007-11-28 陈智丰 Process for making quick hardening aluminosulfate cement
CN100360451C (en) * 2006-04-20 2008-01-09 中国地质大学（北京） Method for preparing sulphate aluminium cement by red mud
CN100396635C (en) * 2006-09-11 2008-06-25 山东大学 Technology of sintering sulfur aluminate cement using desulfur ash
CN101318783B (en) * 2008-07-22 2011-02-16 浙江大学宁波理工学院 Activation method for coal gangue burned ash
CN101596040B (en) * 2009-06-23 2011-02-09 岳大德 Indeformable stone imitation table-board of furniture
CN101671133B (en) * 2009-09-30 2012-03-21 永州市中大特种水泥有限责任公司 Modified low-alkalinity sulphoaluminate cement
CN102424535A (en) * 2011-09-14 2012-04-25 南昌大学 Method for preparing low-alkality sulphate aluminium cement by using lepidolite sulfuric acid method
CN102807333A (en) * 2012-08-23 2012-12-05 黄靖宇 Method for preparing sulphoaluminate cement by using fluorine-containing sludge
CN103601381A (en) * 2013-11-07 2014-02-26 广西云燕特种水泥建材有限公司 Environment-friendly high-performance cement and production method thereof
CN103601381B (en) * 2013-11-07 2015-08-19 广西云燕特种水泥建材有限公司 A kind of Environment-friendlyhigh-performance high-performance cement and production method thereof
CN105331341A (en) * 2015-10-13 2016-02-17 嘉华特种水泥股份有限公司 High-temperature oil gas well cementing material
CN105331341B (en) * 2015-10-13 2018-12-14 嘉华特种水泥股份有限公司 A kind of well cementing material of high temperature oil gas well
CN106634902A (en) * 2016-12-19 2017-05-10 西南石油大学 High-temperature-resistant acid-soluble hydraulic cementing material and oil well cement slurry system
CN106634902B (en) * 2016-12-19 2019-08-23 西南石油大学 The molten hydraulic cementing materials of high temperature resistant theobromine and be used for oil-well cement slurry system
CN108383403A (en) * 2018-04-12 2018-08-10 济南大学 A kind of calcined clay type sulphate aluminium cement gel rubber material
CN108395127A (en) * 2018-04-12 2018-08-14 济南大学 A kind of burnedc lay type phosphor aluminate cement cementitious material
WO2019232687A1 (en) * 2018-06-05 2019-12-12 华智节能(香港)有限公司 Ultra-rapid-hardening special inorganic cement material and preparation method therefor
CN113800794A (en) * 2021-09-26 2021-12-17 乐山嘉豫环境科技有限公司 Preparation method of curing agent for waste drilling mud in oil field

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