CN115505806A - High-strength and high-toughness wrought aluminum alloy and preparation method thereof - Google Patents

High-strength and high-toughness wrought aluminum alloy and preparation method thereof Download PDF

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CN115505806A
CN115505806A CN202211297161.2A CN202211297161A CN115505806A CN 115505806 A CN115505806 A CN 115505806A CN 202211297161 A CN202211297161 A CN 202211297161A CN 115505806 A CN115505806 A CN 115505806A
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aluminum alloy
mass fraction
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intermediate alloy
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隋荣勃
马德良
王婷婷
张积龙
姚超胜
隋来智
李喆
丁春华
任少华
马旭
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Shandong Nanshan Aluminium Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/10Alloys based on aluminium with zinc as the next major constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C23/00Extruding metal; Impact extrusion
    • B21C23/02Making uncoated products
    • B21C23/04Making uncoated products by direct extrusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/001Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
    • B22D11/003Aluminium alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0075Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for rods of limited length
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/02Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working in inert or controlled atmosphere or vacuum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/053Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with zinc as the next major constituent

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Abstract

The invention aims to solve the problem of low mechanical property of the existing aluminum alloy, and provides a high-strength-toughness wrought aluminum alloy free of rare earth and a preparation method thereof. The alloy elements comprise Al, zn, mg, ag, zr, sb, be and Cr, wherein the mass fraction of Zn is 5.0-7.0%, the mass fraction of Mg is 2.0-3.0%, the mass fraction of Ag is 0.5-1.0%, the mass fraction of Zr is 0.2-0.4%, the mass fraction of Sb is 0.1-0.2%, the mass fraction of Be is 0.1-0.2%, the mass fraction of Cr is 0.1-0.2%, and the balance is Al and impurities. The preparation process comprises the following steps: preheating raw materials, smelting alloy, homogenizing and carrying out plastic processing; the texture of the wrought aluminum alloy plate is weakened through a low-cost rare earth microalloying mode, and the obtained wrought aluminum alloy plate has weakened non-basal plane texture, so that the room-temperature plastic forming capacity of the aluminum alloy plate is improved. The method is mainly used for preparing the low-alloy and ultra-high-strength and high-toughness aluminum alloy without rare earth.

Description

High-strength and high-toughness wrought aluminum alloy and preparation method thereof
Technical Field
The invention relates to the field of metal materials and metal material processing, in particular to a high-strength and high-toughness wrought aluminum alloy and a preparation method thereof.
Background
Aluminum and aluminum alloy are known as '21 st century green environment-friendly engineering materials' due to excellent properties of low density, high specific strength, abundant reserves, easy recovery and the like, and have great development prospects in the aspects of realizing light weight of vehicles, light and thin miniaturization of devices, energy conservation, emission reduction, green development and the like. The main design idea of high-strength aluminum alloy at home and abroad for many years is to obtain high-strength aluminum alloy materials by adding rare earth and other alloy elements or by a special preparation process, and various aluminum alloys taking rare earth as main alloy elements or rare earth as trace elements are developed. But the industrial popularization and application progress is slow due to the defects of high material cost or high preparation difficulty and the like. In addition, the ultrahigh-strength aluminum alloy has low ductility and toughness, and the high-efficiency forming and engineering application of important parts are severely restricted.
At present, high-strength and high-toughness wrought aluminum alloys mainly comprise: al-Mg, al-Zn-Mg, al-Mg-Ag and other alloy series. In the field of the development of wrought aluminum alloys, there are three main methods to improve the processing plasticity of aluminum: (1) raising the deformation processing temperature; (2) The size of aluminum crystal grains is reduced through strong deformation, so that the texture is weakened, and the plasticity of the alloy is improved; (3) By adding the alloy elements, the critical shear stress of twin crystals or a sliding system and the like can be changed by causing the change of aluminum crystal lattices through alloying, so that the deformation mode (sliding or twin crystal model) of the alloy is further changed, the texture of the alloy is weakened, and the plasticity of the alloy is increased. During the non-equilibrium solidification process, a large amount of eutectic Mg is precipitated 17 A1 12 The phase is distributed in the crystal boundary of the primary crystal alpha-Al phase in an irregular net shape, and the phase is hard and brittle and has great adverse effect on the mechanical property, particularly the plasticity of the alloy. Therefore, the development of the rare earth-free low-cost high-toughness aluminum alloy has important significance for expanding the application of the aluminum alloy.
Disclosure of Invention
The invention aims to solve the problem of low yield strength of the existing aluminum alloy, and provides a high-strength high-toughness wrought aluminum alloy and a preparation method thereof.
A high-strength and high-toughness wrought aluminum alloy and a preparation method thereof are disclosed, wherein alloy elements comprise Al, zn, mg, ag, zr, sb, be and Cr, the mass fraction of Zn is 5.0-7.0%, the mass fraction of Mg is 2.0-3.0%, the mass fraction of Ag is 0.5-1.0%, the mass fraction of Zr is 0.2-0.4%, the mass fraction of Sb is 0.1-0.2%, the mass fraction of Be is 0.1-0.2%, the mass fraction of Cr is 0.1-0.2%, and the balance is Al and impurities.
The high-strength and high-toughness wrought aluminum alloy and the preparation method thereof are specifically completed according to the following steps:
(1) Preheating raw materials: firstly, preheating pure aluminum, pure magnesium, pure antimony, al-Zn intermediate alloy, al-Zr intermediate alloy, al-Be intermediate alloy, al-Ag intermediate alloy and Al-Cr intermediate alloy to 250 ℃;
(2) Alloy smelting: the smelting furnace adopts a resistance furnace or an intermediate frequency electromagnetic induction furnace, firstly pure aluminum is added, the temperature is raised to completely melt the pure aluminum, then pure magnesium, pure antimony and Al-Zn intermediate alloy, al-Zr intermediate alloy, al-Be intermediate alloy, al-Ag intermediate alloy and Al-Cr intermediate alloy are added, the melt is stirred after all the raw materials are melted, the melt is cooled to a certain temperature after the smelting is finished, then the melt is stood for treatment, then the melt is poured into a cooling crystallizer, and a casting machine is used for carrying out direct cooling type semi-continuous casting at a certain speed to obtain alloy cast ingots;
(3) Two-stage homogenization treatment: carrying out homogenization heat treatment on the alloy cast ingot by adopting a large box type heat treatment furnace filled with flowing argon protective atmosphere to obtain an as-cast alloy blank;
(4) Plastic processing: and carrying out plastic processing on the obtained as-cast alloy blank to obtain an extruded bar.
(5) And (3) aging treatment: and carrying out aging treatment on the extruded bar to obtain the high-strength wrought aluminum alloy.
The invention adopts a semi-continuous casting mode for casting, which is beneficial to controlling the contents of Fe, ag, si and Ni elements which have great influence on mechanical properties in the alloy. The invention mainly has the effects of low alloying, purifying melt, reducing impurities, changing a second phase in the alloy and greatly improving the mechanical property of the alloy.
Further, in the step (1), the Al is 99.9% Al, sb is 99.9% Sb, mg is 99.9% Mg, the Al-Ag intermediate alloy is Al-20Ag, the Al-Zr intermediate alloy is Al-20Zr, the Al-Be intermediate alloy is Al-20Be, and the Al-Cr intermediate alloy is Al-20Cr.
Further, in the step (2), pure Al is placed in a crucible, the temperature is raised to 680-760 ℃, the pure Al is completely melted while maintaining the temperature at 680-760 ℃, then pure magnesium, pure antimony and Al-Zn intermediate alloy, al-Zr intermediate alloy, al-Be intermediate alloy, al-Ag intermediate alloy and Al-Cr intermediate alloy are sequentially added, mechanical stirring is carried out for 15 min-30 min at the temperature of 680-760 ℃, then standing is carried out for 15 min-30 min, alloy melt is obtained, and then the alloy melt is made into ingots by adopting a metal mold water-cooling solidification process, so as to obtain casting alloy.
Further, in the step (3), the cast alloy is placed in a resistance heating furnace, and the two-stage homogenization treatment specifically comprises: firstly, preserving heat for 10-15h at 310-330 ℃, and then raising the temperature to 460-490 ℃ and preserving heat for 4-8h.
Further, in the step (4), the alloy and the extrusion die after the homogenization treatment are subjected to preheating treatment at an extrusion deformation temperature, wherein the hot extrusion specifically comprises the following steps: preheating the aluminum alloy cast ingot and the extrusion die at 430-470 ℃ for 2-4h, and then carrying out forward extrusion under the conditions that the extrusion ratio is 15.
Further, in the step (5), the standby material is subjected to aging treatment at 160-180 ℃ for 8-24 h, and the high-strength wrought aluminum alloy can be obtained.
The invention has the beneficial effects that: the invention provides a high-strength and high-toughness wrought aluminum alloy and a preparation method thereof, wherein the aluminum alloy has high strength and high plasticity and does not contain rare earth, and the problem that the high-strength and high-toughness aluminum alloy generally contains a large amount of rare earth and has high alloy cost in the prior art is solved. Wherein, the content of Ag in the aluminum alloy is controlled to be 0.5-1.0%, ag is a typical element with precipitation strengthening effect in the aluminum alloy, the solubility maximum value of Ag in the aluminum alloy is 14.8% (561 ℃), the solid solubility of Ag in the aluminum alloy is sharply reduced along with the reduction of temperature, and the solid solubility is only 0.45% at 200 ℃. As the temperature is lowered, ag has high melting point (771.5 ℃) and high-hardness Mg in the aluminum alloy 2 Mg with reasonable size, shape and distribution by precipitation of Ag phase 2 The Ag phase can realize the function of precipitation strengthening, and meanwhile, a proper amount of Ag can refine aluminum alloy grains in the aluminum alloy. By adding small amount of Ag element to form Mg 2 Ag phase separation, allowing Mg to react 17 Al 12 Changing from continuous network to semi-continuous network or broken network to improve Mg 17 Al 12 Phase morphology, thereby improving alloy properties. However, when the Ag content is very low (less than 0.5%), mg is contained in the alloy 2 When the Ag content is less, the effects of grain refinement and precipitation strengthening cannot be achieved. The melting point of the alloy decreases with the increase of the Ag content, when the Ag content is higher (especially more than 1.5 percent), the alloy can cause the coarsening of the aluminum alloy crystal grains, and the alloy extends with the increase of the Ag contentThe rate is reduced, the corrosion resistance of the aluminum alloy is also reduced, and the addition of a larger amount of Ag can result in a higher alloy density (the Ag density is 7.28 g/cm) 3 ) Influence the advantage of light weight of the aluminum alloy, and when the Ag content is higher than 3.2%, mg exists in a liquid state 2 Ag phase is formed, the alloy is solidified to room temperature, and Mg begins to be separated out when the alloy is in a liquid state 2 The Ag phase will be very coarse. Therefore, the Ag content in this system is too high and there will be more coarse Mg 2 Ag phase, which affects the alloy performance, and controls the Ag content in the aluminum alloy to be 0.5-1.0% in order to ensure that alloy elements are dissolved into the matrix as much as possible; in addition, cr can be greatly dissolved in Ag (at 139 ℃, the solid solubility of Cr in Ag can reach 21 percent) to form a beta-Ag phase, and the addition effect of Cr element can be influenced by the existence of a large amount of Ag in the alloy. The Cr content in the aluminum alloy is controlled to be 2-3.2%, and the Cr element is also an element with precipitation strengthening effect in the aluminum alloy. The maximum solubility of the Cr element in aluminum is 8.85%, and the solubility decreases greatly with decreasing temperature, and decreases to 1% or less at 200 ℃. After Cr is added into aluminum alloy, mg with better thermal stability and 823 ℃ of melting point can be formed 3 Cr 2 The granular phase can be used as an alpha-Mg nucleation core to achieve the purpose of refining the matrix phase of the aluminum alloy, so that the strength of the alloy is improved, and good plasticity is kept; cr element can also be added to form net Mg 17 Al 12 The phase transition is open mesh.
The ultra-high strength and toughness aluminum alloy without rare earth and low alloy designed by the invention can be extruded and formed once to obtain the ultra-high strength and toughness aluminum alloy extruded bar with excellent surface quality. The preparation process is simple and easy to operate, has low cost and is suitable for industrial production.
Drawings
In order to make the object, technical scheme and beneficial effect of the invention more clear, the invention provides the following drawings for explanation:
FIG. 1 is a photograph of the microstructure of an aluminum alloy material according to example 1 of the present invention.
FIG. 2 is a photograph of the microstructure of the aluminum alloy material according to example 2 of the present invention.
FIG. 3 is a photograph of the microstructure of the aluminum alloy material according to example 3 of the present invention.
FIG. 4 is a photograph of the microstructure of the aluminum alloy material according to example 4 of the present invention.
Fig. 5 is a report of performance testing for various embodiments of the present invention.
Detailed Description
The embodiments of the present invention are described below with reference to specific embodiments, and other advantages and effects of the present invention will be easily understood by those skilled in the art from the disclosure of the present specification. The invention is capable of other and different embodiments and of being practiced or of being carried out in various ways, and its several details are capable of modification in various respects, all without departing from the spirit and scope of the present invention. The following tests were carried out to confirm the effects of the present invention
Example 1
The high-strength and high-toughness wrought aluminum alloy comprises the following components in percentage by mass: 5.0% of Zn, 2.0% of Mg, 0.5% of Ag, 0.2% of Cr and the balance of Al and inevitable impurities.
The preparation of the high-toughness wrought aluminum alloy of the embodiment comprises the following steps:
(1) Preheating raw materials: firstly, preheating pure aluminum, pure zinc, pure magnesium, al-20Ag intermediate alloy and Al-20Cr intermediate alloy to 250 ℃;
(2) Smelting and casting: placing pure Al in a crucible, heating to 680-760 ℃, preserving heat at 680-760 ℃ to completely melt the pure Al, then sequentially adding pure Mg and Al-Ag intermediate alloy and Al-Cr intermediate alloy, mechanically stirring at 680-760 ℃ for 15-30 min, standing for 15-30 min to obtain an alloy melt, and preparing the alloy melt into ingots by adopting a metal mold water condensation solidification process to obtain cast alloys.
(3) Homogenizing: placing the cast aluminum alloy prepared in the step (1) in a resistance heating furnace, wherein the two-stage homogenization treatment specifically comprises the following steps: firstly, preserving heat for 10-15h at 310-330 ℃, then heating to 460-490 ℃, preserving heat for 4-8h, and cooling the cast ingot to room temperature in air after completion;
(4) Extrusion deformation: carrying out hot extrusion deformation on the cast rod obtained in the step (3), and carrying out preheating treatment on the homogenized alloy and an extrusion die at an extrusion deformation temperature, wherein the hot extrusion specifically comprises the following steps: preheating the aluminum alloy cast ingot and the extrusion die at 430-470 ℃ for 2-4h, and then carrying out forward extrusion under the conditions that the extrusion ratio is 15.
(5) Aging treatment: and (4) carrying out aging treatment on the aluminum alloy in the step (4) in a heat treatment furnace, wherein the aging temperature is 180 ℃, and the heat preservation time is 8h.
Example 2
The alloy comprises, by mass, 5.5% of Zn, 2.3% of Mg, 0.6% of Ag, 0.3% of Cr and the balance of Al and inevitable impurities. The other processes are the same as in example 1.
Example 3
The alloy comprises, by mass, 6.3% of Zn, 2.6% of Mg, 0.8% of Ag, 0.4% of Cr and the balance of Al and inevitable impurities. The other processes were the same as in example 1.
Example 4
The alloy comprises, by mass, 7.0% of Zn, 3.0% of Mg, 1.0% of Ag, 0.5% of Cr and the balance of Al and inevitable impurities. The other processes were the same as in example 1.
The aluminum alloy bars of the above examples 1-4 were tested for tensile properties at room temperature, and the results are shown in Table 1.
TABLE 1 Room temperature mechanical Properties of the high toughness wrought aluminum alloys of the present invention
Figure BDA0003901934630000061
Figure BDA0003901934630000071
As can be seen from the table above, the alloy of the invention has higher mechanical properties, the highest tensile strength reaches more than 510MPa, and the application requirements of the aluminum alloy in high-technology industries such as national defense and military industry, aerospace, automobiles and rail transit can be met.

Claims (7)

1. A high-strength-toughness wrought aluminum alloy and a preparation method thereof, wherein alloy elements comprise Al, zn, mg, ag, zr, sb, be and Cr, the mass fraction of Zn is 5.0-7.0%, the mass fraction of Mg is 2.0-3.0%, the mass fraction of Ag is 0.5-1.0%, the mass fraction of Zr is 0.2-0.4%, the mass fraction of Sb is 0.1-0.2%, the mass fraction of Be is 0.1-0.2%, the mass fraction of Cr is 0.1-0.2%, and the balance is Al and impurities.
2. The method for preparing the high-strength high-toughness wrought aluminum alloy according to claim 1, wherein the method for preparing the high-strength high-toughness wrought aluminum alloy is completed by the following steps:
(1) Preheating raw materials: firstly, preheating pure aluminum, pure magnesium, pure antimony, al-Zn intermediate alloy, al-Zr intermediate alloy, al-Be intermediate alloy, al-Ag intermediate alloy and Al-Cr intermediate alloy to 250 ℃;
(2) Alloy smelting: the smelting furnace adopts a resistance furnace or an intermediate frequency electromagnetic induction furnace, firstly pure aluminum is added, the temperature is raised to completely melt the pure aluminum, then pure magnesium, pure antimony and Al-Zn intermediate alloy, al-Zr intermediate alloy, al-Be intermediate alloy, al-Ag intermediate alloy and Al-Cr intermediate alloy are added, the melt is stirred after all raw materials are melted, the melt is cooled to a certain temperature after the melting is finished and then is kept stand, then the melt is poured into a cooling crystallizer, and a casting machine is used for carrying out direct cooling type semi-continuous casting at a certain speed to obtain alloy cast ingots;
(3) Two-stage homogenization treatment: carrying out homogenization heat treatment on the alloy cast ingot by adopting a large box type heat treatment furnace filled with flowing argon protective atmosphere to obtain an as-cast alloy blank;
(4) Plastic processing: and carrying out plastic processing on the obtained as-cast alloy blank to obtain an extruded bar.
(5) Aging treatment: and (4) carrying out aging treatment on the extruded bar to obtain the high-strength wrought aluminum alloy.
3. The high toughness wrought aluminum alloy of claim 2, wherein in step (1), the Al is 99.9% Al, the Sb is 99.9% Sb, the Mg is 99.9% weight percent, the Al-Ag intermediate alloy is Al-20Ag, the Al-Zr intermediate alloy is Al-20Zr, the Al-Be intermediate alloy is Al-20Be, and the Al-Cr intermediate alloy is Al-20Cr.
4. The preparation method of the high strength and toughness wrought aluminum alloy according to claim 2, wherein in the step (2), pure Al is placed in a crucible, the temperature is raised to 680-760 ℃, the pure Al is kept at 680-760 ℃ to Be completely melted, then pure magnesium, pure antimony, al-Zn intermediate alloy, al-Zr intermediate alloy, al-Be intermediate alloy, al-Ag intermediate alloy and Al-Cr intermediate alloy are sequentially added, mechanical stirring is carried out at 680-760 ℃ for 15-30 min, then standing is carried out for 15-30 min to obtain alloy melt, and then the alloy melt is made into ingots by adopting a metal mold water-cooling solidification process to obtain cast alloy.
5. The preparation method of the high-strength high-toughness wrought aluminum alloy according to claim 2, wherein in the step (3), the cast alloy is placed in a resistance heating furnace, and the two-stage homogenization treatment specifically comprises: the temperature is kept for 10 to 15 hours at 310 to 330 ℃, and then the temperature is raised to 460 to 490 ℃ and kept for 4 to 8 hours.
6. The preparation method of the high strength and toughness wrought aluminum alloy according to claim 2, wherein in the step (4), the homogenized alloy and the extrusion die are subjected to preheating treatment at extrusion deformation temperature, and the hot extrusion is specifically as follows: preheating the aluminum alloy cast ingot and the extrusion die at 430-470 ℃ for 2-4h, and then carrying out forward extrusion under the conditions that the extrusion ratio is 15.
7. The method for preparing the high strength and toughness wrought aluminum alloy according to claim 2, wherein in the step (5), the spare material is subjected to aging treatment at 160-180 ℃ for 8-24 h to obtain the high strength wrought aluminum alloy.
CN202211297161.2A 2022-10-21 2022-10-21 High-strength and high-toughness wrought aluminum alloy and preparation method thereof Pending CN115505806A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3852122A (en) * 1972-03-10 1974-12-03 Ardal Og Sunndal Verk Method of producing a weldable and ageable aluminium alloy of great strength and product
JPH09272944A (en) * 1996-04-09 1997-10-21 Toyota Motor Corp High strength cast aluminum alloy and its production
CN107675040A (en) * 2017-09-04 2018-02-09 佛山科学技术学院 A kind of middle intensity high heat conduction aluminium alloy and preparation method thereof
CN109295362A (en) * 2018-11-02 2019-02-01 东北大学 A kind of ultra-high-strength/tenacity Al-Zn-Mg-Cu aluminium alloy and its processing technology
CN111197132A (en) * 2020-01-09 2020-05-26 张煜琰 Non-heat treatment type high-strength die-casting aluminum alloy and preparation method thereof
JP2020152965A (en) * 2019-03-20 2020-09-24 株式会社豊田自動織機 Aluminum alloy material, method for producing the same, and impeller
CN114875286A (en) * 2022-05-30 2022-08-09 山东南山铝业股份有限公司 Rare earth-free low-alloy high-strength and high-toughness aluminum alloy and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3852122A (en) * 1972-03-10 1974-12-03 Ardal Og Sunndal Verk Method of producing a weldable and ageable aluminium alloy of great strength and product
JPH09272944A (en) * 1996-04-09 1997-10-21 Toyota Motor Corp High strength cast aluminum alloy and its production
CN107675040A (en) * 2017-09-04 2018-02-09 佛山科学技术学院 A kind of middle intensity high heat conduction aluminium alloy and preparation method thereof
CN109295362A (en) * 2018-11-02 2019-02-01 东北大学 A kind of ultra-high-strength/tenacity Al-Zn-Mg-Cu aluminium alloy and its processing technology
JP2020152965A (en) * 2019-03-20 2020-09-24 株式会社豊田自動織機 Aluminum alloy material, method for producing the same, and impeller
CN111197132A (en) * 2020-01-09 2020-05-26 张煜琰 Non-heat treatment type high-strength die-casting aluminum alloy and preparation method thereof
CN114875286A (en) * 2022-05-30 2022-08-09 山东南山铝业股份有限公司 Rare earth-free low-alloy high-strength and high-toughness aluminum alloy and preparation method thereof

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