CN1161311A - Method for preparing glass ceramics aventurine plate - Google Patents

Method for preparing glass ceramics aventurine plate Download PDF

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Publication number
CN1161311A
CN1161311A CN 96121436 CN96121436A CN1161311A CN 1161311 A CN1161311 A CN 1161311A CN 96121436 CN96121436 CN 96121436 CN 96121436 A CN96121436 A CN 96121436A CN 1161311 A CN1161311 A CN 1161311A
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CN
China
Prior art keywords
glass
metallic particles
manufacture method
devitrified glass
transition layer
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Pending
Application number
CN 96121436
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Chinese (zh)
Inventor
庾杰仁
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Individual
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Individual
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Priority to CN 96121436 priority Critical patent/CN1161311A/en
Publication of CN1161311A publication Critical patent/CN1161311A/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/18—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing free metals
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/40—Coatings comprising at least one inhomogeneous layer
    • C03C2217/42—Coatings comprising at least one inhomogeneous layer consisting of particles only

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Composite Materials (AREA)
  • Dispersion Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

The mfg. method of neoceramic glass golden star stone plate includes: metal particles with appropriate size are processed, then coated with transition layer, the coated metal particles are heated and scattered on neoceramic glass substrate material, and further embedded into the substrate material, then the substrate material together with the metal particles are sintered under definite tump. for a definite time, the neoceramic glass blank plute together with the embedded metal particles is produced. After polishing and cutting, neoceramic glass golden star stone plates are produced.

Description

The manufacture method of glass ceramics aventurine plate
The present invention relates to a kind of manufacture method of decorative panel for building.
The natural building decoration slabstone that has, the gold dust slabstone and the peacock slabstone that for example are used for building wall or ground decoration, because of natural symbiosis in its matrix have metallic copper the layer piece, through the cutting, the polishing after colorful, burnishing, make the people produce sensation happy and that yearn for, very popular.But this type of lithotome is in great shortage, and especially big area sheet material is more rare, causes such production cost of products and market price very high.Human precipitating metal chromium or crystalline method in glasswork are also arranged, and this method is referred in Ceramic glaze and the glasswork, produce chromium (copper) Venus product.But this method is difficult to separate out the macrobead Metallic Solids, is difficult to produce the ideal decorative effect at the big area metope.In addition, the tiny metallic particles major part that this crystallization method is separated out is present in body material inside, and often owing to devitrification behind the devitrified glass crystallization, most of metal small-crystalline can't manifest, and causes serious waste.
The objective of the invention is: a kind of manufacture method of glass ceramics aventurine plate is provided, the aventurine plate of Zhi Zaoing in this way, its metallic particles adjustable size, being used in has the incomparable decorative effect of traditional method on the big area shingle nail; This method using rate of metal height, the materials consumption of having saved noble metal; In addition, this manufacture method is simple, and is convenient and easy.
Technical scheme of the present invention comprises the steps:
A, process the metallic particles of suitable granularity, and it is coated transition layer;
B, be sprinkling upon devitrified glass base-material upper surface to be sintered and metallic particles is embedded in the base-material after will scribbling the metallic particles heating of transition layer;
C, next plays the sintering certain hour at a constant temperature together with metallic particles to allow base-material, forms the devitrified glass blank flat that surperficial close-coupled has metallic particles;
D, described blank flat surface grinding and stripping and slicing are promptly got the glass ceramics aventurine plate finished product.
Because metallic particles is pre-processed among the present invention, its shape and size can arbitrarily determine within the specific limits, during the big plate that make that metope uses, can process metallic particles more greatly, obtains decorative effect preferably.Must be when adopting this method with melting of metal, sintering temperature can be chosen in the temperature (being relatively low temperature) that the devitrified glass melts has enough viscosity, the metallic particles that is sprinkling upon devitrified glass material surface so can too much not bury in matrix the utilization ratio height; Because metal is without fusing, fine control, technology is simple, and is convenient and easy.
The used metallic particles of the present invention can adopt bright, the corrosion resistant metal or alloy of copper alloy, nickelalloy, Chrome metal powder, nichrome and other color, and shape can be arbitrarily.The purpose that adopts alloy is to improve antioxidant anticorrosive and adapt to the sheet material firing temperature.
The used buffer layer material of the present invention is made up of glass powder and defoamer, and wherein the thermal expansivity of glass powder is between used metallic particles and devitrified glass body material.Transition layer can adopt following prescription (weight %):
SiO 2?55～65；Al 2O 3?2～7；CaO?8～13；Na 2·K 2O?12～20；B 2O 3?0.5～2；BaO?0～4
The used devitrified glass body material of the present invention can adopt following prescription (weight %):
SiO 2?55～65；Al 2O 3?2～8；CaO?10～15；Na 2·K 2O?10～16；B 2O 3?0～1；BaO0～4；MgO?1～4
An amount of metal oxide of glass coloring.
Embodiment 1: devitrified glass black sand gold plate
A, commodity copper material C61500 (90Cu-8Al-2Ni) is processed into length and width is 1～5mm, and thickness is the granular standby of 2mm;
B, by following formulation transition layered material (weight %):
SiO 2?62；Al 2O 3?4；CaO?13；Na 2·K 2O?20；B 2O 3?1
With glass furnace it is smelt glass by above prescription, is ground into 120 powder materials again, add an amount of binding agent, defoamer and water furnishing slurry, be uniformly coated on be equipped with on the copper material;
C, employing cullet are the matrix main raw material, get the raw materials ready by following prescription:
Cullet 800Kg; SODIUMNITRATE 50Kg; Feldspar Powder 50Kg; Manganese oxide 20Kg; Lime carbonate 120Kg; Cobalt oxide 2Kg; Borax 10Kg; Ferric oxide 40Kg; Barium carbonate 30Kg
Above-mentioned batching sent in the glass refining material stove be smelt glass, putting into the pond again, to be broken into 1～5mm pellet standby;
D, coat releasing agent being of a size of on the fireproof die of 700mm * 1000mm, put into step c again and be equipped with devitrified glass pellet 26Kg, after floating, evenly spread fertilizer over the fields step a on the surface and be equipped with shot copper material 1Kg, then mould is sent into together with raw material burn till slab in 900 ℃ the kiln after, through cutting edge, polish, polishing, get product.The outward appearance of present embodiment product is that pitch black colored stone matter matrix surface has clinquant alloy copper sheet.
Embodiment 2: devitrified glass silver starboard
A, to be processed into length and width with commodity stainless steel 1Cr25Ni20Si2 be that 2～15mm, thickness are that the saccharoid of 2mm is standby;
B, by following formulation transition layered material (weight %):
SiO 2?60；Al 2O 3?6；CaO?13；Na 2·K 2O?16；B 2O 3?1；BaO?4
With glass furnace it is smelt glass by above prescription, is ground into 120 powder materials again, add an amount of binding agent, defoamer and water furnishing slurry, be uniformly coated on be equipped with on the stainless steel material;
C, employing cullet are the matrix main raw material, get the raw materials ready by following prescription:
Cullet 800Kg; SODIUMNITRATE 20Kg; Feldspar Powder 100Kg; Aluminum oxide 25Kg; Lime carbonate 120Kg; Borax 10Kg; Barium carbonate 30Kg; Potassium permanganate 20Kg
Above-mentioned batching sent in the glass refining material stove be smelt glass, putting into the pond again, to be broken into 1～8mm pellet standby;
D, coat releasing agent being of a size of on the fireproof die of 700mm * 1000mm, put into step c again and be equipped with devitrified glass pellet 26Kg, after floating, evenly spread fertilizer over the fields step a on the surface and be equipped with stainless steel pellet 1Kg, then mould is sent into together with raw material burn till slab in 1000 ℃ the kiln after, through cutting edge, polish, polishing, get product.The outward appearance of present embodiment product is that purplish red colored stone matter matrix surface has silver-shiny stainless steel substrates.
Embodiment 3: devitrified glass gold and jade plate
A, commodity copper material C61500 (90Cu-8Al-2Ni) is processed into length and width is 1～15mm, and thickness is the granular standby of 2mm;
B, by following formulation transition layered material (weight %):
SiO 2?60；Al 2O 3?4；CaO?13；Na 2·K 2O?20；B 2O 3?1
With glass furnace it is smelt glass by above prescription, is ground into 120 powder materials again, add an amount of binding agent, defoamer and water furnishing slurry, be uniformly coated on be equipped with on the copper material;
C, employing cullet are the matrix main raw material, get the raw materials ready by following prescription:
Cullet 800Kg; SODIUMNITRATE 50Kg; Feldspar Powder 50Kg; Lime carbonate 120Kg; Borax 10Kg; Barium carbonate 30Kg; Potassium bichromate 1.5Kg; Cupric oxide 0.8Kg
Above-mentioned batching sent in the glass refining material stove be smelt glass, putting into the pond again, to be broken into the 1-5mm pellet standby;
D, coat releasing agent being of a size of on the fireproof die of 700mm * 1000mm, put into step c again and be equipped with devitrified glass pellet 26Kg, after floating, evenly spread fertilizer over the fields step a on the surface and be equipped with shot copper material 1Kg, then mould is sent into together with raw material burn till slab in 900 ℃ the kiln after, through cutting edge, polish, polishing, get product.The outward appearance of present embodiment product is that greenstone colored stone matter matrix surface has clinquant alloy copper sheet.
Embodiment 4: produce devitrified glass silver starboard with drawplate oven
A, to be processed into length and width with commodity stainless steel 1Cr25Ni20Si2 be that 1～3mm, thickness are that the saccharoid of 2mm is standby;
B, by following formulation transition layered material (weight %):
SiO 2?60；Al 2O 3?6；CaO?13；Na 2·K 2O?15；B 2O 3?2；BaO?4
With glass furnace it is smelt glass by above prescription, is ground into 180 powder materials again, add an amount of binding agent and water furnishing slurry, be uniformly coated on be equipped with on the stainless steel material;
C, devitrified glass base-material, get the raw materials ready by following prescription:
River sand 42Kg; Feldspar Powder 18Kg; Lime carbonate 25Kg; Borax 1Kg; Barium carbonate 6Kg; Potassium permanganate 6Kg; Soda ash 24Kg; Magnesiumcarbonate 4Kg
Above-mentioned batching sent into be smelt behind the melten glass directly arm-tie crystallization in the input devitrified glass drawplate oven in the glass refining material stove;
D, evenly spread fertilizer over the fields an amount of step b at the upper surface of the suitable temperature section devitrified glass material of drawplate oven and be equipped with the stainless steel material, and insulation appropriate time, the stainless steel material is embedded on the microcrystal glass plate face and together behind the sintering, gets product through cooling, annealing, stripping and slicing, polishing.The present embodiment product grains is tiny, outward appearance is fine and close, resembles very much marble.

Claims (5)

1, a kind of manufacture method of glass ceramics aventurine plate is characterized in that comprising the steps:
A, process the metallic particles of suitable granularity, and it is coated transition layer;
B, be sprinkling upon devitrified glass base-material upper surface to be sintered and metallic particles is embedded in the base-material after will scribbling the metallic particles heating of transition layer;
C, allow base-material, form the devitrified glass blank flat that surperficial close-coupled has metallic particles together with metallic particles sintering certain hour at a certain temperature;
D, described blank flat surface grinding and stripping and slicing are promptly got the glass ceramics aventurine plate finished product.
2, manufacture method according to claim 1 is characterized in that: described metallic particles can be for copper alloy, nickelalloy, Chrome metal powder, nichrome and other color be bright, corrosion resistant metal or alloy, and shape can be arbitrarily.
3, manufacture method according to claim 1 is characterized in that: described buffer layer material is made up of glass powder and defoamer, and wherein the thermal expansivity of glass powder is between used metallic particles and devitrified glass body material.
4, manufacture method according to claim 3 is characterized in that: described transition layer can adopt following prescription (weight %):
SiO 255～65；Al 2O 32～7；CaO8～13；Na 2·K 2O12～20；B 2O 30.5～2；BaO0～4。
5, manufacture method according to claim 1 is characterized in that: the body material of described devitrified glass can adopt following prescription (weight %):
SiO 255～65；Al 2O 32～8；CaO10～15；Na 2·K 2O10～16；B 2O 30～1；BaO0～4；MgO1～4。
CN 96121436 1996-12-13 1996-12-13 Method for preparing glass ceramics aventurine plate Pending CN1161311A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 96121436 CN1161311A (en) 1996-12-13 1996-12-13 Method for preparing glass ceramics aventurine plate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 96121436 CN1161311A (en) 1996-12-13 1996-12-13 Method for preparing glass ceramics aventurine plate

Publications (1)

Publication Number Publication Date
CN1161311A true CN1161311A (en) 1997-10-08

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ID=5126890

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 96121436 Pending CN1161311A (en) 1996-12-13 1996-12-13 Method for preparing glass ceramics aventurine plate

Country Status (1)

Country Link
CN (1) CN1161311A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006136610A3 (en) * 2005-06-23 2007-07-12 Colorobbia Italiana Spa Materials for coating ceramic bodies, processes for the preparation thereof, use thereof and ceramic articles including these materials
CN1329328C (en) * 2004-12-20 2007-08-01 大连交通大学 Method for preparing micro crystal glass plate for building using waste glass
CN113061016A (en) * 2021-03-09 2021-07-02 江西金唯冠建材有限公司 Preparation method of integral metal stair ceramic tile with original groove

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1329328C (en) * 2004-12-20 2007-08-01 大连交通大学 Method for preparing micro crystal glass plate for building using waste glass
WO2006136610A3 (en) * 2005-06-23 2007-07-12 Colorobbia Italiana Spa Materials for coating ceramic bodies, processes for the preparation thereof, use thereof and ceramic articles including these materials
CN113061016A (en) * 2021-03-09 2021-07-02 江西金唯冠建材有限公司 Preparation method of integral metal stair ceramic tile with original groove
CN113061016B (en) * 2021-03-09 2022-07-15 江西金唯冠建材有限公司 Preparation method of integral metal stair ceramic tile with original groove

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