CN115672705B - Wool fiber, preparation method thereof and sweater prepared from wool fiber - Google Patents
Wool fiber, preparation method thereof and sweater prepared from wool fiber Download PDFInfo
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Abstract
The application relates to the technical field of textile, and particularly discloses wool fibers, a preparation method thereof and a woolen sweater prepared from the wool fibers, wherein the wool fibers comprise wool fibers and gel films coated on the surfaces of the wool fibers; the application also provides a preparation method of the wool fiber, which comprises the steps of preparing gel liquid, spraying the gel liquid on the surface of the wool fiber, and drying to obtain the wool fiber; according to the application, the gel liquid is sprayed on the surface of the wool fiber to form the wrapped gel film, so that the damage of the wool fiber caused by processing can be effectively avoided, the plasticity and spinnability of the wool fiber are improved, the processing property, mechanical property and health-care property of the wool fiber are improved, and the obtained wool fiber has the advantages of smooth surface, good glossiness, low fineness and soft hand feeling; the woolen sweater made of the wool fiber has the advantages of high comfort, good elasticity, excellent health-care performance and durable wear.
Description
Technical Field
The application relates to the technical field of textile, in particular to wool fibers, a preparation method thereof and a woolen sweater prepared from the wool fibers.
Background
The wool fabric has the advantages of softness, warmth retention, good elasticity and the like, but also has the defects of easy pilling, fulling, deformation and the like. The main reason for the wool fabric to develop fulling is the directional friction effect produced by the wool surface flakes. Under the combined action of wet, heat and mechanical external force, fibers are mutually inserted and entangled, the fabric is felted, the fabric is tightly contracted, the size is changed, and the pile-milling phenomenon is generated. Therefore, the directional friction effect of the wool fibers is reduced, and the wool fiber is a precondition for shrink prevention of wool fabrics.
In the related art, the method for reducing the directional friction effect of the wool fibers mainly comprises a decrement method and an increment method. The method for reducing the scale comprises the steps of peeling the scale, removing all or part of the scale layer on the surface of the wool by corrosion, and specifically comprises a chlorine oxidation method, a potassium permanganate method, an enzyme treatment method and the like. The chloridizing method is used for stripping scales on the surface of the fiber through chloridizing, so that the interaction between a scale layer and the fiber is destroyed, wool velvet is easily damaged, and serious environmental pollution is generated; the potassium permanganate has strong oxidizing capability and is extremely easy to cause damage to wool fibers; and the enzyme treatment method has high operation difficulty, and the enzyme performance and the treatment program are difficult to accurately control. The increment method is to cover the wool scale layer, and the scale layer outside the wool fiber is covered by resin, sol gel, nano particles, ion crystals and the like. The fineness of the wool fiber obtained by the current incremental processing is obviously increased, the uniformity and the straightness of the surface of the wool fiber are poor, and the spinnability and the softness are reduced. In order to overcome the defects of the wool anti-milling treatment process, a wool fiber, a preparation method thereof and a woolen sweater prepared by adopting the wool fiber are urgently needed to be studied.
Disclosure of Invention
In order to solve the problems of great operation difficulty, easy damage to wool fibers, performance reduction and the like in the conventional wool anti-fulling treatment process, the application provides wool fibers, a preparation method thereof and a woolen sweater prepared from the wool fibers.
In a first aspect, the present application provides wool fibers, which adopts the following technical scheme:
the wool fiber comprises wool fiber and a gel film coated on the surface of the wool fiber; the gel film is obtained by spraying gel liquid on the surface of wool fibers and drying; the spraying amount of the gel solution is 5-8% of the mass of wool fibers;
the gel liquid comprises the following raw materials in parts by weight: 50-60 parts of waterborne polyurethane, 3-7 parts of nano zinc oxide, 2-3 parts of nano graphene, 0.1-0.5 part of cellulose ether, 0.1-0.3 part of methylene succinic acid,Polyethylene glycol1-2 parts of potassium silicate, 1-3 parts of water and 22-28 parts of water.
By adopting the technical scheme, the gel liquid is sprayed on the surface of the wool fiber to form the wrapped gel film, so that the damage of the wool fiber caused by processing can be effectively avoided, the plasticity and spinnability of the wool fiber are improved, and the processing performance, mechanical performance and health care performance of the wool fiber are improved.
Preferably, the gel solution comprises the following raw materials in parts by weight: 55 parts of waterborne polyurethane, 6 parts of nano zinc oxide, 2.5 parts of nano graphene, 0.3 part of cellulose ether, 0.2 part of methylene succinic acid, 1.5 parts of polyethylene glycol, 2 parts of potassium silicate and 25 parts of water.
By adopting the technical scheme, the gel liquid is safe in raw material selection, scientific in formula and excellent in comprehensive performance, and the processing performance, mechanical performance and health-care performance of wool fibers can be further improved.
Preferably, the wool fibers are pretreated by the following method:
washing the wool fiber sequentially with absolute ethyl alcohol and deionized water, then carrying out water bath heat treatment, and drying to obtain the pretreated wool fiber.
By adopting the technical scheme, the washing treatment can effectively remove non-fibrous matters on the wool fibers to obtain the high-purity wool fibers, and then the wool fibers are puffed in a water bath, so that the plasticity of the wool fibers in the subsequent processing process is improved.
Preferably, the water bath treatment temperature is 70-80 ℃ and the time is 30-50min.
By adopting the technical scheme, the wool fiber can be prevented from being damaged by water bath heat treatment while good plasticity is ensured to be obtained.
Preferably, the mass ratio of the nano zinc oxide to the nano graphene is 2.4:1.
By adopting the technical scheme, the nano zinc oxide and the nano graphene have excellent performances of thermal insulation, antibiosis, static resistance, ultraviolet radiation resistance and the like; in addition, the nano zinc oxide has good dispersibility and compatibility, the mass ratio of the nano zinc oxide to the nano graphene in the gel film is controlled, the dispersion uniformity of the nano graphene can be remarkably improved, and the comprehensive properties of the wool fiber such as antibacterial property, strength and the like are further improved.
In a second aspect, the application provides a method for preparing wool fibers, which adopts the following technical scheme:
the preparation method of the wool fiber comprises the following steps:
s1, weighing raw material aqueous polyurethane, nano zinc oxide, nano graphene, cellulose ether, methylene succinic acid, polyethylene glycol, potassium silicate and water, and uniformly mixing to obtain gel liquid;
s2, spraying the gel liquid on the surface of the pretreated wool fiber, and drying to obtain the wool fiber.
Preferably, the specific preparation steps of the gel solution in the step S1 are as follows:
s1.1, adding water to disperse nano zinc oxide and nano graphene, and then adding methylene succinic acid and polyethylene glycol to continuously disperse uniformly to obtain a mixed solution;
s1.2, uniformly blending the aqueous polyurethane, cellulose ether, potassium silicate and the mixed solution prepared in the step S1.1 to obtain the gel solution.
Preferably, the dispersion in the step S1.1 specifically means: firstly, under the conditions that the water temperature is 40-60 ℃, the ultrasonic power is 300-400W, the ultrasonic frequency is 22-28kHz, the ultrasonic dispersion is carried out for 15-30min, the nano zinc oxide and the nano graphene are uniformly dispersed, then the methylene succinic acid and the polyethylene glycol are added, the conditions are kept unchanged, and the dispersion is continued for 1-2h, so as to obtain the mixed solution.
Preferably, the blending in step S1.2 specifically refers to: and (3) controlling the stirring speed to be 700-800r/min, adding the cellulose ether, the potassium silicate and the mixed solution prepared in the step S1.1 into the aqueous polyurethane while stirring, and continuously stirring and mixing for 30-50min after the addition is finished, thus obtaining the gel solution.
By adopting the technical scheme, the application adopts the methylene succinic acid and the polyethylene glycol to carry out modification treatment on the nano zinc oxide and the nano graphene, so that the dispersibility and the compatibility of the nano zinc oxide and the nano graphene can be obviously improved, and the obtained gel liquid is used for wool fiber treatment, and can obviously improve the processing property, the mechanical property and the health care property of wool fibers.
Preferably, the spraying in the step S2 specifically means: uniformly spraying gel liquid with the mass of 2-4% of the pretreated wool fiber onto the surface of the pretreated wool fiber, controlling the length to be 110-150% of the original length after stretching at the temperature of 100-120 ℃, performing primary stretching to obtain stretched fiber, uniformly spraying gel liquid with the mass of 3-4% of the pretreated wool fiber onto the surface of the stretched fiber, controlling the stretching temperature to be unchanged, controlling the length to be 110-120% of the original length after stretching, performing secondary stretching, and performing heat preservation and drying after stretching to obtain the wool fiber.
By adopting the technical scheme, the gel liquid is sprayed onto the surface of the pretreated wool fiber twice, and the surface scales of the wool fiber are thinned and the diameter height is obviously reduced by stretching treatment after each spraying, so that the directional friction effect of the wool fiber is greatly reduced; the sprayed gel solution can not only play a role in avoiding fiber damage in the stretching process, but also realize the shaping of the stretched wool fiber, thereby achieving the effects of shrink prevention, pilling resistance, washing resistance and the like.
In a third aspect, the application provides a woolen sweater made of wool fibers, which adopts the following technical scheme:
the woolen sweater is manufactured by weaving the woolen fiber into a garment.
By adopting the technical scheme, the wool fiber prepared by the application has smooth surface, good glossiness, low fineness and soft hand feeling; the woolen sweater has the advantages of excellent shrink resistance, pilling resistance, washing resistance, warmth retention, antibacterial property, static resistance, ultraviolet radiation resistance and the like, and the woolen sweater prepared by the wool fiber has the advantages of high comfort level, good elasticity, excellent health care performance and durability.
In summary, the application has the following beneficial effects:
1. according to the application, the aqueous polyurethane is selected as a main material, the gel solution is obtained by adding and blending the modified nano zinc oxide, nano graphene and other raw materials, and the wool fiber subjected to gel solution spraying treatment has fine hand feeling and good adhesiveness, so that the damage of the wool fiber caused by processing can be effectively avoided, the plasticity and spinnability of the wool fiber are improved, and the processing performance, mechanical performance and health care performance of the wool fiber are improved.
2. According to the application, the gel liquid is sprayed onto the surface of the pretreated wool fiber twice, and the stretching treatment is carried out after each spraying, so that the scales on the surface of the wool fiber are thinned and thinned, the diameter height is obviously reduced, and the directional friction effect of the wool fiber is greatly reduced; the sprayed gel solution can not only prevent fiber damage in the stretching process, but also realize the shaping of the stretched wool fiber, thereby achieving the effects of shrink prevention, pilling resistance, washing resistance and the like.
3. The wool fiber prepared by the method has smooth surface, good glossiness, low fineness and soft hand feeling; the woolen sweater has the advantages of excellent shrink resistance, pilling resistance, washing resistance, warmth retention, antibacterial property, static resistance, ultraviolet radiation resistance and the like, and the woolen sweater prepared by the wool fiber has the advantages of high comfort level, good elasticity, excellent health care performance and durability.
Detailed Description
The present application will be described in further detail with reference to examples.
Preparation examples 1 to 7 and comparative preparation examples 1 to 3 provide gel solutions and preparation methods thereof, and are described below by taking preparation example 1 as an example.
Preparation example 1
The gel liquid comprises the following raw materials: 50Kg of waterborne polyurethane, 3Kg of nano zinc oxide, 2Kg of nano graphene, 0.1Kg of cellulose ether, 0.1Kg of methylene succinic acid, 1Kg of polyethylene glycol, 1Kg of potassium silicate and 22Kg of water; wherein, the aqueous polyurethane is kesi aqueous polyurethane DL1099.
The concrete preparation steps of the gel liquid are as follows:
s1.1, firstly, under the conditions that the water temperature is 40 ℃, the ultrasonic power is 300W, the ultrasonic frequency is 22kHz, ultrasonic dispersion is carried out for 30min, nano zinc oxide and nano graphene are uniformly dispersed, then methylene succinic acid and polyethylene glycol are added, the conditions are kept unchanged, and dispersion is continued for 1h, so that a mixed solution is obtained;
s1.2, controlling the stirring speed to be 700r/min, adding the cellulose ether, the potassium silicate and the mixed solution prepared in the step S1.1 into the aqueous polyurethane while stirring, and continuously stirring and mixing for 50min after the addition is finished, thus obtaining the gel solution.
Preparation examples 2 to 3 are identical to preparation example 1, except that the raw material amounts of the gel solutions are different, specifically in Table 1 below.
Raw material consumption/Kg | Preparation example 1 | Preparation example 2 | Preparation example 3 |
Water-based polyurethane | 50 | 55 | 60 |
Nano zinc oxide | 3 | 6 | 7 |
Nano graphene | 2 | 2.5 | 3 |
Cellulose ether | 0.1 | 0.3 | 0.5 |
Methylene succinic acid | 0.1 | 0.2 | 0.3 |
Polyethylene glycol | 1 | 1.5 | 2 |
Potassium silicate | 1 | 2 | 3 |
Water and its preparation method | 22 | 25 | 28 |
Preparation examples 4 to 5, which differ from preparation example 2 only in the preparation conditions of the gel solution, are shown in Table 2 below.
Preparation example 6 is identical to preparation example 4, except that the total amount of nano zinc oxide and nano graphene is unchanged, and the mass ratio of nano zinc oxide to nano graphene is 2:1.
Preparation example 7 is identical to preparation example 4, except that the total amount of nano zinc oxide and nano graphene is unchanged, and the mass ratio of nano zinc oxide to nano graphene is 3:1.
Comparative preparation 1, which is identical to preparation 4, differs only in that the quality of nano zinc oxide and the like is replaced with nano graphene.
Comparative preparation 2 the same as preparation 4, except that the quality of nano graphene was replaced with nano zinc oxide.
Comparative preparation 3, which differs from preparation 4 only in that the specific preparation steps of the gel solution are:
s1.1, firstly, under the conditions that the water temperature is 50 ℃, the ultrasonic power is 350W, and the ultrasonic frequency is 25kHz, carrying out ultrasonic dispersion for 112min, and uniformly dispersing nano zinc oxide and nano graphene;
s1.2, controlling the stirring speed to be 750r/min, adding cellulose ether, methylene succinic acid, polyethylene glycol, potassium silicate and the dispersion liquid prepared in the step S1.1 into the aqueous polyurethane while stirring, and continuously stirring and mixing for 40min after the addition is finished to obtain the gel liquid.
Examples 1-9 provide wool fibers and methods for making the same, as exemplified by example 1 below.
The wool fiber comprises wool fiber and gel film coated on the surface of the wool fiber.
The preparation method of the wool fiber specifically comprises the following preparation steps:
s2.1, washing sheep wool fiber raw materials with average diameter of 25 mu m with absolute ethyl alcohol and deionized water in sequence, then carrying out water bath heat treatment, wherein the water bath heat treatment temperature is 70 ℃, the time is 50min, and carrying out heat preservation and drying to obtain pretreated wool fibers;
s2.2, uniformly spraying gel liquid accounting for 2% of the mass of the pretreated wool fiber on the surface of the pretreated wool fiber, controlling the length to be 110% of the original length after stretching at the temperature of 100 ℃, performing primary stretching to obtain stretched fiber, uniformly spraying gel liquid accounting for 3% of the mass of the pretreated wool fiber on the surface of the stretched fiber, controlling the stretching temperature to be unchanged, performing secondary stretching, and performing heat preservation and drying after stretching is completed to obtain the wool fiber, wherein the gel liquid is the gel liquid in preparation example 1.
Examples 2-3 differ from example 1 only in the preparation conditions of the wool fibers, see in particular table 3 below.
Example 4 was identical to example 2 except that the gel solution was the gel solution of preparation example 2.
Example 5 is identical to example 2 except that the gel solution is the gel solution of preparation example 3.
Example 6 is identical to example 2 except that the gel solution is the gel solution of preparation example 4.
Example 7 is identical to example 2 except that the gel solution is the gel solution of preparation example 5.
Example 8 differs from example 2 only in that the gel solution is the gel solution in preparation example 6.
Example 9 was identical to example 2 except that the gel solution was the one in preparation example 7.
To verify the overall properties of the wool fibers produced in examples 1-9 of the present application, the applicant set comparative examples 1-6, which are specifically as follows:
comparative example 1 was identical to example 2 except that the gel solution was the gel solution of comparative preparation example 1.
Comparative example 2 was identical to example 2 except that the gel solution was the gel solution in comparative preparation example 2.
Comparative example 3 differs from example 2 only in that the gel solution is the gel solution in comparative preparation example 3.
Comparative example 4, which is identical to example 2 except that the wool fiber is not pretreated, that is, the gel solution of 3% of the mass of the wool fiber is directly sprayed onto the surface of the wool fiber uniformly, the length of the drawn wool fiber is controlled to be 130% of the original length at 110 ℃, the drawn wool fiber is obtained by first drawing, the gel solution of 3.5% of the mass of the pretreated wool fiber is sprayed onto the surface of the drawn wool fiber uniformly, the drawing temperature is controlled to be unchanged, the length of the drawn wool fiber is 115% of the original length, the second drawing is performed, and the wool fiber is obtained by heat preservation and drying after the drawing is completed, wherein the gel solution is the gel solution in preparation example 1.
Comparative example 5, which is different from example 2 only in that only one spraying and one stretching treatment is performed, namely, a gel solution with a mass of 6.5% of that of the wool fiber is uniformly sprayed on the surface of the pretreated wool fiber, the length after stretching is controlled to 145% of the original length at 110 ℃, one stretching is performed to obtain a stretched fiber, the temperature is controlled to be unchanged, and the wool fiber is obtained by heat preservation and drying, wherein the gel solution is the gel solution in preparation example 1.
Comparative example 6, which is identical to example 2, differs only in that the pretreated wool fiber is stretched and then subjected to gel spray coating, i.e., the pretreated wool fiber is placed at 110 ℃ and stretched at a length of 145% of the original length to obtain a stretched fiber, the gel liquid of which the mass is 6.5% of that of the wool fiber is uniformly sprayed onto the surface of the stretched fiber, the temperature is controlled to be unchanged, and the wool fiber is obtained by heat preservation and drying, wherein the gel liquid is the gel liquid in preparation example 1.
Performance detection
Directional friction effect measurement of wool fibers
Before testing, wool fiber samples in examples 1-9 and comparative examples 1-6 of the application are balanced for 24 hours under standard atmospheric conditions, a Y151 type fiber friction coefficient tester is used according to a winch method, 200mg (f 0) tension clamps are clamped at two ends of a fiber to be tested, the rotating speed of a metal roller is regulated to be 30r/min, a torsion balance reading m is read, each sample is tested for 3 times, 50 samples of each group of wool fiber samples are subjected to friction coefficient measurement, an average value is obtained, and the dynamic friction coefficient between the wool fiber and the metal roller is calculated:
μ=[lgf0-lg(f0-m)]/1.364;
the tip and the root of the wool fiber are separated, the forward friction force and the reverse friction force are respectively measured, the forward friction coefficient (mu w) and the reverse friction coefficient (mu a) are calculated, and then the Directional Friction Effect (DFE) is obtained;
DEF=(μa-μw)/(μa+μw)*100%。
antibacterial property test of wool fiber
Antibacterial Properties of wool fiber samples in examples 1 to 9 and comparative examples 1 to 6 of the present application (refer to GB/T20944.3-2008, evaluation of antibacterial Properties of textiles section 3: vibration method, test bacteria are Staphylococcus aureus and Escherichia coli).
Wool fiber breaking strength test
The wool fiber samples of examples 1 to 9 and comparative examples 1 to 6 of the present application were tested on a tensile tester with a holding length of 180mm and a tensile speed of 100mm/min, and 50 samples of each group of wool fiber samples were sampled for breaking strength test and averaged.
The results of the above performance tests are shown in Table 4 below.
The results shown in Table 4 above indicate that: the wool fibers prepared in the embodiments 1-9 of the application have low directional friction effect, and the comprehensive properties such as antibacterial property, breaking strength and the like are obviously superior to those of the wool fibers prepared in the comparative examples 1-6 and untreated wool fiber raw materials;
in combination with examples 6 and 8-9 and comparative examples 1-2, it is known that in the process of preparing the gel solution, under the condition that the total addition amount is kept unchanged, the mixture of nano zinc oxide and nano graphene is added, and compared with the single addition of nano zinc oxide or nano graphene, the obtained wool fiber has better comprehensive performance, and the comprehensive performance of the finally prepared wool fiber can be further improved by controlling the mass ratio of nano zinc oxide to nano graphene, wherein when the mass ratio of nano zinc oxide to nano graphene in example 4 is 2.4:1, the prepared final wool fiber has the lowest directional friction effect, and has the best antibacterial property and breaking strength;
as can be seen from the combination of example 2 and comparative example 3, in the process of preparing the gel liquid, the modification treatment of nano zinc oxide and nano graphene is performed in advance by selecting methylene succinic acid and polyethylene glycol, so that the comprehensive performance of the finally prepared wool fiber can be remarkably improved; as can be seen from the combination of example 2 and comparative example 4: the raw material of the wool fiber is pretreated, so that the plasticity of the raw material of the wool fiber in the subsequent processing process can be improved, and the comprehensive performance of the finally obtained wool fiber is further improved;
it can be seen from the combination of example 2 and comparative examples 5 to 6 that: the gel liquid is sprayed on the surface of the pretreated wool fiber twice, and the surface scales of the wool fiber are thinned and the diameter height is obviously reduced by stretching after each spraying, so that the directional friction effect of the obtained wool fiber is greatly reduced, and the breaking strength of the wool fiber is improved.
The present embodiment is only for explanation of the present application and is not to be construed as limiting the present application, and modifications to the present embodiment, which may not creatively contribute to the present application as required by those skilled in the art after reading the present specification, are all protected by patent laws within the scope of claims of the present application.
Claims (4)
1. The wool fiber is characterized by comprising wool fiber and a gel film coated on the surface of the wool fiber; the gel film is obtained by spraying gel liquid on the surface of wool fibers and drying; the spraying amount of the gel solution is 5-8% of the mass of wool fibers; the gel liquid comprises the following raw materials in parts by weight: 50-60 parts of waterborne polyurethane, 3-7 parts of nano zinc oxide, 2-3 parts of nano graphene, 0.1-0.5 part of cellulose ether, 0.1-0.3 part of methylene succinic acid, 1-2 parts of polyethylene glycol, 1-3 parts of potassium silicate and 22-28 parts of water; the mass ratio of the nano zinc oxide to the nano graphene is 2.4:1;
the preparation steps of the gel solution are as follows: s1, adding water to disperse nano zinc oxide and nano graphene, and then adding methylene succinic acid and polyethylene glycol to continuously disperse uniformly to obtain a mixed solution; s2, uniformly blending the aqueous polyurethane, the cellulose ether, the potassium silicate and the mixed solution prepared in the step S1 to obtain a gel solution; the dispersion in the step S1 specifically means: firstly, under the conditions that the water temperature is 40-60 ℃, the ultrasonic power is 300-400W, the ultrasonic frequency is 22-28kHz, the ultrasonic dispersion is carried out for 15-30min, nano zinc oxide and nano graphene are uniformly dispersed, then methylene succinic acid and polyethylene glycol are added, the conditions are kept unchanged, and the dispersion is continued for 1-2h, so as to obtain a mixed solution; the blending in the step S2 specifically means: controlling the stirring speed to be 700-800r/min, adding cellulose ether, potassium silicate and the mixed solution prepared in the step S1 into the aqueous polyurethane while stirring, and continuously stirring and mixing for 30-50min after the addition is finished to obtain gel solution;
the wool fiber is pretreated by the following method: washing wool fibers sequentially with absolute ethyl alcohol and deionized water, then carrying out water bath heat treatment, and drying to obtain pretreated wool fibers;
the spraying specifically refers to: uniformly spraying gel liquid with the mass of 2-4% of the pretreated wool fiber onto the surface of the pretreated wool fiber, controlling the length to be 110-150% of the original length after stretching at the temperature of 100-120 ℃, performing primary stretching to obtain stretched fiber, uniformly spraying gel liquid with the mass of 3-4% of the pretreated wool fiber onto the surface of the stretched fiber, controlling the stretching temperature to be unchanged, controlling the length to be 110-120% of the original length after stretching, performing secondary stretching, and performing heat preservation and drying after stretching to obtain the wool fiber.
2. Wool fiber according to claim 1, wherein the water bath treatment temperature is 70-80 ℃ for 30-50min.
3. A method for producing wool fibers according to any one of claims 1 to 2, comprising the steps of:
s1, weighing raw material aqueous polyurethane, nano zinc oxide, nano graphene, cellulose ether, methylene succinic acid, polyethylene glycol, potassium silicate and water, and uniformly mixing to obtain gel liquid;
s2, spraying the gel solution on the surface of the pretreated wool fiber, and drying to obtain the wool fiber;
the concrete preparation steps of the gel solution are as follows:
s1.1, adding water to disperse nano zinc oxide and nano graphene, and then adding methylene succinic acid and polyethylene glycol to continuously disperse uniformly to obtain a mixed solution;
s1.2, uniformly blending the aqueous polyurethane, cellulose ether, potassium silicate and the mixed solution prepared in the step S1.1 to obtain a gel solution; the dispersion in step S1.1 specifically means: firstly, under the conditions that the water temperature is 40-60 ℃, the ultrasonic power is 300-400W, the ultrasonic frequency is 22-28kHz, the ultrasonic dispersion is carried out for 15-30min, nano zinc oxide and nano graphene are uniformly dispersed, then methylene succinic acid and polyethylene glycol are added, the conditions are kept unchanged, and the dispersion is continued for 1-2h, so as to obtain a mixed solution;
the blending in the step S1.2 specifically refers to: controlling the stirring speed to be 700-800r/min, adding cellulose ether, potassium silicate and the mixed solution prepared in the step S1.1 into the aqueous polyurethane while stirring, and continuously stirring and mixing for 30-50min after the addition is finished to obtain gel solution;
the spraying in the step S2 specifically refers to: uniformly spraying gel liquid with the mass of 2-4% of the pretreated wool fiber onto the surface of the pretreated wool fiber, controlling the length to be 110-150% of the original length after stretching at the temperature of 100-120 ℃, performing primary stretching to obtain stretched fiber, uniformly spraying gel liquid with the mass of 3-4% of the pretreated wool fiber onto the surface of the stretched fiber, controlling the stretching temperature to be unchanged, controlling the length to be 110-120% of the original length after stretching, performing secondary stretching, and performing heat preservation and drying after stretching to obtain the wool fiber.
4. A sweater made with the wool fiber of any one of claims 1-2.
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