CN115918646B - Fluopicolide-containing suspending agent and preparation method thereof - Google Patents
Fluopicolide-containing suspending agent and preparation method thereof Download PDFInfo
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
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Abstract
The invention provides a suspending agent and a preparation method thereof, belonging to the field of pesticides. The suspending agent comprises: fluopyram, wetting dispersant, thickener, antifreezing agent, grinding aid, preservative and water; the wetting dispersant is phosphate dispersant 1015, EOPO block 10500, polycarboxylate dispersant RD-95 and anionic modified styrene acrylic polymer ATLOX 4917. The suspending agent provided by the invention has high particle size stability under the conditions of high-content fluopyram and material particle size D98 smaller than 1.000 mu m, such as heat Chu Xishui rate stability, normal storage of particle size, heat storage, normal storage of heat storage and the like, and has high viscosity and good stability and performance.
Description
Technical Field
The invention relates to the field of pesticides, in particular to a fluopyram-containing suspending agent and a preparation method thereof.
Technical Field
Fluopicolide is a new generation of excellent nematicide developed by Bayer corporation and has three major characteristics:
first, fluopyram is the first nematicide to inhibit complex ii, which represents a completely new mechanism of action nematicide. The action mechanism is that the activity of target succinic dehydrogenase is inhibited, thereby disturbing the respiration. When the nematodes are treated by fluopyram, the worms become needle-shaped and the motility decreases sharply.
Second, fluopyram has unique mobility and exhibits significantly different mobility in soil. It can be slowly and uniformly distributed in the soil at the upper layer. So that the root system can be effectively and long-term protected from nematode infection in the rhizosphere range.
Third, it has low toxicity. Fluopicolide is the first nematicidal product in the world that is low in toxicity to users and the environment. It is low in toxicity, environment-friendly, high in efficiency and low in dosage, and can be marketed to make nematode control enter a new era of green and milliliter. Can meet the requirements of environmental safety and can continuously solve the nematode problem.
The inventor finds that the high-content nano-scale fluopyram suspending agent (the particle size D98 is less than 1.000 mu m) can suffer from flocculation, agglomeration, particle growth, difficult grinding, high viscosity and the like in the production process. Is easy to flocculate, agglomerate and grow up during storage. Grinding the drug substance to a small particle size is more likely to cause Oryza sativa. Meanwhile, the finer the particles are, the larger the specific surface area is, the larger the surface energy is, the more aggregation among the particles is easy, and the more auxiliary agents need to be wrapped. Furthermore, at high concentrations, the particles have a much greater chance of Brownian motion collisions than at low concentrations, and under the influence of intermolecular attraction, the high concentration suspending agent forms more chain-like or chain-like network-like aggregates, which are more prone to agglomeration or coalescence. When the product is agglomerated during storage with the inter-particle aggregates merging to become larger, this will lead to precipitation and agglomeration of the product formulation and failure. In addition, the phenomenon of Orderian ripening, which is caused by the difference in solubility of the large and small particles in the high-content suspending agent or the difference in solubility between various crystalline states of some solid pesticidal active ingredients, also leads to instability of the product during storage.
It is known that the viscosity is high, which can cause problems of creaming and even curing during daily transportation due to too high a temperature, and the viscosity is high, which also affects the flowability of the product, which not only affects the ease of processing, but also directly affects metering, packaging and application. Because the fluopyram has high content of active ingredients and is prepared into a nanoscale preparation, the amount of auxiliary agents required to be added is increased, and the viscosity is difficult to control.
Therefore, there is a need for a suspension agent containing fluopyram with small particle size, good particle size stability, small viscosity and high fluopyram content.
Disclosure of Invention
In order to solve the technical problems, the invention provides the following technical scheme.
In a first aspect, the present invention provides a suspending agent.
A suspending agent, comprising: fluopyram, wetting dispersant, thickener, antifreezing agent, grinding aid, preservative and water; the wetting dispersant is phosphate dispersant 1015, EOPO block 10500, polycarboxylate dispersant RD-95 and anionic modified styrene acrylic polymer ATLOX 4917.
In some embodiments, the particle size D98 of the material in the suspension is less than 1.000 μm. In some embodiments, the particle size D98 of the material in the suspension is less than 0.900 μm. In some embodiments, the particle size D98 of the material in the suspension is 0.500 μm to 0.900 μm.
In some embodiments, the thickening agent is magnesium aluminum silicate and xanthan gum.
In some embodiments, the antifreeze is selected from one or more of ethylene glycol, propylene glycol, glycerol.
In some embodiments, the grinding aid is one or more of white carbon black, bentonite and titanium dioxide.
In some embodiments, the defoamer is a silicone defoamer 1572.
In some embodiments, the preservative is pinacolin.
In some embodiments, the fluopyram is present in an amount of 25.00wt% to 50.00wt%, the wetting dispersant is present in an amount of 9.00wt% to 15.00wt%, the thickener is present in an amount of 0.50wt% to 0.90wt%, the antifreeze is present in an amount of 3.00wt% to 6.00wt%, the grinding aid is present in an amount of 1.00wt% to 5.00wt%, the preservative is present in an amount of 0.10wt% to 0.30wt%, and the water is present in an amount of 22.80wt% to 61.40wt%, based on the total mass of the suspension.
In some embodiments, the fluopyram is present in an amount of 25.00wt% to 50.00wt%, the wetting dispersant is present in an amount of 9.00wt% to 15.00wt%, the thickener is present in an amount of 0.50wt% to 0.90wt%, the antifreeze is present in an amount of 3.00wt% to 6.00wt%, the grinding aid is present in an amount of 1.00wt% to 5.00wt%, the preservative is present in an amount of 0.10wt% to 0.30wt%, and the balance is water, based on the total mass of the suspension.
In some embodiments, the fluopyram is present in an amount of 25.00wt% to 50.00wt%, the wetting dispersant is present in an amount of 9.00wt% to 15.00wt%, the thickener is present in an amount of 0.50wt% to 0.90wt%, the antifreeze is present in an amount of 4.00wt%, the grinding aid is present in an amount of 2.00wt%, the preservative is present in an amount of 0.20wt% to 0.30wt%, and the water is present in an amount of 27.80wt% to 59.30wt%, based on the total mass of the suspension.
In some embodiments, the fluopyram is present in an amount of 25.00wt% to 50.00wt%, the wetting dispersant is present in an amount of 9.00wt% to 15.00wt%, the thickener is present in an amount of 0.50wt% to 0.90wt%, the antifreeze is present in an amount of 4.00wt%, the grinding aid is present in an amount of 2.00wt%, the preservative is present in an amount of 0.20wt% to 0.30wt%, and the balance is water, based on the total mass of the suspension.
In some embodiments, the wetting dispersant is phosphate dispersant 1015, EOPO block 10500, polycarboxylate dispersant RD-95, and anionically modified styrene acrylic polymer ATLOX 4917; the thickener is xanthan gum and magnesium aluminum silicate; calculated by the total mass of the suspending agent, the fluopyram content is 25.00-50.00 wt%, the phosphate dispersant 1015 content is 1.00-2.00 wt%, the EOPO block 10500 content is 2.00wt%, the polycarboxylate dispersant RD-95 content is 5.00-8.00 wt%, the anionic modified styrene acrylic polymer ATLOX 4917 content is 1.00-3.00 wt%, the xanthan gum content is 0.10-0.15 wt%, the magnesium aluminum silicate content is 0.40-0.80 wt%, the grinding aid content is 2.00wt%, the antifreeze content is 4.00wt%, the antifoaming agent content is 0.10wt%, the preservative content is 0.20-0.30 wt%, and the balance is water.
In some embodiments, the wetting dispersant is phosphate dispersant 1015, EOPO block 10500, polycarboxylate dispersant RD-95, and anionically modified styrene acrylic polymer ATLOX 4917; the thickener is xanthan gum and magnesium aluminum silicate; the grinding aid is titanium dioxide, and the antifreezing agent is glycol; the defoamer is an organosilicon defoamer 1572; the preservative is pinus koraiensis; calculated by the total mass of the suspending agent, the content of fluopyram is 25.00wt%, the content of phosphate dispersant 1015 is 1.00wt%, the content of EOPO block 10500 is 2.00wt%, the content of polycarboxylate dispersant RD-95 is 5.00wt%, the content of anionic modified styrene acrylic polymer ATLOX 4917 is 1.00wt%, the content of xanthan gum is 0.15wt%, the content of magnesium aluminum silicate is 0.60wt%, the content of grinding aid is 2.00wt%, the content of antifreezing agent is 4.00wt%, the content of antifoaming agent is 0.10wt%, the content of preservative is 0.30wt%, and the balance is water.
In some embodiments, the wetting dispersant is phosphate dispersant 1015, EOPO block 10500, polycarboxylate dispersant RD-95, and anionically modified styrene acrylic polymer ATLOX 4917; the thickener is xanthan gum and magnesium aluminum silicate; the grinding aid is white carbon black, and the antifreezing agent is propylene glycol; the defoamer is an organosilicon defoamer 1572; the preservative is pinus koraiensis; calculated by the total mass of the suspending agent, the content of fluopyram is 35.00wt%, the content of phosphate dispersant 1015 is 2.00wt%, the content of EOPO block 10500 is 2.00wt%, the content of polycarboxylate dispersant RD-95 is 5.00wt%, the content of anionic modified styrene acrylic polymer ATLOX 4917 is 1.00wt%, the content of xanthan gum is 0.10wt%, the content of magnesium aluminum silicate is 0.80wt%, the content of grinding aid is 2.00wt%, the content of antifreezing agent is 4.00wt%, the content of antifoaming agent is 0.10wt%, the content of preservative is 0.20wt%, and the balance is water.
In some preferred embodiments, the wetting dispersant is phosphate dispersant 1015, EOPO block 10500, polycarboxylate dispersant RD-95, and anionically modified styrene acrylic polymer ATLOX 4917; the thickener is xanthan gum and magnesium aluminum silicate; the grinding aid is titanium dioxide, and the antifreezing agent is propylene glycol; the defoamer is an organosilicon defoamer 1572; the preservative is pinus koraiensis; calculated by the total mass of the suspending agent, the fluopyram content is 41.70wt%, the phosphate dispersant 1015 content is 2.00wt%, the EOPO block 10500 content is 2.00wt%, the polycarboxylate dispersant RD-95 content is 8.00wt%, the anionic modified styrene acrylic polymer ATLOX 4917 content is 1.00wt%, the xanthan content is 0.10wt%, the magnesium aluminum silicate content is 0.60wt%, the grinding aid content is 2.00wt%, the antifreeze content is 4.00wt%, the defoamer content is 0.10wt%, the preservative content is 0.20wt%, and the balance is water. The suspending agent obtained by adopting the embodiment has better stability of heat storage water separation rate, lower viscosity, better particle size stability under the conditions of heat storage, normal heat storage, and the like, and has excellent beneficial effects.
In some embodiments, the wetting dispersant is phosphate dispersant 1015, EOPO block 10500, polycarboxylate dispersant RD-95, and anionically modified styrene acrylic polymer ATLOX 4917; the thickener is xanthan gum and magnesium aluminum silicate; the grinding aid is bentonite, and the antifreezing agent is glycol; the defoamer is an organosilicon defoamer 1572; the preservative is pinus koraiensis; calculated by the total mass of the suspending agent, the content of fluopyram is 50.00wt%, the content of phosphate dispersant 1015 is 2.00wt%, the content of EOPO block 10500 is 2.00wt%, the content of polycarboxylate dispersant RD-95 is 8.00wt%, the content of anionic modified styrene acrylic polymer ATLOX 4917 is 3.00wt%, the content of xanthan gum is 0.10wt%, the content of magnesium aluminum silicate is 0.40wt%, the content of grinding aid is 2.00wt%, the content of antifreezing agent is 4.00wt%, the content of antifoaming agent is 0.10wt%, the content of preservative is 0.20wt%, and the balance is water.
In a second aspect, the present invention provides a process for the preparation of the suspending agent of the first aspect.
A method of preparing the suspension of the first aspect, comprising:
step S1: mixing a wetting dispersant, an antifreezing agent, a grinding aid, magnesium aluminum silicate and a defoaming agent with water to obtain a first mixed solution;
step S2: mixing xanthan gum and a preservative with water to obtain a second mixed solution;
step S3: and mixing fluopyram with the first mixed solution, grinding, filtering, taking filtrate, and mixing with the second mixed solution to obtain the suspending agent.
In some embodiments, the milling comprises milling the particle size D98 of the material in the fluopyram and first mixed liquor to a range of 0.500 μm to 0.700 μm.
In some embodiments, the content of the xanthan gum in the second mixed solution is 1wt% to 3wt%. In some embodiments, the content of the xanthan gum in the second mixed liquor is 2wt%.
In some embodiments, the filter membrane employed for the filtration may have a pore size of 60 μm to 75 μm.
Advantageous effects
Compared with the prior art, the embodiment provided by the invention has at least one of the following beneficial effects:
(1) Compared with other wetting dispersing agents or other wetting dispersing agent combinations, the wetting dispersing agent and the prescription of the content thereof adopted by the invention are beneficial to improving the stability of the heat storage water separation rate, the particle size stability of the conditions of normal storage, heat storage, normal heat storage and the like of the nano-level (particle size less than 1.000 mu m) suspending agent containing the high-content fluopyram, and are beneficial to reducing the viscosity of the suspending agent containing the high-content fluopyram.
(2) The preferred prescription of the invention is: a suspending agent, comprising: fluopyram, wetting dispersant, thickener, antifreezing agent, grinding aid, preservative and water; the wetting dispersant is phosphate dispersant 1015, EOPO block 10500, polycarboxylate dispersant RD-95 and anion modified styrene acrylic polymer ATLOX 4917, and the wetting dispersant is phosphate dispersant 1015, EOPO block 10500, polycarboxylate dispersant RD-95 and anion modified styrene acrylic polymer ATLOX 4917; the thickener is xanthan gum and magnesium aluminum silicate; the grinding aid is titanium dioxide, and the antifreezing agent is propylene glycol; the defoamer is an organosilicon defoamer 1572; the preservative is pinus koraiensis; calculated by the total mass of the suspending agent, the fluopyram content is 41.70wt%, the phosphate dispersant 1015 content is 2.00wt%, the EOPO block 10500 content is 2.00wt%, the polycarboxylate dispersant RD-95 content is 8.00wt%, the anionic modified styrene acrylic polymer ATLOX 4917 content is 1.00wt%, the xanthan content is 0.10wt%, the magnesium aluminum silicate content is 0.60wt%, the grinding aid content is 2.00wt%, the antifreeze content is 4.00wt%, the defoamer content is 0.10wt%, the preservative content is 0.20wt%, and the balance is water. Compared with other prescriptions, the suspending agent prepared by adopting the prescription has better stability of heat storage water separation rate, lower viscosity, better particle size stability under the conditions of heat storage, normal heat storage, and the like, and has excellent beneficial effects.
Definition of terms
In the context of the present invention, all numbers disclosed herein are approximations, whether or not the word "about" or "about" is used. Based on the numbers disclosed, there is a possibility that the values of each number may differ by less than + -10% or a reasonable difference as recognized by those skilled in the art, such as + -1%, + -2%, + -3%, + -4%, or + -5%.
The terms "above," "below," "within," and the like are to be construed as including the present number, e.g., two or more means ≡two.
The term "and/or" is understood to mean any one of the selectable items or a combination of any two or more of the selectable items.
The term "wt%" means mass percent.
The term "plurality" means at least two, for example 2, 3, 4, 5, etc.
The term "nanoscale" means a particle size of < 1.000 μm.
In the description of the present specification, a description referring to terms "one embodiment," "some embodiments," "examples," "specific examples," or "some examples," etc., means that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the present invention. In this specification, schematic representations of the above terms are not necessarily directed to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Furthermore, the different embodiments or examples described in this specification and the features of the different embodiments or examples may be combined and combined by those skilled in the art without contradiction.
Detailed Description
In order to better understand the technical solution of the present invention, some non-limiting examples are further disclosed below to further describe the present invention in detail.
The reagents used in the present invention are all commercially available or can be prepared by the methods described herein.
The term "thermal storage" means storage at 54.+ -. 2 ℃.
The term "cold storage" means storage at 0 ℃.
The term "normal storage" means storage under normal temperature conditions; the normal temperature is the ambient temperature, and is generally 30+ -2deg.C.
The full names and manufacturers corresponding to the short names of the auxiliary materials adopted in the embodiment of the invention can be:
examples 1 to 4: preparation of suspending agent
Prescription: see table 1.
Table 1: prescription of suspending agent
The preparation method comprises the following steps:
step S1: mixing a wetting dispersant, an antifreezing agent, a grinding aid, magnesium aluminum silicate and a defoaming agent with water to obtain a first mixed solution;
step S2: mixing xanthan gum and a preservative with water to obtain a second mixed solution with the xanthan gum content of 2 wt%;
step S3: and (2) mixing fluopyram with the first mixed solution, grinding the fluopyram and the particle size D98 of the material in the first mixed solution to 0.500-0.700 mu m, filtering with a filter membrane with the pore diameter of 75 mu m, taking filtrate, and mixing with the second mixed solution obtained in the step (S2) to obtain the suspending agent.
Stability investigation: the suspending agents obtained in examples 1 to 4 were stored for 14 days under heat, for 90 days under cold, for 7 days under cold, and for 30 days under cold, respectively, and the results of the measurements shown in Table 2 were shown.
Table 2: stability investigation results
Note that: the stability of the product after 7 days of cold storage is qualified, and the product is qualified in appearance, suspension rate, wet sieve test (passing 75 mu m test sieve), particle size detection, bottom sticking condition, fluidity and water separation condition.
Comparative example 1-comparative example 16: investigation of wetting dispersant
Prescription: examination of wetting and dispersing agents was carried out based on the formulation of example 3, the specific formulation being shown in tables 3 to 6.
Table 3: wetting dispersant investigation prescription
Table 4: wetting dispersant investigation prescription
Table 5: wetting dispersant investigation prescription
Table 6: wetting dispersant investigation prescription
The preparation method comprises the following steps: the procedure is as in example 3.
Stability investigation: the suspending agents obtained in comparative examples 1 to 16 were stored for 14 days under heat, for 90 days under normal conditions, and for 30 days under normal conditions, and the indexes shown in tables 7 to 10 were measured, respectively, and the results are shown in tables 7 to 10.
Table 7: comparative examples 1 to 4 results of examination of the stability of the suspensions obtained
Table 8: comparative example 5-stability investigation results of the suspension obtained in comparative example 8
Table 9: comparative example 9-stability examination of the suspension obtained in comparative example 12
Table 10: comparative example 13-stability test results of the suspension obtained in comparative example 16
Conclusion:
(1) Compared with the combination of other wetting dispersing agents, the wetting dispersing agents and the prescriptions of the content thereof adopted in the examples 1-4 are beneficial to improving the stability of the heat storage water separation rate, the stability of the particle size of the conditions such as the normal storage, the heat storage, the normal heat storage and the normal heat storage of the nano-scale (particle size less than 1.000 mu m) suspending agent containing high-content fluopyram and reducing the viscosity of the suspending agent containing high-content fluopyram.
(2) The preferable prescription of the invention is the prescription of the example 3, and the suspending agent obtained by the prescription of the example 3 has better stability of heat storage water separation rate, lower viscosity and better particle size stability under the conditions of heat storage, normal storage and the like.
While the methods of this invention have been described in terms of preferred embodiments, it will be apparent to those of skill in the art that variations and combinations of the methods and applications described herein can be made and applied within the spirit and scope of the invention. Those skilled in the art can, with the benefit of this disclosure, suitably modify the process parameters to achieve this. It is expressly noted that all such similar substitutions and modifications will be apparent to those skilled in the art, and are deemed to be included within the present invention.
Claims (12)
1. A suspending agent, comprising: fluopyram, wetting dispersant, thickener, antifreezing agent, grinding aid, preservative, defoamer and water; the wetting dispersant is phosphate dispersant 1015, EOPO block 10500, polycarboxylate dispersant RD-95 and anionic modified styrene acrylic polymer ATLOX 4917; the particle size D98 of the materials in the suspending agent is less than 1.000 mu m; the thickener is xanthan gum and magnesium aluminum silicate; calculated by the total mass of the suspending agent, the fluopyram content is 25.00-50.00 wt%, the phosphate dispersant 1015 content is 1.00-2.00 wt%, the EOPO block 10500 content is 2.00wt%, the polycarboxylate dispersant RD-95 content is 5.00-8.00 wt%, the anionic modified styrene acrylic polymer ATLOX 4917 content is 1.00-3.00 wt%, the xanthan gum content is 0.10-0.15 wt%, the magnesium aluminum silicate content is 0.40-0.80 wt%, the grinding aid content is 2.00wt%, the antifreeze content is 4.00wt%, the antifoaming agent content is 0.10wt%, the preservative content is 0.20-0.30 wt%, and the balance is water.
2. The suspension of claim 1, wherein the particle size D98 of the material in the suspension is less than 0.900 μm.
3. The suspension of claim 1, wherein the particle size D98 of the material in the suspension is 0.500-0.900 μm.
4. The suspending agent according to claim 1, wherein the antifreeze is selected from one or more of ethylene glycol, propylene glycol, glycerol.
5. The suspending agent according to claim 1, wherein the grinding aid is one or more of white carbon black, bentonite and titanium dioxide.
6. The suspension of claim 1, the defoamer being a silicone defoamer 1572; and/or
The preservative is pinus koraiensis.
7. The suspending agent according to any one of claims 1 to 6, wherein the wetting dispersant is phosphate dispersant 1015, EOPO block 10500, polycarboxylate dispersant RD-95, and anionically modified styrene acrylic polymer ATLOX 4917; the thickener is xanthan gum and magnesium aluminum silicate; the grinding aid is titanium dioxide, and the antifreezing agent is glycol; the defoamer is an organosilicon defoamer 1572; the preservative is pinus koraiensis; calculated by the total mass of the suspending agent, the content of fluopyram is 25.00wt%, the content of phosphate dispersant 1015 is 1.00wt%, the content of EOPO block 10500 is 2.00wt%, the content of polycarboxylate dispersant RD-95 is 5.00wt%, the content of anionic modified styrene acrylic polymer ATLOX 4917 is 1.00wt%, the content of xanthan gum is 0.15wt%, the content of magnesium aluminum silicate is 0.60wt%, the content of grinding aid is 2.00wt%, the content of antifreezing agent is 4.00wt%, the content of antifoaming agent is 0.10wt%, the content of preservative is 0.30wt%, and the balance is water.
8. The suspending agent according to any one of claims 1 to 6, wherein the wetting dispersant is phosphate dispersant 1015, EOPO block 10500, polycarboxylate dispersant RD-95, and anionically modified styrene acrylic polymer ATLOX 4917; the thickener is xanthan gum and magnesium aluminum silicate; the grinding aid is white carbon black, and the antifreezing agent is propylene glycol; the defoamer is an organosilicon defoamer 1572; the preservative is pinus koraiensis; calculated by the total mass of the suspending agent, the content of fluopyram is 35.00wt%, the content of phosphate dispersant 1015 is 2.00wt%, the content of EOPO block 10500 is 2.00wt%, the content of polycarboxylate dispersant RD-95 is 5.00wt%, the content of anionic modified styrene acrylic polymer ATLOX 4917 is 1.00wt%, the content of xanthan gum is 0.10wt%, the content of magnesium aluminum silicate is 0.80wt%, the content of grinding aid is 2.00wt%, the content of antifreezing agent is 4.00wt%, the content of antifoaming agent is 0.10wt%, the content of preservative is 0.20wt%, and the balance is water.
9. The suspending agent according to any one of claims 1 to 6, wherein the wetting dispersant is phosphate dispersant 1015, EOPO block 10500, polycarboxylate dispersant RD-95, and anionically modified styrene acrylic polymer ATLOX 4917; the thickener is xanthan gum and magnesium aluminum silicate; the grinding aid is titanium dioxide, and the antifreezing agent is propylene glycol; the defoamer is an organosilicon defoamer 1572; the preservative is pinus koraiensis; calculated by the total mass of the suspending agent, the fluopyram content is 41.70wt%, the phosphate dispersant 1015 content is 2.00wt%, the EOPO block 10500 content is 2.00wt%, the polycarboxylate dispersant RD-95 content is 8.00wt%, the anionic modified styrene acrylic polymer ATLOX 4917 content is 1.00wt%, the xanthan content is 0.10wt%, the magnesium aluminum silicate content is 0.60wt%, the grinding aid content is 2.00wt%, the antifreeze content is 4.00wt%, the defoamer content is 0.10wt%, the preservative content is 0.20wt%, and the balance is water.
10. The suspending agent according to any one of claims 1 to 6, wherein the wetting dispersant is phosphate dispersant 1015, EOPO block 10500, polycarboxylate dispersant RD-95, and anionically modified styrene acrylic polymer ATLOX 4917; the thickener is xanthan gum and magnesium aluminum silicate; the grinding aid is bentonite, and the antifreezing agent is glycol; the defoamer is an organosilicon defoamer 1572; the preservative is pinus koraiensis; calculated by the total mass of the suspending agent, the content of fluopyram is 50.00wt%, the content of phosphate dispersant 1015 is 2.00wt%, the content of EOPO block 10500 is 2.00wt%, the content of polycarboxylate dispersant RD-95 is 8.00wt%, the content of anionic modified styrene acrylic polymer ATLOX 4917 is 3.00wt%, the content of xanthan gum is 0.10wt%, the content of magnesium aluminum silicate is 0.40wt%, the content of grinding aid is 2.00wt%, the content of antifreezing agent is 4.00wt%, the content of antifoaming agent is 0.10wt%, the content of preservative is 0.20wt%, and the balance is water.
11. A method of preparing the suspension of claim 10, the method comprising:
step S1: mixing a wetting dispersant, an antifreezing agent, a grinding aid, magnesium aluminum silicate and a defoaming agent with water to obtain a first mixed solution;
step S2: mixing xanthan gum and a preservative with water to obtain a second mixed solution;
step S3: and mixing fluopyram with the first mixed solution, grinding, filtering, taking filtrate, and mixing with the second mixed solution to obtain the suspending agent.
12. The preparation method according to claim 11, wherein the grinding comprises grinding the particle size D98 of the material in the mixture of fluopyram and the first liquid to 0.500-0.700 μm; and/or
The content of the xanthan gum in the second mixed solution is 1-3 wt%.
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| CN202211489203.2A CN115918646B (en) | 2022-11-25 | 2022-11-25 | Fluopicolide-containing suspending agent and preparation method thereof |
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| CN115918646B true CN115918646B (en) | 2023-08-11 |
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| CN202211489203.2A Active CN115918646B (en) | 2022-11-25 | 2022-11-25 | Fluopicolide-containing suspending agent and preparation method thereof |
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Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105409964A (en) * | 2015-12-23 | 2016-03-23 | 陕西上格之路生物科学有限公司 | Germicidal composition containing fluopyram and proquinazid |
| CN106719673A (en) * | 2016-12-02 | 2017-05-31 | 佛山市普尔玛农化有限公司 | A kind of composition pesticide of containing fluopyram and chitosan |
| CN107439540A (en) * | 2017-08-07 | 2017-12-08 | 惠州市银农科技股份有限公司 | A kind of thiacloprid aqueous suspension agent and preparation method thereof |
| CN108064848A (en) * | 2017-12-26 | 2018-05-25 | 陕西上格之路生物科学有限公司 | A kind of bactericidal composition containing fluopyram and amine benzene pyrrole bacterium ketone |
| CN109952028A (en) * | 2016-09-07 | 2019-06-28 | 拜耳作物科学股份公司 | For preventing and treating the preparation of the containing fluopyram of nematode |
| KR20200114756A (en) * | 2019-03-29 | 2020-10-07 | 동우 화인켐 주식회사 | A cleaning composition |
| CN112042663A (en) * | 2020-10-14 | 2020-12-08 | 惠州市银农科技股份有限公司 | Pyraclostrobin suspending agent and preparation method thereof |
| CN114503990A (en) * | 2022-01-27 | 2022-05-17 | 陕西先农生物科技有限公司 | Suspending agent containing abamectin and fluopyram |
| CN115226719A (en) * | 2022-09-01 | 2022-10-25 | 青岛凯源祥化工有限公司 | Suspending agent containing prothioconazole and fluopyram and preparation method thereof |
-
2022
- 2022-11-25 CN CN202211489203.2A patent/CN115918646B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105409964A (en) * | 2015-12-23 | 2016-03-23 | 陕西上格之路生物科学有限公司 | Germicidal composition containing fluopyram and proquinazid |
| CN109952028A (en) * | 2016-09-07 | 2019-06-28 | 拜耳作物科学股份公司 | For preventing and treating the preparation of the containing fluopyram of nematode |
| CN106719673A (en) * | 2016-12-02 | 2017-05-31 | 佛山市普尔玛农化有限公司 | A kind of composition pesticide of containing fluopyram and chitosan |
| CN107439540A (en) * | 2017-08-07 | 2017-12-08 | 惠州市银农科技股份有限公司 | A kind of thiacloprid aqueous suspension agent and preparation method thereof |
| CN108064848A (en) * | 2017-12-26 | 2018-05-25 | 陕西上格之路生物科学有限公司 | A kind of bactericidal composition containing fluopyram and amine benzene pyrrole bacterium ketone |
| KR20200114756A (en) * | 2019-03-29 | 2020-10-07 | 동우 화인켐 주식회사 | A cleaning composition |
| CN112042663A (en) * | 2020-10-14 | 2020-12-08 | 惠州市银农科技股份有限公司 | Pyraclostrobin suspending agent and preparation method thereof |
| CN114503990A (en) * | 2022-01-27 | 2022-05-17 | 陕西先农生物科技有限公司 | Suspending agent containing abamectin and fluopyram |
| CN115226719A (en) * | 2022-09-01 | 2022-10-25 | 青岛凯源祥化工有限公司 | Suspending agent containing prothioconazole and fluopyram and preparation method thereof |
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| CN115918646A (en) | 2023-04-07 |
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