CN115872781A - Method for enhancing color development of ceramic tile, ceramic tile and application thereof - Google Patents
Method for enhancing color development of ceramic tile, ceramic tile and application thereof Download PDFInfo
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Abstract
The invention relates to the technical field of building materials, and discloses a method for enhancing color development of a ceramic tile, the ceramic tile and application thereof. The method comprises the following steps: (1) Ball milling or grinding the blank layer powder to prepare ceramic powder; (2) Distributing the ceramic powder, and performing compression molding to obtain a green body layer; (3) Ink-jet printing black ink on the green body layer to obtain a black ink-jet layer; (4) Applying a layer of white overglaze on the black ink-jet layer, printing yellow stripe patterns, applying transparent glaze, and firing to obtain the ceramic tile; the white overglaze comprises the following chemical components in percentage by mass: 50-65% of SiO 2 、20‑30％Al 2 O 3 、0.1‑0.5％Fe 2 O 3 、0.05‑0.2％TiO 2 、0.1‑0.4％CaO、0.5‑1.2％MgO、1‑3％K 2 O、0.5‑1％Na 2 O、1‑3％SnO 2 、5‑8％ZrSiO 4 5-6% loss on ignition. The invention solves the problems of white line on the side surface of the ceramic tile and high cost. The invention enhances the whiteness of the glaze, is beneficial to color development of yellow stripe patterns, and ensures that the glaze is smoother and flatter.
Description
Technical Field
The invention relates to the technical field of building materials, in particular to a method for enhancing color development of a ceramic tile, the ceramic tile and application thereof.
Background
With the continuous improvement of living standard of people, people have higher and higher requirements on ceramic tiles. Therefore, the new generation consumer groups prefer simple, light, comfortable and tasteful and simple styles to be compared with those with rich and bright colors. Although the black-white-gray series ceramic tiles are different in military projection in recent years, the practical position of the black series golden yellow and beige ceramic tiles cannot be ignored all the time, and the black series golden yellow and beige ceramic tiles are still the ceramic tile color series which is most widely applied in home decoration. The traditional black golden yellow ceramic tile needs to integrally apply a layer of white overglaze on a ceramic tile blank body firstly because the yellow part pattern is not good in color development, and then black and yellow stripe patterns are printed by ink jet, but the side surface of the ceramic tile prepared by the method has an obvious white line isolation layer, and simultaneously, the white overglaze needs to be integrally applied to the ceramic tile, so that the cost of the ceramic tile is high.
Disclosure of Invention
The present invention is directed to solving at least one of the problems of the prior art described above. Therefore, the invention provides a method for enhancing color development of a ceramic tile, the ceramic tile and application thereof.
The invention conception of the invention is as follows: the ceramic tile provided by the invention is characterized in that black ink is subjected to ink-jet printing on the green body layer to obtain a black ink-jet layer, then white digital overglaze is locally applied to the black ink-jet layer in a digital glaze-spraying manner, yellow stripe patterns are subjected to accurate contraposition ink-jet printing, and finally transparent glaze is applied. The problem of white lines on the side surface of the ceramic tile can be solved by locally applying the white overglaze, and the cost is reduced without integrally applying a layer of white overglaze. The chemical composition of the white overglaze contains tin oxide and zirconium silicate, so that the whiteness of the glaze surface is enhanced, and finally, the color development of the yellow stripe pattern on the white overglaze layer is better.
In a first aspect of the invention, a method for enhancing color development of a ceramic tile is provided.
Specifically, the method comprises the following steps:
(1) Ball milling or grinding the blank layer powder to prepare ceramic powder;
(2) Distributing the ceramic powder, and performing compression molding to obtain a green body layer;
(3) Ink-jet printing black ink on the green body layer to obtain a black ink-jet layer;
(4) Applying a layer of white overglaze on the black ink-jet layer, printing yellow stripe patterns, applying transparent glaze, and firing to obtain the ceramic tile;
the white overglaze comprises the following chemical components in percentage by mass: 50-65% SiO 2 、20-30％ Al 2 O 3 、0.1-0.5％Fe 2 O 3 、0.05-0.2％ TiO 2 、0.1-0.4％ CaO、0.5-1.2％ MgO、1-3％ K 2 O、0.5-1％ Na 2 O、1-3％ SnO 2 、5-8％ ZrSiO 4 5-6% loss on ignition.
The tin oxide and the zirconium silicate contained in the chemical composition of the white overglaze can improve the whiteness of the glaze and are beneficial to color development of yellow stripe patterns, meanwhile, the tin oxide is low in hardness, the tin oxide is easy to form ultrafine particles in the process of grinding the white overglaze to prepare the digital glaze, the tin oxide can enable the glaze to be smoother and smoother, but the excessive tin oxide and the zirconium silicate can enable the overwhite overglaze to cause serious color consumption, and therefore the content of the tin oxide and the zirconium silicate in the white overglaze needs to be controlled.
Preferably, in step (1), the chemical composition of the green body layer comprises, in mass fraction: 65-70% SiO 2 、15-22％Al 2 O 3 、0.5-1％ Fe 2 O 3 、0.1-0.5％ TiO 2 、0.2-0.6％ CaO、1-1.5％ MgO、5-8％ K 2 O、0.6-1％ Na 2 O, 5-6% loss on ignition.
Preferably, in the step (2), the equipment used for the press forming is a 3000-5000t press.
Preferably, in the step (3), the ink-jet printing black ink does not need to be printed on the white overglaze layer, and can also well develop color.
Preferably, in the step (4), the chemical composition of the transparent glaze comprises the following components in percentage by mass: 45-58% SiO 2 ：、13-17％Al 2 O 3 、0.1-0.3％ Fe 2 O 3 、0.01-0.05％ TiO 2 、7-10％ CaO、4-6％ MgO、3-5％ K 2 O、1-3％ Na 2 O、0.3-0.5ZrO 2 13-16% loss on ignition.
Preferably, in step (4), the white overglaze is a partial spray glaze, and the yellow stripe pattern must be printed on the white overglaze layer by using a precise alignment technology. The yellow stripe pattern needs to be on the white overglaze to develop a better color.
Preferably, in the step (4), the firing is kiln firing.
Preferably, in the step (4), the firing temperature is 1000 to 1200 ℃.
Preferably, in the step (4), the firing time is 45-70min.
Preferably, the black ink-jet layer, the white overglaze, the yellow stripe pattern and the transparent glaze are all prepared by adopting a digital glaze spraying technology.
Preferably, the digital glaze spraying technology adopts digital glaze, and the particle size of the digital glaze is 0.01-2 μm.
Further preferably, the digital glaze is added into a digital glaze spraying machine, the glaze spraying position and the glaze discharging amount of each channel are set, the lightness, thinness and uniformity of the glaze surface are guaranteed, and the cost can be greatly saved through digitalized glaze spraying according to needs.
A second aspect of the invention provides a ceramic tile.
Specifically, the glaze comprises a body layer, a black ink-jet layer, a white surface glaze layer, a yellow stripe pattern layer and a transparent glaze layer from bottom to top in sequence.
A third aspect of the invention provides a use of a ceramic tile in the field of construction.
In particular, the application is the decoration of the inner and outer walls and the ground of a building.
Compared with the prior art, the invention has the following beneficial effects:
according to the ceramic tile, the local surface glaze is applied, the accurate alignment technology is used for printing the yellow stripe pattern on the white surface glaze in an ink-jet mode, and all glaze layers are glazed in a digital glaze spraying mode, so that the problems of white lines on the side surface of the ceramic tile and high cost are solved. In addition, the ceramic tile contains tin oxide and zirconium silicate in the chemical composition of the white glaze layer, so that the whiteness of the glaze is enhanced, the color development of yellow stripe patterns is facilitated, and the glaze is smoother and smoother.
Drawings
FIG. 1 is a graph of the effect of example 1 and comparative example 3 ceramic tiles;
FIG. 2 is a graph showing the effect of the ceramic tiles of example 1 and comparative example 1.
Detailed Description
In order to make the technical solutions of the present invention more apparent to those skilled in the art, the following examples are given for illustration. It should be noted that the following examples are not intended to limit the scope of the claimed invention.
The starting materials, reagents or apparatuses used in the following examples are conventionally commercially available or can be obtained by conventionally known methods, unless otherwise specified.
In the following examples and comparative examples, the transparent glaze used was Wandao 888 overglaze and 9165 transparent glaze, and the black ink-jet layer and the yellow stripe pattern layer were purchased from Mirui Cisco technologies, inc.
Example 1
A method for enhancing color development of ceramic tiles and the ceramic tiles.
The method of the embodiment comprises the following steps:
ball-milling the blank powder, and spray-drying to obtain ceramic powder;
distributing the ceramic powder, pressing and forming by a 3000t press, and drying to obtain a green body layer;
carrying out ink-jet printing on the green body layer to obtain a black ink-jet layer;
applying white digital overglaze on the black ink-jet layer in a digital glaze spraying mode, precisely carrying out contraposition ink-jet printing on a yellow stripe pattern, applying transparent glaze, and firing in a kiln at 1190 ℃ to obtain the black series golden yellow beige ceramic tile.
The chemical composition of the green body layer comprises the following components in percentage by mass: 68.75% SiO 2 、17.5％ Al 2 O 3 、0.5％ Fe 2 O 3 、0.2％TiO 2 、0.4％ CaO、1.2％ MgO、5％ K 2 O、0.75％ Na 2 O, 5.7% loss on ignition.
The white overglaze comprises the following chemical components in percentage by mass: 57.5% SiO 2 、27.48％ Al 2 O 3 、0.2％ Fe 2 O 3 、0.05％TiO 2 、0.13％ CaO、0.73％ MgO、1.38％ K 2 O、0.63％ Na 2 O、1.34％ SnO 2 、5.56％ ZrSiO 4 5% loss on ignition.
The transparent glaze comprises the following chemical components in percentage by mass: 48.38% SiO 2 、16.85％ Al 2 O 3 、0.15％ Fe 2 O 3 、0.01％TiO 2 、9.48％ CaO、5.98％ MgO、3.94％ K 2 O、1.61％ Na 2 O、0.41％ZrO 2 13.19% loss on ignition.
The ceramic tile prepared by the method sequentially comprises a body layer, a black ink-jet layer, a white surface glaze layer, a yellow stripe pattern layer and a transparent glaze layer from bottom to top.
Example 2
A method for enhancing color development of ceramic tiles and the ceramic tiles.
The method of the embodiment comprises the following steps:
ball-milling the blank powder, and spray-drying to obtain ceramic powder;
distributing the ceramic powder, pressing and forming by a 3000t press, and drying to obtain a green body layer;
carrying out ink-jet printing on the green body layer to obtain a black ink-jet layer;
applying white digital overglaze on the black ink-jet layer in a digital glaze spraying mode, precisely carrying out contraposition ink-jet printing on a yellow stripe pattern, applying transparent glaze, and firing in a kiln at 1190 ℃ to obtain the black series golden yellow beige ceramic tile.
According to qualityThe chemical composition of the green body layer comprises the following components in percentage by weight: 68.75% SiO 2 、17.5％ Al 2 O 3 、0.5％ Fe 2 O 3 、0.2％TiO 2 、0.4％ CaO、1.2％ MgO、5％ K 2 O、0.75％ Na 2 O, 5.7% loss on ignition.
The white overglaze comprises the following chemical components in percentage by mass: 56% SiO 2 、25.48％ Al 2 O 3 、0.2％ Fe 2 O 3 、0.05％TiO 2 、0.13％ CaO、0.73％ MgO、1.38％ K 2 O、0.63％ Na 2 O、2.84％ SnO 2 、7.56％ ZrSiO 4 5% loss on ignition.
The chemical composition of the transparent glaze comprises the following components in percentage by mass: 48.38% SiO 2 、16.85％ Al 2 O 3 、0.15％ Fe 2 O 3 、0.01％TiO 2 、9.48％ CaO、5.98％ MgO、3.94％ K 2 O、1.61％ Na 2 O、0.41％ZrO 2 13.19% loss on ignition.
The ceramic tile prepared by the method sequentially comprises a body layer, a black ink-jet layer, a white surface glaze layer, a yellow stripe pattern layer and a transparent glaze layer from bottom to top.
Comparative example 1 (different from example 1 in that the glaze is applied by spraying)
A method for enhancing color development of ceramic tiles and the ceramic tiles.
The method of this comparative example, comprising the steps of:
ball-milling the blank powder, and spray-drying to obtain ceramic powder;
distributing the ceramic powder, performing compression molding by a 3000t press, and drying to obtain a green body layer;
carrying out ink-jet printing on the green body layer to obtain a black ink-jet layer;
and applying white digital overglaze on the black ink-jet layer in a glaze pouring mode, accurately printing yellow stripe patterns by contraposition ink-jet, applying transparent glaze, and firing in a kiln at 1190 ℃ to obtain the black series golden yellow beige ceramic tile.
Chemistry of the green body layer in mass fractionThe composition comprises: 68.75% SiO 2 、17.5％ Al 2 O 3 、0.5％ Fe 2 O 3 、0.2％TiO 2 、0.4％ CaO、1.2％ MgO、5％ K 2 O、0.75％ Na 2 O, 5.7% loss on ignition.
The white overglaze comprises the following chemical components in percentage by mass: 57.5% SiO 2 、27.48％ Al 2 O 3 、0.2％ Fe 2 O 3 、0.05％TiO 2 、0.13％ CaO、0.73％ MgO、1.38％ K 2 O、0.63％ Na 2 O、1.34％ SnO 2 、5.56％ ZrSiO 4 5% loss on ignition.
The transparent glaze comprises the following chemical components in percentage by mass: 48.38% SiO 2 、16.85％ Al 2 O 3 、0.15％ Fe 2 O 3 、0.01％TiO 2 、9.48％ CaO、5.98％ MgO、3.94％ K 2 O、1.61％ Na 2 O、0.41％ZrO 2 13.19% loss on ignition.
The ceramic tile prepared by the method sequentially comprises a body layer, a black ink-jet layer, a white surface glaze layer, a yellow stripe pattern layer and a transparent glaze layer from bottom to top.
Comparative example 2 (different from example 1 in that no partial overglaze is applied)
A method for enhancing color development of ceramic tiles and the ceramic tiles.
The method of this comparative example, comprising the steps of:
ball-milling the blank powder, and spray-drying to obtain ceramic powder;
distributing the ceramic powder, pressing and forming by a 3000t press, and drying to obtain a green body layer;
and (3) applying a layer of white overglaze on the green body layer in a digital glaze spraying manner, then sequentially carrying out ink-jet printing on black ink, yellow stripe patterns, applying transparent glaze and firing in a furnace at 1190 ℃ to obtain the black series golden yellow beige ceramic tile.
The chemical composition of the green body layer comprises the following components in percentage by mass: 68.75% SiO 2 、17.5％ Al 2 O 3 、0.5％ Fe 2 O 3 、0.2％TiO 2 、0.4％ CaO、1.2％ MgO、5％ K 2 O、0.75％ Na 2 O, 5.7% loss on ignition.
The white overglaze comprises the following chemical components in percentage by mass: 57.5% SiO 2 、27.48％ Al 2 O 3 、0.2％ Fe 2 O 3 、0.05％TiO 2 、0.13％ CaO、0.73％ MgO、1.38％ K 2 O、0.63％ Na 2 O、1.34％ SnO 2 、5.56％ ZrSiO 4 5% loss on ignition.
The chemical composition of the transparent glaze comprises the following components in percentage by mass: 48.38% SiO 2 、16.85％ Al 2 O 3 、0.15％ Fe 2 O 3 、0.01％TiO 2 、9.48％ CaO、5.98％ MgO、3.94％ K 2 O、1.61％ Na 2 O、0.41％ZrO 2 13.19% loss on ignition.
The ceramic tile prepared by the method sequentially comprises a body layer, a black ink-jet layer, a white surface glaze layer, a yellow stripe pattern layer and a transparent glaze layer from bottom to top.
Comparative example 3 (difference from example 1 in that tin oxide and zirconium silicate are not added to the glaze)
A method for enhancing color development of ceramic tiles and ceramic tiles prepared by the method.
The method of this comparative example, comprising the steps of:
ball-milling the blank powder, and spray-drying to obtain ceramic powder;
distributing the ceramic powder, pressing and forming by a 3000t press, and drying to obtain a green body layer;
carrying out ink-jet printing on the green body layer to obtain a black ink-jet layer;
applying white digital overglaze on the black ink-jet layer in a digital glaze spraying manner, precisely performing contraposition ink-jet printing on yellow stripe patterns, applying transparent glaze, and firing in a kiln at 1190 ℃ to obtain the black series golden yellow beige ceramic tile.
The chemical composition of the green body layer comprises the following components in percentage by mass: 68.75% SiO 2 、17.5％ Al 2 O 3 、0.5％ Fe 2 O 3 、0.2％TiO 2 、0.4％ CaO、1.2％ MgO、5％ K 2 O、0.75％ Na 2 O, 5.7% loss on ignition.
The white overglaze comprises the following chemical components in percentage by mass: 62.8% SiO 2 、28.78％ Al 2 O 3 、0.2％ Fe 2 O 3 、0.05％TiO 2 、0.13％ CaO、0.73％ MgO、1.58％ K 2 O、0.73％ Na 2 O, 5% loss on ignition.
The chemical composition of the transparent glaze comprises the following components in percentage by mass: 48.38% SiO 2 、16.85％ Al 2 O 3 、0.15％ Fe 2 O 3 、0.01％TiO 2 、9.48％ CaO、5.98％ MgO、3.94％ K 2 O、1.61％ Na 2 O、0.41％ZrO 2 13.19% loss on ignition.
The ceramic tile prepared by the method sequentially comprises a body layer, a black ink-jet layer, a white surface glaze layer, a yellow stripe pattern layer and a transparent glaze layer from bottom to top.
Test results
The ceramic tile samples obtained in examples 1-2 and comparative examples 1-3 were subjected to the relevant tests, and the test results are shown in Table 1 below.
The method for measuring the whiteness of the glaze surface comprises the following steps: the method is tested according to the national standard GB/T5950-2008 'whiteness measurement method of building materials and nonmetallic mineral products'.
TABLE 1
As is clear from Table 1, in both examples 1 and 2 of the present application, the color development of the yellow stripe pattern was normal, and the side face of the ceramic tile was free from the problem of white line, and the ceramic tile produced by partially applying the overglaze was low in cost. The problem of obvious white lines occurs in the comparative example 1, and in the comparative example 1, because the ceramic tile glaze produced by the traditional glaze pouring mode is thick and cannot be accurately positioned and applied, the obvious white line isolation layer can be seen from the side surface. Comparative example 2, although the color development was normal and was good, it was too costly to use a topically applied overglaze. Comparative example 3 because tin oxide and zirconium silicate were not contained in the white overglaze layer, the whiteness of the glaze was low, and the color development of the yellow stripe pattern was finally affected. As shown in FIG. 1, (a) is an effect chart of the ceramic tile of example 1, and (b) is an effect chart of the ceramic tile of comparative example 3. The ceramic tile of FIG. 1 (a) exhibits better color development than (b), indicating that the inclusion of tin oxide and zirconium silicate in the white overglaze layer results in better color development of the yellow stripe pattern. As shown in FIG. 2, (a) is an effect chart of the ceramic tile of example 1, and (b) is an effect chart of the ceramic tile of comparative example 1. Fig. 2 (a) shows no white line problem, while (b) shows a white line running through the top and bottom of the tile, which seriously affects the aesthetics of the tile. Therefore, the white digital overglaze is applied on the black ink-jet layer in a digital glaze spraying mode, the yellow stripe pattern is printed by accurately aligning ink-jet, and the problem of white lines can be solved.
The foregoing detailed description of the preferred embodiments of the invention has been presented. It should be understood that numerous modifications and variations could be devised by those skilled in the art in light of the present teachings without departing from the inventive concepts. Therefore, any modification, equivalent replacement, improvement and the like of the technical solutions, which are made by a person skilled in the art through logic analysis, reasoning or limited experiments based on the prior art according to the concept of the present invention, should be within the protection scope determined by the claims.
Claims (10)
1. A method for enhancing the color development of a ceramic tile, comprising the steps of:
(1) Ball milling or grinding the blank layer powder to prepare ceramic powder;
(2) Distributing the ceramic powder, and performing compression molding to obtain a green body layer;
(3) Ink-jet printing black ink on the green body layer to obtain a black ink-jet layer;
(4) Applying a layer of white overglaze on the black ink-jet layer, printing yellow stripe patterns, applying transparent glaze, and firing to obtain the ceramic tile;
the white overglaze comprises the following chemical components in percentage by mass: 50-65% of SiO 2 、20-30％Al 2 O 3 、0.1-0.5％Fe 2 O 3 、0.05-0.2％TiO 2 、0.1-0.4％CaO、0.5-1.2％MgO、1-3％K 2 O、0.5-1％Na 2 O、1-3％SnO 2 、5-8％ZrSiO 4 5-6% loss on ignition.
2. The method according to claim 1, wherein in step (1), the chemical composition of the green body layer comprises, in mass fraction: 65-70% of SiO 2 、15-22％Al 2 O 3 、0.5-1％Fe 2 O 3 、0.1-0.5％TiO 2 、0.2-0.6％CaO、1-1.5％MgO、5-8％K 2 O、0.6-1％Na 2 O, 5-6% loss on ignition.
3. The method according to claim 1, wherein in the step (2), the press forming is performed by using a 3000-5000t press.
4. The method according to claim 1, wherein in the step (4), the firing temperature is 1000 to 1200 ℃.
5. The method according to claim 1, wherein in the step (4), the firing time is 45-70min.
6. The method according to claim 1, wherein in the step (4), the chemical composition of the transparent glaze comprises, in mass fraction: 45-58% of SiO 2 ：、13-17％Al 2 O 3 、0.1-0.3％Fe 2 O 3 、0.01-0.05％TiO 2 、7-10％CaO、4-6％MgO、3-5％K 2 O、1-3％Na 2 O、0.3-0.5ZrO 2 13-16% loss on ignition.
7. The method according to claim 1, wherein the black ink-jet layer, the white overglaze, the yellow stripe pattern and the transparent glaze are all prepared by a digital glaze spraying technology.
8. The method according to claim 7, wherein the digital glaze spraying technology adopts digital glaze, and the particle size of the digital glaze is 0.01-2 μm.
9. The ceramic tile produced by the method of any one of claims 1-8, wherein the ceramic tile comprises a body layer, a black ink-jet layer, a white overglaze layer, a yellow stripe pattern layer and a transparent glaze layer in sequence from bottom to top.
10. Use of the ceramic tiles of claim 9 in the field of construction.
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| JP2010089992A (en) * | 2008-10-08 | 2010-04-22 | Tokan Material Technology Co Ltd | Ink set for inkjet printing on glazed product |
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| CN112500144A (en) * | 2020-12-03 | 2021-03-16 | 佛山欧神诺陶瓷有限公司 | Ceramic material, digital glaze-sprayed ceramic rock plate, and preparation method and application thereof |
| CN113968753A (en) * | 2021-10-21 | 2022-01-25 | 蒙娜丽莎集团股份有限公司 | Dark carving decoration dry grain full-polished ceramic tile and preparation method thereof |
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2022
- 2022-12-19 CN CN202211632914.0A patent/CN115872781A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010089992A (en) * | 2008-10-08 | 2010-04-22 | Tokan Material Technology Co Ltd | Ink set for inkjet printing on glazed product |
| CN108715516A (en) * | 2018-06-27 | 2018-10-30 | 江西和美陶瓷有限公司 | White glaze, the entire body containing white glaze are without boundary line Ceramic Tiles and preparation method thereof |
| CN111620563A (en) * | 2020-06-08 | 2020-09-04 | 东莞市唯美陶瓷工业园有限公司 | Preparation method of high-gray black ink-jet ceramic tile and preparation method of modified glaze slip |
| CN112500144A (en) * | 2020-12-03 | 2021-03-16 | 佛山欧神诺陶瓷有限公司 | Ceramic material, digital glaze-sprayed ceramic rock plate, and preparation method and application thereof |
| CN113968753A (en) * | 2021-10-21 | 2022-01-25 | 蒙娜丽莎集团股份有限公司 | Dark carving decoration dry grain full-polished ceramic tile and preparation method thereof |
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