CN115786027A - Water-based micro-emulsified cutting fluid - Google Patents
Water-based micro-emulsified cutting fluid Download PDFInfo
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- CN115786027A CN115786027A CN202211605104.6A CN202211605104A CN115786027A CN 115786027 A CN115786027 A CN 115786027A CN 202211605104 A CN202211605104 A CN 202211605104A CN 115786027 A CN115786027 A CN 115786027A
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- water
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- nickel
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- 239000002173 cutting fluid Substances 0.000 title claims abstract description 149
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 147
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 71
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 50
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 22
- -1 alcohol amine Chemical class 0.000 claims abstract description 20
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000012991 xanthate Substances 0.000 claims abstract description 18
- 238000005520 cutting process Methods 0.000 claims abstract description 17
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 17
- 239000010413 mother solution Substances 0.000 claims abstract description 15
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 13
- 239000012452 mother liquor Substances 0.000 claims abstract description 13
- 229920000570 polyether Polymers 0.000 claims abstract description 13
- 238000005979 thermal decomposition reaction Methods 0.000 claims abstract description 13
- 239000002199 base oil Substances 0.000 claims abstract description 11
- 239000007788 liquid Substances 0.000 claims abstract description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 10
- 239000003208 petroleum Substances 0.000 claims abstract description 10
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 10
- 239000011734 sodium Substances 0.000 claims abstract description 10
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 claims abstract description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 9
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000012964 benzotriazole Substances 0.000 claims abstract description 9
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 9
- 239000011701 zinc Substances 0.000 claims abstract description 9
- 239000000243 solution Substances 0.000 claims description 21
- 238000002360 preparation method Methods 0.000 claims description 11
- 150000002815 nickel Chemical class 0.000 claims description 9
- 239000002518 antifoaming agent Substances 0.000 claims description 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 5
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims description 5
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 4
- IDOQDZANRZQBTP-UHFFFAOYSA-N 2-[2-(2,4,4-trimethylpentan-2-yl)phenoxy]ethanol Chemical compound CC(C)(C)CC(C)(C)C1=CC=CC=C1OCCO IDOQDZANRZQBTP-UHFFFAOYSA-N 0.000 claims description 4
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims description 4
- 229920004929 Triton X-114 Polymers 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 claims description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 3
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 claims description 3
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims description 3
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 3
- 229920004890 Triton X-100 Polymers 0.000 claims description 3
- 239000013504 Triton X-100 Substances 0.000 claims description 3
- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 claims description 3
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 229940078494 nickel acetate Drugs 0.000 claims description 3
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 3
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims description 3
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims description 3
- 235000011067 sorbitan monolaureate Nutrition 0.000 claims description 3
- XOGODJOZAUTXDH-UHFFFAOYSA-M (N-methylanilino)methanesulfonate Chemical compound CN(CS([O-])(=O)=O)c1ccccc1 XOGODJOZAUTXDH-UHFFFAOYSA-M 0.000 abstract description 3
- 239000013530 defoamer Substances 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 22
- 238000012360 testing method Methods 0.000 description 20
- 230000001050 lubricating effect Effects 0.000 description 17
- 238000010079 rubber tapping Methods 0.000 description 14
- 239000008367 deionised water Substances 0.000 description 13
- 229910021641 deionized water Inorganic materials 0.000 description 13
- 231100000241 scar Toxicity 0.000 description 10
- 238000011156 evaluation Methods 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- 238000003756 stirring Methods 0.000 description 5
- 238000004945 emulsification Methods 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000003917 TEM image Methods 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000006061 abrasive grain Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000013556 antirust agent Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
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- Lubricants (AREA)
Abstract
The invention belongs to the technical field of cutting fluid, and provides a water-based micro-emulsion cutting fluid. The water-based micro-emulsified cutting fluid comprises the following components in parts by weight: 2 parts of cutting liquid mother liquor, 0.06-0.4 part of nano nickel sulfide and 37-38 parts of water; the cutting liquid mother solution comprises the following components in parts by weight: 5 to 15 parts of base oil, 2 to 4 parts of zinc dialkyl dithiophosphate, 0.3 to 0.7 part of benzotriazole, 0.3 to 0.7 part of defoamer, 5 to 7 parts of organic alcohol amine, 6 to 10 parts of triton, 1 to 3 parts of petroleum sodium sulfonate, 4 to 6 parts of polyether, 4 to 6 parts of span and 18 to 20 parts of water; the nano nickel sulfide is obtained by thermal decomposition of long-chain alkyl nickel xanthate. The water-based micro-emulsified cutting fluid provided by the invention has excellent extreme pressure anti-wear performance, and the maximum non-seizure load can reach 1069N.
Description
Technical Field
The invention relates to the technical field of cutting fluid, in particular to water-based micro-emulsified cutting fluid.
Background
The cutting fluid is used for cooling and lubricating the tool and industrial fluid of a workpiece in the metal cutting and grinding process, and the reasonable use of the cutting fluid in the metal cutting process can reduce the friction between the tool and a processed surface, reduce the cutting force and the cutting temperature and reduce the tool abrasion. The cutting fluid can be divided into oil-based cutting fluid and water-based cutting fluid, the oil-based cutting fluid is synthesized by compounding base oil with extreme pressure wear-resistant additives, lubricants, antirust agents and the like in different proportions, the cutting performance such as cutter durability, dimensional accuracy and surface roughness are good, but the oil-based cutting fluid has the problems of low flash point, strong irritation, difficulty in cleaning, high cost and the like. In recent years, water-based cutting fluids have the advantages of poor irritation, easiness in cleaning and low cost due to the fact that water is used as a matrix, and further the water-based cutting fluids are developed rapidly.
Disclosure of Invention
In view of the above, the invention aims to provide a water-based micro-emulsion cutting fluid. The water-based micro-emulsified cutting fluid provided by the invention has excellent extreme pressure performance and lubricating performance.
In order to achieve the above object, the present invention provides the following technical solutions:
the invention provides a water-based micro-emulsified cutting fluid which comprises the following components in parts by weight:
2 parts of cutting liquid mother liquor, 0.06-0.4 part of nano nickel sulfide and 37-38 parts of water;
the cutting liquid mother solution comprises the following components in parts by weight:
5-15 parts of base oil, 2-4 parts of Zinc Dialkyl Dithiophosphate (ZDDP), 0.3-0.7 part of benzotriazole, 0.3-0.7 part of defoaming agent, 18-20 parts of water, 5-7 parts of organic alcohol amine, 6-10 parts of triton, 1-3 parts of petroleum sodium sulfonate, 4-6 parts of polyether and 4-6 parts of span;
the nano nickel sulfide is obtained by thermal decomposition of long-chain alkyl nickel xanthate.
Preferably, the preparation method of the nano nickel sulfide comprises the following steps:
mixing and stirring the long-chain alkyl xanthate potassium aqueous solution and the nickel salt aqueous solution to obtain a long-chain alkyl xanthate nickel solution;
carrying out thermal decomposition on the long-chain alkyl nickel xanthate solution to obtain the nano nickel sulfide;
the concentration of the long-chain alkyl nickel xanthate solution is 0.005-0.015 mol/L.
Preferably, the temperature of the thermal decomposition is 70-90 ℃ and the time is 80-100 min.
Preferably, the number of carbon in the long-chain alkyl group in the water-soluble long-chain alkyl potassium xanthate is 10-35; the water-soluble nickel salt comprises one or more of nickel nitrate, nickel chloride, nickel sulfate and nickel acetate.
Preferably, the molar ratio of the water-soluble nickel salt to the water-soluble long-chain alkyl potassium xanthate is 1:0.5 to 1.5.
Preferably, the triton comprises triton X-100 and/or triton X-114.
Preferably, the polyether comprises one or more of ethylene glycol monobutyl ether, diethylene glycol butyl ether, and dipropylene glycol butyl ether.
Preferably, the span includes one or more of span 20, span 40, span 60 and span 80.
Preferably, the organic alcohol amine comprises one or more of triisopropanolamine, diethanolamine, and triethanolamine.
The invention provides a water-based micro-emulsified cutting fluid which comprises the following components in parts by weight: 2 parts of cutting liquid mother liquor, 0.06-0.4 part of nano nickel sulfide and 37-38 parts of water; the cutting liquid mother solution comprises the following components in parts by weight: 5 to 15 parts of base oil, 2 to 4 parts of zinc dialkyl dithiophosphate, 0.3 to 0.7 part of benzotriazole, 0.3 to 0.7 part of defoamer, 18 to 20 parts of water, 5 to 7 parts of organic alcohol amine, 6 to 10 parts of triton, 1 to 3 parts of petroleum sodium sulfonate, 4 to 6 parts of polyether and 4 to 6 parts of span; the nano nickel sulfide is obtained by thermal decomposition of long-chain alkyl nickel xanthate. In the water-based micro-emulsified cutting fluid, the zinc dialkyl dithiophosphate has very excellent lubricating and bearing capacity; the lubricating oil can improve the lubricating property of the water-based micro-emulsion cutting fluid by compounding with base oil and nano nickel sulfide, and has high antiwear extreme pressure synergistic effect.
Drawings
FIG. 1 shows the maximum non-seizure load P of the water-based microemulsified cutting fluids obtained in comparative example 1 and examples 1 to 5 B A value map;
FIG. 2 is a friction coefficient curve chart of the water-based microemulsion cutting fluid obtained in comparative example 1 and examples 1-5 (load is 392N, and rotating speed is 1450 r/min);
FIG. 3 is a graph showing the tapping torque of the water-based microemulsified cutting fluids obtained in comparative example 1 and examples 1 to 5;
FIG. 4 is a wear pattern of the water-based microemulsion cutting fluid obtained in comparative example 1 (load: 392N, rotation speed: 1450 r/min);
FIG. 5 is a wear pattern of the water-based microemulsified cutting fluid obtained in example 1 (load: 392N, rotation speed: 1450 r/min);
FIG. 6 is a friction coefficient curve and a wear pattern of the water-based micro-emulsified cutting fluid obtained in example 1 (load is 392N, and rotating speed is 1200 r/min);
FIG. 7 is a friction coefficient curve and a wear pattern of the water-based micro-emulsified cutting fluid obtained in example 1 (load is 510N, and rotating speed is 1450 r/min);
FIG. 8 is a transmission electron micrograph of the nano nickel sulfide obtained in example 1;
FIG. 9 is a wear pattern of the water-based micro-emulsified cutting fluid obtained in example 2 (load 392N, rotation speed 1450 r/min);
FIG. 10 is a friction coefficient curve and a wear pattern of the water-based micro-emulsified cutting fluid obtained in example 2 (load: 392N, rotation speed: 1200 r/min);
FIG. 11 is a friction coefficient curve and a wear pattern of the water-based micro-emulsified cutting fluid obtained in example 2 (load 510N, rotation speed 1450 r/min);
FIG. 12 is a wear pattern of the water-based microemulsified cutting fluid obtained in example 3 (load: 392N, rotation speed: 1450 r/min);
FIG. 13 is a wear pattern of the water-based microemulsified cutting fluid obtained in example 4 (load: 392N, rotation speed: 1450 r/min);
FIG. 14 is a wear pattern of the water-based microemulsified cutting fluid obtained in example 5 (load: 392N, rotation rate: 1450 r/min).
Detailed Description
The invention provides a water-based micro-emulsified cutting fluid which comprises the following components in parts by weight:
2 parts of cutting fluid mother liquor, 0.06-0.4 part of nano nickel sulfide and 37-38 parts of water;
the cutting liquid mother solution comprises the following components in parts by weight:
5-15 parts of base oil, 2-4 parts of Zinc Dialkyl Dithiophosphate (ZDDP), 0.3-0.7 part of benzotriazole, 0.3-0.7 part of defoaming agent, 5-7 parts of organic alcohol amine, 6-10 parts of triton, 1-3 parts of sodium petroleum sulfonate, 4-6 parts of polyether, 4-6 parts of span and 18-20 parts of deionized water;
the nano nickel sulfide is obtained by thermal decomposition of long-chain alkyl nickel xanthate.
In the present invention, the starting materials used in the present invention are preferably commercially available products unless otherwise specified.
The water-based micro-emulsified cutting fluid provided by the invention comprises 2 parts by weight of cutting fluid mother solution. In the invention, the cutting liquid mother solution comprises the following components in parts by weight: 5 to 15 parts of base oil, 2 to 4 parts of zinc dialkyl dithiophosphate ZDDP, 0.3 to 0.7 part of benzotriazole, 0.3 to 0.7 part of defoaming agent, 5 to 7 parts of organic alcohol amine, 6 to 10 parts of triton, 1 to 3 parts of petroleum sodium sulfonate, 4 to 6 parts of polyether, 4 to 6 parts of span and 18 to 20 parts of deionized water.
In the present invention, the cutting fluid mother liquor includes 5 to 15 parts by weight, preferably 7 to 13 parts by weight, and more preferably 9 to 11 parts by weight of a base oil. In the present invention, the base oil preferably includes one or more of white oil, vegetable oil and paraffin oil, and more preferably white oil.
In the present invention, the cutting fluid stock solution includes 2 to 4 parts by weight, preferably 2.5 to 3.5 parts by weight, and more preferably 3 parts by weight of zinc dialkyldithiophosphate.
In the invention, the cutting liquid mother solution comprises 0.3 to 0.7 weight part of benzotriazole, preferably 0.4 to 0.6 weight part, and more preferably 0.5 weight part. In the invention, the benzotriazole has good antirust lubrication effect and antibacterial stabilization effect, and can effectively prevent corrosion and deterioration.
In the present invention, the cutting fluid mother liquor includes 0.3 to 0.7 parts by weight of a defoaming agent, preferably 0.4 to 0.6 parts by weight, and more preferably 0.5 parts by weight. In the present invention, the defoaming agent preferably includes one or more of modified silicone oil, natural oil and fat, and polyether, and more preferably modified silicone oil.
In the present invention, the cutting fluid mother liquor includes 18 to 20 parts by weight of water, preferably 18.5 to 19.5 parts by weight, and more preferably 19 parts by weight. In the present invention, the water preferably includes deionized water.
In the present invention, the cutting fluid mother liquor includes 5 to 7 parts by weight, preferably 5.5 to 6.5 parts by weight, and more preferably 6 parts by weight of the organic alcohol amine. In the present invention, the organic alcohol amine preferably includes one or more of triisopropanolamine, diethanolamine, and triethanolamine, and more preferably triethanolamine.
In the present invention, the cutting fluid mother liquor includes 6 to 10 parts by weight of triton, preferably 7 to 9 parts by weight, and more preferably 8 parts by weight. In the invention, the triton preferably comprises triton X-100 and/or triton X-114, and more preferably triton X-114.
In the present invention, the cutting fluid mother liquor comprises 1 to 3 parts by weight of sodium petroleum sulfonate, preferably 1.5 to 2.5 parts by weight, and more preferably 2 parts by weight. In the present invention, the sodium petroleum sulfonate has a very excellent rust preventive effect.
In the present invention, the cutting fluid mother liquor includes 4 to 6 parts by weight of polyether, preferably 4.5 to 5.5 parts by weight, and more preferably 5 parts by weight. In the present invention, the polyether preferably includes one or more of ethylene glycol monobutyl ether, diethylene glycol butyl ether, and dipropylene glycol butyl ether, and is further preferably diethylene glycol butyl ether. In the invention, the polyether has the functions of emulsification, dispersion and lubrication in the water-based micro-emulsified cutting fluid.
In the present invention, the cutting fluid mother liquor comprises span 4 to 6 parts by weight, preferably 4.5 to 5.5 parts by weight, and more preferably 5 parts by weight. In the present invention, the span preferably includes one or more of span 20, span 40, span 60 and span 80, and more preferably span 80. In the invention, the span has strong emulsifying, dispersing and lubricating properties and is also a good stabilizer and defoamer.
In the invention, the polyether, span and petroleum sodium sulfonate are compounded to play a good role in emulsification and stabilization, so that each component is uniformly and stably dispersed in water, the sedimentation, layering, agglomeration, flocculation or aging of effective components are prevented, and the storage stability of the water-based micro-emulsion cutting fluid is improved.
The water-based micro-emulsion cutting fluid provided by the invention comprises 0.06-0.4 part by weight of nano nickel sulfide, and particularly preferably 0.2 part by weight, 0.3 part by weight, 0.4 part by weight, 0.1 part by weight and 0.06 part by weight. In the invention, the nano nickel sulfide is obtained by thermal decomposition of long-chain alkyl nickel xanthate. In the present invention, the method for preparing the nano nickel sulfide preferably comprises the following steps: uniformly mixing a long-chain alkyl potassium xanthate aqueous solution and a nickel salt aqueous solution to obtain a long-chain alkyl nickel xanthate solution; and carrying out thermal decomposition on the long-chain alkyl nickel xanthate solution to obtain the nano nickel sulfide. In the present invention, the concentration of the long-chain alkyl nickel xanthate solution is preferably 0.005 to 0.015mol/L, and more preferably 0.01mol/L. In the present invention, the temperature of the thermal decomposition is preferably 70 to 90 ℃, and more preferably 80 ℃; the time is preferably 80 to 100min, more preferably 90min. After the thermal decomposition, the invention preferably further comprises extraction drying, and the operation of the extraction drying is not particularly limited as long as the nano nickel sulfide can be extracted and dried.
In the present invention, the number of carbons in the long-chain alkyl group in the water-soluble long-chain alkyl potassium xanthate is preferably 10 to 35, and more preferably 33. In the present invention, the water-soluble nickel salt preferably includes one or more of nickel nitrate, nickel chloride, nickel sulfate, and nickel acetate, and more preferably is nickel nitrate. In the present invention, the molar ratio of the water-soluble nickel salt to the water-soluble long-chain alkyl potassium xanthate is preferably 1:0.5 to 1.5, more preferably 1:1.
in the invention, the zinc dialkyl dithiophosphate has very excellent lubricating and bearing capacity, can improve the lubricating performance of the water-based micro-emulsified cutting fluid by compounding with base oil and nano nickel sulfide, and has high anti-wear extreme pressure synergistic effect. The water-based micro-emulsified cutting fluid provided by the invention comprises 37-38 parts by weight of water. In the present invention, the water preferably includes deionized water.
The preparation method of the water-based micro-emulsified cutting fluid is not particularly limited, and a person skilled in the art can adopt a conventional preparation method of a mixture.
The water-based microemulsified cutting fluids provided by the present invention are described in detail below with reference to the following examples, but they should not be construed as limiting the scope of the present invention.
Comparative example 1
A preparation method of a water-based micro-emulsified cutting fluid comprises the following steps:
adding 10 parts by weight of white oil, 3 parts by weight of ZDDP, 0.5 part by weight of benzotriazole and 0.5 part by weight of defoaming agent into a flask, heating to 40 ℃, and stirring for 30min to obtain a first solution.
And adding 19 parts by weight of deionized water and 6 parts by weight of triethanolamine into the other flask, heating to 40 ℃, and stirring for 30min to obtain a second solution.
Pouring the second solution into the first solution, keeping the temperature at 40 ℃, sequentially adding 2 parts by weight of petroleum sodium sulfonate, 5 parts by weight of diethylene glycol monobutyl ether and 805 parts by weight of span into the second solution, and stirring for 30min to obtain a yellowish, semitransparent and uniform cutting fluid mother solution.
Adding 2 parts by weight of cutting fluid mother solution and 38 parts by weight of deionized water into a flask, and uniformly mixing to obtain the semitransparent uniform water-based micro-emulsion cutting fluid.
And testing the tribological performance of the obtained water-based micro-emulsified cutting fluid by using a four-ball friction tester (MS-10A). The steel ball used in the test is
The GCr15 bearing steel ball has the following test conditions: maximum no-seizing load P B The values were determined and the coefficient of friction (COF) was measured at room temperature at a load of 392N, a rotational speed of 1450r/min and a long wear of 30 min. And testing the abrasion spot diameter of the surface of the steel ball by adopting an XDS-0745D optical microscope and a MicroXAM3D non-contact surface tester.
And testing the cutting or deformation process in the metal machining process by adopting a tapping torque testing system. The testing conditions are that the rotating speed is 800r/min, the nut is 6082# aluminum alloy, the inner diameter is 3.7mm, the screw tap is a high-precision yellow titanium plating extrusion screw tap, and the model is TTT _ M4F-TINT.
Maximum non-seizure load P of obtained water-based micro-emulsified cutting fluid B The values are shown in FIG. 1, the friction coefficient is shown in FIG. 2, the tapping torque is shown in FIG. 3, and the wear pattern is shown in FIG. 4.
As shown in figure 1, the maximum non-seizure load of the obtained water-based micro-emulsion cutting fluid can reach 588N, and the water-based micro-emulsion cutting fluid has certain extreme pressure performance. As shown in FIG. 2, the friction coefficient of the obtained water-based microemulsion cutting fluid is 0.078. As shown in FIG. 3, the tapping torque value of the obtained water-based microemulsion cutting fluid is low, which indicates that the obtained water-based microemulsion cutting fluid has certain lubricating property. As shown in FIG. 4, the obtained water-based micro-emulsified cutting fluid has a Wear Scar Diameter (WSD) of 0.566mm, and the wear scar diameter is smaller; in addition, the surface of the grinding spot is smooth and flat.
Example 1
A preparation method of a water-based micro-emulsified cutting fluid comprises the following steps:
2 parts by weight of cutting fluid mother solution (same as comparative example 1), 0.2 part by weight of nano nickel sulfide and 37.8 parts by weight of deionized water are added into a flask, and the materials are uniformly mixed to obtain the semitransparent and uniform water-based micro-emulsified cutting fluid.
The preparation method of the nano nickel sulfide comprises the following steps:
dissolving 2mmol of water-soluble long-chain alkyl potassium xanthate (the number of carbon of long-chain alkyl in the water-soluble long-chain alkyl potassium xanthate is 33) in 150mL of deionized water, and uniformly stirring to obtain a first solution. And dissolving equimolar nickel nitrate into 50mL of deionized water, and uniformly shaking to obtain a second solution. And dropwise adding the second solution into the first solution to obtain a long-chain alkyl nickel xanthate solution with the concentration of 0.01mol/L, thermally decomposing the long-chain alkyl nickel xanthate solution at 80 ℃ for 90min, and extracting and drying to obtain the nano nickel sulfide.
The tribological performance evaluation test conditions of the water-based micro-emulsified cutting fluid are the same as those of comparative example 1. Maximum non-seizure load P of obtained water-based micro-emulsified cutting fluid B The values are shown in FIG. 1, the friction coefficient is shown in FIG. 2, the tapping torque is shown in FIG. 3, and the wear pattern is shown in FIG. 5.
As can be seen from fig. 1: the maximum non-seizure load of the obtained water-based micro-emulsion cutting fluid can reach 1069N, and is greatly improved compared with comparative example 1. As can be seen from fig. 2: the friction coefficient of the obtained water-based micro-emulsified cutting fluid is 0.088 and is always kept below 0.1. As can be seen from fig. 3: compared with the comparative example 1, the tapping torque value of the water-based micro-emulsion cutting fluid containing nickel sulfide is not greatly different, which shows that the obtained water-based micro-emulsion cutting fluid has good lubricating property. As can be seen from fig. 5: the obtained water-based micro-emulsified cutting fluid has a Wear Scar Diameter (WSD) of 0.474mm, a small wear scar diameter and a smooth and flat surface.
The rotational speed of 1200r/min in the tribology performance evaluation test condition in comparative example 1 is set, and the tribology performance of the obtained water-based microemulsion cutting fluid is measured, and the result is shown in fig. 6. As can be seen from fig. 6: the rotating speed is reduced to 1200r/min, the friction coefficient of the water-based microemulsion cutting fluid obtained in example 1 is below 0.1, and the Wear Scar Diameter (WSD) is 0.426mm, which shows that the water-based microemulsion cutting fluid obtained in example 1 has good lubricating property under the test condition of rotating speed reduction. In addition, the diameter of the abrasive grains is reduced along with the reduction of the rotating speed, and the surface is smoother and smoother.
The tribological performance evaluation test condition of example 1 was set to a load of 510N, and the tribological performance of the obtained water-based microemulsion cutting fluid was measured, and the results are shown in FIG. 7. As can be seen from fig. 7: the bearing capacity is increased to 510N, the friction coefficient of the water-based micro-emulsion cutting fluid obtained in the embodiment 1 is still stable and is always kept below 0.1; the Wear Scar Diameter (WSD) is 0.459mm, which shows that the water-based micro-emulsified cutting fluid obtained in example 1 still has good lubricating performance under more severe test conditions. In addition, the diameter of the abrasion spots does not change greatly with the increase of the bearing capacity, and the surface is still smooth and flat.
Fig. 8 is a transmission electron micrograph of the obtained nano nickel sulfide, and it can be seen from fig. 8 that: the particle size of the particles is uniform and no agglomeration phenomenon exists.
Example 2
A preparation method of a water-based micro-emulsified cutting fluid comprises the following steps:
2 parts by weight of cutting fluid mother solution (same as comparative example 1), 0.3 part by weight of nano nickel sulfide (same as example 1) and 37.7 parts by weight of deionized water are added into a flask and uniformly mixed to obtain the semitransparent uniform water-based micro-emulsion cutting fluid.
The tribological performance evaluation test conditions of the water-based micro-emulsified cutting fluid are the same as those of comparative example 1. Maximum non-seizure load P of obtained water-based micro-emulsified cutting fluid B The values are shown in FIG. 1, the friction coefficient is shown in FIG. 2, the tapping torque is shown in FIG. 3, and the wear pattern is shown in FIG. 9.
As shown in figure 1, the maximum non-bite load P of the obtained water-based micro-emulsified cutting fluid B The value is still 1069N. As shown in the figure2, the friction coefficient of the water-based micro-emulsified cutting fluid is 0.091 and is always kept below 0.1. As shown in fig. 3: the tapping torque value of the obtained water-based micro-emulsion cutting fluid is lower than that of the comparative example 1, which shows that the lubricating property of the obtained water-based micro-emulsion cutting fluid is improved. As shown in FIG. 9, the obtained water-based micro-emulsified cutting fluid has a Wear Scar Diameter (WSD) of 0.412mm, a small wear scar diameter and a smooth and flat surface, and is suitable for being used as a metal cutting fluid. Comprehensively, the mass percentage of the nano nickel sulfide in the water-based micro-emulsion cutting fluid is increased to 15%, and the extreme pressure performance, the bearing capacity and the maximum non-seizure load of the water-based micro-emulsion cutting fluid can be effectively improved.
The rotational speed of 1200r/min in the tribology performance evaluation test conditions of example 2 was set, and the tribology performance of the obtained water-based microemulsion cutting fluid was measured, and the results are shown in fig. 10. As can be seen from fig. 10: the rotating speed is reduced to 1200r/min, and the friction coefficient of the water-based micro-emulsion cutting fluid obtained in the example 2 is kept below 0.1; the Wear Scar Diameter (WSD) is 0.446mm, which shows that the water-based micro-emulsified cutting fluid obtained in example 2 has good lubricating property under the test condition of reducing the rotating speed. In addition, the surface of the grinding spot is smooth and flat.
The tribological performance evaluation test condition of example 2 was set to a load of 510N, and the tribological performance of the obtained water-based microemulsion cutting fluid was measured, and the result is shown in FIG. 11. As can be seen from fig. 11: the bearing capacity is increased to 510N, the friction coefficient of the obtained water-based micro-emulsion cutting fluid is still stable and is always kept below 0.1; the Wear Scar Diameter (WSD) is 0.477mm, which shows that the water-based micro-emulsified cutting fluid obtained in example 2 still has good lubricating property under more severe test conditions. In addition, the diameter of the wear point slightly increases with the increase of the bearing capacity, but the surface is still smooth and flat.
Example 3
A preparation method of a water-based micro-emulsified cutting fluid comprises the following steps:
2 parts by weight of cutting fluid mother solution (same as comparative example 1), 0.4 part by weight of nano nickel sulfide (same as example 1) and 37.6 parts by weight of deionized water are added into a flask and uniformly mixed to obtain the semitransparent uniform water-based micro-emulsion cutting fluid.
The tribological performance evaluation test conditions of the water-based micro-emulsified cutting fluid are the same as those of comparative example 1. Maximum non-seizure load P of obtained water-based micro-emulsified cutting fluid B The values are shown in FIG. 1, the friction coefficient is shown in FIG. 2, the tapping torque is shown in FIG. 3, and the wear pattern is shown in FIG. 12.
As shown in figure 1, the maximum non-seizure load P of the obtained water-based micro-emulsified cutting fluid B 1069N may still be achieved. As shown in FIG. 2, the friction coefficient of the obtained water-based microemulsion cutting fluid is 0.075, which is lower than that of the water-based microemulsion cutting fluid obtained in comparative example 1, and the friction coefficient is always kept below 0.1. As shown in FIG. 3, the tapping torque value of the water-based microemulsion cutting fluid containing water-soluble nano nickel sulfide is lower than that of the comparative example 1, which shows that the lubricating property of the obtained water-based microemulsion cutting fluid is better. As shown in fig. 12, the spot diameter (WSD) is 0.498mm, the spot diameter is small, and the surface is smooth and flat, which is suitable for being used as a metal cutting fluid. The comprehensive results show that: the mass percentage of the nano nickel sulfide in the water-based micro-emulsion cutting fluid is increased to 20%, and the extreme pressure performance, the bearing capacity and the maximum non-seizure load of the water-based micro-emulsion cutting fluid can be effectively improved.
Example 4
A preparation method of a water-based micro-emulsified cutting fluid comprises the following steps:
2 parts by weight of cutting fluid mother solution (same as comparative example 1), 0.1 part by weight of nano nickel sulfide (same as example 1) and 37.9 parts by weight of deionized water are added into a flask and uniformly mixed to obtain the semitransparent uniform water-based micro-emulsion cutting fluid.
The tribological performance evaluation test conditions of the water-based micro-emulsified cutting fluid are the same as those of comparative example 1. Maximum non-seizure load P of obtained water-based micro-emulsified cutting fluid B The values are shown in FIG. 1, the friction coefficient graph is shown in FIG. 2, the tapping torque graph is shown in FIG. 3, and the wear pattern graph is shown in FIG. 13.
As shown in FIG. 1, the maximum non-seizure load P of the obtained water-based microemulsified cutting fluid B 755N may be reached. As shown in FIG. 2, the friction coefficient of the obtained water-based microemulsified cutting fluid is 0.081 and is always kept below 0.1. As shown in figure 3, the tapping torque value of the water-based micro-emulsion cutting fluid containing the water-soluble nano nickel sulfide is obviousLower than that in comparative example 1, the lubricating performance of the obtained water-based micro-emulsified cutting fluid is good. As shown in fig. 13, the diameter of the wear mark (WSD) is 0.508mm, the diameter of the wear mark is small, and the surface is smooth and flat, and is suitable for being used as a metal cutting fluid. The comprehensive results show that: the mass percentage of the nano nickel sulfide in the water-based micro-emulsion cutting fluid is reduced to 5%, and the extreme pressure performance, the bearing capacity and the maximum non-seizure load of the water-based micro-emulsion cutting fluid can be improved to a certain extent.
Example 5
A preparation method of a water-based micro-emulsified cutting fluid comprises the following steps:
2 parts by weight of cutting fluid mother solution (same as example 1), 0.06 part by weight of nano nickel sulfide (same as example 1) and 37.94 parts by weight of deionized water are added into a flask and uniformly mixed to obtain the semitransparent uniform water-based micro-emulsion cutting fluid.
The tribological performance evaluation test conditions of the water-based micro-emulsified cutting fluid are the same as those of comparative example 1. Maximum non-seizure load P of obtained water-based micro-emulsified cutting fluid B The values are shown in FIG. 1, the friction coefficient curve is shown in FIG. 2, the tapping torque graph is shown in FIG. 3, and the wear pattern graph is shown in FIG. 14.
As shown in FIG. 1, the maximum non-seizure load P of the obtained water-based microemulsified cutting fluid B 618N may be reached. As shown in FIG. 2, the friction coefficient of the obtained water-based microemulsified cutting fluid is 0.073 and is always kept below 0.1. As shown in FIG. 3, the tapping torque value of the water-based microemulsion cutting fluid containing water-soluble nano nickel sulfide is not much different from that of the comparative example 1, which shows that the obtained water-based microemulsion cutting fluid has certain lubricating property. As shown in fig. 14, the spot diameter (WSD) is 0.490mm, the spot diameter is small, and the surface is smooth and flat, suitable for use as a metal cutting fluid. The comprehensive results show that: the mass percentage of the nano nickel sulfide in the water-based micro-emulsification cutting fluid is reduced to 3%, and the extreme pressure performance, the bearing capacity and the maximum non-seizure load of the water-based micro-emulsification cutting fluid can be effectively improved.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.
Claims (9)
1. The water-based micro-emulsified cutting fluid is characterized by comprising the following components in parts by weight:
2 parts of cutting liquid mother liquor, 0.06-0.4 part of nano nickel sulfide and 37-38 parts of water;
the cutting liquid mother solution comprises the following components in parts by weight:
5-15 parts of base oil, 2-4 parts of zinc dialkyl dithiophosphate, 0.3-0.7 part of benzotriazole, 0.3-0.7 part of defoaming agent, 5-7 parts of organic alcohol amine, 6-10 parts of triton, 1-3 parts of petroleum sodium sulfonate, 4-6 parts of polyether, 4-6 parts of span and 18-20 parts of water;
the nano nickel sulfide is obtained by thermal decomposition of long-chain alkyl nickel xanthate.
2. The water-based microemulsion cutting fluid as claimed in claim 1, wherein the preparation method of the nano nickel sulfide comprises the following steps:
uniformly mixing a long-chain alkyl potassium xanthate aqueous solution and a nickel salt aqueous solution to obtain a long-chain alkyl nickel xanthate solution;
carrying out thermal decomposition on the long-chain alkyl nickel xanthate solution to obtain the nano nickel sulfide;
the concentration of the long-chain alkyl nickel xanthate solution is 0.005-0.015 mol/L.
3. The water-based microemulsion cutting fluid according to claim 1 or 2, wherein the temperature of thermal decomposition is 70-90 ℃ and the time is 80-100 min.
4. The water-based microemulsion cutting fluid according to claim 2, wherein the number of carbons in the long-chain alkyl group in the water-soluble long-chain alkyl potassium xanthate is 10-35; the water-soluble nickel salt comprises one or more of nickel nitrate, nickel chloride, nickel sulfate and nickel acetate.
5. The water-based microemulsion cutting fluid according to claim 2, wherein the molar ratio of the water-soluble nickel salt to the water-soluble long-chain alkyl potassium xanthate is 1:0.5 to 1.5.
6. The water-based microemulsion cutting fluid according to claim 1, wherein the triton comprises triton X-100 and/or triton X-114.
7. The water-based microemulsion cutting fluid of claim 1 wherein the polyether comprises one or more of ethylene glycol monobutyl ether, diethylene glycol butyl ether, and dipropylene glycol butyl ether.
8. The water-based microemulsified cutting fluid according to claim 1, wherein the span comprises one or more of span 20, span 40, span 60 and span 80.
9. The water-based microemulsified cutting fluid according to claim 1, wherein the organic alcohol amine comprises one or more of triisopropanolamine, diethanolamine, and triethanolamine.
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Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1775933A (en) * | 2005-12-15 | 2006-05-24 | 北京交通大学 | Method for preparing nano lubricating fluid comprising oleophilic metal sulfide |
| CN102226123A (en) * | 2011-05-16 | 2011-10-26 | 卓建材 | Dry type lubricant without containing grease, its mother liquor and its preparation method |
| KR101330185B1 (en) * | 2013-04-12 | 2013-12-06 | 주식회사 오일시티 | Additives for engine oil and manufacturing method thereof |
| CN103468382A (en) * | 2013-08-30 | 2013-12-25 | 广州机械科学研究院有限公司 | Boron-free chlorine-free formaldehyde-free microemulsified cutting fluid and application thereof |
| CN104124438A (en) * | 2014-08-12 | 2014-10-29 | 温州大学 | Flower-shaped nickel-tellurium sulfide composite material, preparation method and application thereof |
| CN105861135A (en) * | 2016-04-14 | 2016-08-17 | 上海禾泰特种润滑科技股份有限公司 | Environment-friendly metal cutting liquid and preparing method thereof |
| CN106281630A (en) * | 2016-08-17 | 2017-01-04 | 南通科星化工有限公司 | A kind of micro emulsion cutting fluid and preparation technology thereof |
| CN107384567A (en) * | 2017-08-15 | 2017-11-24 | 肥西县通力机械有限公司 | A kind of ormolu cold stamping high-performance water based lubricating oil |
| CN108384623A (en) * | 2018-03-30 | 2018-08-10 | 天长市润达金属防锈助剂有限公司 | A kind of semi-synthetic metalworking fluid of high-performance environment protection type |
| CN113652292A (en) * | 2021-08-13 | 2021-11-16 | 四川欧力泰尔新材料有限公司 | Preparation method of microemulsion cutting fluid for machining aluminum alloy of aircraft engine |
| CN114276854A (en) * | 2021-12-16 | 2022-04-05 | 东风汽车集团股份有限公司 | Special lubricating grease for guide pin of clamp |
| JP2022071283A (en) * | 2020-10-28 | 2022-05-16 | 日産自動車株式会社 | Slide mechanism |
-
2022
- 2022-12-14 CN CN202211605104.6A patent/CN115786027B/en active Active
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1775933A (en) * | 2005-12-15 | 2006-05-24 | 北京交通大学 | Method for preparing nano lubricating fluid comprising oleophilic metal sulfide |
| CN102226123A (en) * | 2011-05-16 | 2011-10-26 | 卓建材 | Dry type lubricant without containing grease, its mother liquor and its preparation method |
| KR101330185B1 (en) * | 2013-04-12 | 2013-12-06 | 주식회사 오일시티 | Additives for engine oil and manufacturing method thereof |
| CN103468382A (en) * | 2013-08-30 | 2013-12-25 | 广州机械科学研究院有限公司 | Boron-free chlorine-free formaldehyde-free microemulsified cutting fluid and application thereof |
| CN104124438A (en) * | 2014-08-12 | 2014-10-29 | 温州大学 | Flower-shaped nickel-tellurium sulfide composite material, preparation method and application thereof |
| CN105861135A (en) * | 2016-04-14 | 2016-08-17 | 上海禾泰特种润滑科技股份有限公司 | Environment-friendly metal cutting liquid and preparing method thereof |
| CN106281630A (en) * | 2016-08-17 | 2017-01-04 | 南通科星化工有限公司 | A kind of micro emulsion cutting fluid and preparation technology thereof |
| CN107384567A (en) * | 2017-08-15 | 2017-11-24 | 肥西县通力机械有限公司 | A kind of ormolu cold stamping high-performance water based lubricating oil |
| CN108384623A (en) * | 2018-03-30 | 2018-08-10 | 天长市润达金属防锈助剂有限公司 | A kind of semi-synthetic metalworking fluid of high-performance environment protection type |
| JP2022071283A (en) * | 2020-10-28 | 2022-05-16 | 日産自動車株式会社 | Slide mechanism |
| CN113652292A (en) * | 2021-08-13 | 2021-11-16 | 四川欧力泰尔新材料有限公司 | Preparation method of microemulsion cutting fluid for machining aluminum alloy of aircraft engine |
| CN114276854A (en) * | 2021-12-16 | 2022-04-05 | 东风汽车集团股份有限公司 | Special lubricating grease for guide pin of clamp |
Non-Patent Citations (3)
| Title |
|---|
| 张春丽;张晟卯;卢春;吴志申;张平余;: "无溶剂热分解单源前驱体法制备有机单分子层表面修饰NiS纳米微粒", 无机化学学报, no. 03, pages 582 * |
| 熊云;王九;方建华;: "纳米硫化物添加剂在润滑脂中的微动磨损性能", 石油学报(石油加工), no. 1 * |
| 王芳辉;朱红;王滨;郭洪范;: "原位合成油酸修饰纳米硫化镍颗粒及其摩擦学行为研究", 功能材料, no. 01 * |
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