CN116219641A - High-fatigue-resistance air fiber mat and preparation method thereof - Google Patents
High-fatigue-resistance air fiber mat and preparation method thereof Download PDFInfo
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- CN116219641A CN116219641A CN202310279635.9A CN202310279635A CN116219641A CN 116219641 A CN116219641 A CN 116219641A CN 202310279635 A CN202310279635 A CN 202310279635A CN 116219641 A CN116219641 A CN 116219641A
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- Prior art keywords
- fiber mat
- parts
- thermoplastic elastomer
- high fatigue
- air fiber
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- 239000000835 fiber Substances 0.000 title claims abstract description 88
- 238000002360 preparation method Methods 0.000 title abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229920002725 thermoplastic elastomer Polymers 0.000 claims abstract description 23
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 20
- 229920005672 polyolefin resin Polymers 0.000 claims abstract description 15
- 239000003999 initiator Substances 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 13
- 238000001816 cooling Methods 0.000 claims abstract description 12
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 10
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 10
- 239000003054 catalyst Substances 0.000 claims abstract description 10
- 239000006057 Non-nutritive feed additive Substances 0.000 claims abstract description 8
- 239000012530 fluid Substances 0.000 claims abstract description 5
- 230000000694 effects Effects 0.000 claims abstract description 4
- -1 polyethylene Polymers 0.000 claims description 23
- 238000010438 heat treatment Methods 0.000 claims description 21
- 239000004698 Polyethylene Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 229920000573 polyethylene Polymers 0.000 claims description 8
- UJBORAMHOAWXLF-UHFFFAOYSA-N 1-(aziridin-1-yl)octadecan-1-one Chemical compound CCCCCCCCCCCCCCCCCC(=O)N1CC1 UJBORAMHOAWXLF-UHFFFAOYSA-N 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- QNRSKOMEMRENSK-UHFFFAOYSA-L C(C=C/C(=O)[O-])(=O)[O-].C(CCC)[Sn+2]CCCC.C(CCCCCCCCCCC)(=O)O Chemical compound C(C=C/C(=O)[O-])(=O)[O-].C(CCC)[Sn+2]CCCC.C(CCCCCCCCCCC)(=O)O QNRSKOMEMRENSK-UHFFFAOYSA-L 0.000 claims description 5
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 5
- 239000012975 dibutyltin dilaurate Substances 0.000 claims description 5
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 5
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 claims description 5
- XCPFSALHURPPJE-UHFFFAOYSA-N (3,5-ditert-butyl-4-hydroxyphenyl) propanoate Chemical compound CCC(=O)OC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 XCPFSALHURPPJE-UHFFFAOYSA-N 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 229920006345 thermoplastic polyamide Polymers 0.000 claims description 3
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 2
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 claims description 2
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims description 2
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 2
- UAUDZVJPLUQNMU-UHFFFAOYSA-N Erucasaeureamid Natural products CCCCCCCCC=CCCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-UHFFFAOYSA-N 0.000 claims description 2
- GIATZHZBSIMOEE-UHFFFAOYSA-N P(O)(O)O.P(O)(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1)C(C)(C)C)C(C)(C)C Chemical compound P(O)(O)O.P(O)(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1)C(C)(C)C)C(C)(C)C GIATZHZBSIMOEE-UHFFFAOYSA-N 0.000 claims description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 2
- HLXGBWBZPNMJJQ-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] dioctadecyl phosphite Chemical compound P(OCCCCCCCCCCCCCCCCCC)(OCCCCCCCCCCCCCCCCCC)OCC(CO)(CO)CO HLXGBWBZPNMJJQ-UHFFFAOYSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 150000001408 amides Chemical class 0.000 claims description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 claims description 2
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 claims description 2
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- HYTJADYUOGDVRL-UHFFFAOYSA-N n-phenyl-n-(2-phenylpropan-2-yl)aniline Chemical compound C=1C=CC=CC=1C(C)(C)N(C=1C=CC=CC=1)C1=CC=CC=C1 HYTJADYUOGDVRL-UHFFFAOYSA-N 0.000 claims description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- 239000004800 polyvinyl chloride Substances 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000000344 soap Chemical class 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- QEQBMZQFDDDTPN-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy benzenecarboperoxoate Chemical compound CC(C)(C)OOOC(=O)C1=CC=CC=C1 QEQBMZQFDDDTPN-UHFFFAOYSA-N 0.000 claims 1
- CCNDOQHYOIISTA-UHFFFAOYSA-N 1,2-bis(2-tert-butylperoxypropan-2-yl)benzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC=C1C(C)(C)OOC(C)(C)C CCNDOQHYOIISTA-UHFFFAOYSA-N 0.000 claims 1
- 238000001125 extrusion Methods 0.000 claims 1
- 238000007493 shaping process Methods 0.000 abstract description 11
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000002844 melting Methods 0.000 abstract description 3
- 230000008018 melting Effects 0.000 abstract description 3
- 230000035699 permeability Effects 0.000 abstract description 3
- 238000004804 winding Methods 0.000 abstract description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 21
- 239000000463 material Substances 0.000 description 10
- 238000005520 cutting process Methods 0.000 description 8
- GXBCWRMJQPLZDU-UHFFFAOYSA-N 2-methyl-2-propan-2-ylperoxypropane Chemical compound CC(C)OOC(C)(C)C GXBCWRMJQPLZDU-UHFFFAOYSA-N 0.000 description 7
- 229920006026 co-polymeric resin Polymers 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 229920013716 polyethylene resin Polymers 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 230000006835 compression Effects 0.000 description 5
- 238000007906 compression Methods 0.000 description 5
- 238000007373 indentation Methods 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 3
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 3
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 3
- 239000004816 latex Substances 0.000 description 3
- 229920000126 latex Polymers 0.000 description 3
- 239000002861 polymer material Substances 0.000 description 3
- 238000005452 bending Methods 0.000 description 2
- 230000001739 rebound effect Effects 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical group CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000007541 indentation hardness test Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 150000002978 peroxides Chemical group 0.000 description 1
- 229920005594 polymer fiber Polymers 0.000 description 1
- 229920006124 polyolefin elastomer Polymers 0.000 description 1
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/005—Synthetic yarns or filaments
- D04H3/007—Addition polymers
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/005—Synthetic yarns or filaments
- D04H3/009—Condensation or reaction polymers
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/005—Synthetic yarns or filaments
- D04H3/009—Condensation or reaction polymers
- D04H3/011—Polyesters
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/14—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
- D04H3/147—Composite yarns or filaments
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Nonwoven Fabrics (AREA)
Abstract
The invention discloses a high fatigue resistance air fiber mat and a preparation method thereof, wherein the high fatigue resistance air fiber mat comprises 60-90 parts of thermoplastic elastomer resin, 10-40 parts of polyolefin resin, 1-2 parts of cross-linking agent, 0.1-0.4 part of initiator, 0.1-0.5 part of catalyst, 0.3-0.6 part of antioxidant and 0.5-2 parts of processing aid; adding thermoplastic elastomer resin, polyolefin resin, a cross-linking agent, an initiator, a catalyst and an antioxidant into an extruder, melting to form fluid, extruding the fluid through a die head to form fiber filaments, winding and bonding the fiber filaments under the buoyancy effect when the fiber filaments fall to the water surface, and performing water cooling shaping to obtain the high fatigue-resistant air fiber mat. Compared with the conventional air fiber pad, the high-fatigue-resistance air fiber pad prepared by the invention has the advantages of better high elasticity, high permeability, high support, high fatigue resistance and the like, is suitable for manufacturing mattresses or automobile cushions, sleeping mats and the like with higher use frequency, and has simple preparation method and easy production, popularization and application.
Description
Technical Field
The invention belongs to the technical field of high polymer materials, and particularly relates to a high fatigue-resistant air fiber mat and a preparation method thereof.
Background
The main material types of the mattress or cushion commonly used at present are sponge, spring, latex and the like. The resilience of the sponge is poor, so that the sponge cushion is easy to dent; the spring pad with enough support degree lacks softness, and has quicker loss after long-term use, so that the surface is uneven; the cost of the latex pad is high and the latex pad is easy to cause allergy to human body. The high polymer fiber pad is a high polymer material which is heated and melted, after spinning plate spinning, fiber filaments are wound to form bonding points, and the bonding points are gathered to form a three-dimensional ring connector with irregular holes. Chinese patent (publication No. CN 113287902A) discloses a preparation method of an air fiber cushion, which uses polyolefin elastomer as a base polymer and is matched with proper additives, and the air fiber cushion with high elasticity, high support and good air permeability is obtained through the steps of mixing, stirring, heating and melting, extruding filaments, cooling, shaping, flattening, cutting and the like.
However, large-area collapse often occurs in the use process of the common fiber mat, the supporting hardness and rebound effect are seriously deteriorated, and the service life of the common fiber mat is greatly shortened; the bond points between the filaments were analyzed as critical stress sites, which resulted in increased collapse stiffness loss (after compression fatigue) of the fiber mat once debonded and destroyed. Therefore, how to increase the number of bonding points and the bonding strength becomes a key problem in preparing a high fatigue resistant fiber mat.
Disclosure of Invention
Aiming at the problems of large collapse area, poor supporting hardness and rebound effect and short service life of the fiber mat in the prior art, the invention provides the high-fatigue-resistant air fiber mat and the preparation method thereof, the number of bonding points among fiber filaments and the bonding strength of the bonding points are improved, and the prepared air fiber mat has high supporting degree and high fatigue resistance.
The invention is realized by the following technical scheme:
the high fatigue resistance air fiber mat comprises the following components in parts by weight: 60-90 parts of thermoplastic elastomer resin, 10-40 parts of polyolefin resin, 1-2 parts of cross-linking agent, 0.1-0.4 part of initiator, 0.1-0.5 part of catalyst, 0.3-0.6 part of antioxidant and 0.5-2 parts of processing aid.
Further, the high fatigue resistance air fiber mat comprises the following components in parts by weight: 73 parts of thermoplastic elastomer resin, 10 parts of polyolefin resin, 1 part of cross-linking agent, 0.2 part of initiator, 0.5 part of catalyst, 0.5 part of antioxidant and 1 part of processing aid.
Further, the thermoplastic elastomer resin is one or more of polyurethane thermoplastic elastomer, styrene thermoplastic elastomer, olefin thermoplastic elastomer, dynamic vulcanization thermoplastic elastomer, polyester thermoplastic elastomer and polyamide thermoplastic elastomer.
Further, the polyolefin resin is one or more of polyethylene, polypropylene and polyvinyl chloride.
Further, the cross-linking agent is more than one of vinyl trimethoxy silane, vinyl triethoxy silane, vinyl tri (2-methoxyethoxy) silane and 3-methacryloxypropyl trimethoxy silane.
The initiator is more than one of dicumyl peroxide, di (tert-butyl isopropyl peroxide) benzene, tert-butyl peroxybenzoate and dibenzoyl peroxide.
Further, the catalyst is more than one of dibutyl tin laurate maleate, naphthalene sulfonic acid, toluene sulfonic acid, dodecylbenzene sulfonic acid and dibutyl tin dilaurate maleate; the processing aid is more than one of ethyl bis-oleamide, primary unsaturated amide derivative compounds, fatty acid esters, a mixture of various amide compounds and soap salts, glycerol, ethylene stearamide, polyethylene wax and erucamide.
Further, the antioxidant is one or more of pentaerythritol dodecyl thiopropyl ester, 4-bis (alpha, alpha-dimethylbenzyl) diphenylamine, bis (2, 4-di-tert-butylphenyl) pentaerythritol bisphosphite, pentaerythritol tetrakis (beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate), tris (2, 4-di-tert-butylphenyl) phosphite, pentaerythritol distearyl phosphite, (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate, methyl tetramethylene (3, 5-di-tert-butyl-4-hydroxyphenyl propionate) and dioctadecyl tetraol bisphosphite.
In the invention, the preparation method of the high fatigue resistance air fiber mat comprises the following steps: adding thermoplastic elastomer resin, polyolefin resin, a cross-linking agent, an initiator, a catalyst and an antioxidant into an extruder, melting to form fluid, extruding the fluid through a die head to form fiber filaments, winding and bonding the fiber filaments under the buoyancy effect when the fiber filaments fall to the water surface, and performing water cooling shaping to obtain the high fatigue-resistant air fiber mat.
Further, the extruder is a double-screw extruder and comprises 8 sections of heating areas, wherein the temperature of the heating areas is 160-250 ℃.
According to the invention, the thermoplastic elastomer is melt-blended with the polyolefin resin, the cross-linking agent, the initiator and the like, so that the polyolefin resin, the cross-linking agent and the initiator are uniformly distributed in the thermoplastic elastomer, and the cross-linking agent is hydrolyzed and the polyolefin resin is crosslinked by utilizing the process that fibers are shaped and pulled in water; the cross-linked polyolefin resin is uniformly dispersed in the thermoplastic elastomer resin in a more stable three-dimensional structure, so that the tearing strength of the bonding part of the fiber yarn is improved, and the fiber yarn without the bonding structure has more micro-cross-linked structures inside, so that the performances of the fiber pad such as wear resistance, heat resistance deformation resistance, bending resistance and the like are integrally improved;
advantageous effects
The invention improves the number of bonding points among fiber filaments and the bonding strength thereof, so that the prepared high fatigue-resistant air fiber mat has the advantages of better high elasticity, high permeability, high support, high fatigue resistance and the like compared with the conventional air fiber mat, is suitable for manufacturing mattresses or automobile cushions, sleeping mats and the like with higher use frequency, and has simple preparation method and easy production, popularization and application.
Drawings
FIG. 1 is a block diagram of a high fatigue resistance air fiber mat made in accordance with the present invention.
Detailed Description
In order that the invention may be readily understood, a more particular description of the invention will be rendered by reference to specific embodiments that are illustrated below. It should be understood that these embodiments are provided so that this disclosure will be thorough and complete, and should not be construed as limiting the scope of the invention. Some insubstantial modifications and adaptations of the invention by those skilled in the art in light of the instant disclosure remain within the scope of the invention.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. The "parts" in the present invention refer to parts by weight unless otherwise specified.
Example 1
73 parts of ethylene-propylene copolymer resin, 10 parts of polyethylene resin, 1 part of vinyl triethoxysilane, 0.3 part of bis (tert-butyl isopropyl peroxide) benzene, 0.5 part of dibutyl tin laurate maleate, 0.5 part of pentaerythritol dodecyl propyl sulfide and 1 part of polyethylene wax are uniformly mixed, then the mixture is added into a feeding port of a double-screw extruder, the temperature of a heating zone (comprising 8 heating zones) of the double-screw extruder is controlled to be 200+/-5 ℃, materials are heated, melted and extruded, fiber yarns are formed through a die head, the fiber yarns are subjected to buoyancy when falling to the water surface, the fiber yarns are wound and bonded with each other, and are subjected to water cooling shaping, traction, drying and cutting to obtain the high fatigue-resistant air fiber mat, and the structure of the high fatigue-resistant air fiber mat is shown in figure 1.
Example 2
73 parts of propylene-octene copolymer resin, 10 parts of polypropylene resin, 1 part of vinyl triethoxysilane, 0.3 part of bis (tert-butyl isopropyl peroxide) benzene, 0.5 part of dibutyl tin laurate maleate, 0.5 part of pentaerythritol dodecyl propyl thioate and 1 part of ethylene stearamide are uniformly mixed, then the mixture is added into a feeding port of a double-screw extruder, the temperature of a heating zone (comprising 8 heating zones) of the double-screw extruder is controlled to be 220+/-5 ℃, the materials are heated, melted and extruded, fiber yarns are formed through a die head, the fiber yarns are mutually wound and bonded due to buoyancy when falling to the water surface, and are subjected to water cooling shaping, traction, drying and cutting to obtain the high fatigue-resistant air fiber mat.
Example 3
73 parts of thermoplastic polyester copolymer resin containing ester bonds and soft segments of ether bonds, 10 parts of polyethylene resin, 1 part of vinyl tri (2-methoxyethoxy) silane, 0.3 part of bis (tert-butyl isopropyl peroxide) benzene, 0.5 part of dibutyl tin dilaurate, 0.5 part of dioctadecyl tetraol diphosphite and 1 part of ethylene stearamide are uniformly mixed, then the mixture is added into a feeding port of a double screw extruder, the heating area (comprising 8 heating areas) of the double screw extruder is controlled to be 220+/-5 ℃, the materials are heated, melted and extruded, fiber filaments are formed through the die head, and are mutually wound and bonded due to buoyancy when the fiber filaments fall to the water surface, and the fiber filaments are subjected to water cooling shaping, traction, drying and cutting to obtain the high fatigue resistance air fiber mat.
Example 4
73 parts of polystyrene-poly (ethylene-butylene) -polystyrene copolymer resin, 10 parts of polyethylene resin, 1 part of vinyl tri (2-methoxyethoxy) silane, 0.3 part of bis (tert-butyl isopropyl peroxide) benzene, 0.5 part of dibutyl tin dilaurate, 0.5 part of dioctadecyl tetraol diphosphite and 1 part of ethylene stearamide are uniformly mixed, then the mixture is added into a feeding port of a double screw extruder, the heating area (comprising 8 heating areas) of the double screw extruder is controlled to be 220+/-5 ℃, the materials are heated, melted and extruded, fiber filaments are formed through a die head, and are mutually wound and bonded due to buoyancy when the fiber filaments fall to the water surface, and the fiber filaments are subjected to water cooling shaping, traction, drying and cutting to obtain the high fatigue air resistant fiber mat.
Example 5
73 parts of thermoplastic polyamide copolymer resin containing polyester soft segments, 10 parts of polyethylene resin, 1 part of vinyl tri (2-methoxyethoxy) silane, 0.3 part of bis (tert-butyl isopropyl peroxide) benzene, 0.5 part of dibutyl tin dilaurate, 0.5 part of dioctadecyl tetraol diphosphite and 1 part of ethylene stearamide are uniformly mixed, then the mixture is added into a feeding port of a double screw extruder, the heating area (comprising 8 heating areas) of the double screw extruder is controlled to be 230+/-5 ℃, the materials are heated, melted and extruded, the fiber filaments are formed through the die head, and are mutually wound and bonded due to buoyancy when the fiber filaments fall to the water surface, and the fiber filaments are subjected to water cooling shaping, traction, drying and cutting to obtain the high fatigue-resistant air fiber mat.
Comparative example 1
73 parts of ethylene-propylene copolymer resin, 10 parts of polyethylene resin, 0.5 part of pentaerythritol dodecyl thiopropyl ester and 1 part of polyethylene wax are uniformly mixed, then are added into a feeding port of a double-screw extruder, the temperature of a heating zone (comprising 8 heating zones) of the double-screw extruder is controlled to be 200+/-5 ℃, materials are heated and melted and extruded, fiber filaments are formed through a die head, are subjected to buoyancy when falling to the water surface, are wound and bonded with each other, and are subjected to water cooling shaping, traction, drying and cutting, thus obtaining the air fiber mat.
Comparative example 2
73 parts of propylene-octene copolymer tree, 10 parts of polypropylene resin, 0.5 part of pentaerythritol dodecyl propyl thio ester and 1 part of polyethylene wax are uniformly mixed, then are added into a feeding port of a double-screw extruder, the temperature of a heating zone (comprising 8 heating zones) of the double-screw extruder is controlled to be 220+/-5 ℃, materials are heated and melted to be extruded, fiber filaments are formed through a die head, are subjected to buoyancy when falling to the water surface, are wound and adhered with each other, are shaped through water cooling, and are pulled, dried and cut, thus obtaining the air fiber mat.
Comparative example 3
73 parts of ethylene-propylene copolymer resin, 10 parts of polyethylene resin, 3 parts of vinyl triethoxysilane, 1 part of bis (tert-butyl isopropyl peroxide) benzene, 0.5 part of dibutyl tin laurate maleate, 0.5 part of pentaerythritol dodecyl propyl sulfide and 1 part of polyethylene wax are uniformly mixed, then the mixture is added into a feeding port of a double-screw extruder, the temperature of a heating zone (comprising 8 heating zones) of the double-screw extruder is controlled to be 200+/-5 ℃, the materials are heated, melted and extruded, fiber yarns are formed through a die head, the fiber yarns are subjected to buoyancy when falling to the water surface, so that the fiber yarns are mutually wound and bonded, and are subjected to water cooling shaping, traction, drying and cutting to obtain the air fiber mat,
performance testing
The air fiber mats prepared in examples 1 to 5 and comparative examples 1 to 3 were tested for tensile strength, elongation at break, 25% indentation hardness, indentation ratio, and compressive fatigue hardness loss, wherein the indentation ratio is the ratio of 65% to 25% deformation corresponding values when the fiber mats were subjected to an open indentation hardness test; compression fatigue hardness loss: the fiber mat was repeatedly compressed about one hundred thousand times, and the difference in the corresponding collapse hardness at 40% of the compressed fiber mat thickness was measured, with the compression frequency (70.+ -. 5) times/min. The test results are shown in table 1 below:
table 1 results of air fiber mat performance tests prepared in examples 1 to 5 and comparative examples 1 to 3
As can be seen from table 1, the addition of the crosslinking agent can crosslink the air fiber mat in the shaping process in water, thereby improving the tensile strength and 25% indentation hardness and greatly reducing the compression fatigue hardness loss; however, the elongation at break is reduced due to the presence of more micro network structures after crosslinking; there is no obvious trend in the variation of the collapse ratio. From the results of examples 1 and 3, it can be seen that the more the crosslinking agent is added, the better the crosslinking agent is, the more the amount of the crosslinking agent is added, the more the corresponding initiator is needed, the initiator is peroxide, which is easy to degrade the polymer material in the melting process, so that the material performance is reduced, the compression fatigue hardness loss is higher, and the more the crosslinking agent is, the more the odor is present, and the greater the odor is present in the air fiber mat under the condition of the more the amount of the crosslinking agent is added, so that the user experience is affected.
The addition of the cross-linking agent is favorable for forming a cross-linking structure by the polyolefin resin, improves the tearing strength of the bonding part of the fiber yarn, and improves various performance indexes such as wear resistance, heat resistance, bending resistance and the like of the fiber yarn due to the fact that the fiber yarn which does not form the bonding structure also has more micro-cross-linking structures.
Claims (10)
1. The high fatigue resistance air fiber mat is characterized by comprising the following components in parts by weight: 60-90 parts of thermoplastic elastomer resin, 10-40 parts of polyolefin resin, 1-2 parts of cross-linking agent, 0.1-0.4 part of initiator, 0.1-0.5 part of catalyst, 0.3-0.6 part of antioxidant and 0.5-2 parts of processing aid.
2. The high fatigue resistant air fiber mat according to claim 1, comprising the following components in parts by weight: 73 parts of thermoplastic elastomer resin, 10 parts of polyolefin resin, 1 part of cross-linking agent, 0.2 part of initiator, 0.5 part of catalyst, 0.5 part of antioxidant and 1 part of processing aid.
3. The high fatigue resistant air fiber mat according to claim 1, wherein the thermoplastic elastomer resin is one or more of polyurethane thermoplastic elastomer, styrene thermoplastic elastomer, olefin thermoplastic elastomer, dynamically vulcanized thermoplastic elastomer, polyester thermoplastic elastomer and polyamide thermoplastic elastomer.
4. The high fatigue resistant air fiber mat according to claim 1, wherein the polyolefin resin is one or more of polyethylene, polypropylene and polyvinyl chloride.
5. The high fatigue resistant air fiber mat according to claim 1, wherein the cross-linking agent is one or more of vinyltrimethoxysilane, vinyltriethoxysilane, vinyltris (2-methoxyethoxy) silane and 3-methacryloxypropyl trimethoxysilane.
6. The high fatigue resistant air fiber mat according to claim 1, wherein the initiator is one or more of dicumyl peroxide, bis (t-butylperoxyisopropyl) benzene, t-butyl peroxybenzoate and dibenzoyl peroxide.
7. The high fatigue resistance air fiber mat according to claim 1, wherein the catalyst is one or more of dibutyl tin laurate maleate, naphthalene sulfonic acid, toluene sulfonic acid, dodecylbenzene sulfonic acid and dibutyl tin dilaurate maleate; the processing aid is more than one of ethyl bis-oleamide, primary unsaturated amide derivative compounds, fatty acid esters, a mixture of various amide compounds and soap salts, glycerol, ethylene stearamide, polyethylene wax and erucamide.
8. The high fatigue-resistant air fiber mat according to claim 1, wherein the antioxidant is one or more of pentaerythritol dodecyl propyl ester, 4-bis (alpha, alpha-dimethylbenzyl) diphenylamine, bis (2, 4-di-tert-butylphenyl) pentaerythritol bisphosphite, tetrakis (beta- (3, 5-di-tert-butyl 4-hydroxyphenyl) propionate) pentaerythritol ester, tris (2, 4-di-tert-butylphenyl) phosphite, pentaerythritol distearyl phosphite, (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate n-stearyl alcohol ester, methyl tetramethylene (3, 5-di-tert-butyl-4-hydroxyphenyl propionate) and dioctadecyl tetraol bisphosphite.
9. A method for preparing a high fatigue resistance air fiber mat according to any one of claims 1-8, which is characterized in that thermoplastic elastomer resin, polyolefin resin, a cross-linking agent, an initiator, a catalyst and an antioxidant, and a processing aid are added into an extruder to be melted into fluid, fiber filaments are formed after extrusion through a die head, and the fiber filaments are wound and bonded with each other under the buoyancy effect when falling to the water surface, and are shaped by water cooling to obtain the high fatigue resistance air fiber mat.
10. The method for preparing the high fatigue resistance air fiber mat according to claim 9, wherein the extruder is a twin screw extruder, comprising 8 sections of heating zones, and the temperature of the heating zones is 160-250 ℃.
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| CN101360779A (en) * | 2005-04-29 | 2009-02-04 | 埃克森美孚化学专利公司 | Polypropylene based fibers and nonwovens |
| JP2009079341A (en) * | 2007-09-04 | 2009-04-16 | Idemitsu Kosan Co Ltd | Elastic nonwoven fabric, process for producing the same, and textile product |
| US20140145367A1 (en) * | 2012-11-28 | 2014-05-29 | Milliken & Company | Method of forming a point bridged fiber bundle |
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| CN111655783A (en) * | 2018-01-31 | 2020-09-11 | Mcpp创新有限公司 | Modified elastomer composition, crosslinked elastomer composition, and molded article thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101360779A (en) * | 2005-04-29 | 2009-02-04 | 埃克森美孚化学专利公司 | Polypropylene based fibers and nonwovens |
| JP2009079341A (en) * | 2007-09-04 | 2009-04-16 | Idemitsu Kosan Co Ltd | Elastic nonwoven fabric, process for producing the same, and textile product |
| US20140145367A1 (en) * | 2012-11-28 | 2014-05-29 | Milliken & Company | Method of forming a point bridged fiber bundle |
| CN105239274A (en) * | 2015-11-12 | 2016-01-13 | 浙江金三发非织造布有限公司 | Two-sided hydrophilic punched non-woven fabric special for sanitary consumables and production method thereof |
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