CN115584583A - Skin-friendly antibacterial breathable fabric - Google Patents

Skin-friendly antibacterial breathable fabric Download PDF

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Publication number
CN115584583A
CN115584583A CN202211222474.1A CN202211222474A CN115584583A CN 115584583 A CN115584583 A CN 115584583A CN 202211222474 A CN202211222474 A CN 202211222474A CN 115584583 A CN115584583 A CN 115584583A
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Prior art keywords
antibacterial
fibers
skin
blending
polyester
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CN202211222474.1A
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Chinese (zh)
Inventor
施金鹏
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Jieshouyi New Textile New Material Technology Co ltd
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Jieshouyi New Textile New Material Technology Co ltd
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Priority to CN202211222474.1A priority Critical patent/CN115584583A/en
Publication of CN115584583A publication Critical patent/CN115584583A/en
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    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/208Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
    • D03D15/217Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based natural from plants, e.g. cotton
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/103Agents inhibiting growth of microorganisms
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/208Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
    • D03D15/225Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based artificial, e.g. viscose
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/16Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B21/00Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/10Bamboo
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • D10B2201/22Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24Viscose
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Botany (AREA)
  • Manufacturing & Machinery (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Artificial Filaments (AREA)

Abstract

The invention discloses a skin-friendly antibacterial breathable fabric, which belongs to the technical field of functional fabrics and is formed by blending bamboo fibers, antibacterial polyester fibers and viscose fibers; and the blending ratio of the bamboo fibers, the antibacterial polyester fibers and the viscose fibers is 50/20/30. The fabric is formed by blending the bamboo fibers, the antibacterial polyester fibers and the viscose fibers, the bamboo fibers are natural regenerated cellulose fibers and have good antibacterial and bacteriostatic properties, and the porous structure of the bamboo fibers enables the bamboo fibers to have the characteristics of good moisture absorption and breathability, soft, smooth and full hand feeling; the viscose fiber has good hygroscopicity, is easy to dye, is difficult to generate static electricity and has better spinnability; the antibacterial polyester fiber has the advantages of good strength, safety, high efficiency, lasting washing resistance and antibacterial performance, so that the fabric formed by blending the antibacterial polyester fiber, the antibacterial polyester fiber and the antibacterial polyester fiber has the characteristics of skin friendliness, air permeability and good antibacterial effect, and can meet the requirements of antibacterial textiles.

Description

Skin-friendly antibacterial breathable fabric
Technical Field
The invention belongs to the technical field of functional fabrics, and particularly relates to a skin-friendly antibacterial breathable fabric.
Background
The garment is a product directly contacted with a human body, and in order to ensure the comfort of the garment, the fabric has good skin-friendly property. In addition, in life, people always have inevitable contact with various microorganisms, the microorganisms are parasitic on textiles, common textiles have no antibacterial performance, certain secretions of human bodies provide nutrients for bacteria to cause the bacteria to grow continuously, the microorganisms not only pollute the environment, but also cause a plurality of diseases, particularly workers in special industries, such as medical staff, animal breeders and the like, work in the environment with thousands of bacteria every day, and various diseases are caused to be cross-infected, so that the health is influenced.
In order to improve the antibacterial performance of the fabric, the prior art mostly adopts a mode of finishing by adopting an antibacterial finishing agent; the traditional antibacterial finishing adopts chemical agents, and the method has the characteristics of simple process and low processing cost, but also has the following great defects: 1. the durability of the antibacterial is poor, and the antibacterial function is almost not realized after 5 to 10 times of washing; 2. the chemical agent has certain irritation and toxic and side effects on human skin, thereby having influence on human health. Therefore, it is of great significance to find a functional fabric with skin-friendly, breathable, durable antibacterial effect and wash-resistant performance.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides a skin-friendly antibacterial breathable fabric.
The fabric is formed by blending the bamboo fibers, the antibacterial polyester fibers and the viscose fibers, the bamboo fibers are natural regenerated cellulose fibers and have good antibacterial and bacteriostatic properties, and the porous structure of the bamboo fibers enables the bamboo fibers to have the characteristics of good moisture absorption and breathability, soft, smooth and full hand feeling; the viscose fiber has good hygroscopicity, is easy to dye, is difficult to generate static electricity and has better spinnability; the antibacterial polyester fiber has the advantages of good strength, safety, high efficiency, lasting washing resistance and antibacterial performance, so that the fabric formed by blending the antibacterial polyester fiber, the antibacterial polyester fiber and the antibacterial polyester fiber has the characteristics of skin friendliness, air permeability and good antibacterial effect, and can meet the requirements of antibacterial textiles.
The purpose of the invention can be realized by the following technical scheme:
a skin-friendly antibacterial breathable fabric is formed by blending bamboo fibers, antibacterial polyester fibers and viscose fibers; and the blending ratio of the bamboo fibers, the antibacterial polyester fibers and the viscose fibers is 50/20/30.
Further, the antibacterial polyester fiber is prepared by the following steps:
s1, adding piperazine and acetone into a dry three-neck flask with a stirring device and a reflux device, vacuumizing at normal temperature, and introducing N 2 After three iterations, at N 2 Slowly dropping an acetone solution dissolved with allyl alcohol glycidyl ether into a flask under protection and stirring, stirring and reacting for 2 hours at a constant temperature of 50-55 ℃ after the dropping is finished, and removing acetone by rotary evaporation after the reaction is finished to obtain an intermediate; the dosage ratio of the acetone solution of piperazine, acetone and allyl alcohol glycidyl ether is 0.1mol; the concentration of the acetone solution of allyl alcohol glycidyl ether is 1.025mol/L;
the-NH-on the piperazine molecule and the epoxy group on the allyl alcohol glycidyl ether molecule are subjected to ring-opening reaction to obtain an intermediate, and the reaction process is as follows:
Figure BDA0003877847720000021
s2, adding the intermediate and chloroform into a three-neck flask, stirring and mixing uniformly, adding bromobutane, carrying out reflux reaction for 6 hours under the conditions of magnetic stirring and 70 ℃, after the reaction is finished, carrying out rotary evaporation to remove most of the chloroform, separating and purifying by a silica gel column (using n-hexane/ethyl acetate as an eluent), carrying out rotary evaporation to remove a solvent, and finally drying the product in a vacuum oven at 80 ℃ for 2 hours to obtain the antibacterial agent; the ratio of the intermediate to the chloroform to the butyl bromide is 1.3g, 20mL;
carrying out quaternization reaction on bromobutane and an intermediate to obtain the quaternary ammonium salt type antibacterial agent, wherein the reaction process is as follows:
Figure BDA0003877847720000031
s3, pre-crystallizing the polyester chips in a drying oven at 90 ℃ for 8 hours, then drying the polyester chips in a vacuum drying oven at 110 ℃ for 24 hours, blending the dried polyester chips with an antibacterial agent, and spinning the polyester chips on a melt spinning machine to obtain antibacterial polyester fibers; the mass ratio of the polyester chip to the antibacterial agent is 100;
the linear density of the antibacterial polyester fiber is 140-160dtex, and the spinning speed is 1000m/min.
The molecules of the antibacterial agent are quaternary ammonium salt compounds, and a single antibacterial agent molecule contains two quaternary ammonium salt cationic groups, and belongs to a high-efficiency and safe antibacterial component, and the molecules of the antibacterial agent contain alcoholic hydroxyl groups, so that the molecules of the antibacterial agent can participate in the copolymerization process of polyester in the melting process, the acting force of the antibacterial agent and a polyester matrix is improved, the uniform dispersion of the antibacterial agent in the polyester is promoted, and the obtained polyester fiber has high-efficiency, safe and uniform-component antibacterial performance; in addition, compared with a finishing mode, the antibacterial agent molecules and the polyester have a chemical bonding effect, and the polyester fiber has the characteristic of long antibacterial function through melt spinning forming.
The invention has the beneficial effects that:
the fabric is formed by blending the bamboo fibers, the antibacterial polyester fibers and the viscose fibers, the bamboo fibers are natural regenerated cellulose fibers and have good antibacterial and bacteriostatic properties, and the porous structure of the bamboo fibers enables the bamboo fibers to have the characteristics of good moisture absorption and breathability, soft, smooth and full hand feeling; the viscose fiber has good hygroscopicity, is easy to dye, is difficult to generate static electricity and has better spinnability; the antibacterial polyester fiber has the advantages of good strength, safety, high efficiency, lasting washing resistance and antibacterial performance, so that the fabric formed by blending the antibacterial polyester fiber, the antibacterial polyester fiber and the antibacterial polyester fiber has the characteristics of skin friendliness, air permeability and good antibacterial effect, and can meet the requirements of antibacterial textiles.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
Preparing the antibacterial polyester fiber:
s1, adding 0.1mol of piperazine and 100mL of acetone into a dry three-neck flask with a stirring device and a reflux device, vacuumizing at normal temperature, and introducing N 2 After three times of repeated operation, the reaction is performed at N 2 Under protection and stirring, slowly dropping 200mL of acetone solution dissolved with allyl alcohol glycidyl ether into a flask, stirring and reacting for 2 hours at a constant temperature of 50 ℃ after dropping is finished, and removing acetone by rotary evaporation after the reaction is finished to obtain an intermediate; the concentration of the acetone solution of allyl alcohol glycidyl ether is 1.025mol/L;
s2, adding 13g of the intermediate and 100mL of chloroform into a three-neck flask, stirring and mixing uniformly, adding 200mL of bromobutane, carrying out reflux reaction for 6 hours under the conditions of magnetic stirring and 70 ℃, after the reaction is finished, carrying out rotary evaporation to remove most of chloroform, separating and purifying through a silica gel column (using normal hexane/ethyl acetate as an eluent), carrying out rotary evaporation to remove a solvent, and finally putting the product into a vacuum oven at 80 ℃ for drying for 2 hours to obtain the antibacterial agent;
s3, pre-crystallizing 100g of polyester chips in a drying oven at 90 ℃ for 8h, then placing the polyester chips in a vacuum drying oven at 110 ℃ for drying for 24h, blending the dried polyester chips with 9g of antibacterial agent, and then spinning on a melt spinning machine to obtain antibacterial polyester fibers; the linear density of the antibacterial polyester fiber is 140dtex, and the spinning speed is 1000m/min.
Example 2
Preparing the antibacterial polyester fiber:
s1, adding 0.2mol of piperazine and 200mL of acetone into a dry three-neck flask with a stirring device and a reflux device, vacuumizing at normal temperature, and introducing N 2 After three iterations, at N 2 Under protection and stirring, 400mL of acetone solution containing allyl alcohol glycidyl ether was bufferedSlowly dropping into a flask, stirring and reacting for 2 hours at the constant temperature of 55 ℃ after the dropping is finished, and removing acetone by rotary evaporation after the reaction is finished to obtain an intermediate; the concentration of the acetone solution of allyl alcohol glycidyl ether is 1.025mol/L;
s2, adding 26g of the intermediate and 200mL of chloroform into a three-neck flask, stirring and mixing uniformly, adding 400mL of bromobutane, carrying out reflux reaction for 6 hours under the conditions of magnetic stirring and 70 ℃, after the reaction is finished, carrying out rotary evaporation to remove most of chloroform, separating and purifying through a silica gel column (using n-hexane/ethyl acetate as an eluent), carrying out rotary evaporation to remove a solvent, and finally putting the product into a vacuum oven at 80 ℃ for drying for 2 hours to obtain the antibacterial agent;
s3, pre-crystallizing 100g of polyester chips in a drying oven at 90 ℃ for 8h, then drying the polyester chips in a vacuum drying oven at 110 ℃ for 24h, blending the dried polyester chips with 10g of antibacterial agent, and spinning on a melt spinning machine to obtain the antibacterial polyester fiber; the linear density of the antibacterial polyester fiber is 160dtex, and the spinning speed is 1000m/min.
Example 3
A skin-friendly antibacterial breathable fabric is formed by blending bamboo fibers, the antibacterial polyester fibers prepared in the embodiment 1 and viscose fibers; and the blending ratio of the bamboo fibers, the antibacterial polyester fibers and the viscose fibers is 50/20/30.
Example 4
A skin-friendly antibacterial breathable fabric is formed by blending bamboo fibers, the antibacterial polyester fibers prepared in the embodiment 2 and viscose fibers; and the blending ratio of the bamboo fibers, the antibacterial polyester fibers and the viscose fibers is 50/20/30.
The fabrics prepared in examples 4-5 were tested for moisture permeability (GB 9994-2008), tactile sensation, and antibacterial property (GB/T20944.3-2008);
the results obtained are shown in the following table:
example 3 Example 4
Moisture permeability (Ret) 16.2 15.9
Sense of touch Smooth and soft Smooth and soft
Escherichia coli bacteriostatic ratio/%) 92.3 91.8
Candida albicans inhibitory rate/%) 86.6 86.2
The data in the table show that the fabric obtained by the invention has high moisture permeability, smooth and soft touch, and excellent antibacterial performance, and has wide application space.
In the description of the specification, reference to the description of "one embodiment," "an example," "a specific example" or the like means that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The foregoing is illustrative and explanatory only, and it will be appreciated by those skilled in the art that various modifications, additions and substitutions can be made to the embodiments described without departing from the scope of the invention as defined in the appended claims.

Claims (6)

1. A skin-friendly antibacterial breathable fabric is characterized by being formed by blending bamboo fibers, antibacterial polyester fibers and viscose fibers;
wherein the antibacterial polyester fiber is prepared by the following steps:
s1, adding piperazine and acetone into a dry three-neck flask with a stirring device and a reflux device, vacuumizing at normal temperature, and introducing N 2 After three iterations, at N 2 Slowly dropping an acetone solution dissolved with allyl alcohol glycidyl ether into a flask under protection and stirring, stirring and reacting for 2 hours at a constant temperature of 50-55 ℃ after the dropping is finished, and removing acetone by rotary evaporation after the reaction is finished to obtain an intermediate;
s2, adding the intermediate and chloroform into a three-neck flask, uniformly stirring and mixing, adding bromobutane, carrying out reflux reaction for 6 hours under the conditions of magnetic stirring and 70 ℃, after the reaction is finished, removing most of chloroform by rotary evaporation, separating and purifying through a silica gel column, removing a solvent by rotary evaporation, and finally drying the product in a vacuum oven at 80 ℃ for 2 hours to obtain an antibacterial agent;
s3, pre-crystallizing the polyester chips in a drying oven at 90 ℃ for 8h, then drying the polyester chips in a vacuum drying oven at 110 ℃ for 24h, blending the dried polyester chips with an antibacterial agent, and spinning on a melt spinning machine to obtain the antibacterial polyester fiber.
2. The skin-friendly antibacterial breathable fabric according to claim 1, wherein the dosage ratio of the acetone solution of piperazine, acetone and allyl alcohol glycidyl ether in the step S1 is 0.1 mol; the concentration of the acetone solution of allyl alcohol glycidyl ether was 1.025mol/L.
3. The skin-friendly antibacterial breathable fabric according to claim 1, wherein the ratio of the amount of the intermediate, chloroform and butyl bromide in step S2 is 1.3 g.
4. The skin-friendly antibacterial breathable fabric according to claim 1, wherein the mass ratio of the polyester chips to the antibacterial agent in step S3 is 100.
5. The skin-friendly antibacterial breathable fabric according to claim 1, wherein the linear density of the antibacterial polyester fibers in the step S3 is 140-160dtex, and the spinning speed is 1000m/min.
6. The skin-friendly antibacterial breathable fabric according to claim 1, wherein the blending ratio of the bamboo fibers, the antibacterial polyester fibers and the viscose fibers is 50/20/30.
CN202211222474.1A 2022-10-08 2022-10-08 Skin-friendly antibacterial breathable fabric Pending CN115584583A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116121930A (en) * 2023-02-27 2023-05-16 亿吉万(深圳)新材料科技有限公司 Moisture-absorbing antibacterial textile
CN117845364A (en) * 2023-12-18 2024-04-09 潮州市明旦婚纱礼服有限公司 Preparation process of moisture-absorbing antibacterial fiber fabric

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116121930A (en) * 2023-02-27 2023-05-16 亿吉万(深圳)新材料科技有限公司 Moisture-absorbing antibacterial textile
CN116121930B (en) * 2023-02-27 2023-11-03 亿吉万(深圳)新材料科技有限公司 Moisture-absorbing antibacterial textile
CN117845364A (en) * 2023-12-18 2024-04-09 潮州市明旦婚纱礼服有限公司 Preparation process of moisture-absorbing antibacterial fiber fabric

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