CN116180438A - High-stability in-bath lubricating softener - Google Patents
High-stability in-bath lubricating softener Download PDFInfo
- Publication number
- CN116180438A CN116180438A CN202111418453.2A CN202111418453A CN116180438A CN 116180438 A CN116180438 A CN 116180438A CN 202111418453 A CN202111418453 A CN 202111418453A CN 116180438 A CN116180438 A CN 116180438A
- Authority
- CN
- China
- Prior art keywords
- parts
- softener
- preservative
- mixture
- bath
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000001050 lubricating effect Effects 0.000 title abstract description 16
- 239000004902 Softening Agent Substances 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000003755 preservative agent Substances 0.000 claims abstract description 23
- 230000002335 preservative effect Effects 0.000 claims abstract description 23
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 20
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 15
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 18
- 239000002808 molecular sieve Substances 0.000 claims description 18
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 18
- -1 alkyl glycoside Chemical class 0.000 claims description 13
- 229930182470 glycoside Natural products 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 13
- 239000000314 lubricant Substances 0.000 claims description 12
- 239000000284 extract Substances 0.000 claims description 11
- 239000000243 solution Substances 0.000 claims description 11
- 150000002191 fatty alcohols Chemical class 0.000 claims description 9
- 239000012452 mother liquor Substances 0.000 claims description 9
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims description 7
- 235000011613 Pinus brutia Nutrition 0.000 claims description 7
- 241000018646 Pinus brutia Species 0.000 claims description 7
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 7
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- 229920002545 silicone oil Polymers 0.000 claims description 4
- 241000628997 Flos Species 0.000 claims description 3
- 239000003377 acid catalyst Substances 0.000 claims description 3
- 150000001450 anions Chemical class 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 3
- 238000006555 catalytic reaction Methods 0.000 claims description 3
- 238000005119 centrifugation Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 229960001031 glucose Drugs 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 239000011541 reaction mixture Substances 0.000 claims description 3
- 239000012266 salt solution Substances 0.000 claims description 3
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 3
- 238000005292 vacuum distillation Methods 0.000 claims description 3
- 239000004744 fabric Substances 0.000 abstract description 38
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 10
- 238000005461 lubrication Methods 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 15
- 239000008399 tap water Substances 0.000 description 15
- 235000020679 tap water Nutrition 0.000 description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000010008 shearing Methods 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 230000001804 emulsifying effect Effects 0.000 description 3
- 241000205585 Aquilegia canadensis Species 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 230000003385 bacteriostatic effect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 241000191940 Staphylococcus Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/11—Compounds containing epoxy groups or precursors thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention belongs to the technical field of fabric treatment, and particularly discloses a high-stability in-bath lubricating softener, which comprises the following components in percentage by weight: softening agent, antibacterial agent, nonionic surfactant, preservative, PH regulator and water, wherein the weight portions of the components are as follows: 0.3-1.5 parts of softening agent, 1.2-3.7 parts of antibacterial agent, 13.1-19.7 parts of nonionic surfactant, 0.2-0.5 part of preservative, 1.4-2.1 parts of PH regulator and 5.1-8.3 parts of water. The invention has excellent in-bath lubrication effect, in-bath softening effect and antibacterial property.
Description
Technical Field
The invention belongs to the technical field of fabric treatment, and particularly relates to a high-stability in-bath lubricating softener.
Background
At present, as the demand of textiles is higher and higher, the types and structures of fabrics are more and more, including single fibers, composite materials, blending interweaving and the like, and the fabrics are developed to higher and more complex directions, although corresponding mechanical equipment is used according to various fabric types and different fabric structures in the dyeing and finishing wet process processing process, the processing modes of high efficiency, small bath ratio and large capacity are continuously increased, and the processing modes of small bath ratio and large capacity can lead to the increase of mutual friction among fabrics and between fabrics and equipment, so that the problems of wrinkling, crease, scratch, abrasion and the like of the fabrics are easy to generate; in addition, the fabric is hard and rough after being washed by water; secondly, because the stability of equipment is poor, the problems of demulsification, sticking to rollers and the like are easy to generate in the using process, and the dyeing effect of the fabric is affected. The problems can seriously affect the color light and the fastness of the fabric, and finally seriously affect the quality of the fabric; the swelling of fabrics such as rayon can significantly exacerbate the problem, especially in heavy and tight fabrics, which can seriously affect the quality of the fabric.
Therefore, development of a high stability in-bath lubricant softener has a very broad prospect.
Disclosure of Invention
In view of the above technical problems in the related art, the present invention provides a high-stability in-bath lubricant softener, which can overcome the above disadvantages of the prior art.
In order to achieve the technical purpose, the technical scheme of the invention is realized as follows:
a high stability in-bath lubricant softener comprising: softening agent, antibacterial agent, nonionic surfactant, preservative, PH regulator and water, wherein the weight portions of the components are as follows: 0.3-1.5 parts of softening agent, 1.2-3.7 parts of antibacterial agent, 13.1-19.7 parts of nonionic surfactant, 0.2-0.5 part of preservative, 1.4-2.1 parts of PH regulator and 5.1-8.3 parts of water.
Further: the antibacterial agent is a mixture of honeysuckle extract or pine extract, and has good antibacterial and bactericidal effects after the honeysuckle extract and the pine extract are mixed.
Further: the softening agent is water-soluble silicone oil, so that the fabric has good softening and lubricating effects.
Further: the nonionic surfactant is a mixture of alkyl glycoside and polyoxyethylene ether, and the two are mixed according to the following formula 1: (1.1-1.5). Therefore, the two can have good surface activity and emulsifying dispersion performance after being mixed.
Further: the nonionic surfactant is prepared by the following method:
continuously reacting anhydrous glucose with fatty alcohol under the catalysis of an acid catalyst to obtain a reaction mixture containing alkyl glycoside and fatty alcohol;
removing fatty alcohol through vacuum distillation dealcoholization treatment to obtain alkyl glycoside;
adding the alkyl glycoside and the polyoxyethylene ether into a V-shaped mixer, and mixing for 10-15 minutes to obtain the required nonionic surfactant.
Further: the preservative is a mixture of a porous molecular sieve and elemental silver nano particles. The preservative can prolong the shelf life of the lubricating softener and avoid the problem of waste caused by the fact that the lubricating softener cannot be used in a limited period.
Further: the preservative is prepared by the following method:
adding an anion donor solution and a soluble silver salt solution into the aqueous solution to form a mixture, adding a catalyst into the mixture, catalyzing the mixture to form elemental silver nano-particles through the catalyst, and filtering the elemental silver nano-particles to obtain elemental silver nano-particles;
the molecular sieve is prepared by adopting a grinding method, water is added into the molecular sieve and stirred to obtain molecular sieve mother liquor, elemental silver nano particles are added into the molecular sieve mother liquor, the elemental silver nano particles account for 20% -35% of the molecular sieve mother liquor, and the product is subjected to centrifugation, washing, drying and roasting to obtain the preservative.
The invention discloses a high-stability in-bath lubricating softener, which has the following beneficial effects:
1. the invention has excellent lubricating effect in bath, and effectively reduces the mutual friction between fabrics and equipment;
2. the invention has excellent softening effect in bath, and can effectively prevent crease, scratch, piling mark and the like from being generated in the wet processing process;
3. the invention has better antibacterial effect.
Detailed Description
The following description of the technical solutions in the embodiments of the present invention will be clear and complete, and it is obvious that the described embodiments are only some embodiments of the present invention, but not all embodiments. All other embodiments, which are derived by a person skilled in the art based on the embodiments of the invention, fall within the scope of protection of the invention.
A high stability in-bath lubricant softener comprising: softening agent, antibacterial agent, nonionic surfactant, preservative, PH regulator and water, wherein the weight portions of the components are as follows: 0.3-1.5 parts of softening agent, 1.2-3.7 parts of antibacterial agent, 13.1-19.7 parts of nonionic surfactant, 0.2-0.5 part of preservative, 1.4-2.1 parts of PH regulator and 5.1-8.3 parts of water.
Wherein the antibacterial agent is flos Lonicerae extract or mixture of pine extracts, wherein flos Lonicerae extract has inhibiting effect on Escherichia coli and Staphylococcus, and has aromatic smell; the pine extract has pine fragrance and antibacterial effect, and the mixed pine extract has good antibacterial and bactericidal effects, and the antibacterial agent is dissolved in water and can kill bacteria in water and bacteria on fabrics.
The softening agent is water-soluble silicone oil, and the water-soluble silicone oil has good softening and lubricating effects, and can avoid the problems of wrinkling, creasing, scratching, abrasion and the like of the fabric.
The nonionic surfactant is a mixture of alkyl glycoside and polyoxyethylene ether, and the two are mixed according to the following formula 1: (1.1-1.5). The alkyl glycoside has the advantages of good surface activity, mild human body, easy degradation and good environmental compatibility; the polyoxyethylene ether has better emulsifying and dispersing properties; therefore, the two materials can have good surface activity and emulsifying dispersion performance after being mixed; and the nonionic surfactant is prepared by the following method:
continuously reacting anhydrous glucose with fatty alcohol under the catalysis of an acid catalyst to obtain a reaction mixture containing alkyl glycoside and fatty alcohol;
removing fatty alcohol through vacuum distillation dealcoholization treatment to obtain alkyl glycoside;
adding the alkyl glycoside and the polyoxyethylene ether into a V-shaped mixer, and mixing for 10-15 minutes to obtain the required nonionic surfactant.
The preservative is a mixture of a porous molecular sieve and elemental silver nano particles. The preservative can prolong the shelf life of the lubricating softener to avoid the problem of waste caused by incapability of being used in a limited period, the shelf life of the common softener is 12 months to 18 months, and the shelf life can be prolonged to more than 24 months after the preservative is added. And the preservative is prepared by the following method:
adding an anion donor solution and a soluble silver salt solution into the aqueous solution to form a mixture, adding a catalyst into the mixture, catalyzing the mixture to form elemental silver nano-particles through the catalyst, and filtering the elemental silver nano-particles to obtain elemental silver nano-particles;
the molecular sieve is prepared by adopting a grinding method, water is added into the molecular sieve and stirred to obtain molecular sieve mother liquor, elemental silver nano particles are added into the molecular sieve mother liquor, the elemental silver nano particles account for 20% -35% of the molecular sieve mother liquor, and the product is subjected to centrifugation, washing, drying and roasting to obtain the preservative.
The performance of the high stability bath lubricant softener of the present invention was analyzed by different experiments.
Embodiment one:
the softener is prepared by taking 0.3 part by mass of softener, 1.2 parts by mass of antibacterial agent, 13.1 parts by mass of nonionic surfactant, 0.2 part by mass of preservative, 1.4 parts by mass of PH regulator and 5.1 parts by mass of water.
Embodiment two:
1.0 part of softening agent, 2.3 parts of antibacterial agent, 15.5 parts of nonionic surfactant, 0.4 part of preservative, 2.0 parts of PH regulator and 7.5 parts of water are taken according to the parts by mass to prepare the softening agent.
Embodiment III:
1.5 parts of softening agent, 3.7 parts of antibacterial agent, 19.7 parts of nonionic surfactant, 0.5 part of preservative, 2.1 parts of PH regulator and 8.3 parts of water are taken according to the parts by mass to prepare the softening agent.
Comparative example one:
taking softening agent in textile bath produced by Toguan-city Taiyang textile products Co.
Comparative example two:
the softener in the textile bath produced by the company of high new materials, corp.
Experiment one:
taking the softening agents of the first embodiment, the second embodiment, the third embodiment, the first comparative embodiment and the second comparative embodiment, and putting the prepared softening agent into tap water, wherein the ratio of the softening agent to the tap water is 20g:1L, then observing the stability condition of the softener after mixing with tap water, wherein the stability condition comprises alkali resistance, alkali resistance and salt resistance, color fixing agent resistance, high temperature resistance and shearing resistance; wherein the alkali resistance is judged by adding NaOH powder into tap water containing a softener, the ratio of the NaOH powder to the tap water is 120g:1L, the alkali resistance and the salt resistance are judged by adding sodium carbonate and sodium sulfate into the tap water containing the softener, the ratio of the sodium carbonate to the tap water is 60g:1L, and the ratio of the sodium sulfate to the tap water is 15g:1L, the condition of resisting the fixing agent is judged by adding the fixing agent into tap water containing the softening agent, the ratio of the fixing agent to the tap water is 60g to 1L, the condition of resisting high temperature is judged by heating the tap water containing the softening agent to 130 ℃, and keeping the temperature for 40 minutes at the temperature according to the condition of the solution, the condition of resisting shearing comprises the condition of resisting shearing at normal temperature and the condition of resisting shearing at 60 ℃, the condition of resisting shearing refers to the condition of stirring the solution for 30 minutes at the speed of 2000r/min to observe the solution, in the experiment, the solution is unstable if the solution is turbid, precipitates and the like, and the solution is stable if the condition does not appear; table one is obtained:
table one: stability of softener under different conditions
As can be seen from the above table, the high stability bath lubricating softener of the present invention has better stability under various conditions than the comparative example, which has no stability under alkaline solution and high temperature conditions, and the comparative example, which has no stability under alkaline environment, anhydrous sodium sulfate environment and color fixing agent environment.
2. Lubricating effect experiment of wet-evaluated fabrics after treatment of fabrics with different softeners
Taking the softening agents of the first embodiment, the second embodiment, the third embodiment, the first comparative embodiment and the second comparative embodiment, putting the prepared softening agents into tap water, respectively, wherein the ratio of the softening agents to the tap water is 1g/L, 2g/L and 4g/L, wrapping square heavy objects with the obtained wet fabrics, the weight of the heavy objects is 1kg, placing the wrapped heavy objects on the same position of an angle-adjustable inclined plate, adjusting the included angle between the inclined plate and the ground to enable the heavy objects to start to slide downwards, and recording the critical angle (unit: degree) of the sliding of the heavy objects.
And (II) table: experimental results of different softener lubrication effect experiments
It should be noted that: the data of critical angles are obtained in the table above, and the smaller the critical angle value is, the better the lubricating effect of the softener is, so that the lubricating effect of the softener is obviously better than that of the comparative example.
3. After the fabrics are treated by different softening agents, the fabric color influence condition experiment is carried out:
taking softening agents of the first embodiment, the second embodiment, the third embodiment, the first comparative embodiment and the second comparative embodiment, and sequentially treating 10g of the full cotton grey cloth of 40cmX cm or 133cmX cm according to the following sequence: putting the fabric into water, adding a softening agent into the water, washing the fabric with water at the ratio of the softening agent to tap water of 2g/L, putting a PH regulator into the washed water, regulating PH, taking out the fabric to dye the fabric, washing the dyed fabric with water again, soaping the fabric again at 98 ℃ for 10min, adding the softening agent into the soaped water at the ratio of the softening agent to the water of 1g/L, washing and drying the fabric after the soaping, and testing the color difference of the dried fabric.
Table three: fabric color difference test meter for lubricating softening agents in different baths
It should be noted that: after the softener is used, the influence on the color depth value of the fabric is small.
4. After the fabrics are treated by different softening agents, the antibacterial effect of the fabrics is tested:
taking the softening agents of the first embodiment, the second embodiment, the third embodiment, the first comparative embodiment and the second comparative embodiment, adding the softening agents into water, wherein the ratio of the softening agents to tap water is 2g/L, and determining the antibacterial effect evaluation of the first embodiment, the third embodiment, the first comparative embodiment and the second comparative embodiment according to the antibacterial effect test method of the antibacterial and bacteriostatic daily chemical products in QB/T2738-2005 evaluation method of antibacterial and bacteriostatic effect of daily chemical products, wherein the results are shown in the table IV:
table four: antibacterial effect meter
From the fourth table, the softener has a good sterilization effect, can reach more than 89.7, and has a good sterilization effect on staphylococcus aureus and escherichia coli.
The preferred embodiments of the present invention have been described in detail above, but the present invention is not limited to the specific details of the above embodiments, and various equivalent changes can be made to the technical solution of the present invention within the scope of the technical concept of the present invention, and all the equivalent changes belong to the protection scope of the present invention.
Claims (7)
1. A high stability in-bath lubricant softener comprising: softening agent, antibacterial agent, nonionic surfactant, preservative, PH regulator and water, wherein the weight portions of the components are as follows: 0.3-1.5 parts of softening agent, 1.2-3.7 parts of antibacterial agent, 13.1-19.7 parts of nonionic surfactant, 0.2-0.5 part of preservative, 1.4-2.1 parts of PH regulator and 5.1-8.3 parts of water.
2. A high stability in-bath lubricant softener according to claim 1, characterized in that: the antibacterial agent is flos Lonicerae extract or mixture of pine extracts.
3. A high stability in-bath lubricant softener according to claim 2, characterized in that: the softening agent is water-soluble silicone oil.
4. A high stability in-bath lubricant softener according to claim 3, characterized in that: the nonionic surfactant is a mixture of alkyl glycoside and polyoxyethylene ether, and the two are mixed according to the following formula 1: (1.1-1.5).
5. A high stability in-bath lubricant softener according to claim 4, characterised in that: the nonionic surfactant is prepared by the following method:
continuously reacting anhydrous glucose with fatty alcohol under the catalysis of an acid catalyst to obtain a reaction mixture containing alkyl glycoside and fatty alcohol;
removing fatty alcohol through vacuum distillation dealcoholization treatment to obtain alkyl glycoside;
adding the alkyl glycoside and the polyoxyethylene ether into a V-shaped mixer, and mixing for 10-15 minutes to obtain the required nonionic surfactant.
6. A high stability in-bath lubricant softener according to claim 5, characterised in that: the preservative is a mixture of a porous molecular sieve and elemental silver nano particles.
7. A high stability in-bath lubricant softener according to claim 6, characterized in that: the preservative is prepared by the following method:
adding an anion donor solution and a soluble silver salt solution into the aqueous solution to form a mixture, adding a catalyst into the mixture, catalyzing the mixture to form elemental silver nano-particles through the catalyst, and filtering the elemental silver nano-particles to obtain elemental silver nano-particles;
the molecular sieve is prepared by adopting a grinding method, water is added into the molecular sieve and stirred to obtain molecular sieve mother liquor, elemental silver nano particles are added into the molecular sieve mother liquor, the elemental silver nano particles account for 20% -35% of the molecular sieve mother liquor, and the product is subjected to centrifugation, washing, drying and roasting to obtain the preservative.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111418453.2A CN116180438A (en) | 2021-11-26 | 2021-11-26 | High-stability in-bath lubricating softener |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111418453.2A CN116180438A (en) | 2021-11-26 | 2021-11-26 | High-stability in-bath lubricating softener |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN116180438A true CN116180438A (en) | 2023-05-30 |
Family
ID=86450978
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111418453.2A Pending CN116180438A (en) | 2021-11-26 | 2021-11-26 | High-stability in-bath lubricating softener |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN116180438A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103232497A (en) * | 2013-04-09 | 2013-08-07 | 浙江赞宇科技股份有限公司 | Alkyl glucoside preparation method |
| CN105418699A (en) * | 2015-12-29 | 2016-03-23 | 河北合佳医药科技集团有限公司 | Method and production device for continuously producing alkyl glucoside |
| CN108130739A (en) * | 2017-12-19 | 2018-06-08 | 江苏新瑞贝科技股份有限公司 | A kind of wetting softener and preparation method thereof |
| CN110820352A (en) * | 2019-11-21 | 2020-02-21 | 江苏宇道生物科技有限公司 | High-safety non-yellowing smooth and elastic soft finishing agent and preparation method thereof |
-
2021
- 2021-11-26 CN CN202111418453.2A patent/CN116180438A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103232497A (en) * | 2013-04-09 | 2013-08-07 | 浙江赞宇科技股份有限公司 | Alkyl glucoside preparation method |
| CN105418699A (en) * | 2015-12-29 | 2016-03-23 | 河北合佳医药科技集团有限公司 | Method and production device for continuously producing alkyl glucoside |
| CN108130739A (en) * | 2017-12-19 | 2018-06-08 | 江苏新瑞贝科技股份有限公司 | A kind of wetting softener and preparation method thereof |
| CN110820352A (en) * | 2019-11-21 | 2020-02-21 | 江苏宇道生物科技有限公司 | High-safety non-yellowing smooth and elastic soft finishing agent and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Aminoddin | Antibacterial dyeing of wool with natural cationic dye using metal mordants | |
| CN104396965B (en) | A kind of response type halogen amine antiseptic-germicide and its preparation method and application | |
| CN104775173A (en) | Preparation method for viscose containing wormwood extract | |
| Teli et al. | Multifunctional finishing of cotton using chitosan extracted from bio-waste | |
| CN104805520B (en) | A kind of preparation method of the viscose containing apocynum extract | |
| EP1786957A1 (en) | Anti-microbial fibres and their production | |
| CN102337669A (en) | Method for processing antibacterial wool fiber | |
| CN103554085A (en) | Reaction-type halogen amine antibacterial agent, and synthetic method and application thereof | |
| CN111733021B (en) | Sterilizing washing powder containing PCMX and preparation method thereof | |
| CN105586774A (en) | Antibacterial finishing process for pure cotton towel | |
| CN112227071A (en) | Antimicrobial softener composition | |
| AU8844598A (en) | Process for the treatment of textile materials with an antimicrobial agent | |
| CN110541308A (en) | Preparation method of long-acting antibacterial pure cotton fabric | |
| CN113047038B (en) | Composite tea saponin auxiliary agent for textile pretreatment and preparation method thereof | |
| CN116180438A (en) | High-stability in-bath lubricating softener | |
| RU2640277C2 (en) | Method for production of antimicrobial silver-containing cellulose material | |
| WO2010129006A1 (en) | Bluing composition and method for treating textile articles using the same | |
| JP3779124B2 (en) | Antibacterial and antifungal processing methods for fibers | |
| JP3792984B2 (en) | Antibacterial and antifungal processing methods for fibers | |
| CN112376265B (en) | Method for preparing antimicrobial treatment agent for textiles | |
| JP2012180323A (en) | Method for producing antimicrobial agent for fiber, antimicrobial agent for fiber obtained by the production method, and antimicrobial fiber product | |
| JP2002370911A (en) | Antimicrobially finishing agent and antimicrobially finishing method for textile product | |
| JP5399859B2 (en) | Method for producing polyphenol processed fiber | |
| JP2001288017A (en) | Zinc pyrithione-containing dispersion for antibacterial and antifungal processing and method for antibacterial and antifungal processing of fibers using the dispersion | |
| CN109594367A (en) | The dyeing of woven fabric |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |