CN115403299A - Preparation method and application of superfine material soil stabilizer - Google Patents

Preparation method and application of superfine material soil stabilizer Download PDF

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Publication number
CN115403299A
CN115403299A CN202210805001.8A CN202210805001A CN115403299A CN 115403299 A CN115403299 A CN 115403299A CN 202210805001 A CN202210805001 A CN 202210805001A CN 115403299 A CN115403299 A CN 115403299A
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industrial solid
solid waste
preparation
soil stabilizer
superfine
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Chinese (zh)
Inventor
李晓明
乔延德
李军
丁宁
李聪
雷安奇
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Rizhao Dehong New Material Technology Co ltd
Lianyungang Changrui Environmental Protection Technology Co ltd
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Rizhao Dehong New Material Technology Co ltd
Lianyungang Changrui Environmental Protection Technology Co ltd
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Priority to CN202210805001.8A priority Critical patent/CN115403299A/en
Publication of CN115403299A publication Critical patent/CN115403299A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/006Boron-containing compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/26Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2623Polyvinylalcohols; Polyvinylacetates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/28Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/32Polyethers, e.g. alkylphenol polyglycolether
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/38Polysaccharides or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/40Compounds containing silicon, titanium or zirconium or other organo-metallic compounds; Organo-clays; Organo-inorganic complexes
    • C04B24/42Organo-silicon compounds

Abstract

The invention discloses a preparation method and application of a superfine material soil curing agent, and belongs to the technical field of curing agents. Which comprises the following steps: collecting industrial solid wastes; homogenizing and aging the collected industrial solid waste, then removing iron, sending into a crusher for crushing, metering and batching by a microcomputer to an ultrafine ball mill for grinding, and finally obtaining ultrafine powder; mixing the obtained superfine powder with a treating agent. Tests show that the compression resistance and the bending resistance of the material are superior to those of the prior art.

Description

Preparation method and application of superfine material soil stabilizer
Technical Field
The invention belongs to the technical field of curing agents, and particularly relates to a preparation method and application of a superfine material soil curing agent.
Background
In the application of the existing silty soil curing agent, because of the influence of raw materials and exciting agents, the variety of the prepared curing agent is single, the application range of the curing agent for curing soil or gravel, sand and stone with different properties is limited, the pertinence is poor, the performance requirement is usually met by increasing the mixing amount of the curing agent in use, the good effect can not be achieved under many conditions, the construction cost is increased, and even hidden danger and secondary pollution to the environment can be brought to the engineering quality.
Disclosure of Invention
1. Problems to be solved
Aiming at the problems in the prior art, the invention provides a preparation method and application of an ultrafine material soil curing agent, and the invention innovatively introduces oxalic acid, polyethylene glycol, lignosulfonate, magnesium hexafluorosilicate hexahydrate, gamma-glycidyl ether oxypropyltrimethoxysilane, triethanolamine borate, sodium alginate, fatty alcohol-polyoxyethylene ether and other raw materials, wherein the combined use of the triethanolamine borate and the gamma-glycidyl ether oxypropyltrimethoxysilane can improve the comprehensive performance of the ultrafine material soil curing agent.
2. Technical scheme
In order to solve the above problems, the present invention adopts the following technical solutions.
A preparation method of a superfine material soil stabilizer comprises the following steps:
(1) Collecting industrial solid wastes;
(2) Homogenizing and aging the industrial solid waste collected in the step (1), then removing iron, sending into a crusher for crushing, metering and batching by a microcomputer to an ultrafine ball mill for grinding, and finally obtaining ultrafine powder;
(3) And (3) mixing the powder obtained in the step (2) with a treating agent.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comprises slag, steel slag, fly ash and desulfurized gypsum.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comes from steel plants.
In the preparation method of the superfine material soil stabilizer,
the adding mass of the treating agent in the step (3) is 60% of the mass of the industrial solid waste;
the treating agent in the step (3) comprises the following components in parts by weight:
Figure RE-GDA0003913790450000011
Figure RE-GDA0003913790450000021
in the preparation method of the superfine material soil stabilizer,
the treating agent in the step (3) comprises the following components in parts by weight:
Figure RE-GDA0003913790450000022
the application of the soil stabilizer prepared by the preparation method,
it is applied to the production of cement, high-performance concrete and assembled building components.
3. Advantageous effects
Compared with the prior art, the invention has the beneficial effects that:
the invention innovatively introduces oxalic acid, polyethylene glycol, lignosulfonate, gamma-glycidyl ether oxypropyl trimethoxysilane, triethanolamine borate, sodium alginate, fatty alcohol-polyoxyethylene ether and other raw materials, wherein the combined use of the triethanolamine borate and the gamma-glycidyl ether oxypropyl trimethoxysilane can improve the comprehensive performance of the composite material, and the compression resistance and the fracture resistance of the composite material are superior to those of the prior art.
Detailed Description
Example 1
The preparation method of the superfine material soil stabilizer comprises the following steps:
(1) Collecting industrial solid wastes;
(2) Homogenizing and aging the industrial solid waste collected in the step (1), then removing iron, sending into a crusher for crushing, metering and batching by a microcomputer to an ultrafine ball mill for grinding, and finally obtaining ultrafine powder;
(3) And (3) mixing the powder obtained in the step (2) with a treating agent.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comprises slag, steel slag, fly ash and desulfurized gypsum.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comes from steel plants.
In the preparation method of the superfine material soil stabilizer,
the adding mass of the treating agent in the step (3) is 60% of the mass of the industrial solid waste;
the treating agent in the step (3) comprises the following components in parts by weight:
Figure RE-GDA0003913790450000031
in the preparation method of the superfine material soil stabilizer,
example 2
The preparation method of the superfine material soil stabilizer comprises the following steps:
(1) Collecting industrial solid wastes;
(2) Homogenizing and aging the industrial solid waste collected in the step (1), then removing iron, sending into a crusher for crushing, metering and batching by a microcomputer to an ultrafine ball mill for grinding, and finally obtaining ultrafine powder;
(3) And (3) mixing the powder obtained in the step (2) with a treating agent.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comprises slag, steel slag, fly ash and desulfurized gypsum.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comes from steel works.
In the preparation method of the superfine material soil stabilizer,
the adding mass of the treating agent in the step (3) is 60% of the mass of the industrial solid waste;
the treating agent in the step (3) comprises the following components in parts by weight:
Figure RE-GDA0003913790450000032
example 3
The preparation method of the superfine material soil stabilizer comprises the following steps:
(1) Collecting industrial solid wastes;
(2) Homogenizing and aging the industrial solid waste collected in the step (1), then removing iron, conveying the industrial solid waste into a crusher for crushing, metering and batching the industrial solid waste by a microcomputer, and grinding the industrial solid waste into superfine powder by a superfine ball mill to obtain the superfine powder;
(3) And (3) mixing the powder obtained in the step (2) with a treating agent.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comprises slag, steel slag, fly ash and desulfurized gypsum.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comes from steel plants.
In the preparation method of the superfine material soil stabilizer,
the adding mass of the treating agent in the step (3) is 60% of the mass of the industrial solid waste;
the treating agent in the step (3) comprises the following components in parts by weight:
Figure RE-GDA0003913790450000041
example 4
The preparation method of the superfine material soil stabilizer comprises the following steps:
(1) Collecting industrial solid wastes;
(2) Homogenizing and aging the industrial solid waste collected in the step (1), then removing iron, sending into a crusher for crushing, metering and batching by a microcomputer to an ultrafine ball mill for grinding, and finally obtaining ultrafine powder;
(3) And (3) mixing the powder obtained in the step (2) with a treating agent.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comprises slag, steel slag, fly ash and desulfurized gypsum.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comes from steel works.
In the preparation method of the superfine material soil stabilizer,
in the step (3), the adding mass of the treating agent is 60% of the mass of the industrial solid waste;
the treating agent in the step (3) comprises the following components in parts by weight:
Figure RE-GDA0003913790450000042
example 5
The preparation method of the superfine material soil stabilizer comprises the following steps:
(1) Collecting industrial solid wastes;
(2) Homogenizing and aging the industrial solid waste collected in the step (1), then removing iron, sending into a crusher for crushing, metering and batching by a microcomputer to an ultrafine ball mill for grinding, and finally obtaining ultrafine powder;
(3) And (3) mixing the powder obtained in the step (2) with a treating agent.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comprises slag, steel slag, fly ash and desulfurized gypsum.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comes from steel plants.
In the preparation method of the superfine material soil stabilizer,
in the step (3), the adding mass of the treating agent is 60% of the mass of the industrial solid waste;
the treating agent in the step (3) comprises the following components in parts by weight:
Figure RE-GDA0003913790450000051
comparative example 1
The preparation method of the superfine material soil stabilizer comprises the following steps:
(1) Collecting industrial solid wastes;
(2) Homogenizing and aging the industrial solid waste collected in the step (1), then removing iron, conveying the industrial solid waste into a crusher for crushing, metering and batching the industrial solid waste by a microcomputer, and grinding the industrial solid waste into superfine powder by a superfine ball mill to obtain the superfine powder;
(3) And (3) mixing the powder obtained in the step (2) with a treating agent.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comprises slag, steel slag, fly ash and desulfurized gypsum.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comes from steel plants.
In the preparation method of the superfine material soil stabilizer,
the adding mass of the treating agent in the step (3) is 60% of the mass of the industrial solid waste;
the treating agent in the step (3) comprises the following components in parts by weight:
Figure RE-GDA0003913790450000061
comparative example 2
The preparation method of the superfine material soil stabilizer comprises the following steps:
(1) Collecting industrial solid wastes;
(2) Homogenizing and aging the industrial solid waste collected in the step (1), then removing iron, sending into a crusher for crushing, metering and batching by a microcomputer to an ultrafine ball mill for grinding, and finally obtaining ultrafine powder;
(3) And (3) mixing the powder obtained in the step (2) with a treating agent.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comprises slag, steel slag, fly ash and desulfurized gypsum.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comes from steel plants.
In the preparation method of the superfine material soil stabilizer,
the adding mass of the treating agent in the step (3) is 60% of the mass of the industrial solid waste;
the treating agent in the step (3) comprises the following components in parts by weight:
Figure RE-GDA0003913790450000062
comparative example 3
The preparation method of the superfine material soil stabilizer comprises the following steps:
(1) Collecting industrial solid wastes;
(2) Homogenizing and aging the industrial solid waste collected in the step (1), then removing iron, conveying into a crusher for crushing, metering and batching by a microcomputer, and grinding in an ultrafine ball mill to obtain ultrafine powder.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comprises slag, steel slag, fly ash and desulfurized gypsum.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comes from steel plants.
In the preparation method of the superfine material soil stabilizer,
the adding mass of the treating agent in the step (3) is 60% of the mass of the industrial solid waste;
the treating agent in the step (3) comprises the following components in parts by weight:
Figure RE-GDA0003913790450000071
comparative example 4
The preparation method of the superfine material soil stabilizer comprises the following steps:
(1) Collecting industrial solid wastes;
(2) Homogenizing and aging the industrial solid waste collected in the step (1), then removing iron, conveying the industrial solid waste into a crusher for crushing, metering and batching the industrial solid waste by a microcomputer, and grinding the industrial solid waste into superfine powder by a superfine ball mill to obtain the superfine powder;
(3) And (3) mixing the powder obtained in the step (2) with a treating agent.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comprises slag, steel slag, fly ash and desulfurized gypsum.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comes from steel plants.
In the preparation method of the superfine material soil stabilizer,
the adding mass of the treating agent in the step (3) is 60% of the mass of the industrial solid waste;
the treating agent in the step (3) comprises the following components in parts by weight:
70 parts of gamma-glycidyl ether oxypropyltrimethoxysilane,
40 parts of sodium alginate, namely 40 parts of sodium alginate,
160 parts of polyvinyl alcohol.
Comparative example 5
The preparation method of the superfine material soil stabilizer comprises the following steps:
(1) Collecting industrial solid wastes;
(2) Homogenizing and aging the industrial solid waste collected in the step (1), then removing iron, sending into a crusher for crushing, metering and batching by a microcomputer to an ultrafine ball mill for grinding, and finally obtaining ultrafine powder;
(3) And (3) mixing the powder obtained in the step (2) with a treating agent.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comprises slag, steel slag, fly ash and desulfurized gypsum.
In the preparation method of the superfine material soil stabilizer,
the industrial solid waste in the step (1) comes from steel works.
In the preparation method of the superfine material soil stabilizer,
the adding mass of the treating agent in the step (3) is 60% of the mass of the industrial solid waste;
the treating agent in the step (3) comprises the following components in parts by weight:
70 parts of gamma-glycidyl ether oxypropyltrimethoxysilane,
40 parts of sodium alginate, namely 40 parts of sodium alginate,
60 parts of triethanolamine borate.
The test scheme is as follows:
the specific test method is as follows: selecting cement (No. 45), bentonite and a soil stabilizer in a ratio of 10:2: mixing at a mass ratio of 0.5, and testing the compressive strength and the flexural strength according to GB/T32064-2015 standard; .
TABLE 1
Compressive strength Flexural strength
Comparative example 1 0.45MPa 0.68MPa
Comparative example 2 0.41MPa 0.65MPa
Comparative example 3 0.48MPa 0.67MPa
Comparative example 4 0.36MPa 0.50MPa
Comparative example 5 0.38MPa 0.52MPa
Example 1 0.85MPa 0.83MPa
Example 2 0.87MPa 0.91MPa
Example 3 0.86MPa 0.94MPa
Example 4 0.88MPa 0.97MPa
Example 5 0.91MPa 0.93MPa
In conclusion, the invention innovatively introduces oxalic acid, polyethylene glycol, lignosulfonate, gamma-glycidyl ether oxypropyltrimethoxysilane, triethanolamine borate, magnesium hexafluorosilicate hexahydrate, sodium alginate, fatty alcohol polyoxyethylene ether and other raw materials, wherein the combined use of the triethanolamine borate and the gamma-glycidyl ether oxypropyltrimethoxysilane can improve the comprehensive performance, the compression resistance and the fracture resistance of the composite material are superior to those of the prior art, and the significant difference is large.
While the invention has been described in further detail in connection with specific embodiments thereof, it will be understood that the invention is not limited thereto, and that various other modifications and substitutions may be made by those skilled in the art without departing from the spirit of the invention, which should be considered to be within the scope of the invention as defined by the appended claims.

Claims (6)

1. A preparation method of a superfine material soil stabilizer is characterized by comprising the following steps:
the method comprises the following steps:
(1) Collecting industrial solid wastes;
(2) Homogenizing and aging the industrial solid waste collected in the step (1), then removing iron, conveying the industrial solid waste into a crusher for crushing, metering and batching the industrial solid waste by a microcomputer, and grinding the industrial solid waste into superfine powder by a superfine ball mill to obtain the superfine powder;
(3) And (3) mixing the powder obtained in the step (2) with a treating agent.
2. The method for preparing the superfine material soil stabilizer according to claim 1, wherein the method comprises the following steps:
the industrial solid waste in the step (1) comprises slag, steel slag, fly ash and desulfurized gypsum.
3. The method for preparing the superfine material soil stabilizer according to claim 2, wherein the method comprises the following steps:
the industrial solid waste in the step (1) comes from steel plants.
4. The method for preparing the superfine material soil stabilizer according to claim 1, wherein the method comprises the following steps:
in the step (3), the adding mass of the treating agent is 60% of the mass of the industrial solid waste;
the treating agent in the step (3) comprises the following components in parts by weight:
Figure FDA0003736654600000011
5. the method for preparing the superfine material soil stabilizer according to claim 4, wherein the method comprises the following steps:
the treating agent in the step (3) comprises the following components in parts by weight:
Figure FDA0003736654600000012
6. use of a soil stabilizer obtained by the preparation method according to claims 1 to 5, wherein:
the curing agent is applied to curing of sandy soil, cohesive soil and the like.
CN202210805001.8A 2022-07-08 2022-07-08 Preparation method and application of superfine material soil stabilizer Pending CN115403299A (en)

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