CN115678646A - Diesel engine oil with ultralow-temperature starting performance - Google Patents

Diesel engine oil with ultralow-temperature starting performance Download PDF

Info

Publication number
CN115678646A
CN115678646A CN202210944038.9A CN202210944038A CN115678646A CN 115678646 A CN115678646 A CN 115678646A CN 202210944038 A CN202210944038 A CN 202210944038A CN 115678646 A CN115678646 A CN 115678646A
Authority
CN
China
Prior art keywords
diesel engine
engine oil
temperature
oil
ultra
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202210944038.9A
Other languages
Chinese (zh)
Inventor
沈丽新
朱佳清
潘稼刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Li Guang Tai Fu Suzhou Technology Co ltd
Original Assignee
Li Guang Tai Fu Suzhou Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Li Guang Tai Fu Suzhou Technology Co ltd filed Critical Li Guang Tai Fu Suzhou Technology Co ltd
Priority to CN202210944038.9A priority Critical patent/CN115678646A/en
Publication of CN115678646A publication Critical patent/CN115678646A/en
Pending legal-status Critical Current

Links

Abstract

The invention discloses diesel engine oil with ultralow temperature starting performance, which comprises the following components in parts by weight: 65-70% of third-class hydrogenated base oil; 8-12% of polyol ester; 5-9% of ethylene propylene rubber ester; 8-12% of a composite additive; 0.2 to 0.5 percent of polypropylene polybasic ester; 10-15ppm of methyl silicone oil. The diesel engine oil is prepared by blending high-quality synthetic hydrocarbon base oil with high viscosity index and an additive with extremely strong functions, so that the excellent low-temperature pneumatic performance is achieved, the base oil is investigated and the oil additive is selected, so that the product has the advantages of outstanding cleaning performance, ultra-strong soot holding capacity, excellent wear resistance and excellent low-temperature starting performance, the maneuvering flexibility of operation in severe cold areas is increased, and the operation stability of equipment in the severe cold areas is guaranteed. The product is superior to the standard of the existing diesel engine, has excellent low-temperature starting performance, effectively improves low-temperature power, reduces power consumption, saves energy, increases the benefit of equipment operation, and fills the blank of the diesel engine oil standard.

Description

Diesel engine oil with ultralow-temperature starting performance
Technical Field
The invention relates to the technical field of lubricating oil, in particular to diesel engine oil with ultralow temperature starting performance.
Background
The engine oil, namely engine lubricating oil, can play roles in lubricating, antifriction, auxiliary cooling, temperature reduction, sealing, leakage prevention, rust prevention, corrosion prevention, shock absorption, buffering and the like for the engine. The engine oil consists of base oil and additive. The base oil is the main component of the lubricating oil, the basic properties of the lubricating oil are determined, the additives can make up and improve the deficiency of the base oil in performance, and the additives endow certain new performance and are important components of the lubricating oil.
Diesel engine oil on national defense equipment needs to have lubricating, corrosion-resistant and cleaning and dispersing performances, but cannot be directly started in a severe cold area at minus 40 ℃, needs to be started after being preheated, lacks maneuvering flexibility and affects timely, rapid, maneuvering and lying operation efficiency.
Disclosure of Invention
The invention overcomes the defects of the prior art and provides the diesel engine oil with ultralow temperature starting performance. The diesel engine oil with ultralow-temperature starting performance is prepared by mixing high-quality synthetic hydrocarbon base oil with high viscosity index and an additive with extremely strong function, so that the excellent low-temperature pneumatic performance is achieved, and the product has the advantages of superior cleaning performance, ultra-strong soot containing capacity, excellent wear resistance and excellent low-temperature starting performance through the investigation of the base oil and the selection of the oil additive, the maneuvering flexibility of operation in severe cold areas is increased, and the operation stability of equipment in severe cold areas is ensured.
In order to achieve the purpose, the invention adopts the technical scheme that: the diesel engine oil with ultralow-temperature starting performance is characterized by comprising the following components in parts by weight: 65-70% of three types of hydrogenated base oil; 8-12% of polyol ester; 5-9% of ethylene propylene rubber ester; 8-12% of a composite additive; 0.2 to 0.5 percent of polypropylene polybasic ester; 10-15ppm of methyl silicone oil.
In a preferred embodiment of the present invention, the composite additive comprises: the lubricating oil comprises a viscosity regulator, an antioxidant and an antiwear agent, wherein the viscosity regulator, the antioxidant and the antiwear agent respectively account for 1-2%, 0.3-0.5% and 0.2-2% of the engine oil component.
In a preferred embodiment of the invention, the viscosity regulator is one or a mixture of polyisobutylene, polymethacrylate, olefin copolymer and hydrogenated styrene diene copolymer.
In a preferred embodiment of the invention, the polyol ester is a tetraester of pentaerythritol reacted with a mixture of isononanoic acid and diethyl hexanoic acid, wherein the ratio of isononanoic acid to diethyl hexanoic acid is 3:5.
in a preferred embodiment of the invention, the antiwear agent is selected from one or more of zinc alkyl dithiophosphate, sulfurized isobutylene, dibenzyl disulfide, tricresyl phosphate, triphenyl phosphate and boronated oleamide.
In a preferred embodiment of the invention, the antioxidant is prepared by mixing zinc dialkyl dithiophosphate and a phenolic antioxidant in a mass ratio of 2:1 is prepared by compounding.
In a preferred embodiment of the invention, the antiwear agent is prepared by mixing tricresyl phosphate and sulfurized isobutylene, wherein the tricresyl phosphate and the sulfurized isobutylene are prepared according to the proportion of 5.
In a preferred embodiment of the present invention, the three types of hydrogenated base oils are one or two of 32N three types of hydrogenated base oils or 32NS three types of hydrogenated base oils.
The invention solves the defects in the background art, and has the following beneficial effects:
(1) The product is superior to the standard of the existing diesel engine, has excellent low-temperature starting performance, effectively improves low-temperature power, reduces power consumption, saves energy, increases the benefit of equipment operation, and fills the blank of the diesel engine oil standard. The product standard level meets the quality grade requirement of CF-40W-40 products.
(2) The diesel engine oil with ultralow-temperature starting performance is prepared by blending high-quality synthetic hydrocarbon base oil with high viscosity index and an additive with extremely strong function, so that the excellent low-temperature pneumatic performance is achieved, the base oil is investigated and the oil additive is selected, so that the product has the advantages of superior cleaning performance, ultra-strong soot holding capacity, excellent wear resistance and excellent low-temperature starting performance, the maneuvering flexibility of operation in severe cold areas is increased, and the operation stability of the equipment in the severe cold areas is guaranteed.
(3) The viscosity regulator added in the invention has a long-chain structure, has more interaction points with the three types of hydrogenation base oil molecules, and can well improve the viscosity-temperature performance.
(4) The antioxidant can improve the oxidation stability of the hydrogenated base oil, particularly has a particularly obvious effect on improving three types of 32N hydrogenated base oil, remarkably reduces the increase of the oxidation viscosity of the base oil, effectively controls the increase of the acid value, and reduces the chain transfer of free radicals while decomposing peroxide by compounding the two antioxidants, thereby improving the oxidation resistance of hydraulic oil and reducing the using amount of the antioxidant.
Detailed Description
In order that the above objects, features and advantages of the present invention can be more clearly understood, the present invention will be described in further detail below with reference to specific embodiments. It should be noted that the embodiments and features of the embodiments of the present application may be combined with each other without conflict.
In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present invention, however, the present invention may be practiced in other ways than those specifically described herein, and therefore the scope of the present invention is not limited by the specific embodiments disclosed below.
The diesel engine oil with ultralow temperature starting performance comprises the following components in parts by weight: 65-70% of three types of hydrogenated base oil; 8-12% of polyol ester; 5-9% of ethylene propylene rubber ester; 8-12% of a composite additive; 0.2 to 0.5 percent of polypropylene polybasic ester; 10-15ppm of methyl silicone oil.
The three types of hydrogenated base oil in the invention is one or two of 32N three types of hydrogenated base oil or 32NS three types of hydrogenated base oil. The polyol ester is a tetraester of pentaerythritol reacted with a mixture of isononanoic acid and diethyl hexanoic acid in a ratio of isononanoic acid to diethyl hexanoic acid of 3:5.
the composite additive comprises: viscosity modifier, antioxidant and antiwear agent, wherein the viscosity modifier, antioxidant and antiwear agent respectively account for 1-2%, 0.3-0.5% and 0.2-2% of the engine oil component. The viscosity regulator is one or a mixture of polyisobutylene, polymethacrylate, olefin copolymer and hydrogenated styrene diene copolymer. The viscosity regulator added in the invention has a long-chain structure, has more interaction points with the three types of hydrogenation base oil molecules, and can well improve the viscosity-temperature performance.
The antioxidant is prepared from zinc dialkyl dithiophosphate and a phenolic antioxidant in a mass ratio of 2:1 is prepared by compounding. The antioxidant can improve the oxidation stability of the hydrogenated base oil, particularly has a particularly obvious effect on improving three types of 32N hydrogenated base oil, remarkably reduces the increase of the oxidation viscosity of the base oil, effectively controls the increase of the acid value, and reduces the chain transfer of free radicals while decomposing peroxide by compounding the two antioxidants, thereby improving the oxidation resistance of hydraulic oil and reducing the using amount of the antioxidant.
The antiwear agent is one or more selected from zinc alkyl dithiophosphate, sulfurized isobutylene, dibenzyl disulfide, tricresyl phosphate, triphenyl phosphate and boronized oleamide. The antiwear agent is preferably prepared by mixing tricresyl phosphate and sulfurized isobutylene, wherein the tricresyl phosphate and the sulfurized isobutylene are prepared according to the proportion of 5.
A preparation method of diesel engine oil with ultralow temperature starting performance comprises the following steps:
s1, adding three types of hydrogenated base oil, polyol ester, ethylene propylene rubber ester, polypropylene polyol ester and methyl silicone oil into a reaction kettle, and uniformly stirring at the stirring speed of 200-400r/min for 30-40min;
s2, adding a viscosity regulator, an antioxidant and an antiwear agent into the S1 in sequence, and reacting for 1-2h at 60 ℃;
and S3, adding the antifoaming agent into the S2, continuing stirring for 30min at the stirring speed of 400-500r/min, and filtering at 4 stages to obtain the diesel engine oil with ultralow-temperature starting performance.
Example one
Adding 70 parts of three-class hydrogenated base oil (40 parts and 30 parts of a mixture of 32N three-class hydrogenated base oil or 32NS three-class hydrogenated base oil, respectively), 10 parts of polyol ester, 9 parts of ethylene propylene rubber ester, 0.5 part of polypropylene polyol ester and 0.2 part of methyl silicone oil into a reaction kettle, and uniformly stirring at the stirring speed of 200-400r/min for 30-40min; then adding 10.3 parts of compound additive (3.6 parts of viscosity regulator, 4.3 parts of antioxidant and 2.4 parts of antiwear agent) into the reactant, and reacting for 1-2h at 60 ℃; and adding 0.5 part of antifoaming agent, continuously stirring for 30min at the stirring speed of 400-500r/min, and then filtering and cooling for 4 stages to obtain the diesel engine oil with ultralow temperature starting performance in the embodiment. The physical and chemical properties of the diesel engine oil obtained by the test are shown in the table 1:
table 1 shows the physical and chemical properties of diesel engine oil of example 1 of the present invention
Figure RE-GDA0004016173060000051
The product is superior to the standard of the existing diesel engine, has excellent low-temperature starting performance, effectively improves low-temperature power, reduces power consumption, saves energy, increases the benefit of equipment operation, and fills the blank of the diesel engine oil standard. The product standard grade meets the quality grade requirement of CF-40W-40 products. The diesel engine oil with ultralow-temperature starting performance is prepared by mixing high-quality synthetic hydrocarbon base oil with high viscosity index and an additive with extremely strong function, so that the excellent low-temperature pneumatic performance is achieved, and the product has the advantages of superior cleaning performance, ultra-strong soot containing capacity, excellent wear resistance and excellent low-temperature starting performance through the investigation of the base oil and the selection of the oil additive, the maneuvering flexibility of operation in severe cold areas is increased, and the operation stability of equipment in severe cold areas is ensured.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.

Claims (8)

1. The diesel engine oil with ultralow-temperature starting performance is characterized by comprising the following components in parts by weight: 65-70% of third-class hydrogenated base oil; 8-12% of polyol ester; 5-9% of ethylene propylene rubber ester; 8-12% of a composite additive; 0.2 to 0.5 percent of polypropylene polybasic ester; 10-15ppm of methyl silicone oil.
2. The ultra-low-temperature-start diesel engine oil as set forth in claim 1, wherein: the composite additive comprises: the lubricating oil comprises a viscosity regulator, an antioxidant and an antiwear agent, wherein the viscosity regulator, the antioxidant and the antiwear agent respectively account for 1-2%, 0.3-0.5% and 0.2-2% of the engine oil component.
3. The ultra-low-temperature-start diesel engine oil according to claim 2, characterized in that:
the viscosity regulator is one or a mixture of polyisobutylene, polymethacrylate, olefin copolymer and hydrogenated styrene diene copolymer.
4. The ultra-low-temperature-start diesel engine oil according to claim 1, characterized in that: the polyol ester is a tetraester of pentaerythritol reacted with a mixture of isononanoic acid and diethyl hexanoic acid, wherein the ratio of isononanoic acid to diethyl hexanoic acid is 3:5.
5. the ultra-low-temperature-start diesel engine oil according to claim 2, characterized in that: the antiwear agent is selected from one or more of zinc alkyl dithiophosphate, sulfurized isobutylene, dibenzyl disulfide, tricresyl phosphate, triphenyl phosphate and boronated oleamide.
6. The ultra-low-temperature-start diesel engine oil according to claim 2, characterized in that: the antioxidant is prepared from zinc dialkyl dithiophosphate and a phenolic antioxidant in a mass ratio of 2:1 is prepared by compounding.
7. The ultra-low-temperature-start diesel engine oil according to claim 2, characterized in that: the antiwear agent is prepared by mixing tricresyl phosphate and sulfurized isobutylene, wherein the tricresyl phosphate and the sulfurized isobutylene are prepared according to the proportion of 5.
8. The ultra-low-temperature-start diesel engine oil as set forth in claim 1, wherein: the three types of hydrogenated base oil are one or two of 32N three types of hydrogenated base oil or 32NS three types of hydrogenated base oil.
CN202210944038.9A 2022-08-05 2022-08-05 Diesel engine oil with ultralow-temperature starting performance Pending CN115678646A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210944038.9A CN115678646A (en) 2022-08-05 2022-08-05 Diesel engine oil with ultralow-temperature starting performance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202210944038.9A CN115678646A (en) 2022-08-05 2022-08-05 Diesel engine oil with ultralow-temperature starting performance

Publications (1)

Publication Number Publication Date
CN115678646A true CN115678646A (en) 2023-02-03

Family

ID=85061221

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202210944038.9A Pending CN115678646A (en) 2022-08-05 2022-08-05 Diesel engine oil with ultralow-temperature starting performance

Country Status (1)

Country Link
CN (1) CN115678646A (en)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0588561A1 (en) * 1992-09-14 1994-03-23 Oronite Japan Limited Low phosphorous engine oil compositions and additive compositions
US20030022798A1 (en) * 2001-06-15 2003-01-30 Bell Ian A. W. Lubricating oil compositions
CN101851546A (en) * 2009-03-31 2010-10-06 中国石油化工股份有限公司 Refrigerating machine oil composition
CN104845712A (en) * 2015-04-27 2015-08-19 苏州劲元油压机械有限公司 High-performance anti-wear hydraulic oil and preparation method thereof
CN111849594A (en) * 2020-07-16 2020-10-30 天津内燃机研究所(天津摩托车技术中心) Diesel engine oil and preparation method thereof
CN112725058A (en) * 2019-10-14 2021-04-30 中国石油化工股份有限公司 Low-temperature-resistant diesel engine oil composition
CN113913232A (en) * 2020-07-08 2022-01-11 中国石油化工股份有限公司 Energy-saving low-ash long-oil-change-period diesel engine oil and preparation method and application thereof
CN114717041A (en) * 2021-01-06 2022-07-08 中国石油天然气股份有限公司 Diesel engine oil composition with long oil change period

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0588561A1 (en) * 1992-09-14 1994-03-23 Oronite Japan Limited Low phosphorous engine oil compositions and additive compositions
US20030022798A1 (en) * 2001-06-15 2003-01-30 Bell Ian A. W. Lubricating oil compositions
CN101851546A (en) * 2009-03-31 2010-10-06 中国石油化工股份有限公司 Refrigerating machine oil composition
CN104845712A (en) * 2015-04-27 2015-08-19 苏州劲元油压机械有限公司 High-performance anti-wear hydraulic oil and preparation method thereof
CN112725058A (en) * 2019-10-14 2021-04-30 中国石油化工股份有限公司 Low-temperature-resistant diesel engine oil composition
CN113913232A (en) * 2020-07-08 2022-01-11 中国石油化工股份有限公司 Energy-saving low-ash long-oil-change-period diesel engine oil and preparation method and application thereof
CN111849594A (en) * 2020-07-16 2020-10-30 天津内燃机研究所(天津摩托车技术中心) Diesel engine oil and preparation method thereof
CN114717041A (en) * 2021-01-06 2022-07-08 中国石油天然气股份有限公司 Diesel engine oil composition with long oil change period

Similar Documents

Publication Publication Date Title
CN106701284B (en) Open gear oil composition and preparation method thereof
CN1151243C (en) Universal oil composition for manual speed variator
CN100497562C (en) Combination of general gear oil
CN105073963A (en) Lubricating oil composition for automatic transmission
WO2007115042A2 (en) Lubricant oil additive compositions
CN109679742A (en) A kind of dedicated fluid composition of low viscosity manual transmission
CN105087113A (en) Lubricating oil composition for electric vehicle transmission system
CN107868691A (en) A kind of viscosity rank heavy duty automobile gear oil compositions of 75W 90 and its application
WO2011099207A1 (en) Lubricating oil composition
CN113563941A (en) Preparation method of screw air compressor oil additive for coal CTL base oil
CN113046159A (en) Engine lubricating oil and preparation method thereof
CN111394159A (en) Economical gasoline engine oil SN5W/30 and preparation method thereof
US6063741A (en) Engine oil composition
CN105482869B (en) A kind of anti-friction agent of nitrogenous sulphur molybdenum phosphate and preparation method thereof
CN103642563B (en) A kind of energy-saving complete synthesis automatic transmission transmission fluid and synthetic method thereof
CN104946367A (en) Special lubricating oil for engines and preparation method of special lubricating oil
CN115678646A (en) Diesel engine oil with ultralow-temperature starting performance
CN113930275B (en) Lubricating oil for oil-cooled motor hybrid power reduction gearbox and application thereof
JP4095750B2 (en) Lubricating oil composition for internal combustion engines
CN115261102A (en) Gear lubricating grease and preparation method and application thereof
CN1181168C (en) Engine lubricating oil composition
CN109504515B (en) Energy-saving environment-friendly agricultural machine oil and preparation method thereof
CN111808655A (en) Dispersed acidic amine phosphate extreme pressure antiwear agent and pure electric passenger vehicle transmission system lubricating oil composition
JP2022532907A (en) Low corrosive organic molybdenum compound as a lubricating oil additive
CN113930274B (en) Low-viscosity energy-saving engine oil composition with low-speed pre-ignition control performance

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20230203