CN115873434A - Water-based interior wall coating prepared from traditional Chinese medicinal materials and having anti-mosquito effect and preparation method thereof - Google Patents
Water-based interior wall coating prepared from traditional Chinese medicinal materials and having anti-mosquito effect and preparation method thereof Download PDFInfo
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- CN115873434A CN115873434A CN202211719156.6A CN202211719156A CN115873434A CN 115873434 A CN115873434 A CN 115873434A CN 202211719156 A CN202211719156 A CN 202211719156A CN 115873434 A CN115873434 A CN 115873434A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 135
- 238000000576 coating method Methods 0.000 title claims abstract description 99
- 239000011248 coating agent Substances 0.000 title claims abstract description 93
- 239000000463 material Substances 0.000 title claims abstract description 76
- 230000000694 effects Effects 0.000 title claims abstract description 62
- 230000001442 anti-mosquito Effects 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000007788 liquid Substances 0.000 claims abstract description 118
- 241000723346 Cinnamomum camphora Species 0.000 claims abstract description 109
- 239000003814 drug Substances 0.000 claims abstract description 55
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 40
- 239000001913 cellulose Substances 0.000 claims abstract description 38
- 229920002678 cellulose Polymers 0.000 claims abstract description 38
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims abstract description 22
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims abstract description 21
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 21
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 19
- 229940072033 potash Drugs 0.000 claims abstract description 19
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims abstract description 19
- 235000015320 potassium carbonate Nutrition 0.000 claims abstract description 19
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 19
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000004094 surface-active agent Substances 0.000 claims abstract description 19
- 239000011256 inorganic filler Substances 0.000 claims abstract description 18
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 18
- 239000007787 solid Substances 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims description 68
- 238000003756 stirring Methods 0.000 claims description 54
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 47
- 239000002518 antifoaming agent Substances 0.000 claims description 41
- 239000000203 mixture Substances 0.000 claims description 36
- 239000000843 powder Substances 0.000 claims description 30
- 239000002994 raw material Substances 0.000 claims description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 24
- 239000004408 titanium dioxide Substances 0.000 claims description 21
- 239000011521 glass Substances 0.000 claims description 20
- 239000005995 Aluminium silicate Substances 0.000 claims description 19
- 235000012211 aluminium silicate Nutrition 0.000 claims description 19
- 239000002270 dispersing agent Substances 0.000 claims description 19
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 19
- 239000010445 mica Substances 0.000 claims description 19
- 229910052618 mica group Inorganic materials 0.000 claims description 19
- 239000000080 wetting agent Substances 0.000 claims description 18
- 239000004005 microsphere Substances 0.000 claims description 17
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 15
- 230000003449 preventive effect Effects 0.000 claims description 14
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 10
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- 238000000926 separation method Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 3
- RLQWHDODQVOVKU-UHFFFAOYSA-N tetrapotassium;silicate Chemical compound [K+].[K+].[K+].[K+].[O-][Si]([O-])([O-])[O-] RLQWHDODQVOVKU-UHFFFAOYSA-N 0.000 abstract description 3
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- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 239000004480 active ingredient Substances 0.000 description 5
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- 239000008367 deionised water Substances 0.000 description 4
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- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
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- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 description 3
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
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- 239000003063 flame retardant Substances 0.000 description 2
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
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- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- 229940099451 3-iodo-2-propynylbutylcarbamate Drugs 0.000 description 1
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- 239000004215 Carbon black (E152) Substances 0.000 description 1
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 description 1
- 244000248349 Citrus limon Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 239000005770 Eugenol Substances 0.000 description 1
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- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- PXRCIOIWVGAZEP-UHFFFAOYSA-N Primaeres Camphenhydrat Natural products C1CC2C(O)(C)C(C)(C)C1C2 PXRCIOIWVGAZEP-UHFFFAOYSA-N 0.000 description 1
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229930006739 camphene Natural products 0.000 description 1
- ZYPYEBYNXWUCEA-UHFFFAOYSA-N camphenilone Natural products C1CC2C(=O)C(C)(C)C1C2 ZYPYEBYNXWUCEA-UHFFFAOYSA-N 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
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- 229910001385 heavy metal Inorganic materials 0.000 description 1
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- 238000003905 indoor air pollution Methods 0.000 description 1
- 230000004199 lung function Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The invention belongs to the technical field of coatings, and particularly relates to a water-based interior wall coating with an anti-mosquito effect and prepared from traditional Chinese medicinal materials and a preparation method thereof. The invention provides a water-based interior wall coating which comprises the following components: 20 to 25 percent of potash water glass, 5 to 10 percent of styrene-acrylic polymer, 0.2 to 0.5 percent of cellulose, 0.9 to 1.5 percent of aqueous auxiliary agent, 1 to 3 percent of film-forming auxiliary agent, 36 to 55 percent of inorganic filler, 0.2 to 0.5 percent of mildew inhibitor, 22 to 23.6 percent of camphor tree liquid medicine, 0.6 to 1 percent of surfactant and 0.5 to 1 percent of ammonia water; the solid content of the camphor tree liquid medicine is 5-15%. The indoor coating formed by the water-based interior wall coating with the anti-mosquito effect prepared by the traditional Chinese medicinal materials is filtered to obtain fresh and clean air, and is anti-mosquito, so that the indoor living environment is more comfortable. Meanwhile, the invention adopts the potassium water glass and the styrene-acrylic polymer to compound. So that the storage stability of the coating is obviously improved.
Description
Technical Field
The invention belongs to the technical field of coatings, and particularly relates to a water-based interior wall coating with an anti-mosquito effect and prepared from traditional Chinese medicinal materials and a preparation method thereof.
Background
In recent years, with the improvement of living standard, the standards of people for indoor environment requirements are more and more strict. Indoor air pollution can cause stimulation to eyes, nose, mouth and pharynx, which causes respiratory system diseases of human bodies, lung function reduction, heart pressure increase and influences body health. Therefore, the paint with the indoor air purification function becomes an important development direction.
Compared with the traditional indoor organic coating, the indoor inorganic coating product mostly uses water as a dispersion medium, and the production and use of the base material have little pollution to the environment, so that the indoor inorganic coating is highly valued by people. In the existing indoor inorganic paint in the market at present, nano titanium dioxide powder is mostly added as an air purification bactericide, the principle is that the high photocatalytic activity of nano titanium dioxide is utilized, when titanium dioxide is irradiated by photons with energy larger than the forbidden bandwidth, electrons in a valence band jump from the valence band to a conduction band, an electron-hole pair is generated, the electrons have reducibility, the holes have oxidability, the holes react with hydroxyl (-OH) on the surface of a material to generate hydroxyl (-OH) free radicals with extremely strong oxidability, and the active hydroxyl free radicals can oxidize and decompose decoration chemical pollutants such as indoor formaldehyde, benzene, toluene and the like to generate inorganic substances such as carbon dioxide, water and the like, so that the aim of purifying indoor air is fulfilled. However, the existing indoor paint has poor capability of purifying volatile organic compounds and free formaldehyde in the air, and has no mosquito-proof effect.
Disclosure of Invention
The invention aims to provide a water-based interior wall coating with an anti-mosquito effect and prepared by using traditional Chinese medicinal materials and a preparation method thereof.
In order to achieve the above purpose, the invention provides the following technical scheme:
the invention provides a water-based interior wall coating with an anti-mosquito effect, which is prepared from traditional Chinese medicinal materials and comprises the following components in percentage by mass:
20 to 25 percent of potash water glass, 5 to 10 percent of styrene-acrylic polymer, 0.2 to 0.5 percent of cellulose, 0.9 to 1.5 percent of water-based auxiliary agent, 1 to 3 percent of film-forming auxiliary agent, 36 to 55 percent of inorganic filler, 0.2 to 0.5 percent of mildew preventive, 22 to 23.6 percent of camphor tree liquid medicine, 0.6 to 1 percent of surfactant and 0.5 to 1 percent of ammonia water;
the camphor tree liquid medicine is prepared by mixing and decocting camphor tree raw materials and water, and the solid content of the camphor tree liquid medicine is 5-15%;
the water-based auxiliary agent comprises a water-based dispersing agent, a water-based wetting agent and a water-based defoaming agent;
the inorganic filler comprises titanium dioxide, calcined kaolin, mica powder, silica powder and hollow glass microspheres;
the mass percentage of the ammonia water is less than or equal to 25 percent.
Preferably, the preparation method of the camphor tree liquid medicine comprises the following steps:
mixing the camphor tree raw material with water to obtain a mixture; the camphor tree raw material comprises one or more of a trunk, branches and roots of the camphor tree;
heating the mixture to boiling for decocting to obtain a decocted feed liquid; the temperature of the decocted liquid is 100 ℃, and the temperature of the decocted liquid is 1-3 h;
and carrying out solid-liquid separation on the decocted feed liquid to obtain the camphor tree liquid medicine.
Preferably, the aqueous auxiliary agent comprises 0.5-0.8% of aqueous dispersant, 0.1-0.2% of aqueous wetting agent and 0.3-0.5% of aqueous defoaming agent.
Preferably, the inorganic filler comprises 15-20% of titanium dioxide, 5-10% of calcined kaolin, 3-5% of mica powder, 10-15% of silicon micropowder and 3-5% of hollow glass microspheres.
Preferably, the aqueous antifoaming agent comprises a first aqueous antifoaming agent, which is a basf antifoaming agent, foamstar a10, and a second aqueous antifoaming agent, which is a rosidiya DF-681F antifoaming agent.
Preferably, the film forming aid comprises a first film forming aid and a second film forming aid, the first film forming aid is propylene glycol, and the second film forming aid is a film forming aid AH-12.
The invention provides a preparation method of a water-based interior wall coating with an anti-mosquito effect, which is prepared from traditional Chinese medicinal materials and comprises the following steps:
mixing cellulose, camphor tree liquid medicine, a water-based auxiliary agent, a film-forming auxiliary agent, an inorganic filler, a styrene-acrylic polymer, potash water glass, a mildew preventive, a surfactant and ammonia water to obtain the water-based interior wall coating with the mosquito-proof effect, which is prepared from traditional Chinese medicinal materials.
Preferably, the mixing comprises the steps of:
dissolving the cellulose in a first part of camphor tree medicinal water to obtain a cellulose solution;
mixing the cellulose solution, the water-based dispersing agent, part of water-based defoaming agent, the water-based wetting agent, part of film-forming auxiliary agent and a second part of camphor tree liquid medicine under first stirring to obtain a first mixture; the rotating speed of the first stirring and mixing is 300-400 r/min, and the time of the first stirring and mixing is 5-10 min;
secondly stirring and mixing the first mixture, titanium dioxide, mica powder, calcined kaolin, silica micropowder and hollow glass microspheres to obtain a second mixture; the rotating speed of the second stirring and mixing is 800-1000r/min, and the time of the first stirring and mixing is 15-20 min;
thirdly mixing the second mixture, the styrene-acrylic polymer and the residual aqueous defoaming agent to obtain a third mixture; the rotating speed of the third stirring and mixing is 400-600 r/min, and the time of the third stirring and mixing is 5-10 min;
fourthly, mixing the third mixed material, the potash water glass, the rest film-forming auxiliary agent, the mildew preventive and the surfactant to obtain a fourth mixed material; the rotating speed of the fourth stirring and mixing is 400-600 r/min, and the time of the fourth stirring and mixing is 10-15 min;
and mixing the fourth mixture, ammonia water and the rest camphor tree liquid medicine for the fifth time to obtain the water-based interior wall coating with the mosquito-proof effect, which is prepared from the traditional Chinese medicinal materials.
The invention provides application of the water-based interior wall coating with the anti-mosquito effect prepared from the traditional Chinese medicinal materials in the technical scheme or the water-based interior wall coating with the anti-mosquito effect prepared by the preparation method in the technical scheme as a coating for an indoor wall of a house.
Preferably, the application comprises the following steps: coating the water-based interior wall coating with the anti-mosquito effect, which is prepared by using the traditional Chinese medicinal materials, on the surface of the interior wall coated with the primer layer, and obtaining an interior wall coating on the surface of the primer layer; the thickness of the inner wall coating is 60-80 μm.
The invention provides a water-based interior wall coating with an anti-mosquito effect, which is prepared from traditional Chinese medicinal materials and comprises the following components in percentage by mass: 20 to 25 percent of potash water glass, 5 to 10 percent of styrene-acrylic polymer, 0.2 to 0.5 percent of cellulose, 0.9 to 1.5 percent of aqueous auxiliary agent, 1 to 3 percent of film-forming auxiliary agent, 36 to 55 percent of inorganic filler, 0.2 to 0.5 percent of mildew inhibitor, 22 to 23.6 percent of camphor tree liquid medicine, 0.6 to 1 percent of surfactant and 0.5 to 1 percent of ammonia water; the camphor tree liquid medicine is prepared by mixing and decocting camphor tree raw materials and water, and the solid content of the camphor tree liquid medicine is 5-15%; the water-based auxiliary agent comprises a water-based dispersing agent, a water-based wetting agent and a water-based defoaming agent; the inorganic filler comprises titanium dioxide, calcined kaolin, mica powder, silica powder and hollow glass microspheres; the mass percentage of the ammonia water is less than or equal to 25 percent. The water-based interior wall coating with the anti-mosquito effect, which is prepared by using the camphor tree medicinal liquid as the diluent of the coating and is prepared by using the traditional Chinese medicinal materials, is coated on the surface of an interior wall, after water is volatilized, active ingredients such as camphor, camphene, diepoxide, lemon hydrocarbon, eugenol and the like contained in the camphor tree medicinal liquid are uniformly distributed in the coating, so that an indoor coating has the capacity of purifying toxic air, the active ingredients in the camphor tree medicinal liquid and titanium dioxide in the coating can jointly purify Volatile Organic Compounds (VOC) and free formaldehyde in the air, and the active ingredients in the camphor tree medicinal liquid can enable the coating to have the anti-mosquito effect. The indoor coating formed by the water-based interior wall coating with the anti-mosquito effect prepared by the traditional Chinese medicinal materials is filtered to obtain fresh and clean air, and is anti-mosquito, so that the indoor living environment is more comfortable. Meanwhile, the hollow glass beads and the silica powder are adopted, so that gaps among coatings prepared by the coating are enhanced, and richer active ingredients in camphor tree medicinal liquid are stored in the coating, so that the long-acting insect prevention effect is achieved; the invention obtains the water-based interior wall coating by compounding the potassium water glass and the styrene-acrylic polymer, thereby optimizing the defects of poor flow leveling of inorganic potassium water glass, poor decorative effect and the like, and the styrene-acrylic polymer enhances the wetting effect of a water-based auxiliary agent in the coating on an inorganic filler, so that the storage stability of the coating is obviously improved.
Drawings
Fig. 1 shows a cinnamomum camphora raw material used in example 1 of the present invention.
Detailed Description
The invention provides a water-based interior wall coating with an anti-mosquito effect, which is prepared from traditional Chinese medicinal materials and comprises the following components in percentage by mass:
20 to 25 percent of potash water glass, 5 to 10 percent of styrene-acrylic polymer, 0.2 to 0.5 percent of cellulose, 0.9 to 1.5 percent of water-based auxiliary agent, 1 to 3 percent of film-forming auxiliary agent, 36 to 55 percent of inorganic filler, 0.2 to 0.5 percent of mildew preventive, 22 to 23.6 percent of camphor tree liquid medicine, 0.6 to 1 percent of surfactant and 0.5 to 1 percent of ammonia water;
the camphor tree liquid medicine is prepared by mixing and decocting camphor tree raw materials and water, and the solid content of the camphor tree liquid medicine is 5-15%;
the water-based auxiliary agent comprises a water-based dispersing agent, a water-based wetting agent and a water-based defoaming agent;
the inorganic filler comprises titanium dioxide, calcined kaolin, mica powder, silica powder and hollow glass microspheres;
the mass percentage of the ammonia water is less than or equal to 25 percent.
In the present invention, all the preparation starting materials/components are commercially available products well known to those skilled in the art unless otherwise specified.
The water-based interior wall coating with the anti-mosquito effect, which is prepared by utilizing the traditional Chinese medicinal materials, comprises 20-25% of potash water glass by mass percentage, and the preferred content is 21.5-24%.
In the invention, the potash water glass is preferably AH-K1 in Austhan, oriental China, beijing.
The water-based interior wall coating with the anti-mosquito effect, which is prepared by using the traditional Chinese medicinal materials, comprises 5-10% of styrene-acrylic polymer by mass percentage, and preferably 5.5-8%.
In the present invention, the styrene-acrylic polymer is constant water newness 8807.
The water-based interior wall coating with the anti-mosquito effect, which is prepared from the traditional Chinese medicinal materials, comprises 0.2-0.5% of cellulose, preferably 0.25-0.45% by mass.
In the present invention, the cellulose is preferably hydroxyethyl cellulose.
In the present invention, the cellulose is particularly preferably german cozy hydroxyethyl cellulose-HS 30000YP2.
The water-based interior wall coating with the mosquito-proof effect, which is prepared from the traditional Chinese medicinal materials, comprises 0.9-1.5% of water-based auxiliary agent by mass percentage, and preferably 0.85-1.33%.
In the present invention, the aqueous auxiliary agent includes an aqueous dispersant, an aqueous wetting agent, and an aqueous defoaming agent.
In the invention, the aqueous auxiliary agent preferably comprises 0.5 to 0.8 percent of aqueous dispersant, 0.1 to 0.2 percent of aqueous wetting agent and 0.3 to 0.5 percent of aqueous defoaming agent, more preferably comprises 0.55 to 0.7 percent of aqueous dispersant, 0.05 to 0.18 percent of aqueous wetting agent and 0.25 to 0.45 percent of aqueous defoaming agent
In the present invention, the aqueous dispersant is preferably a nopinaceous 5040 dispersant.
In the present invention, the aqueous wetting agent is dow 070.
In the present invention, the aqueous antifoaming agent preferably includes a first aqueous antifoaming agent, preferably a basf antifoaming agent, foamstar a10, and a second aqueous antifoaming agent, preferably a rosidiya DF-681F antifoaming agent.
In the present invention, the first aqueous defoaming agent is mainly foam suppressing effect, and the second defoaming agent is mainly defoaming effect.
In the present invention, the mass ratio of the first aqueous defoaming agent to the second aqueous defoaming agent is preferably (1 to 2) to (2 to 3), more preferably 1.
The water-based interior wall coating with the anti-mosquito effect, which is prepared from the traditional Chinese medicinal materials, comprises 1-3% of film-forming auxiliary agent by mass percentage, and preferably 1.5-2.5%. In the present invention, the film forming aid preferably comprises a first film forming aid, preferably propylene glycol, and a second film forming aid, preferably AH-12; the membrane adjuvant AH-12 is preferably purchased from Australian Ohio GmbH, beijing Oriental.
In the present invention, the mass ratio of the first film-forming aid to the second film-forming aid is preferably (1 to 2): 1 to 2, and more preferably 2.
In the present invention, the first film-forming aid is specifically preferably tetramethylweierb propylene glycol.
The water-based interior wall coating with the anti-mosquito effect, which is prepared from the traditional Chinese medicinal materials, comprises 36-55% of inorganic filler, preferably 39-51.5% by mass.
In the invention, the inorganic filler comprises titanium dioxide, calcined kaolin, mica powder, silica powder and hollow glass microspheres.
In the invention, the inorganic filler preferably comprises 15-20% of titanium dioxide, 5-10% of calcined kaolin, 3-5% of mica powder, 10-15% of silica micropowder and 3-5% of hollow glass microspheres; more preferably comprises 15.5 to 19.5 percent of titanium dioxide, 5.5 to 9 percent of calcined kaolin, 3.5 to 4.5 percent of mica powder, 11 to 14 percent of silicon micropowder and 3.5 to 4.5 percent of hollow glass microspheres
In the invention, the titanium dioxide is preferably rutile titanium dioxide.
In a specific embodiment of the invention, the titanium dioxide is preferably python R996 titanium dioxide.
In the present invention, the calcined kaolin is preferably Inmunogu Sanxin Kaolin SX 80A
In the invention, the particle size of the mica powder is preferably less than or equal to 10 mu m; the production place of the mica powder is preferably Chuzhou.
In the present invention, the fine silicon powder preferably has a particle size of 10 μm or less, and is preferably purchased from Shandong Boken energy BK94.
In the invention, the hollow glass beads are C40 series of Chinese Huaxing.
The water-based interior wall coating with the anti-mosquito effect, which is prepared by using the traditional Chinese medicinal materials, comprises 0.2-0.5% of mildew preventive, preferably 0.25-0.45% by mass.
In the present invention, the mildewcide is preferably iodopropynyl butylcarbamate.
In a specific embodiment of the invention, the fungicide is preferably IPBC, available from welbo, sichuan.
The water-based interior wall coating with the anti-mosquito effect, which is prepared from the traditional Chinese medicinal materials, comprises 22-23.6% of camphor tree liquid medicine, and preferably 22.5-23% by mass.
In the invention, the camphor tree liquid medicine is prepared by mixing and decocting camphor tree raw materials and water, and the solid content of the camphor tree liquid medicine is 5-15%, preferably 10%
In the present invention, the preparation method of the camphor tree liquid preferably comprises the following steps:
mixing the camphor tree raw material with water to obtain a mixture; the camphor tree raw material comprises one or more of a trunk, branches and roots of the camphor tree;
heating the mixture to boiling for decocting to obtain a decocted feed liquid; the temperature for boiling is 100 ℃, and the time for boiling is 1-3 h;
and carrying out solid-liquid separation on the decocted feed liquid to obtain the camphor tree liquid medicine.
Mixing the camphor tree raw material with water to obtain a mixture; the camphor tree raw material comprises one or more of a trunk, branches and roots of the camphor tree.
In the invention, before the camphor tree raw material is mixed with water, the camphor tree raw material is preferably stacked in an outdoor shady and ventilated place to be dried for 60 days, so that the moisture on the inner layer and the surface of the camphor tree raw material is dried in the air.
In the present invention, the mass ratio of the camphor tree raw material to the water is preferably 1.
After a mixture is obtained, heating the mixture to boiling for decocting to obtain a decocted feed liquid; the temperature of the decocted liquid is 100 ℃, and the temperature of the decocted liquid is 1-3 h;
in the invention, the stewing heat preservation time is preferably 2h.
In the invention, the pH value of the decocted feed liquid obtained by decoction is preferably 7.5 +/-0.5.
In the invention, the color of the decocted feed liquid obtained by decoction is yellowish.
After the decocted feed liquid is obtained, the invention carries out solid-liquid separation on the decocted feed liquid to obtain the camphor tree liquid medicine.
In the invention, the solid-liquid separation is preferably carried out after the decocted feed liquid is cooled to room temperature.
In the present invention, the solid-liquid separation is preferably vacuum filtration.
In the present invention, the sieve used in the vacuum filtration is preferably a 200 mesh sieve.
In the present invention, before the camphor tree medicinal liquid is used, deionized water is preferably used to adjust the solid content of the camphor tree medicinal liquid to a desired requirement.
In the present invention, the method for determining the solid content of the camphor tree water is preferably as follows: and baking the camphor tree liquid medicine to be dry, wherein the mass content of the obtained solid active ingredients in the camphor tree liquid medicine is the solid content of the camphor tree liquid medicine. In the present invention, the temperature of the baking is preferably 100 ± 10 ℃.
The water-based interior wall coating with the anti-mosquito effect, which is prepared from the traditional Chinese medicinal materials, comprises 0.6-1% of surfactant by mass, and preferably 0.7-0.9%.
In the present invention, the surfactant is preferably BYK-SILCLEAN 3720, a Pico chemical coating surfactant.
The water-based interior wall coating with the anti-mosquito effect, which is prepared from the traditional Chinese medicinal materials, comprises 0.5-1% of ammonia water by mass percentage, and preferably 0.55-0.9%.
In the invention, the mass percentage of the ammonia water is preferably less than or equal to 25 percent, and preferably 17 to 25 percent.
In the invention, the pH value of the water-based interior wall coating with the anti-mosquito effect prepared by using the traditional Chinese medicinal materials is preferably 8.5-9; the viscosity of the water-based interior wall coating with the anti-mosquito effect prepared from the traditional Chinese medicinal materials is preferably 80-90 KU.
The invention provides a preparation method of a water-based interior wall coating with an anti-mosquito effect, which is prepared from traditional Chinese medicinal materials and comprises the following steps:
mixing cellulose, camphor tree liquid medicine, a water-based auxiliary agent, a film forming auxiliary agent, an inorganic filler, a styrene-acrylic polymer, potash water glass, a mildew preventive, a surfactant and ammonia water to obtain the water-based interior wall coating with the mosquito-proof effect, which is prepared by utilizing traditional Chinese medicinal materials.
In the present invention, the mixing preferably comprises the steps of:
dissolving the cellulose in a first part of camphor tree medicinal water to obtain a cellulose solution;
mixing the cellulose solution, the water-based dispersing agent, part of water-based defoaming agent, the water-based wetting agent, part of film-forming auxiliary agent and a second part of camphor tree liquid medicine under first stirring to obtain a first mixture; the rotating speed of the first stirring and mixing is 300-400 r/min, and the time of the first stirring and mixing is 5-10 min;
secondly stirring and mixing the first mixture, the titanium dioxide, the mica powder, the calcined kaolin, the silicon micro powder and the hollow glass microspheres to obtain a second mixture; the rotating speed of the second stirring and mixing is 800-1000r/min, and the time of the first stirring and mixing is 15-20 min;
thirdly mixing the second mixture, the styrene-acrylic polymer and the residual aqueous defoaming agent to obtain a third mixture; the rotating speed of the third stirring and mixing is 400-600 r/min, and the time of the third stirring and mixing is 5-10 min;
fourthly, mixing the third mixed material, the potash water glass, the rest film-forming auxiliary agent, the mildew preventive and the surfactant to obtain a fourth mixed material; the rotating speed of the fourth stirring and mixing is 400-600 r/min, and the time of the fourth stirring and mixing is 10-15 min;
and mixing the fourth mixture, ammonia water and the rest camphor tree liquid medicine for the fifth time to obtain the water-based interior wall coating with the mosquito-proof effect, which is prepared from the traditional Chinese medicinal materials.
The cellulose is dissolved in the first part of camphor tree medicinal water to obtain a cellulose solution. In the present invention, the solvent is preferably stirred at a rotation speed of 800 to 1000r/min. The dosage of the first part of camphor tree liquid medicine is not specially required, and the cellulose can be completely dissolved.
After a cellulose solution is obtained, the cellulose solution, a water-based dispersing agent, a part of water-based antifoaming agent, a water-based wetting agent, a part of film-forming auxiliary agent and a second part of camphor tree liquid medicine are stirred and mixed for the first time to obtain a first mixture; the rotating speed of the first stirring and mixing is preferably 300-400 r/min, and more preferably 350r/min; the time for the first stirring and mixing is preferably 5 to 10min, and more preferably 5.5 to 8min. The invention has no special requirement on the dosage of the second part of camphor tree liquid medicine, and the first stirring and mixing can be carried out smoothly. In the present invention, the partially aqueous defoaming agent is particularly preferably the first aqueous defoaming agent. In the present invention, the part of the film-forming assistant is particularly preferably the first film-forming assistant.
After the first mixture is obtained, the first mixture, titanium dioxide, mica powder, calcined kaolin, silica micropowder and hollow glass microspheres are stirred and mixed for the second time to obtain a second mixture; the rotation speed of the second stirring and mixing is preferably 800-1000r/min, and more preferably 850-950 r/min; the time for the first stirring and mixing is preferably 15 to 20min, and more preferably 15.5 to 17min.
After the second mixture is obtained, the second mixture, the styrene-acrylic polymer and the residual water-based defoaming agent are mixed for the third time to obtain a third mixture; the rotating speed of the third stirring and mixing is preferably 400-600 r/min, and more preferably 450-550 r/min; the time for the third stirring and mixing is preferably 5 to 10min, and more preferably 5.5 to 8min. In the present invention, the residual aqueous defoaming agent is particularly preferably a second aqueous defoaming agent.
After the third mixed material is obtained, fourth mixing the third mixed material, the potash water glass, the residual film-forming assistant, the mildew preventive and the surfactant to obtain a fourth mixed material; the rotation speed of the fourth stirring and mixing is preferably 400-600 r/min, and more preferably 450-550 r/min; the fourth stirring and mixing time is preferably 10 to 15min, and more preferably 11 to 13min. In the present invention, the remaining film-forming assistant is particularly preferably a second film-forming assistant.
After the fourth mixture is obtained, the fourth mixture, ammonia water and the rest camphor tree liquid medicine are mixed for the fifth time to obtain the water-based interior wall coating which is prepared from the traditional Chinese medicinal materials and has the mosquito-proof effect.
In the present invention, the mixing is preferably carried out in a production cylinder.
The invention provides the application of the water-based interior wall coating with the mosquito-proof effect prepared by the traditional Chinese medicinal materials in the technical scheme or the water-based interior wall coating with the mosquito-proof effect prepared by the preparation method in the technical scheme as the interior wall coating of a house.
In the present invention, the application preferably comprises the steps of: coating the water-based interior wall coating with the anti-mosquito effect, which is prepared by using the traditional Chinese medicinal materials, on the surface of the interior wall coated with the primer layer, and obtaining an interior wall coating on the surface of the primer layer; the thickness of the inner wall coating is 60-80 μm.
In the invention, after the inner wall coating is obtained, the appearance, surface drying time, actual drying time, low-temperature film forming property and gloss of the inner wall coating are preferably detected; and (3) detecting the comprehensive properties (including water resistance, alkali resistance, scrubbing resistance and flame retardance) after drying for 7 days under natural environment conditions.
In order to further illustrate the present invention, the following detailed description of the technical solutions provided by the present invention is made with reference to the accompanying drawings and examples, but they should not be construed as limiting the scope of the present invention.
The sources of raw materials used in the practice of the invention are as follows:
camphor tree liquid medicine (self-made);
potash water glass (AH-K1 Australian Oriental Australian);
styrene-acrylic polymer (8807 equiv water novice);
cellulose (HS 30000YP2 coyen);
an aqueous dispersant (5040 Nostolacaceae);
aqueous wetting agents (070 dow);
a first aqueous defoamer (basf foamstar a 10);
a second aqueous defoamer (DF-681F Rhodia);
a first film-forming aid (propylene glycol Sichuan Wilbo);
a second film forming aid (AH-12 Aohan Oriental);
a surfactant (3320 BYK);
mildewcides (IPBC Sichuan Wilbo);
rutile titanium dioxide (996 python);
hollow glass microspheres (C40 series of chinese huaxing);
calcined kaolin (SX-80A sanxin);
mica powder (1250 mesh Chuzhou);
silicon micropowder (1250 mesh Shandong Boken energy BK 94).
Example 1
Cleaning the trunks, roots and branches of the camphor trees, stacking the trunks, roots and branches in an outdoor shady and ventilated place, and airing for 60 days to obtain camphor tree raw material blocks after moisture on the inner layer and the surface is aired; putting 1 ton of camphor tree raw material lump material into a 5 cubic boiler, then adding 3 tons of tap water, and covering the boiler cover; heating with natural gas, heating at constant temperature when the water in the boiler reaches 100 deg.C, decocting with slow fire for 2 hr, detecting the yellowish color of Cinnamomum camphora material liquid with pH of 7.5 + -0.5, and extinguishing; cooling by introducing cooling water, vacuumizing the camphor tree liquid medicine into the blending kettle, filtering by using a 200-mesh filter screen in the extraction process to obtain the camphor tree liquid medicine, and diluting the solid content of the camphor tree liquid medicine to 10% by using deionized water;
according to the formula of the water-based interior wall coating with the anti-mosquito effect prepared from the traditional Chinese medicinal materials in the example 1 provided in table 1, the water-based interior wall coating with the anti-mosquito effect prepared from the traditional Chinese medicinal materials is prepared;
the preparation method comprises the following steps:
slowly adding cellulose into camphor tree liquid medicine, and stirring at 800 rpm until the cellulose is fully dissolved to obtain a cellulose solution;
slowly adding a water-based dispersing agent, a first defoaming agent, a water-based wetting agent, a first film-forming auxiliary agent and camphor tree liquid medicine into the cellulose solution, and stirring for 5 minutes at 300 revolutions per minute; obtaining a first feed liquid;
adding rutile type titanium dioxide, mica powder, calcined kaolin, silica fume and hollow glass microspheres into the first feed liquid, stirring for 15 minutes at 800 rpm, and detecting no particles to obtain a second feed liquid;
adding the styrene-acrylic polymer and a second defoaming agent into the second material liquid, and stirring for 5 minutes at 400 rpm to obtain a third material liquid;
adding potash water glass, a second film forming auxiliary agent, a mildew preventive and a surfactant into a third feed liquid in a production cylinder, and stirring at a medium speed of 400 revolutions per minute for 10 minutes to obtain a fourth feed liquid;
and adjusting the pH value of the fourth feed liquid to 8.5-9 by adopting ammonia water, and then adjusting the viscosity of the fourth feed liquid to 80-90 KU by adopting camphor tree medicinal liquid to obtain the water-based interior wall coating with the anti-mosquito effect, which is prepared by utilizing traditional Chinese medicinal materials.
Example 2
Cleaning the trunks, roots and branches of the camphor trees, stacking the trunks, roots and branches in an outdoor shady and ventilated place, and airing for 60 days to obtain camphor tree raw material blocks after moisture on the inner layer and the surface is aired; putting 1 ton of camphor tree raw material block into a 5 cubic boiler, adding 3 tons of tap water, and covering the boiler cover; heating with natural gas, heating at constant temperature when the water in the boiler reaches 100 deg.C, decocting with slow fire for 2 hr, detecting the yellowish color of the Cinnamomum camphora material liquid with pH of 7.5 + -0.5, and extinguishing; cooling by introducing cooling water, vacuumizing the camphor tree liquid medicine into a blending kettle, filtering by using a 200-mesh filter screen in the process of extraction to obtain camphor tree liquid medicine, and diluting the solid content of the camphor tree liquid medicine to 10% by using deionized water;
according to the formula of the water-based interior wall coating with the anti-mosquito effect prepared from the traditional Chinese medicinal materials in the example 2 provided in the table 1, the water-based interior wall coating with the anti-mosquito effect prepared from the traditional Chinese medicinal materials is prepared;
the preparation method comprises the following steps:
slowly adding cellulose into camphor tree liquid medicine, and stirring at 1000 rpm until the cellulose is fully dissolved to obtain a cellulose solution;
slowly adding a water-based dispersing agent, a first defoaming agent, a water-based wetting agent, a first film-forming auxiliary agent and camphor tree liquid medicine into the cellulose solution, and stirring for 10 minutes at 400 revolutions per minute; obtaining a first feed liquid;
adding rutile type titanium dioxide, mica powder, calcined kaolin, wollastonite powder and hollow glass microspheres into the first feed liquid, stirring for 20 minutes at 1000 rpm, and detecting that no particles exist to obtain a second feed liquid;
adding the styrene-acrylic polymer and a second defoaming agent into the second material liquid, and stirring for 10 minutes at 600 rpm to obtain a third material liquid;
adding the potash water glass, the second film forming auxiliary agent, the mildew preventive and the surfactant into the third feed liquid in the production cylinder, and stirring at the medium speed of 600 revolutions per minute for 15 minutes to obtain a fourth feed liquid;
and adjusting the pH value of the fourth feed liquid to 8.5-9 by adopting ammonia water, and then adjusting the viscosity of the fourth feed liquid to 80-90 KU by adopting camphor tree medicinal liquid to obtain the water-based interior wall coating with the anti-mosquito effect, which is prepared by utilizing traditional Chinese medicinal materials.
Example 3
Cleaning the trunks, roots and branches of the camphor trees, stacking the trunks, roots and branches in an outdoor shady and ventilated place, and airing for 60 days to obtain camphor tree raw material blocks after moisture on the inner layer and the surface is aired; putting 1 ton of camphor tree raw material lump material into a 5 cubic boiler, then adding 3 tons of tap water, and covering the boiler cover; heating with natural gas, heating at constant temperature when the water in the boiler reaches 100 deg.C, decocting with slow fire for 2 hr, detecting the yellowish color of the Cinnamomum camphora material liquid with pH of 7.5 + -0.5, and extinguishing; cooling by introducing cooling water, vacuumizing the camphor tree liquid medicine into the blending kettle, filtering by using a 200-mesh filter screen in the extraction process to obtain the camphor tree liquid medicine, and diluting the solid content of the camphor tree liquid medicine to 10% by using deionized water;
according to the formula of the water-based interior wall coating with the anti-mosquito effect prepared from the traditional Chinese medicinal materials in the example 3 provided in the table 1, the water-based interior wall coating with the anti-mosquito effect prepared from the traditional Chinese medicinal materials is prepared;
the preparation method comprises the following steps:
slowly adding cellulose into camphor tree liquid medicine, and stirring at 900 revolutions per minute until the cellulose is fully dissolved to obtain a cellulose solution;
slowly adding a water-based dispersing agent, a first defoaming agent, a water-based wetting agent, a first film-forming auxiliary agent and camphor tree liquid medicine into the cellulose solution, and stirring for 8 minutes at 350 revolutions per minute; obtaining a first feed liquid;
adding rutile type titanium dioxide, mica powder, calcined kaolin, wollastonite powder and hollow glass microspheres into the first feed liquid, stirring for 18 minutes at 900 revolutions per minute, and detecting that no particles exist to obtain a second feed liquid;
adding the styrene-acrylic polymer and a second defoaming agent into the second material liquid, and stirring for 8 minutes at 500 revolutions per minute to obtain a third material liquid;
adding potash water glass, a second film forming auxiliary agent, a mildew preventive and a surfactant into a third feed liquid in a production cylinder, and stirring at a medium speed of 500 revolutions per minute for 12 minutes to obtain a fourth feed liquid;
and adjusting the pH value of the fourth feed liquid to 8.5-9 by adopting ammonia water, and then adjusting the viscosity of the fourth feed liquid to 80-90 KU by adopting camphor tree medicinal liquid to obtain the water-based interior wall coating with the anti-mosquito effect, which is prepared by utilizing traditional Chinese medicinal materials.
Table 1: example 1-example 3 component formula proportion
Comparative example 1
The organic-inorganic hybrid flame-retardant mildew-resistant coating is prepared according to the preparation method described in example 1 of Chinese patent CN 113621261A.
Application example 1
Carrying out sealing primer construction on the integrated plate, after the integrated plate is dried thoroughly for 12 hours, respectively brushing the inner wall coatings prepared in the examples 1-3 and the comparative example 1, controlling the construction thickness to be 60-80 micrometers, and detecting appearance, surface drying time, actual drying time, low-temperature film forming property and gloss after construction; and (4) drying for 7 days under natural environment conditions to detect the comprehensive properties (water resistance, alkali resistance, scrubbing resistance and flame retardance). Raw paint detection items: viscosity, contrast ratio, low temperature stability, VOC content, free formaldehyde content, (total of benzene, toluene, ethylbenzene and xylene content), heavy metal content, glycol ether and esters thereof.
The comprehensive performance of the product is detected by GB/T9756-2018 synthetic resin emulsion interior wall coating and GB/T8624-2012 building material and product combustion performance and grading.
The results of the overall performance tests are shown in table 2.
Table 2: combination of Properties of examples 1 to 3 and comparative example 1
It can be seen from examples 1 to 3 that the larger the ratio of the potash water glass to the styrene-acrylic polymer is, the stronger the flame retardant performance is, and the smaller the mass loss rate is, but the average temperature rise in the furnace is almost the same. According to the invention, camphor tree liquid medicine is used as a diluent, and the produced inorganic paint for the inner wall ensures that all performances meet various indexes in GB/T9756-2018 synthetic resin emulsion inner wall paint and GB/T8624-2012 building material and product combustion performance and grading standards, and has the effects of preventing mosquitoes and simultaneously achieving the effect of purifying air. According to the invention, the hollow glass beads and the silica powder are added in the formula, so that gaps among the coatings are enhanced, more abundant camphor tree medicinal components are stored in the coatings, and the long-acting insect prevention effect is achieved. The mildew resistance and the mildew resistance durability both meet the standard requirements in JC/2177-2013 diatom ooze decorative wall material. The coating product provided by the invention utilizes camphor trees as medicinal materials to obtain the coating with the medicinal efficacy, and the product passes third-party detection.
Although the present invention has been described in detail with reference to the above embodiments, it is only a part of the embodiments of the present invention, not all of the embodiments, and other embodiments can be obtained without inventive step according to the embodiments, and all of the embodiments belong to the protection scope of the present invention.
Claims (10)
1. The water-based interior wall coating with the mosquito-proof effect, which is prepared from traditional Chinese medicinal materials, is characterized by comprising the following components in percentage by mass:
20 to 25 percent of potash water glass, 5 to 10 percent of styrene-acrylic polymer, 0.2 to 0.5 percent of cellulose, 0.9 to 1.5 percent of water-based auxiliary agent, 1 to 3 percent of film-forming auxiliary agent, 36 to 55 percent of inorganic filler, 0.2 to 0.5 percent of mildew preventive, 22 to 23.6 percent of camphor tree liquid medicine, 0.6 to 1 percent of surfactant and 0.5 to 1 percent of ammonia water;
the camphor tree liquid medicine is prepared by mixing and decocting camphor tree raw materials and water, and the solid content of the camphor tree liquid medicine is 5-15%;
the water-based auxiliary agent comprises a water-based dispersing agent, a water-based wetting agent and a water-based defoaming agent;
the inorganic filler comprises titanium dioxide, calcined kaolin, mica powder, silica powder and hollow glass microspheres;
the mass percentage of the ammonia water is less than or equal to 25 percent.
2. The water-based interior wall coating material according to claim 1, wherein the preparation method of the camphor tree water comprises the following steps:
mixing the camphor tree raw material with water to obtain a mixture; the camphor tree raw material comprises one or more of a trunk, branches and roots of the camphor tree;
heating the mixture to boiling for decocting to obtain a decocted feed liquid; the temperature for boiling is 100 ℃, and the time for boiling is 1-3 h;
and carrying out solid-liquid separation on the decocted feed liquid to obtain the camphor tree liquid medicine.
3. The water-based interior wall coating material according to claim 1, wherein the water-based auxiliary agent comprises 0.5-0.8% of water-based dispersant, 0.1-0.2% of water-based wetting agent and 0.3-0.5% of water-based defoaming agent.
4. The water-based interior wall coating of claim 1, wherein the inorganic filler comprises 15-20% of titanium dioxide, 5-10% of calcined kaolin, 3-5% of mica powder, 10-15% of silica micropowder and 3-5% of hollow glass microspheres.
5. The aqueous interior wall coating of claim 1 or 3, wherein the aqueous defoamer comprises a first aqueous defoamer being a basf defoamer, foamstar a10, and a second aqueous defoamer being a rosidiya DF-681F defoamer.
6. The aqueous interior wall coating of claim 1, wherein the film-forming aid comprises a first film-forming aid and a second film-forming aid, wherein the first film-forming aid is propylene glycol, and the second film-forming aid is film-forming aid AH-12.
7. The preparation method of the water-based interior wall coating with anti-mosquito effect prepared from the traditional Chinese medicinal materials according to any one of claims 1 to 6 is characterized by comprising the following steps:
mixing cellulose, camphor tree liquid medicine, a water-based auxiliary agent, a film forming auxiliary agent, an inorganic filler, a styrene-acrylic polymer, potash water glass, a mildew preventive, a surfactant and ammonia water to obtain the water-based interior wall coating with the mosquito-proof effect, which is prepared by utilizing traditional Chinese medicinal materials.
8. The method of claim 7, wherein the mixing comprises the steps of:
dissolving the cellulose in a first part of camphor tree medicinal water to obtain a cellulose solution;
mixing the cellulose solution, the water-based dispersing agent, part of water-based defoaming agent, the water-based wetting agent, part of film-forming auxiliary agent and a second part of camphor tree liquid medicine under first stirring to obtain a first mixture; the rotating speed of the first stirring and mixing is 300-400 r/min, and the time of the first stirring and mixing is 5-10 min;
secondly stirring and mixing the first mixture, titanium dioxide, mica powder, calcined kaolin, silica micropowder and hollow glass microspheres to obtain a second mixture; the rotating speed of the second stirring and mixing is 800-1000r/min, and the time of the first stirring and mixing is 15-20 min;
thirdly mixing the second mixture, the styrene-acrylic polymer and the residual aqueous defoaming agent to obtain a third mixture; the rotating speed of the third stirring and mixing is 400-600 r/min, and the time of the third stirring and mixing is 5-10 min;
fourthly, mixing the third mixed material, the potash water glass, the rest film-forming auxiliary agent, the mildew preventive and the surfactant to obtain a fourth mixed material; the rotating speed of the fourth stirring and mixing is 400-600 r/min, and the time of the fourth stirring and mixing is 10-15 min;
and mixing the fourth mixture, ammonia water and the rest camphor tree liquid medicine for the fifth time to obtain the water-based interior wall coating with the mosquito-proof effect, which is prepared from the traditional Chinese medicinal materials.
9. The use of the water-based interior wall coating with anti-mosquito effect prepared from the Chinese medicinal materials according to any one of claims 1 to 6 or the water-based interior wall coating with anti-mosquito effect prepared from the Chinese medicinal materials according to the preparation method of claim 7 or 8 as an interior wall coating of a house.
10. The application according to claim 9, characterized in that it comprises the following steps: coating the water-based interior wall coating with the anti-mosquito effect, which is prepared by using the traditional Chinese medicinal materials, on the surface of the interior wall coated with the primer layer, and obtaining an interior wall coating on the surface of the primer layer; the thickness of the inner wall coating is 60-80 μm.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105199462A (en) * | 2015-10-28 | 2015-12-30 | 漳州三德利油漆涂料有限公司 | Plant sterilizing insect-repelling functional type inner wall emulsion paint and preparation method thereof |
| CN109135444A (en) * | 2018-07-31 | 2019-01-04 | 安徽富瑞雪化工科技股份有限公司 | A kind of agalloch eaglewood interior wall coating and preparation method thereof |
| CN111925673A (en) * | 2020-07-31 | 2020-11-13 | 江苏华夏制漆科技有限公司 | Inorganic coating and preparation method thereof |
| CN112322091A (en) * | 2020-11-23 | 2021-02-05 | 成都市富百乐装饰材料实业有限公司 | Air purification, sterilization and mildew-proof coating and preparation method thereof |
| CN113321977A (en) * | 2021-06-17 | 2021-08-31 | 中节能(唐山)环保装备有限公司 | Water-based antibacterial and mildewproof coating and preparation method thereof |
| CN113621261A (en) * | 2020-05-07 | 2021-11-09 | 成都虹润制漆有限公司 | Organic-inorganic mixed flame-retardant mildew-proof coating and preparation method thereof |
-
2022
- 2022-12-30 CN CN202211719156.6A patent/CN115873434A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105199462A (en) * | 2015-10-28 | 2015-12-30 | 漳州三德利油漆涂料有限公司 | Plant sterilizing insect-repelling functional type inner wall emulsion paint and preparation method thereof |
| CN109135444A (en) * | 2018-07-31 | 2019-01-04 | 安徽富瑞雪化工科技股份有限公司 | A kind of agalloch eaglewood interior wall coating and preparation method thereof |
| CN113621261A (en) * | 2020-05-07 | 2021-11-09 | 成都虹润制漆有限公司 | Organic-inorganic mixed flame-retardant mildew-proof coating and preparation method thereof |
| CN111925673A (en) * | 2020-07-31 | 2020-11-13 | 江苏华夏制漆科技有限公司 | Inorganic coating and preparation method thereof |
| CN112322091A (en) * | 2020-11-23 | 2021-02-05 | 成都市富百乐装饰材料实业有限公司 | Air purification, sterilization and mildew-proof coating and preparation method thereof |
| CN113321977A (en) * | 2021-06-17 | 2021-08-31 | 中节能(唐山)环保装备有限公司 | Water-based antibacterial and mildewproof coating and preparation method thereof |
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Application publication date: 20230331 |