CN115838570B - Nail piece capable of being repeatedly and circularly used - Google Patents
Nail piece capable of being repeatedly and circularly used Download PDFInfo
- Publication number
- CN115838570B CN115838570B CN202310019109.9A CN202310019109A CN115838570B CN 115838570 B CN115838570 B CN 115838570B CN 202310019109 A CN202310019109 A CN 202310019109A CN 115838570 B CN115838570 B CN 115838570B
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- nail
- parts
- plate body
- nail plate
- pressure
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- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims abstract description 20
- 239000007788 liquid Substances 0.000 claims abstract description 12
- 239000010410 layer Substances 0.000 claims abstract description 11
- 239000011241 protective layer Substances 0.000 claims abstract description 11
- 238000001771 vacuum deposition Methods 0.000 claims abstract description 8
- 239000011248 coating agent Substances 0.000 claims abstract description 6
- 238000000576 coating method Methods 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 12
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 9
- 239000004925 Acrylic resin Substances 0.000 claims description 8
- 229920000058 polyacrylate Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 6
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 6
- 229920002472 Starch Polymers 0.000 claims description 6
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 6
- 235000019698 starch Nutrition 0.000 claims description 6
- 239000008107 starch Substances 0.000 claims description 6
- 239000004593 Epoxy Substances 0.000 claims description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000003822 epoxy resin Substances 0.000 claims description 5
- 230000009477 glass transition Effects 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 229920001228 polyisocyanate Polymers 0.000 claims description 5
- 239000005056 polyisocyanate Substances 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 4
- 229920000578 graft copolymer Polymers 0.000 claims description 4
- RBQRWNWVPQDTJJ-UHFFFAOYSA-N methacryloyloxyethyl isocyanate Chemical compound CC(=C)C(=O)OCCN=C=O RBQRWNWVPQDTJJ-UHFFFAOYSA-N 0.000 claims description 4
- 229910001120 nichrome Inorganic materials 0.000 claims description 4
- 238000010023 transfer printing Methods 0.000 claims description 4
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 3
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical group C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 3
- 238000005516 engineering process Methods 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims 1
- 238000005034 decoration Methods 0.000 abstract description 4
- 239000008236 heating water Substances 0.000 abstract 1
- 238000007654 immersion Methods 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 8
- 238000001723 curing Methods 0.000 description 5
- 239000002313 adhesive film Substances 0.000 description 4
- 238000000016 photochemical curing Methods 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- 239000012790 adhesive layer Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 241000234282 Allium Species 0.000 description 1
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/80—Packaging reuse or recycling, e.g. of multilayer packaging
Landscapes
- Cosmetics (AREA)
Abstract
The invention relates to the technical field of nail decoration, in particular to a nail plate capable of being recycled, which comprises a nail plate body, wherein vacuum coating is firstly carried out on the nail plate body, then a color pattern layer is prepared on the front surface of the nail plate body after coating, then back gel is coated on the back surface of the nail plate body, the nail plate body is solidified to form a photo-solidified protective layer through light irradiation, pressure-sensitive adhesive liquid is coated on the photo-solidified protective layer, and then the nail plate body and the nail plate body are adhered to form a whole. The nail piece is designed with pressure-sensitive adhesive liquid, so that the nail piece can be detached in use in a heating water immersion mode.
Description
Technical Field
The invention relates to the technical field of nail decoration, in particular to a repeatedly-usable nail piece.
Background
The beauty is the nature of women, and the nail is to make corresponding decoration and beautification to the nails. First nail art is to apply nail polish and the like to the nail surface, and later, nail art patches have been developed. The nail-beautifying paste is a nail ornament which is quite popular among young females in recent years, is an indispensable prop for nail-beautifying lovers, and has unique use methods and special effects which are not replaced by other nail-beautifying tools. When the nail-beautifying adhesive is used, the adhesive layer is attached to the surface of a nail, the nail-beautifying adhesive is attached to the nail through the adhesive layer, decoration is carried out, and after the nail-beautifying adhesive is used, the nail-beautifying adhesive is taken down.
The nail art is usually printed with patterns, and earlier conventional practice is to print color patterns on the nail by means of film, plate making and the like, and in addition, the nail is decorated by means of gold stamping, printing onion powder, hot stamping laser, sticking and drilling, sticking and patterning, flocking, hollowed-out and the like. The most direct and most common way is to print a color pattern by means including film, plate making, etc. Recently, printing by a water transfer technique has been developed.
The prior nail piece is usually disposable in the use process, namely, after the nail piece is attached to the nail, the nail piece cannot be detached until the nail piece is used, and once the nail piece is detached, the nail piece cannot be reused.
Therefore, the company focuses on developing the nail piece which can be repeatedly used, so that the nail piece can be detached from the nail more conveniently for a user, and the use experience is improved.
Disclosure of Invention
The present invention has been made to solve the above-mentioned problems, and an object of the present invention is to provide a nail sheet which can be repeatedly recycled, and which can be detached by a simple method after being adhered to a nail, and which can be reused after a simple process.
The technical scheme adopted for solving the technical problems is as follows:
a nail piece capable of being recycled comprises a nail piece body, wherein vacuum coating is firstly carried out on the nail piece body, then a color pattern layer is prepared on the front surface of the coated nail piece body, then back gel is coated on the back surface of the nail piece body, the nail piece body is cured through light irradiation to form a photo-curing protective layer, pressure-sensitive adhesive liquid is coated on the photo-curing protective layer, and then the nail piece is integrated with nails after being attached.
Further preferably, the pressure-sensitive adhesive liquid comprises the following components in parts by weight: 100 parts of polyacrylate pressure-sensitive resin with glass transition temperature of minus 40 ℃ to minus 20 ℃, 5-8 parts of starch acrylamide graft copolymer, 3-5 parts of methacrylic acid polyisocyanate, 0.5-1 part of epoxy curing agent, 5-10 parts of epoxy acrylate resin, 3-5 parts of epoxy resin, 10-20 parts of solvent and 0.5-1 part of photoinitiator.
Further preferably, in the polyacrylate pressure sensitive resin, the polymeric elastomer is isooctyl acrylate and butyl acrylate, and the using amount ratio of the isooctyl acrylate to the butyl acrylate is 2-3:1.
Further preferably, the specific method for vacuum coating comprises the following steps: and respectively heating and gasifying isocyanoethyl methacrylate, diethanolamine and di-tert-butyl peroxide, respectively introducing the components into a cavity in a vacuum state through different pipelines, heating a nichrome wire in the cavity to 180-200 ℃ in the cavity, and growing a film on a first sheet body with the temperature of 25-30 ℃.
Further preferably, the photoinitiator is 1-hydroxycyclohexyl phenyl ketone.
Further preferably, the color pattern layer on the front surface of the nail body is prepared by a water batch transfer printing technology.
Further preferably, the epoxy acrylate resin is polyurethane modified epoxy acrylate.
The beneficial effects of the invention are as follows:
through the vacuum coating of pretreatment, a layer of protective film can be coated on the nail body, and the film is helpful for preparing the water transfer printing pattern; meanwhile, the layer of protective film can conveniently set a photo-curing protective layer on the armor plate body;
then the nail piece is adhered to the nail through pressure sensitive adhesive to finish the use of the nail piece;
in the present invention, the pressure sensitive adhesive is specially designed in structure, and the pressure sensitive adhesive is partially decomposed at relatively high temperature to reduce the viscosity of the pressure sensitive adhesive, and the adhesive solution is easy to separate from nail plate and nail, so that the nail plate is convenient for the user to detach from the nail for secondary use.
The starch acrylamide grafted copolymer is added into the pressure-sensitive adhesive liquid, and can drive the adhesive film formed by the adhesive liquid to be pyrolyzed when being soaked in hot water with higher temperature, so that the adhesiveness of the adhesive film is reduced, the adhesive force for bonding the nail plate body and the nail is reduced, and a user can conveniently tear the nail plate body from the nail.
The nail plate can be repeatedly and circularly used, so that the nail plate is greatly convenient for users to use, and the use experience is improved.
Detailed Description
The technical scheme of the invention is further specifically described by the following specific examples.
In the present invention, the materials and equipment used are commercially available or commonly used in the art, unless otherwise specified. The methods in the following examples are conventional in the art unless otherwise specified.
As pointed out in the background art, the applicant has developed a reusable nail sheet comprising a nail sheet body, first vacuum coating the nail sheet body, then preparing a color pattern layer on the front side of the coated nail sheet body, specifically by a water batch transfer technique, then coating a backside gel on the back side of the nail sheet body, curing the back side gel by light irradiation to form a photo-cured protective layer, coating a pressure-sensitive adhesive solution on the photo-cured protective layer, and then bonding the nail sheet to form an integral body.
The pressure-sensitive adhesive liquid comprises the following components in parts by weight: 100 parts of polyacrylate pressure-sensitive resin with glass transition temperature of minus 40 ℃ to minus 20 ℃, 5-8 parts of starch acrylamide graft copolymer, 3-5 parts of methacrylic acid polyisocyanate, 0.5-1 part of epoxy curing agent, 5-10 parts of epoxy acrylate resin, 3-5 parts of epoxy resin, 10-20 parts of solvent and 0.5-1 part of photoinitiator. In the polyacrylate pressure-sensitive resin, the polymer elastomer is isooctyl acrylate and butyl acrylate, and the using amount ratio of the isooctyl acrylate to the butyl acrylate is 2-3:1. The photoinitiator is 1-hydroxycyclohexyl phenyl ketone. The epoxy acrylate resin is polyurethane modified epoxy acrylate.
The vacuum coating method specifically comprises the following steps: and respectively heating and gasifying isocyanoethyl methacrylate, diethanolamine and di-tert-butyl peroxide, respectively introducing the components into a cavity in a vacuum state through different pipelines, heating a nichrome wire in the cavity to 180-200 ℃ in the cavity, and growing a film on a first sheet body with the temperature of 25-30 ℃.
Example 1:
firstly, preparing a nail body by using polyester, polypropylene, and the like, and then placing the nail body in a heating cavity for coating operation.
The method specifically comprises the following steps: and respectively heating and gasifying isocyanoethyl methacrylate, diethanolamine and di-tert-butyl peroxide, respectively introducing the components into a cavity in a vacuum state through different pipelines, heating a nichrome wire in the cavity to 180 ℃ in the cavity, and growing a film on a first sheet body with the temperature of 25 ℃.
And thirdly, preparing a color pattern layer on the coated nail body, specifically on the front surface of the coated nail body by a water batch transfer printing technology.
And fourthly, the light is irradiated to solidify the nail plate to form a light-cured protective layer, and the light-cured protective layer can form a buffer layer, so that the buffer layer is utilized to prevent the adhesive solution from being adhered to the nail plate too tightly, and the nail plate from being adhered to the nail too firmly to cause discomfort to the nail.
And fifthly, selling with glue, and coating pressure-sensitive adhesive liquid to adhere the nail plate body to the nails in the using process of a user. The pressure-sensitive adhesive liquid comprises the following components in parts by weight: 100 parts of polyacrylate pressure-sensitive resin with glass transition temperature of-40 ℃ to-20 ℃,5 parts of starch acrylamide graft copolymer, 5 parts of methacrylic acid polyisocyanate, 0.5 part of epoxy curing agent, 10 parts of epoxy acrylate resin, 3 parts of epoxy resin, 20 parts of solvent and 0.5 part of photoinitiator.
And sixthly, when the nail piece is not needed temporarily, soaking the nail piece in hot water at 50-60 ℃ for 20-50s to enable the pressure-sensitive adhesive to be pyrolyzed, so that the viscosity of the pressure-sensitive adhesive is greatly reduced, then, tearing the nail piece off the nail, tearing off the adhesive film from the nail piece body, and storing the nail piece body for the next use.
Example 2:
on the basis of example 1, unlike the example, the pressure-sensitive adhesive liquid comprises, in parts by weight: 100 parts of polyacrylate pressure-sensitive resin with glass transition temperature of-40 ℃ to-20 ℃, 8 parts of starch acrylamide grafted copolymer, 3 parts of methacrylic acid polyisocyanate, 1 part of epoxy curing agent, 10 parts of epoxy acrylate resin, 5 parts of epoxy resin, 20 parts of solvent and 1 part of photoinitiator.
Example 2 only used a protocol with minor adjustments to the pressure sensitive adhesive formulation.
The prepared nail sheets and pressure-sensitive adhesive were used for 10 subjects, 5 persons group, using the nail sheets of example 1 and example 2, respectively.
The nail plates of the two embodiments are not much different in use. Wherein 3 subjects can tear the nail pieces from the nails after adhering the nail pieces to the nails and soaking the nail pieces in hot water at 50 ℃ for 20-30 seconds, and the adhesive film and the nail pieces are easy to separate.
Wherein 5 subjects need to soak in hot water at 50 ℃ for more than 30 seconds to tear off the nail pieces.
In another 2 subjects, the nail pieces were only hard to tear off after soaking in water at 55℃for 30 s.
The subject does not affect reuse after the obtained nail pieces are simply cleaned.
The above-described embodiment is only a preferred embodiment of the present invention, and is not limited in any way, and other variations and modifications may be made without departing from the technical aspects set forth in the claims.
Claims (5)
1. A nail piece capable of being repeatedly recycled, which is characterized in that: the nail plate comprises a plate body, wherein vacuum coating is firstly carried out on the plate body, then a color pattern layer is prepared on the front surface of the plate body after coating, then back gel is coated on the back surface of the plate body, the plate body is solidified by light irradiation to form a photo-solidified protective layer, pressure-sensitive adhesive liquid is coated on the photo-solidified protective layer, and then the plate body is integrated with nails after being attached;
the pressure-sensitive adhesive liquid comprises the following components in parts by weight: 100 parts of polyacrylate pressure-sensitive resin with glass transition temperature of minus 40 ℃ to minus 20 ℃, 5-8 parts of starch acrylamide graft copolymer, 3-5 parts of methacrylic acid polyisocyanate, 0.5-1 part of epoxy curing agent, 5-10 parts of epoxy acrylate resin, 3-5 parts of epoxy resin, 10-20 parts of solvent and 0.5-1 part of photoinitiator; in the polyacrylate pressure-sensitive resin, the polymerized monomers are isooctyl acrylate and butyl acrylate, and the using amount ratio of the isooctyl acrylate to the butyl acrylate is 2-3:1.
2. A reusable nail plate according to claim 1, wherein: the vacuum coating method specifically comprises the following steps: and respectively heating and gasifying isocyanoethyl methacrylate, diethanolamine and di-tert-butyl peroxide, respectively introducing the components into a cavity in a vacuum state through different pipelines, heating a nichrome wire in the cavity to 180-200 ℃ in the cavity, and growing a film on a first sheet body with the temperature of 25-30 ℃.
3. A reusable nail plate according to claim 2, wherein: the photoinitiator is 1-hydroxycyclohexyl phenyl ketone.
4. A reusable nail plate according to claim 1, wherein: the color pattern layer on the front surface of the nail body is prepared by a water batch transfer printing technology.
5. A reusable nail plate according to claim 2, wherein: the epoxy acrylate resin is polyurethane modified epoxy acrylate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310019109.9A CN115838570B (en) | 2023-01-06 | 2023-01-06 | Nail piece capable of being repeatedly and circularly used |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310019109.9A CN115838570B (en) | 2023-01-06 | 2023-01-06 | Nail piece capable of being repeatedly and circularly used |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115838570A CN115838570A (en) | 2023-03-24 |
| CN115838570B true CN115838570B (en) | 2024-04-09 |
Family
ID=85579467
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202310019109.9A Active CN115838570B (en) | 2023-01-06 | 2023-01-06 | Nail piece capable of being repeatedly and circularly used |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115838570B (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1481428A (en) * | 2001-01-10 | 2004-03-10 | 化研科技株式会社 | Removable adhesive compsns and process for producing same |
| FR2998768A1 (en) * | 2012-12-05 | 2014-06-06 | Oreal | Adhesive article, useful for makeup and/or care of nails and/or false nails, comprises adhesive layer comprising a mixture of block copolymers, tackifying resin, aromatic tackifying resin, and optionally plasticizer |
| CN106377046A (en) * | 2016-09-08 | 2017-02-08 | 上海慕蓝实业有限公司 | Nail film and production technology thereof |
| JP2017099467A (en) * | 2015-11-30 | 2017-06-08 | 谷丸 響子 | Artificial nail patch and method for manufacturing and using artificial nail patch |
| CN108047368A (en) * | 2017-11-01 | 2018-05-18 | 宁波大学 | A kind of preparation method and application of isocyanates polymer |
| KR102158446B1 (en) * | 2020-04-17 | 2020-09-21 | 김홍철 | Method for Manufacturing Nail polish sticker |
| CN113684469A (en) * | 2021-08-06 | 2021-11-23 | 宁波摩华科技有限公司 | Organic protective coating for electronic device and preparation method thereof |
-
2023
- 2023-01-06 CN CN202310019109.9A patent/CN115838570B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1481428A (en) * | 2001-01-10 | 2004-03-10 | 化研科技株式会社 | Removable adhesive compsns and process for producing same |
| FR2998768A1 (en) * | 2012-12-05 | 2014-06-06 | Oreal | Adhesive article, useful for makeup and/or care of nails and/or false nails, comprises adhesive layer comprising a mixture of block copolymers, tackifying resin, aromatic tackifying resin, and optionally plasticizer |
| JP2017099467A (en) * | 2015-11-30 | 2017-06-08 | 谷丸 響子 | Artificial nail patch and method for manufacturing and using artificial nail patch |
| CN106377046A (en) * | 2016-09-08 | 2017-02-08 | 上海慕蓝实业有限公司 | Nail film and production technology thereof |
| CN108047368A (en) * | 2017-11-01 | 2018-05-18 | 宁波大学 | A kind of preparation method and application of isocyanates polymer |
| KR102158446B1 (en) * | 2020-04-17 | 2020-09-21 | 김홍철 | Method for Manufacturing Nail polish sticker |
| CN113684469A (en) * | 2021-08-06 | 2021-11-23 | 宁波摩华科技有限公司 | Organic protective coating for electronic device and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115838570A (en) | 2023-03-24 |
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