CN115590788B - 可发泡清洁组合物 - Google Patents
可发泡清洁组合物 Download PDFInfo
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- CN115590788B CN115590788B CN202211264047.XA CN202211264047A CN115590788B CN 115590788 B CN115590788 B CN 115590788B CN 202211264047 A CN202211264047 A CN 202211264047A CN 115590788 B CN115590788 B CN 115590788B
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- skin cleansing
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- RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000004094 surface-active agent Substances 0.000 claims abstract description 17
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 16
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 10
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- 125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 claims description 6
- 229940071160 cocoate Drugs 0.000 claims description 5
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- 125000003104 hexanoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 5
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- 238000000034 method Methods 0.000 claims description 5
- MRUAUOIMASANKQ-UHFFFAOYSA-O carboxymethyl-[3-(dodecanoylamino)propyl]-dimethylazanium Chemical group CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)=O MRUAUOIMASANKQ-UHFFFAOYSA-O 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
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- 239000003945 anionic surfactant Substances 0.000 claims description 3
- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 claims description 3
- IIRDTKBZINWQAW-UHFFFAOYSA-N hexaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCO IIRDTKBZINWQAW-UHFFFAOYSA-N 0.000 claims description 3
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- GBMPATKVZSIKPO-UYWIDEMCSA-N n-methyl-n-[(2s,3r,4r,5r)-2,3,4,5,6-pentahydroxyhexyl]tetradecanamide Chemical compound CCCCCCCCCCCCCC(=O)N(C)C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO GBMPATKVZSIKPO-UYWIDEMCSA-N 0.000 claims description 3
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- OPJWPPVYCOPDCM-UHFFFAOYSA-N 2-ethylhexyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC OPJWPPVYCOPDCM-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- DLAHAXOYRFRPFQ-UHFFFAOYSA-N dodecyl benzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1 DLAHAXOYRFRPFQ-UHFFFAOYSA-N 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 2
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 claims description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 claims description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 claims 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims 2
- AFSHUZFNMVJNKX-UHFFFAOYSA-N 1,2-di-(9Z-octadecenoyl)glycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(CO)OC(=O)CCCCCCCC=CCCCCCCCC AFSHUZFNMVJNKX-UHFFFAOYSA-N 0.000 claims 1
- AFSHUZFNMVJNKX-LLWMBOQKSA-N 1,2-dioleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](CO)OC(=O)CCCCCCC\C=C/CCCCCCCC AFSHUZFNMVJNKX-LLWMBOQKSA-N 0.000 claims 1
- SJZXQPSYVNYKFD-UHFFFAOYSA-N CCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O Chemical compound CCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O SJZXQPSYVNYKFD-UHFFFAOYSA-N 0.000 claims 1
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- 150000001733 carboxylic acid esters Chemical class 0.000 claims 1
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- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims 1
- 229940089456 isopropyl stearate Drugs 0.000 claims 1
- 229920000570 polyether Polymers 0.000 claims 1
- ZPWFUIUNWDIYCJ-UHFFFAOYSA-N propan-2-yl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(C)C ZPWFUIUNWDIYCJ-UHFFFAOYSA-N 0.000 claims 1
- 238000009472 formulation Methods 0.000 description 24
- 239000007788 liquid Substances 0.000 description 20
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 238000005187 foaming Methods 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
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- 235000011187 glycerol Nutrition 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 229940057950 sodium laureth sulfate Drugs 0.000 description 4
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 4
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- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 3
- 235000010234 sodium benzoate Nutrition 0.000 description 3
- 239000004299 sodium benzoate Substances 0.000 description 3
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- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
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- 239000000828 canola oil Substances 0.000 description 2
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- 150000002170 ethers Chemical class 0.000 description 2
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
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- DRAWQKGUORNASA-UHFFFAOYSA-N (2-hydroxy-3-octadec-9-enoyloxypropyl) octadec-9-enoate Chemical compound CCCCCCCCC=CCCCCCCCC(=O)OCC(O)COC(=O)CCCCCCCC=CCCCCCCCC DRAWQKGUORNASA-UHFFFAOYSA-N 0.000 description 1
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
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- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- AZLWQVJVINEILY-UHFFFAOYSA-N 2-(2-dodecoxyethoxy)ethanol Chemical compound CCCCCCCCCCCCOCCOCCO AZLWQVJVINEILY-UHFFFAOYSA-N 0.000 description 1
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- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- QHOSFZIXOKVGHK-UHFFFAOYSA-N 2-oxohexanal Chemical compound CCCCC(=O)C=O QHOSFZIXOKVGHK-UHFFFAOYSA-N 0.000 description 1
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- 239000004471 Glycine Substances 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
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- 235000021314 Palmitic acid Nutrition 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
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- 125000003158 alcohol group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
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- 239000003963 antioxidant agent Substances 0.000 description 1
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- MSWZFWKMSRAUBD-UHFFFAOYSA-N beta-D-galactosamine Natural products NC1C(O)OC(CO)C(O)C1O MSWZFWKMSRAUBD-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
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- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
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- 238000011010 flushing procedure Methods 0.000 description 1
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- 239000008103 glucose Substances 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 229940031726 laureth-10 Drugs 0.000 description 1
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- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
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- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
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- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
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- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 description 1
- 229940066675 ricinoleate Drugs 0.000 description 1
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- 229910052710 silicon Inorganic materials 0.000 description 1
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- 239000011780 sodium chloride Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
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- 125000006850 spacer group Chemical group 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
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- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
-
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Abstract
本发明描述了可发泡皮肤和手部清洁组合物,其包含在每种情况中基于清洁组合物的总组成的以下组分:a)0.1重量%至5重量%的至少一种乳化剂;b)0.5重量%至7重量%的至少一种油,尤其是烷基脂肪酸酯;c)0重量%至10重量%的至少一种疏水性润肤剂;d)5重量%至20重量%的至少一种用作去污剂的表面活性剂;e)0.5重量%至12重量%的至少一种脂肪酸葡糖酰胺;f)1重量%至8重量%的至少一种用作发泡剂的表面活性剂;g)0重量%至1重量%的至少一种防腐剂;h)0重量%至1重量%的pH调节剂;i)0重量%至10重量%的一种或多种助剂或添加剂;j)用于补足100重量%的水。
Description
本发明涉及可发泡皮肤和手部清洁组合物,尤其涉及适合与倒置空气泵组合使用以产生发泡产品的那些。
液体皮肤和手部清洁制剂通常是本领域已知的。它们通常设置在容器中,所述容器倾倒或具有泵以将液体组合物泵送到待清洁的皮肤上。这种液体皂通常具有非常好的清洁效率。
在放置在于皮肤或手上手之前发泡的制剂在本领域中通常也是已知的。泡沫倾向于比相应的液体更容易扩散,此外,由于泡沫具有比液体高得多的表面张力,因此由于飞溅或流出的引起的浪费更少。与液体皂相比,与泡沫相关的一个问题是它们往往倾向于具有较低的清洁效率。然而,泡沫具有比不发泡液体高得多的表面积,因此如果泡沫的清洁效率可以提高,则可以生产具有与使用不发泡液体获得的相同清洁能力的泡沫,但其需要更少的要待使用的初始液体。
许多清洁制剂使用油和乳化剂的组合来帮助去除待处理的皮肤或手的污垢。申请人决定尝试和生产这种能够发泡的基于油的清洁制剂。
发泡泵通常是本领域已知的。它们通常是立式的,其中可发泡液体放置在诸如瓶子的容器内。泵送单元连接至瓶子的顶部并且包括分配器,所述分配器向下泵送至瓶子并迫使空气通过液体以使泡沫从分配器分配至皮肤或手上。当申请人试图用这种立式泵生产制剂时,它们能够通过添加诸如月桂基胺氧化物和甜菜碱的常规洗涤添加剂来生产合适的泡沫。
还已知倒置泵,其中泡沫分配器设置在放置于例如房间的墙壁上的分配器内的容器的底部。这种分配器的优点在于,可发泡液体不需要通过向下延伸至容器底部的管道从储存容器的底部泵送。这消除了与这种立式容器相关的问题,即当液体耗尽时,必须在泵送程序中施加较大的力,以便在分配液体期间从容器的底部升起液体。倒置泡沫分配器示于例如WO 99/49769和WO 2014/138958中。这种分配器从分配器的底部起泡,而不是顶部泵泡沫分配器。发泡元件和/或泵通常位于容器的底部。在启动泵(例如,手动操作的泵)时,泡沫从分配器的底部排出,以通过分配器的发泡组件或元件排出可发泡组合物。
然而,当申请人试图使用基于油和乳化剂的清洁制剂时,与常规洗涤添加剂结合时,他们发现它们不能从倒置的分配器获得令人满意的品质的泡沫,尽管事实上相同的制剂与常规立式分配器一起使用。尝试了宽范围的不同的添加剂,直到申请人意外地发现了一类允许产生制剂的添加剂,其可以用于倒置和立式泡沫分配器。
这个问题的解决方案并不是立即显而易见的,因为仍然发现包含不含油的洗涤添加剂的制剂存在从倒置分配器分配的问题。只有当洗涤添加剂与油和乳化剂结合时才能解决倒置分配器的问题。
用于克服使用倒置泡沫分配器的问题的添加剂的种类被称为脂肪酸葡糖酰胺。这些先前已用于洗涤和清洁制剂以及化妆品工业中作为表面活性剂。通常在EP 1072615中描述并且可以以商品名GlucotainTM从德国Clariant GmbH商购获得。它们通常由糖(例如,D-葡萄糖)经由与甲胺的反应和氢化以打开葡萄糖的结构来产生葡糖胺而产生。然后将其与例如脂肪酸甲酯或甘油三酯反应以产生葡糖酰胺。
因此,本发明提供了可发泡皮肤和手部清洁组合物,其包含在每种情况中基于清洁组合物的总组成的以下组分:
a)0.1重量%至5重量%的至少一种乳化剂;
b)0.5重量%至7重量%的至少一种油;
c)0重量%至10重量%的至少一种疏水性润肤剂;
d)5重量%至20重量%的至少一种用作去污剂的表面活性剂;
e)0.5重量%至12重量%的至少一种脂肪酸葡糖酰胺
f)1重量%至8重量%的至少一种用作发泡剂的表面活性剂
g)0重量%至1重量%的至少一种防腐剂
h)0重量%至1重量%的pH调节剂
i)0重量%至10重量%的一种或多种助剂或添加剂
j)用于补足100重量%的水。
所述组合物通常包含0.7重量%至10重量%,或1重量%至重量%的至少一种脂肪酸葡糖酰胺(e)。脂肪酸葡糖酰胺(e)通常具有通式:
其中:
R1=H或C1至C4烷基,最通常为H或-CH3,尤其是-CH3
R2=C6至C20直链或支链的烃残基,最通常为C8至C18直链或无支链的烃残基。烃残基可以是饱和的或不饱和的。
可以使用葡糖胺的混合物。例如,葡糖酰胺可以是辛酰基/己酰基甲基葡糖酰胺;月桂酰基/肉豆蔻酰基甲基葡糖酰胺;或椰油酰基甲基葡糖酰胺的混合物。也可以使用这些的混合物,例如,可以使用椰油酰基甲基葡糖酰胺和辛酰基/己酰基甲基葡糖酰胺的混合物。最典型地,葡糖酰胺是椰油酰基甲基葡糖酰胺,其包含来自椰子油的脂肪酸残基。
油(b)可以是烷基脂肪酸酯,最通常是异丙基脂肪酸酯或乙基己基脂肪酸酯。酯的脂肪酸部分可以是C6至C20,例如C12至C15饱和的或不饱和的脂肪酸。这些包括,例如,饱和脂肪酸,并且包括肉豆蔻酸、棕榈酸和硬脂酸,以及诸如来自菜籽油的脂肪酸的混合物,例如衍生自菜籽油。最典型地,烷基部分包含1-5个碳,包括甲基、乙基、丙基、丁基、异丙基、戊基或乙基己基,或者是苯甲酸烷基酯,例如C12至C15苯甲酸C12至C15烷基酯。更通常地,烷基是异丙基或乙基己基,尤其是异丙基。可以使用两种或多种油的混合物。最典型的地,油是肉豆蔻酸异丙酯或肉豆蔻酸异丙酯和棕榈酸异丙酯的混合物。可以使用硬脂酸乙基己酯。油通常是基本上透明的油。该所述组合物可可以包含1重量%至5wt重量%,、或3重量%至5wt重量%的油。
乳化剂(a)可可以选自本领域通常已知的那些,包括PEG-18蓖麻二油酸酯、聚甘油4-己酸酯、氢化蓖麻油、PEG-10甘油基二油酸甘油酯和双子表面活性剂及其混合物。双子表面活性剂是具有多于一个疏水尾部和亲水头部基团的表面活性剂分子的家族。双子表面活性剂通常具有比相同链长的相应常规表面活性剂更好的表面活性性质。例如,它们具有通过间隔物彼此连接的疏水性至亲水性头基头部基团。这些描述在例如S.K.Hate和S.P.Moulik,Current Science,Vol 82(9)(2002)1101-1111的评论文章中有所描述。
最典型地,乳化剂是PEG-18蓖麻油二油酸酯、双子表面活性剂或PEG 10-二油酸酯,尤其是PEG-10二油酸酯或双子表面活性剂。
可以使用的其他乳化剂是甘油聚醚-7辛酸酯/癸酸酯(Emanon Ev-E)。
所述组合物可以包含1重量%至5重量%的乳化剂(a)或2重量%至3重量%的乳化剂(a)。
润肤剂(c)可以是任何合适的润肤剂,其也被称为本领域已知的增溶剂,但通常是PEG-7椰油酸甘油酯。其他合适的润肤剂包括聚甘油4癸酸酯、甘油聚醚-2椰油酸酯或PEG-6辛酸/癸酸甘油酯。
润肤剂通常具有至少10且通常至少12的HLB值。
它们通常是多元醇酯,例如聚甘油偏酯或聚甘油脂肪酸酯,根据本发明特别优选的是例如聚甘油-3癸酸酯或聚甘油-4癸酸酯,其可以以名称TEGOSOFTPC31和TEGOSOFT/>PC41从Degussa获得。
此外,用于本发明目的的多元醇酯是聚乙二醇酯,例如PEG-7椰油酸甘油酯(如上所述),其可从Croda Chemicals Europe Ltd.以名称Glycerox HE获得。
所述组合物通常包含8重量%至15重量%的阴离子表面活性剂(d)。阴离子表面活性剂可以是,例如,烷基硫酸盐,例如十二烷基硫酸钠或铵,或者烷基醚硫酸盐例如月桂醇聚醚硫酸钠。其他合适的表面活性剂包括α-烯烃磺酸钠、N-椰油酰谷氨酸钠盐、烷基脂肪酸羟乙基磺酸盐、烷基羟基磺基甜菜碱、烷基酰氨基丙基甜菜碱、N-椰油酰基甘氨酸钠盐、磺化和硫酸化的蓖麻油。
可以使用2%至3%的发泡剂(f)。发泡剂通常是本领域已知的。这通常不是含硅发泡剂,因为已发现它们改变了汽车工业中涂漆表面的能力。它们包括,例如,椰油酰氨基丙基甜菜碱、辛酰基/己酰氨基丙基甜菜碱脂肪醇醚羧酸和羧酸酯、链烷醇酰胺和氧化胺、乙氧基化烷基磺基琥珀酸酯。
可以使用至多1重量%的一种或多种防腐剂(g)。这些通常是本领域已知的,并且包括例如1,2-己二醛、辛二醇和环庚三烯酚酮。更典型地,使用苯甲酸钠。可以通过添加更多或更多pH调节剂(例如柠檬酸)来调节制剂的pH。
在制剂中可以使用0重量%-10重量%,更通常2重量%-8重量%或3重量%-7重量%的一种或多种助剂或添加剂(i)。这些通常是本领域技术人员已知的。它们可以包括例如,稠度调节剂、芳香剂、诸如聚合物的增稠剂、无机和有机UV光保护过滤剂、颜料、抗氧化剂、植物提取物、稳定剂和保湿剂。可以使用0%-1%,更典型地0.1%-0.8%的芳香剂。这改善了组合物的气味。这种芳香剂通常是本领域已知的。
通常,不向制剂中添加额外的助剂。
使用水将组合物补足至100重量%。
通常,组合物占组合物总重量的7%-20%。洗涤活性物质是表面活性剂、烷基葡糖酰胺和发泡剂的总重量。(D、E、F。)
更通常地,洗涤添加剂含有8重量%-16重量%或10重量%-14重量%的洗涤添加剂。
还提供了所述组合物用于皮肤和/或手洗涤的用途以及将制剂用于皮肤和/或手洗涤的组合物的方法。
现在将参考下图仅以实例的方式描述本发明:
图1示出与StephalenTM清新泡沫和RefreshTM天蓝色泡沫相比,并与两种液体清洁剂GojoEco SoyTM和EstesolTM温和清洗剂相比,根据本发明制备的两种泡沫(Estesol纯泡沫和Estesol泡沫)的平均清洁效率。
泡沫生产
使用可从Albea(Le Cignac,Gennevilliers,France)商购获得的立式泡沫泵测试下述制剂。倒置泵(Optidose)是可从英国Deb Limited获得的市售壁挂式分配器。
清洁性能
通常使用以下方法进行清洁性能:
使用标准化污渍或涂料的洗手测试的测试模型给出了关于待测试产品的清洁效果的信息。为了实践中的相关性,所有受试者必须在手掌上具有由手工操作引起的特征性皮肤结构。一次使用一种产品,在上午和下午进行以下测试:
具有水的测试程序:
将0.5g的污渍(模型污渍、实践污渍或涂料)分布在手掌和手背上并且擦拭
静置干燥1 1/2分钟
施用1.2g的清洁组合物并且擦拭
添加1ml的水并洗涤30秒
再添加1ml的水并洗涤30秒
在冷的自来水下冲洗
根据比例对手背和手掌上的残留污渍(RS)进行视觉评估,见下文
无水的测试程序:
将0.5g的污渍(模型污渍、实践污渍或涂料)分布在手掌和手背上并且擦拭
静置干燥1 1/2分钟
施用1.2g的清洁组合物并且擦拭
使用纤维素纸,将手部表面上的污渍与产品一起去除
根据比例对手背和手掌上的残留污渍(RS)进行视觉评估,见下文0=清洁5=没有清洁效果(以0.5的步长分级是可能的)
根据以下式计算清洁效果百分比:
RSpalm=n个测量系列(受试者)的手掌上残留污渍的平均值。
RSback=n个测量系列(受试者)的手背上的残留污渍的平均值。
由于清洁效果的劣化具有较宽的变化范围,因此允许两个测量系列之间的5%的绝对偏差。
合适的模型污渍的组成:
火焰烟尘:5.42%
氧化铁(Fe2O3):0.72%
比较例1
现有技术制剂Sasol编号11574。
Sasol制剂11574是温和的护理沐浴泡沫组合物,其包含油并且类似于发明人试图鉴定的预期最终产品。使用传统的立式Albea发泡器,可以使制剂发泡。然而,倒置的Optidose泵不能产生泡沫。
比较例2
比较例2显示出含有脂肪酸烷基葡糖酰胺的基于非油的清洁剂。同样,该制剂能够使用立式发泡器发泡,但是不能使用倒置发泡装置产生泡沫并且其也没有合适的清洁性能。
在使用倒置发泡器确定问题时,申请人尝试了许多不同类型的添加剂以试图产生令人满意的在立式泵和倒置泵中均产生发泡的组合物。这些包括:
非离子型如脂肪醇乙氧基化物,例如十三烷醇的聚乙二醇醚,其具有良好的清洁功效但抑制泡沫品质。用脂肪醇乙氧基化物稳定泡沫的各种试验都失败了。
改善发泡与清洁性质相结合。申请人还尝试了月桂醇聚醚-6羧酸和MIPA月桂醇聚醚硫酸盐。尝试烷基聚葡萄糖、月桂醇聚醚磺基琥珀酸二钠、月桂醇聚醚-10、椰油酰两性丙酸钠和N,N-二甲基9-癸烯酰胺作为替代品,但也失败了。
从聚乙二醇醚至甲基葡糖酰胺(例如,辛酰基/己酰基甲基葡糖酰胺、月桂酰基/肉豆蔻酰基甲基葡糖酰胺、椰油酰基甲基葡糖酰胺)的变化在发泡时表现出至少有益效果并且提供良好的清洁性能。
结果表明,将油与脂肪酸烷基葡糖酰胺组合产生可以用于立式和倒置发泡泵的制剂。使用不含烷基葡糖酰胺的替代制剂,使用倒置泵产生具有较低泡沫品质的制剂。
图1显示出两种制剂(Estesol纯泡沫和Estesol泡沫)与两种市售发泡组合物和两种液体清洁组合物相比的平均清洁功效。Estesol泡沫均基于制剂A3。Estesol泡沫具有0.2重量%的芳香剂和0.001重量%的染料,并且添加的水的量减少。
StephalenTM清新泡沫可从德国Euskirchen的Peter Greven Physioderm GmbH获得并包含
水、
甘油、
月桂醇聚醚硫酸钠、
PEG-7椰油酸甘油酯、
椰油酰氨基丙基甜菜碱、
柠檬酸钠、
柠檬酸、
苯甲酸钠、
山梨酸钾、
香料以及
C.I.42051
RefreshTM天蓝色泡沫可从英国Deb Limited获得。它含有:
Aqua
月桂醇聚醚硫酸钠
丙二醇
甘油
PEG-7椰油酸甘油酯
椰油酰氨基丙基甜菜碱
香料
柠檬酸
2-溴-2-硝基丙烷-1,3-二醇
甲基氯异噻唑啉酮
甲基异噻唑啉酮
硝酸镁
氯化镁
CI 42090
GojoTMEco SoyTM是可从Gojo获得的液体手部清洁剂。它是基于醇的手部清洁剂,并且包括:
水
富含乙氧基化支链C11-14、C13的醇
脂肪酸、大豆甲基酯
聚氧乙烯十三烷基醚
乙醇
丙二醇
丙-2-醇
Estesol温和洗液可从英国Deb Limited获得,包括:
Aqua
月桂醇聚醚硫酸钠
氯化钠
月桂醇聚醚磺基琥珀酸二钠
月桂醇聚醚-2
磺化蓖麻油
乙二醇二硬脂酸酯
硬脂醇聚醚-4
聚季铵盐-7
柠檬酸
PEG-30椰油酸甘油酯
苯甲酸钠
附图显示出常规的泡沫产品具有比常规液体的、未发泡的手部清洁剂更低的清洁效果。本发明的发泡组合物产生的泡沫的清洁效率超过常规发泡组合物,并且超过或与液体清洁组合物相当。
Claims (21)
1.包含可发泡皮肤清洁组合物的倒置泡沫分配器,所述可发泡皮肤清洁组合物包含在每种情况中基于清洁组合物的总组成的以下组分:
a)0.1重量%至5重量%的至少一种乳化剂,其选自PEG-18蓖麻油二油酸酯、聚甘油4-己酸酯、氢化蓖麻油、PEG-10二油酸甘油酯、甘油聚醚-7辛酸酯/癸酸酯、双子表面活性剂及其混合物;
b)0.5重量%至7重量%的至少一种油;
c)0重量%至10重量%的至少一种疏水性润肤剂,其选自多元醇酯;
d)5重量%至20重量%的至少一种用作去污剂的表面活性剂;
e)0.5重量%至12重量%的至少一种脂肪酸甲基葡糖酰胺;
f)1重量%至8重量%的至少一种用作发泡剂的表面活性剂;
g)0重量%至1重量%的至少一种防腐剂;
h)0重量%至1重量%的pH调节剂;
i)0重量%至10重量%的一种或多种助剂或添加剂;
j)用于补足100重量%的水。
2.根据权利要求1所述的包含可发泡皮肤清洁组合物的倒置泡沫分配器,其中所述可发泡皮肤清洁组合物是可发泡手部清洁组合物。
3.根据权利要求1所述的包含可发泡皮肤清洁组合物的倒置泡沫分配器,其中所述油(b)是烷基脂肪酸酯。
4.根据权利要求1所述的包含可发泡皮肤清洁组合物的倒置泡沫分配器,其中所述疏水性润肤剂选自PEG 7椰油酸甘油酯、聚甘油4癸酸酯、甘油聚醚2-椰油酸酯、PEG-6辛酸/癸酸甘油酯、聚甘油3癸酸酯、聚甘油4-癸酸酯及其混合物。
5.根据权利要求1所述的包含可发泡皮肤清洁组合物的倒置泡沫分配器,包含1%至5.5%的脂肪酸甲基葡糖酰胺(e)。
6.根据权利要求1或5所述的包含可发泡皮肤清洁组合物的倒置泡沫分配器,其中所述至少一种脂肪酸葡糖酰胺具有通式:
其中:
R1=-CH3,
R2=C6至C20直链或支链、饱和或不饱和的烃残基。
7.根据权利要求6所述的包含可发泡皮肤清洁组合物的倒置泡沫分配器,其中R2是C8至C18直链支链或无支链的、饱和或不饱和的烃残基。
8.根据权利要求1所述的包含可发泡皮肤清洁组合物的倒置泡沫分配器,其中所述脂肪酸甲基葡糖酰胺(e)包括选自辛酰基/己酰基甲基葡糖酰胺、月桂酰基/肉豆蔻酰基甲基葡糖酰胺;以及椰油酰基甲基葡糖酰胺的混合物。
9.根据权利要求1所述的包含可发泡皮肤清洁组合物的倒置泡沫分配器,其中所述脂肪酸甲基葡糖酰胺(e)是椰油酰基甲基葡糖酰胺。
10.根据权利要求1所述的包含可发泡皮肤清洁组合物的倒置泡沫分配器,其中所述油(b)是异丙基或乙基己基脂肪酸酯或苯甲酸烷基酯。
11.根据权利要求10所述的包含可发泡皮肤清洁组合物的倒置泡沫分配器,其中所述油(b)选自硬脂酸乙基己酯、肉豆蔻酸异丙酯、棕榈酸异丙酯、硬脂酸异丙酯和菜籽油的异丙酯或其混合物。
12.根据权利要求1所述的包含可发泡皮肤清洁组合物的倒置泡沫分配器,其中所述组合物包含1重量%至3重量%的油(b)。
13.根据权利要求1所述的包含可发泡皮肤清洁组合物的倒置泡沫分配器,其中所述发泡剂选自椰油酰氨基丙基甜菜碱、辛酰基/己酰氨基丙基甜菜碱、脂肪醇醚羧酸和羧酸酯、链烷醇酰胺、氧化胺和乙氧基化烷基磺基琥珀酸酯。
14.根据权利要求1所述的包含可发泡皮肤清洁组合物的倒置泡沫分配器,包含1重量%至3重量%的乳化剂(a)。
15.根据权利要求1所述的包含可发泡皮肤清洁组合物的倒置泡沫分配器,包含PEG-7椰油酸甘油酯、聚甘油-3-癸酸酯、聚甘油4癸酸酯、甘油聚醚-2椰油酸酯或PEG-6辛酸/癸酸甘油酯作为润肤剂(c)。
16.根据权利要求1所述的包含可发泡皮肤清洁组合物的倒置泡沫分配器,其中所述组合物包含8%至15%的阴离子表面活性剂(d)。
17.根据权利要求1所述的包含可发泡皮肤清洁组合物的倒置泡沫分配器,包含2重量%至5重量%的发泡剂(f)。
18.根据权利要求1所述的包含可发泡皮肤清洁组合物的倒置泡沫分配器,其中洗涤活性物质占所述组合物的总重量的7%至20%。
19.权利要求1至18中任一项所述的包含可发泡皮肤清洁组合物的倒置泡沫分配器用于皮肤洗涤的用途。
20.根据权利要求19所述的用途,其中所述皮肤洗涤包括手部洗涤。
21.产生泡沫的方法,包括提供权利要求1至18中任一项所述的倒置泡沫分配器并且操作所述分配器以产生所述泡沫。
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CA3047366C (en) | 2023-10-31 |
RU2019127046A (ru) | 2021-03-23 |
EP3541356B1 (en) | 2020-04-22 |
RU2751633C2 (ru) | 2021-07-15 |
WO2018154298A1 (en) | 2018-08-30 |
US20190374794A1 (en) | 2019-12-12 |
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JP2020508314A (ja) | 2020-03-19 |
AU2018224346B2 (en) | 2023-04-06 |
EP3541356A1 (en) | 2019-09-25 |
CA3047366A1 (en) | 2018-08-30 |
GB201702905D0 (en) | 2017-04-12 |
MX2019010037A (es) | 2019-10-15 |
CN115590788A (zh) | 2023-01-13 |
BR112019017549B1 (pt) | 2022-11-22 |
AU2018224346A1 (en) | 2019-07-04 |
RU2019127046A3 (zh) | 2021-03-23 |
BR112019017549A2 (pt) | 2020-04-07 |
PL3541356T3 (pl) | 2021-01-25 |
CN110312504A (zh) | 2019-10-08 |
JP7071988B2 (ja) | 2022-05-19 |
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