CN115637023B - Biodegradable blown film - Google Patents

Biodegradable blown film Download PDF

Info

Publication number
CN115637023B
CN115637023B CN202110812945.3A CN202110812945A CN115637023B CN 115637023 B CN115637023 B CN 115637023B CN 202110812945 A CN202110812945 A CN 202110812945A CN 115637023 B CN115637023 B CN 115637023B
Authority
CN
China
Prior art keywords
parts
blown film
antioxidant
biodegradable blown
filler
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202110812945.3A
Other languages
Chinese (zh)
Other versions
CN115637023A (en
Inventor
肖红杰
梁国伟
廖青雄
宋光春
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Xiangli Technology Group Co ltd
Original Assignee
Guangdong Xiangli Technology Group Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong Xiangli Technology Group Co ltd filed Critical Guangdong Xiangli Technology Group Co ltd
Priority to CN202110812945.3A priority Critical patent/CN115637023B/en
Publication of CN115637023A publication Critical patent/CN115637023A/en
Application granted granted Critical
Publication of CN115637023B publication Critical patent/CN115637023B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W90/00Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
    • Y02W90/10Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics

Landscapes

  • Compositions Of Macromolecular Compounds (AREA)
  • Biological Depolymerization Polymers (AREA)

Abstract

The invention discloses a biodegradable blown film which is obtained by stirring the following components in parts by weight by a high-speed mixer and then blowing by a film blowing machine: 100 parts of polybutylene sebacate, 30-60 parts of tetramethyl adipate-terephthalate copolyester, 25-50 parts of polylactic acid, 3-8 parts of epoxidized soybean oil, 2-5 parts of 4-hydroxybutyl acrylate glycidyl ether, 1-3 parts of dodecenyl succinic anhydride, 0.5-2 parts of ethylene bis-stearamide, 1-3 parts of lauric acid monoglyceride, 0.5-1.5 parts of an antioxidant, 0.3-1 part of a release agent and 3-6 parts of a filler. The puncture energy of the biodegradable blown film is larger than 22J/mm, and the puncture resistance strength is high, so that the carrying capacity of the film is improved.

Description

Biodegradable blown film
Technical Field
The invention relates to the technical field of plastics, in particular to a biodegradable blown film.
Background
The shopping bag provides great convenience for people in daily life, is a necessary article for people to go out for shopping, and is the most widely used in China, so that serious pollution to ecological environment is caused, and the development and application of the degradable plastic are one of the most effective ways for solving the problem. Although degradable films have been used in the prior art, the strength of existing degradable shopping bags is to be improved, and thus the weight of the carrier is limited.
Disclosure of Invention
The invention aims to provide a biodegradable blown film which has puncture energy of more than 22J/mm and high puncture resistance strength, so that the carrying capacity of the film is improved.
In order to achieve the purpose, the brightening agent adopts the following technical scheme: the biodegradable blown film is obtained by stirring the following components in parts by weight by a high-speed mixer and then blowing by a film blowing machine:
100 parts of polybutylene sebacate terephthalate,
30-60 parts of tetramethyl adipate-terephthalate copolyester,
25-50 parts of polylactic acid,
3-8 parts of epoxidized soybean oil,
2-5 parts of 4-hydroxybutyl acrylate glycidyl ether,
1-3 parts of dodecenyl succinic anhydride,
0.5-2 parts of ethylene bis-stearamide,
1-3 parts of lauric acid monoglyceride,
0.5-1.5 parts of antioxidant,
0.3-1 part of a release agent,
3-6 parts of filler.
The technical scheme further improved in the technical scheme is as follows:
1. in the above scheme, the antioxidant is at least one of antioxidant 1010, antioxidant 1076, antioxidant 2246 and antioxidant 168.
2. In the above scheme, the filler is an inorganic filler or an organic filler.
3. In the scheme, the inorganic filler is talcum powder, pearl powder, aluminum oxide, shell powder, calcium carbonate or barium sulfate.
4. In the above scheme, the organic filler is natural starch, straw, natural fiber or chitosan.
5. In the above scheme, the release agent is silicone master batch or a montan wax.
Due to the application of the technical scheme, compared with the prior art, the invention has the following advantages:
the biodegradable blown film realizes that the biodegradation rate after 12 weeks exceeds 90%, and simultaneously, based on 100 parts of polybutylene sebacate, 30-60 parts of tetramethyl adipate-terephthalate copolyester, 2-5 parts of 4-hydroxybutyl acrylate glycidyl ether and 1-3 parts of dodecenyl succinic anhydride are further added, the puncture energy is larger than 22J/mm, and the puncture resistance strength is high, so that the carrying capacity of the film is improved.
Detailed Description
In the description of the present invention, it should be noted that the directions or positional relationships indicated by the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer", etc. are based on the directions or positional relationships shown, are merely for convenience of describing the present invention and simplifying the description, and do not indicate or imply that the devices or elements referred to must have a specific orientation, be constructed and operated in a specific orientation, and thus should not be construed as limiting the present invention; the terms "first," "second," and "third" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance; furthermore, unless explicitly specified and limited otherwise, the terms "mounted," "connected," and "connected" are to be construed broadly, and may be either fixedly connected, detachably connected, or integrally connected, for example; can be mechanically or electrically connected; can be directly connected or indirectly connected through an intermediate medium, and can be communication between two elements. The specific meaning of the above terms in the present invention will be understood in specific cases by those of ordinary skill in the art.
The invention is further described below with reference to examples:
examples 1 to 4: the biodegradable blown film is obtained by stirring the following components in parts by weight by a high-speed mixer and then blowing by a film blowing machine, and is shown in table 1:
TABLE 1
Figure 791958DEST_PATH_IMAGE002
The antioxidant of example 1 is antioxidant 1010, the filler is talc and the release agent is silicone masterbatch.
The antioxidant 2246 of example 2, wherein the filler is natural starch and the release agent is a montan wax.
The antioxidant of example 3 is antioxidant 1076, the filler is pearl powder, and the release agent is silicone masterbatch.
The antioxidant of example 4 is antioxidant 1010, the filler chitosan, and the release agent is a montan wax.
Comparative examples 1 to 2: a biodegradable blown film consisting of the following components in parts by weight, as shown in table 2:
TABLE 2
Figure 771415DEST_PATH_IMAGE004
The solvents of comparative example 1 and comparative example 2 were deionized water and the antioxidants were antioxidant 168.
The blown film of the comparative example is obtained by blowing the corresponding components by a film blowing machine after stirring the components by a high speed mixer.
The properties of the blown films obtained in examples 1 to 4 and comparative examples 1 to 2 are shown in Table 3:
TABLE 3 Table 3
Figure 754415DEST_PATH_IMAGE006
As shown by the evaluation results in Table 3, the puncture energy of the blown films formed by the compositions of examples 1 to 4 of the present invention is greater than 22J/mm, while the puncture energy of the blown films formed by the compositions of comparative examples 1 to 2 is less than 17J/mm; the biodegradable blown film provided by the embodiment of the invention has high puncture resistance, so that the carrying capacity of the film is improved.
The above embodiments are provided to illustrate the technical concept and features of the present invention and are intended to enable those skilled in the art to understand the content of the present invention and implement the same, and are not intended to limit the scope of the present invention. All equivalent changes or modifications made in accordance with the spirit of the present invention should be construed to be included in the scope of the present invention.

Claims (6)

1. A biodegradable blown film characterized by: the biodegradable blown film is obtained by stirring the following components in parts by weight through a high-speed mixer and then blowing through a film blowing machine:
100 parts of polybutylene sebacate terephthalate,
30-60 parts of tetramethyl adipate-terephthalate copolyester,
25-50 parts of polylactic acid,
3-8 parts of epoxidized soybean oil,
2-5 parts of 4-hydroxybutyl acrylate glycidyl ether,
1-3 parts of dodecenyl succinic anhydride,
0.5-2 parts of ethylene bis-stearamide,
1-3 parts of lauric acid monoglyceride,
0.5-1.5 parts of antioxidant,
0.3-1 part of a release agent,
3-6 parts of filler.
2. The biodegradable blown film according to claim 1, characterized in that: the antioxidant is at least one of antioxidant 1010, antioxidant 1076, antioxidant 2246 and antioxidant 168.
3. The biodegradable blown film according to claim 1, characterized in that: the filler is an inorganic filler or an organic filler.
4. A biodegradable blown film according to claim 3, characterized in that: the inorganic filler is talcum powder, pearl powder, aluminum oxide, shell powder, calcium carbonate or barium sulfate.
5. A biodegradable blown film according to claim 3, characterized in that: the organic filler is natural starch, straw, natural fiber or chitosan.
6. The biodegradable blown film according to claim 1, characterized in that: the release agent is silicone master batch or Montana wax.
CN202110812945.3A 2021-07-19 2021-07-19 Biodegradable blown film Active CN115637023B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110812945.3A CN115637023B (en) 2021-07-19 2021-07-19 Biodegradable blown film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110812945.3A CN115637023B (en) 2021-07-19 2021-07-19 Biodegradable blown film

Publications (2)

Publication Number Publication Date
CN115637023A CN115637023A (en) 2023-01-24
CN115637023B true CN115637023B (en) 2023-07-07

Family

ID=84939723

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110812945.3A Active CN115637023B (en) 2021-07-19 2021-07-19 Biodegradable blown film

Country Status (1)

Country Link
CN (1) CN115637023B (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102477153A (en) * 2010-11-23 2012-05-30 远东新世纪股份有限公司 Copolyester composition with thermal stability
WO2013017431A1 (en) * 2011-07-29 2013-02-07 Basf Se Biodegradable polyester film
CN108219396A (en) * 2017-12-27 2018-06-29 杨红梅 A kind of biodegradable polymer blend and its application
CN110330773A (en) * 2019-07-19 2019-10-15 深圳利琒环保材料有限公司 A kind of controllable full-biodegradable mulch and preparation method thereof
CN113461930A (en) * 2021-05-25 2021-10-01 广东省科学院生物工程研究所 Anhydride and epoxy macromolecule chain-extending tackifier and preparation method and application thereof
CN114752155A (en) * 2021-01-12 2022-07-15 广东祥利科技有限公司 Environment-friendly PVC cable material and preparation process thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107556536B (en) * 2017-09-12 2021-02-12 江苏金聚合金材料有限公司 Low-cost bio-based fully-degradable film and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102477153A (en) * 2010-11-23 2012-05-30 远东新世纪股份有限公司 Copolyester composition with thermal stability
WO2013017431A1 (en) * 2011-07-29 2013-02-07 Basf Se Biodegradable polyester film
CN108219396A (en) * 2017-12-27 2018-06-29 杨红梅 A kind of biodegradable polymer blend and its application
CN110330773A (en) * 2019-07-19 2019-10-15 深圳利琒环保材料有限公司 A kind of controllable full-biodegradable mulch and preparation method thereof
CN114752155A (en) * 2021-01-12 2022-07-15 广东祥利科技有限公司 Environment-friendly PVC cable material and preparation process thereof
CN113461930A (en) * 2021-05-25 2021-10-01 广东省科学院生物工程研究所 Anhydride and epoxy macromolecule chain-extending tackifier and preparation method and application thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Characterization of PLA/PBSeT Blends Prepared with Various Hexamethylene Diisocyanate Contents;Sun Jong Kim,等;《materials》;第1-16页 *
Melt Processing of Maleic Anhydride Grafted Poly(lactic acid) and Its Compatibilizing Effect on Poly(lactic acid)/Poly(butylene adipate-co-terephthalate) Blend and Their Composite1;A. Teamsinsungvon,等;《polymer blends》;第1-13页 *
聚乳酸/改性淀粉/甲基丙烯酸缩水甘油醚接枝 乙烯-醋酸乙烯共聚物复合材料的制备及性能;张臣,等;《华东理工大学学报(自然科学版)》;第42卷(第6期);第808-813页、第870页 *

Also Published As

Publication number Publication date
CN115637023A (en) 2023-01-24

Similar Documents

Publication Publication Date Title
CN111718566A (en) PLA/PBAT biodegradable composite material and product thereof
CN106397974B (en) A kind of cup and preparation method thereof that high-barrier is anti-aging
CN112940474B (en) Antibacterial puncture-resistant biodegradable packaging bag and preparation method thereof
CN110760169B (en) Barrier material and preparation method thereof
CN104086905B (en) Modified polypropylene soft bottle material, as well as preparation method and applications thereof
WO2018056539A1 (en) Biodegradable resin composition and biodegradable article manufactured therefrom
CN113429754A (en) Composite filled fully-degradable material composition, film and preparation method thereof
CN111662539A (en) Biodegradable bubble bag material and preparation method thereof
CN114015369A (en) PLA-based degradable adhesive tape
CN116694045B (en) Ultrathin biodegradable mulching film and preparation method thereof
CN115637023B (en) Biodegradable blown film
CN115637024B (en) Degradable plastic shopping bag
CN107312295A (en) A kind of lactic acid composite material of high transparency low cost and preparation method thereof
CN111423689A (en) Modified polypropylene material and preparation method and application thereof
CN102617911A (en) Reclaimed high-density polyethylene/polypropylene composite material prepared through reaction extruding
CN112538242A (en) Environment-friendly full-degradable novel garbage bag and preparation thereof
CN111763410B (en) Biodegradable PBAT alloy with high starch content and preparation method thereof
CN107488338A (en) A kind of plastic packaging bag and its processing technology
CN113861643B (en) High-barrier biodegradable material and preparation method and application thereof
CN114921069B (en) Full-biodegradable film with high heat seal strength and preparation method and application thereof
CN113831699B (en) Biodegradable material with high strength and high elongation and application thereof
CN101896545B (en) Molded object and process for producing the same
CN111320808B (en) Low-melting-point input packaging film for silicone rubber and preparation process thereof
CN113980598A (en) Preparation method of PLA-based degradable adhesive tape
CN107189390A (en) A kind of preparation method of plastic packaging bag

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information

Address after: 527499 No. 9, Xincheng Second Road, Xincheng Industrial Park, Xincheng Town, Xinxing County, Yunfu City, Guangdong Province

Applicant after: Guangdong Xiangli Technology Group Co.,Ltd.

Address before: 527400 No. 9, Xincheng Second Road, Xincheng Industrial Park, Xincheng Town, Xinxing County, Yunfu City, Guangdong Province

Applicant before: GUANGDONG XIANGLI TECHNOLOGY Co.,Ltd.

CB02 Change of applicant information
GR01 Patent grant
GR01 Patent grant
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: Biodegradable blown film

Effective date of registration: 20231226

Granted publication date: 20230707

Pledgee: Yunfu branch of Guangdong Nanyue Bank Co.,Ltd.

Pledgor: Guangdong Xiangli Technology Group Co.,Ltd.

Registration number: Y2023980074477

PE01 Entry into force of the registration of the contract for pledge of patent right