CN115477870A - Preparation method and method of environment-friendly vegetable oil-based book and periodical printing ink - Google Patents
Preparation method and method of environment-friendly vegetable oil-based book and periodical printing ink Download PDFInfo
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- CN115477870A CN115477870A CN202211315593.1A CN202211315593A CN115477870A CN 115477870 A CN115477870 A CN 115477870A CN 202211315593 A CN202211315593 A CN 202211315593A CN 115477870 A CN115477870 A CN 115477870A
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- 235000015112 vegetable and seed oil Nutrition 0.000 title claims abstract description 25
- 239000008158 vegetable oil Substances 0.000 title claims abstract description 25
- 238000007639 printing Methods 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title abstract description 13
- 235000021388 linseed oil Nutrition 0.000 claims abstract description 21
- 239000000944 linseed oil Substances 0.000 claims abstract description 21
- 239000002383 tung oil Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000049 pigment Substances 0.000 claims abstract description 16
- 239000012860 organic pigment Substances 0.000 claims abstract description 14
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 12
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 12
- 238000001035 drying Methods 0.000 claims abstract description 11
- 239000002966 varnish Substances 0.000 claims abstract description 11
- 239000000654 additive Substances 0.000 claims abstract description 10
- 239000003349 gelling agent Substances 0.000 claims abstract description 8
- 230000000996 additive effect Effects 0.000 claims abstract description 7
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003831 antifriction material Substances 0.000 claims abstract description 5
- OEOIWYCWCDBOPA-UHFFFAOYSA-N 6-methyl-heptanoic acid Chemical compound CC(C)CCCCC(O)=O OEOIWYCWCDBOPA-UHFFFAOYSA-N 0.000 claims abstract description 4
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 claims abstract description 4
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 claims abstract description 4
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 9
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 claims description 6
- 239000010773 plant oil Substances 0.000 claims description 6
- -1 amyl ester Chemical class 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- PHEDXBVPIONUQT-RGYGYFBISA-N phorbol 13-acetate 12-myristate Chemical compound C([C@]1(O)C(=O)C(C)=C[C@H]1[C@@]1(O)[C@H](C)[C@H]2OC(=O)CCCCCCCCCCCCC)C(CO)=C[C@H]1[C@H]1[C@]2(OC(C)=O)C1(C)C PHEDXBVPIONUQT-RGYGYFBISA-N 0.000 claims description 3
- 238000001556 precipitation Methods 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 239000000463 material Substances 0.000 claims 1
- PPQREHKVAOVYBT-UHFFFAOYSA-H dialuminum;tricarbonate Chemical compound [Al+3].[Al+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O PPQREHKVAOVYBT-UHFFFAOYSA-H 0.000 abstract description 4
- 230000015556 catabolic process Effects 0.000 abstract description 3
- 238000006731 degradation reaction Methods 0.000 abstract description 3
- 239000002761 deinking Substances 0.000 abstract description 3
- 229940118662 aluminum carbonate Drugs 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000011230 binding agent Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000013410 fast food Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 235000020238 sunflower seed Nutrition 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- 235000014101 wine Nutrition 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention provides preparation and a method of environment-friendly vegetable oil-based book and periodical printing ink, and relates to the field of printing ink preparation. The environment-friendly vegetable oil-based book and periodical printing ink comprises the following raw materials in parts by mass: 15% of organic pigment, 25% to 35% of linseed oil, 10% to 15% of tung oil, 3% to 5% of water-based acrylic resin, 1% to 5% of an anti-friction agent, 5% of a gelling agent, 10% of an additive, 10% of quick-drying water and 10% of varnish, wherein the organic pigment is any one of azo pigment, lake pigment, phthalocyanine pigment and quinacridone pigment, and the gelling agent is one or more of aluminum isopropoxide and derivatives thereof, aluminum isooctanoate, lower aluminum carbonate and active organic aluminum compounds. Through using linseed oil and tung oil mixed use, performance is environmental protection more, and simultaneously inside waterborne acrylic resin and the antifriction agent and the quick drying water that add for accomplish the deinking very degradation processing easily when retrieving, make the whole ductility of printing ink, wearability and quick drying nature all obtain good promotion moreover.
Description
Technical Field
The invention relates to the technical field of ink preparation, in particular to preparation and a method of environment-friendly vegetable oil-based book and periodical ink.
Background
The vegetable oil-based environment-friendly ink uses vegetable oil as a binder, the vegetable oil binder mainly comprises soybean oil, rapeseed oil, sunflower seed oil and the like, the vegetable oil binder can reduce the release amount of volatile organic compounds, completely removes hydrocarbon resin in the common ink, reduces the content of aromatic hydrocarbon, is harmless to human bodies, has wide application range, can be suitable for flexible packages, box bags, hygienic product packages, fast food lunch boxes, shopping bags, paper cups, cigarette boxes and other trademarks, newspapers, magazines, adhesive labels, beverages, wines, medicines and various cosmetics, can not generate friction electrification phenomenon in the vegetable oil-based environment-friendly ink, can emit natural fragrance, and has multiple characteristics in technology and application, so the vegetable oil-based environment-friendly ink becomes the environment-friendly ink with wide application prospect.
However, the existing ink has general extensibility after production, a large amount of ink is often used in the using process, the production cost is greatly increased, meanwhile, the existing ink has low air drying speed, the traditional ink is not easy to deink when being recycled, the traditional ink is not convenient to degrade after deinking and is not environment-friendly enough, and the traditional ink can generate pungent smell when being used, so that the preparation method of the environment-friendly vegetable oil-based book ink and the preparation method thereof are provided by technical personnel in the field, and the problems provided by the background technology are solved.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides a preparation method of environment-friendly vegetable oil-based book and periodical printing ink and a method thereof, and solves the problems of poor ductility, inconvenient degradation and insufficient environmental protection of the existing printing ink.
(II) technical scheme
In order to achieve the purpose, the invention is realized by the following technical scheme: the environment-friendly vegetable oil-based book and periodical printing ink comprises the following raw materials in parts by mass: 15% of organic pigment, 25% -35% of linseed oil, 10% -15% of tung oil, 3% -5% of water-based acrylic resin, 1% -5% of an anti-friction agent, 5% of a gel agent, 10% of an additive, 10% of quick-drying water and 10% of varnish.
Preferably, the organic pigment is any one of an azo pigment, a lake pigment, a phthalocyanine pigment and a quinacridone pigment.
Preferably, the gelling agent is one or more of aluminum isopropoxide and its derivatives, aluminum isooctanoate, lower aluminum carbonate and active organoaluminum compounds.
Preferably, the varnish may be one of No. 6 ink or No. 0 ink.
Preferably, the additive is one or more of isophorone, a mixture of amyl esters, PMA and n-butanol.
A preparation method of environment-friendly vegetable oil-based book and periodical printing ink comprises the following steps:
s1, taking 25-35% of linseed oil and 10-15% of tung oil by mass, adding 10% of additives by mass in the linseed oil and the tung oil by mass, and heating and stirring the linseed oil and the tung oil to obtain a mixture of the linseed oil and the tung oil;
s2, stirring and mixing 3-5% by mass of water-based acrylic resin and 15% by mass of organic pigment, and filtering out particles which are not fully fused in the water-based acrylic resin and the organic pigment after precipitation;
s3, fully cooling the mixture of the linseed oil and the tung oil in the step 1, fully stirring and mixing the mixture with the mixture in the step 2,
s4, adding 1-5% by mass of a friction-resistant agent, 5% by mass of a gelling agent, 10% by mass of quick-drying water and 10% by mass of ink mixing oil into the ink mixture obtained in the step 3, and uniformly stirring to obtain environment-friendly plant oil-based book and periodical ink;
and S5, detecting each index of the environment-friendly plant oil-based book and periodical printing ink obtained in the step 4.
Preferably, the heating temperature in the step 1 is 120-180 ℃, and the heating time is 10-20 minutes.
(III) advantageous effects
The invention provides a preparation method of environment-friendly plant oil-based book and periodical printing ink and a preparation method thereof. The method has the following beneficial effects:
1. according to the invention, the linseed oil and the tung oil are mixed for use, the service performance is more environment-friendly, and meanwhile, the water-based acrylic resin, the friction-resistant agent and the quick drying water which are added inside are easy to perform deinking degradation treatment during recovery, and the overall ductility, the wear resistance and the quick drying property of the printing ink are all well improved.
Detailed Description
The technical solutions of the present invention are described clearly and completely below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
the embodiment of the invention provides environment-friendly vegetable oil-based book and periodical printing ink which comprises the following raw materials in parts by mass: 15% of organic pigment, 25% to 35% of linseed oil, 10% to 15% of tung oil, 3% to 5% of water-based acrylic resin, 1% to 5% of an anti-friction agent, 5% of a gelling agent, 10% of an additive, 10% of quick-drying water and 10% of varnish, wherein the organic pigment is any one of azo pigment, lake pigment, phthalocyanine pigment and quinacridone pigment, the gelling agent is one or more of aluminum isopropoxide and a derivative thereof, aluminum isooctanoate, low-carbon aluminum and an active organic aluminum compound, the varnish can be one of No. 6 varnish or No. 0 varnish, and the additive is one or more of isophorone, a mixture of amyl ester, PMA and n-butyl alcohol.
A preparation method of environment-friendly vegetable oil-based book and periodical printing ink comprises the following steps:
s1, taking 25-35% of linseed oil and 10-15% of tung oil by mass, adding 10% of additives by mass in the linseed oil and the tung oil by mass, and heating and stirring the linseed oil and the tung oil to obtain a mixture of the linseed oil and the tung oil;
s2, stirring and mixing 3-5% by mass of water-based acrylic resin and 15% by mass of organic pigment, and filtering out particles which are not fully fused in the water-based acrylic resin and the organic pigment after precipitation;
s3, fully cooling the mixture of the linseed oil and the tung oil in the step 1, fully stirring and mixing the mixture and the mixture in the step 2,
s4, adding 1-5% by mass of a friction-resistant agent, 5% by mass of a gelling agent, 10% by mass of quick-drying water and 10% by mass of varnish into the ink mixture obtained in the step 3, and uniformly stirring to obtain the environment-friendly plant oil-based book and periodical ink;
and S5, detecting each index of the environment-friendly vegetable oil-based book and periodical ink obtained in the step 4.
The heating temperature in the step 1 is 120-180 ℃, and the heating time is 10-20 minutes.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that various changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (7)
1. The environment-friendly vegetable oil-based book and periodical printing ink is characterized in that: the material comprises the following raw materials in percentage by mass: 15% of organic pigment, 25% -35% of linseed oil, 10% -15% of tung oil, 3% -5% of water-based acrylic resin, 1% -5% of an anti-friction agent, 5% of a gel agent, 10% of an additive, 10% of quick-drying water and 10% of varnish.
2. The environment-friendly vegetable oil-based book and periodical ink according to claim 1, wherein: the organic pigment is any one of azo pigment, lake pigment, phthalocyanine pigment and quinacridone pigment.
3. The environment-friendly vegetable oil-based book and periodical ink as recited in claim 1, wherein: the gel is one or more of aluminum isopropoxide and derivatives thereof, aluminum isooctanoate, low-carbon aluminum and active organic aluminum compounds.
4. The environment-friendly vegetable oil-based book and periodical ink according to claim 1, wherein: the varnish may be one of No. 6 ink or No. 0 ink.
5. The environment-friendly vegetable oil-based book and periodical ink according to claim 1, wherein: the additive is one or more of isophorone, a mixture of amyl ester, PMA and n-butanol.
6. The method for preparing the environment-friendly vegetable oil-based book and periodical ink according to claim 1, wherein the method comprises the following steps: the method comprises the following steps:
s1, taking 25-35% of linseed oil and 10-15% of tung oil by mass, adding 10% of additives by mass in the linseed oil and the tung oil by mass, and heating and stirring the linseed oil and the tung oil to obtain a mixture of the linseed oil and the tung oil;
s2, stirring and mixing 3-5% by mass of water-based acrylic resin and 15% by mass of organic pigment, and filtering out particles which are not fully fused in the water-based acrylic resin and the organic pigment after precipitation;
s3, fully cooling the mixture of the linseed oil and the tung oil in the step 1, fully stirring and mixing the mixture and the mixture in the step 2,
s4, adding 1-5% by mass of a friction-resistant agent, 5% by mass of a gelling agent, 10% by mass of quick-drying water and 10% by mass of varnish into the ink mixture obtained in the step 3, and uniformly stirring to obtain the environment-friendly plant oil-based book and periodical ink;
and S5, detecting each index of the environment-friendly vegetable oil-based book and periodical ink obtained in the step 4.
7. The method for preparing the environment-friendly plant oil-based book and periodical ink as claimed in claim 1, wherein the method comprises the following steps: the heating temperature in the step 1 is 120-180 ℃, and the heating time is 10-20 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211315593.1A CN115477870A (en) | 2022-10-26 | 2022-10-26 | Preparation method and method of environment-friendly vegetable oil-based book and periodical printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211315593.1A CN115477870A (en) | 2022-10-26 | 2022-10-26 | Preparation method and method of environment-friendly vegetable oil-based book and periodical printing ink |
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| Publication Number | Publication Date |
|---|---|
| CN115477870A true CN115477870A (en) | 2022-12-16 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202211315593.1A Pending CN115477870A (en) | 2022-10-26 | 2022-10-26 | Preparation method and method of environment-friendly vegetable oil-based book and periodical printing ink |
Country Status (1)
| Country | Link |
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| CN (1) | CN115477870A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107778965A (en) * | 2016-08-31 | 2018-03-09 | 天津天女化工集团股份有限公司 | A kind of nano-particle vegetable oil base rubber printing ink and preparation method thereof |
| CN108997818A (en) * | 2018-08-15 | 2018-12-14 | 芜湖扬展新材料科技服务有限公司 | A kind of environment protecting plant oil type ink and its preparation process |
| CN109971247A (en) * | 2017-12-28 | 2019-07-05 | 宁波龙茂文教科技有限公司 | A kind of aqueous plant type ink and preparation method thereof |
| TWI767738B (en) * | 2021-06-03 | 2022-06-11 | 位速科技股份有限公司 | Conductive ink resin composition, transparent conductive film and transparent conductive substrate structure and manufacturing method thereof |
-
2022
- 2022-10-26 CN CN202211315593.1A patent/CN115477870A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107778965A (en) * | 2016-08-31 | 2018-03-09 | 天津天女化工集团股份有限公司 | A kind of nano-particle vegetable oil base rubber printing ink and preparation method thereof |
| CN109971247A (en) * | 2017-12-28 | 2019-07-05 | 宁波龙茂文教科技有限公司 | A kind of aqueous plant type ink and preparation method thereof |
| CN108997818A (en) * | 2018-08-15 | 2018-12-14 | 芜湖扬展新材料科技服务有限公司 | A kind of environment protecting plant oil type ink and its preparation process |
| TWI767738B (en) * | 2021-06-03 | 2022-06-11 | 位速科技股份有限公司 | Conductive ink resin composition, transparent conductive film and transparent conductive substrate structure and manufacturing method thereof |
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Application publication date: 20221216 |
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