CN115684975A - Method and system for quantizing battery micro short circuit based on balanced electric quantity - Google Patents

Method and system for quantizing battery micro short circuit based on balanced electric quantity Download PDF

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CN115684975A
CN115684975A CN202211691908.2A CN202211691908A CN115684975A CN 115684975 A CN115684975 A CN 115684975A CN 202211691908 A CN202211691908 A CN 202211691908A CN 115684975 A CN115684975 A CN 115684975A
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battery
data
short circuit
electric quantity
short
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姜久春
幸小宇
常春
李太宇
代林娜
苏广伟
张震
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Hubei University of Technology
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Abstract

The invention provides a method and a system for quantifying micro short circuit of a battery based on balanced electric quantity, the method comprises the steps of marking the battery with the lowest voltage when two adjacent balances start, researching a topological structure of a battery pack and a balancing scheme to calculate the balanced electric quantity of each battery, calculating a leakage current and a short circuit resistance data set of the marked battery according to the balanced electric quantity, positioning an abnormally aged battery by a 3 sigma rule, rejecting data of the abnormally aged battery, averaging residual data to obtain the abnormally aged batteryI MSC R MSC Finally, judging and calibrating the fault severity of the battery and giving out safety early warning in advance; the invention considers the influence of battery balance and can accurately calculate the micro-short-circuit batteryI MSC AndR MSC the method has the advantages of no manual intervention, strong robustness,whether the battery has micro short circuit or not can be accurately judged, and the false alarm rate is greatly reduced.

Description

Method and system for quantizing battery micro short circuit based on balanced electric quantity
Technical Field
The invention belongs to the technical field of power lithium battery fault diagnosis, and particularly relates to a method and a system for calculating balanced electric quantity after battery charging is finished and quantifying battery micro short circuit based on the balanced electric quantity.
Background
When the market share of new energy automobiles is increased and the number of electric automobiles is rapidly increased, safety accidents of power lithium batteries also frequently occur, life and property safety of people is seriously threatened, and the problem of battery safety becomes a bottleneck problem restricting the development of the electric automobiles. Through analysis, the electric vehicle fire accident is usually caused by thermal runaway caused by internal and external faults occurring in the use process of the battery monomer. The abnormal single batteries are accurately identified and treated earlier before thermal runaway occurs, so that battery safety accidents can be effectively avoided, and the method has great significance for saving lives and preventing property loss.
At present, accurate judgment and quantification of short circuit severity of an internal short circuit battery at a critical value are still the research difficulties for controlling the safety problem of the battery, and on one hand, after the lithium ion battery is loaded and operated, only cell voltage and temperature signals are collected in consideration of cost, and the signals are single; on the other hand, the BMS has an equalization system to eliminate the inconsistency among the batteries, so that the fault information of the micro-short-circuit batteries is hidden, and the detection difficulty is increased.
In the existing technologies, the scheme of balanced quantitative detection of micro short circuit is realized by compensating the original method by considering the calculation of balanced electric quantity. For example, the relation between the Residual Charge Capacity (RCC) and the Equalized Electric Quantity (EEQ) is researched, the electric quantity generated by equalization after charging is calculated to correct the RCC, the leakage current and the short-circuit resistance are obtained through the difference value of the RCC for two times, and finally whether the internal circuit occurs and the severity of the internal short circuit are quantitatively analyzed. The relation between EEQ and SOC difference is also researched, the SOC is corrected through over-balanced electric quantity, and EEQ compensation is carried out on the traditional ISC detection method based on SOC difference to achieve fault detection. The judgment of the micro short circuit has high requirement on the precision of quantitative calculation, the method needs manual intervention, the error of the quantitative micro short circuit is large, and the actual effect is not ideal.
Disclosure of Invention
In view of the above, it is desirable to provide a quantitative battery micro short detection method with a short determination period and a more accurate identification in consideration of battery equalization.
The invention relates to a method for quantizing micro short circuit of a battery based on balanced electric quantity, which comprises the steps of firstly marking the battery with the lowest voltage when two adjacent balances start, researching a topological structure of a battery pack and a balancing scheme to calculate the balanced electric quantity of each battery, calculating and marking a leakage current and short circuit resistance data set of the battery according to the balanced electric quantity, positioning an abnormally aged battery by a 3 sigma rule, removing data of the abnormally aged battery, averaging the rest data to obtain the abnormally aged batteryI MSC 、R MSC Finally, judging and calibrating the fault severity of the battery and giving out safety early warning in advance; the invention specifically comprises the following steps:
a method for quantifying micro short circuit of battery based on equalized electric quantity comprises
Acquiring data and a balancing strategy of all single batteries, and calibrating a fault battery with internal short circuit;
calculating the balance electric quantity, the leakage current and the short circuit internal resistance data of all the batteries for n times according to the balance strategy;
positioning the abnormal aged battery by using a 3 sigma rule according to the data of the leakage resistance and the short-circuit resistance, and rejecting the data to obtain leakage current data and the short-circuit resistance of the marked battery;
and judging and marking the severity of the battery, and performing safety early warning.
In the above method for quantifying micro-short circuit of battery based on equalized electric quantity, the single battery data includes battery charging voltage data
Figure 9899DEST_PATH_IMAGE001
Voltage data at cell equalization
Figure 395881DEST_PATH_IMAGE002
Cell in which equalization occurs
Figure 582143DEST_PATH_IMAGE003
And the time when the equalization takes place and is cut off
Figure 383877DEST_PATH_IMAGE004
In the method for quantifying the micro short circuit of the battery based on the balanced electric quantity, the balancing strategy of the battery is obtained from the BMS system, and the balancing strategy comprises a topological structure and a balancing scheme of the battery; the cells with the lowest voltage at the beginning of the two adjacent balancing n-1 times and n times are fault cells with the possibility of internal short circuit.
In the method for quantizing the battery micro short circuit based on the balanced electric quantity, the balanced electric quantity is based on the voltages at two ends when the batteries are balanced
Figure 401512DEST_PATH_IMAGE005
And calculating the topological structures of the passive balance of different electric vehicles, setting the balance resistance as R, and balancing the battery i, wherein the balance current is calculated by
Figure 707464DEST_PATH_IMAGE006
Formula is obtained, and balance electric quantity is obtained by
Figure 912180DEST_PATH_IMAGE007
Thus obtaining the product.
In the above-mentioned method for quantifying micro-short circuit of battery based on equalized power,
the leakage current is calculated by the formula
Figure 252026DEST_PATH_IMAGE008
In which
Figure 124167DEST_PATH_IMAGE009
In order to be the leakage current data,
Figure 586372DEST_PATH_IMAGE010
for the equalized power amount for the nth time,
Figure 809543DEST_PATH_IMAGE011
the equalization ending time of the N-1 th equalization of the battery i,
Figure 687501DEST_PATH_IMAGE012
the nth equalization end time of the battery i;
short-circuit resistance of battery
Figure 148569DEST_PATH_IMAGE013
Wherein
Figure 778746DEST_PATH_IMAGE014
In order to be a short-circuit resistor,
Figure 489213DEST_PATH_IMAGE015
and marking the average voltage of the battery from the N-1 equalization ending time to the Nth equalization ending time.
In the foregoing method for quantifying micro short circuit of battery based on equalized electric quantity, based on the definition:
the nth equalized electric quantity of the abnormally aged battery is higher than that of the normal battery, and the leakage current is higher
Figure 702020DEST_PATH_IMAGE009
Large data, short circuit resistance
Figure 955278DEST_PATH_IMAGE014
The data is small;
the abnormally aged cell is located using the 3 σ method, as follows:
Figure 493706DEST_PATH_IMAGE016
Figure 691469DEST_PATH_IMAGE017
(3)
Figure 911229DEST_PATH_IMAGE018
(4)
wherein
Figure 84240DEST_PATH_IMAGE019
Figure 324729DEST_PATH_IMAGE020
Is the average of the leakage current and short circuit resistance data,
Figure 744209DEST_PATH_IMAGE021
Figure 564397DEST_PATH_IMAGE022
the standard deviation is used as the standard deviation,
Figure 57827DEST_PATH_IMAGE023
and
Figure 203637DEST_PATH_IMAGE024
the calculated leakage current and short circuit resistance data for all cells,
Figure 110413DEST_PATH_IMAGE025
to calculate the number of short circuit current data.
In the above method for quantifying micro short circuit of battery based on equalized electric quantity, the calculation formula of leakage current and short circuit resistance of the faulty battery obtained by averaging the effective data is as follows:
Figure 999872DEST_PATH_IMAGE026
wherein
Figure 144545DEST_PATH_IMAGE027
And
Figure 661590DEST_PATH_IMAGE028
the calculated leakage current and short circuit resistance data for a normal cell,
Figure 55662DEST_PATH_IMAGE029
is 3 sigmaThe total number of short-circuit current data after the abnormal data is removed is determined by the rule,
Figure 483232DEST_PATH_IMAGE030
and
Figure 13571DEST_PATH_IMAGE031
respectively representing the short-circuit resistance and the leakage current of the faulty battery.
In the above method for quantifying micro short circuit of battery based on equalized electric quantity, the calculated leakage current of the calibration battery is compared with the rated capacity thereof, and the first judgment is made according to the comparison result:
when in use
Figure 173288DEST_PATH_IMAGE032
When the ratio of (A) to (B) is less than or equal to 1/10000, the short circuit is not generated;
when in use
Figure 789077DEST_PATH_IMAGE032
If the ratio of (1/10000) to (1/100) is greater than or equal to the ratio of (1/10000), the battery is determined to have micro short circuit;
when the temperature is higher than the set temperature
Figure 285918DEST_PATH_IMAGE032
When the ratio of (A)/(B) is greater than 1/100, the battery is judged to have a relatively serious internal short circuit.
In the method for quantifying the micro short circuit of the battery based on the balanced electric quantity, the short circuit resistance is calculated and is a comparison result two, the comparison result one and the comparison result two are subjected to combined verification, and the internal short circuit degree is in inverse proportion to the comparison result.
A system for quantifying battery micro-shorts based on equalized electrical quantities, comprising:
a first module: the battery balancing method comprises the steps that the battery balancing method is configured to be used for obtaining all single battery data and balancing strategies and calibrating fault batteries with internal short circuits possibly existing;
a second module: the balancing strategy is configured to calculate balancing electric quantity, leakage current and short-circuit internal resistance data of all the batteries for n times;
a third module: the battery short-circuit detection device is configured to locate the abnormal aged battery by using a 3 sigma rule according to the leakage resistance and short-circuit resistance data, and reject the data to obtain leakage current data and short-circuit resistance of the marked battery;
a fourth module: is configured to judge the severity of the marked battery and perform safety precaution.
The invention can accurately calculate the micro short circuit batteryI MSC AndR MSC and the missing judgment and the misjudgment of the short-circuit battery are reduced, so that the accuracy of battery fault diagnosis can be effectively improved, and the personal safety of a driver and the vehicle running safety are better guaranteed.
Drawings
Fig. 1 is a diagram of a passive equalization topology.
Fig. 2 is a flow chart of a fault diagnosis of a micro-short circuit of a battery based on a quantity of equalized electricity.
Detailed Description
The method for quantitatively analyzing the battery failure provided by the present invention will be described in further detail below.
The method for detecting and diagnosing the fault of the input battery signal comprises the following specific steps:
s1, collecting data of each single battery in the battery charging process, wherein the data comprises battery charging voltage dataU 1 (t)Voltage data at cell equalizationU 2 (t)Cell in which equalization occursC i And time T of occurrence and cut-off of equalization i
S2, acquiring a balancing strategy of the battery, wherein the balancing strategy mainly comprises a topological structure and a balancing scheme of the battery; and calibrating the battery with the lowest voltage at the beginning of two adjacent balances, and recording the balance of the two balances as n-1 and n times respectively.
S3, calculating the balanced electric quantity of all the batteries balanced for the nth time, wherein the step S3 comprises the following steps:
s3.1, balancing electric quantity mainly according to voltage at two ends of battery when battery is balancedU 2 (t)Calculated for different topologies for passive balancing of electric vehicles, e.g. balancing resistance RAt this time, the battery i is balanced, the balancing topological graph is shown in fig. 1, and the specific balancing control strategy is as follows:
(1) Equalization being turned on only after charging has ended
(2) And controlling the starting time of the equalization according to the voltage difference of the batteries, namely starting the equalization when the difference between the battery voltage and the minimum voltage battery is more than 0.02V.
(3) When the voltage difference between the batteries is less than 0.01V or the equalization time period exceeds four hours, the equalization is stopped.
By analyzing the balanced topological structure, the balanced current and the balanced electric quantity of the battery when the balance occurs are obtained by the following formulas:
Figure 670762DEST_PATH_IMAGE033
wherein the content of the first and second substances,
Figure 63698DEST_PATH_IMAGE034
in order to equalize the currents,
Figure 830098DEST_PATH_IMAGE035
in order to equalize the voltage across the battery,
Figure 599471DEST_PATH_IMAGE036
in order to equalize the resistance, the resistance is,
Figure 369981DEST_PATH_IMAGE037
to equalize the electrical quantities. The above-mentioned electricity quantity equalization algorithm is only for the current equalization topological structure, and the equalization electricity quantity can be calculated according to the actual topological structure in the application.
S4, calculating leakage current and short-circuit internal resistance data according to the balance current, wherein the step S4 comprises the following steps:
s4.1, if the balance reference battery is an inner short-circuit battery, balancing electric quantity according to balance
Figure 199396DEST_PATH_IMAGE037
Calculating leakage current and short-circuit resistance data of the short-circuit battery, wherein the calculation formula of the leakage current and the short-circuit resistance is
Figure 196302DEST_PATH_IMAGE038
Wherein
Figure 34945DEST_PATH_IMAGE039
In order to be the leakage current data,
Figure 128803DEST_PATH_IMAGE040
the last equalization end time of the battery i,
Figure 394699DEST_PATH_IMAGE041
and the battery i is the balance finishing time of this time.
Figure 941218DEST_PATH_IMAGE042
In order to be a short-circuit resistor,
Figure 252727DEST_PATH_IMAGE043
is the average voltage of the entire equalization period.
And S4.2, repeating the operation of the S4.1 to obtain leakage current data and short-circuit resistance data of all the short-circuit batteries to all other batteries.
Locating abnormal aged battery by using 3 sigma rule according to data of leakage resistance and short circuit resistance, and removing data to obtain marked battery
Figure 466670DEST_PATH_IMAGE039
And
Figure 637889DEST_PATH_IMAGE042
the step of S5 comprises:
s5.1, positioning the abnormally aged battery by the balance electric quantity, wherein the balance electric quantity of the abnormally aged battery is obviously higher than that of the normal battery by considering the balance strategy because the capacity of the abnormally aged battery is much smaller than that of the normal battery, so that the calculated balance electric quantity is caused
Figure 78228DEST_PATH_IMAGE039
The data will be larger,
Figure 993095DEST_PATH_IMAGE042
The data will be small; by this principle, an abnormally aged battery is located using the 3 σ method, and the formula is as follows:
Figure 61545DEST_PATH_IMAGE044
Figure 669244DEST_PATH_IMAGE017
(3)
Figure 662126DEST_PATH_IMAGE018
(4)
wherein
Figure 583946DEST_PATH_IMAGE045
Figure 38061DEST_PATH_IMAGE046
Is the average of the leakage current and short circuit resistance data,
Figure 551082DEST_PATH_IMAGE047
Figure 825068DEST_PATH_IMAGE048
is the standard deviation of the measured data to be measured,
Figure 753841DEST_PATH_IMAGE049
~
Figure 62463DEST_PATH_IMAGE050
and
Figure 11964DEST_PATH_IMAGE051
~
Figure 773247DEST_PATH_IMAGE052
the calculated leakage current and short circuit resistance data for all cells, the normal short circuit current data are distributed
Figure 33939DEST_PATH_IMAGE053
The probability in the interval is more than 99.7%, and the short circuit resistance data are distributed in
Figure 134751DEST_PATH_IMAGE054
The probability in the interval is also more than 99.7%, so if the calculated short-circuit current exists or the short-circuit resistance is out of the interval, the battery for calculating the data is judged to be an abnormal aging battery, and the short-circuit resistance and the short-circuit current calculated by the balance data are removed.
S5.2, averagely calculating the effective data to obtain the leakage current and the short-circuit resistance of the fault battery according to the following calculation formula:
Figure 255153DEST_PATH_IMAGE055
wherein
Figure 769311DEST_PATH_IMAGE027
And
Figure 633362DEST_PATH_IMAGE028
the calculated leakage current and short circuit resistance data for a normal cell,
Figure 57521DEST_PATH_IMAGE029
the total number of short-circuit current data after abnormal data is removed for the 3 sigma rule,
Figure 348825DEST_PATH_IMAGE030
and
Figure 819121DEST_PATH_IMAGE031
respectively, representing the short-circuit resistance and leakage current of a faulty battery.
S6, the step of judging the severity of the battery comprises the following steps:
and S6.1, comparing the leakage current and the capacity of the battery with the lowest electric quantity, judging the severity of the fault, and performing combined verification by using a short-circuit resistor, wherein the smaller the short-circuit resistor is, the more serious the internal short circuit is. The determination conditions were as follows:
Figure 501511DEST_PATH_IMAGE056
and S7, making safety early warning aiming at the judgment fault.
The invention provides a method for quantifying micro short circuit of a battery based on balanced electric quantity, which comprises the steps of firstly marking the battery with the lowest voltage when two adjacent balances start, researching a topological structure of a battery pack and a balancing scheme to calculate the balanced electric quantity of each battery, calculating and marking a leakage current and short circuit resistance data set of the battery according to the balanced electric quantity, positioning an abnormally aged battery by a 3 sigma rule, rejecting data of the abnormally aged battery, averaging residual data to obtain the abnormally aged battery
Figure 373652DEST_PATH_IMAGE057
Figure 507961DEST_PATH_IMAGE058
Finally, judging and calibrating the fault severity of the battery and giving out safety early warning in advance; the invention can accurately calculate the micro-short circuit battery
Figure 465553DEST_PATH_IMAGE057
And
Figure 405827DEST_PATH_IMAGE058
it is critical to improve the safety of the battery pack product.
In addition, other changes may be made by those skilled in the art of battery technology within the spirit of the invention, and it is intended that the scope of the invention be limited to such changes as fall within the spirit of the invention.

Claims (10)

1. A method for quantizing battery micro short circuit based on balanced electric quantity is characterized by comprising
Acquiring data and a balancing strategy of all single batteries, and calibrating a fault battery with internal short circuit;
calculating the balance electric quantity, the leakage current and the short circuit internal resistance data of all the batteries for n times according to a balance strategy;
positioning the abnormal aged battery by using a 3 sigma rule according to the data of the leakage resistance and the short-circuit resistance, and rejecting the data to obtain leakage current data and the short-circuit resistance of the marked battery;
and judging and marking the severity of the battery, and carrying out safety early warning.
2. The method as claimed in claim 1, wherein the cell data comprises cell charging voltage data
Figure 841642DEST_PATH_IMAGE001
Voltage data at battery equalization
Figure 943591DEST_PATH_IMAGE002
Cell in which equalization occurs
Figure 388478DEST_PATH_IMAGE003
And the time when the equalization takes place and ends
Figure 99820DEST_PATH_IMAGE004
3. The method for quantifying the micro short circuit of the battery based on the equalized electric quantity according to claim 1, wherein the equalization strategy of the battery is obtained from a BMS system, and comprises a topological structure and an equalization scheme of the battery; the cell with the lowest voltage at the beginning of two adjacent equalizations n-1 and n times is the faulty cell where there may be an internal short.
4. The method for quantifying micro-short circuit of battery based on equalized electric quantity according to claim 1, wherein the equalized electric quantity is based on voltage at two ends of battery during equalization
Figure 212133DEST_PATH_IMAGE005
And calculating the topological structures of the passive balance of different electric vehicles, setting the balance resistance as R, and balancing the battery i, wherein the balance current is calculated by
Figure 422665DEST_PATH_IMAGE006
Formula is obtained, and balance electric quantity is obtained by
Figure 886008DEST_PATH_IMAGE007
Thus obtaining the product.
5. The method for quantifying micro-short circuit of battery based on equalized electric quantity according to claim 1,
the leakage current is calculated by the formula
Figure 138391DEST_PATH_IMAGE008
Wherein
Figure 105210DEST_PATH_IMAGE009
In order to be the leakage current data,
Figure 814540DEST_PATH_IMAGE010
for the equalized power amount for the nth time,
Figure 437282DEST_PATH_IMAGE011
at the equalization end time of the N-1 th cell i,
Figure 287164DEST_PATH_IMAGE012
the nth equalization finishing moment of the battery i;
short-circuit resistance of battery
Figure 311752DEST_PATH_IMAGE013
In which
Figure 723142DEST_PATH_IMAGE014
In order to be a short-circuit resistor,
Figure 36443DEST_PATH_IMAGE015
and marking the average voltage of the battery from the N-1 equalization end time to the Nth equalization end time.
6. The method for quantifying the micro-short circuit of the battery based on the equalized electric quantity according to claim 1, wherein the method comprises the following steps based on definition:
the nth equalized electric quantity of the abnormally aged battery is higher than that of the normal battery, and the leakage current is higher
Figure 692945DEST_PATH_IMAGE009
Large data, short circuit resistance
Figure 837619DEST_PATH_IMAGE014
The data is small;
the abnormally aged cell is located using the 3 σ method, as follows:
Figure 154331DEST_PATH_IMAGE016
Figure 282824DEST_PATH_IMAGE017
(3)
Figure 412191DEST_PATH_IMAGE018
(4)
wherein
Figure 208109DEST_PATH_IMAGE019
Figure 164564DEST_PATH_IMAGE020
Is the average of the leakage current and short circuit resistance data,
Figure 311511DEST_PATH_IMAGE021
Figure 462481DEST_PATH_IMAGE022
is the standard deviation of the measured data to be measured,
Figure 112905DEST_PATH_IMAGE023
and
Figure 240261DEST_PATH_IMAGE024
the calculated leakage current and short circuit resistance data for all cells,
Figure 874505DEST_PATH_IMAGE025
to calculate the number of short circuit current data.
7. The method for quantizing the micro short circuit of the battery based on the equalized electric quantity according to claim 1, wherein the calculation formula for the leakage current and the short circuit resistance of the fault battery obtained by averaging the effective data is as follows:
Figure 17779DEST_PATH_IMAGE026
(5)
Figure 991551DEST_PATH_IMAGE027
(6)
wherein
Figure 86546DEST_PATH_IMAGE028
And
Figure 208086DEST_PATH_IMAGE029
the calculated leakage current and short circuit resistance data for a normal cell,
Figure 689139DEST_PATH_IMAGE030
the total number of short-circuit current data after abnormal data is removed for the 3 sigma rule,
Figure 517418DEST_PATH_IMAGE031
and
Figure 783314DEST_PATH_IMAGE032
respectively, representing the short-circuit resistance and leakage current of a faulty battery.
8. The method for quantifying the micro short circuit of the battery based on the equalized electric quantity according to claim 7, wherein the calculated leakage current of the calibrated battery is compared with the rated capacity of the calibrated battery, and the determination of the leakage current is carried out according to the comparison result:
when in use
Figure 860992DEST_PATH_IMAGE033
When the ratio of (A) to (B) is less than or equal to 1/10000, the short circuit is not generated;
when the temperature is higher than the set temperature
Figure 939544DEST_PATH_IMAGE033
If the ratio of (1/10000) to (1/100) is greater than or equal to the ratio of (1/10000), the battery is determined to have micro short circuit;
when the temperature is higher than the set temperature
Figure 356750DEST_PATH_IMAGE033
When the ratio of (A) is more than 1/100, the battery is judged to have a relatively serious internal short circuit.
9. The method for quantifying the micro short circuit of the battery based on the equalized electric quantity according to claim 1, wherein a short circuit resistance is calculated and is a comparison result two, the comparison result one and the comparison result two are subjected to combined verification, and the internal short circuit degree is in inverse proportion to the comparison result.
10. A system for quantifying battery micro-short circuit based on equalized electric quantity is characterized by comprising:
a first module: the battery balancing method comprises the steps that the battery balancing method is configured to be used for obtaining all single battery data and balancing strategies and calibrating fault batteries with internal short circuits possibly existing;
a second module: the method comprises the steps of calculating balanced electric quantity, leakage current and short-circuit internal resistance data of all batteries for n times according to a balancing strategy;
a third module: the battery short-circuit detection device is configured to locate the abnormal aged battery by using a 3 sigma rule according to the leakage resistance and short-circuit resistance data, and reject the data to obtain leakage current data and short-circuit resistance of the marked battery;
a fourth module: is configured to judge the severity of the marked battery and perform safety precaution.
CN202211691908.2A 2022-12-28 2022-12-28 Method and system for quantizing battery micro short circuit based on balanced electric quantity Pending CN115684975A (en)

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