CN115364512A - Low-temperature crystallization process for snow honey - Google Patents
Low-temperature crystallization process for snow honey Download PDFInfo
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- CN115364512A CN115364512A CN202211006877.2A CN202211006877A CN115364512A CN 115364512 A CN115364512 A CN 115364512A CN 202211006877 A CN202211006877 A CN 202211006877A CN 115364512 A CN115364512 A CN 115364512A
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- 235000012907 honey Nutrition 0.000 title claims abstract description 144
- 238000002425 crystallisation Methods 0.000 title claims abstract description 121
- 230000008025 crystallization Effects 0.000 title claims abstract description 119
- 238000000034 method Methods 0.000 title claims abstract description 20
- 238000010438 heat treatment Methods 0.000 claims abstract description 63
- 238000000926 separation method Methods 0.000 claims abstract description 42
- 238000012216 screening Methods 0.000 claims abstract description 33
- 239000013078 crystal Substances 0.000 claims abstract description 26
- 239000000463 material Substances 0.000 claims abstract description 17
- 239000012535 impurity Substances 0.000 claims abstract description 16
- 239000007788 liquid Substances 0.000 claims abstract description 10
- 238000001914 filtration Methods 0.000 claims abstract description 8
- 238000007599 discharging Methods 0.000 claims abstract description 7
- 238000007789 sealing Methods 0.000 claims description 37
- 230000005540 biological transmission Effects 0.000 claims description 32
- 238000003756 stirring Methods 0.000 claims description 30
- 238000000605 extraction Methods 0.000 claims description 17
- 238000001179 sorption measurement Methods 0.000 claims description 10
- 230000000149 penetrating effect Effects 0.000 claims description 9
- 238000003466 welding Methods 0.000 claims description 9
- 230000000903 blocking effect Effects 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 230000000694 effects Effects 0.000 claims description 7
- 230000001174 ascending effect Effects 0.000 claims description 5
- 230000004888 barrier function Effects 0.000 claims description 4
- 238000002347 injection Methods 0.000 claims description 3
- 239000007924 injection Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 241001233242 Lontra Species 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000001816 cooling Methods 0.000 abstract 1
- 238000009434 installation Methods 0.000 description 4
- 240000007313 Tilia cordata Species 0.000 description 3
- 241000219071 Malvaceae Species 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 241000257303 Hymenoptera Species 0.000 description 1
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- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003028 elevating effect Effects 0.000 description 1
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- 235000019634 flavors Nutrition 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D9/00—Crystallisation
- B01D9/0036—Crystallisation on to a bed of product crystals; Seeding
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L21/00—Marmalades, jams, jellies or the like; Products from apiculture; Preparation or treatment thereof
- A23L21/20—Products from apiculture, e.g. royal jelly or pollen; Substitutes therefor
- A23L21/25—Honey; Honey substitutes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D29/00—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor
- B01D29/01—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor with flat filtering elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D29/00—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor
- B01D29/50—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor with multiple filtering elements, characterised by their mutual disposition
- B01D29/56—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor with multiple filtering elements, characterised by their mutual disposition in series connection
- B01D29/58—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor with multiple filtering elements, characterised by their mutual disposition in series connection arranged concentrically or coaxially
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D36/00—Filter circuits or combinations of filters with other separating devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D9/00—Crystallisation
- B01D9/0018—Evaporation of components of the mixture to be separated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D9/00—Crystallisation
- B01D9/02—Crystallisation from solutions
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- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
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- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Centrifugal Separators (AREA)
Abstract
The invention discloses a low-temperature crystallization process for snow honey, which comprises the following steps of S1: selecting honey materials: the worker selects the required honey and classifies different honey; s2: and (3) honey filtration: the selected honey is separated through the screening box, the separation net plate, the limiting electric push rod and the fixed discharging plate, so that crystallized honey, impurities and liquid honey are separated, and the influence of crystal seeds and impurities of the crystallized honey on the subsequent crystallization of the liquid honey is avoided; through heating barrel to honey heating concentration for honey concentration increases, avoids its condition because of the moisture content too high leads to unable crystallization to take place, carries out cooling treatment to honey through the crystallization barrel, simultaneously through aspiration pump, the discharge pipe, compressed gas jar and input tube inject the air into honey, when accelerating its inside radiating, make inside a large amount of bubbles that produce, thereby avoid the bottom to harden when the crystallization, the bulk degree of the snow honey of having guaranteed the crystallization production, make the snow honey that the crystallization produced better.
Description
Technical Field
The invention relates to the technical field of snow honey crystallization, in particular to a low-temperature crystallization process for snow honey.
Background
The snow honey is formed after natural mature basswood honey is crystallized, because the crystallized snow honey is high in concentration and more aromatic in flavor and is convenient to store in transportation, the snow honey is obtained by bees from the basswood, the flower honey is naturally matured after repeated brewing, a high-tech physical process is used for changing a crystal nucleus finished product to be a semi-solid state, and because the properties of the snow honey are fine and white and the color of the snow honey is as white as snow, the crystallization is generally accelerated by using a low-temperature environment during the crystallization treatment of the snow honey.
However, at present, because of the high water content of part of the linden honey, the honey cannot be effectively crystallized, and meanwhile, when the linden honey is crystallized at low temperature, the honey placed in a barrel is downwards extruded under the influence of gravity, so that the bottom end of the honey produced by crystallization is hardened, and the quality of the honey is influenced.
Disclosure of Invention
The invention provides a low-temperature crystallization process for honey, which can effectively solve the problems that the honey cannot be effectively crystallized due to higher water content of part of linden honey during crystallization, and the honey placed in a barrel is downwards extruded under the influence of gravity during low-temperature crystallization, so that the bottom end of the honey subjected to crystallization is hardened, and the quality of the honey is influenced.
In order to achieve the purpose, the invention provides the following technical scheme: a low-temperature crystallization process for snow honey comprises the following steps:
s1: selecting honey materials: the working personnel select the required honey and classify different honey;
s2: and (3) honey filtration: the selected honey is separated through the screening box, the separation net plate, the limiting electric push rod and the fixed discharging plate, so that crystallized honey, impurities and liquid honey are separated, and the influence of crystal seeds and impurities of the crystallized honey on the subsequent crystallization of the liquid honey is avoided;
s3: stirring and concentrating: the honey is heated, stirred and concentrated through the fixed supporting table, the transmission motor, the transmission rod, the stirring frame, the extraction pump, the extraction pipe and the heating barrel, so that the water content of the honey is reduced, and the honey is easier to crystallize;
s4: seed crystal feeding: putting the crystal seeds into the concentrated and cooled honey, and uniformly mixing the crystal seeds through a transmission motor, a transmission rod and a stirring frame, thereby ensuring the crystallization effect;
s5: and (3) low-temperature crystallization: through sealed apron, back flow, accelerating fan, place bucket, compressed gas jar, discharge pipe, aspiration pump and input tube and to the continuous gas injection that carries on of honey, carry out comprehensive low temperature to it simultaneously and place, make it looser when the crystallization, make its crystallization environment temperature difference less simultaneously, guarantee the stability of crystallization.
Preferably, a concentrated crystallization assembly is mounted on one side of the fixed support platform, and comprises a linkage electric slide rail, a support fixing plate, a support hydraulic cylinder, a heating barrel, a movable hydraulic cylinder, a crystallization barrel, a movable electric slide rail, a sealing cover plate, a return pipe, an accelerating fan, a support fixing sleeve, a placing barrel, a compressed air tank, a discharge pipe, an air pump, an input pipe, a fixed support box, a lower piezoelectric slide rail, a drainage threaded pipe, a concentration barrel, a limiting fixing hopper and a discharge arc plate;
the placing barrel is inserted into the top end of the supporting fixed sleeve at the position of the heating barrel, the supporting hydraulic cylinder drives the heating barrel to ascend, the movable electric slide rail drives the sealing cover plate to seal and limit the heating barrel, the placing barrel is heated through the heating barrel, and meanwhile, the accelerating fan and the return pipe are used for heating and circulating internal hot air;
the movable electric sliding rail drives the sealing cover plate to seal the crystallization barrel, the lower piezoelectric sliding rail drives the input pipe to be embedded into the inner side of the placing barrel, meanwhile, the limiting fixing bucket is inserted into the inner side of the crystallization barrel, air in the compressed air tank is extracted through the discharge pipe by the air extracting pump, and the air is injected into honey in the placing barrel through the input pipe.
Preferably, the middle of the top end of the fixed supporting table is clamped with a linkage electric sliding rail, the top end of the linkage electric sliding rail is connected with a supporting fixed plate through a sliding rail seat, one side of the top end of the supporting fixed plate is connected with a supporting hydraulic cylinder in a penetrating manner, the top end of the supporting hydraulic cylinder is clamped with a heating barrel in a penetrating manner, the other side of the top end of the supporting fixed plate is connected with a moving hydraulic cylinder in a penetrating manner, the top ends of the heating barrel and the crystallizing barrel are clamped with a plurality of moving electric sliding rails at equal intervals, the top end of the moving electric sliding rail is connected with a sealing cover plate through the sliding rail seat, one ends of the heating barrel, the crystallizing barrel and the sealing cover plate are connected with a backflow pipe in a penetrating manner, and an accelerating fan is embedded in the position, corresponding to the backflow pipe, of the top end of the sealing cover plate;
the utility model discloses a crystallization device, including heating bucket and crystallization bucket, the inboard bottom of heating bucket and crystallization bucket all welds and supports fixed cover, support fixed cover top embedding and install and place the bucket, crystallization bucket side end joint has compressed gas tank, compressed gas tank top through connection has the discharge pipe, compressed gas tank top is connected with the aspiration pump through the motor cabinet, the aspiration pump inlet end is given vent to anger with the discharge pipe and is held the joint and be connected, the aspiration pump exhaust end is connected with input tube inlet end joint, is located the welding of sealed apron top of crystallization bucket position department has the fixed stay box, the inboard joint that corresponds input tube position department of fixed stay box has lower piezoelectricity slide rail, piezoelectricity slide rail one end is passed through the slide rail seat and is connected with the input tube joint down, input tube side end has cup jointed spacing fixed the fill, the symmetrical welding of crystallization bucket bottom has row material arc board, the inboard bottom of crystallization bucket is close to row material arc board position department through connection and has the drainage screwed pipe, the drainage screwed pipe side has cup jointed the centralized bucket through the screw thread.
Preferably, the supporting and fixing plate is rotatably installed at the top end of the fixed supporting table, the sealing cover plate is respectively and slidably installed at the top ends of the heating barrel and the crystallization barrel, the input ends of the linkage electric sliding rail, the heating barrel, the movable hydraulic cylinder, the crystallization barrel, the movable electric sliding rail, the accelerating fan, the air pump and the lower-voltage electric sliding rail are electrically connected with the output end of the external controller, and the input end of the external controller is electrically connected with the output end of the external power supply.
Preferably, the longitudinal section of the sealing cover plate is semicircular, one end of the input pipe is attached to one end of the sealing cover plate to slide, the input pipe is embedded into the inner side of the crystallization barrel, the inner diameter of the discharge pipe is equal to that of the input pipe, the longitudinal section of the limiting fixed hopper is trapezoidal, and the longitudinal section of the discharge arc plate is triangular.
Compared with the prior art, the invention has the following beneficial effects:
1. be provided with concentrated crystallization subassembly, it seals heating bucket and crystallization bucket to drive sealed apron by removing the electric slide rail, make can reduce the influence of external environment to inside temperature when handling, circulate gas through fan and back flow with higher speed, make the even that can guarantee inside temperature when handling, avoid the speed that the influence of difference in temperature was handled about the upper and lower, it is concentrated to the honey heating through the heating bucket, make honey concentration increase, avoid it to take place because of the too high condition that leads to unable crystallization of moisture content, cool down the processing to honey through the crystallization bucket, simultaneously through the aspiration pump, the discharge pipe, compressed gas jar and input tube inject the air into honey, when accelerating its inside heat dissipation, make inside a large amount of bubbles that produce, thereby avoid bottom hardening when the crystallization, the bulk degree of the snow honey of the production of having guaranteed the crystallization, make the snow honey of crystallization production better.
2. Be provided with the screening and concentrate the subassembly, drive the screening case by the electric push rod that rises and push down, make two conveying pipelines cup joint the joint, make the stability that can guarantee the unloading when the unloading, the condition of avoiding unloading offset appears, carry out twice filtration of thickness to honey through separation otter board and separation net box, thereby impurity in with honey and the honey separation rejection of crystallization, the native seed crystal that contains in the honey has been reduced, avoid native seed crystal to influence the actual effect and the look of honey crystallization, collect the honey of crystallization simultaneously, thereby be convenient for follow-up draw the seed crystal and handle it, thereby follow-up effect to the crystallization treatment of snow honey has been guaranteed.
3. Be provided with lift stirring subassembly, drive linkage mount and drive motor through lift electric push rod and remove for can be quick when needs stir honey and mix adjust the position according to honey, guaranteed the effect that the stirring was mixed, extract inside gas through extraction pump and extraction tube, reduce inside atmospheric pressure, thereby accelerate the concentrated speed of honey, mutually support through a plurality of parts, make the auxiliary operation that can rapid stabilization when honey is concentrated.
To sum up, concentrate the subassembly through concentrated crystallization subassembly and screening and mutually support for can obtain effectual processing before the concentrated crystallization of snow honey, avoid containing impurity and primary crystallization honey in the honey, thereby guarantee the quality of snow honey crystallization, mutually support through concentrated crystallization subassembly and lift stirring subassembly, make and to accelerate concentrated speed in concentrated receipts, guaranteed whole concentrated quality, mutually support through a plurality of subassemblies, guaranteed the speed and the quality of snow honey crystallization.
Drawings
The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and together with the description serve to explain the principles of the invention and not to limit the invention.
In the drawings:
FIG. 1 is a schematic diagram of the process flow structure of the present invention;
FIG. 2 is a schematic perspective view of the present invention;
FIG. 3 is a schematic diagram of the structure of a concentrated crystallization assembly of the present invention;
FIG. 4 is a schematic view of an installation structure of the heating bucket of the present invention;
FIG. 5 is a schematic view of the installation structure of the crystallization bucket of the present invention;
fig. 6 is a schematic view of the mounting structure of the support harness of the present invention;
FIG. 7 is a schematic structural view of a screen concentration assembly of the present invention;
FIG. 8 is a schematic view showing an installation structure of a separation screen according to the present invention;
FIG. 9 is a schematic view of the mounting structure of the stationary support ring of the present invention;
FIG. 10 is a schematic structural view of the elevating agitator assembly of the present invention;
the reference numbers in the figures: 1. fixing the support table;
2. a concentration crystallization component; 201. an electric slide rail is linked; 202. a support fixing plate; 203. a support hydraulic cylinder; 204. a heating barrel; 205. a moving hydraulic cylinder; 206. a crystallization barrel; 207. moving the electrical slide; 208. sealing the cover plate; 209. a return pipe; 210. an accelerating fan; 211. supporting the fixing sleeve; 212. placing the barrel; 213. a compressed gas tank; 214. a discharge pipe; 215. an air pump; 216. an input tube; 217. fixing the support box; 218. a lower piezoelectric slide rail; 219. a drainage threaded pipe; 220. a centralized barrel; 221. limiting and fixing the hopper; 222. discharging an arc plate;
3. screening the centralized components; 301. fixing the support plate; 302. a linkage motor; 303. supporting the mounting plate; 304. raising the electric push rod; 305. a screening box; 306. fixing the support ring; 307. separating the net box; 308. clamping the fixing ring; 309. separating the screen plate; 310. a torsion spring; 311. a discharge blocking plate; 312. an adsorption electromagnet; 313. a limiting electric push rod; 314. fixing a discharge plate; 315. a delivery pipe; 316. a limiting valve; 317. a collection box;
4. lifting the stirring component; 401. lifting the electric push rod; 402. a linkage fixing frame; 403. a drive motor; 404. a support fixing plate; 405. a transmission rod; 406. a stirring frame; 407. fixing the electromagnet; 408. clamping an electromagnet; 409. a pump; 410. and (4) extracting the tube.
Detailed Description
The preferred embodiments of the present invention will be described in conjunction with the accompanying drawings, and it will be understood that they are described herein for the purpose of illustration and explanation and not limitation.
Example (b): as shown in fig. 1-10, the present invention provides a technical solution, a low temperature crystallization process for honey, comprising the following steps:
s1: selecting honey materials: the working personnel select the required honey and classify different honey;
s2: and (3) honey filtration: the selected honey is separated through the screening box 305, the separation net box 307, the separation net plate 309, the limiting electric push rod 313 and the fixed discharging plate 314, so that crystallized honey, impurities and liquid honey are separated, and the influence of crystal seeds and impurities of the crystallized honey on the subsequent crystallization of the liquid honey is avoided;
s3: stirring and concentrating: the honey is heated, stirred and concentrated by the fixed supporting table 1, the transmission motor 403, the transmission rod 405, the stirring frame 406, the extraction pump 409, the extraction pipe 410 and the heating barrel 204, so that the water content of the honey is reduced, and the honey is easier to crystallize;
s4: seed crystal feeding: putting the crystal seeds into the concentrated and cooled honey, and uniformly mixing the crystal seeds through a transmission motor 403, a transmission rod 405 and a stirring frame 406, thereby ensuring the crystallization effect;
s5: and (3) low-temperature crystallization: through sealed apron 208, back pipe 209, accelerating fan 210, place bucket 212, compressed gas jar 213, discharge tube 214, aspiration pump 215 and input tube 216 and continue to carry out the gas injection to honey, place it at comprehensive low temperature simultaneously, make it more loose when the crystallization, make its crystallization environment temperature difference less simultaneously, guarantee the stability of crystallization.
A concentrated crystallization component 2 is arranged on one side of the fixed support platform 1, and the concentrated crystallization component 2 comprises a linkage electric slide rail 201, a support fixing plate 202, a support hydraulic cylinder 203, a heating barrel 204, a movable hydraulic cylinder 205, a crystallization barrel 206, a movable electric slide rail 207, a sealing cover plate 208, a return pipe 209, an accelerating fan 210, a support fixing sleeve 211, a placing barrel 212, a compressed air tank 213, a discharge pipe 214, an air suction pump 215, an input pipe 216, a fixed support box 217, a lower piezoelectric slide rail 218, a drainage threaded pipe 219, a concentration barrel 220, a limiting fixing hopper 221 and a discharge arc plate 222;
the placing barrel 212 is inserted into the top end of the supporting fixing sleeve 211 at the position of the heating barrel 204, the supporting hydraulic cylinder 203 drives the heating barrel 204 to ascend, the movable electric slide rail 207 drives the sealing cover plate 208 to carry out sealing limitation on the heating barrel 204, the placing barrel 212 is heated through the heating barrel 204, and meanwhile, the accelerating fan 210 and the return pipe 209 carry out heating circulation on internal hot air;
the electric slide rail 207 is moved to drive the sealing cover plate 208 to seal the crystallization barrel 206, the lower piezoelectric slide rail 218 drives the input pipe 216 to be embedded into the inner side of the placing barrel 212, the limit fixing bucket 221 is inserted into the inner side of the crystallization barrel 206, the air in the compressed air tank 213 is pumped by the air pump 215 through the discharge pipe 214, and the air is injected into the honey in the placing barrel 212 through the input pipe 216.
The middle of the top end of the fixed supporting table 1 is clamped with a linkage electric slide rail 201, the top end of the linkage electric slide rail 201 is connected with a supporting fixed plate 202 through a slide rail seat, the supporting fixed plate 202 is rotatably installed at the top end of the fixed supporting table 1, so that the supporting linkage can be effectively carried and fixed when in supporting linkage, one side of the top end of the supporting fixed plate 202 is in through connection with a supporting hydraulic cylinder 203, the top end of the supporting hydraulic cylinder 203 is clamped with a heating barrel 204, the other side of the top end of the supporting fixed plate 202 is in through connection with a moving hydraulic cylinder 205, the top end of the moving hydraulic cylinder 205 is clamped with a crystallization barrel 206, the side ends of the heating barrel 204 and the crystallization barrel 206 are in equal distance clamping with a plurality of moving electric slide rails 207, the top end of the moving electric slide rail 207 is connected with a sealing cover plate 208 through the slide rail seat, the longitudinal section of the sealing cover plate 208 is semicircular, so that effective joint clamping can be ensured when in sealing protection is required, the sealing cover plate 208 is respectively and is in sliding installation at the top ends of the heating barrel 204 and the crystallization barrel 206, one end of the sealing cover plate 208 is in through connection with a sealing cover plate 209, and a return pipe 209, and the top end of the sealing cover plate 208 is embedded with an acceleration fan 210;
the bottom ends of the inner sides of the heating barrel 204 and the crystallization barrel 206 are respectively welded with a supporting fixing sleeve 211, the top end of the supporting fixing sleeve 211 is embedded with a placing barrel 212, the side end of the crystallization barrel 206 is clamped with a compressed air tank 213, the top end of the compressed air tank 213 is connected with an exhaust pipe 214 in a penetrating way, the inner diameter of the exhaust pipe 214 is equal to that of an input pipe 216, the stability of air inlet and outlet is ensured, the condition of pipe explosion caused by air pressure difference is avoided, the top end of the compressed air tank 213 is connected with an air suction pump 215 through a motor base, the air inlet end of the air suction pump 215 is connected with the air outlet end of the exhaust pipe 214 in a clamping way, one end of the input pipe 216 is attached to and slides with one end of a sealing cover plate 208, the input pipe 216 is embedded and placed on the inner side of the crystallization barrel 206, so that the downward pressing direction and position of the input pipe 216 can be controlled when the input pipe is pressed downward, the exhaust end of the air pump 215 is connected with the air inlet end of the input pipe 216 in a clamping manner, the top end of the sealing cover plate 208 at the position of the crystallization barrel 206 is welded with a fixed support box 217, the inner side of the fixed support box 217 corresponding to the position of the input pipe 216 is connected with a lower piezoelectric slide rail 218 in a clamping manner, one end of the lower piezoelectric slide rail 218 is connected with the input pipe 216 in a clamping manner through a slide rail seat, the side end of the input pipe 216 is sleeved with a limiting fixed hopper 221, the longitudinal section of the limiting fixed hopper 221 is trapezoidal, and the longitudinal section of the discharge arc plate 222 is triangular, the guide that makes can be stable when drainage and catchment, crystallization bucket 206 bottom symmetrical weld has row material arc board 222, crystallization bucket 206 inboard bottom is close to row material arc board 222 position department through connection with drainage screwed pipe 219, drainage screwed pipe 219 side has concentrated bucket 220 through the screw cup joint, linkage electric slide rail 201, heating barrel 204, mobile hydraulic cylinder 205, crystallization bucket 206, mobile electric slide rail 207, fan 210 with higher speed, aspiration pump 215 and lower piezoelectric slide rail 218 input all with external control ware output electric connection, external control ware input and external power supply output electric connection.
A screening concentration component 3 is arranged on one side of the fixed support table 1, and the screening concentration component 3 comprises a fixed support plate 301, a linkage motor 302, a support mounting plate 303, an ascending electric push rod 304, a screening box 305, a fixed support ring 306, a separation net box 307, a clamping fixing ring 308, a separation net plate 309, a torsion spring 310, a discharge blocking plate 311, an adsorption electromagnet 312, a limiting electric push rod 313, a fixed discharge plate 314, a feed delivery pipe 315, a limiting valve 316 and a collection box 317;
the top end of the fixed support table 1 is welded with a fixed support plate 301, one end of the fixed support plate 301 is provided with a linkage motor 302 through a motor base, the top end of an output shaft of the linkage motor 302 is clamped with a support mounting plate 303, the support mounting plate 303 is rotatably connected with the fixed support plate 301 so as to effectively clamp and limit when supporting and fixing, the top end of the support mounting plate 303 is symmetrically clamped with an ascending electric push rod 304, an output shaft of the ascending electric push rod 304 is clamped with a screening box 305, one end of the inner side of the screening box 305 is welded with a fixed support ring 306, the top end of the fixed support ring 306 is embedded with a separation net box 307, the separation net box 307 is embedded and mounted at the inner side of the screening box 305 so as to obtain effective limiting support when screening, the separation caused by insufficient bearing during supporting is avoided, the middle part of the inner side of the separation net box 307 is welded with a clamping fixing ring 308, and the top end of the clamping fixing ring 308 is embedded with a separation net plate 309, one end of a separation net box 307 is welded with a torsion spring 310, the position of the torsion spring 310 corresponding to the separation net box 307 is welded with a discharge blocking plate 311, one end of the separation net box 307 corresponding to the position of the discharge blocking plate 311 is clamped with an adsorption electromagnet 312, the discharge blocking plate 311 is rotatably installed at the inner side of the separation net box 307, the adsorption electromagnet 312 is attached to the discharge blocking plate 311, so that the effective fixed limitation can be realized during the discharge, and the stability of the limiting and discharging can be ensured, one end of the separation net box 307 is clamped with a limiting electric push rod 313, an output shaft of the limiting electric push rod 313 is clamped with a fixed discharge plate 314, the bottom end of the fixed discharge plate 314 is attached to the top end of the separation net plate 309, so that the impurities attached to the top end of the separation net plate 309 can be stably and completely removed during the impurity discharge, the bottom end of the screening box 305 and the top end of the placing barrel 212 are both penetratingly connected with a feed delivery pipe 315, and one end of the feed pipe 315 is embedded with a limiting valve 316, the screening case 305 corresponds the one end joint of arranging material barrier plate 311 and has collection box 317, linkage motor 302, the electric push rod 304 that rises, adsorption electromagnet 312 and spacing electric push rod 313 input all with external control ware output electric connection.
A lifting stirring assembly 4 is arranged on one side of the fixed supporting plate 301, and the lifting stirring assembly 4 comprises a lifting electric push rod 401, a linkage fixing frame 402, a transmission motor 403, a supporting auxiliary plate 404, a transmission rod 405, a stirring frame 406, a fixed electromagnet 407, a clamping electromagnet 408, an extraction pump 409 and an extraction pipe 410;
the lifting electric push rod 401 is clamped at one end of the fixed support plate 301, the linkage fixing frame 402 is clamped at an output shaft of the lifting electric push rod 401, the linkage fixing frame 402 is slidably mounted at one end of the fixed support plate 301, so that effective supporting and fixing can be achieved during lifting, the transmission motor 403 is mounted at one end of the linkage fixing frame 402 through a motor base, the supporting auxiliary plate 404 is welded at the bottom end of the linkage fixing frame 402 corresponding to the position of the transmission motor 403, the transmission rod 405 is clamped at the bottom end of the output shaft of the transmission motor 403, the stirring frame 406 is welded at the bottom end of the side end of the transmission rod 405, the fixed electromagnet 407 is clamped at the bottom end of the supporting auxiliary plate 404, the clamping electromagnet 408 is clamped at the position of the inner side of the placing barrel 212 corresponding to the position of the fixed electromagnet 407, one end of the fixed electromagnet 407 is attached to one end of the clamping electromagnet 408, so that the barrel 212 can be quickly and stably adsorbed and fixed when fixedly clamped, the extracting pump 409 is mounted at one end of the screening box 305 through the motor base, the extracting pipe 410 is connected to the air outlet end of the extracting pump 409, the lifting electric push rod 401, the transmission motor 403, the fixed fixing frame 407, the fixed electromagnet 407, and the input ends of the clamping electromagnet 408 are electrically connected to the output end of the external controller.
The working principle and the using process of the invention are as follows: when the snow honey is crystallized, a worker inserts the placing barrel 212 into the top end of the supporting fixing sleeve 211 at the position of the heating barrel 204, the supporting hydraulic cylinder 203 drives the heating barrel 204 to ascend, the heating barrel 204 is driven to a fixed position, the lifting electric push rod 401 drives the linkage fixing frame 402 to press downwards, so that the transmission rod 405 and the stirring frame 406 are embedded into the inner side of the placing barrel 212, the fixed electromagnet 407 is attached to the side end of the clamping electromagnet 408, the fixed electromagnet 407 and the clamping electromagnet 408 are mutually adsorbed, the supporting auxiliary plate 404 is fixed to the top end of the placing barrel 212, the linkage motor 302 drives the supporting mounting plate 303 and the screening box 305 to rotate to the top end of the heating barrel 204, the lifting electric push rod 304 drives the screening box 305 to press downwards, so that the two material conveying pipes 315 are in socket joint clamping connection, the extraction pipe 410 is embedded into the inner side of the placing barrel 212, the limiting valve 316 is opened, clamping a separation net box 307 to the inner side of a screening box 305 through a fixed support ring 306, sleeving a separation net plate 309 to the position of the separation net box 307 through a clamping fixing ring 308, injecting honey to be processed to the top end of the separation net plate 309, performing coarse filtration on the honey through the separation net plate 309, separating and separating impurity contained in the honey, separating part of crystallized honey, performing fine filtration through the separation net box 307, further reducing crystal content in the honey, removing impurities contained in the honey through two times of filtration with different degrees, simultaneously reducing impurity-contained primary crystal seeds in the honey, preventing the actual effect and color formation of the honey crystal from being influenced by excessive primary crystal seeds during subsequent crystallization, driving a fixed discharge plate 314 to push the separated impurities and the crystallized honey along the separation net box 307 by a limit electric push rod 313, closing an adsorption electromagnet 312, the impurities and the crystallized honey push the discharge blocking plate 311 and are finally discharged to the inner side of the collection box 317, so that the crystallized honey is collected, workers can conveniently extract the crystal seeds from the primary crystallized honey, the quality of the crystal seeds is guaranteed, and the separated liquid honey is input to the inner side of the placing barrel 212 along the screening box 305 and the material conveying pipe 315, so that feeding is completed;
meanwhile, the transmission motor 403 drives the transmission rod 405 and the stirring frame 406 to stir the honey, the movable electric slide rail 207 drives the sealing cover plate 208 to seal and limit the heating barrel 204, the placing barrel 212 is heated through the heating barrel 204, and meanwhile, the accelerating fan 210 and the return pipe 209 perform heating circulation on the internal hot air, so that the uniformity of heating temperature can be ensured when the inside of the placing barrel 212 is heated, and the condition of uneven heating is avoided;
after the honey is uniformly mixed with the seed crystal, after the honey is mixed, the limit valve 316 is closed, the lifting electric push rod 304 drives the screening box 305 to lift, so that the two material conveying pipes 315 are separated, after the concentration is finished, the linkage motor 302 drives the support mounting plate 303 to rotate, so that the screening box 305 is moved away from the top end of the heating barrel 204, the sealing cover plate 208 is driven by the movable electric slide rail 207 to open the heating barrel 204, so that the inside is cooled, the heating barrel 204 is driven by the support hydraulic cylinder 203 to reset, when the heating barrel 204 moves downwards, the placing barrel 212 is fixed to the side ends of the support auxiliary plate 404 and the linkage fixing frame 402 by the fixed electromagnet 407 and the clamping electromagnet 408, the support fixing plate 202 is driven by the linkage electric slide rail 201 to rotate along the fixed support table 1, so that the crystal barrel 206 is rotated to the placing barrel 212 position, the crystal barrel 206 is driven to the placing barrel 212 position by the movable hydraulic cylinder 205, the work is closed, the fixed electromagnet 407 and the clamping electromagnet 408, the support plate 404 is separated from the placing barrel 212, the worker drops, the transmission motor 403 drives the transmission rod 405 and the stirring frame 406 to continuously stir the honey and the stirring rack 406, so that the honey is uniformly mixed with the honey is mixed with the honey, the honey stirring rack, the heating barrel 202, the placing rack 402 is lifted and the heating barrel fixing rack 402, and the heating barrel 202, and the heating barrel fixing rack can be reset, and the combined rack 402, and the heating barrel 202, and the combined rack can be replaced in the combined treatment rack under the concentrating rack 204;
the sealing cover plate 208 is driven by the movable electric sliding rail 207 to seal the crystallization barrel 206, the input pipe 216 is driven by the lower piezoelectric sliding rail 218 to be embedded into the placing barrel 212, the limiting fixing bucket 221 is inserted into the crystallization barrel 206, the internal temperature is reduced through the crystallization barrel 206 at the moment, the air flow is accelerated through the return pipe 209 and the accelerating fan 210, the internal temperature is balanced, air in the compressed air tank 213 is extracted through the discharge pipe 214 by the air suction pump 215 and is injected into honey in the placing barrel 212 through the input pipe 216, so that a large amount of air is filled into the honey, bubbles are generated in the honey, air is discharged with high temperature, the high temperature gas is in contact with the limiting fixing bucket 221 and is in contact with cold air, condensation is performed, water beads generated by condensation flow to the position of the discharge arc plate 222 along the limiting fixing bucket 221, water is input to the position of the concentration barrel 220 along the discharge arc plate 222 and the drainage threaded pipe 219 after collection, so that the internal water is discharged, the influence of liquid on crystallization is avoided, and simultaneously, the bottom hardening condition during crystallization is avoided by injecting a large amount of air, thereby further ensuring the looseness of crystallization, and enabling the snow to be better.
Finally, it should be noted that: although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that changes may be made in the embodiments and/or equivalents thereof without departing from the spirit and scope of the invention. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (10)
1. A low-temperature crystallization process for snow honey is characterized by comprising the following steps:
s1: selecting honey materials: the worker selects the required honey and classifies different honey;
s2: and (3) honey filtration: the selected honey is separated through a screening box (305), a separation net box (307), a separation net plate (309), a limiting electric push rod (313) and a fixed discharging plate (314), so that crystallized honey, impurities and liquid honey are separated, and the influence of crystal seeds and impurities of the crystallized honey on the subsequent crystallization of the liquid honey is avoided;
s3: stirring and concentrating: honey is heated, stirred and concentrated through a fixed supporting table (1), a transmission motor (403), a transmission rod (405), a stirring frame (406), an extraction pump (409), an extraction pipe (410) and a heating barrel (204), so that the water content of the honey is reduced, and the honey is easier to crystallize;
s4: seed crystal feeding: putting the crystal seeds into the concentrated and cooled honey, and uniformly mixing the crystal seeds through a transmission motor (403), a transmission rod (405) and a stirring frame (406), thereby ensuring the crystallization effect;
s5: and (3) low-temperature crystallization: through sealed apron (208), back flow (209), accelerating fan (210), place bucket (212), compressed gas jar (213), discharge pipe (214), aspiration pump (215) and input tube (216) to the continuous gas injection that carries on of honey, carry out comprehensive low temperature to it simultaneously and place, make it looser when the crystallization, make its crystallization environment temperature difference less simultaneously, guarantee the stability of crystallization.
2. The low-temperature crystallization process for the snow honey according to claim 1, characterized in that a concentrated crystallization component (2) is installed on one side of the fixed support platform (1), and the concentrated crystallization component (2) comprises a linkage electric slide rail (201), a support fixing plate (202), a support hydraulic cylinder (203), a heating barrel (204), a movable hydraulic cylinder (205), a crystallization barrel (206), a movable electric slide rail (207), a sealing cover plate (208), a return pipe (209), an accelerating fan (210), a support fixing sleeve (211), a placing barrel (212), a compressed gas tank (213), a discharge pipe (214), a suction pump (215), an input pipe (216), a fixed support box (217), a lower pressure electric slide rail (218), a drainage threaded pipe (219), a concentration barrel (220), a limit fixing hopper (221) and a discharge arc plate (222);
the placing barrel (212) is inserted into the top end of a supporting fixed sleeve (211) at the position of the heating barrel (204), the heating barrel (204) is driven to ascend by a supporting hydraulic cylinder (203), a sealing cover plate (208) is driven by a movable electric slide rail (207) to carry out sealing limitation on the heating barrel (204), the placing barrel (212) is heated by the heating barrel (204), and meanwhile, the internal hot air is heated and circulated by an accelerating fan (210) and a return pipe (209);
the movable electric sliding rail (207) drives the sealing cover plate (208) to seal the crystallization barrel (206), the lower piezoelectric sliding rail (218) drives the input pipe (216) to be embedded into the inner side of the placing barrel (212), meanwhile, the limiting fixing bucket (221) is inserted into the inner side of the crystallization barrel (206), the air in the compressed air tank (213) is extracted through the discharge pipe (214) by the air extracting pump (215), and the air is injected into the honey in the placing barrel (212) through the input pipe (216).
3. The low-temperature crystallization process for the snow honey as claimed in claim 1, characterized in that a linkage electric slide rail (201) is clamped in the middle of the top end of the fixed support platform (1), the top end of the linkage electric slide rail (201) is connected with a support fixing plate (202) through a slide rail seat, one side of the top end of the support fixing plate (202) is connected with a support hydraulic cylinder (203) in a penetrating way, the top end of the support hydraulic cylinder (203) is clamped with a heating barrel (204), the other side of the top end of the support fixing plate (202) is connected with a moving hydraulic cylinder (205) in a penetrating way, the top end of the moving hydraulic cylinder (205) is clamped with a crystallization barrel (206), a plurality of moving electric slide rails (207) are clamped in a uniform distance at the side ends of the heating barrel (204) and the crystallization barrel (206), the top end of the moving electric slide rail (207) is connected with a sealing cover plate (208) through a slide rail seat, one end of the heating barrel (204), one end of the crystallization barrel (206) and one end of the sealing cover plate (208) are connected with a return pipe (209) in a penetrating way, and an accelerating fan (210) is embedded in the top end of the return pipe (209) at a position corresponding to the top end of the sealing cover plate (208);
the bottom ends of the inner sides of the heating barrel (204) and the crystallization barrel (206) are respectively welded with a supporting fixed sleeve (211), the top end of the supporting fixing sleeve (211) is embedded with a placing barrel (212), a compressed air tank (213) is clamped at the side end of the crystallization barrel (206), the top end of the compressed air tank (213) is connected with a discharge pipe (214) in a penetrating way, the top end of the compressed air tank (213) is connected with an air pump (215) through a motor base, the air inlet end of the air pump (215) is connected with the air outlet end of the discharge pipe (214) in a clamping way, the exhaust end of the air pump (215) is connected with the air inlet end of the input pipe (216) in a clamping way, the top end of a sealing cover plate (208) positioned at the position of the crystallization barrel (206) is welded with a fixed supporting box (217), a lower piezoelectric slide rail (218) is clamped at the position corresponding to the input tube (216) at the inner side of the fixed supporting box (217), one end of the lower piezoelectric slide rail (218) is connected with the input tube (216) in a clamping way through a slide rail seat, a limiting fixed hopper (221) is sleeved at the side end of the input pipe (216), the bottom end of the crystallization barrel (206) is symmetrically welded with a discharging arc plate (222), a drainage threaded pipe (219) is penetratingly connected at the bottom end of the inner side of the crystallization barrel (206) close to the discharge arc plate (222), the side end of the drainage threaded pipe (219) is sleeved with a centralized barrel (220) through threads.
4. The low-temperature crystallization process for the snow honey as claimed in claim 3, wherein the supporting and fixing plate (202) is rotatably mounted at the top end of the fixed supporting platform (1), the sealing cover plate (208) is respectively slidably mounted at the top ends of the heating barrel (204) and the crystallization barrel (206), the input ends of the linkage electric slide rail (201), the heating barrel (204), the moving hydraulic cylinder (205), the crystallization barrel (206), the moving electric slide rail (207), the accelerating fan (210), the air suction pump (215) and the lower piezoelectric slide rail (218) are electrically connected with the output end of an external controller, and the input end of the external controller is electrically connected with the output end of an external power supply.
5. A low temperature crystallisation process for snow honey according to claim 3, characterised in that the longitudinal section of the sealing cover plate (208) is semicircular, one end of the input tube (216) is fitted to one end of the sealing cover plate (208) to slide, the input tube (216) is embedded inside the crystallisation bucket (206), the internal diameter of the discharge tube (214) is equal to the internal diameter of the input tube (216), the longitudinal section of the limiting fixed bucket (221) is trapezoidal, and the longitudinal section of the discharge arc plate (222) is triangular.
6. The low-temperature crystallization process for the snow honey according to claim 1, characterized in that one side of the fixed support platform (1) is provided with a screening concentration component (3), and the screening concentration component (3) comprises a fixed support plate (301), a linkage motor (302), a support mounting plate (303), an ascending electric push rod (304), a screening box (305), a fixed support ring (306), a separation net box (307), a clamping fixing ring (308), a separation net plate (309), a torsion spring (310), a discharge blocking plate (311), an adsorption electromagnet (312), a limiting electric push rod (313), a fixed discharge plate (314), a material conveying pipe (315), a limiting valve (316) and a collection box (317);
the welding of fixed support platform (1) top has fixed support plate (301), linkage motor (302) is installed through the motor cabinet to fixed support plate (301) one end, linkage motor (302) output shaft top joint has support mounting panel (303), support mounting panel (303) top symmetry joint has the electric push rod (304) that rises, electric push rod (304) output shaft joint has screening case (305), screening case (305) inboard one end welding has fixed support ring (306), fixed support ring (306) top embedding is installed separation net box (307), the welding of separation net box (307) inboard middle part has the solid fixed ring of joint (308), the solid fixed ring of joint (308) top embedding is installed separation otter board (309), separation net box (307) one end welding has torque spring (310), torque spring (310) correspond separation net box (307) position department welding has row material barrier plate (311), separation net box (307) one end corresponds row material barrier plate (311) position department joint has adsorption electromagnet (312), separation net box (307) one end joint has spacing electric push rod (313), spacing electric push rod (313) fixed support plate (313) top end joint (314) and all discharge barrel (315) are connected with material conveying barrel (305), restriction valve (316) are installed in conveying pipeline (315) one end embedding, screening case (305) correspond the one end joint of arranging material barrier plate (311) and have collection box (317).
7. A low temperature crystallization process for snow honey according to claim 6, characterized in that the supporting mounting plate (303) is rotatably connected with the fixed supporting plate (301), the separating net box (307) is embedded and mounted inside the screening box (305), and the input ends of the linkage motor (302), the ascending electric push rod (304), the adsorption electromagnet (312) and the limiting electric push rod (313) are all electrically connected with the output end of the external controller.
8. A low temperature crystallization process for snow honey according to claim 6, characterized in that the discharge baffle plate (311) is rotatably installed inside the separation screen box (307), the adsorption electromagnet (312) is attached to the discharge baffle plate (311), and the bottom end of the fixed discharge plate (314) is attached to the top end of the separation screen plate (309).
9. A low temperature crystallization process for snow honey according to claim 1, characterized in that one side of the fixed support plate (301) is equipped with a lifting stirring component (4), the lifting stirring component (4) comprises a lifting electric push rod (401), a linkage fixing frame (402), a transmission motor (403), a support auxiliary plate (404), a transmission rod (405), a stirring frame (406), a fixed electromagnet (407), a clamping electromagnet (408), an extraction pump (409) and an extraction pipe (410);
fixed support plate (301) one end joint has lift electric push rod (401), lift electric push rod (401) output shaft joint has linkage mount (402), transmission motor (403) are installed through the motor cabinet to linkage mount (402) one end, linkage mount (402) bottom corresponds transmission motor (403) position department welding and has support accessory plate (404), transmission motor (403) output shaft bottom joint has transfer line (405), the welding of transfer line (405) side bottom has stirring frame (406), support accessory plate (404) bottom joint has fixed electro-magnet (407), it has joint electro-magnet (408) to place bucket (212) inboard corresponding fixed electro-magnet (407) position department joint, extraction pump (409) are installed through the motor cabinet to screening case (305) one end, extraction pump (409) give vent to anger the end joint and have extraction pipe (410).
10. The low-temperature crystallization process for the snow honey as claimed in claim 9, wherein the linkage fixing frame (402) is slidably mounted at one end of the fixing support plate (301), one end of the fixing electromagnet (407) is attached to one end of the clamping electromagnet (408), and input ends of the lifting electric push rod (401), the transmission motor (403), the fixing electromagnet (407), the clamping electromagnet (408) and the extraction pump (409) are electrically connected with an output end of an external controller.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211006877.2A CN115364512A (en) | 2022-08-22 | 2022-08-22 | Low-temperature crystallization process for snow honey |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211006877.2A CN115364512A (en) | 2022-08-22 | 2022-08-22 | Low-temperature crystallization process for snow honey |
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| Publication Number | Publication Date |
|---|---|
| CN115364512A true CN115364512A (en) | 2022-11-22 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202211006877.2A Withdrawn CN115364512A (en) | 2022-08-22 | 2022-08-22 | Low-temperature crystallization process for snow honey |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117224993A (en) * | 2023-11-11 | 2023-12-15 | 河北华晨药业集团有限公司 | Crystallization reactor for pharmaceutical chemical industry |
-
2022
- 2022-08-22 CN CN202211006877.2A patent/CN115364512A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117224993A (en) * | 2023-11-11 | 2023-12-15 | 河北华晨药业集团有限公司 | Crystallization reactor for pharmaceutical chemical industry |
| CN117224993B (en) * | 2023-11-11 | 2024-01-12 | 河北华晨药业集团有限公司 | Crystallization reactor for pharmaceutical chemical industry |
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Application publication date: 20221122 |