CN104193199A - High magnesium slag doped cement - Google Patents
High magnesium slag doped cement Download PDFInfo
- Publication number
- CN104193199A CN104193199A CN201410459657.4A CN201410459657A CN104193199A CN 104193199 A CN104193199 A CN 104193199A CN 201410459657 A CN201410459657 A CN 201410459657A CN 104193199 A CN104193199 A CN 104193199A
- Authority
- CN
- China
- Prior art keywords
- magnesium slag
- cement
- equal
- wingdale
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002893 slag Substances 0.000 title claims abstract description 74
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 229910052749 magnesium Inorganic materials 0.000 title claims abstract description 64
- 239000011777 magnesium Substances 0.000 title claims abstract description 64
- 239000004568 cement Substances 0.000 title claims abstract description 58
- 239000002994 raw material Substances 0.000 claims abstract description 31
- 239000003245 coal Substances 0.000 claims abstract description 18
- 238000001035 drying Methods 0.000 claims abstract description 4
- 239000000126 substance Substances 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract 4
- 229910052681 coesite Inorganic materials 0.000 claims abstract 2
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract 2
- 239000000377 silicon dioxide Substances 0.000 claims abstract 2
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract 2
- 229910052682 stishovite Inorganic materials 0.000 claims abstract 2
- 229910052905 tridymite Inorganic materials 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims description 20
- 235000021321 essential mineral Nutrition 0.000 claims description 16
- 239000002002 slurry Substances 0.000 claims description 15
- 238000000227 grinding Methods 0.000 claims description 12
- 239000010881 fly ash Substances 0.000 claims description 7
- 239000011505 plaster Substances 0.000 claims description 6
- 239000013256 coordination polymer Substances 0.000 claims description 3
- 235000012054 meals Nutrition 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 9
- 235000019738 Limestone Nutrition 0.000 abstract description 3
- 239000006028 limestone Substances 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 3
- 239000010440 gypsum Substances 0.000 abstract description 2
- 229910052602 gypsum Inorganic materials 0.000 abstract description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000010883 coal ash Substances 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 238000006477 desulfuration reaction Methods 0.000 abstract 1
- 230000023556 desulfurization Effects 0.000 abstract 1
- 239000002440 industrial waste Substances 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 19
- 239000000292 calcium oxide Substances 0.000 description 17
- 238000001354 calcination Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 6
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- 238000000034 method Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910004261 CaF 2 Inorganic materials 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229910000519 Ferrosilicon Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000010436 fluorite Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000011404 masonry cement Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000003469 silicate cement Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000001149 thermolysis Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
Landscapes
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses high magnesium slag doped cement. The raw materials of the cement comprise the following main minerals in percentage by weight: 65-82% of limestone, 1-20% of magnesium slag, 5.5-9.4% of sandstone and 4-8% of coal gangue, wherein the magnesium slag comprises the following main chemical components: less than or equal to 55% and greater than or equal to 50% of CaO, greater than or equal to 20% and less than or equal to 30% of SiO2, greater than or equal to 8% and less than or equal to 12% of MgO, greater than or equal to 4% and less than or equal to 6% of Fe2O3, and greater than 0% and less than or equal to 2% of Al2O3. The cement is prepared by sequentially passing blended raw materials through a raw material drying mill, a raw material homogenizing silo, a decomposing furnace and a rotary kiln, blending the prepared clinker with coal ash, desulfurization gypsum and slag, and feeding the above materials into a cement mill. As high as 20% of magnesium slag is doped into the high magnesium slag doped cement, so that not only is the service life of a limestone mine prolonged, but also industrial wastes such as greatly piled magnesium slag are effectively utilized, the burnability of the clinker is also improved, the content of f-CaO in the clinker is reduced, and the national standard is met.
Description
Technical field
The present invention relates to a kind of material of construction, particularly relate to a kind of high magnesium slag volume cement.
Background technology
Cement is as engineering foundation material indispensable in construction work, with the quickening of China's industrialization and urban-rural integration process, and within the quite a long time, can be more and more large to the demand of cement.Estimate before and after 2015, China's cement demand will reach hundred million tons of 19-23, to reach hundred million tons of 11.6-14.1 to the consumption of main raw material Wingdale, in addition, Wingdale also has larger consumption in solvent for metallurgy, structural stone, medication chemistry production etc., go down for a long time, the retained reserve of China's Wingdale is constituted a threat to.So China encourages enterprise to adopt Industry Waste waste (as: metallurgical slag, coal gangue, flyash etc.) replacing partial cement raw materials for production from the perspective of policy, magnesium slag is huge because of industrial output amount, and in magnesium slag, contains CaO, SiO
2, Al
2o
3and Fe
2o
3, and these compositions are all that manufacture of cement is necessary, therefore, utilize magnesium slag Substitute For Partial lime masonry cement producting material, are turned bane into boon, and have good economic benefit and environmental benefit, are the modes that present cement production enterprise is generally taked.
But magnesium slag Substitute For Partial Wingdale is produced cement and is had the following problem at present.
(1) magnesium slag this as powdery, and through shrend, enter factory's moisture in 15% left and right, enter after mill, too high because of the comprehensive moisture of material, can cause raw mill unit-hour output in a slight decrease.
(2) in the blanking of magnesium slag, transport process, easily adhere on Belt Conveying equipment, cause the smooth and putty phenomenon of blanking.
(3) ratio of magnesium slag replace lime stone is not high, mostly is the volume that is less than 12%, and the situation innovation dynamics that magnesium slag waste material bulk deposition and Wingdale reserves are in an emergency is not obvious.
(4), when magnesium slag burden calcination of chamotte, be prone to the detrimentally affects such as circle after rotary kiln knot, balling.
Summary of the invention
The invention discloses a kind of high magnesium slag volume cement, aim to provide a kind of low cost, high magnesium slag volume, produce stable high-quality silicate cement.
The solid slag of discharging when magnesium slag is industrial employing Pidgeon process production MAGNESIUM METAL.The main raw material of production MAGNESIUM METAL is rhombspar, ferrosilicon and the fluorite as reducing catalyst, and main chemical reactions is:
CaCO
3·MgCO
3 CaO+MgO+2CO
2
2MgO+2CaO+Si(Fe)
2Mg
+2CaO·SiO
2+Fe
The magnesium slag of discharging is cooling in air, is canescence block material, and small part is powdery.The main chemical compositions of magnesium slag is CaO, SiO
2, MgO, Fe
2o
3with a small amount of Al
2o
3, essential mineral composition is γ-C
2s, α-C
2s, MgO, FeO, CaF
2deng, can reduce grog free calcium oxide (be called for short: f-CaO) content, improve the burn-ability of raw material.
Admixture has one can improve and regulate concrete or mortar function, and in raw material, suitable interpolation admixture also can reduce the f-CaO content of grog, improves the burn-ability of raw material.
Technical scheme of the present invention is: a kind of high magnesium slag volume cement, in cement slurry, essential mineral composition and weight percentage are respectively, Wingdale 65%-82%, magnesium slag 1%-20%, sandstone 5.5%-9.4%, coal gangue 4%-8%, wherein, selected magnesium slag main chemical compositions is 55%>=CaO>=50%, 20%≤SiO
2≤ 30%, 8%≤MgO≤12%, 4%≤Fe
2o
3≤ 6%, 0 < Al
2o
3≤ 2%, the raw material that prepare are ground through drying raw meal successively, raw material homogenizing silo, (temperature out of decomposing furnace is within the scope of 850 DEG C-930 DEG C for decomposing furnace, decompose outlet pressure of furnace and be controlled at 950Pa-1300Pa), after rotary kiln (calcining temperature is 1350 DEG C-1500 DEG C), the grog obtaining and flyash, desulfurated plaster, slag, one or more allotments in Wingdale, enter the cement that cement grinding mill obtains different model, as: can be by 75% grog and 5% flyash, 5% desulfurated plaster, 15% slag allotment, enter cement grinding mill, it is 9.8% PO42.5 cement that fine grinding obtains fineness, can, by 60% grog and 5% desulfurated plaster, 20% slag, 10% flyash, 5% Wingdale allotment, enter cement grinding mill, it is 9.9% PC42.5 cement that fine grinding obtains fineness, can, by 40% grog and 6% desulfurated plaster, 31% slag, 15% flyash, 8% Wingdale allotment, enter cement grinding mill, it is 9.9% PC32.5 cement cement that fine grinding obtains fineness, by 85% grog, 5% gypsum, 10% slag enters cement grinding mill, and it is 9.8% PO52.5 cement that fine grinding obtains fineness.
As a kind of preferred implementation, in cement slurry, essential mineral composition and weight percentage are respectively, Wingdale 65%-70%, magnesium slag 18%-20%, sandstone 5.5%-6.5%, coal gangue 5%-6%.
As a kind of preferred implementation, in cement slurry, essential mineral composition and weight percentage are respectively, Wingdale 71%-73%, magnesium slag 15%-16%, sandstone 7.0%-8.0%, coal gangue 4%-5%.
As a kind of preferred implementation, in cement slurry, essential mineral composition and weight percentage are respectively, Wingdale 74%-76%, magnesium slag 11%-13%, sandstone 8.0%-9.0%, coal gangue 4.8%-5.5%.
As a kind of preferred implementation, admixture CB or the CP of additional 0.3%-1.2%, for improving the inflammableness of raw material, wherein CB or CP are prepared by analytically pure chemical reagent.
As a kind of preferred implementation, in cement slurry, essential mineral composition and weight percentage are respectively, Wingdale 68.7%, magnesium slag 20%, sandstone 6%, coal gangue 5.3%.
As a kind of preferred implementation, in cement slurry, essential mineral composition and weight percentage are respectively, Wingdale 68.7%, magnesium slag 20%, sandstone 6%, coal gangue 5.3%; Separately add the admixture that accounts for above-mentioned raw material gross weight 0.5%.
As a kind of preferred implementation, in cement slurry, essential mineral composition and weight percentage are respectively, Wingdale 68.7%, magnesium slag 20%, sandstone 6%, coal gangue 5.3%; Separately add the admixture that accounts for above-mentioned raw material gross weight 1%.
In order to study the burn-ability under different magnesium slags and admixture dosage condition, high magnesium slag volume cement to different magnesium slags and admixture dosage is calcined under differing temps, the present invention calcines under differing temps by the raw material of mixing the magnesium quantity of slag 0%, 10%, 15%, 20%, and the cement raw material of the additional admixture CB that accounts for raw material gross weight 0.5% and 1% is calcined under differing temps, and to burn grog in f-CaO content carry out statistical study, shown in result accompanying drawing 1.
Can be obtained by accompanying drawing 1, accompanying drawing 2, accompanying drawing 3: no matter Mixed With Admixture whether in raw material, along with adding of magnesium slag, under each calcining temperature in gained material the content of f-CaO all lower than f-CaO in admixture magnesium slag sample not; Accompanying drawing 1 and accompanying drawing 2 show: for the sample of not mixing admixture, in the time that the magnesium slag volume in raw material is increased to 20% by 0, f-CaO in 1350 DEG C of calcining samples is reduced to 1.26% by 6.48%, when 1400 DEG C of calcinings, when magnesium slag addition content is by 0 increase most 15% time, the reduction curve of f-CaO is milder, and effect is distant; Magnesium slag volume continues to increase, and in sintered specimen, f-Ca0 is linear reduction; Accompanying drawing 1 and accompanying drawing 3 show: for the sample of Mixed With Admixture, in the time that admixture dosage is increased to 1% by 0.5%, the f-CaO of 1350 DEG C of calcining samples is reduced to 1.12% by 1.21%, and amplitude is 7.4%; And the f-CaO that calcines sample at 1250 DEG C is reduced to 5.24% by 7.75%, amplitude is 32.4%.To sum up can obtain: under admixture effect, in the time of the magnesium slag of admixture in raw material 20%, material has good burn-ability, particularly, within the scope of 1250 DEG C ~ 1350 DEG C, in the time of 1350 ~ 1400 DEG C, grog burns till substantially, oneself is very low through being reduced to for the f-CaO content of grog, without the f-CaO that reduces sample by further increase magnesium slag volume, and now MgO in clinker content has reached higher level, is just no more than the limitation that national standard technical indicator specifies.
Brief description of the drawings
Accompanying drawing 1 is that in the present invention, differing temps is calcined the f-Ca0 result in different constitutive material gained grogs.
Accompanying drawing 2 is that the raw material of different magnesium slag volumes in the present invention are calcined data plot under differing temps.
Accompanying drawing 3 is at the calcining data plot containing Mixed With Admixture CB in the raw material of 20% magnesium slag in the present invention.
Embodiment
The present invention is respectively with essential mineral composition in cement slurry and weight percentage: Wingdale 68.7%, magnesium slag 20%, sandstone 6%, coal gangue 5.3%(wherein: in magnesium slag, contain 52.3% CaO, 21.4% SiO
2, 10.3% MgO, 5.0% Fe
2o
3, 1.0% Al
2o
3) for embodiment, the present invention program is described further.
Wingdale, sandstone, coal gangue are first crushed to homogenizing after 80mm, batching, magnesium slag directly carries out homogenizing, batching, the raw material that prepare are entered to drying raw meal mill dries, while going out to grind, the moisture of raw material is no more than 0.5%, then enters raw material homogenizing silo and carry out homogenizing, enters subsequently TDF decomposing furnace and carries out pre-thermolysis, the temperature out of decomposing furnace is 860 DEG C of left and right, decompose outlet pressure of furnace at 980 Pa, then enter rotary kiln, obtain grog at 1450 DEG C of temperature lower calcinations; By 60% grog and 5% desulfurated plaster, 20% slag, 10% flyash, 5% Wingdale allotment, enter cement grinding mill, it is 9.9% PC42.5 cement that fine grinding obtains fineness, the fineness of gained cement is 2.1%, specific surface area 355 m
2/ kg, folding strength: being 7.2 MPa 3 days time, is 9.8 MPa 28 days time; Ultimate compression strength: being 34 MPa 3 days time, is 59 MPa 28 days time.
Claims (8)
1. one kind high magnesium slag volume cement, it is characterized in that: in cement slurry, essential mineral composition and weight percentage are respectively, Wingdale 65%-82%, magnesium slag 1%-20%, sandstone 5.5%-9.4%, coal gangue 4%-8%, wherein, the main chemical compositions of selected magnesium slag is 55%>=CaO>=50%, 20%≤SiO2≤30%, 8%≤MgO≤12%, 4%≤Fe
2o
3≤ 6%, 0 < Al
2o
3≤ 2%, by the raw material that prepare, successively after drying raw meal mill, raw material homogenizing silo, decomposing furnace, rotary kiln, one or more allotments in the grog obtaining and flyash, desulfurated plaster, slag, Wingdale, enter cement grinding mill and obtain the cement of different model.
2. high magnesium slag volume cement as claimed in claim 1, is characterized in that: in cement slurry, essential mineral composition and weight percentage are respectively, Wingdale 65%-70%, magnesium slag 18%-20%, sandstone 5.5%-6.5%, coal gangue 5%-6%.
3. high magnesium slag volume cement as claimed in claim 1, is characterized in that: in cement slurry, essential mineral composition and weight percentage are respectively, Wingdale 71%-73%, magnesium slag 15%-16%, sandstone 7.0%-8.0%, coal gangue 4%-5%.
4. high magnesium slag volume cement as claimed in claim 1, is characterized in that: in cement slurry, essential mineral composition and weight percentage are respectively, Wingdale 74%-76%, magnesium slag 11%-13%, sandstone 8.0%-9.0%, coal gangue 4.8%-5.5%.
5. as the high magnesium slag volume cement as described in arbitrary in claim 1-4, it is characterized in that: admixture CB or the CP of additional 0.3%-1.2%, for improving the inflammableness of raw material.
6. high magnesium slag volume cement as claimed in claim 2, is characterized in that: in cement slurry, essential mineral composition and weight percentage are respectively, Wingdale 68.7%, magnesium slag 20%, sandstone 6%, coal gangue 5.3%.
7. high magnesium slag volume cement as claimed in claim 5, is characterized in that: in cement slurry, essential mineral composition and weight percentage are respectively, Wingdale 68.7%, magnesium slag 20%, sandstone 6%, coal gangue 5.3%; Separately add the admixture that accounts for above-mentioned raw material gross weight 0.5%.
8. high magnesium slag volume cement as claimed in claim 5, is characterized in that: in cement slurry, essential mineral composition and weight percentage are respectively, Wingdale 68.7%, magnesium slag 20%, sandstone 6%, coal gangue 5.3%; Separately add the admixture that accounts for above-mentioned raw material gross weight 1%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410459657.4A CN104193199B (en) | 2014-09-11 | 2014-09-11 | A kind of high magnesium slag volume cement |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410459657.4A CN104193199B (en) | 2014-09-11 | 2014-09-11 | A kind of high magnesium slag volume cement |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104193199A true CN104193199A (en) | 2014-12-10 |
| CN104193199B CN104193199B (en) | 2016-08-17 |
Family
ID=52078618
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410459657.4A Active CN104193199B (en) | 2014-09-11 | 2014-09-11 | A kind of high magnesium slag volume cement |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104193199B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107473613A (en) * | 2017-09-19 | 2017-12-15 | 华润水泥（富川）有限公司 | It is a kind of to utilize cement of industrial solid-state castoff production and preparation method thereof |
| CN109354424A (en) * | 2018-12-22 | 2019-02-19 | 山西中条山新型建材有限公司 | A kind of cement slurry |
| CN111499230A (en) * | 2020-04-28 | 2020-08-07 | 安徽盘景水泥有限公司 | Coal gangue solid waste material as raw material admixture |
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| CN103420630A (en) * | 2013-07-11 | 2013-12-04 | 山西东义集团特种水泥有限公司 | Silicate clinker and cement prepared with same |
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2014
- 2014-09-11 CN CN201410459657.4A patent/CN104193199B/en active Active
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| JP2001180992A (en) * | 1999-12-28 | 2001-07-03 | Ube Ind Ltd | Cement clinker composition of reduced environmental load type |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107473613A (en) * | 2017-09-19 | 2017-12-15 | 华润水泥（富川）有限公司 | It is a kind of to utilize cement of industrial solid-state castoff production and preparation method thereof |
| CN107473613B (en) * | 2017-09-19 | 2018-08-31 | 华润水泥（富川）有限公司 | A kind of cement and preparation method thereof using industrial solid-state castoff production |
| CN109354424A (en) * | 2018-12-22 | 2019-02-19 | 山西中条山新型建材有限公司 | A kind of cement slurry |
| CN111499230A (en) * | 2020-04-28 | 2020-08-07 | 安徽盘景水泥有限公司 | Coal gangue solid waste material as raw material admixture |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104193199B (en) | 2016-08-17 |
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