CN115637023A - Biodegradable blown film - Google Patents
Biodegradable blown film Download PDFInfo
- Publication number
- CN115637023A CN115637023A CN202110812945.3A CN202110812945A CN115637023A CN 115637023 A CN115637023 A CN 115637023A CN 202110812945 A CN202110812945 A CN 202110812945A CN 115637023 A CN115637023 A CN 115637023A
- Authority
- CN
- China
- Prior art keywords
- parts
- blown film
- antioxidant
- biodegradable blown
- filler
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 239000000945 filler Substances 0.000 claims abstract description 9
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 8
- -1 tetramethyl adipate-terephthalate Chemical compound 0.000 claims abstract description 7
- WVRNUXJQQFPNMN-VAWYXSNFSA-N 3-[(e)-dodec-1-enyl]oxolane-2,5-dione Chemical compound CCCCCCCCCC\C=C\C1CC(=O)OC1=O WVRNUXJQQFPNMN-VAWYXSNFSA-N 0.000 claims abstract description 5
- 238000007664 blowing Methods 0.000 claims abstract description 5
- 238000010096 film blowing Methods 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims abstract description 5
- NCAVPEPBIJTYSO-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate;2-(oxiran-2-ylmethoxymethyl)oxirane Chemical compound C1OC1COCC1CO1.OCCCCOC(=O)C=C NCAVPEPBIJTYSO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920001634 Copolyester Polymers 0.000 claims abstract description 4
- ARIWANIATODDMH-UHFFFAOYSA-N Lauric acid monoglyceride Natural products CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 claims abstract description 3
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229920000747 poly(lactic acid) Polymers 0.000 claims abstract description 3
- 239000004626 polylactic acid Substances 0.000 claims abstract description 3
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 3
- 239000003549 soybean oil Substances 0.000 claims abstract description 3
- 239000000843 powder Substances 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 4
- 239000011256 inorganic filler Substances 0.000 claims description 4
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 4
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 4
- 239000012766 organic filler Substances 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 claims description 3
- 229920001661 Chitosan Polymers 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 claims description 3
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical group O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 239000010902 straw Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 4
- ARIWANIATODDMH-AWEZNQCLSA-N 1-lauroyl-sn-glycerol Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)CO ARIWANIATODDMH-AWEZNQCLSA-N 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 6
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 229920006238 degradable plastic Polymers 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W90/00—Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
- Y02W90/10—Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
Abstract
The invention discloses a biodegradable blown film, which is prepared by stirring the following components in parts by weight through a high-speed mixer and then blowing the mixture through a film blowing machine: 100 parts of poly-sebacic acid-terephthalic acid butanediol ester, 30 to 60 parts of tetramethyl adipate-terephthalate copolyester, 25 to 50 parts of polylactic acid, 3425 parts of epoxidized soybean oil, 3425 parts of zxft, 3562 parts of 4-hydroxybutyl acrylate glycidyl ether, 3562 parts of dodecenyl succinic anhydride, 4324 parts of dodecenyl succinic anhydride, 0.5 to 2 parts of ethylene bisstearamide, 3245 parts of glycerol monolaurate, 3245 parts of zxft, 0.5 to 1.5 parts of antioxidant, 0.3 to 1 part of release agent and 3732 parts of filler, namely zxft 3732. The puncture energy of the biodegradable blown film is more than 22J/mm, and the puncture resistance strength is high, so that the carrying capacity of the film is improved.
Description
Technical Field
The invention relates to the technical field of plastics, in particular to a biodegradable blown film.
Background
The shopping bag provides great convenience for people in daily life, is a necessary article for people to go out for shopping, the plastic shopping bag in the shopping bag is most extensive in China, so that the serious pollution to the ecological environment is caused, and the development and application of the degradable plastic are one of the most effective ways for solving the problem. Although degradable films have been used in the prior art, the strength of the existing degradable shopping bags is to be improved, so that the carrying weight thereof is limited.
Disclosure of Invention
The invention aims to provide a biodegradable blown film, which has the puncture energy of more than 22J/mm and high puncture resistance strength, so that the carrying capacity of the film is improved.
In order to achieve the purpose, the technical scheme of the brightener is as follows: the biodegradable blown film is prepared by stirring the following components in parts by weight through a high-speed mixer and then blowing through a film blowing machine:
100 parts of polybutylene sebacate terephthalate,
30 to 60 portions of tetramethyl adipate-terephthalate copolyester,
25 to 50 parts of polylactic acid,
epoxidized soybean oil 3~8 portions,
4-hydroxybutyl acrylate glycidyl ether 2~5 parts,
5363 parts of dodecenyl succinic anhydride 1~3 parts,
0.5 to 2 portions of ethylene bis stearamide,
5363 parts of lauric acid monoglyceride 1~3 parts,
0.5 to 1.5 portions of antioxidant,
0.3 to 1 part of a release agent,
and 5363 parts of filler 3~6.
The technical scheme of further improvement in the technical scheme is as follows:
1. in the scheme, the antioxidant is at least one of an antioxidant 1010, an antioxidant 1076, an antioxidant 2246 and an antioxidant 168.
2. In the above scheme, the filler is an inorganic filler or an organic filler.
3. In the scheme, the inorganic filler is talcum powder, pearl powder, alumina, shell powder, calcium carbonate or barium sulfate.
4. In the scheme, the organic filler is natural starch, straw, natural fiber or chitosan.
5. In the scheme, the release agent is silicone master batch or montmorillonite wax.
Due to the application of the technical scheme, compared with the prior art, the invention has the following advantages:
the biodegradable blown film disclosed by the invention has the advantages that the biodegradation rate after 12 weeks is over 90%, and based on 100 parts of polybutylene sebacate terephthalate and 30-60 parts of tetramethyl adipate-terephthalate copolyester, 4-hydroxybutyl acrylate glycidyl ether 2~5 parts and dodecenyl succinic anhydride 1~3 parts, the puncture energy is more than 22J/mm, the puncture resistance is high, and the carrying capacity of the film is improved.
Detailed Description
In the description of the present invention, it should be noted that the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer", etc., indicate orientations or positional relationships based on the illustrated orientations or positional relationships, and are only used for convenience in describing the present invention and simplifying the description, but do not indicate or imply that the device or element referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus, should not be construed as limiting the present invention; the terms "first," "second," and "third" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance; furthermore, unless expressly stated or limited otherwise, the terms "mounted," "connected," and "connected" are to be construed broadly, as they may be fixedly connected, detachably connected, or integrally connected, for example; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art.
The invention is further described below with reference to the following examples:
example 1~4: a biodegradable blown film is obtained by stirring the following components in parts by weight through a high-speed mixer and then blowing the mixture through a film blowing machine, wherein the components are shown in Table 1:
TABLE 1
The antioxidant of example 1 is antioxidant 1010, the filler is talc, and the release agent is silicone master batch.
The antioxidant 2246 of example 2, the filler is natural starch, and the release agent is a montmorillonite wax.
The antioxidant of example 3 is antioxidant 1076, the filler is pearl powder, and the release agent is silicone master batch.
The antioxidant of the embodiment 4 is an antioxidant 1010, the filler is chitosan, and the release agent is montmorillonite wax.
Comparative example 1~2: a biodegradable blown film consisting of the following components in parts by weight, as shown in Table 2:
TABLE 2
The solvents of comparative example 1 and comparative example 2 were both deionized water and the antioxidants were both antioxidants 168.
Comparative example blown films the same examples were obtained by stirring the respective components in a high-speed mixer and then blowing the same in a film blowing machine.
The properties of the blown films obtained in example 1~4 and comparative example 1~2 described above are shown in table 3:
TABLE 3
As shown in the evaluation results in Table 3, the compositions of inventive example 1~4 all formed blown films with puncture energies greater than 22J/mm, while the composition of comparative example 1~2 formed blown films with puncture energies less than 17J/mm; the biodegradable blown film disclosed by the embodiment of the invention has high puncture resistance, so that the carrying capacity of the film is improved.
The above embodiments are merely illustrative of the technical ideas and features of the present invention, and the purpose thereof is to enable those skilled in the art to understand the contents of the present invention and implement the present invention, and not to limit the protection scope of the present invention. All equivalent changes and modifications made according to the spirit of the present invention should be covered within the protection scope of the present invention.
Claims (6)
1. A biodegradable blown film characterized by: the biodegradable blown film is prepared by stirring the following components in parts by weight through a high-speed mixer and then blowing through a film blowing machine:
100 parts of polybutylene sebacate terephthalate,
30 to 60 parts of tetramethyl adipate-terephthalate copolyester,
25 to 50 parts of polylactic acid,
epoxidized soybean oil 3~8 portions,
4-hydroxybutyl acrylate glycidyl ether 2~5 parts,
5363 parts of dodecenyl succinic anhydride 1~3 parts,
0.5 to 2 portions of ethylene bis stearamide,
5363 parts of lauric acid monoglyceride 1~3 parts,
0.5 to 1.5 portions of antioxidant,
0.3 to 1 part of a release agent,
and 5363 parts of filler 3~6.
2. The biodegradable blown film according to claim 1, characterized in that: the antioxidant is at least one of antioxidant 1010, antioxidant 1076, antioxidant 2246 and antioxidant 168.
3. The biodegradable blown film according to claim 1, characterized in that: the filler is an inorganic filler or an organic filler.
4. The biodegradable blown film according to claim 3, characterized in that: the inorganic filler is talcum powder, pearl powder, alumina, shell powder, calcium carbonate or barium sulfate.
5. The biodegradable blown film according to claim 3, characterized in that: the organic filler is natural starch, straw, natural fiber or chitosan.
6. The biodegradable blown film according to claim 1, characterized in that: the release agent is silicone master batch or montmorillonite wax.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110812945.3A CN115637023B (en) | 2021-07-19 | 2021-07-19 | Biodegradable blown film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110812945.3A CN115637023B (en) | 2021-07-19 | 2021-07-19 | Biodegradable blown film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115637023A true CN115637023A (en) | 2023-01-24 |
| CN115637023B CN115637023B (en) | 2023-07-07 |
Family
ID=84939723
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110812945.3A Active CN115637023B (en) | 2021-07-19 | 2021-07-19 | Biodegradable blown film |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115637023B (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102477153A (en) * | 2010-11-23 | 2012-05-30 | 远东新世纪股份有限公司 | Copolyester composition with thermal stability |
| WO2013017431A1 (en) * | 2011-07-29 | 2013-02-07 | Basf Se | Biodegradable polyester film |
| CN108219396A (en) * | 2017-12-27 | 2018-06-29 | 杨红梅 | A kind of biodegradable polymer blend and its application |
| CN110330773A (en) * | 2019-07-19 | 2019-10-15 | 深圳利琒环保材料有限公司 | A kind of controllable full-biodegradable mulch and preparation method thereof |
| US20200291225A1 (en) * | 2017-09-12 | 2020-09-17 | Jiangsu Golden-Poly Alloy Material Co.,Ltd. | Low cost bio-based full degradable film and preparation method thereof |
| CN113461930A (en) * | 2021-05-25 | 2021-10-01 | 广东省科学院生物工程研究所 | Anhydride and epoxy macromolecule chain-extending tackifier and preparation method and application thereof |
| CN114752155A (en) * | 2021-01-12 | 2022-07-15 | 广东祥利科技有限公司 | Environment-friendly PVC cable material and preparation process thereof |
-
2021
- 2021-07-19 CN CN202110812945.3A patent/CN115637023B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102477153A (en) * | 2010-11-23 | 2012-05-30 | 远东新世纪股份有限公司 | Copolyester composition with thermal stability |
| WO2013017431A1 (en) * | 2011-07-29 | 2013-02-07 | Basf Se | Biodegradable polyester film |
| US20200291225A1 (en) * | 2017-09-12 | 2020-09-17 | Jiangsu Golden-Poly Alloy Material Co.,Ltd. | Low cost bio-based full degradable film and preparation method thereof |
| CN108219396A (en) * | 2017-12-27 | 2018-06-29 | 杨红梅 | A kind of biodegradable polymer blend and its application |
| CN110330773A (en) * | 2019-07-19 | 2019-10-15 | 深圳利琒环保材料有限公司 | A kind of controllable full-biodegradable mulch and preparation method thereof |
| CN114752155A (en) * | 2021-01-12 | 2022-07-15 | 广东祥利科技有限公司 | Environment-friendly PVC cable material and preparation process thereof |
| CN113461930A (en) * | 2021-05-25 | 2021-10-01 | 广东省科学院生物工程研究所 | Anhydride and epoxy macromolecule chain-extending tackifier and preparation method and application thereof |
Non-Patent Citations (3)
| Title |
|---|
| A. TEAMSINSUNGVON,等: "Melt Processing of Maleic Anhydride Grafted Poly(lactic acid) and Its Compatibilizing Effect on Poly(lactic acid)/Poly(butylene adipate-co-terephthalate) Blend and Their Composite1", 《POLYMER BLENDS》, pages 1 - 13 * |
| SUN JONG KIM，等: "Characterization of PLA/PBSeT Blends Prepared with Various Hexamethylene Diisocyanate Contents", 《MATERIALS》, pages 1 - 16 * |
| 张臣，等: "聚乳酸／改性淀粉／甲基丙烯酸缩水甘油醚接枝 乙烯－醋酸乙烯共聚物复合材料的制备及性能", 《华东理工大学学报（自然科学版）》, vol. 42, no. 6, pages 808 - 813 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115637023B (en) | 2023-07-07 |
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| CB02 | Change of applicant information |
Address after: 527499 No. 9, Xincheng Second Road, Xincheng Industrial Park, Xincheng Town, Xinxing County, Yunfu City, Guangdong Province Applicant after: Guangdong Xiangli Technology Group Co.,Ltd. Address before: 527400 No. 9, Xincheng Second Road, Xincheng Industrial Park, Xincheng Town, Xinxing County, Yunfu City, Guangdong Province Applicant before: GUANGDONG XIANGLI TECHNOLOGY Co.,Ltd. |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Biodegradable blown film Effective date of registration: 20231226 Granted publication date: 20230707 Pledgee: Yunfu branch of Guangdong Nanyue Bank Co.,Ltd. Pledgor: Guangdong Xiangli Technology Group Co.,Ltd. Registration number: Y2023980074477 |
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