CN110241477A - Antibacterial pro-skin polypropylene filament yarn and preparation method thereof - Google Patents
Antibacterial pro-skin polypropylene filament yarn and preparation method thereof Download PDFInfo
- Publication number
- CN110241477A CN110241477A CN201910639082.7A CN201910639082A CN110241477A CN 110241477 A CN110241477 A CN 110241477A CN 201910639082 A CN201910639082 A CN 201910639082A CN 110241477 A CN110241477 A CN 110241477A
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- Prior art keywords
- parts
- skin
- filament yarn
- polypropylene filament
- antibacterial pro
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention provides a kind of antibacterial pro-skin polypropylene filament yarns, it comprises the following components in parts by weight: 80-120 parts of PP, poly- hydroxyl acrylic resin 10-30 parts, 1-3 parts of silane coupling agent, 1-3 parts of talcum powder, 5-10 parts of carbon nanotube, 1-5 parts of nano phase ag_2 o, 0.5-3 parts of ceramic powder, 1-4 parts of nano zine oxide, 5-10 parts of nanometer grade calcium carbonate.Antibacterial pro-skin polypropylene filament yarn provided by the invention, it can be in the case where not changing polypropylene fiber physicochemical characteristics, have good hygroscopicity and fungistatic effect, improve comfort, the skin-friendly of polypropylene fiber fabric, can be used for making the clothes of directly contact skin or skin-proximal dress.And technical maturity, easy to spread, market prospects are very considerable.
Description
Technical field:
The present invention relates to polypropylene spinning technical fields more particularly to a kind of antibacterial pro-skin polypropylene filament yarn and preparation method thereof.
Background technique:
Polypropylene (PP) is as one kind has excellent performance, is nontoxic, is heat-resisting, chemical-resistant resistance, being easily worked molding, cost is relatively low
Thermoplastic, it is long fine and in terms of be widely applied.Since polypropylene fiber manufacturing cost is low, have excellent
Good physical and chemical performance and rapidly developed, but existing polypropylene fiber generally antibacterial skin-friendly is poor at present, is making
It is poor compared with natural fiber on comfort when underwear etc. directly contacts the clothes that skin or skin-proximal are worn and easy to breed thin
Bacterium, thus affect its application on textile fabric.
Summary of the invention:
The purpose of the present invention is in view of the drawbacks of the prior art, provide a kind of antibacterial pro-skin third for being able to solve the above problem
Synthetic fibre long filament and preparation method thereof.
Realizing the technical solution of the object of the invention is: a kind of antibacterial pro-skin polypropylene filament yarn, it is described by following parts by weight at
It is grouped as:
80-120 parts of PP, poly- hydroxyl acrylic resin 10-30 parts, 1-3 parts of silane coupling agent, 1-3 parts of talcum powder, carbon
5-10 parts of nanotube, 1-5 parts of nano phase ag_2 o, 0.5-3 parts of ceramic powder, 1-4 parts of nano zine oxide, nanometer grade calcium carbonate 5-10
Part.
In a preferred embodiment of the present invention, the antibacterial pro-skin polypropylene filament yarn prepares material preferably by following parts by weight
At being grouped as:
100 parts of PP, 25 parts of poly- hydroxyl acrylic resin, 2 parts of silane coupling agent, 1.5 parts of talcum powder, carbon nanotube 8
Part, 4 parts of nano phase ag_2 o, 1 part of ceramic powder, 3 parts of nano zine oxide, 6 parts of nanometer grade calcium carbonate.
Preferably, the silane coupling agent is vinyltriethoxysilane or vinyltrimethoxysilane.
Preferably, the poly- hydroxyl acrylic resin is hydroxyethyl acrylate, polyhydroxypropyl acrylate, polypropylene
One of sour hydroxy butyl ester, polyacrylic acid caprolactone or multiple combinations.
The present invention also provides a kind of production methods of antibacterial pro-skin polypropylene filament yarn, include the following steps:
(1) by quantitative PP, poly- hydroxyl acrylic resin, silane coupling agent, talcum powder, carbon nanotube is nano oxidized
Silver, ceramic powder, nano zine oxide, nanometer grade calcium carbonate are added to the mixer, and are uniformly mixed with the speed of 350-360r/min,
Obtain mixture；
(2) it by double screw extruder, is granulated in 220-230 DEG C of technological temperature bottom brace, obtains mangcorn；
(3) by spinning equipment, 240-250 DEG C at a temperature of, with 1500-2500 ms/min of speed melt spinning, most
Antibacterial pro-skin polypropylene filament yarn is obtained eventually.
The beneficial effects of the present invention are:
A kind of antibacterial pro-skin polypropylene filament yarn provided by the invention, can be in the feelings for not changing polypropylene fiber physicochemical characteristics
Under condition, have good hygroscopicity and fungistatic effect, improves comfort, the skin-friendly of polypropylene fiber fabric, can be used for
Production directly contacts the clothes of skin or skin-proximal dress.And technical maturity, easy to spread, market prospects are very considerable.
Specific embodiment:
The preferred embodiments of the present invention will be described in detail below, so that advantages and features of the invention can be easier to by this
Field personnel understanding, so as to make a clearer definition of the protection scope of the present invention.
Embodiment 1
A kind of antibacterial pro-skin polypropylene filament yarn, prepares material and comprises the following components in parts by weight:
100 parts of PP, 25 parts of polyhydroxypropyl acrylate, 2 parts of vinyltriethoxysilane, 1.5 parts of talcum powder, carbon nanometer
8 parts of pipe, 4 parts of nano phase ag_2 o, 1 part of ceramic powder, 3 parts of nano zine oxide, 6 parts of nanometer grade calcium carbonate.
Embodiment 2
A kind of antibacterial pro-skin polypropylene filament yarn, prepares material and comprises the following components in parts by weight:
80 parts of PP, 15 parts of hydroxyethyl acrylate, 1 part of vinyltrimethoxysilane, 1 part of talcum powder, carbon nanotube 7
Part, 1 part of nano phase ag_2 o, 0.5 part of ceramic powder, 1 part of nano zine oxide, 5 parts of nanometer grade calcium carbonate.
Embodiment 3
A kind of antibacterial pro-skin polypropylene filament yarn, prepares material and comprises the following components in parts by weight:
120 parts of PP, 10 parts of polyacrylic acid hydroxy butyl ester, 3 parts of vinyltriethoxysilane, 3 parts of talcum powder, carbon nanotube 5
Part, 5 parts of nano phase ag_2 o, 2 parts of ceramic powder, 4 parts of nano zine oxide, 10 parts of nanometer grade calcium carbonate.
Embodiment 4
A kind of antibacterial pro-skin polypropylene filament yarn, prepares material and comprises the following components in parts by weight:
90 parts of PP, 30 parts of polyacrylic acid caprolactone, 2 parts of vinyltrimethoxysilane, 2 parts of talcum powder, carbon nanotube 10
Part, 2 parts of nano phase ag_2 o, 3 parts of ceramic powder, 2 parts of nano zine oxide, 8 parts of nanometer grade calcium carbonate.
The production method of the antibacterial pro-skin polypropylene filament yarn of the various embodiments described above, includes the following steps:
(1) by quantitative PP, poly- hydroxyl acrylic resin, silane coupling agent, talcum powder, carbon nanotube is nano oxidized
Silver, ceramic powder, nano zine oxide, nanometer grade calcium carbonate are added to the mixer, and are uniformly mixed with the speed of 350-360r/min,
Obtain mixture；
(2) it by double screw extruder, is granulated in 220-230 DEG C of technological temperature bottom brace, obtains mangcorn；
(3) by spinning equipment, 240-250 DEG C at a temperature of, with 1500-2500 ms/min of speed melt spinning, most
Antibacterial pro-skin polypropylene filament yarn is obtained eventually.
The performance of fabric prepared by antibacterial pro-skin polypropylene filament yarn of the present invention is tested by the following method, and testing result is shown in Table
1。
(1) hydroscopicity
It takes sample 16 hours dry in 105 DEG C, measures weight (W1)；Then it is 20 DEG C that the sample after drying, which is placed in temperature,
It is placed 24 hours in the constant temperature and humidity machine that relative humidity is 65%, measures example weight (W2), be then calculated as follows out and be saturated
Hydroscopicity (%):
Hydroscopicity (%)=(W2-W1)/W1*100%
(2) biocidal property
The biocidal property is tested using 20944.3 succusion of GB/T.Bacterium: staphylococcus aureus, Escherichia coli is used in detection
It is antibacterial.
Table 1
It can be obtained by table 1, antibacterial pro-skin polypropylene filament yarn good hygroscopicity of the present invention, make one to feel soft not stiff when contacting skin
Firmly, skin-friendly is good, and has good antibacterial effect.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously
It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art
It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to protection of the invention
Range.
Claims (5)
1. a kind of antibacterial pro-skin polypropylene filament yarn, it is characterised in that: the polypropylene filament yarn comprises the following components in parts by weight:
80-120 parts of PP, poly- hydroxyl acrylic resin 10-30 parts, 1-3 parts of silane coupling agent, 1-3 parts of talcum powder, carbon nanometer
5-10 parts of pipe, 1-5 parts of nano phase ag_2 o, 0.5-3 parts of ceramic powder, 1-4 parts of nano zine oxide, 5-10 parts of nanometer grade calcium carbonate.
2. antibacterial pro-skin polypropylene filament yarn according to claim 1, it is characterised in that: the polypropylene filament yarn prepare material by
Following parts by weight at being grouped as:
100 parts of PP, 25 parts of poly- hydroxyl acrylic resin, 1.5 parts of talcum powder, 8 parts of carbon nanotube, is received by 2 parts of silane coupling agent
4 parts of silver oxide, 1 part of ceramic powder, 3 parts of nano zine oxide, 6 parts of nanometer grade calcium carbonate of rice.
3. antibacterial pro-skin polypropylene filament yarn according to claim 1, it is characterised in that: the silane coupling agent is vinyl three
Ethoxysilane or vinyltrimethoxysilane.
4. antibacterial pro-skin polypropylene filament yarn according to claim 1, it is characterised in that: the poly- hydroxyl acrylic resin is
One of hydroxyethyl acrylate, polyhydroxypropyl acrylate, polyacrylic acid hydroxy butyl ester, polyacrylic acid caprolactone or a variety of groups
It closes.
5. a kind of production method of the antibacterial pro-skin polypropylene filament yarn as described in claim 1-4 is any, it is characterised in that: including such as
Lower step:
(1) by quantitative PP, poly- hydroxyl acrylic resin, silane coupling agent, talcum powder, carbon nanotube, nano phase ag_2 o, pottery
Porcelain powder, nano zine oxide, nanometer grade calcium carbonate are added to the mixer, and are uniformly mixed, are mixed with the speed of 350-360r/min
Close material；
(2) it by double screw extruder, is granulated in 220-230 DEG C of technological temperature bottom brace, obtains mangcorn；
(3) by spinning equipment, 240-250 DEG C at a temperature of, it is final with 1500-2500 ms/min of speed melt spinning
To antibacterial pro-skin polypropylene filament yarn.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910639082.7A CN110241477A (en) | 2019-07-16 | 2019-07-16 | Antibacterial pro-skin polypropylene filament yarn and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910639082.7A CN110241477A (en) | 2019-07-16 | 2019-07-16 | Antibacterial pro-skin polypropylene filament yarn and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110241477A true CN110241477A (en) | 2019-09-17 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910639082.7A Pending CN110241477A (en) | 2019-07-16 | 2019-07-16 | Antibacterial pro-skin polypropylene filament yarn and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114045683A (en) * | 2021-11-17 | 2022-02-15 | 浙江力佳隆毛刷有限公司 | A kind of antibacterial aromatic plush fabric and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102973986A (en) * | 2012-07-19 | 2013-03-20 | 黄斌 | Medical super-lubricity antibacterial catheter coating liquid |
| CN103788552A (en) * | 2012-10-26 | 2014-05-14 | 厦门加岩高分子材料有限公司 | Polyvinyl alcohol blend |
| CN109594140A (en) * | 2018-12-24 | 2019-04-09 | 广东蒙泰高新纤维股份有限公司 | A kind of functional hollow polypropylene fiber and preparation method thereof |
| CN109706533A (en) * | 2017-10-26 | 2019-05-03 | 中国石油化工股份有限公司 | A kind of antibacterial and mouldproof polypropylene filament yarn and preparation method thereof |
-
2019
- 2019-07-16 CN CN201910639082.7A patent/CN110241477A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102973986A (en) * | 2012-07-19 | 2013-03-20 | 黄斌 | Medical super-lubricity antibacterial catheter coating liquid |
| CN103788552A (en) * | 2012-10-26 | 2014-05-14 | 厦门加岩高分子材料有限公司 | Polyvinyl alcohol blend |
| CN109706533A (en) * | 2017-10-26 | 2019-05-03 | 中国石油化工股份有限公司 | A kind of antibacterial and mouldproof polypropylene filament yarn and preparation method thereof |
| CN109594140A (en) * | 2018-12-24 | 2019-04-09 | 广东蒙泰高新纤维股份有限公司 | A kind of functional hollow polypropylene fiber and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114045683A (en) * | 2021-11-17 | 2022-02-15 | 浙江力佳隆毛刷有限公司 | A kind of antibacterial aromatic plush fabric and preparation method and application thereof |
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Application publication date: 20190917 |