CN115467189A - Method for manufacturing yellow high-transparency formed paper - Google Patents

Method for manufacturing yellow high-transparency formed paper Download PDF

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Publication number
CN115467189A
CN115467189A CN202211130089.4A CN202211130089A CN115467189A CN 115467189 A CN115467189 A CN 115467189A CN 202211130089 A CN202211130089 A CN 202211130089A CN 115467189 A CN115467189 A CN 115467189A
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Prior art keywords
pulp
paper
surface sizing
formed paper
yellow
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CN202211130089.4A
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Chinese (zh)
Inventor
汤新根
陈飞
邓根青
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Welbon Special Material Co ltd
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Welbon Special Material Co ltd
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Priority to CN202211130089.4A priority Critical patent/CN115467189A/en
Publication of CN115467189A publication Critical patent/CN115467189A/en
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/02Chemical or chemomechanical or chemothermomechanical pulp
    • D21H11/04Kraft or sulfate pulp
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03Non-macromolecular organic compounds
    • D21H17/05Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/17Ketenes, e.g. ketene dimers
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24Polysaccharides
    • D21H17/28Starch
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16Sizing or water-repelling agents
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/28Colorants ; Pigments or opacifying agents

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paper (AREA)

Abstract

The invention discloses a method for manufacturing yellow high-transparency formed paper, which belongs to the technical field of formed paper, wherein bleached sulfate needle-leaf pulp, flash-dried pulp and bleached sulfate broad-leaf pulp are disintegrated by a hydrapulper to obtain pulp, the pulp is treated by a high-frequency fluffer and then added with water to prepare fiber dispersion liquid, the fiber dispersion liquid is screened by a head box and a pulp distributor for dewatering, papermaking and forming, then paper is prepared by drying of a drying part of a production system, sizing materials and pigment liquid are uniformly mixed on the surface of the paper, and then the paper is subjected to surface sizing and dyeing, drying and slitting to prepare the yellow high-transparency formed paper; the manufacturing method does not add dye or pigment in the pulp, thereby being convenient for cleaning a production system; the surface sizing process and the dyeing process are synchronously combined, the surface sizing material is used for coating the pigment on the paper surface, and the pigment is not required to be dyed independently and dried at high temperature, so that the process is more convenient and faster; discoloration can be prevented by utilizing the water resistance of AKD wax and the hydrophobicity of styrene-acrylate copolymer.

Description

Method for manufacturing yellow high-transparency formed paper
Technical Field
The invention belongs to the technical field of forming paper, and particularly relates to a method for manufacturing yellow high-transparency forming paper.
Background
The cigarette is a strip-shaped cigarette product formed by rolling tobacco shreds with cigarette paper, and the cigarette comprises tipping paper, forming paper and tows besides the tobacco shreds and the cigarette paper in the preparation process. The forming paper is divided into common forming paper and high-air-permeability forming paper, is special paper for wrapping tows, and can wrap soft tows into long strip-shaped filter rods. The high-air-permeability forming paper is generally used in combination with tipping paper drilled by laser, and has great effects on tar reduction and harm reduction of cigarettes.
The dyeing mode of common high air permeability shaping paper is add the dyestuff for thick liquid usually, makes with making again after the spacing dyeing of thick liquids, and this kind of mode is comparatively serious to production system's pollution, and the dyestuff dynamics of colouring is strong moreover, and production system is difficult for wasing after the production is finished. In addition, the yellow dye is easy to change color after being dried in a drying part of the production system, and obvious color difference is generated. A new method of making formed paper is needed.
Disclosure of Invention
The invention aims to provide a method for manufacturing yellow high-transparency formed paper, which solves the problems in the background art.
The purpose of the invention can be realized by the following technical scheme:
a method for manufacturing yellow high-transmittance formed paper comprises the following steps:
the method comprises the following steps: pulping bleached sulfate coniferous pulp, flash-dried pulp and bleached sulfate broadleaf pulp by using a hydrapulper to obtain pulp;
step two: treating the pulp by a high-frequency fluffer to completely disperse fibers in the pulp, and adding water to prepare a fiber dispersion liquid with the concentration of 1-2%;
step three: and (2) dewatering the fiber dispersion liquid on a net through a high-position box and a pulp distributor, making into paper, drying through a drying part of a production system to obtain paper, uniformly mixing a surface sizing material and a pigment liquid, then carrying out surface sizing dyeing on the paper, drying, and slitting to obtain the yellow high-transparency formed paper.
Further, the mass ratio of the solid in the bleached sulfate needle-leaf pulp, the flash-dried pulp and the bleached sulfate broad-leaf pulp in the step one is 10-20:30-40:30-50.
Further, the dosage ratio of the surface sizing material to the pigment liquid in the third step is 10-50g:1g.
Further, the preparation method of the surface sizing material comprises the following steps: and (3) stirring and dissolving starch with water, then mixing with polyvinyl alcohol powder, and decocting and curing with steam to obtain the surface sizing material.
Furthermore, the content of starch in the surface sizing material is 2-3wt%, and the content of polyvinyl alcohol is 1-1.5wt%.
Further, the pigment liquid comprises 1 part of medium chrome yellow, 2 parts of lemon yellow, 0.1 part of AKD wax, 0.2 part of styrene-acrylate copolymer and 5 parts of water in parts by mass.
The invention has the beneficial effects that:
1. the manufacturing method of the yellow high-transparency forming paper does not add dye or pigment into the pulp, and is convenient for cleaning a production system.
2. The surface sizing material and the pigment liquid are mixed for use, the surface sizing process and the dyeing process are synchronously carried out in a combined manner, the pigment is hung on the paper surface by utilizing the surface sizing material, and the pigment is not required to be dyed and dried at high temperature independently, so that the method is more convenient and faster.
3. According to the manufacturing method of the yellow high-transparency forming paper, dye is not used for in-pulp dyeing, so that a color fixing agent is not required to be added, the water resistance of AKD wax and the hydrophobicity of styrene-acrylate copolymer are utilized, the yellow high-transparency forming paper is prevented from fading in the processes of rolling a rod, coating line glue, lap glue and the like on a forming machine, and the problems that the surface of the forming paper is too smooth to cause machine slipping or long and short rods and the like due to the use of the color fixing agent are avoided.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
Preparing yellow high-transparency formed paper, comprising the following steps:
the method comprises the following steps: 100g of medium chrome yellow, 200g of lemon yellow, 10g of AKD wax, 20g of styrene-acrylate copolymer and 500g of water are stirred and mixed to obtain a pigment liquid for later use.
Step two: stirring and dissolving starch with water, then mixing the starch with polyvinyl alcohol powder, boiling and curing with steam to obtain a surface sizing material with the starch content of 2wt% and the polyvinyl alcohol content of 1wt% for later use.
Step three: pulping bleached sulfate needle-leaf pulp with the solid mass of 10kg, flash-dried pulp with the solid mass of 30kg and bleached sulfate broad-leaf pulp with the solid mass of 30kg by using a hydrapulper to obtain pulp;
step four: treating the pulp by a high-frequency fluffer to completely disperse fibers in the pulp, and adding water to prepare a fiber dispersion liquid with the concentration of 1%;
step five: the fiber dispersion liquid is made into paper by a high-level box and a pulp distributor through net-surfing dehydration and papermaking, and then the paper is made by drying of a drying part of a production system; and (3) applying sizing materials and pigment liquid on the surface according to the weight ratio of 10g:1g of the raw materials are uniformly mixed, then the paper is subjected to surface sizing dyeing, and the paper after the surface sizing dyeing is dried and cut to prepare the yellow high-transparency formed paper.
Example 2
Preparing yellow high-transparency formed paper, comprising the following steps:
the method comprises the following steps: 100g of medium chrome yellow, 200g of lemon yellow, 10g of AKD wax, 20g of styrene-acrylate copolymer and 500g of water are stirred and mixed to obtain a pigment liquid for later use.
Step two: stirring and dissolving starch with water, then mixing with polyvinyl alcohol powder, decocting and curing with steam to obtain a surface sizing material with the starch content of 2.5wt% and the polyvinyl alcohol content of 1.2wt%, and reserving for later use.
Step three: pulping bleached sulfate needle-leaf pulp with the solid mass of 15kg, flash-dried pulp with the solid mass of 35kg and bleached sulfate broad-leaf pulp with the solid mass of 4kg by using a hydrapulper to obtain pulp;
step four: treating the pulp by a high-frequency fluffer to completely disperse fibers in the pulp, and adding water to prepare a fiber dispersion liquid with the concentration of 1.5%;
step five: the fiber dispersion liquid is dewatered and manufactured into paper by a high-position box and a pulp distributor, and then the paper is prepared by drying through a drying part of a production system; and (3) applying the sizing material and the pigment liquid on the surface according to the weight ratio of 25g:1g of the additive is uniformly mixed, then the paper is subjected to surface sizing dyeing, and the paper after the surface sizing dyeing is dried and cut to prepare yellow high-transparency formed paper.
Example 3
Preparing yellow high-transparency formed paper, comprising the following steps:
the method comprises the following steps: 100g of medium chrome yellow, 200g of lemon yellow, 10g of AKD wax, 20g of styrene-acrylate copolymer and 500g of water are stirred and mixed to obtain a pigment liquid for later use.
Step two: stirring and dissolving starch with water, then mixing the starch with polyvinyl alcohol powder, boiling and curing with steam to obtain a surface sizing material with the starch content of 3wt% and the polyvinyl alcohol content of 1.5wt% for later use.
Step three: pulping bleached sulfate needle-leaf pulp with the solid mass of 20kg, flash-dried pulp with the solid mass of 40kg and bleached sulfate broad-leaf pulp with the solid mass of 50kg by using a hydrapulper to obtain pulp;
step four: treating the pulp by a high-frequency fluffer to completely disperse fibers in the pulp, and adding water to prepare a fiber dispersion liquid with the concentration of 2%;
step five: the fiber dispersion liquid is dewatered and manufactured into paper by a high-position box and a pulp distributor, and then the paper is prepared by drying through a drying part of a production system; and (3) applying the sizing material and the pigment liquid on the surface according to the weight ratio of 50g:1g of the additive is uniformly mixed, then the paper is subjected to surface sizing dyeing, and the paper after the surface sizing dyeing is dried and cut to prepare yellow high-transparency formed paper.
Comparative example 1: on the basis of the example 2, the existing process is adopted, the pulp is dyed in a mode of adding yellow dye into the pulp, the color fixing agent with the same proportion as the yellow dye needs to be added when the concentration of fibers in the pulp is low, then the high-frequency fluffer in the fourth step is adopted for processing, the pulp is dewatered, manufactured and formed, the yellow dye needs to be dried under the condition of 140 +/-10 ℃, the dried paper is directly subjected to surface sizing by using a surface sizing material, and the yellow high-transparency forming paper is prepared after drying again.
Comparative example 2: on the basis of the comparative example 1, the color fixing agent is not added, and the rest steps are kept unchanged, so that the yellow high-transmittance forming paper is prepared.
Comparative example 3: on the basis of comparative example 2, AKD wax and styrene-acrylate copolymer are not added when preparing the pigment liquid in the first step, and the subsequent steps are kept unchanged to prepare yellow high-transmittance molding paper.
The yellow high-transparency molded papers obtained by the methods of examples 1 to 3 and comparative examples 1 to 2 were observed for appearance, and then each group of the yellow high-transparency molded papers was wetted with water, and after 10 seconds, the water content of each group of the yellow high-transparency molded papers was sucked off with a white paper towel to observe whether or not the colors were faded, and the results are shown in table 1:
TABLE 1
Figure BDA0003849886410000051
As can be seen from table 1, the yellow high-permeability formed papers obtained in examples 1 to 3 did not cause color difference after drying at high temperature and had flat surfaces. The surface of the paper is too smooth due to the addition of the color fixing agent in the prior art in the comparative example 1, the color fixing agent is not added in the comparative example 2, AKD wax and styrene-acrylate copolymer are not added in the comparative example 3, and the paper has a color losing phenomenon after meeting water.
It should be noted that, in this document, terms such as "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (6)

1. A method for manufacturing yellow high-transmittance formed paper is characterized by comprising the following steps:
the method comprises the following steps: pulping bleached sulfate needle-leaf pulp, flash-dried pulp and bleached sulfate broad-leaf pulp by using a hydrapulper to obtain pulp;
step two: treating the pulp by a high-frequency fluffer to disperse fibers, and adding water to prepare a fiber dispersion liquid with the concentration of 1-2%;
step three: and (3) dehydrating the fiber dispersion liquid, making paper into a shape, drying to obtain paper, mixing the surface sizing material and the pigment liquid, then performing surface sizing dyeing on the paper, drying, and slitting to obtain yellow high-transparency formed paper.
2. The method for manufacturing yellow high-permeability formed paper according to claim 1, wherein the mass ratio of solids in the bleached kraft softwood pulp, the flash dried pulp and the bleached kraft broad leaf pulp in the first step is 10-20:30-40:30-50.
3. The method for manufacturing yellow high-transparency formed paper according to claim 1, wherein the ratio of the amount of the surface sizing material to the amount of the pigment liquid in the third step is 10-50g:1g.
4. The method for manufacturing yellow high-transparency formed paper according to claim 1, wherein the preparation method of the surface sizing material comprises the following steps: and (3) stirring and dissolving starch with water, then mixing with polyvinyl alcohol powder, and decocting and curing with steam to obtain the surface sizing material.
5. A method for manufacturing yellow high-transparency formed paper according to claim 4, characterized in that the starch content in the surface sizing agent is 2-3wt% and the polyvinyl alcohol content is 1-1.5wt%.
6. The method for manufacturing yellow high-transparency formed paper according to claim 1, wherein the pigment liquid comprises 1 part of medium chrome yellow, 2 parts of lemon yellow, 0.1 part of AKD wax, 0.2 part of styrene-acrylate copolymer and 5 parts of water in parts by mass.
CN202211130089.4A 2022-09-16 2022-09-16 Method for manufacturing yellow high-transparency formed paper Pending CN115467189A (en)

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