CN115464956B - Weather-resistant sealing tape and processing method - Google Patents

Weather-resistant sealing tape and processing method Download PDF

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Publication number
CN115464956B
CN115464956B CN202211040115.4A CN202211040115A CN115464956B CN 115464956 B CN115464956 B CN 115464956B CN 202211040115 A CN202211040115 A CN 202211040115A CN 115464956 B CN115464956 B CN 115464956B
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China
Prior art keywords
weather
layer
ink layer
granulating
powdering
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CN202211040115.4A
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Chinese (zh)
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CN115464956A (en
Inventor
柯建生
郑智华
杨浩春
胡新悦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUOFEIYA HOME COLLECTION CO Ltd
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SUOFEIYA HOME COLLECTION CO Ltd
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Publication of CN115464956A publication Critical patent/CN115464956A/en
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47B—TABLES; DESKS; OFFICE FURNITURE; CABINETS; DRAWERS; GENERAL DETAILS OF FURNITURE
    • A47B95/00—Fittings for furniture
    • A47B95/04—Keyplates; Ornaments or the like
    • A47B95/043—Protecting rims, buffers or the like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/14—Printing or colouring
    • B32B38/145—Printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
    • B32B2037/243—Coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/552—Fatigue strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/71—Resistive to light or to UV
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/712—Weather resistant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2479/00—Furniture

Abstract

The invention discloses a weather-proof edge sealing tape and a processing method thereof, wherein the weather-proof edge sealing tape comprises a base material, an ink layer, a protective layer and a back coating, wherein the ink layer is coated on the front surface of the base material; the protective layer is coated on the front surface of the ink layer, and comprises PVDF fluorocarbon film; the back coating is coated on the back side of the substrate. The PVDF fluorocarbon film is designed in the protective layer of the weather-proof sealing tape, so that the weather resistance of the weather-proof sealing tape can be improved; in the process of processing the weather-proof sealing tape, the anti-ultraviolet antioxidant is added during powdering and granulating, so that the weather resistance of the base material can be improved. The weather-resistant edge sealing tape designed by the invention has high weather resistance and good ageing resistance, and can be widely applied to the technical field of edge sealing tape production.

Description

Weather-resistant sealing tape and processing method
Technical Field
The invention relates to the technical field of edge banding production, in particular to a weather-proof edge banding and a processing method.
Background
The edge sealing belt is used for fixedly sealing the section of the furniture board, so that the board is prevented from being damaged by moisture and the volatilization of pungent odor in the board is prevented, and the decorative and attractive effects are achieved. The edge sealing tape in the current industry mainly comprises an ABS edge sealing tape, an HM edge sealing tape, a PVC edge sealing tape and an acrylic edge sealing tape, and the problem that the edge sealing tape is easy to age due to insufficient weather resistance is generally existed.
Disclosure of Invention
In order to solve at least one of the above technical problems, the invention provides a weather-proof sealing tape and a processing method thereof, and the adopted technical scheme is as follows.
The weather-resistant edge sealing tape provided by the invention comprises a base material, an ink layer, a protective layer and a back coating, wherein the ink layer is coated on the front surface of the base material; the protective layer is coated on the front surface of the ink layer, and comprises PVDF fluorocarbon film; the back coating is coated on the back surface of the substrate.
In certain embodiments of the invention, the weatherstrip is made as a single tape.
In certain embodiments of the invention, the weatherable seal tape is made as a sheet seal tape.
In certain embodiments of the present invention, the protective layer comprises an AC paint layer coated between the PVDF fluorocarbon film and the ink layer.
The processing method provided by the invention is used for producing the weather-proof edge banding, and comprises the following steps: pulverizing and granulating; extruding a substrate and embossing; printing an ink layer, a protective layer and a back coating; wherein the anti-violet antioxidant is added in the process of powdering and granulating.
In certain embodiments of the invention, the substrate is extrusion embossed followed by gumming, printing, laminating and packaging.
In certain embodiments of the invention, the substrate is printed, glued, laminated, slit and packaged after extrusion embossing.
The embodiment of the invention has at least the following beneficial effects: the PVDF fluorocarbon film is designed in the protective layer of the weather-resistant edge sealing tape, so that the weather resistance can be improved; in the process of processing the weather-proof sealing tape, the anti-ultraviolet antioxidant is added during powdering and granulating, so that the weather resistance of the base material can be improved. The weather-resistant edge sealing tape designed by the invention has high weather resistance and good ageing resistance, and can be widely applied to the technical field of edge sealing tape production.
Drawings
The foregoing and/or additional aspects and advantages of the present invention will be apparent and readily appreciated from the following description of the embodiments, taken in conjunction with the accompanying drawings.
FIG. 1 is a schematic diagram of a weather-resistant tape.
Reference numerals: 100. a substrate; 101. an ink layer; 102. an AC paint layer; 103. PVDF fluorocarbon film; 104. and (3) a back coating.
Detailed Description
Embodiments of the present invention are described in detail below in conjunction with fig. 1, examples of which are illustrated in the accompanying drawings, wherein like or similar reference numerals refer to like or similar elements or elements having like or similar functionality throughout. The embodiments described below by referring to the drawings are illustrative only and are not to be construed as limiting the invention.
In the description of the present invention, it should be understood that, if the terms "center", "middle", "longitudinal", "transverse", "length", "width", "thickness", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", "axial", "radial", "circumferential", etc. are used as directions or positional relationships based on the directions shown in the drawings, the directions are merely for convenience of description and for simplification of description, and do not indicate or imply that the apparatus or element to be referred to must have a specific direction, be constructed and operated in a specific direction, and thus should not be construed as limiting the present invention. Features defining "first", "second" are used to distinguish feature names from special meanings, and furthermore, features defining "first", "second" may explicitly or implicitly include one or more such features. In the description of the present invention, unless otherwise indicated, the meaning of "a plurality" is two or more.
In the description of the present invention, it should be noted that, unless explicitly specified and limited otherwise, the terms "mounted," "connected," and "connected" are to be construed broadly, and may be either fixedly connected, detachably connected, or integrally connected, for example; can be mechanically or electrically connected; can be directly connected or indirectly connected through an intermediate medium, and can be communication between two elements. The specific meaning of the above terms in the present invention will be understood in specific cases by those of ordinary skill in the art.
The invention relates to a weather-proof edge sealing tape, which comprises a base material 100, an ink layer 101 and a protective layer, wherein the ink layer 101 is coated on the front surface of the base material 100, and the protective layer is coated on the front surface of the ink layer 101. Further, the weatherable bead tape includes a back coating 104, the back coating 104 being applied to the back side of the substrate 100.
It is understood that the ink layer 101 is a layer of ink coating that is printed on the substrate 100. Specifically, the ink coating is a pasty colloid formed by mixing pigment, binder and filler.
Further, the protection layer comprises the PVDF fluorocarbon film 103, and compared with the common edge banding coated with UV gloss oil, the weather resistance can be improved by taking the PVDF fluorocarbon film 103 as the protection layer. It will be appreciated that the protective layer may be formed from other materials that provide improved weatherability.
Further, the protective layer includes an AC paint layer 102, which plays a role in protecting the glossiness of the product, and the AC paint layer 102 is coated between the PVDF fluorocarbon film 103 and the ink layer 101. The weatherability of the AC coating is better than coating with UV varnish.
In some examples, the weatherable tape is made into a single tape after it has been glued. In some examples, the weatherable tape is slit into sheet tape strips after it has been glued.
The invention relates to a processing method, which is used for producing a weather-proof edge sealing belt, the processed weather-proof edge sealing belt has high weather resistance, and the service life of a plate and an outdoor cabinet adopting the weather-proof edge sealing belt can be prolonged.
The processing method comprises the following steps: pulverizing and granulating; extruding the substrate 100, embossing the surface of the substrate 100, and playing a decorative and attractive role; an ink layer 101, a protective layer and a back coating 104 are printed on the surface of the substrate 100. Wherein the ink layer 101 and the protective layer are coated on the front surface of the substrate 100, and the back coating 104 is coated on the back surface of the substrate 100.
The polyvinyl chloride material used for powdering and granulating is used as a main raw material, the material purity is high, the auxiliary agents such as a plasticizer, a stabilizer, a lubricant, a dye and the like are added, the thermoplastic coiled material is prepared into the base material 100 by mixing and pressing, the surface of the base material 100 is coated with the ink layer 101 to prepare grain patterns such as wood grains, stone grains and cloth grains, and the surface gloss is soft, so that the thermoplastic coiled material has heat resistance, chemical resistance, corrosion resistance, wear resistance and scratch resistance.
Further, the anti-ultraviolet antioxidant is added in the process of powdering and granulating to play a role in resisting ultraviolet rays and oxidization, so that the extruded base material 100 has weather resistance, can resist outdoor ultraviolet radiation, and compared with a common edge sealing belt, the weather-resistant edge sealing belt is ensured to have the characteristics of preventing edge trimming from being reversed white, being difficult to shrink and crack and the like by utilizing the designed base material 100.
Further, to improve weather resistance, the protective layer includes PVDF fluorocarbon film 103, and the protective layer is bonded to ink layer 101.
In some examples, the substrate 100 is extrusion embossed, then sized to prevent shrinkage cracking, printed with the ink layer 101, protective layer and back coating 104, and laminated and packaged to form a single tape.
Specifically, the processing method of the single tape is as follows.
Pulverizing and granulating: the raw materials, the auxiliary agent, the anti-violet antioxidant and the toner are uniformly mixed in a powder grinding device according to a set formula, and extruded by a granulator to form colloidal particles. Wherein the raw materials comprise PVC powder (70% by mass), calcium carbonate powder (10% by mass), an antioxidant and anti-violet agent (3-4% by mass) and a stabilizer (4% by mass).
Extruding, embossing and gluing: the colloidal particles are extruded into a substrate 100 by a single extrusion line, and simultaneously, corresponding textures can be pressed as required, and back-coating glue can be uniformly coated on the back surface to produce a plain semi-finished product.
Printing: printing colors and textures on the surface of the plain color product, and simultaneously coating AC paint to prepare a semi-finished product.
And (3) film coating: and (3) placing the plain product or the semi-finished product with the surface texture into a laminating machine for laminating, and adjusting the laminating machine to a set temperature to produce a laminated finished product.
And (3) packaging: and (5) preprocessing and packaging the finished product.
In some examples, the substrate 100 is extrusion embossed with the ink layer 101, protective layer, and back coating 104, and then sized to prevent shrinkage cracking, and then laminated, slit, and packaged to form a sheet edge seal.
Specifically, the processing method of the sheet edge sealing tape is as follows.
Pulverizing and granulating: the raw materials, the auxiliary agent, the anti-violet antioxidant and the toner are uniformly mixed in a powder grinding device according to a set formula, and extruded by a granulator to form colloidal particles. Wherein the raw materials comprise PVC powder (70% by mass), calcium carbonate powder (10% by mass), an antioxidant and anti-violet agent (3-4% by mass) and a stabilizer (4% by mass).
Extruding and embossing: and extruding and shaping by a sheet extruder, pressing corresponding textures according to the requirement, and rolling into a substrate.
Printing: color and texture are printed on the surface of the substrate while AC paint is applied.
And (3) glue coating: and (3) uniformly coating back coating glue on the back surface of the printed substrate through a glue passing machine.
And (3) film coating: and (5) putting the semi-finished product into a laminating machine for laminating, and adjusting the temperature to a set temperature to produce a semi-finished product of the laminating.
Cutting: and cutting the semi-finished product into finished products with different specifications according to requirements.
And (3) packaging: and (5) preprocessing and packaging the finished product.
In the description of the present specification, if a description appears that makes reference to the term "one embodiment," "some examples," "some embodiments," "an exemplary embodiment," "an example," "a particular example," or "some examples," etc., it is intended that the particular feature, structure, material, or characteristic described in connection with the embodiment or example be included in at least one embodiment or example of the invention. In this specification, schematic representations of the above terms do not necessarily refer to the same embodiments or examples. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The embodiments of the present invention have been described in detail with reference to the drawings, but the present invention is not limited to the above embodiments, and various changes can be made within the knowledge of one of ordinary skill in the art without departing from the spirit of the present invention.
In the description of the present invention, the terms "and" if used in the singular are intended to mean "and" as opposed to "or". For example, the patent name "a A, B" describes that what is claimed in the present invention is: a technical scheme with a subject name A and a technical scheme with a subject name B.

Claims (3)

1. A processing method, which is characterized in that: the weather-proof tape is a single tape, and the processing method comprises the following steps of
Powdering and granulating, wherein polyvinyl chloride is used as a main raw material of the powdering and granulating material, and an anti-violet antioxidant is added in the powdering and granulating process;
extruding a base material (100) and embossing, and performing gluing, printing, film coating and packaging after the base material (100) is extruded and embossed;
a printing ink layer (101), a protective layer and a back coating layer (104);
the raw materials for powdering and granulating comprise 70% by mass of PVC powder, 10% by mass of calcium carbonate powder, 3-4% by mass of antioxidant and anti-violet agent and 4% by mass of stabilizer, wherein the ink coating adopted by the ink layer (101) is pasty colloid formed by mixing pigment, connecting material and filler.
2. A processing method, which is characterized in that: the weather-proof tape is a sheet tape produced by the processing method, and the processing method comprises the following steps of
Powdering and granulating, wherein polyvinyl chloride is used as a main raw material of the powdering and granulating material, and an anti-violet antioxidant is added in the powdering and granulating process;
extruding a base material (100) and embossing, and printing, gluing, laminating, slitting and packaging after the base material (100) is extruded and embossed;
a printing ink layer (101), a protective layer and a back coating layer (104);
the raw materials for powdering and granulating comprise 70% by mass of PVC powder, 10% by mass of calcium carbonate powder, 3-4% by mass of antioxidant and anti-violet agent and 4% by mass of stabilizer, wherein the ink coating adopted by the ink layer (101) is pasty colloid formed by mixing pigment, connecting material and filler.
3. A weather-resistant tape comprising: the weather-resistant edge banding is made by the processing method as claimed in claim 1 or 2, and comprises
A base material (100);
an ink layer (101), wherein the ink layer (101) is coated on the front surface of the base material (100), and the ink coating adopted by the ink layer (101) is a pasty colloid formed by mixing pigment, binder and filler;
a protective layer coated on the front surface of the ink layer (101), the protective layer comprising a PVDF fluorocarbon film (103);
a back coating (104), the back coating (104) being coated on the back side of the substrate (100);
wherein the protective layer further comprises an AC coating layer (102), the AC coating layer (102) being coated between the PVDF fluorocarbon film (103) and the ink layer (101).
CN202211040115.4A 2022-08-29 2022-08-29 Weather-resistant sealing tape and processing method Active CN115464956B (en)

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Application Number Priority Date Filing Date Title
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CN115464956B true CN115464956B (en) 2023-11-21

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5506031A (en) * 1989-10-19 1996-04-09 Avery Dennison Corporation Plastic siding panels with outdoor weatherable embossed surfaces
CN103183900A (en) * 2013-04-10 2013-07-03 东莞欧德雅装饰材料有限公司 ABS resin edge banding for furniture and manufacturing technology thereof
CN204640994U (en) * 2015-05-13 2015-09-16 杭州谦欣塑胶科技有限公司 Outdoor environment-friendlyweather-proof weather-proof decorating film
CN204725966U (en) * 2015-05-13 2015-10-28 杭州谦欣塑胶科技有限公司 A kind of environment-friendlyweather-proof weather-proof decorating film for steel plate
CN210989152U (en) * 2019-11-04 2020-07-14 河南恒大欧派门业有限责任公司 Elastic pre-painted edge sealing belt
CN113354857A (en) * 2021-06-22 2021-09-07 湖南鼎一致远科技发展有限公司 Thermal transfer printing resin carbon ribbon with excellent weather resistance and preparation method thereof
CN215620589U (en) * 2021-09-18 2022-01-25 百晟新材料有限公司 Water-based UV surface coating treatment scratch-resistant PVC film
CN114714713A (en) * 2022-03-07 2022-07-08 江苏万拓新材料科技有限公司 Weather-resistant PVC decorative film

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5506031A (en) * 1989-10-19 1996-04-09 Avery Dennison Corporation Plastic siding panels with outdoor weatherable embossed surfaces
CN103183900A (en) * 2013-04-10 2013-07-03 东莞欧德雅装饰材料有限公司 ABS resin edge banding for furniture and manufacturing technology thereof
CN204640994U (en) * 2015-05-13 2015-09-16 杭州谦欣塑胶科技有限公司 Outdoor environment-friendlyweather-proof weather-proof decorating film
CN204725966U (en) * 2015-05-13 2015-10-28 杭州谦欣塑胶科技有限公司 A kind of environment-friendlyweather-proof weather-proof decorating film for steel plate
CN210989152U (en) * 2019-11-04 2020-07-14 河南恒大欧派门业有限责任公司 Elastic pre-painted edge sealing belt
CN113354857A (en) * 2021-06-22 2021-09-07 湖南鼎一致远科技发展有限公司 Thermal transfer printing resin carbon ribbon with excellent weather resistance and preparation method thereof
CN215620589U (en) * 2021-09-18 2022-01-25 百晟新材料有限公司 Water-based UV surface coating treatment scratch-resistant PVC film
CN114714713A (en) * 2022-03-07 2022-07-08 江苏万拓新材料科技有限公司 Weather-resistant PVC decorative film

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