CN115635570A - Preparation method of ceramic tile with bright, carved, matte and deep-carved three-dimensional texture - Google Patents
Preparation method of ceramic tile with bright, carved, matte and deep-carved three-dimensional texture Download PDFInfo
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- CN115635570A CN115635570A CN202210862024.2A CN202210862024A CN115635570A CN 115635570 A CN115635570 A CN 115635570A CN 202210862024 A CN202210862024 A CN 202210862024A CN 115635570 A CN115635570 A CN 115635570A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
A preparation method of a ceramic tile with bright, carved, matte and deep-carved stereoscopic textures comprises the following steps: preparing a ceramic tile green body, wherein the surface of the ceramic tile green body is provided with a surface glaze layer; two groups of spray heads are adopted, wherein one group of spray heads firstly spray bright and precise engraving ink to the surface of the surface glaze layer of the ceramic tile blank to form bright textures, then the other group of spray heads spray matte and deep engraving ink to form matte textures, and the matte and deep engraving ink and the bright and precise engraving ink are respectively sprayed on different areas of the surface of the ceramic tile blank, so that the bright textures and the matte textures existing at the same time are formed on the surface of the ceramic tile blank; printing antibacterial ink to form an antibacterial layer; and then drying and sintering to obtain a ceramic tile finished product. The matte texture with the bright effect is prepared by the method, and meanwhile, the matte texture with the bright effect has a certain antibacterial effect.
Description
Technical Field
The invention relates to the technical field of ceramic tiles, in particular to a preparation method of a ceramic tile with bright, carved, matte and deep stereoscopic textures.
Background
Ceramic tiles are indispensable decorative materials for modern home decoration. It can beautify decorative space, create various living spaces with harmonious and warm features, and has very high artistic and appreciation values. With the change of the world fashion trend and fashion color, the home decoration style is also changed greatly, and the fashion is started to be simple. The simple style is expressed by the surface texture and the ornamentation of the decorative material, and most importantly, the original color expressed by the decorative material, and the color requirements of designers on the decorative material are strict or even harsh.
For ceramic tiles, corresponding textures are formed by ink-jet printing, and the existing ceramic tile printing mode can only be used for forming the textures by fine carving or forming the textures by deep carving, so that the compatibility of the two is difficult to achieve.
Disclosure of Invention
The invention aims to solve the technical problem of providing a preparation method of a ceramic tile with bright, carved, matte and deep stereoscopic textures.
In order to solve the technical problems, the invention adopts the following technical scheme:
a preparation method of a ceramic tile with bright, carved, matte and deep-carved stereoscopic textures comprises the following steps:
preparing a ceramic tile green body, wherein the surface of the ceramic tile green body is provided with a surface glaze layer;
two groups of spray heads are adopted, wherein one group of spray heads firstly spray bright and precise engraving ink to the surface of the surface glaze layer of the ceramic tile blank to form bright textures, then the other group of spray heads spray matte and deep engraving ink to form matte textures, and the matte and deep engraving ink and the bright and precise engraving ink are respectively sprayed on different areas of the surface of the ceramic tile blank, so that the bright textures and the matte textures existing at the same time are formed on the surface of the ceramic tile blank;
printing antibacterial ink to form an antibacterial layer;
and then drying and sintering to obtain a ceramic tile finished product.
The carved black water comprises the following components in parts by weight and 100:
3-25 parts of high-temperature frit, 5-13 parts of fused quartz, 1-4 parts of calcined zinc oxide, 5-20 parts of zirconium silicate, 1-5 parts of diaspore, 1-3 parts of oxidized silica, 2-6 parts of a dispersant, 1-5 parts of a defoaming agent and 35-65 parts of a solvent;
the high-temperature frit consists of the following components in parts by mass, wherein the components are counted in the sum of 100:
35-65 parts of SiO 2 15-30 parts of Al 2 O 3 5-10 parts of K 2 O, 5-10 parts of Na 2 O, 5-10 parts of ZnO and 5-10 parts of CaO.
The matte deep engraving ink comprises the following components in parts by weight, wherein the components are counted according to the sum of 100:
3-20 parts of high-temperature frit, 5-13 parts of fused quartz, 1-5 parts of wollastonite, 5-20 parts of zirconium silicate, 1-5 parts of diaspore, 1-3 parts of oxidized silica, 2-6 parts of a dispersing agent, 1-5 parts of a defoaming agent and 35-65 parts of a solvent;
the dispersant is one or a composition of two of polyurethane dispersant and polymerized hydrogenated ricinoleic acid.
The defoaming agent is one or the combination of BYK-055 and BYK-028.
The solvent is any one or the combination of more than two of mineral oil, isopropyl laurate, methyl oleate and isooctyl cocoate.
The antibacterial ink comprises the following components in parts by mass and 100:
30-50 parts of titanium dioxide, 15-30 parts of silicon nitride, 10-20 parts of phosphorus pentoxide, 10-15 parts of potassium oxide, 3-8 parts of strontium oxide and 1-5 parts of silver ions.
The antibacterial ink is prepared according to the following steps:
dissolving butyl titanate and ethyl orthosilicate in isopropanol, and stirring to obtain an antibacterial precursor solution;
mixing 30-50 parts of titanium dioxide, 15-30 parts of silicon nitride, 10-20 parts of phosphorus pentoxide, 10-15 parts of potassium oxide, 3-8 parts of strontium oxide and 1-5 parts of silver ions together and grinding the mixture to form mixed powder;
and adding the mixed powder into the antibacterial precursor solution, uniformly stirring, and filtering to obtain the antibacterial ink.
The ink-jet printing amount of the bright finishing carving ink and the matte deep engraving ink is 10-20 g/m 2， The ink-jet printing amount of the antibacterial ink is 5-10g/m 2， 。
The invention combines the bright carved ink and the matte deep carved ink for use, forms a light and dark combined form by respectively spraying and carving the bright texture and the matte texture in different areas, combines the antibacterial property and has a certain antibacterial function.
Detailed Description
The present invention will be described in further detail with reference to specific embodiments in order to further understand the features and technical means of the invention and achieve specific objects and functions.
Example one
The prepared bright engraving ink comprises the following components in parts by mass: 20 parts of high-temperature frit, 5 parts of fused quartz, 1 part of calcined zinc oxide, 20 parts of zirconium silicate, 5 parts of diaspore, 3 parts of oxidized silica, 5 parts of dispersant, 5 parts of defoamer and 41 parts of solvent. The solvent is a mixture of isopropyl laurate and methyl oleate, wherein the isopropyl laurate accounts for 40 parts by mass, and the methyl oleate accounts for 60 parts by mass. The high-temperature frit consists of the following components in parts by mass: siO 2 2 50 parts of Al 2 O 3 30 parts of, K 2 O5 parts, na 2 5 parts of O, 5 parts of ZnO and 5 parts of CaO. The dispersant is a polyurethane type dispersant. The addition of bismuth oxide can effectively improve the activity and promote the catalysis. The high-temperature frit can be combined with the glaze layer of the ceramic tile more firmly.
Preparing matte deep ink, which comprises the following components in parts by massConsists of the following components: 20 parts of high-temperature frit, 5 parts of fused quartz, 1 part of wollastonite, 20 parts of zirconium silicate, 5 parts of diaspore, 3 parts of oxidized silica, 5 parts of dispersing agent, 5 parts of defoaming agent and 41 parts of solvent. The solvent is a mixture of isopropyl laurate and methyl oleate, wherein the mass part of the isopropyl laurate accounts for 40 parts, and the mass part of the methyl oleate accounts for 60 parts. The high-temperature frit consists of the following components in parts by mass: siO 2 2 50 parts of Al 2 O 3 30 parts of, K 2 O5 parts, na 2 5 parts of O, 5 parts of ZnO and 5 parts of CaO. The dispersant is a polyurethane type dispersant.
The prepared antibacterial ink comprises the following components in parts by weight: 40 parts of titanium dioxide, 30 parts of silicon nitride, 10 parts of phosphorus pentoxide, 10 parts of potassium oxide, 6 parts of strontium oxide and 4 parts of silver ions, wherein the silver ions can be formed by a load carrying silver ions. Dissolving butyl titanate and ethyl orthosilicate in isopropanol, and stirring to obtain an antibacterial precursor solution; mixing titanium dioxide, silicon nitride, phosphorus pentoxide, potassium oxide, strontium oxide and silver ions together and grinding to form mixed powder. And adding the mixed powder into the antibacterial precursor solution, uniformly stirring, and filtering to obtain the antibacterial ink. The potassium oxide and the strontium oxide can improve certain alkalinity, can improve the color of a glaze surface to a certain extent, and cannot influence the original pigment.
A preparation method of a ceramic tile with bright, carved, matte and deep-carved stereoscopic textures comprises the following steps:
preparing a ceramic tile green body, wherein the surface of the ceramic tile green body is provided with a surface glaze layer; the ceramic tile blank is made of conventional materials and in a conventional manner, for example, the blank is subjected to conventional procedures such as ball milling, compression molding and the like.
The method comprises the steps of adopting two groups of spray heads, spraying bright and carved ink to the surface of a surface glaze layer of a ceramic tile blank to form bright textures by one group of spray heads, then spraying matte and deep carved ink to form matte textures by the other group of spray heads, respectively spraying the matte and deep carved ink and the bright and deep carved ink to different areas of the surface of the ceramic tile blank, so that the bright textures and the matte textures existing simultaneously are formed on the surface of the ceramic tile blank, and forming the appearance form combining bright and matte on the surface of the tile body through secondary printing.
And then, printing antibacterial ink to form an antibacterial layer, so that a certain antibacterial property can be formed, and the functionality of the ceramic tile is improved. The ink-jet printing amount of the bright finishing carving ink and the matte deep engraving ink is 10g/m 2， The antibacterial ink has an ink-jet printing amount of 5g/m 2， 。
And then drying and sintering to obtain a ceramic tile finished product.
Example two
The prepared bright engraving ink comprises the following components in parts by mass: 5 parts of high-temperature frit, 10 parts of fused quartz, 3 parts of calcined zinc oxide, 15 parts of zirconium silicate, 5 parts of diaspore, 3 parts of oxidized silica, 5 parts of dispersing agent, 5 parts of defoaming agent and 49 parts of solvent. The solvent is a mixture of isopropyl laurate and methyl oleate, wherein the isopropyl laurate accounts for 45 parts by mass, and the methyl oleate accounts for 55 parts by mass. The high-temperature frit consists of the following components in parts by mass: siO 2 2 52 parts of Al 2 O 3 20 parts of, K 2 O5 parts, na 2 10 parts of O, 8 parts of ZnO and 5 parts of CaO. The dispersant is a polyurethane type dispersant. The addition of bismuth oxide can effectively improve the activity and promote the catalysis. The high-temperature frit can be combined with the glaze layer of the ceramic tile more firmly.
The matte deep engraving ink is prepared from the following components in parts by mass: 5 parts of high-temperature frit, 10 parts of fused quartz, 3 parts of wollastonite, 15 parts of zirconium silicate, 5 parts of diaspore, 3 parts of oxidized silica, 5 parts of dispersing agent, 5 parts of defoaming agent and 49 parts of solvent. The solvent is a mixture of isopropyl laurate and methyl oleate, wherein the mass part of the isopropyl laurate accounts for 40 parts, and the mass part of the methyl oleate accounts for 60 parts. The high-temperature frit consists of the following components in parts by mass: siO 2 2 50 parts of Al 2 O 3 30 parts of, K 2 O5 parts, na 2 5 parts of O, 5 parts of ZnO and 5 parts of CaO. The dispersant is a polyurethane type dispersant.
The prepared antibacterial ink comprises the following components in parts by weight: 30 parts of titanium dioxide, 30 parts of silicon nitride, 20 parts of phosphorus pentoxide, 15 parts of potassium oxide, 3 parts of strontium oxide and 2 parts of silver ions, wherein the silver ions can be formed by a load carrying silver ions. Dissolving butyl titanate and ethyl orthosilicate in isopropanol, and stirring to obtain an antibacterial precursor solution; mixing titanium dioxide, silicon nitride, phosphorus pentoxide, potassium oxide, strontium oxide and silver ions together and grinding to form mixed powder. And adding the mixed powder into the antibacterial precursor solution, uniformly stirring, and filtering to obtain the antibacterial ink. The potassium oxide and the strontium oxide can improve certain alkalinity, can improve the color of a glaze surface to a certain extent, and cannot influence the original pigment.
A preparation method of a ceramic tile with bright, carved, matte and deep-carved stereoscopic textures comprises the following steps:
preparing a ceramic tile green body, wherein the surface of the ceramic tile green body is provided with a surface glaze layer; the ceramic tile blank is made of conventional materials and in a conventional manner, for example, the blank is subjected to conventional procedures such as ball milling, compression molding and the like.
The method comprises the steps of adopting two groups of spray heads, spraying bright and carved ink to the surface of a surface glaze layer of a ceramic tile blank to form bright textures by one group of spray heads, then spraying matte and deep carved ink to form matte textures by the other group of spray heads, respectively spraying the matte and deep carved ink and the bright and deep carved ink to different areas of the surface of the ceramic tile blank, so that the bright textures and the matte textures existing simultaneously are formed on the surface of the ceramic tile blank, and forming the appearance form combining bright and matte on the surface of the tile body through secondary printing.
And then, printing antibacterial ink to form an antibacterial layer, so that a certain antibacterial property can be formed, and the functionality of the ceramic tile is improved. The ink-jet printing amount of the bright finishing carving ink and the matte deep engraving ink is 15g/m 2， The antibacterial ink has an ink-jet printing amount of 8g/m 2， 。
And then drying and sintering to obtain a ceramic tile finished product.
EXAMPLE III
The prepared bright engraving ink comprises the following components in parts by mass: 15 parts of high-temperature clinker, 13 parts of fused quartz, 4 parts of calcined zinc oxide, 10 parts of zirconium silicate, 3 parts of diaspore and 2 parts of oxidized silica6 parts of dispersing agent, 4 parts of defoaming agent and 43 parts of solvent. The solvent is a mixture of isopropyl laurate and methyl oleate, wherein the mass part of the isopropyl laurate accounts for 50 parts, and the mass part of the methyl oleate accounts for 50 parts. The high-temperature frit consists of the following components in parts by mass: siO 2 2 65 parts of Al 2 O 3 15 parts of, K 2 O5 parts, na 2 5 parts of O, 5 parts of ZnO and 5 parts of CaO. The dispersant is a polyurethane type dispersant. The addition of bismuth oxide can effectively improve the activity and promote the catalysis. The high-temperature frit can be combined with the glaze layer of the ceramic tile more firmly.
The matte deep engraving ink is prepared from the following components in parts by mass: 15 parts of high-temperature frit, 13 parts of fused quartz, 4 parts of wollastonite, 10 parts of zirconium silicate, 3 parts of diaspore, 2 parts of oxidized silica, 6 parts of a dispersing agent, 4 parts of a defoaming agent and 43 parts of a solvent. The solvent is a mixture of isopropyl laurate and methyl oleate, wherein the mass part of the isopropyl laurate accounts for 40 parts, and the mass part of the methyl oleate accounts for 60 parts. The high-temperature frit consists of the following components in parts by mass: siO 2 2 50 parts of Al 2 O 3 30 parts of, K 2 O5 parts, na 2 5 parts of O, 5 parts of ZnO and 5 parts of CaO. The dispersant is a polyurethane type dispersant.
The prepared antibacterial ink comprises the following components in parts by weight: 45 parts of titanium dioxide, 25 parts of silicon nitride, 10 parts of phosphorus pentoxide, 10 parts of potassium oxide, 5 parts of strontium oxide and 5 parts of silver ions, wherein the silver ions can be formed by a load carrying silver ions. Dissolving butyl titanate and ethyl orthosilicate in isopropanol, and stirring to obtain an antibacterial precursor solution; mixing titanium dioxide, silicon nitride, phosphorus pentoxide, potassium oxide, strontium oxide and silver ions together and grinding to form mixed powder. And adding the mixed powder into the antibacterial precursor solution, uniformly stirring, and filtering to obtain the antibacterial ink. The potassium oxide and the strontium oxide can improve certain alkalinity, can improve the color of a glaze surface to a certain extent, and cannot influence the original pigment.
A preparation method of a ceramic tile with bright, carved, matte and deep-carved stereoscopic textures comprises the following steps:
preparing a ceramic tile green body, wherein the surface of the ceramic tile green body is provided with a surface glaze layer; the ceramic tile blank is made of conventional materials and in a conventional manner, for example, the blank is subjected to conventional procedures such as ball milling, compression molding and the like.
The method comprises the steps of adopting two groups of spray heads, spraying bright and carved ink to the surface of a surface glaze layer of a ceramic tile blank to form bright textures by one group of spray heads, then spraying matte and deep carved ink to form matte textures by the other group of spray heads, respectively spraying the matte and deep carved ink and the bright and deep carved ink to different areas of the surface of the ceramic tile blank, so that the bright textures and the matte textures existing simultaneously are formed on the surface of the ceramic tile blank, and forming the appearance form combining bright and matte on the surface of the tile body through secondary printing.
And then, the antibacterial ink is printed to form an antibacterial layer, so that a certain antibacterial property can be formed, and the functionality of the ceramic tile is improved. The ink-jet printing amount of the bright finishing carving ink and the matte deep engraving ink is 15g/m 2， The antibacterial ink has an ink-jet printing amount of 8g/m 2， 。
And then drying and sintering to obtain a ceramic tile finished product.
Although the present invention has been described in detail with reference to the embodiments, it will be apparent to those skilled in the art that modifications, equivalents, improvements, and the like can be made in the technical solutions of the foregoing embodiments or in some of the technical features of the foregoing embodiments, but those modifications, equivalents, improvements, and the like are all within the spirit and principle of the present invention.
Claims (9)
1. A preparation method of a ceramic tile with bright, carved, matte and deep stereoscopic textures is characterized by comprising the following steps:
preparing a ceramic tile green body, wherein the surface of the ceramic tile green body is provided with a surface glaze layer;
two groups of spray heads are adopted, wherein one group of spray heads firstly spray bright and precise engraving ink to the surface of the surface glaze layer of the ceramic tile blank to form bright textures, then the other group of spray heads spray matte and deep engraving ink to form matte textures, and the matte and deep engraving ink and the bright and precise engraving ink are respectively sprayed on different areas of the surface of the ceramic tile blank, so that the bright textures and the matte textures existing at the same time are formed on the surface of the ceramic tile blank;
printing antibacterial ink to form an antibacterial layer;
and then drying and sintering to obtain a ceramic tile finished product.
2. The preparation method of the bright carved matte deep-carved three-dimensional texture ceramic tile as claimed in claim 1, wherein the carved black water consists of the following components in parts by weight and 100:
3-25 parts of high-temperature frit, 5-13 parts of fused quartz, 1-4 parts of calcined zinc oxide, 5-20 parts of zirconium silicate, 1-5 parts of diaspore, 1-3 parts of oxidized silica, 2-6 parts of a dispersant, 1-5 parts of a defoaming agent and 35-65 parts of a solvent;
the high-temperature frit consists of the following components in parts by mass, wherein the components are counted in the sum of 100:
35-65 parts of SiO 2 15-30 parts of Al 2 O 3 5-10 parts of K 2 O, 5-10 parts of Na 2 O, 5-10 parts of ZnO and 5-10 parts of CaO.
3. The preparation method of the bright carved matte deeply textured ceramic tile as claimed in claim 2, wherein the matte deeply textured ink consists of the following components in parts by weight and 100 parts by weight:
3-20 parts of high-temperature frit, 5-13 parts of fused quartz, 1-5 parts of wollastonite, 5-20 parts of zirconium silicate, 1-5 parts of diaspore, 1-3 parts of oxidized silica, 2-6 parts of a dispersing agent, 1-5 parts of a defoaming agent and 35-65 parts of a solvent.
4. The method for preparing the ceramic tile with the bright, carved, matte and deep stereoscopic textures as claimed in claim 3, wherein the dispersant is one or a combination of polyurethane type dispersant and polymerized hydrogenated ricinoleic acid.
5. The method for preparing the ceramic tile with the bright and carved matte and deep stereoscopic textures as claimed in claim 4, wherein the defoaming agent is one or a combination of BYK-055 and BYK-028.
6. The method for preparing the ceramic tile with the bright and carved matte and deep stereoscopic textures as claimed in claim 5, wherein the solvent is one or a combination of more than two of mineral oil, isopropyl laurate, methyl oleate and isooctyl cocoate.
7. The preparation method of the bright carved matte deep-carved three-dimensional texture ceramic tile according to claim 6, wherein the antibacterial ink comprises the following components in parts by weight, wherein the components are in the sum of 100:
30-50 parts of titanium dioxide, 15-30 parts of silicon nitride, 10-20 parts of phosphorus pentoxide, 10-15 parts of potassium oxide, 3-8 parts of strontium oxide and 1-5 parts of silver ions.
8. The preparation method of the ceramic tile with the bright, carved, matte and deep stereoscopic textures as claimed in claim 8, wherein the antibacterial ink is prepared according to the following steps:
dissolving butyl titanate and ethyl orthosilicate in isopropanol, and stirring to obtain an antibacterial precursor solution;
mixing 30-50 parts of titanium dioxide, 15-30 parts of silicon nitride, 10-20 parts of phosphorus pentoxide, 10-15 parts of potassium oxide, 3-8 parts of strontium oxide and 1-5 parts of silver ions together and grinding the mixture to form mixed powder;
and adding the mixed powder into the antibacterial precursor solution, uniformly stirring, and filtering to obtain the antibacterial ink.
9. The method for preparing the ceramic tile with the bright carved matte and the deep carved stereoscopic texture as claimed in claim 9, wherein the ink-jet printing amount of the bright carved ink and the matte deep carved ink is 10-20 g/m 2， The ink-jet printing amount of the antibacterial ink is 5-10g/m 2， 。
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210862024.2A CN115635570A (en) | 2022-07-20 | 2022-07-20 | Preparation method of ceramic tile with bright, carved, matte and deep-carved three-dimensional texture |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210862024.2A CN115635570A (en) | 2022-07-20 | 2022-07-20 | Preparation method of ceramic tile with bright, carved, matte and deep-carved three-dimensional texture |
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| CN115635570A true CN115635570A (en) | 2023-01-24 |
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| CN202210862024.2A Pending CN115635570A (en) | 2022-07-20 | 2022-07-20 | Preparation method of ceramic tile with bright, carved, matte and deep-carved three-dimensional texture |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116969779A (en) * | 2023-09-22 | 2023-10-31 | 陶丽西(苏州)陶瓷釉色料有限公司 | Ultrathin ceramic tile with concave-convex textures and preparation method thereof |
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2022
- 2022-07-20 CN CN202210862024.2A patent/CN115635570A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116969779A (en) * | 2023-09-22 | 2023-10-31 | 陶丽西(苏州)陶瓷釉色料有限公司 | Ultrathin ceramic tile with concave-convex textures and preparation method thereof |
| CN116969779B (en) * | 2023-09-22 | 2024-01-05 | 陶丽西(苏州)陶瓷釉色料有限公司 | Ultrathin ceramic tile with concave-convex textures and preparation method thereof |
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