CN1157343C - Process for preparing concentrated Se-contained natural mineral water - Google Patents
Process for preparing concentrated Se-contained natural mineral water Download PDFInfo
- Publication number
- CN1157343C CN1157343C CNB011335572A CN01133557A CN1157343C CN 1157343 C CN1157343 C CN 1157343C CN B011335572 A CNB011335572 A CN B011335572A CN 01133557 A CN01133557 A CN 01133557A CN 1157343 C CN1157343 C CN 1157343C
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- Prior art keywords
- water
- filtered
- selenium
- concentrated solution
- amicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 235000020682 bottled natural mineral water Nutrition 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 42
- 229910001868 water Inorganic materials 0.000 claims abstract description 40
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910052711 selenium Inorganic materials 0.000 claims abstract description 28
- 239000011669 selenium Substances 0.000 claims abstract description 28
- 238000000108 ultra-filtration Methods 0.000 claims abstract description 6
- 229910001385 heavy metal Inorganic materials 0.000 claims abstract description 4
- 244000005700 microbiome Species 0.000 claims abstract description 4
- 238000003828 vacuum filtration Methods 0.000 claims abstract description 4
- 229910052793 cadmium Inorganic materials 0.000 claims abstract description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 230000008030 elimination Effects 0.000 claims description 10
- 238000003379 elimination reaction Methods 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 4
- 241000370738 Chlorion Species 0.000 claims description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 2
- 230000000274 adsorptive effect Effects 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 239000002923 metal particle Substances 0.000 claims description 2
- 238000005325 percolation Methods 0.000 claims description 2
- 229920002492 poly(sulfone) Polymers 0.000 claims description 2
- 229910052573 porcelain Inorganic materials 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 239000010935 stainless steel Substances 0.000 claims description 2
- 230000001954 sterilising effect Effects 0.000 claims description 2
- 238000004659 sterilization and disinfection Methods 0.000 claims description 2
- 238000000967 suction filtration Methods 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 6
- 239000011707 mineral Substances 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 4
- 238000001556 precipitation Methods 0.000 abstract description 2
- 239000011859 microparticle Substances 0.000 abstract 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003337 fertilizer Substances 0.000 abstract 1
- 230000036571 hydration Effects 0.000 abstract 1
- 238000006703 hydration reaction Methods 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 12
- 239000002994 raw material Substances 0.000 description 4
- 235000010755 mineral Nutrition 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 230000032258 transport Effects 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 208000019926 Keshan disease Diseases 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 206010039921 Selenium deficiency Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011026 diafiltration Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001640 fractional crystallisation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000003308 immunostimulating effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 208000019423 liver disease Diseases 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 201000008482 osteoarthritis Diseases 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000006385 ozonation reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
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- Separation Using Semi-Permeable Membranes (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Water Treatment By Sorption (AREA)
Abstract
The present invention provides a technique for processing concentrated natural selenium-containing mineral water, and relates to a technique for concentrating natural selenium-containing mineral water. The present invention has the processing technique that the natural selenium-containing mineral water is coarsely filtered by a ceramic purifier; microparticles with the particle size greater than or equal to 0.1 micrometer in the water is filtered, and is adsorbed and percolated by a filter tank; heavy metal microparticles of chlorine ion, lead, cadmium, etc. in the water can be filtered; microorganisms in the water are filtered again; the water is loaded in an open reaction kettle, and is heated under the condition of temperature control, water vapor is diffused and evaporated by a fan, the water carries out still precipitation and vacuum filtration, hydration microparticles are filtered, and concentrated solution with the selenium of 8000 to 8500 mu g/kg can be prepared after the ultrafiltration. After the concentrated solution is diluted, the concentrated solution can be used as various selenium-enriching drinks, or trace selenium-containing spraying fertilizers for plant leaf surfaces.
Description
Technical field
The present invention relates to a kind of with the high process for preparing concentrated Se-contained natural mineral water of natural selenium spring simmer down to selenium content.
Background technology
Selenium is the important trace element of needed by human, and it can protect diseases such as heart, prevention Keshan disease, Kaschin-Beck disease, hepatopathy and cancer, and human body is had tangible immuno-stimulating effect and anti-aging effects.At present, China and even global many geographic people's selenium intake deficiencies, the human body selenium deficiency is ubiquitous.
The Hubei Province autonomous prefecture that bestows favour is rare in the world high selenium zone, and the content of selenium has 20 μ g/ kilograms in the natural selenium water.Because of the poor transport of Enshi,, must spend a large amount of transportation expenses as will only being that the selenium spring of 20 μ g/ kilograms transports with selenium content.Therefore it is particularly necessary selenium spring to be processed into the concentrated solution of guaranteeing the quality.
The applicant was once making extensive work aspect the processing concentrated solution, and applied for patent, as " natural selenium mineral concentrated water " (number of patent application 9310414. and 98113593.5), its concrete procedure of processing is, with natural selenium mineral water through purify absorption, concentrating and separating, staticly settle, boil, constant volume, packing sterilize concentrated solution.Purifying absorption is to select natural mineral through pulverizing, macerate, cleaning and oxidation, make weak acid (RS) type and weak base (RJ) type sorbent material respectively, in reactor, raw material is carried out negative electrode and anode ionic adsorption reverse osmosis continuous purification, to reduce content and the microorganism and the impurity of harmful element in the raw material.Concentrating and separating system will put in the reactor through the raw material after purifying adsorption treatment, make a large amount of moisture content volatilizations obtain concentrated solution through heating, and concentrated solution is elimination coagulation impurity while hot.Staticly settling is that after-filtration is left standstill in the concentrated solution stirring that will obtain through concentrating and separating, to remove the hydrate crystal precipitation that a part is formed after cooling by hot water dissolving's ion.Boil is that the concentrated solution that will obtain after staticly settling boils, leaves standstill cooling, filters with the fractional crystallization thing.Constant volume system will boil the concentrated solution mensuration that obtains and adjust selenium content and reach the design code standard.
Summary of the invention
Purpose of the present invention aims to provide a kind of selenium content that can make and reaches 800-8500 μ g/ kilogram process for preparing concentrated Se-contained natural mineral water.
The implementation of the object of the invention is, process for preparing concentrated Se-contained natural mineral water, and specific embodiment may further comprise the steps in order:
1) natural selenium spring is through the coarse filtration of porcelain cleaner, in the elimination water 〉=and the particulate of 0.1um,
2) filtered water activated carbon filter pocket adsorptive percolation, chlorion in the elimination water and aluminium, cadmium heavy metal particle,
3) filtered water is filtered with amicon, the microorganism in the elimination water,
4) filtered water is placed uncovered stainless steel cauldron, heat with the steam jacket mode, vapor pressure 0.3Mpa, temperature 60-80 ℃, open-mouth dress axial-flow type electric fan is used to spread the water vapour from uncovered effusion,
5) the condensed water quiescent setting is 24 hours,
6) with vacuum filtration machine suction filtration, the hydrated particulate in the elimination water,
7) filtered water refilters through amicon,
8) ultrafiltration water pot dress fills ozone sterilization simultaneously, gets the concentrated solution that selenium content reaches 8000-8500 μ g/kg.
The present invention is that natural selenium spring filters with amicon through coarse filtration, activated carbon adsorption, diafiltration, filtered water again.It is the tubular fibre amicon that the polysulfone plastic of 5000-8000 is made that amicon adopts by 0.003 micron, molecular weight.Surpass drainage and place uncovered reactor again, heat, spread water vapor, carry out concentrating with respect to boiling for cryogenic wind spreads with fan with the steam jacket mode.Condensed water staticly settles about 24 hours again, vacuum filtration again, heavy metal hydrated particulate such as the calcium in the elimination water, lead, arsenic, mercury, ultra-filtration again.The ultra-filtration water pot is adorned, and fills simultaneously to get the concentrated solution finished product that selenium content reaches 8000-8500 μ g/kg after ozonization is sterilized.The tail water of ultra-filtration returns to staticly settling device again and staticly settles.
With the concentrated solution of the present invention processing, the selenium content height can conveniently transport, the quality better of concentrated solution, and the trace selenium that can make various selenium-rich beverages after the dilution or make plant leaf surface sprays raw material.
Description of drawings
Accompanying drawing is a mechanical flow digram of the present invention.
Claims (3)
1, process for preparing concentrated Se-contained natural mineral water is characterized in that specific embodiment may further comprise the steps in order:
1) natural selenium spring is through the coarse filtration of porcelain cleaner, in the elimination water 〉=and the particulate of 0.1um,
2) filtered water activated carbon filter pocket adsorptive percolation, chlorion in the elimination water and aluminium, cadmium heavy metal particle,
3) filtered water is filtered with amicon, the microorganism in the elimination water,
4) filtered water is placed uncovered stainless steel cauldron, heat with the steam jacket mode, vapor pressure 0.3Mpa, temperature 60-80 ℃, open-mouth dress axial-flow type electric fan is used to spread the water vapour from uncovered effusion,
5) the condensed water quiescent setting is 24 hours,
6) with vacuum filtration machine suction filtration, the hydrated particulate in the elimination water,
7) filtered water refilters through amicon,
8) ultrafiltration water pot dress fills ozone sterilization simultaneously, gets the concentrated solution that selenium content reaches 8000-8500 μ g/kg.
2, concentrated solution complete processing according to claim 1 is characterized in that amicon adopts by 0.003 micron, and molecular weight is the tubular fibre amicon that the polysulfone plastic of 5000-8000 is made.
3, concentrated solution complete processing according to claim 1 is characterized in that returning to the 5th step quiescent setting through the tail water of the described amicon of the 7th step again.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011335572A CN1157343C (en) | 2001-10-15 | 2001-10-15 | Process for preparing concentrated Se-contained natural mineral water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011335572A CN1157343C (en) | 2001-10-15 | 2001-10-15 | Process for preparing concentrated Se-contained natural mineral water |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1356272A CN1356272A (en) | 2002-07-03 |
| CN1157343C true CN1157343C (en) | 2004-07-14 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011335572A Expired - Fee Related CN1157343C (en) | 2001-10-15 | 2001-10-15 | Process for preparing concentrated Se-contained natural mineral water |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1157343C (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100378007C (en) * | 2006-04-30 | 2008-04-02 | 湖南大学 | Method for treating cadmium-containing waste water by intensified ultrafiltration of hollow fiber ultrafiltration membrane and foam floatation |
| CN101560042B (en) * | 2009-05-26 | 2011-12-07 | 吴光辉 | Method for treating municipal sewage and device thereof |
| CN108793464A (en) * | 2018-06-14 | 2018-11-13 | 湖北省恩施天然硒生物科技有限责任公司 | Natural plasma selenium water thickening-purification technology technique |
| CN115121223B (en) * | 2022-06-06 | 2023-07-07 | 湖北省生态环境科学研究院(省生态环境工程评估中心) | High-cadmium biochar-based adsorbent and preparation method thereof |
-
2001
- 2001-10-15 CN CNB011335572A patent/CN1157343C/en not_active Expired - Fee Related
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| Publication number | Publication date |
|---|---|
| CN1356272A (en) | 2002-07-03 |
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Effective date of registration: 20090109 Address after: No. 225, Wuyang Avenue, Enshi, Hubei Patentee after: Enshi Tujia and Miao Autonomous Prefecture Preventive Medicine Association Address before: Hubei Province, Enshi Wuyang Road No. 208 Patentee before: Enshi Tujia Nationality Autonomous Prefecture Medical & Hygenic Apparatus Develo |
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Owner name: ENSHI TUJIA NATIONALITY MIAO NATIONALITY AUTONOMOU Free format text: FORMER OWNER: ENSHI TUJIA NATIONALITY MIAO NATIONALITY AUTONOMOUS PREFECTURE MEDICAL TREATMENT TOILET ARTICLES DEVELOPMENT CO.,LTD. Effective date: 20090109 |
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Owner name: ZHIZHENG INTERNATIONAL ENTERPRISE MANAGEMENT CONSU Free format text: FORMER OWNER: PREVENTIVE MEDICINE ASSOCIATION OF ENSHI TUJIA AND MIAO AUTONOMOUS PREFECTURE Effective date: 20120319 |
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Effective date of registration: 20120319 Address after: 100102 Beijing City, Chaoyang District Wangjing starsource international B block 1702 Patentee after: Wise International Enterprise Management Consultants (Beijing) Limited Address before: 435000 No. 225, Wuyang Avenue, Enshi, Hubei Patentee before: Enshi Tujia and Miao Autonomous Prefecture Preventive Medicine Association |
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Owner name: XIQUANKANG BIO-TECHNOLOGY (BEIJING) CO., LTD. Free format text: FORMER OWNER: ZHIZHENG INTERNATIONAL ENTERPRISE MANAGEMENT CONSULTANT (BEIJING) CO., LTD. Effective date: 20150212 |
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Effective date of registration: 20150212 Address after: 100102 Beijing City, Chaoyang District Wangjing Xiyuan 222 floor 17 room B-1702 Patentee after: Selenium spring Biotechnology (Beijing) Co., Ltd. Address before: 100102 Beijing City, Chaoyang District Wangjing starsource international B block 1702 Patentee before: Wise International Enterprise Management Consultants (Beijing) Limited |
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