CN115491895A - Anti-radiation and anti-ultraviolet down jacket for pregnant women and preparation method thereof - Google Patents
Anti-radiation and anti-ultraviolet down jacket for pregnant women and preparation method thereof Download PDFInfo
- Publication number
- CN115491895A CN115491895A CN202211198074.1A CN202211198074A CN115491895A CN 115491895 A CN115491895 A CN 115491895A CN 202211198074 A CN202211198074 A CN 202211198074A CN 115491895 A CN115491895 A CN 115491895A
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- Prior art keywords
- radiation
- proof
- ultraviolet
- parts
- down jacket
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- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 230000003471 anti-radiation Effects 0.000 title claims abstract description 17
- 239000004744 fabric Substances 0.000 claims abstract description 124
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- 238000001035 drying Methods 0.000 claims abstract description 48
- 229910052751 metal Inorganic materials 0.000 claims abstract description 45
- 239000002184 metal Substances 0.000 claims abstract description 45
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 36
- 238000009941 weaving Methods 0.000 claims abstract description 27
- 238000005406 washing Methods 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920013822 aminosilicone Polymers 0.000 claims abstract description 17
- 239000003921 oil Substances 0.000 claims abstract description 17
- 238000004140 cleaning Methods 0.000 claims abstract description 16
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 16
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 16
- 238000006243 chemical reaction Methods 0.000 claims abstract description 15
- 239000011248 coating agent Substances 0.000 claims abstract description 13
- 238000000576 coating method Methods 0.000 claims abstract description 13
- 241000872931 Myoporum sandwicense Species 0.000 claims abstract description 11
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 9
- 239000003513 alkali Substances 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 9
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- 238000011049 filling Methods 0.000 claims description 54
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 24
- 239000003795 chemical substances by application Substances 0.000 claims description 23
- 239000012752 auxiliary agent Substances 0.000 claims description 18
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 16
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 16
- 239000000843 powder Substances 0.000 claims description 16
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims description 16
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- 239000004753 textile Substances 0.000 claims description 9
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 claims description 8
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 8
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 claims description 8
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 8
- CMIWMNWAWBHTDY-UHFFFAOYSA-N 3-iodoprop-1-ynyl formate Chemical compound ICC#COC=O CMIWMNWAWBHTDY-UHFFFAOYSA-N 0.000 claims description 8
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 8
- 108091005804 Peptidases Proteins 0.000 claims description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 8
- 239000004365 Protease Substances 0.000 claims description 8
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 8
- -1 alkyl glycoside Chemical class 0.000 claims description 8
- 238000010009 beating Methods 0.000 claims description 8
- 229930182470 glycoside Natural products 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 8
- 229940069338 potassium sorbate Drugs 0.000 claims description 8
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- 239000004302 potassium sorbate Substances 0.000 claims description 8
- 239000001294 propane Substances 0.000 claims description 8
- 238000009958 sewing Methods 0.000 claims description 8
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 8
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 8
- 238000005507 spraying Methods 0.000 claims description 8
- 229940095064 tartrate Drugs 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 238000001291 vacuum drying Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 230000000052 comparative effect Effects 0.000 description 7
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- 238000012360 testing method Methods 0.000 description 7
- 229920000742 Cotton Polymers 0.000 description 6
- 230000006750 UV protection Effects 0.000 description 6
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Natural products OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 6
- 244000025254 Cannabis sativa Species 0.000 description 5
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 5
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 5
- 235000009120 camo Nutrition 0.000 description 5
- 235000005607 chanvre indien Nutrition 0.000 description 5
- 239000011487 hemp Substances 0.000 description 5
- 238000005457 optimization Methods 0.000 description 4
- 230000004913 activation Effects 0.000 description 2
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- 230000004048 modification Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 241001391944 Commicarpus scandens Species 0.000 description 1
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Abstract
The invention discloses a preparation method of a radiation-proof and ultraviolet-proof down jacket for pregnant women, which comprises the steps of weaving metal fiber wires to form a metal fiber wire mesh, coating paint formed by mixing amino silicone oil and nano silicon dioxide on the surface of the metal fiber wire mesh, drying, and weaving cotton-flax fibers on the two sides of the metal fiber wire mesh to form radiation-proof base cloth; feeding the radiation-proof base cloth into a potassium hydroxide solution for reaction for 2 hours, cleaning and drying, and immersing the alkali-activated radiation-proof base cloth into NaIO 4 Reacting in the solution in a dark place, treating in 0.1mol/L glycerol solution for 12h, washing and drying; immersing the oxidized radiation-proof base cloth into HBP-NH 2 And washing and drying the solution to obtain the modified radiation-proof base cloth. According to the anti-radiation and anti-ultraviolet down jacket for the pregnant women and the preparation method thereof, the down jacket keeps good anti-ultraviolet performance, and the water washing resistance of the down jacket fabric is ensured; and the friction resistance of the down jacket fabric is enhanced.
Description
Technical Field
The invention relates to the technical field of down jacket processing, in particular to a radiation-proof and ultraviolet-proof down jacket for pregnant women and a preparation method thereof.
Background
When pregnant women are pregnant, in order to ensure that children are not radiated, the pregnant women can be prevented from contacting electronic equipment such as a computer and the like as far as possible, but office working women still needing to work in the early stage of pregnancy still can be affected by radiation, and the growth of the children can be influenced for a long time, so that adjustment can be made on clothes, such as down jackets, but when the down jackets for pregnant women, which are provided with radiation protection and ultraviolet protection, are processed, the fabric for manufacturing the down jackets is usually soaked by using an ultraviolet-resistant auxiliary agent, so that the fabric has ultraviolet resistance, but after the fabric processed by the processing mode is used in subsequent washing for multiple times, the ultraviolet resistance of the fabric is reduced, and the pregnant women cannot be well protected; in order to ensure the radiation resistance of the fabric, metal fibers are usually added into the fabric, but when the metal fibers are compounded with other fibers, the fibers are easy to break due to overlarge friction force among the fibers, and further the down jacket is easy to damage.
Disclosure of Invention
The invention mainly aims to provide a radiation-proof and ultraviolet-proof down jacket for pregnant women and a preparation method thereof, which can effectively solve the problems that the down jacket is not washable and the fabric is extremely easy to damage.
In order to achieve the purpose, the invention adopts the technical scheme that:
a preparation method of a radiation-proof and ultraviolet-proof down jacket for pregnant women comprises the following steps:
step S1, weaving metal fiber wires in a warp and weft mode to form a metal fiber wire mesh, coating paint formed by mixing amino silicone oil and nano silicon dioxide on the surface of the metal fiber wire mesh, drying, and weaving cotton-flax fibers on the surface of the metal fiber wire mesh in a double-sided mode by using a weaving machine to form radiation-proof base cloth;
and S2, feeding the woven radiation-proof base cloth into a potassium hydroxide solution with the mass fraction of 18% for reaction for 2 hours, cleaning and drying, and immersing the radiation-proof base cloth activated by alkali into NaIO according to the bath ratio of 1 4 Reacting in the solution for 1-1.5h in a dark place, treating in 0.1mol/L glycerol solution for 12h, washing with ionized water, and drying in an oven at 60-85 ℃;
step S3, soaking the oxidized radiation-proof base cloth into HBP-NH 2 In the solution, grafting reaction is carried out for 2h at 70 ℃, the solution is washed by deionized water and is put into a vacuum drying oven at 65-70 ℃ for drying for 1-2h to obtain modified radiation-proof base cloth;
s4, soaking the modified radiation-proof base cloth dried in the step S3 in an ultraviolet auxiliary agent, and drying after soaking;
s5, cleaning and drying the radiation-proof base cloth dried in the step S4 to obtain a radiation-proof and ultraviolet-proof fabric;
s6, processing a down filling part by taking the radiation-proof and ultraviolet-proof fabric as a down jacket fabric and reserving a down filling port;
s7, filling down feather into the down feather filling port reserved in the step S6;
and S8, sewing the down filling opening by adopting a textile wire harness to obtain the radiation-proof and ultraviolet-proof down jacket.
As a further optimization scheme of the invention, the warp density of the front and back surfaces of the radiation-proof base cloth in the step S1 is 100-200.
As a further optimization scheme of the invention, naIO in the step S2 4 The concentration of the solution was 6g/L.
As a further optimization scheme of the invention, the concentration of the HBP-NH2 solution in the step S3 is 15-25g/L.
As a further optimized scheme of the invention, the ultraviolet auxiliary agent in the step S4 consists of the following components in parts by weight: 2,4 dihydroxy benzophenone 10-14 parts, polyvinyl alcohol 10-12 parts, iodopropynyl formate 6-8 parts, potassium sorbate 5-8 parts, cocoyl monoethanolamine 10-14 parts, glycerol 6-8 parts, protease 5-8 parts, alkyl glycoside 6-9 parts, titanium isopropoxide 10-14 parts, ethylene glycol 22-25 parts, and diphenol propane 10-12 parts.
As a further optimized scheme of the present invention, the method for filling down feather in step S7 comprises:
step A1, filling the cleaned down into a filling part of the down jacket until the inner space is completely filled, atomizing a fluffing agent, and spraying the atomized fluffing agent onto the surface of a down ball to obtain an unsealed semi-finished down jacket;
step A2: and vibrating and beating the semi-finished down jacket to uniformly disperse down balls in the filling part of the down jacket.
As a further optimization of the invention, the bulking agent is a mixture of baking soda powder and tartrate powder in a mass ratio of 1:1.
As a further optimized scheme of the invention, the weight ratio of the amino silicone oil to the nano silicon dioxide in the step S1 is 2:1.
A radiation-proof and ultraviolet-proof down jacket for pregnant women is prepared by the preparation method.
Compared with the prior art, the invention has the following beneficial effects:
1. in the invention, the down jacket fabric is dipped in the potassium hydroxide solution and NaIO before the ultraviolet auxiliary agent 4 The solution, the glycerol and the HBP-NH2 solution are used for carrying out alkali activation, oxidation and grafting treatment on the fabric to obtain the modified radiation-proof base fabric, so that the ultraviolet resistance of the modified base fabric is remarkably improved, good ultraviolet resistance is still kept after multiple times of water washing, and the water washing resistance of the down jacket fabric is ensured.
2. According to the invention, the metal fiber mesh is formed by weaving the metal fiber wires in a warp-weft manner, and the coating mixed by the base silicone oil and the nano silicon dioxide is coated on the surface of the metal fiber mesh, so that the surface of the metal fiber mesh is smooth, the friction force between the metal fiber mesh and the cotton and linen fibers is reduced, the integral friction resistance of the fabric is improved, and meanwhile, the radiation resistance of the fabric can be enhanced by coating the coating on the surface of the metal fiber mesh.
Detailed Description
The present application is described in further detail below, and it should be noted that the following detailed description is provided for illustrative purposes only, and is not intended to limit the scope of the present application, which is defined by the appended claims.
Example 1
A preparation method of a radiation-proof and ultraviolet-proof down jacket for pregnant women comprises the following steps:
step S1, weaving metal fiber wires in a warp-weft mode to form a metal fiber wire mesh, coating paint formed by mixing amino silicone oil and nano silicon dioxide on the surface of the metal fiber wire mesh, drying, weaving cotton-flax fibers on the surface of the dried metal fiber wire mesh on two sides by using a weaving machine to form radiation-proof base cloth, wherein the warp density of the front surface and the back surface of the radiation-proof base cloth is 100 threads, and the weight ratio of the amino silicone oil to the nano silicon dioxide is 2:1;
s2, feeding the woven radiation-proof base cloth into a potassium hydroxide solution with the mass fraction of 18% for reaction for 2 hours, cleaning and drying, and carrying out alkali activation on the radiation-proof base cloth according to a bath ratio of 1The radiation base cloth is immersed in NaIO with the concentration of 6g/L 4 Reacting the solution for 1 hour in a dark place, treating the solution in 0.1mol/L glycerol solution for 12 hours, washing the solution by using ionized water, and drying the solution in an oven at the temperature of between 60 and 85 ℃;
s3, immersing the oxidized radiation-proof base cloth into HBP-NH2 solution with the solution concentration of 15g/L, carrying out grafting reaction for 2h at 70 ℃, washing with deionized water, and drying in a vacuum drying oven at 65-70 ℃ for 1h to obtain modified radiation-proof base cloth;
and S4, soaking the modified radiation-proof base cloth dried in the step S3 in an ultraviolet auxiliary agent, and drying the soaked base cloth, wherein the ultraviolet auxiliary agent consists of the following components in parts by weight: 2,4 dihydroxy benzophenone 12 parts, polyvinyl alcohol 11 parts, iodopropynyl formate 7 parts, potassium sorbate 6 parts, cocoyl monoethanolamine 12 parts, glycerol 7 parts, protease 6 parts, alkyl glycoside 8 parts, titanium isopropoxide 12 parts, ethylene glycol 24 parts, and diphenol propane 11 parts;
s5, cleaning and drying the radiation-proof base cloth dried in the step S4 to obtain a radiation-proof and ultraviolet-proof fabric;
s6, processing a down filling part by taking the radiation-proof and ultraviolet-proof fabric as a down jacket fabric and reserving a down filling port;
step S7, filling the cleaned down feather into a filling part of the down jacket until the inner space is completely filled, atomizing a fluffing agent and spraying the atomized fluffing agent onto the surface of a down feather ball to obtain an unsealed semi-finished down jacket, wherein the fluffing agent is a mixture of baking soda powder and tartrate powder in a mass ratio of 1:1; vibrating and beating the semi-finished down jacket to uniformly disperse down balls in the filling part of the down jacket;
and S8, sewing the down filling port by adopting a textile wire harness to obtain the anti-radiation and anti-ultraviolet down jacket.
Example 2
A preparation method of a radiation-proof and ultraviolet-proof down jacket for pregnant women comprises the following steps:
step S1, weaving metal fiber wires in a warp and weft mode to form a metal fiber wire mesh, coating paint formed by mixing amino silicone oil and nano silicon dioxide on the surface of the dried metal fiber wire mesh, drying, weaving cotton and hemp fibers on the surface of the metal fiber wire mesh on two sides by using a weaving machine to form radiation-proof base cloth, wherein the warp density of the front side and the back side of the radiation-proof base cloth is 100, and the weight ratio of the amino silicone oil to the nano silicon dioxide is 2:1;
and S2, feeding the woven radiation-proof base cloth into a potassium hydroxide solution with the mass fraction of 18% for reaction for 2 hours, cleaning and drying, and immersing the radiation-proof base cloth activated by alkali into NaIO with the concentration of 6g/L according to the bath ratio of 1 4 Reacting the solution for 1 hour in a dark place, treating the solution in 0.1mol/L glycerol solution for 12 hours, washing the solution by using ionized water, and drying the solution in an oven at the temperature of between 60 and 85 ℃;
s3, immersing the oxidized radiation-proof base cloth into HBP-NH2 solution with the solution concentration of 25g/L, carrying out grafting reaction for 2h at 70 ℃, washing with deionized water, and drying in a vacuum drying oven at 65-70 ℃ for 1h to obtain modified radiation-proof base cloth;
and S4, soaking the modified radiation-proof base cloth dried in the step S3 in an ultraviolet auxiliary agent, and drying the soaked base cloth, wherein the ultraviolet auxiliary agent consists of the following components in parts by weight: 2,4 dihydroxy benzophenone 12 parts, polyvinyl alcohol 11 parts, iodopropynyl formate 7 parts, potassium sorbate 6 parts, cocoyl monoethanolamine 12 parts, glycerol 7 parts, protease 6 parts, alkyl glycoside 8 parts, titanium isopropoxide 12 parts, ethylene glycol 24 parts, and diphenol propane 11 parts;
s5, cleaning and drying the radiation-proof base cloth dried in the step S4 to obtain a radiation-proof and ultraviolet-proof fabric;
s6, processing down filling parts by taking the radiation-proof and ultraviolet-proof fabric as the down jacket fabric and reserving down filling openings;
step S7, filling the cleaned down into a down jacket filling part until the inner space is completely filled, atomizing a fluffing agent, and spraying the atomized fluffing agent onto the surface of a down ball to obtain an unsealed semi-finished down jacket, wherein the fluffing agent is a mixture of baking soda powder and tartrate powder in a mass ratio of 1:1; vibrating and beating the semi-finished down jacket to uniformly disperse down balls in the filling part of the down jacket;
and S8, sewing the down filling opening by adopting a textile wire harness to obtain the radiation-proof and ultraviolet-proof down jacket.
Example 3
A preparation method of a radiation-proof and ultraviolet-proof down jacket for pregnant women comprises the following steps:
step S1, weaving metal fiber wires in a warp and weft mode to form a metal fiber wire mesh, coating paint formed by mixing amino silicone oil and nano silicon dioxide on the surface of the metal fiber wire mesh, drying, weaving cotton and hemp fibers on the surface of the dried metal fiber wire mesh on two sides by using a weaving machine to form radiation-proof base cloth, wherein the warp density of the front side and the back side of the radiation-proof base cloth is 200 tracks, and the weight ratio of the amino silicone oil to the nano silicon dioxide is 2:1;
and S2, feeding the woven radiation-proof base cloth into a potassium hydroxide solution with the mass fraction of 18% for reaction for 2 hours, cleaning and drying, and immersing the radiation-proof base cloth activated by alkali into NaIO with the concentration of 6g/L according to the bath ratio of 1 4 Reacting the solution for 1 hour in a dark place, treating the solution in 0.1mol/L glycerol solution for 12 hours, washing the solution by using ionized water, and drying the solution in an oven at the temperature of between 60 and 85 ℃;
s3, soaking the oxidized radiation-proof base cloth into HBP-NH2 solution with the solution concentration of 25g/L, performing grafting reaction for 2 hours at 70 ℃, washing with deionized water, and drying in a vacuum drying oven at 65-70 ℃ for 1 hour to obtain modified radiation-proof base cloth;
and S4, soaking the modified radiation-proof base cloth dried in the step S3 in an ultraviolet auxiliary agent, and drying after soaking, wherein the ultraviolet auxiliary agent consists of the following components in parts by weight: 2,4 dihydroxy benzophenone 12 parts, polyvinyl alcohol 11 parts, iodopropynyl formate 7 parts, potassium sorbate 6 parts, cocoyl monoethanolamine 12 parts, glycerol 7 parts, protease 6 parts, alkyl glycoside 8 parts, titanium isopropoxide 12 parts, ethylene glycol 24 parts, and diphenol propane 11 parts;
s5, cleaning and drying the radiation-proof base cloth dried in the step S4 to obtain a radiation-proof and ultraviolet-proof fabric;
s6, processing a down filling part by taking the radiation-proof and ultraviolet-proof fabric as a down jacket fabric and reserving a down filling port;
step S7, filling the cleaned down into a down jacket filling part until the inner space is completely filled, atomizing a fluffing agent, and spraying the atomized fluffing agent onto the surface of a down ball to obtain an unsealed semi-finished down jacket, wherein the fluffing agent is a mixture of baking soda powder and tartrate powder in a mass ratio of 1:1; vibrating and beating the semi-finished down jacket to uniformly disperse down balls in the filling part of the down jacket;
and S8, sewing the down filling opening by adopting a textile wire harness to obtain the radiation-proof and ultraviolet-proof down jacket.
Example 4
A preparation method of a radiation-proof and ultraviolet-proof down jacket for pregnant women comprises the following steps:
step S1, weaving metal fiber wires in a warp and weft mode to form a metal fiber wire mesh, coating paint formed by mixing amino silicone oil and nano silicon dioxide on the surface of the metal fiber wire mesh, drying, weaving cotton and hemp fibers on the surface of the dried metal fiber wire mesh on two sides by using a weaving machine to form radiation-proof base cloth, wherein the warp density of the front side and the back side of the radiation-proof base cloth is 200 tracks, and the weight ratio of the amino silicone oil to the nano silicon dioxide is 2:1;
and S2, feeding the woven radiation-proof base cloth into a potassium hydroxide solution with the mass fraction of 18% for reaction for 2 hours, cleaning and drying, and immersing the radiation-proof base cloth activated by alkali into NaIO with the concentration of 6g/L according to the bath ratio of 1 4 Reacting in the solution in a dark place for 1h, treating in 0.1mol/L glycerol solution for 12h, washing with ionized water, and drying in an oven at 60-85 ℃;
s3, immersing the oxidized radiation-proof base cloth into HBP-NH2 solution with the solution concentration of 20g/L, carrying out grafting reaction for 2h at 70 ℃, washing with deionized water, and drying in a vacuum drying oven at 65-70 ℃ for 1h to obtain modified radiation-proof base cloth;
and S4, soaking the modified radiation-proof base cloth dried in the step S3 in an ultraviolet auxiliary agent, and drying the soaked base cloth, wherein the ultraviolet auxiliary agent consists of the following components in parts by weight: 2,4 dihydroxy benzophenone 12 parts, polyvinyl alcohol 11 parts, iodopropynyl formate 7 parts, potassium sorbate 6 parts, cocoyl monoethanolamine 12 parts, glycerol 7 parts, protease 6 parts, alkyl glycoside 8 parts, titanium isopropoxide 12 parts, ethylene glycol 24 parts, and diphenol propane 11 parts;
s5, cleaning and drying the radiation-proof base cloth dried in the step S4 to obtain a radiation-proof and ultraviolet-proof fabric;
s6, processing a down filling part by taking the radiation-proof and ultraviolet-proof fabric as a down jacket fabric and reserving a down filling port;
step S7, filling the cleaned down feather into a filling part of the down jacket until the inner space is completely filled, atomizing a fluffing agent and spraying the atomized fluffing agent onto the surface of a down feather ball to obtain an unsealed semi-finished down jacket, wherein the fluffing agent is a mixture of baking soda powder and tartrate powder in a mass ratio of 1:1; vibrating and beating the semi-finished down jacket to uniformly disperse down balls in the filling part of the down jacket;
and S8, sewing the down filling opening by adopting a textile wire harness to obtain the radiation-proof and ultraviolet-proof down jacket.
Comparative example 1
A preparation method of a radiation-proof and ultraviolet-proof down jacket for pregnant women comprises the following steps:
step S1, weaving metal fiber wires in a warp and weft mode to form a metal fiber wire mesh, and weaving cotton and hemp fibers on the surface of the metal fiber wire mesh on two sides by using a weaving machine to form radiation-proof base cloth, wherein the warp density of the radiation-proof base cloth is 200;
and S2, feeding the radiation-proof base cloth obtained in the step S1 into a potassium hydroxide solution with the mass fraction of 18% for reaction for 2 hours, cleaning and drying, and immersing the radiation-proof base cloth activated by alkali into NaIO with the concentration of 6g/L according to the bath ratio of 1 4 Reacting in the solution in a dark place for 1h, treating in 0.1mol/L glycerol solution for 12h, washing with ionized water, and drying in an oven at 60-85 ℃;
s3, soaking the oxidized radiation-proof base cloth into HBP-NH2 solution with the solution concentration of 20g/L, performing grafting reaction for 2 hours at 70 ℃, washing with deionized water, and drying in a vacuum drying oven at 65-70 ℃ for 1 hour to obtain modified radiation-proof base cloth;
and S4, soaking the modified radiation-proof base cloth dried in the step S3 in an ultraviolet auxiliary agent, and drying after soaking, wherein the ultraviolet auxiliary agent consists of the following components in parts by weight: 2,4 dihydroxy benzophenone 12 parts, polyvinyl alcohol 11 parts, iodopropynyl formate 7 parts, potassium sorbate 6 parts, cocoyl monoethanolamine 12 parts, glycerol 7 parts, protease 6 parts, alkyl glycoside 8 parts, titanium isopropoxide 12 parts, ethylene glycol 24 parts, and diphenol propane 11 parts;
s5, cleaning and drying the radiation-proof base cloth dried in the step S4 to obtain a radiation-proof and ultraviolet-proof fabric;
s6, processing a down filling part by taking the radiation-proof and ultraviolet-proof fabric as a down jacket fabric and reserving a down filling port;
step S7, filling the cleaned down feather into a filling part of the down jacket until the inner space is completely filled, atomizing a fluffing agent and spraying the atomized fluffing agent onto the surface of a down feather ball to obtain an unsealed semi-finished down jacket, wherein the fluffing agent is a mixture of baking soda powder and tartrate powder in a mass ratio of 1:1; vibrating and beating the semi-finished down jacket to uniformly disperse down balls in the filling part of the down jacket;
and S8, sewing the down filling opening by adopting a textile wire harness to obtain the radiation-proof and ultraviolet-proof down jacket.
Comparative example 2
A preparation method of a radiation-proof and ultraviolet-proof down jacket for pregnant women comprises the following steps:
step S1, weaving metal fiber wires in a warp and weft mode to form a metal fiber wire mesh, coating paint formed by mixing amino silicone oil and nano silicon dioxide on the surface of the metal fiber wire mesh, drying, weaving cotton and hemp fibers on the surface of the dried metal fiber wire mesh on two sides by using a weaving machine to form radiation-proof base cloth, wherein the warp density of the front side and the back side of the radiation-proof base cloth is 200 tracks, and the weight ratio of the amino silicone oil to the nano silicon dioxide is 2:1;
step S2, dipping the woven radiation-proof base cloth into an ultraviolet auxiliary agent, and drying the dipped radiation-proof base cloth, wherein the ultraviolet auxiliary agent comprises the following components in parts by weight: 2,4 dihydroxy benzophenone 12 parts, polyvinyl alcohol 11 parts, iodopropynyl formate 7 parts, potassium sorbate 6 parts, cocoyl monoethanolamine 12 parts, glycerol 7 parts, protease 6 parts, alkyl glycoside 8 parts, titanium isopropoxide 12 parts, ethylene glycol 24 parts, and diphenol propane 11 parts;
s3, cleaning and drying the radiation-proof base cloth dried in the step S2 to obtain a radiation-proof and ultraviolet-proof fabric;
s4, processing a down filling part by using the radiation-proof and ultraviolet-proof fabric as a down jacket fabric and reserving a down filling port;
step S5, filling the cleaned down into a down jacket filling part until the inner space is completely filled, atomizing a fluffing agent, and spraying the atomized fluffing agent onto the surface of a down ball to obtain an unsealed semi-finished down jacket, wherein the fluffing agent is a mixture of baking soda powder and tartrate powder in a mass ratio of 1:1; vibrating and beating the semi-finished down jacket to uniformly disperse down balls in the filling part of the down jacket;
and S6, sewing the down filling opening by adopting a textile wire harness to obtain the anti-radiation and anti-ultraviolet down jacket.
The method for preparing the anti-radiation and anti-ultraviolet down jackets according to the examples 1 to 4, the comparative examples 1 to 2 and the preparation method comprises the following steps of respectively preparing the anti-radiation and anti-ultraviolet down jackets, respectively washing six groups of samples with water, wherein the washing times are 30 times, and respectively carrying out anti-ultraviolet performance, anti-radiation performance and fabric shrinkage rate test on each group of anti-radiation and anti-ultraviolet down jacket fabrics before and after washing with water, wherein the anti-radiation and anti-ultraviolet down jacket fabrics comprise the following components: (1) rubbing fastness test: performing fastness test according to the GB/T3920-2008 'Friction fastness test'; (2) According to GB/T23463-2009 microwave radiation protective clothing, the shielding effectiveness of the fabric on electromagnetic waves is tested, and the testing frequency in the test is 300MHZ. (3) According to Chinese standard GB/T17032-1997 test method for ultraviolet transmittance of textile fabrics, ultraviolet resistance detection experiments are carried out on the down jacket fabric, and the test results are as follows:
combining the above experimental data, the following conclusions can be drawn:
from the data of examples 1 to 4, it can be seen that the dry rubbing fastness and the wet rubbing fastness of the fabrics of examples 1 to 4 reach 4 grades, and the dry rubbing fastness and the wet rubbing fastness of the fabrics of example 4 reach more than 4 grades, while the dry rubbing fastness and the wet rubbing fastness of the down jacket in comparative example 1 are significantly reduced compared with those of example 4, and it can be seen that the wear resistance of the down jacket fabric can be enhanced by coating the coating formed by mixing amino silicone oil and nano silica on the surface of the metal fiber mesh, and in addition, as compared with examples 1 to 4, the UPF value of the down jacket fabric in comparative example 2 is significantly reduced after 30 times of washing, and it can be seen that the fabric is modified before being impregnated with the ultraviolet assistant, the durability of the fabric against ultraviolet ray can be improved, while as compared with comparative example 1, it can be seen that the fabric of the metal fiber mesh down jacket which is not sprayed with amino silicone oil and nano silica has a lower radiation shielding performance, and as compared with comparative example 1, the fabric not only has an enhanced ultraviolet ray resistance, but also has a certain reduction effect on the shrinkage of the down jacket after washing.
The foregoing shows and describes the general principles and features of the present invention, together with the advantages thereof. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are given by way of illustration of the principles of the present invention, but that various changes and modifications may be made without departing from the spirit and scope of the invention, and such changes and modifications are within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (9)
1. A preparation method of a radiation-proof and ultraviolet-proof down jacket for pregnant women is characterized by comprising the following steps: the method comprises the following steps:
step S1, weaving metal fiber wires in a warp and weft mode to form a metal fiber wire mesh, coating paint formed by mixing amino silicone oil and nano silicon dioxide on the surface of the metal fiber wire mesh, drying, and weaving cotton-flax fibers on the surface of the dried metal fiber wire mesh in a double-sided mode by using a weaving machine to form radiation-proof base cloth;
step S2, feeding the woven radiation-proof base cloth into a potassium hydroxide solution with the mass fraction of 18% for reaction for 2 hours, cleaning and drying, and immersing the radiation-proof base cloth activated by alkali into NaIO according to the bath ratio of 1 4 Reacting in the solution for 1-1.5h in a dark place, treating in 0.1mol/L glycerol solution for 12h, washing with ionized water, and drying in an oven at 60-85 ℃;
s3, immersing the oxidized radiation-proof base cloth into HBP-NH 2 In the solution, grafting reaction is carried out for 2h at 70 ℃, the solution is washed by deionized water and is put into a vacuum drying oven at 65-70 ℃ for drying for 1-2h to obtain modified radiation-proof base cloth;
s4, soaking the modified radiation-proof base cloth dried in the step S3 in an ultraviolet auxiliary agent, and drying after soaking;
s5, cleaning and drying the radiation-proof base cloth dried in the step S4 to obtain a radiation-proof and ultraviolet-proof fabric;
s6, processing a down filling part by taking the radiation-proof and ultraviolet-proof fabric as a down jacket fabric and reserving a down filling port;
s7, filling down feather into the down feather filling port reserved in the step S6;
and S8, sewing the down filling opening by adopting a textile wire harness to obtain the radiation-proof and ultraviolet-proof down jacket.
2. The preparation method of the anti-radiation and anti-ultraviolet down jacket for pregnant women, according to claim 1, is characterized in that: the warp density of the front and back surfaces of the radiation-proof base cloth in the step S1 is 100-200.
3. The preparation method of the anti-radiation and anti-ultraviolet down jacket for pregnant women, according to claim 1, is characterized in that: naIO in the step S2 4 The concentration of the solution was 6g/L.
4. The preparation method of the anti-radiation and anti-ultraviolet down jacket for pregnant women, according to claim 1, is characterized in that: the concentration of the HBP-NH2 solution in the step S3 is 15-25g/L.
5. The preparation method of the anti-radiation and anti-ultraviolet down jacket for pregnant women, according to claim 1, is characterized in that: the ultraviolet auxiliary agent in the step S4 comprises the following components in parts by weight: 2,4 dihydroxy benzophenone 10-14 parts, polyvinyl alcohol 10-12 parts, iodopropynyl formate 6-8 parts, potassium sorbate 5-8 parts, cocoyl monoethanolamine 10-14 parts, glycerol 6-8 parts, protease 5-8 parts, alkyl glycoside 6-9 parts, titanium isopropoxide 10-14 parts, ethylene glycol 22-25 parts, and diphenol propane 10-12 parts.
6. The preparation method of the anti-radiation and anti-ultraviolet down jacket for pregnant women, according to claim 1, is characterized in that: the method for filling the down feather in the step S7 comprises the following steps:
step A1, filling the cleaned down into a filling part of the down jacket until the inner space is completely filled, atomizing a fluffing agent, and spraying the atomized fluffing agent onto the surface of a down ball to obtain an unsealed semi-finished down jacket;
step A2: and vibrating and beating the semi-finished down jacket to uniformly disperse down balls in the filling part of the down jacket.
7. The preparation method of the anti-radiation and anti-ultraviolet down jacket for pregnant women, according to claim 6, is characterized in that: the fluffing agent is a mixture of baking soda powder and tartrate powder with the mass ratio of 1:1.
8. The preparation method of the anti-radiation and anti-ultraviolet down jacket for pregnant women, according to claim 1, is characterized in that: the weight ratio of the amino silicone oil to the nano silicon dioxide in the step S1 is 2:1.
9. A radiation-proof ultraviolet-proof down jacket for pregnant women, which is manufactured by the manufacturing method of any one of claims 1 to 8.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN202211198074.1A CN115491895B (en) | 2022-09-29 | 2022-09-29 | Radiation-proof ultraviolet-proof down jacket for pregnant women and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN202211198074.1A CN115491895B (en) | 2022-09-29 | 2022-09-29 | Radiation-proof ultraviolet-proof down jacket for pregnant women and preparation method thereof |
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