CN115926599A - Membrane material for protecting curved screen of mobile phone - Google Patents

Membrane material for protecting curved screen of mobile phone Download PDF

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Publication number
CN115926599A
CN115926599A CN202211742335.1A CN202211742335A CN115926599A CN 115926599 A CN115926599 A CN 115926599A CN 202211742335 A CN202211742335 A CN 202211742335A CN 115926599 A CN115926599 A CN 115926599A
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film
mobile phone
stirring
coating
film coating
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钱桂林
徐长才
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Wuxi Tuohui New Materials Technology Co ltd
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Wuxi Tuohui New Materials Technology Co ltd
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Priority to CN202211742335.1A priority Critical patent/CN115926599A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation

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Abstract

The invention relates to a high polymer film material, in particular to a film material for protecting a curved screen of a mobile phone. The film material for protecting the curved screen of the mobile phone, which is prepared by the invention, can reach the thickness (100-150 mu m) of the traditional base material and has softness, and meanwhile, the film material has high stain resistance and high smooth hand feeling which are not possessed by TPU and TPH base materials. In addition, the invention has ideal attachable performance on any cambered surface, and can protect the display screens of mobile phones and pads from being broken in the process of falling on the ground while resisting general scratches. The product can be used in the fields of electronic product display screens and the like such as mobile phones and the like, and the single coating process replaces the processes of base films and coatings, so that the production cost is greatly reduced, and the production efficiency is improved.

Description

Membrane material for protecting curved screen of mobile phone
Technical Field
The invention relates to a high polymer film material, in particular to a film material for protecting a curved screen of a mobile phone.
Technical Field
The mobile phone film is also called as mobile phone beauty film and mobile phone protective film, which is a film material for mounting mobile phone body and screen. The mobile phone film can protect eyesight and does not hurt eyes. In addition, according to the usage of different mobile phone films, the mobile phone films can be divided into: smart phone screen protection film, phone body protection film, da qin 150 film, peep-proof film, mirror film, AR film, frosted film, scratch-proof protection film, phone body decoration protection film, etc. According to the mobile phone film material, the mobile phone film can be divided into: PC protective film, PVC protective film, PET protective film, AR protective film, etc. of the mobile phone. In addition, the mobile phone films are classified into other categories according to different purposes and mounting modes.
With the popularization of digital products such as mobile phones in China, the protective film has become a general name of the screen protective film slowly, and the function of the protective film in the field of screen protective film materials is also five-door, so that the VIPO functional protective film is popular at the earliest time for high-definition scratch resistance. The materials have undergone years of development from the earliest PP materials to the current popular AR materials, and are slowly accepted by the vast cell phone population. In the current market, the film pasting products are various, the quality is more disordered, and many defective products fill the market, such as gum protective films, which are advocated by merchants once due to low cost, but the gum can damage mobile phone screens and the characteristics of difficult taking down and glue retention are not enough, so that the electrostatic pasting protective films made of PET or ARM are more available.
The current mobile phone film does not have the function of protecting a mobile phone, is not firm enough in installation and has poor structural stability. The traditional mobile phone screen protective film material is prepared from aromatic TPU and a coating. The mobile phone protective film material has the defects of poor yellowing, poor repairability and complex process. The existing mobile phone protective film has poor yellowing and no rebound resilience, and the preparation process is more complex and has low efficiency. Firstly, a TPU base film is prepared by tape casting, and then a coating is applied for construction, so that the process is long, the working procedures are multiple, and the cost is high. Cast TPU has no rebound resilience, no hand feel, no stain resistance, and poor yellow change.
Disclosure of Invention
The invention provides a super-soft mobile phone screen film material capable of replacing traditional TPU (thermoplastic polyurethane rubber) and TPH (thermoplastic polyurethane) base materials.
A film coating for protecting a curved screen of a mobile phone comprises the following components in parts by weight:
a main agent:
Figure BDA0004027942820000011
Figure BDA0004027942820000021
curing agent:
10-20 parts of HDI
The acrylic polyol is chenopodium album 273 or YH-0768.
The drier is preferably delayed drier, and can be one or two of DY-5508 and T12.
The inhibitor is acetylacetone or butanone oxime.
The hand feeling auxiliary agent is one or more of DSP-3890 and BYK-3700.
The invention also comprises a preparation method of the membrane material, which comprises the following steps:
(1) Premixing: taking acrylic polyol, stirring, adding a hand feeling auxiliary agent, and mixing to obtain a premix;
(2) Mixing: adding a drier and an inhibitor into the premix obtained in the step (1), and stirring to obtain the main agent;
(3) The main agent and the curing agent are uniformly mixed to obtain the film coating, which can be used for construction.
In the above preparation method, in the step (1), the conditions of vortex mixing are conventional in the art, and are preferably: dispersing for 30 minutes at 800 revolutions per minute; in step (2), the stirring conditions are conventional in the art, and are preferably: stirring at 400 rpm for 10 minutes; in step (3), the stirring conditions are conventional in the art, and are preferably: stirring at 400 rpm for 10 minutes.
In addition, the invention also comprises an application of the mobile phone curved screen protective film coating in preparing a coating, and the specific application method comprises the following steps:
(1) Coating the protective film paint for the curved screen of the mobile phone on a release film by using a micrometer wire rod until the thickness of a wet film is 150-200 micrometers, and forming a paint film;
(2) Placing the paint film which is subjected to blade coating in an oven for baking;
(3) And (4) after baking the paint film, coating a film with a fluorine film for later use.
The film material for protecting the curved screen of the mobile phone, which is prepared by the invention, can reach the thickness (100-150 mu m) of the traditional base material and has softness, and meanwhile, the film material has high stain resistance and high smooth hand feeling which are not possessed by TPU and TPH base materials. In addition, the invention has ideal attachable performance on any cambered surface, and can protect the display screens of mobile phones and pads from being broken in the process of falling on the ground while resisting general scratches. The product can be used in the fields of display screens of electronic products such as mobile phones and the like, and the single coating process replaces the processes of base films and coatings, so that the production cost is greatly reduced, and the production efficiency is improved.
Detailed Description
In particular embodiments all starting materials are commercially available.
Example 1
(1) Premixing: taking 80 parts of functional acrylic polyol (EMTK-273), stirring, adding 3 parts of handfeel auxiliary agent (DSP-3890), and mixing to obtain a premix, wherein vortex mixing conditions are as follows: disperse for 30 minutes at 800 rpm.
(2) Mixing: adding 0.01 part of drier (DY-5508) and 5 parts of inhibitor (acetylacetone) into the premix obtained in the step (1), and stirring to obtain a main agent finally, wherein the stirring conditions are as follows: stirring at 400 rpm for 10 minutes.
(3) And mixing 100 parts of main agent and 100 parts of curing agent TSE-10020 parts for construction.
Example 2
(1) Premixing: taking 80 parts of functional acrylic polyol (EMTK-273), stirring, adding 3 parts of handfeel auxiliary agent (BYK-3700), and mixing to obtain a premix, wherein vortex mixing conditions are as follows: disperse for 30 minutes at 800 rpm.
(2) Mixing: adding 0.01 part of drier (T12) and 5 parts of inhibitor (butanone oxime) into the premix obtained in the step (1), and stirring to obtain a main agent finally, wherein the stirring conditions are as follows: stirring at 400 rpm for 10 minutes.
(3) And mixing 100 parts of main agent and 100 parts of curing agent TSE-10020 parts for construction.
Example 3
(1) Pre-mixing: taking 80 parts of functional acrylic polyol YH-0768, stirring, adding 3 parts of hand feeling auxiliary agent (DSP-3890) and mixing to obtain a premix, wherein the vortex mixing conditions are as follows: disperse for 30 minutes at 800 rpm.
(2) Mixing: adding 0.01 part of drier (DY-5508) and 5 parts of inhibitor (acetylacetone) into the premix obtained in the step (1), and stirring to obtain a main agent finally, wherein the stirring conditions are as follows: stirring at 400 rpm for 10 minutes.
(3) The main agent 100 parts and the curing agent E405-80T 20 parts are mixed and then constructed.
Example 4
(1) Premixing: taking 80 parts of functional acrylic polyol YH-0768, stirring, adding 3 parts of a hand feeling assistant (BYK-3700), and mixing to obtain a premix, wherein vortex mixing conditions are as follows: disperse for 30 minutes at 800 rpm.
(2) Mixing: adding 0.01 part of drier (T12) and 5 parts of inhibitor (butanone oxime) into the premix obtained in the step (1), and stirring to finally obtain the substituted mobile phone curved screen protective film coating 1, wherein the stirring conditions are as follows: stirring at 400 rpm for 10 minutes.
(3) The main agent 100 parts and the curing agent E405-80T 20 parts are mixed and then constructed. Comparative example prepared TPU material was cast.
Table 1 examples 1-4 and comparative examples performance testing
Figure BDA0004027942820000041
/>

Claims (8)

1. A film coating for protecting a curved screen of a mobile phone is characterized by comprising the following components in parts by weight:
the main agent is as follows:
Figure FDA0004027942810000011
curing agent:
10-20 parts of HDI.
2. The film paint of claim 1, wherein the acrylic polyol is chenopone 273 or YH-0768.
3. The film coating of claim 1, wherein the drier is one or both of DY-5508 and T12.
4. The film coating of claim 1, wherein the inhibitor is acetylacetone or butanone oxime is added.
5. The film coating of claim 1, wherein the hand aid is one or more of DSP-3890, BYK-3700.
6. The method for preparing a film coating according to claim 1, characterized in that the method comprises the following steps:
(1) Premixing: taking acrylic polyol, stirring, adding a hand feeling auxiliary agent, and mixing to obtain a premix;
(2) Mixing: adding a drier and an inhibitor into the premix obtained in the step (1), and stirring to obtain the main agent;
(3) The main agent and the curing agent are uniformly mixed to obtain the film coating, which can be used for construction.
7. The method for preparing a film coating according to claim 6, wherein in the step (1), the vortex mixing condition is 800 rpm for 30 minutes; in the step (2), stirring for 10 minutes at the stirring condition of 400 revolutions per minute; in the step (3), the stirring condition was 400 rpm for 10 minutes.
8. The use of the film coating according to claim 1, wherein the specific application method is as follows:
(1) Coating the protective film coating for the mobile phone curved screen on a release film by using a micrometer wire rod until the thickness of a wet film is 150-200 micrometers, so as to form a paint film;
(2) Placing the paint film which is subjected to blade coating in an oven for baking;
(3) And (4) after baking the paint film, coating a film by using a fluorine film for later use.
CN202211742335.1A 2022-12-29 2022-12-29 Membrane material for protecting curved screen of mobile phone Pending CN115926599A (en)

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Application Number Priority Date Filing Date Title
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111363488A (en) * 2020-04-23 2020-07-03 广东邦固薄膜涂料创新研究院有限公司 3D curved screen self-repairing TPU protective film and preparation method thereof
CN112694820A (en) * 2020-12-31 2021-04-23 三棵树(上海)新材料研究有限公司 Preparation method of ultrafast-drying aqueous double-component acrylic acid refinishing paint

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111363488A (en) * 2020-04-23 2020-07-03 广东邦固薄膜涂料创新研究院有限公司 3D curved screen self-repairing TPU protective film and preparation method thereof
CN112694820A (en) * 2020-12-31 2021-04-23 三棵树(上海)新材料研究有限公司 Preparation method of ultrafast-drying aqueous double-component acrylic acid refinishing paint

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